ATE255606T1 - Verfahren zur herstellung eines homogenen polyethylenmaterials in gegenwart eines katalysators - Google Patents

Verfahren zur herstellung eines homogenen polyethylenmaterials in gegenwart eines katalysators

Info

Publication number
ATE255606T1
ATE255606T1 AT99923624T AT99923624T ATE255606T1 AT E255606 T1 ATE255606 T1 AT E255606T1 AT 99923624 T AT99923624 T AT 99923624T AT 99923624 T AT99923624 T AT 99923624T AT E255606 T1 ATE255606 T1 AT E255606T1
Authority
AT
Austria
Prior art keywords
molecular weight
producing
polyethylene
weight portion
catalyst
Prior art date
Application number
AT99923624T
Other languages
English (en)
Inventor
Auli Nummila-Pakarinen
Jarmo Lindroos
Paeivi Waldvogel
Thomas Garoff
Ole Jan Myhre
Original Assignee
Borealis Tech Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Tech Oy filed Critical Borealis Tech Oy
Application granted granted Critical
Publication of ATE255606T1 publication Critical patent/ATE255606T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2415Tubular reactors
    • B01J19/2435Loop-type reactors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905Polymerization in presence of transition metal containing catalyst in presence of hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
AT99923624T 1998-05-08 1999-05-10 Verfahren zur herstellung eines homogenen polyethylenmaterials in gegenwart eines katalysators ATE255606T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI981034A FI981034A (fi) 1998-05-08 1998-05-08 HD-polyeteenikoostumukset ja menetelmä niiden valmistamiseksi
PCT/FI1999/000392 WO1999058584A1 (en) 1998-05-08 1999-05-10 Process for producing a homogeneous polyethylene material in the presence of a catalyst

Publications (1)

Publication Number Publication Date
ATE255606T1 true ATE255606T1 (de) 2003-12-15

Family

ID=8551689

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99923624T ATE255606T1 (de) 1998-05-08 1999-05-10 Verfahren zur herstellung eines homogenen polyethylenmaterials in gegenwart eines katalysators

Country Status (14)

Country Link
US (2) US6455642B1 (de)
EP (2) EP1086155A1 (de)
JP (1) JP2002514665A (de)
KR (1) KR100537935B1 (de)
CN (2) CN1130387C (de)
AT (1) ATE255606T1 (de)
AU (2) AU741875B2 (de)
BR (1) BR9910294B1 (de)
CA (1) CA2331628C (de)
DE (1) DE69913346T2 (de)
ES (1) ES2211091T3 (de)
FI (1) FI981034A (de)
WO (2) WO1999058584A1 (de)
ZA (1) ZA200006010B (de)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI111954B (fi) * 2000-02-21 2003-10-15 Borealis Tech Oy Menetelmä polyeteenipäällysteen valmistamiseksi substraatille
EP1146077B1 (de) * 2000-04-13 2006-06-07 Borealis Technology Oy HDPE Polymerzusammensetzung
US6486270B1 (en) * 2000-08-25 2002-11-26 Equistar Chemicals, Lp High molecular weight, medium density polyethylene
SE0103425D0 (sv) * 2001-10-16 2001-10-16 Borealis Tech Oy Pipe for hot fluids
ES2236371T5 (es) 2002-02-04 2011-08-01 Borealis Technology Oy Material laminar con elevada resistencia al impacto.
DE60203707T2 (de) * 2002-06-24 2006-03-02 Borealis Technology Oy Verfahren zur Herstellung einer Lldpe Zusammensetzung
EP1572760B1 (de) * 2002-12-18 2016-12-07 Borealis Technology Oy Verfahren zur herstellung von einem katalysatorträger und katalysator zur olefinpolymerisation
TW200504093A (en) * 2003-05-12 2005-02-01 Dow Global Technologies Inc Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom
BRPI0413229B1 (pt) * 2003-08-20 2015-05-05 Basell Poliolefine Srl Processo para preparar um polietileno de larga distribuição de pesos moleculares
SA04250276B1 (ar) 2003-09-24 2009-02-07 باسيل بوليوليفين جي ام بي اتش عملية بلمرة لوسط معلق مع تركيزات عالية للمواد الصلبة خلال مفاعل حلقي
EP1555292B1 (de) * 2004-01-13 2015-12-23 Borealis Technology Oy Polyethylen für extrusionsbeschichtung
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
GB0418581D0 (en) * 2004-08-20 2004-09-22 Solvay Polymer composition
DE602005020040D1 (de) 2004-10-14 2010-04-29 Basell Poliolefine Srl Verfahren zur gasphasenpolymerisation von olefinen
PT1655335E (pt) * 2004-11-03 2007-02-28 Borealis Tech Oy Composição polimérica para moldagem por injecção
ES2298666T3 (es) * 2004-11-03 2008-05-16 Borealis Technology Oy Compuesto de polietileno multimodal con homogeneidad mejorada.
EP1655339A1 (de) * 2004-11-03 2006-05-10 Borealis Technology Oy Multimodale Polyethylenzusammensetzung erhältlich mittels eines hochaktiven Katalysators
ES2309445T3 (es) 2004-12-17 2008-12-16 Borealis Technology Oy Proceso para la polimerizacion de olefinas en presencia de un catalizador de polimerizacion de las mismas.
EP1674504A1 (de) * 2004-12-22 2006-06-28 Total Petrochemicals Research Feluy Geo-Membran-Anwendungen
DE102005009896A1 (de) 2005-03-01 2006-09-07 Basell Polyolefine Gmbh Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften
DE102005030941A1 (de) * 2005-06-30 2007-01-11 Basell Polyolefine Gmbh Polyethylen Formmasse zur Herstellung von spritzgegossenen Fertigteilen
DE102005040390A1 (de) * 2005-08-25 2007-03-01 Basell Polyolefine Gmbh Multimodale Polyethylen Formmasse zur Herstellung von Rohren mit verbesserten mechanischen Eigenschaften
CN1923861B (zh) * 2005-09-02 2012-01-18 北方技术股份有限公司 在烯烃聚合催化剂存在下的烯烃聚合方法
US7786203B2 (en) * 2005-09-16 2010-08-31 Milliken & Company Polymer compositions comprising nucleating or clarifying agents and articles made using such compositions
EP1767556B1 (de) * 2005-09-22 2009-08-26 Borealis Technology Oy Polyethylenzusammensetzung mit breiter Molekulargewichtsverteilung
CN101273445B (zh) * 2005-09-28 2012-07-25 大见忠弘 可控气氛的接合装置、接合方法及电子装置
EP1780225A1 (de) * 2005-11-01 2007-05-02 Borealis Technology Oy Ziegler-Natta Katalysator und deseen Verwendung zur Herstellung von multimodalen Polyolefinen
WO2008077530A2 (en) * 2006-12-22 2008-07-03 Basell Polyolefine Gmbh Multimodal polyethylene composition, mixed catalyst and process for preparing the composition
EP1950241A1 (de) 2007-01-25 2008-07-30 Borealis Technology Oy Multimodale Polyethylenzusammensetzung
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
ES2407121T3 (es) * 2007-12-18 2013-06-11 Univation Technologies, Llc Método para controlar la actividad de un catalizador bimodal durante una polimerización
WO2010009242A2 (en) * 2008-07-16 2010-01-21 Zimmer, Inc. Thermally treated ceramic coating for implants
ES2381849T3 (es) * 2008-11-17 2012-06-01 Borealis Ag Procedimiento multietapa para producir polietileno con formación de gel reducida
KR101822805B1 (ko) * 2010-06-22 2018-01-29 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀의 기체상 중합 방법
WO2012143421A1 (en) 2011-04-19 2012-10-26 Basell Polyolefine Gmbh Novel polymer composition for use in blow moulding
EP2607385B1 (de) 2011-12-19 2014-03-19 Borealis AG Schlaufenreaktor mit verbesserter Herstellungsteilungssteuerung
WO2014060231A1 (en) * 2012-10-16 2014-04-24 Ineos Europe Ag Process for the production of a polymer in a gas phase fluidised bed reactor
EP2909264B1 (de) * 2012-10-22 2020-11-25 Basell Polyolefine GmbH Polyethylenzusammensetzung mit hohem schwellverhältnis
US10266625B2 (en) 2014-12-09 2019-04-23 China Petroleum & Chemical Corporation Olefin polymerization apparatus and olefin polymerization process
WO2017207221A1 (en) 2016-06-03 2017-12-07 Borealis Ag Multilayer structure
CN109863183B (zh) * 2016-11-04 2021-09-07 巴塞尔聚烯烃意大利有限公司 烯烃聚合的工艺
MY192386A (en) * 2016-12-22 2022-08-18 Basell Polyolefine Gmbh Process for start-up of a multizone circulating reactor
CN111902467B (zh) 2018-02-05 2022-11-11 埃克森美孚化学专利公司 通过添加超高分子量高密度聚乙烯增强的lldpe的加工性
WO2020025757A1 (en) 2018-08-02 2020-02-06 Borealis Ag Process for polymerizing ethylene in a multi-stage polymerization process
MY194659A (en) 2018-10-26 2022-12-12 Borealis Ag Multi-layered article with improved adhesion
CN113993977A (zh) 2019-05-24 2022-01-28 伊士曼化工公司 进入气体裂化器中加工的液体流中混入少量热解油
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
WO2021092306A1 (en) 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content alpha olefins and fatty alcohols
CN112300312B (zh) * 2020-11-05 2023-03-14 杭州双安科技有限公司 一种聚乙烯的合成方法
WO2022111966A1 (en) 2020-11-27 2022-06-02 Borealis Ag Catalyst feed system
US20230416428A1 (en) 2020-11-27 2023-12-28 Borealis Ag Process
US11845814B2 (en) 2022-02-01 2023-12-19 Chevron Phillips Chemical Company Lp Ethylene polymerization processes and reactor systems for the production of multimodal polymers using combinations of a loop reactor and a fluidized bed reactor

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3723526A1 (de) 1987-07-16 1989-01-26 Hoechst Ag Verfahren zur herstellung eines polyolefins mit einer breiten molmassenverteilung
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
FI98819C (fi) 1993-03-26 1997-08-25 Borealis Polymers Oy Prosessi olefiinipolymeerien valmistamiseksi ja prosessilla valmistetut tuotteet
FI942949A0 (fi) * 1994-06-20 1994-06-20 Borealis Polymers Oy Prokatalysator foer producering av etenpolymerer och foerfarande foer framstaellning daerav
US5405901A (en) 1994-07-06 1995-04-11 Union Carbide Chemicals & Plastics Technology Corporation Process of producing ethylene polymer blends in gas phase
FI96216C (fi) * 1994-12-16 1996-05-27 Borealis Polymers Oy Prosessi polyeteenin valmistamiseksi
FI101546B (fi) * 1994-12-16 1998-07-15 Borealis Polymers Oy Polyeteenikompositio
FI104827B (fi) * 1995-04-12 2000-04-14 Borealis Polymers Oy Menetelmä likaantumisen ja kerrostumisen estämiseksi kaasufaasireaktoreissa
SE504455C2 (sv) * 1995-07-10 1997-02-17 Borealis Polymers Oy Kabelmantlingskomposition, dess användning samt sätt för dess framställning
US5677375A (en) 1995-07-21 1997-10-14 Union Carbide Chemicals & Plastics Technology Corporation Process for producing an in situ polyethylene blend
ID16442A (id) 1996-01-22 1997-10-02 Dow Chemical Co Polimer etilena berat molekul ultra rendah

Also Published As

Publication number Publication date
KR20010071223A (ko) 2001-07-28
FI981034A0 (fi) 1998-05-08
ZA200006010B (en) 2001-04-24
CN1125091C (zh) 2003-10-22
EP1090048B1 (de) 2003-12-03
ES2211091T3 (es) 2004-07-01
CN1311801A (zh) 2001-09-05
WO1999058584A1 (en) 1999-11-18
DE69913346T2 (de) 2004-10-14
JP2002514665A (ja) 2002-05-21
AU4042899A (en) 1999-11-29
KR100537935B1 (ko) 2005-12-21
AU741875B2 (en) 2001-12-13
AU4042799A (en) 1999-11-29
CA2331628C (en) 2009-01-27
EP1086155A1 (de) 2001-03-28
BR9910294A (pt) 2001-01-16
EP1090048A1 (de) 2001-04-11
CN1130387C (zh) 2003-12-10
BR9910294B1 (pt) 2009-05-05
CN1308644A (zh) 2001-08-15
US6642323B1 (en) 2003-11-04
US6455642B1 (en) 2002-09-24
CA2331628A1 (en) 1999-11-18
FI981034A (fi) 1999-11-09
DE69913346D1 (de) 2004-01-15
WO1999058583A1 (en) 1999-11-18

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