CN1210314C - 在一个单一反应器中制备具有宽分子量分布的聚合物共混物的方法 - Google Patents
在一个单一反应器中制备具有宽分子量分布的聚合物共混物的方法 Download PDFInfo
- Publication number
- CN1210314C CN1210314C CNB008115648A CN00811564A CN1210314C CN 1210314 C CN1210314 C CN 1210314C CN B008115648 A CNB008115648 A CN B008115648A CN 00811564 A CN00811564 A CN 00811564A CN 1210314 C CN1210314 C CN 1210314C
- Authority
- CN
- China
- Prior art keywords
- alkyl
- blend polymer
- catalyzer
- blend
- ethene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009826 distribution Methods 0.000 title claims description 15
- 229920002959 polymer blend Polymers 0.000 title abstract description 5
- 238000004519 manufacturing process Methods 0.000 title description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 145
- 239000003054 catalyst Substances 0.000 claims abstract description 113
- 238000000034 method Methods 0.000 claims abstract description 55
- 239000004711 α-olefin Substances 0.000 claims abstract description 53
- 238000006243 chemical reaction Methods 0.000 claims abstract description 35
- 239000000203 mixture Substances 0.000 claims description 203
- 229920000642 polymer Polymers 0.000 claims description 141
- -1 tetrahydro indenyl Chemical group 0.000 claims description 90
- 229910052751 metal Inorganic materials 0.000 claims description 84
- 239000002184 metal Substances 0.000 claims description 84
- 125000000217 alkyl group Chemical group 0.000 claims description 74
- 239000000126 substance Substances 0.000 claims description 56
- 230000003647 oxidation Effects 0.000 claims description 48
- 238000007254 oxidation reaction Methods 0.000 claims description 48
- 239000002585 base Substances 0.000 claims description 41
- 239000003446 ligand Substances 0.000 claims description 39
- 238000002360 preparation method Methods 0.000 claims description 39
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 38
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 claims description 37
- 230000009257 reactivity Effects 0.000 claims description 34
- 150000002500 ions Chemical class 0.000 claims description 30
- 230000007935 neutral effect Effects 0.000 claims description 28
- 229910052757 nitrogen Inorganic materials 0.000 claims description 28
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 25
- 239000010936 titanium Substances 0.000 claims description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- 230000000379 polymerizing effect Effects 0.000 claims description 22
- 239000005864 Sulphur Substances 0.000 claims description 21
- 150000001450 anions Chemical class 0.000 claims description 20
- 239000001257 hydrogen Substances 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 20
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 19
- 239000004327 boric acid Substances 0.000 claims description 19
- 229920001577 copolymer Polymers 0.000 claims description 19
- 125000004429 atom Chemical group 0.000 claims description 18
- 230000000737 periodic effect Effects 0.000 claims description 18
- 239000004215 Carbon black (E152) Substances 0.000 claims description 17
- 229930195733 hydrocarbon Natural products 0.000 claims description 17
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 17
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 16
- 229910052698 phosphorus Inorganic materials 0.000 claims description 16
- 239000011574 phosphorus Substances 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 239000001301 oxygen Substances 0.000 claims description 15
- 229910000077 silane Inorganic materials 0.000 claims description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 239000000470 constituent Substances 0.000 claims description 14
- 229920002397 thermoplastic olefin Polymers 0.000 claims description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 13
- 229910052796 boron Inorganic materials 0.000 claims description 13
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 125000001188 haloalkyl group Chemical group 0.000 claims description 12
- 238000000518 rheometry Methods 0.000 claims description 12
- OOFBCIMKQKUUQF-UHFFFAOYSA-N C=CC=CC.[Ti].C[SiH](C1=C(C=C2C=C3C=CC=C3C=C12)C)C Chemical compound C=CC=CC.[Ti].C[SiH](C1=C(C=C2C=C3C=CC=C3C=C12)C)C OOFBCIMKQKUUQF-UHFFFAOYSA-N 0.000 claims description 11
- DFSWNYUWLQKNQP-UHFFFAOYSA-N [Ti].CC=CC=C Chemical compound [Ti].CC=CC=C DFSWNYUWLQKNQP-UHFFFAOYSA-N 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical class CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 claims description 11
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims description 9
- 125000002947 alkylene group Chemical group 0.000 claims description 9
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 9
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 150000004820 halides Chemical class 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- 238000001746 injection moulding Methods 0.000 claims description 7
- QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 7
- 238000003856 thermoforming Methods 0.000 claims description 7
- GDDAJHJRAKOILH-QFXXITGJSA-N (2e,5e)-octa-2,5-diene Chemical compound CC\C=C\C\C=C\C GDDAJHJRAKOILH-QFXXITGJSA-N 0.000 claims description 6
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 6
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims description 6
- 125000005103 alkyl silyl group Chemical group 0.000 claims description 6
- 238000000748 compression moulding Methods 0.000 claims description 6
- 239000010408 film Substances 0.000 claims description 6
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 125000005265 dialkylamine group Chemical group 0.000 claims description 5
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 5
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 claims description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
- 239000002879 Lewis base Substances 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 125000005237 alkyleneamino group Chemical group 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 4
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 4
- 150000004678 hydrides Chemical class 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 150000007527 lewis bases Chemical class 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 3
- 125000003800 germyl group Chemical group [H][Ge]([H])([H])[*] 0.000 claims description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000010276 construction Methods 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims description 2
- 235000013305 food Nutrition 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 239000005022 packaging material Substances 0.000 claims description 2
- 239000012071 phase Substances 0.000 claims description 2
- 238000001175 rotational moulding Methods 0.000 claims description 2
- 239000004902 Softening Agent Substances 0.000 claims 3
- 239000000945 filler Substances 0.000 claims 3
- 239000003921 oil Substances 0.000 claims 3
- 239000012745 toughening agent Substances 0.000 claims 3
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 abstract description 58
- 238000006116 polymerization reaction Methods 0.000 abstract description 36
- 230000008569 process Effects 0.000 abstract description 8
- 150000004291 polyenes Chemical class 0.000 abstract description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 52
- 239000002904 solvent Substances 0.000 description 29
- 150000001993 dienes Chemical class 0.000 description 26
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 26
- 239000000178 monomer Substances 0.000 description 23
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 22
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- 238000002844 melting Methods 0.000 description 12
- 230000008018 melting Effects 0.000 description 12
- 230000000704 physical effect Effects 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 238000000113 differential scanning calorimetry Methods 0.000 description 11
- 150000002430 hydrocarbons Chemical group 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 10
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 10
- 150000001336 alkenes Chemical class 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 10
- 229920002943 EPDM rubber Polymers 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- 238000001816 cooling Methods 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 9
- 229920000098 polyolefin Polymers 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 8
- 241001441571 Hiodontidae Species 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 8
- 238000005868 electrolysis reaction Methods 0.000 description 8
- 229920001897 terpolymer Polymers 0.000 description 8
- 230000003213 activating effect Effects 0.000 description 7
- 239000012190 activator Substances 0.000 description 7
- 239000000806 elastomer Substances 0.000 description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 150000003863 ammonium salts Chemical class 0.000 description 6
- 150000001721 carbon Chemical group 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- 241000894007 species Species 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 230000021615 conjugation Effects 0.000 description 5
- 150000004696 coordination complex Chemical class 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 229910052723 transition metal Inorganic materials 0.000 description 5
- 150000003624 transition metals Chemical class 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- RURFJXKOXIWFJX-UHFFFAOYSA-N (2,3,4,6-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C=C(F)C(F)=C1F RURFJXKOXIWFJX-UHFFFAOYSA-N 0.000 description 4
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 4
- 229920003314 Elvaloy® Polymers 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 4
- 229910000085 borane Inorganic materials 0.000 description 4
- 238000006758 bulk electrolysis reaction Methods 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000001939 inductive effect Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical class O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- PMZBHPUNQNKBOA-UHFFFAOYSA-N 5-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=CC(C(O)=O)=CC(C(O)=O)=C1 PMZBHPUNQNKBOA-UHFFFAOYSA-N 0.000 description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 239000012968 metallocene catalyst Substances 0.000 description 3
- CUXQLKLUPGTTKL-UHFFFAOYSA-M microcosmic salt Chemical compound [NH4+].[Na+].OP([O-])([O-])=O CUXQLKLUPGTTKL-UHFFFAOYSA-M 0.000 description 3
- DMEKUKDWAIXWSL-UHFFFAOYSA-N n,n-dimethyl-7-nitro-9h-fluoren-2-amine Chemical compound [O-][N+](=O)C1=CC=C2C3=CC=C(N(C)C)C=C3CC2=C1 DMEKUKDWAIXWSL-UHFFFAOYSA-N 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 229960001866 silicon dioxide Drugs 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- AFVDZBIIBXWASR-AATRIKPKSA-N (E)-1,3,5-hexatriene Chemical compound C=C\C=C\C=C AFVDZBIIBXWASR-AATRIKPKSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 2
- BKILWHYRLBCASZ-UHFFFAOYSA-M 2-[bis(2-hydroxyethyl)amino]ethanol;2-hydroxypropanoate;phenylmercury(1+) Chemical compound CC(O)C([O-])=O.[Hg+]C1=CC=CC=C1.OCCN(CCO)CCO BKILWHYRLBCASZ-UHFFFAOYSA-M 0.000 description 2
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- PNWSHHILERSSLF-UHFFFAOYSA-N 4-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=CC=C(C(O)=O)C=C1C(O)=O PNWSHHILERSSLF-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 2
- 229910000528 Na alloy Inorganic materials 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 229920003182 Surlyn® Polymers 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910052728 basic metal Inorganic materials 0.000 description 2
- 150000003818 basic metals Chemical group 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N cycloheptane Chemical compound C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- OTTZHAVKAVGASB-UHFFFAOYSA-N hept-2-ene Chemical compound CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 description 2
- JAGYXYUAYDLKNO-UHFFFAOYSA-N hepta-2,5-diene Chemical compound CC=CCC=CC JAGYXYUAYDLKNO-UHFFFAOYSA-N 0.000 description 2
- 239000002638 heterogeneous catalyst Substances 0.000 description 2
- DPUXQWOMYBMHRN-UHFFFAOYSA-N hexa-2,3-diene Chemical compound CCC=C=CC DPUXQWOMYBMHRN-UHFFFAOYSA-N 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 150000008040 ionic compounds Chemical class 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 150000002738 metalloids Chemical class 0.000 description 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 2
- OXUCOTSGWGNWGC-UHFFFAOYSA-N octane Chemical compound CCCCCCC[CH2-] OXUCOTSGWGNWGC-UHFFFAOYSA-N 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- WEMQMWWWCBYPOV-UHFFFAOYSA-N s-indacene Chemical compound C=1C2=CC=CC2=CC2=CC=CC2=1 WEMQMWWWCBYPOV-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 125000005353 silylalkyl group Chemical group 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000007614 solvation Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 description 1
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 1
- PPWUTZVGSFPZOC-UHFFFAOYSA-N 1-methyl-2,3,3a,4-tetrahydro-1h-indene Chemical compound C1C=CC=C2C(C)CCC21 PPWUTZVGSFPZOC-UHFFFAOYSA-N 0.000 description 1
- UUFQTNFCRMXOAE-UHFFFAOYSA-N 1-methylmethylene Chemical compound C[CH] UUFQTNFCRMXOAE-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- CMSUNVGIWAFNBG-UHFFFAOYSA-N 2,4-dimethylpenta-1,3-diene Chemical compound CC(C)=CC(C)=C CMSUNVGIWAFNBG-UHFFFAOYSA-N 0.000 description 1
- JFLOKYMVJXMYFI-UHFFFAOYSA-N 3-ethylpenta-1,3-diene Chemical compound CCC(=CC)C=C JFLOKYMVJXMYFI-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- MFFLHSOMUHHGKG-UHFFFAOYSA-N CC(C)NC(C)C.OB(O)O Chemical compound CC(C)NC(C)C.OB(O)O MFFLHSOMUHHGKG-UHFFFAOYSA-N 0.000 description 1
- CQMWBOOZPOZPKY-UHFFFAOYSA-N CC(C=CC=C1)=C1OC1=C(C)C=CC=C1.CC(C=CC=C1)=C1OC1=C(C)C=CC=C1.CC(C=CC=C1)=C1OC1=C(C)C=CC=C1.OB(O)O Chemical compound CC(C=CC=C1)=C1OC1=C(C)C=CC=C1.CC(C=CC=C1)=C1OC1=C(C)C=CC=C1.CC(C=CC=C1)=C1OC1=C(C)C=CC=C1.OB(O)O CQMWBOOZPOZPKY-UHFFFAOYSA-N 0.000 description 1
- BWOMHUALSIOVHY-UHFFFAOYSA-N CC(C=CC=C1)=C1SC1=C(C)C=CC=C1.OB(O)O Chemical compound CC(C=CC=C1)=C1SC1=C(C)C=CC=C1.OB(O)O BWOMHUALSIOVHY-UHFFFAOYSA-N 0.000 description 1
- JCIVHWUGDBWOCH-UHFFFAOYSA-N CCCN(CCC)CCC.OB(O)OC(C(F)=CC(F)=C1F)=C1F Chemical compound CCCN(CCC)CCC.OB(O)OC(C(F)=CC(F)=C1F)=C1F JCIVHWUGDBWOCH-UHFFFAOYSA-N 0.000 description 1
- QLMGTNHGAKDLTL-UHFFFAOYSA-N CCN(CC)CC.OB(O)OC(C(F)=CC(F)=C1F)=C1F Chemical compound CCN(CC)CC.OB(O)OC(C(F)=CC(F)=C1F)=C1F QLMGTNHGAKDLTL-UHFFFAOYSA-N 0.000 description 1
- DTVXJURYFDTPRW-UHFFFAOYSA-N CN(C(C)(C)C)C.FC1=C(C(=CC(=C1F)F)F)OB(O)O Chemical compound CN(C(C)(C)C)C.FC1=C(C(=CC(=C1F)F)F)OB(O)O DTVXJURYFDTPRW-UHFFFAOYSA-N 0.000 description 1
- MKCYGUSUATUWAJ-UHFFFAOYSA-N CN(C)C.OB(O)OC(C(F)=CC(F)=C1F)=C1F Chemical compound CN(C)C.OB(O)OC(C(F)=CC(F)=C1F)=C1F MKCYGUSUATUWAJ-UHFFFAOYSA-N 0.000 description 1
- XJONFIGVOQMBIP-UHFFFAOYSA-L Cl[Zr](Cl)C1C=CC=C1 Chemical compound Cl[Zr](Cl)C1C=CC=C1 XJONFIGVOQMBIP-UHFFFAOYSA-L 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000007818 Grignard reagent Substances 0.000 description 1
- 229910000645 Hg alloy Inorganic materials 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 229910000574 NaK Inorganic materials 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- YKPONVOKUCHKIW-UHFFFAOYSA-N OB(O)O.C(C=C1)=CC=C1C1=CC=CC=C1.O.O.O Chemical compound OB(O)O.C(C=C1)=CC=C1C1=CC=CC=C1.O.O.O YKPONVOKUCHKIW-UHFFFAOYSA-N 0.000 description 1
- OKLLJDSNZXDTSL-UHFFFAOYSA-N OB(O)O.C(C=C1)=CC=C1C1=CC=CC=C1.S Chemical compound OB(O)O.C(C=C1)=CC=C1C1=CC=CC=C1.S OKLLJDSNZXDTSL-UHFFFAOYSA-N 0.000 description 1
- UFWCTKIALLYOOL-UHFFFAOYSA-N OB(O)O.C(CC1)CCC1NC1CCCCC1 Chemical compound OB(O)O.C(CC1)CCC1NC1CCCCC1 UFWCTKIALLYOOL-UHFFFAOYSA-N 0.000 description 1
- AYDQIZKZTQHYIY-UHFFFAOYSA-N OC(=O)C1(C)CC(C(O)=O)=CC=C1 Chemical compound OC(=O)C1(C)CC(C(O)=O)=CC=C1 AYDQIZKZTQHYIY-UHFFFAOYSA-N 0.000 description 1
- KVOZXXSUSRZIKD-UHFFFAOYSA-N Prop-2-enylcyclohexane Chemical compound C=CCC1CCCCC1 KVOZXXSUSRZIKD-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- UMAPFJZTGMTFIR-UHFFFAOYSA-N [2,3,5,6-tetrafluoro-4-tri(propan-2-yl)silylphenoxy]boronic acid Chemical compound CC(C)[Si](C(C)C)(C(C)C)C1=C(F)C(F)=C(OB(O)O)C(F)=C1F UMAPFJZTGMTFIR-UHFFFAOYSA-N 0.000 description 1
- BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 1
- QQZWQOQLMGMKDC-UHFFFAOYSA-N [4-[tert-butyl(dimethyl)silyl]-2,3,5,6-tetrafluorophenoxy]boronic acid Chemical compound CC(C)(C)[Si](C)(C)C1=C(F)C(F)=C(OB(O)O)C(F)=C1F QQZWQOQLMGMKDC-UHFFFAOYSA-N 0.000 description 1
- MFWDFTZSKUUNLN-UHFFFAOYSA-N [O].FC=1C(=C(C(=C(C1)F)F)F)F Chemical compound [O].FC=1C(=C(C(=C(C1)F)F)F)F MFWDFTZSKUUNLN-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 150000001334 alicyclic compounds Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000005530 alkylenedioxy group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000001399 aluminium compounds Chemical class 0.000 description 1
- 229940024548 aluminum oxide Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- UORVGPXVDQYIDP-BJUDXGSMSA-N borane Chemical class [10BH3] UORVGPXVDQYIDP-BJUDXGSMSA-N 0.000 description 1
- SRTFLHALJBGRMP-UHFFFAOYSA-N boric acid;n,n-diethylethanamine Chemical compound OB(O)O.CCN(CC)CC SRTFLHALJBGRMP-UHFFFAOYSA-N 0.000 description 1
- LYSQGYSICZCRKO-UHFFFAOYSA-N boric acid;n,n-dimethylmethanamine Chemical compound CN(C)C.OB(O)O LYSQGYSICZCRKO-UHFFFAOYSA-N 0.000 description 1
- NIEOJMQLFYNMAI-UHFFFAOYSA-N boric acid;n,n-dipropylpropan-1-amine Chemical compound OB(O)O.CCCN(CCC)CCC NIEOJMQLFYNMAI-UHFFFAOYSA-N 0.000 description 1
- DXWSZLNAWOWMAN-UHFFFAOYSA-N boric acid;tetrabutylazanium Chemical compound OB(O)O.CCCC[N+](CCCC)(CCCC)CCCC DXWSZLNAWOWMAN-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000011951 cationic catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- CHVJITGCYZJHLR-UHFFFAOYSA-N cyclohepta-1,3,5-triene Chemical compound C1C=CC=CC=C1 CHVJITGCYZJHLR-UHFFFAOYSA-N 0.000 description 1
- UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 description 1
- NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 125000002897 diene group Chemical group 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 1
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 210000003195 fascia Anatomy 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- CXHZYOISZDAYCU-UHFFFAOYSA-N hepta-1,3,6-triene Chemical compound C=CCC=CC=C CXHZYOISZDAYCU-UHFFFAOYSA-N 0.000 description 1
- GEAWFZNTIFJMHR-UHFFFAOYSA-N hepta-1,6-diene Chemical compound C=CCCCC=C GEAWFZNTIFJMHR-UHFFFAOYSA-N 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 125000005027 hydroxyaryl group Chemical group 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 150000002467 indacenes Chemical class 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000001457 metallic cations Chemical class 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229920005623 miscible polymer blend Polymers 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- PYLWMHQQBFSUBP-UHFFFAOYSA-N monofluorobenzene Chemical compound FC1=CC=CC=C1 PYLWMHQQBFSUBP-UHFFFAOYSA-N 0.000 description 1
- URXNVXOMQQCBHS-UHFFFAOYSA-N naphthalene;sodium Chemical compound [Na].C1=CC=CC2=CC=CC=C21 URXNVXOMQQCBHS-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- WYROLENTHWJFLR-ACLDMZEESA-N queuine Chemical compound C1=2C(=O)NC(N)=NC=2NC=C1CN[C@H]1C=C[C@H](O)[C@@H]1O WYROLENTHWJFLR-ACLDMZEESA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 230000003938 response to stress Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 238000000974 shear rheometry Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- SCABQASLNUQUKD-UHFFFAOYSA-N silylium Chemical compound [SiH3+] SCABQASLNUQUKD-UHFFFAOYSA-N 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- NQRYJNQNLNOLGT-UHFFFAOYSA-N tetrahydropyridine hydrochloride Natural products C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-O tributylazanium Chemical compound CCCC[NH+](CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-O 0.000 description 1
- RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000012725 vapour phase polymerization Methods 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/083—Copolymers of ethene with aliphatic polyenes, i.e. containing more than one unsaturated bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Wrappers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
批次 | 1 | 2 | 3 | 4 | 5 | 6 |
催化剂* | A | A/B | B | A | A/B | B |
温度℃ | 89.5 | 89.4 | 89.9 | 109.9 | 109.8 | 109.9 |
1-辛烯,g | 351.4 | 351.1 | 350.9 | 450.2 | 451.2 | 450.1 |
Ti,μmolc | 1.50 | 1.25 | 1.25 | 1.75 | 1.75 | 1.50 |
B/Ti | 4.00 | 3.96 | 3.96 | 4.03 | 4.03 | 4.00 |
Al/Ti | 5.00 | 5.20 | 5.20 | 5.14 | 5.14 | 5.00 |
放热℃ | 8.7 | 9.2 | 6.0 | 4.1 | 8.2 | 5.3 |
C2流量,最大 | 20.1 | 19.7 | 15.8 | 21.3 | 25.0 | 20.6 |
C2末端速率 | 0 | 0.4 | 0 | 0 | 0 | 0 |
所用C2,g | 54.8 | 59.4 | 52.1 | 43.3 | 62.8 | 50.5 |
计算的效率 | 763,105 | 992.506 | 870,864 | 516,887 | 749,018 | 703,031 |
溶剂,g | 1504.3 | 1505.4 | 1500.2 | 1402.7 | 1402.3 | 1405.0 |
压力,psig | 457.4 | 456.8 | 458.1 | 456.3 | 456.6 | 456.1 |
C2负载,g | 212.0 | 214.6 | 212.6 | 181.0 | 182.5 | 182.2 |
C2压力,psig | 444.3 | 443.8 | 445.6 | 437.7 | 439.7 | 439.2 |
H2mmole | 8.0 | 8.0 | 8.0 | 8.1 | 8.2 | 8.2 |
Mw | 72,400 | 130,700 | 198,800 | 49,500 | 87,000 | 125,200 |
Mn | 39,100 | 54.600 | 102,500 | 25,800 | 35,800 | 63,000 |
MWD | 1.85 | 2.39 | 1.94 | 1.92 | 2.43 | 1.99 |
Mw1 | - | 222,827 | - | - | 150,081 | - |
Mw2 | - | 74,454 | - | - | 51,747 | - |
MW比Hi/Lo | - | 2.99 | - | - | 2.90 | - |
I2 | 6.27 | 0.796 | 0.16 | 30.99 | 4.35 | 0.99 |
I10 | 38.62 | 6.00 | 0.93 | 188.02 | 33.35 | 6.41 |
I10/I2 | 6.2 | 7.5 | 5.8 | 6.1 | 7.7 | 6.5 |
DSC溶融峰温度Tm | 67.69 | 62.87 | 59.91 | 65.42 | 59.65 | 50.95 |
%结晶 | 23.09 | 19.85 | 17.89 | 21.07 | 19.58 | 15.06 |
DSCTg | -51.69 | -54.99 | -51.35 | -52.56 | -53.47 | -58.13 |
Tc(开始) | 53.03 | 50.35 | 48.58 | 53.19 | 48.31 | 40.37 |
Tc(峰值) | 50.09 | 47.89 | 45.95 | 47.24 | 44.13 | 36.18 |
J/g | 70.05 | 61.26 | 53.02 | 54.55 | 54.49 | 48.64 |
批次 | 7 | 8 | 9(对比例) |
催化剂* | B | C | C/B |
温度℃ | 109.9 | 110.1 | 109.6 |
辛烯,g | 750.7 | 750.9 | 750.6 |
Ti,μmole | 1.50 | 1.50 | 1.40 |
B/Ti | 4.00 | 4.00 | 3.96 |
Al/Ti | 5.00 | 5.00 | 5.00 |
放热℃ | 3.5 | 3.9 | 1.9 |
C2流量,最大 | 17.1 | 22.3 | 10.2 |
C2末端速率 | 0 | 0.1 | 0.2 |
所用C2,g | 38.7 | 28.3 | 13.1 |
计算的效率 | 538,701 | 393,199 | 196,149 |
溶剂,g | 1078.2 | 1081.2 | 1081.5 |
压力,psig | 456.1 | 455.5 | 456.3 |
C2负载,g | 185.7 | 184.9 | 186.6 |
C2压力 | 443.4 | 442.1 | 443.4 |
H2mmole | 1.6 | 1.6 | 1.6 |
Mw | 142,400 | 324,700 | 253,600 |
Mn | 74,100 | 182,000 | 104.000 |
MWD | 1.92 | 1.78 | 2.44 |
Mw1 | - | - | 359,791 |
Mw2 | - | - | 124,571 |
MW比Hi/Lo | - | - | 2.89 |
DSC溶融峰 | 宽 | 66.51 | 78.38 |
%结晶 | 10.23 | 23.20 | 20.19 |
DSC Tg | -59.77 | -46.05 | -61.49 |
Tc(开始)#1 | 10.10 | 66.51 | 68.39 |
冷却峰#1 | 0.31 | 63.94 | 65.79 |
J/G#1 | 30.54 | 67.74 | 54.56 |
Tc(开始)#2 | - | - | - |
冷却峰#2 | - | - | -0.89 |
批次 | 催化剂百分数A* | 催化剂百分数B* | 丙烯质量g | ENB质量g | 温度,℃ | H2mmol | 乙烯质量g | 乙烯分压,psig |
10 | 100% | 0% | 200.8 | 40.2 | 99.8 | 12.50 | 143.7 | 318.3 |
11 | 75% | 25% | 200 | 40.3 | 99.9 | 12.10 | 148.6 | 321.4 |
12 | 50% | 50% | 202 | 40.1 | 100.3 | 12.00 | 149.5 | 328.8 |
13 | 25% | 75% | 201.2 | 40.3 | 99.7 | 12.2 | 149.6 | 329.7 |
14 | 0% | 100% | 201.1 | 40.2 | 100.4 | 12.3 | 150.3 | 335 |
批次 | 催化剂百分数A | 效率MM lbPE/lb Ti | Tiμmole | B/Ti比 | Al/Ti比 | 放热℃ | 最大温度℃ | 溶剂质量g | 总压力,psig |
10 | 100 | 1.36 | 1 | 3 | 10 | 3.3 | 103.1 | 1401.3 | 461.50 |
11 | 75 | 1.82 | 1 | 3 | 10 | 3.7 | 103.6 | 1403.8 | 458.50 |
12 | 50 | 1.71 | 1.5 | 3 | 10 | 9.3 | 109.6 | 1403.1 | 463.90 |
13 | 25 | 1.67 | 1.25 | 3 | 10 | 3.4 | 103.1 | 1406.3 | 462.4 |
14 | 0 | 1.15 | 1.5 | 3 | 10 | 2.2 | 102.6 | 1405.1 | 462.2 |
批次 | GPCMw | GPC Mn | GPCMWD | Mw1 | Mw2 | Hi/Lo Mw比 | Tc(开始)C | TcC | Tg C | Tm C |
10 | 174700 | 87700 | 1.99 | - | 52353 | - | 10.98 | 5.73 | -40.42 | 3.77 |
11 | 165500 | 63700 | 2.6 | 174700 | 51165 | 4.15 | 12.73 | 7.21 | -41.58 | 9.01 |
12 | 123800 | 41700 | 2.97 | 217056 | 51423 | 3.96 | 14.95 | 9.17 | -41.68 | 7.3 |
13 | 93900 | 33100 | 2.84 | 202696 | 56900 | 3.73 | 18.87 | 12.04 | -41.52 | 10.41 |
14 | 56900 | 30200 | 1.88 | 191659 | - | - | 21.62 | 13.59 | -42.94 | 6.73 |
批次 | FTIR±法 | FTIR±乙烯百分数 | FTIR±丙烯百分数 | FTIR±ENB百分数 | 乙烯/丙烯比 | 密度 | %Xtal |
10 | EPDM | 67.1 | 26.2 | 6.7 | 71.9/28.1 | 0.867 | 10.47 |
11 | EPDM | 66.4 | 27.8 | 5.8 | 70.5/29.5 | 0.865 | 10.78 |
12 | EPDM | 66.4 | 28.6 | 5.0 | 69.9/30.1 | 0.865 | 11.71 |
13 | EPDM | 66.9 | 28.3 | 4.8 | 70.3/29.7 | 0.866 | 13.51 |
14 | EPDM | 66.0 | 30.2 | 3.9 | 68.6/31.4 | 0.863 | 13.83 |
批次 | 催化剂百分数A | 断裂拉伸强度(psi) | 断裂伸长率(%) | I2@190C/2.16kg | I10@190C/10.1kg | I10/I2@190C |
10 | 100 | 381 | 1988 | 0.20 | 1.23 | 6.26 |
11 | 75 | 445 | 1699 | 0.23 | 1.50 | 6.51 |
12 | 50 | 403 | 1904 | 0.80 | 6.64 | 8.28 |
13 | 25 | 438 | 1999 | 2.42 | 21.52 | 8.88 |
14 | 0 | 102 | 306 | 17.14 | 102.48 | 5.98 |
批次 | 催化剂百分数A* | 催化剂百分数B* | 丁烯质量,g | ENB质量,g | 温度℃ | H2mmol | 乙烯质量,g | 乙烯分压psig |
15 | 100% | 0% | 265.5 | 40.0 | 100 | 12.2 | 185.6 | 399.7 |
16 | 75% | 25% | 265.2 | 40.5 | 100.1 | 12.2 | 183 | 395.3 |
17 | 50% | 50% | 265.4 | 40.4 | 99.4 | 12 | 183.6 | 392.9 |
18 | 25% | 75% | 265.5 | 40.4 | 99.7 | 12.1 | 182 | 391.3 |
19 | 0% | 100% | 265 | 40.2 | 100.3 | 12.2 | 182.4 | 399.4 |
批次 | 催化剂百分数A | 效率MM lbPE/lb Ti | Tiμmole | B/Ti比 | Al/Ti比 | 放热℃ | 最大温度℃ | 溶剂质量,g | 总压力psig |
15 | 100% | 1.94 | 1 | 3 | 10 | 4.7 | 104.7 | 1401 | 463.5 |
16 | 75% | 2.96 | 0.75 | 3 | 10 | 5.7 | 105.8 | 1401.1 | 463.7 |
17 | 50% | 2.4 | 1 | 3 | 10 | 7.2 | 106.6 | 1405.7 | 462.2 |
18 | 25% | 2.34 | 0.75 | 3 | 10 | 4.3 | 104 | 1401.4 | 462 |
19 | 0% | 0.96 | 2.5 | 3 | 10 | 3.6 | 103.9 | 1406.6 | 467.5 |
批次 | GPCMw | GPC Mn | GPCMWD | Mw1 | Mw2 | Hi/LoMw比 | Tc(开始)C | Tc(峰)C | Tg C | Tm C |
15 | 163800 | 87900 | 1.86 | - | 56773 | - | 33.13 | 28.52 | -44.47 | 43.99 |
16 | 145300 | 60400 | 2.41 | 163800 | 53056 | 3.06 | 41.88 | 33.94 | -44.71 | 40.38 |
17 | 113400 | 45300 | 2.5 | 173465 | 51459 | 3.38 | 44.19 | 38.94 | -42.80 | 42.65 |
18 | 84700 | 36300 | 2.33 | 179418 | 55200 | 3.68 | 47.22 | 42.81 | -47.01 | 58.52 |
19 | 55200 | 29900 | 1.85 | 189163 | - | - | 50.18 | 46.67 | -42.15 | 62.74 |
批次 | FTIR±法 | FTIR±乙烯百分数 | FTIR±丁烯百分数 | FTIR±ENB百分数 | 乙烯/丁烯比 | 密度 | %Xtal |
15 | EBDM | 75.68 | 19.16 | 5.16 | 79.80/20.20 | 0.882 | 13.95 |
16 | EBDM | 75.47 | 19.89 | 4.65 | 79.14/20.86 | 0.885 | 15.87 |
17 | EBDM | 76.65 | 19.38 | 3.98 | 79.82/20.18 | 0.882 | 16.87 |
18 | EBDM | 76.98 | 19.75 | 3.27 | 79.58/20.42 | 0.886 | 18.29 |
19 | EBDM | 79.31 | 18.18 | 2.52 | 81.35/18.65 | 0.888 | 18.78 |
批次 | 催化剂百分数A | 断裂拉伸强度(psi) | 断裂伸长率(%) | I2@190C/2.16kg | I10@190C/10.1kg | I10/I2@190C |
15 | 100 | 1142 | 784 | 0.19 | 1.29 | 6.79 |
16 | 75 | 1185 | 842 | 0.37 | 2.67 | 7.22 |
17 | 50 | 1154 | 908 | 1.03 | 7.86 | 7.63 |
18 | 25 | 1288 | 1208 | 3.98 | 31.4 | 7.88 |
19 | 0 | 1054 | 1052 | 16.2 | 95.3 | 5.89 |
批次 | EB-1 | EB-2 | EB-3 |
催化剂* | A | B | A/B |
温度℃ | 100.4 | 100.0 | 100.1 |
1-丁烯,g | 351.4 | 351.1 | 351.2 |
Ti,μmole | 1.0 | 0.50 | 0.65 |
B/Ti | 3.0 | 3.0 | 3.0 |
Al/Ti | 10.0 | 10.0 | 10.0 |
放热℃ | 10.2 | 5.9 | 4.0 |
C2流量,最大 | 22.6 | 17.6 | 17.3 |
C2末端速率 | 0 | 0 | 0 |
所用C2,g | 85.9 | 57.4 | 52.0 |
计算的效率 | 1,794,134 | 2,369,572 | 1,669,132 |
溶剂,g | 1401.5 | 1406.1 | 1403.2 |
压力,psig | 455.1 | 452.4 | 452.4 |
C2负载,g | 171.8 | 174.2 | 172.5 |
C2压力,psig | 376.5 | 373.8 | 374.5 |
H2mmole | 6.6 | 6.4 | 6.6 |
Mw | 62,800 | 178,300 | 137,500 |
Mn | 32,800 | 86,500 | 57,300 |
MWD | 1.91 | 2.06 | 2.40 |
Mw1 | - | - | 69,213 |
Mw2 | - | - | 207,262 |
MW比Hi/Lo | - | - | 2.995 |
I2 | 10.5 | 0.31 | 0.82 |
I10 | 64.8 | 1.83 | 5.45 |
I10/I2 | 6.17 | 5.90 | 6.65 |
密度(g/cm3) | 0.872 | 0.866 | 0.868 |
DSC溶融峰温度Tm | 56.02 | 37.34 | 32.01 |
%结晶 | 14.27 | 11.05 | 12.5 |
DSCTg | -51.56 | -53.54 | -54.46 |
Tc(开始) | 46.78 | 30.43 | 42.26 |
Tc(峰值) | 40.92 | 19.1 | 17.78 |
J/g | 41.67 | 32.26 | 36.51 |
批次 | 20 | 21 | 22 |
中试条件 | |||
主催化剂比例 | 50/50 | 60/40 | 50/50 |
主催化剂1*加料量(pph) | 0.63 | 0.85 | 0.62 |
主催化剂2*加料量(pph) | 0.63 | 0.56 | 0.62 |
主助催化剂加料量(pph) | 0.44 | 0.45 | 0.42 |
第二助催化剂加料量(pph) | 0.43 | 0.52 | 0.48 |
主催化剂1浓度(ppm) | 10 | 10 | 10 |
主催化剂2浓度(ppm) | 10 | 11 | 10 |
主助催化剂浓度(ppm) | 1250 | 1404 | 1250 |
第二助催化剂浓度(ppm) | 125 | 125 | 125 |
主助催化剂摩尔比例 | 4.0 | 4.9 | 3.91 |
第二助催化剂摩尔比例 | 7.36 | 9.6 | 8.4 |
反应器温度(℃) | 80.9 | 81.3 | 88.9 |
反应器压力(psig) | 476.5 | 469.1 | 474.3 |
乙烯加料量(pph) | 30.1 | 30.3 | 29.0 |
辛烯加料量(pph) | 35.1 | 36.2 | 28.9 |
乙烯转化率(%) | 78.7 | 81.0 | 82.7 |
溶剂流量(pph) | 359.6 | 379.9 | 243 |
固体(%) | 9.8 | 9.9 | 13.1 |
生产速率(pph) | 39.5 | 42.0 | 37.6 |
产物性能 | |||
门尼值 | 49.9 | 54.7 | 33.1 |
Mw1(重均分子量) | 262976 | 267269 | 208088 |
Mw2(重均分子量) | 88310 | 90245 | 70390 |
Mw1/Mw2 | 2.98 | 2.96 | 2.96 |
总的MW(重均分子量) | 183377 | 188425 | 148463 |
Mw/Mn | 2.83 | 2.75 | 2.76 |
190℃粘度@0.1rad/sec | 453300 | 568590 | 289730 |
190℃粘度@100rad/sec | 27837 | 31714 | 22092 |
流变比(0.1/100) | 16.28 | 17.93 | 13.11 |
密度(g/cm3) | 0.8657 | 0.8675 | 0.8705 |
DSC冷却峰温度(℃) | 38.85 | 40.76 | 45.69 |
DSC熔融峰温度(℃) | 52.89 | 56.25 | 54.98 |
样品序号 | 23 | 24 | 25 | 26 | 27 | 28 | 29 | 30 | 31 |
主催化剂2* | 主催化剂1* | 二元催化剂* | |||||||
DICUP_ ADDITION(pph) | 1.5 | 2.5 | 3.5 | 1.5 | 2.5 | 3.5 | 1.5 | 2.5 | 3.5 |
聚合物称重 | 200 | 200 | 200 | 200 | 200 | 200 | 200 | 200 | 200 |
过氧化物称重 | 3 | 5 | 7 | 3 | 5 | 7 | 3 | 5 | 7 |
邵氏A硬度ASTM D-2240 | |||||||||
1秒 | 67.6 | 67.5 | 66.8 | 68.8 | 68.4 | 67.7 | 72.6 | 70.8 | 71.4 |
10秒 | 65.2 | 65.0 | 64.3 | 66.3 | 65.9 | 65.4 | 70.3 | 68.6 | 69.1 |
密度ASTM D-792 | |||||||||
23℃下 | 0.870 | 0.871 | 0.871 | 0.871 | 0.870 | 0.871 | 0.871 | 0.872 | 0.873 |
拉伸20in./minASTM D-638 | |||||||||
断裂拉伸强度(psi) | 872 | 597 | 502 | 953 | 650 | 543 | 993 | 759 | 566 |
最终伸长度(%) | 582 | 444 | 357 | 624 | 460 | 378 | 588 | 447 | 332 |
屈服拉伸强度(psi) | 172 | 158 | 162 | 190 | 158 | 140 | 224 | 185 | 192 |
屈服伸长率(%) | 29 | 27 | 28 | 31 | 24 | 20 | 34 | 26 | 28 |
杨氏模量(psi) | 872 | 940 | 939 | 799 | 962 | 1014 | 910 | 1097 | 1191 |
韧性(lbs-in.) | 83 | 54 | 39 | 99 | 60 | 45 | 96 | 67 | 45 |
100%定伸模量(psi) | 289 | 286 | 291 | 305 | 306 | 310 | 336 | 340 | 341 |
类型C撕裂ASTMD-624 | |||||||||
撕裂强度(pli) | 187.90 | 163.60 | 134.00 | 184.30 | 177.90 | 147.60 | 214.50 | 194.70 | 177.30 |
总能量(in.-lbs) | 57.72 | 37.12 | 21.52 | 53.94 | 45.12 | 22.43 | 64.92 | 42.75 | 29.13 |
裤型试样撕裂ASTM D-624 | |||||||||
撕裂强度(pli) | 22.40 | 18.30 | 12.40 | 28.90 | 14.20 | 11.60 | 35.20 | 22.00 | 14.70 |
总能量(in.lbs) | 11.37 | 9.11 | 3.95 | 13.60 | 5.37 | 4.37 | 19.48 | 8.33 | 3.91 |
ODR@177C ASTMD-2084 | |||||||||
最小扭矩 | 9.40 | 10.22 | 10.34 | 8.96 | 9.70 | 10.96 | 11.47 | 10.64 | 11.36 |
最大扭矩 | 60.03 | 68.20 | 79.12 | 57.83 | 71.71 | 79.24 | 72.08 | 73.85 | 82.09 |
δ | 50.63 | 57.98 | 68.78 | 48.87 | 62.01 | 68.28 | 60.61 | 63.21 | 70.73 |
T2 | 0.49 | 0.57 | 0.43 | 1.04 | 1.01 | 0.52 | 1.04 | 0.48 | 0.57 |
T90 | 5.09 | 5.09 | 4.35 | 5.35 | 5.08 | 4.44 | 4.56 | 4.35 | 4.33 |
样品序号 | 32 | 33 | 34 | 35 | 36 | 37 |
Accpro 9934*(35熔融指数) | 70 | 70 | - | - | - | - |
Profax 6323*2 | - | - | 70 | 63 | 70 | 63 |
批次22聚合物共混物(33门尼值) | 30 | - | 30 | 27 | - | - |
批次20聚合物共混物(52门尼值) | - | 30 | - | - | 30 | 27 |
AG 101滑石*3 | - | - | - | 10 | - | 10 |
Irganox 1076*4 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
样品序号 | 32 | 33 | 34 | 35 | 36 | 37 |
邵氏D硬度ASTM D-2240 | ||||||
1秒 | 66.9 | 66.3 | 61.6 | 64.5 | 63.8 | 65.4 |
10秒 | 64.3 | 63.7 | 58.1 | 61.2 | 60.8 | 62.3 |
拉伸@w in./min ASTM D-6382 | ||||||
断裂拉伸强度(psi) | 2878 | 2542 | 2790 | 2583 | 3259 | 2665 |
最终伸长率(%) | 25 | 65 | 577 | 351 | 534 | 194 |
屈服拉伸强度(psi) | 3267 | 2972 | 2718 | 2495 | 2861 | 3242 |
屈服伸长率(%) | 4 | 5 | 14 | 7 | 8 | 6 |
流变测试(dg/10min)ASTM D-1238 | ||||||
I2@230C/2.16kg | 14.4 | 10.7 | 5.9 | 5.6 | 5.7 | 4.5 |
融合线@2 in./min ASTM D-638 | ||||||
断裂拉伸强度(psi) | 2139 | 2568 | 1984 | 1915 | 2370 | 2088 |
最终伸长率(%) | 1 | 3 | 3 | 1 | 8 | 3 |
屈服拉伸强度(psi) | 2131 | 2562 | 1982 | 1912 | 2406 | 2079 |
屈服伸长率(%) | 1 | 3 | 3 | 1 | 6 | 2 |
3点挠曲测试ASTM D-790 | ||||||
挠曲模量(psi) | 168900 | 155576 | 102315 | 170010 | 112305 | 172583 |
2%正割模量(psi) | 154042 | 142289 | 93316 | 137421 | 103310 | 141590 |
光泽ASTM D-523 | ||||||
20° | 35.1 | 16.8 | 67.8 | 45.9 | 27.5 | 36.3 |
60° | 51.2 | 30.9 | 82.3 | 68.9 | 66.6 | 67.6 |
85° | 84.3 | 79.1 | 98.8 | 95.3 | 92.1 | 91.5 |
Dynacup总能量(ft lb) | ||||||
23C | 27.9 | 27.7 | 26 | 27.2 | 31 | 32.3 |
-30C | 26.6 | 25.9 | 39.4 | 24.5 | 36.1 | 17.0 |
悬臂梁冲击强度(ft lbs/in.) | ||||||
23C | 1.54 | 1.64 | 14.39 | 12.03 | 13.89 | 12.3 |
0C | 1.48 | 1.16 | 9.93 | 5.34 | 1.85 | 2.25 |
RT熔合线悬臂梁冲击强度(ft lbs/in.) | ||||||
23C | 1.74 | 3.95 | 5.85 | 2.56 | 7.66 | 2.49 |
热变形66psi | ||||||
热变形温度℃ | 99.5 | 91.7 | 80.3 | 78.9 | 77.5 | 81.2 |
共混物 | 38 | 38-C1 | 38-C2 |
Profax 6323 | 25 | 25 | 25 |
Surlyn 9520 | 27 | 27 | 27 |
Elvaloy AS | 3 | 3 | 3 |
Nordel 3681 | 0 | 45 | 0 |
ENGAGE 8150 | 0 | 0 | 45 |
EO聚合物共混物 | 45 | 0 | 0 |
性能 | 38 | 38-C1 | 38-C2 |
邵氏D硬度1秒 | 42.8 | 45.0 | 38.3 |
拉伸@7.9cm/min断裂拉伸强度(Mpa) | 12.9 | 8.9 | 12.2 |
最终伸长率(%) | 435 | 262 | 486 |
类型C撕裂撕裂强度 | 398 | 295 | 374 |
NBS磨损指数 | 71 | 58 | 49 |
热应力-应变@140C最大工程应力,Mpa | 0.306 | 0.354 | 0.235 |
真实应力@500%伸长率,Mpa | 1.78 | 1.88 | 1.38 |
批次序号 | 催化剂编号 | 反应器温度℃ | 聚合物组成 | ||
C2wt% | C8Wt% | r1值 | |||
1 | A | 90 | 64.59 | 35.41 | 3.5 |
3 | B | 90 | 65.17 | 34.83 | 3.6 |
4 | A | 110 | 64.91 | 35.09 | 5.1 |
6 | B | 110 | 58.40 | 41.60 | 3.8 |
7 | B | 110 | 45.50 | 54.50 | 3.3 |
8 | C | 110 | 76.00 | 24.00 | 14.3 |
组成 | ||||||
批次序号 | 催化剂编号 | C2wt% | C3Wt% | ENB Wt% | C3的r1值 | ENB的r1值 |
14 | A | 66 | 30.2 | 3.9 | 2.8 | 5.5 |
10 | B | 67.1 | 26.2 | 6.7 | 3.5 | 3.6 |
组成 | ||||||
批次序号 | 催化剂编号 | C2wt% | C4Wt% | ENB Wt% | C4的r1值 | ENB的r1值 |
19 | A | 79.31 | 18.18 | 2.52 | 7.3 | 8.7 |
15 | B | 75.68 | 19.16 | 5.16 | 6.4 | 4.2 |
Claims (28)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14985399P | 1999-08-19 | 1999-08-19 | |
US60/149,853 | 1999-08-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1368982A CN1368982A (zh) | 2002-09-11 |
CN1210314C true CN1210314C (zh) | 2005-07-13 |
Family
ID=22532064
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB008115648A Expired - Lifetime CN1210314C (zh) | 1999-08-19 | 2000-08-16 | 在一个单一反应器中制备具有宽分子量分布的聚合物共混物的方法 |
Country Status (13)
Country | Link |
---|---|
US (2) | US6369176B1 (zh) |
EP (1) | EP1214365B1 (zh) |
JP (2) | JP5633996B2 (zh) |
KR (1) | KR100700765B1 (zh) |
CN (1) | CN1210314C (zh) |
AT (1) | ATE319751T1 (zh) |
AU (1) | AU772057B2 (zh) |
BR (1) | BR0013335B1 (zh) |
CA (1) | CA2382182C (zh) |
DE (1) | DE60026545T2 (zh) |
ES (1) | ES2255506T3 (zh) |
MX (1) | MXPA02001763A (zh) |
WO (1) | WO2001014434A1 (zh) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3157163B2 (ja) * | 1991-12-30 | 2001-04-16 | ザ・ダウ・ケミカル・カンパニー | エチレンインターポリマーの重合 |
KR100623106B1 (ko) * | 1998-11-02 | 2006-09-13 | 다우 글로벌 테크놀로지스 인크. | 전단시닝 에틸렌/α―올레핀 인터폴리머 및 그의 제조 방법 |
US6369176B1 (en) * | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
CA2323307A1 (en) * | 2000-10-16 | 2002-04-16 | Peter Jackson | Crosslinked, heat shrinkable polypropylene compositions |
MY131000A (en) * | 2001-03-16 | 2007-07-31 | Dow Global Technologies Inc | High melt strength polymers and method of making same |
JP2004532909A (ja) * | 2001-03-27 | 2004-10-28 | ユニオン・カーバイド・ケミカルズ・アンド・プラスチックス・テクノロジー・コーポレーション | 第4族金属錯体触媒を用いるポリマーの気相製造方法 |
AR040146A1 (es) * | 2002-06-04 | 2005-03-16 | Union Carbide Chem Plastic | Composiciones de polimeros y metodo para fabricar canos |
JP4482448B2 (ja) * | 2002-08-02 | 2010-06-16 | ダウ グローバル テクノロジーズ インコーポレイティド | 4−アリール−置換三環状インデニル誘導体含有第4族金属錯体 |
EP1620479B1 (en) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
US7829645B2 (en) | 2003-07-09 | 2010-11-09 | Dsm Ip Assets B.V. | Process for the production of a polymer comprising monomeric units of ethylene, an α-oplefin and a vinyl norbornene |
US7000131B2 (en) * | 2003-11-14 | 2006-02-14 | Via Technologies, Inc. | Apparatus and method for assuming mastership of a bus |
US20050209403A1 (en) * | 2003-12-09 | 2005-09-22 | Walton Kim L | Thermoplastic olefinic compositions |
US7906586B2 (en) * | 2003-12-09 | 2011-03-15 | Dow Global Technologies Llc | Thermoplastic olefinic compositions |
EP3009459B1 (en) * | 2004-06-16 | 2017-08-02 | Dow Global Technologies LLC | Olefin polymerization process using a modifier |
US7456231B2 (en) * | 2005-02-02 | 2008-11-25 | Shawcor Ltd. | Radiation-crosslinked polyolefin compositions |
KR101338569B1 (ko) * | 2005-05-12 | 2013-12-12 | 다우 글로벌 테크놀로지스 엘엘씨 | 감소된 광택을 갖는 열성형된 압출 시팅 |
ATE557066T1 (de) | 2005-09-12 | 2012-05-15 | Dow Global Technologies Llc | Ethylen/alpha-olefin-zusammensetzungen, daraus hergestellte artikel und verfahren zu ihrer herstellung |
CN101003595B (zh) * | 2006-01-18 | 2010-12-15 | 住友化学株式会社 | 制备乙烯-α-烯烃-多烯无规共聚物的方法 |
JP5378224B2 (ja) | 2006-11-01 | 2013-12-25 | ダウ グローバル テクノロジーズ エルエルシー | ポリウレタン組成物およびそれから調製される物品、ならびにその製造方法 |
KR101455425B1 (ko) | 2006-12-21 | 2014-10-27 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올레핀 조성물 및 그로부터 제조된 물품 및 그의 제조 방법 |
US8653191B2 (en) * | 2007-07-27 | 2014-02-18 | Dow Global Technologies Llc | Polyolefin compositions and articles prepared therefrom, and methods for making the same |
EP2354170B1 (en) * | 2008-12-01 | 2015-10-21 | Mitsui Chemicals, Inc. | Copolymer, rubber compositions, crosslikned rubber, crosslinked foam, and uses of same |
US20100227966A1 (en) * | 2009-03-06 | 2010-09-09 | Shawcor Ltd. | Moisture-crosslinked polyolefin compositions |
US9102824B2 (en) * | 2009-07-15 | 2015-08-11 | Dow Global Technologies Llc | Polymer compositions, methods of making the same, and articles prepared from the same |
US8679639B2 (en) * | 2009-11-24 | 2014-03-25 | Dow Global Technologies Llc | Extrusion coating composition |
JP5476172B2 (ja) * | 2010-03-18 | 2014-04-23 | 三井化学株式会社 | 難燃性ゴム組成物およびゴム成形体 |
US20130203939A1 (en) | 2010-05-21 | 2013-08-08 | Shuwen Peng | Thermoplastic compositions and articles formed from the same |
JP2014133785A (ja) * | 2013-01-08 | 2014-07-24 | Mitsui Chemicals Inc | エチレン・炭素数4〜20のα−オレフィン・非共役ポリエン共重合体からなるフィルム |
EP3013900B1 (en) | 2013-06-24 | 2018-05-02 | Dow Global Technologies LLC | Reinforced polypropylene composition |
KR101585204B1 (ko) | 2013-06-28 | 2016-01-13 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
IN2015DN02232A (zh) | 2013-06-28 | 2015-08-21 | Lg Chemical Ltd | |
JP2015532361A (ja) | 2013-06-28 | 2015-11-09 | エルジー・ケム・リミテッド | ジエンを含む三元系弾性共重合体およびその製造方法 |
CN104797610A (zh) | 2013-06-28 | 2015-07-22 | 株式会社Lg化学 | 弹性二烯三元共聚物及其制备方法 |
US9803037B1 (en) * | 2016-05-03 | 2017-10-31 | Exxonmobil Chemical Patents Inc. | Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof |
JP7277368B2 (ja) * | 2016-10-17 | 2023-05-18 | エル.ブリュッグマン ゲーエムベーハー ウント コー.カーゲー | ポリアミドの制御された粘度調整のための添加剤 |
KR101846412B1 (ko) * | 2016-12-06 | 2018-05-18 | 한화케미칼 주식회사 | 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀 |
CN109627366A (zh) * | 2017-10-09 | 2019-04-16 | 中国石化扬子石油化工有限公司 | 一种茂金属催化剂及在环烯烃共聚物制备中的应用 |
CN109251265A (zh) * | 2018-07-20 | 2019-01-22 | 北京理工大学 | 一种cgc型胺芴稀土金属催化剂、制备方法及应用 |
WO2020169552A1 (en) | 2019-02-18 | 2020-08-27 | Total Research & Technology Feluy | Polyolefin compositions and process to produce such compositions by the addition of ionomers |
KR20210076701A (ko) | 2019-12-16 | 2021-06-24 | 현대자동차주식회사 | 연료전지용 에틸렌-프로필렌-디엔 공중합체 및 그 제조방법 |
KR20220123255A (ko) * | 2019-12-27 | 2022-09-06 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/부텐 다중블록 공중합체 및 이를 제조하는 방법 |
EP4047051A4 (en) * | 2020-04-16 | 2023-01-18 | LG Chem, Ltd. | ENCAPSULATION FILM COMPOSITION COMPRISING AN ETHYLENE/ALPHA OLEFIN COPOLYMER AND ENCAPSULATION FILM THEREOF |
KR102348518B1 (ko) * | 2020-04-16 | 2022-01-10 | 주식회사 엘지화학 | 전기 절연성이 우수한 에틸렌/알파-올레핀 공중합체 |
KR102348519B1 (ko) * | 2020-04-16 | 2022-01-10 | 주식회사 엘지화학 | 전기 절연성이 우수한 에틸렌/알파-올레핀 공중합체 |
WO2021210749A1 (ko) | 2020-04-16 | 2021-10-21 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체를 포함하는 봉지재 필름용 조성물 및 이를 포함하는 봉지재 필름 |
JP7371228B2 (ja) * | 2020-04-16 | 2023-10-30 | エルジー・ケム・リミテッド | 電気絶縁性に優れたエチレン/α-オレフィン共重合体 |
US20230002526A1 (en) * | 2020-04-16 | 2023-01-05 | Lg Chem, Ltd. | Ethylene/Alpha-Olefin Copolymer with Excellent Electrical Insulation |
KR102389719B1 (ko) * | 2020-04-16 | 2022-04-25 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체를 포함하는 봉지재 필름용 조성물 및 이를 포함하는 봉지재 필름 |
Family Cites Families (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
CA1231702A (en) * | 1983-06-06 | 1988-01-19 | John A. Ewen | Process and catalyst for producing reactor blend polyolefins |
US4786697A (en) | 1983-06-15 | 1988-11-22 | Exxon Research & Engineering Co. | Molecular weight distribution modification in a tubular reactor |
US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5231106A (en) | 1988-05-18 | 1993-07-27 | Novo Nordisk A/S | Azacyclic carboxylic acid derivatives and their preparation and use |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
PL166690B1 (pl) | 1990-06-04 | 1995-06-30 | Exxon Chemical Patents Inc | Sposób wytwarzania polimerów olefin PL |
US5453510A (en) | 1990-07-13 | 1995-09-26 | Burroughs Wellcome Co. | Neuromuscular blocking agents |
JP3275211B2 (ja) | 1991-05-20 | 2002-04-15 | ザ ダウ ケミカル カンパニー | 付加重合触媒の製造方法 |
CA2068939C (en) | 1991-05-20 | 1996-04-09 | Takashi Ueda | Olefin polymerization catalyst and olefin polymerization |
US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5359015A (en) | 1991-11-07 | 1994-10-25 | Exxon Chemical Patents Inc. | Metallocene catalysts and their production and use |
US6545088B1 (en) * | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
JP3157163B2 (ja) * | 1991-12-30 | 2001-04-16 | ザ・ダウ・ケミカル・カンパニー | エチレンインターポリマーの重合 |
EP0802204B1 (en) | 1992-01-06 | 2001-12-12 | The Dow Chemical Company | Improved catalyst composition |
JP3160067B2 (ja) * | 1992-01-16 | 2001-04-23 | 三井化学株式会社 | オレフィン重合用触媒およびオレフィンの重合方法 |
JP3197314B2 (ja) * | 1992-02-24 | 2001-08-13 | 三井化学株式会社 | 分子量分布の広いポリオレフィンの製造方法 |
US5374696A (en) | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
JPH06136195A (ja) | 1992-09-08 | 1994-05-17 | Mitsui Petrochem Ind Ltd | エチレン系共重合体組成物 |
CA2103401C (en) | 1992-11-19 | 2002-12-17 | Mamoru Takahashi | Ethylene copolymer composition |
US5464905A (en) | 1992-11-19 | 1995-11-07 | Mitsui Petrochemical Industries, Ltd. | Ethylene/α-olefin copolymer composition, graft modified ethylene/α-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process |
US5420220A (en) | 1993-03-25 | 1995-05-30 | Mobil Oil Corporation | LLDPE films |
PL175108B1 (pl) | 1993-01-29 | 1998-11-30 | Dow Chemical Co | Sposób wytwarzania kompozycji interpolimerów etylen/alfa-olefina |
WO1994018250A1 (en) | 1993-02-05 | 1994-08-18 | Idemitsu Kosan Co., Ltd. | Polyethylene, thermoplastic resin composition containing the same, and process for producing polyethylene |
US5372682A (en) | 1993-06-24 | 1994-12-13 | The Dow Chemical Company | Electrochemical preparation of addition polymerization catalysts |
US5470993A (en) | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
CA2164525C (en) | 1993-06-24 | 2005-03-01 | David D. Devore | Titanium (ii) or zirconium (ii) complexes and addition polymerization catalysts therefrom |
WO1995014024A1 (fr) | 1993-11-18 | 1995-05-26 | Idemitsu Kosan Co., Ltd. | Compose de metal de transition, catalyseur de polymerisation d'olefines et procede pour produire un polymere d'olefines en utilisant ce catalyseur |
EP0733652A4 (en) | 1993-12-08 | 1997-06-11 | Asahi Chemical Ind | NEW OLEFIN POLYMERIZATION CATALYST AND METHOD FOR OLEFIN POLYMERIZATION USING THE SAME |
EP0664304B1 (en) | 1993-12-27 | 1999-08-04 | Mitsui Chemicals, Inc. | Olefin polymerization catalyst and process for olefin polymerization |
US5442018A (en) | 1994-04-01 | 1995-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene polymerization using a titanium and vanadium catalyst system in staged reactors |
US5648438A (en) | 1994-04-01 | 1997-07-15 | Exxon Chemical Patents, Inc. | Process for producing polymers with multimodal molecular weight distributions |
US5486632A (en) | 1994-06-28 | 1996-01-23 | The Dow Chemical Company | Group 4 metal diene complexes and addition polymerization catalysts therefrom |
US5625087A (en) | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
US5677382A (en) | 1994-12-19 | 1997-10-14 | Japan Synthetic Rubber Co., Ltd. | Ethylene-α-olefin-non-conjugated diene copolymer rubber composition |
US5491246A (en) | 1995-04-24 | 1996-02-13 | The Dow Chemical Company | Synthesis of group 4 metal diene complexes |
US5882750A (en) | 1995-07-03 | 1999-03-16 | Mobil Oil Corporation | Single reactor bimodal HMW-HDPE film resin with improved bubble stability |
CA2188722A1 (en) * | 1995-10-26 | 1997-04-27 | George Norris Foster | Process for preparing an in situ polyethylene blend |
WO1997042237A1 (en) | 1996-05-03 | 1997-11-13 | Dsm N.V. | A process for making polyolefins having broad molecular weight distributions |
HU223533B1 (hu) * | 1996-06-17 | 2004-08-30 | Exxonmobil Chemical Patents Inc. | Vegyes átmenetifém katalizátor-rendszer olefinek polimerizálására |
EP0926166A4 (en) | 1996-08-21 | 2000-07-19 | Japan Polyolefins Co Ltd | CATALYTIC COMPONENT FOR POLYMERIZATION OF OLEFINS, CATALYST FOR POLYMERIZATION OF OLEFINS AND PROCESS FOR THE PREPARATION OF POLYOLEFINS |
JPH10330414A (ja) * | 1997-06-03 | 1998-12-15 | Nippon Polyolefin Kk | オレフィン重合用触媒およびポリオレフィンの製造方法 |
US5965756A (en) | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
EP0981556A1 (en) | 1997-04-30 | 2000-03-01 | The Dow Chemical Company | Ethylene/alpha-olefin/diene interpolymers and their preparation |
EP0881237A1 (en) | 1997-05-26 | 1998-12-02 | Fina Research S.A. | Process to produce bimodal polyolefins with metallocene catalysts using two reaction zones |
GB9712663D0 (en) * | 1997-06-16 | 1997-08-20 | Borealis As | Process |
CN1234810A (zh) | 1997-07-22 | 1999-11-10 | 三井化学株式会社 | 乙烯/α-烯烃共聚物、组合物和共聚物和组合物的制备方法 |
US6069213A (en) | 1997-12-16 | 2000-05-30 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst system |
AR022608A1 (es) | 1999-02-17 | 2002-09-04 | Dow Chemical Co | Producto interpolimerico aromatico de alfa-olefina/vinilo o vinilideno y proceso para su elaboracion mediante sistemas catalizadores multiples |
US6369176B1 (en) * | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
-
2000
- 2000-08-14 US US09/638,846 patent/US6369176B1/en not_active Expired - Lifetime
- 2000-08-16 ES ES00959254T patent/ES2255506T3/es not_active Expired - Lifetime
- 2000-08-16 JP JP2001518762A patent/JP5633996B2/ja not_active Expired - Lifetime
- 2000-08-16 DE DE60026545T patent/DE60026545T2/de not_active Expired - Lifetime
- 2000-08-16 BR BRPI0013335-3A patent/BR0013335B1/pt not_active IP Right Cessation
- 2000-08-16 WO PCT/US2000/022500 patent/WO2001014434A1/en active IP Right Grant
- 2000-08-16 AU AU16387/01A patent/AU772057B2/en not_active Ceased
- 2000-08-16 KR KR1020027002171A patent/KR100700765B1/ko active IP Right Grant
- 2000-08-16 CA CA002382182A patent/CA2382182C/en not_active Expired - Fee Related
- 2000-08-16 AT AT00959254T patent/ATE319751T1/de not_active IP Right Cessation
- 2000-08-16 EP EP00959254A patent/EP1214365B1/en not_active Expired - Lifetime
- 2000-08-16 CN CNB008115648A patent/CN1210314C/zh not_active Expired - Lifetime
- 2000-08-16 MX MXPA02001763A patent/MXPA02001763A/es active IP Right Grant
-
2002
- 2002-01-03 US US10/038,920 patent/US6610800B2/en not_active Expired - Lifetime
-
2014
- 2014-07-04 JP JP2014139034A patent/JP6165685B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
AU772057B2 (en) | 2004-04-08 |
US6369176B1 (en) | 2002-04-09 |
KR100700765B1 (ko) | 2007-03-27 |
JP6165685B2 (ja) | 2017-07-19 |
JP2003507541A (ja) | 2003-02-25 |
DE60026545T2 (de) | 2006-08-10 |
ES2255506T3 (es) | 2006-07-01 |
MXPA02001763A (es) | 2003-09-25 |
JP2014208840A (ja) | 2014-11-06 |
US20020143122A1 (en) | 2002-10-03 |
BR0013335B1 (pt) | 2010-05-04 |
DE60026545D1 (de) | 2006-05-04 |
AU1638701A (en) | 2001-03-19 |
US6610800B2 (en) | 2003-08-26 |
CA2382182C (en) | 2009-10-06 |
JP5633996B2 (ja) | 2014-12-03 |
CN1368982A (zh) | 2002-09-11 |
BR0013335A (pt) | 2002-04-02 |
EP1214365B1 (en) | 2006-03-08 |
CA2382182A1 (en) | 2001-03-01 |
KR20020029752A (ko) | 2002-04-19 |
WO2001014434A1 (en) | 2001-03-01 |
EP1214365A1 (en) | 2002-06-19 |
ATE319751T1 (de) | 2006-03-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1210314C (zh) | 在一个单一反应器中制备具有宽分子量分布的聚合物共混物的方法 | |
CN1093141C (zh) | 最大分子量出现在共聚单体含量最高的组合物部分中的聚烯烃共聚物组合物 | |
CN1203076C (zh) | 可用作烯烃聚合的助催化剂的有机金属化合物 | |
CN1309744C (zh) | 制备共聚体的方法和由其制得的产物 | |
CN1102935C (zh) | 生产环烯烃无规共聚物的方法 | |
CN1084342C (zh) | 单烯烃/多烯烃共聚合物、其制备方法、含该聚合物的组合物和由其生产的制品 | |
CN1050135C (zh) | 烯烃聚合催化剂和烯烃聚合方法 | |
CN1544484A (zh) | 生产聚烯烃弹性体的聚合方法、助催化剂、弹性体及其产品 | |
CN1043648C (zh) | 烯烃的气相聚合法 | |
CN1131953A (zh) | 聚合催化剂及其制备和用途 | |
CN1067087C (zh) | 环状烯烃共聚物的生产方法及用该方法制造的共聚物 | |
CN1102601C (zh) | 基于烯烃的不饱和共聚物及其生产方法和应用 | |
CN1088219A (zh) | 生产α-烯烃聚合物的方法 | |
CN1842544A (zh) | 由取代二铝氧烷配合物获得的活化催化剂体系 | |
CN1871292A (zh) | 聚合物共混物 | |
CN1182439A (zh) | 乙烯-α-烯烃/二烯烃聚合物的溶液聚合方法 | |
CN1835978A (zh) | 用于生产共轭二烯/单烯烃共聚物的催化体系和所述共聚物 | |
CN1128537A (zh) | 金属茂化合物及其在用于烯烃聚合的催化剂中的应用 | |
CN1484658A (zh) | 催化剂组合物、聚合方法及由其生产的聚合物 | |
CN1098110A (zh) | 烯烃聚合催化体的固体组分及其制备和该催化剂及其应用 | |
CN1277618A (zh) | 基本无定形的α-烯烃聚合物的制备方法和含有它们的组合物以及桥连配位体的制备方法 | |
CN1350552A (zh) | 烯烃(共)聚合的多阶段方法 | |
CN100347206C (zh) | 多成分催化剂体系的启动方法 | |
CN1271089C (zh) | 多成分催化剂聚合体系的启动程序 | |
CN1287561A (zh) | 乙烯-芳香族乙烯基化合物共聚物及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: DOW GLOBAL TECHNICAL COMPANY Free format text: FORMER OWNER: WEBY BLOEMTEIN JOINT VENTURE COMPANY Effective date: 20060317 Owner name: WEBY BLOEMTEIN JOINT VENTURE COMPANY Free format text: FORMER OWNER: DUPONT BOFUMANS ELASTOMER CO., LTD. Effective date: 20060317 |
|
C41 | Transfer of patent application or patent right or utility model | ||
C56 | Change in the name or address of the patentee |
Owner name: DUPONT BOFUMANS ELASTOMER CO., LTD. Free format text: FORMER NAME OR ADDRESS: DUPONT DOW ELASTOMERS L.L.C. |
|
CP03 | Change of name, title or address |
Address after: American Delaware Patentee after: DuPont Perot, Furman elastomer Co.,Ltd. Address before: American Delaware Patentee before: DUPONT DOW ELASTOMERS LLC |
|
TR01 | Transfer of patent right |
Effective date of registration: 20060317 Address after: michigan Patentee after: Wei company Address before: American Delaware Patentee before: DuPont Perot, Furman elastomer Co.,Ltd. Effective date of registration: 20060317 Address after: Michigan Patentee after: Dow Global Technologies Inc. Address before: michigan Patentee before: Wei company |
|
CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20050713 |