BR0013335A - Processo para preparar em um único reator misturas poliméricas tendo uma ampla distribuição de peso molecular - Google Patents

Processo para preparar em um único reator misturas poliméricas tendo uma ampla distribuição de peso molecular

Info

Publication number
BR0013335A
BR0013335A BR0013335-3A BR0013335A BR0013335A BR 0013335 A BR0013335 A BR 0013335A BR 0013335 A BR0013335 A BR 0013335A BR 0013335 A BR0013335 A BR 0013335A
Authority
BR
Brazil
Prior art keywords
single reactor
molecular weight
weight distribution
wide molecular
preparing polymeric
Prior art date
Application number
BR0013335-3A
Other languages
English (en)
Other versions
BR0013335B1 (pt
Inventor
Michael K Laughner
Debra J Mangold
Deepak R Parikh
Original Assignee
Dupont Dow Elastomers Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dupont Dow Elastomers Llc filed Critical Dupont Dow Elastomers Llc
Publication of BR0013335A publication Critical patent/BR0013335A/pt
Publication of BR0013335B1 publication Critical patent/BR0013335B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/083—Copolymers of ethene with aliphatic polyenes, i.e. containing more than one unsaturated bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

"PROCESSO PARA PREPARAR PM UM úNICO REATOR MISTURAS POLIMéRICAS TENDO UMA AMPLA DISTRIBUIçãO DE PESO MOLECULAR". Misturas poliméricas baseadas em etileno tendo uma MWD de pelo menos 2 foram produzidas em um reator único usando um sistema de catalisadores de geometria restringida (CGC) . O processo compreende as etapas de contatar sob condições de polimerização e em um vaso de reação único (i) etileno, (ii) pelo menos uma <244>-olefina C~ 3~-C~ 20~, (iii) opcionalmente, pelo menos um polieno, e (iv) um sistema de CGC misturado.
BRPI0013335-3A 1999-08-19 2000-08-16 mistura polimérica baseada em etileno, e artigo BR0013335B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14985399P 1999-08-19 1999-08-19
PCT/US2000/022500 WO2001014434A1 (en) 1999-08-19 2000-08-16 Process for preparing in a single reactor polymer blends having a broad molecular weight distribution

Publications (2)

Publication Number Publication Date
BR0013335A true BR0013335A (pt) 2002-04-02
BR0013335B1 BR0013335B1 (pt) 2010-05-04

Family

ID=22532064

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0013335-3A BR0013335B1 (pt) 1999-08-19 2000-08-16 mistura polimérica baseada em etileno, e artigo

Country Status (13)

Country Link
US (2) US6369176B1 (pt)
EP (1) EP1214365B1 (pt)
JP (2) JP5633996B2 (pt)
KR (1) KR100700765B1 (pt)
CN (1) CN1210314C (pt)
AT (1) ATE319751T1 (pt)
AU (1) AU772057B2 (pt)
BR (1) BR0013335B1 (pt)
CA (1) CA2382182C (pt)
DE (1) DE60026545T2 (pt)
ES (1) ES2255506T3 (pt)
MX (1) MXPA02001763A (pt)
WO (1) WO2001014434A1 (pt)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0619827B1 (en) * 1991-12-30 1996-06-12 The Dow Chemical Company Ethylene interpolymer polymerizations
KR100623106B1 (ko) * 1998-11-02 2006-09-13 다우 글로벌 테크놀로지스 인크. 전단시닝 에틸렌／α―올레핀 인터폴리머 및 그의 제조 방법
US6369176B1 (en) * 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
CA2323307A1 (en) * 2000-10-16 2002-04-16 Peter Jackson Crosslinked, heat shrinkable polypropylene compositions
MY131000A (en) * 2001-03-16 2007-07-31 Dow Global Technologies Inc High melt strength polymers and method of making same
WO2002077045A2 (en) * 2001-03-27 2002-10-03 Union Carbide Chemicals & Plastics Technology Corporation Gas phase process for polymers with group 4 metal complex catalyst addition
RU2326904C2 (ru) * 2002-06-04 2008-06-20 Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн Полимерные композиции и способ изготовления труб
JP4482448B2 (ja) * 2002-08-02 2010-06-16 ダウ グローバル テクノロジーズ インコーポレイティド ４−アリール−置換三環状インデニル誘導体含有第４族金属錯体
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) * 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) * 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
EP1641847A2 (en) 2003-07-09 2006-04-05 DSM IP Assets B.V. Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene
US7000131B2 (en) * 2003-11-14 2006-02-14 Via Technologies, Inc. Apparatus and method for assuming mastership of a bus
US7906586B2 (en) * 2003-12-09 2011-03-15 Dow Global Technologies Llc Thermoplastic olefinic compositions
US20050209403A1 (en) * 2003-12-09 2005-09-22 Walton Kim L Thermoplastic olefinic compositions
ATE504349T1 (de) * 2004-06-16 2011-04-15 Dow Global Technologies Inc Verfahren zur auswahl von polymerisationsmodifikatoren
US7456231B2 (en) * 2005-02-02 2008-11-25 Shawcor Ltd. Radiation-crosslinked polyolefin compositions
KR101338569B1 (ko) * 2005-05-12 2013-12-12 다우 글로벌 테크놀로지스 엘엘씨 감소된 광택을 갖는 열성형된 압출 시팅
KR20080055907A (ko) 2005-09-12 2008-06-19 다우 글로벌 테크놀로지스 인크. 에틸렌/α-올레핀 조성물, 그로부터 제조된 물품 및 그의제조 방법
CN101003595B (zh) * 2006-01-18 2010-12-15 住友化学株式会社 制备乙烯-α-烯烃-多烯无规共聚物的方法
EP2078055B1 (en) 2006-11-01 2017-11-22 Dow Global Technologies LLC Blends and aqueous dispersions comprising nonpolar polyolefin and polyurethane
TWI438238B (zh) * 2006-12-21 2014-05-21 Dow Global Technologies Llc 聚烯烴組成物與由其製備之物件，以及其之製造方法
EP2294102B1 (en) * 2008-06-30 2013-08-21 Dow Global Technologies LLC Polyolefin compositions and articles prepared therefrom and methods of making the same
CN102203146B (zh) * 2008-12-01 2015-01-21 三井化学株式会社 共聚物、橡胶组合物、交联橡胶、交联发泡体以及它们的用途
US20100227966A1 (en) * 2009-03-06 2010-09-09 Shawcor Ltd. Moisture-crosslinked polyolefin compositions
US9102824B2 (en) * 2009-07-15 2015-08-11 Dow Global Technologies Llc Polymer compositions, methods of making the same, and articles prepared from the same
US8679639B2 (en) * 2009-11-24 2014-03-25 Dow Global Technologies Llc Extrusion coating composition
JP5476172B2 (ja) * 2010-03-18 2014-04-23 三井化学株式会社 難燃性ゴム組成物およびゴム成形体
EP2571935B1 (en) 2010-05-21 2014-12-17 Dow Global Technologies LLC Thermoplastic compositions and formed articles thereof
JP2014133785A (ja) * 2013-01-08 2014-07-24 Mitsui Chemicals Inc エチレン・炭素数４〜２０のα−オレフィン・非共役ポリエン共重合体からなるフィルム
US10208193B2 (en) 2013-06-24 2019-02-19 Dow Global Technologies Llc Reinforced polypropylene composition
WO2014209085A1 (ko) 2013-06-28 2014-12-31 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
JP2015536368A (ja) 2013-06-28 2015-12-21 エルジー・ケム・リミテッド ジエンを含む三元系弾性共重合体およびその製造方法
KR101585204B1 (ko) 2013-06-28 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
US9650460B2 (en) 2013-06-28 2017-05-16 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
US9803037B1 (en) * 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
KR101846412B1 (ko) * 2016-12-06 2018-05-18 한화케미칼 주식회사 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀
CN109627366A (zh) * 2017-10-09 2019-04-16 中国石化扬子石油化工有限公司 一种茂金属催化剂及在环烯烃共聚物制备中的应用
CN109251265A (zh) * 2018-07-20 2019-01-22 北京理工大学 一种cgc型胺芴稀土金属催化剂、制备方法及应用
WO2020169552A1 (en) 2019-02-18 2020-08-27 Total Research & Technology Feluy Polyolefin compositions and process to produce such compositions by the addition of ionomers
KR20210076701A (ko) 2019-12-16 2021-06-24 현대자동차주식회사 연료전지용 에틸렌-프로필렌-디엔 공중합체 및 그 제조방법
BR112022012694A2 (pt) * 2019-12-27 2022-09-06 Dow Global Technologies Llc Copolímero em multiblocos de etileno/buteno e processo para produzir o mesmo
KR102348519B1 (ko) * 2020-04-16 2022-01-10 주식회사 엘지화학 전기 절연성이 우수한 에틸렌/알파-올레핀 공중합체
EP4047026A4 (en) * 2020-04-16 2023-01-18 Lg Chem, Ltd. ETHYLENE/ALPHA-OLEFIN COPOLYMER WITH EXCELLENT ELECTRICAL INSULATION
WO2021210755A1 (ko) * 2020-04-16 2021-10-21 주식회사 엘지화학 전기 절연성이 우수한 에틸렌/알파-올레핀 공중합체
KR102387101B1 (ko) * 2020-04-16 2022-04-18 주식회사 엘지화학 에틸렌/알파-올레핀 공중합체를 포함하는 봉지재 필름용 조성물 및 이를 포함하는 봉지재 필름
EP3988614A4 (en) * 2020-04-16 2022-10-12 LG Chem, Ltd. ENCAPSULATING FILM COMPOSITION COMPRISING ETHYLENE/ALPHA-OLEFIN COPOLYMER AND ENCAPSULATING FILM COMPRISING THE SAME
WO2021210749A1 (ko) 2020-04-16 2021-10-21 주식회사 엘지화학 에틸렌/알파-올레핀 공중합체를 포함하는 봉지재 필름용 조성물 및 이를 포함하는 봉지재 필름
US20230002526A1 (en) 2020-04-16 2023-01-05 Lg Chem, Ltd. Ethylene/Alpha-Olefin Copolymer with Excellent Electrical Insulation

Family Cites Families (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
NO164547C (no) * 1983-06-06 1990-10-17 Exxon Research Engineering Co Katalysatorsystem og en polymeringsprosess som benytter systemet.
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4786697A (en) 1983-06-15 1988-11-22 Exxon Research & Engineering Co. Molecular weight distribution modification in a tubular reactor
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5096867A (en) 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5231106A (en) 1988-05-18 1993-07-27 Novo Nordisk A/S Azacyclic carboxylic acid derivatives and their preparation and use
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5453510A (en) 1990-07-13 1995-09-26 Burroughs Wellcome Co. Neuromuscular blocking agents
CA2068939C (en) 1991-05-20 1996-04-09 Takashi Ueda Olefin polymerization catalyst and olefin polymerization
JP3275211B2 (ja) 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5359015A (en) 1991-11-07 1994-10-25 Exxon Chemical Patents Inc. Metallocene catalysts and their production and use
US6545088B1 (en) * 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
EP0619827B1 (en) 1991-12-30 1996-06-12 The Dow Chemical Company Ethylene interpolymer polymerizations
WO1993014132A1 (en) 1992-01-06 1993-07-22 The Dow Chemical Company Improved catalyst composition
JP3160067B2 (ja) * 1992-01-16 2001-04-23 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
JP3197314B2 (ja) * 1992-02-24 2001-08-13 三井化学株式会社 分子量分布の広いポリオレフィンの製造方法
US5374696A (en) 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
JPH06136195A (ja) 1992-09-08 1994-05-17 Mitsui Petrochem Ind Ltd エチレン系共重合体組成物
CA2103380C (en) 1992-11-19 2002-07-02 Mitsui Chemicals, Inc. Ethylene/.alpha.-olefin copolymer composition, graft modified ethylene/.alpha.-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process
CA2103401C (en) 1992-11-19 2002-12-17 Mamoru Takahashi Ethylene copolymer composition
US5420220A (en) 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
ATE195538T1 (de) 1993-01-29 2000-09-15 Dow Chemical Co Äthylen copolymerisation
DE69430795T2 (de) 1993-02-05 2002-11-28 Idemitsu Kosan Co Polyethylen, thermoplastische harzzusammensetzung dieselbige enthaltend und verfahren zur herstellung von polyethylen
US5470993A (en) 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
ES2096475T3 (es) 1993-06-24 1997-03-01 Dow Chemical Co Complejos de titanio (ii) o circonio (ii) y catalizadores de polimerizacion por adicion obtenidos a partir de los mismos.
WO1995014024A1 (fr) 1993-11-18 1995-05-26 Idemitsu Kosan Co., Ltd. Compose de metal de transition, catalyseur de polymerisation d'olefines et procede pour produire un polymere d'olefines en utilisant ce catalyseur
WO1995015985A1 (fr) 1993-12-08 1995-06-15 Asahi Kasei Kogyo Kabushiki Kaisha Nouveau catalyseur de polymerisation d'olefines et procede pour polymeriser des olefines a l'aide de ce catalyseur
EP0664304B1 (en) 1993-12-27 1999-08-04 Mitsui Chemicals, Inc. Olefin polymerization catalyst and process for olefin polymerization
US5648438A (en) 1994-04-01 1997-07-15 Exxon Chemical Patents, Inc. Process for producing polymers with multimodal molecular weight distributions
US5442018A (en) 1994-04-01 1995-08-15 Union Carbide Chemicals & Plastics Technology Corporation Ethylene polymerization using a titanium and vanadium catalyst system in staged reactors
US5486632A (en) 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
US5677382A (en) 1994-12-19 1997-10-14 Japan Synthetic Rubber Co., Ltd. Ethylene-α-olefin-non-conjugated diene copolymer rubber composition
US5491246A (en) 1995-04-24 1996-02-13 The Dow Chemical Company Synthesis of group 4 metal diene complexes
US5882750A (en) 1995-07-03 1999-03-16 Mobil Oil Corporation Single reactor bimodal HMW-HDPE film resin with improved bubble stability
CA2188722A1 (en) * 1995-10-26 1997-04-27 George Norris Foster Process for preparing an in situ polyethylene blend
WO1997042237A1 (en) 1996-05-03 1997-11-13 Dsm N.V. A process for making polyolefins having broad molecular weight distributions
JP2000513399A (ja) * 1996-06-17 2000-10-10 エクソン・ケミカル・パテンツ・インク オレフィン重合用の混合遷移金属触媒系
JPH10330414A (ja) * 1997-06-03 1998-12-15 Nippon Polyolefin Kk オレフィン重合用触媒およびポリオレフィンの製造方法
EP0926166A4 (en) 1996-08-21 2000-07-19 Japan Polyolefins Co Ltd CATALYTIC COMPONENT FOR POLYMERIZATION OF OLEFINS, CATALYST FOR POLYMERIZATION OF OLEFINS AND PROCESS FOR THE PREPARATION OF POLYOLEFINS
US5965756A (en) 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
CA2287963A1 (en) 1997-04-30 1998-11-05 Debra J. Mangold Ethylene/alpha-olefin/diene interpolymers and their preparation
EP0881237A1 (en) 1997-05-26 1998-12-02 Fina Research S.A. Process to produce bimodal polyolefins with metallocene catalysts using two reaction zones
GB9712663D0 (en) * 1997-06-16 1997-08-20 Borealis As Process
KR20000068602A (ko) 1997-07-22 2000-11-25 나까니시 히로유끼 에틸렌/α-올레핀 공중합체, 그 조성물 및, 공중합체 및 조성물
US6069213A (en) 1997-12-16 2000-05-30 Union Carbide Chemicals & Plastics Technology Corporation Mixed catalyst system
AR022608A1 (es) 1999-02-17 2002-09-04 Dow Chemical Co Producto interpolimerico aromatico de alfa-olefina/vinilo o vinilideno y proceso para su elaboracion mediante sistemas catalizadores multiples
US6369176B1 (en) * 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution

Also Published As

Publication number Publication date
ES2255506T3 (es) 2006-07-01
EP1214365B1 (en) 2006-03-08
CN1368982A (zh) 2002-09-11
JP5633996B2 (ja) 2014-12-03
EP1214365A1 (en) 2002-06-19
US6369176B1 (en) 2002-04-09
AU1638701A (en) 2001-03-19
AU772057B2 (en) 2004-04-08
WO2001014434A1 (en) 2001-03-01
MXPA02001763A (es) 2003-09-25
DE60026545D1 (de) 2006-05-04
JP6165685B2 (ja) 2017-07-19
CA2382182A1 (en) 2001-03-01
US6610800B2 (en) 2003-08-26
KR100700765B1 (ko) 2007-03-27
JP2003507541A (ja) 2003-02-25
KR20020029752A (ko) 2002-04-19
DE60026545T2 (de) 2006-08-10
ATE319751T1 (de) 2006-03-15
JP2014208840A (ja) 2014-11-06
BR0013335B1 (pt) 2010-05-04
CN1210314C (zh) 2005-07-13
CA2382182C (en) 2009-10-06
US20020143122A1 (en) 2002-10-03

Similar Documents

Publication Publication Date Title
BR0013335A (pt) Processo para preparar em um único reator misturas poliméricas tendo uma ampla distribuição de peso molecular
BR9913083A (pt) Processo de polietileno em reator duplo usando um catalisador de fosfinimina
BR9813438B1 (pt) processo para polimerizaÇço de olefinas, pelÍcula e polÍmero de etileno-alfa-olefina.
MY137183A (en) Method of making interpolymers and products made therefrom
EA199800005A1 (ru) Способ взаимного перехода несовместимых катализаторов полимеризации
BR9708645A (pt) Processo de polimerização para produzir elastÈmero de poliolefina, cocatalisador gerador de cátion para ativar um procatalisador de metaloceno, elastÈmero de poliolefina possuindo uma combinação única de propriedades e produtos fabricados a partir do mesmo
BR9505777A (pt) Processo contínuo para a polimerizaçao em fase gasosa de alfa-olefínas
BR9914227A (pt) Sistema catalisador, processo para preparar uma poliolefina, e, uso de um sistema catalisador
SG64939A1 (en) Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer
CA2193882A1 (en) Polymerization catalyst systems, their production and use
ES2169057T3 (es) Procedimiento para la preparacion de poliolefinas.
AU7119800A (en) Preparation of ultra-high-molecular-weight polyethylene
BG100904A (en) Metallocenes, method for their preparation and their application in catalysts for olefine polymerization
CO4990981A1 (es) Composicion de poliolefina en donde se presenta el maximo peso molecular en la parte de la composicion que tiene el contenido de comonomero mas alto
ES2163428T3 (es) Procedimiento de produccion de polietileno que tiene una amplia distribucion de peso molecular.
ES2082233T3 (es) Catalizadores soportados con monociclopentadienilo de metal de transicion para la polimerizacion de olefinas.
BR9402680A (pt) Processo para preparar um produto de organo-aluminóxi, sistema catalisador e processo para polimenrização de olefina.
EP0770629A3 (en) A process for preparing an in situ polyethylene blend
DE59508140D1 (de) Verfahren zur herstellung eines trägerkatalysators für die polymerisation von ethylen und copolymerisation von ethylen mit alpha-olefinen
BR9600991A (pt) Sólido catalítico para a (co)polimerização de etileno processo para sua preparação sistema catalitico para a (co) polimerização de etileno e processo de (co)polimerização de etileno
DE69722152D1 (de) Verbesserte Polymerausbeute durch geträgerte Metallocenkatalysatoren
BR0114228B1 (pt) &#34;precesso para preativar catalisadores para a polimerização de olefinas c2-c20.&#34;.
SG81898A1 (en) Olefin polymerization catalyst component, olefin polymerization catalyst and process for producing olefin polymer
BR9404332A (pt) Sistema catalítico utilizável para a polimerização de alfa-olefinas, cocatalisador não halogenado utilizável para a polimerização das alfa-olefinas, e, processo para a polimerização de alfa-olefinas.
AU7540700A (en) Modified supported catalysts for the polymerization of olefins

Legal Events

Date Code Title Description
B25D Requested change of name of applicant approved

Owner name: DUPONT PERFORMANCE ELASTOMERS L.L.C. (US)

Free format text: ALTERADO DE: DUPONT DOW ELASTOMERS L.L.C.

B25D Requested change of name of applicant approved

Owner name: WENBEN INC. (US)

Free format text: ALTERADO DE: DUPONT PERFORMANCE ELASTOMERS L.L.C.

B25A Requested transfer of rights approved

Owner name: DOW GLOBAL TECHNOLOGIES INC. (US)

Free format text: TRANSFERIDO DE: WENBEN INC.

B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 16/08/2000, OBSERVADAS AS CONDICOES LEGAIS.

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 16.08.2020