DE60022678D1 - Verfahren zur herstellung eines geträgerten katalysatorsystems und dessen verwendung in einem polymerisationsverfahren - Google Patents
Verfahren zur herstellung eines geträgerten katalysatorsystems und dessen verwendung in einem polymerisationsverfahrenInfo
- Publication number
- DE60022678D1 DE60022678D1 DE60022678T DE60022678T DE60022678D1 DE 60022678 D1 DE60022678 D1 DE 60022678D1 DE 60022678 T DE60022678 T DE 60022678T DE 60022678 T DE60022678 T DE 60022678T DE 60022678 D1 DE60022678 D1 DE 60022678D1
- Authority
- DE
- Germany
- Prior art keywords
- supported catalyst
- catalyst system
- producing
- polymerization process
- catalyst composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US426779 | 1999-10-22 | ||
US09/426,779 US6346586B1 (en) | 1999-10-22 | 1999-10-22 | Method for preparing a supported catalyst system and its use in a polymerization process |
PCT/US2000/027085 WO2001030863A1 (en) | 1999-10-22 | 2000-10-02 | A method for preparing a supported catalyst system and its use in a polymerization process |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60022678D1 true DE60022678D1 (de) | 2005-10-20 |
DE60022678T2 DE60022678T2 (de) | 2006-06-29 |
Family
ID=23692166
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60022678T Expired - Lifetime DE60022678T2 (de) | 1999-10-22 | 2000-10-02 | Verfahren zur herstellung eines geträgerten katalysatorsystems und dessen verwendung in einem polymerisationsverfahren |
Country Status (9)
Country | Link |
---|---|
US (2) | US6346586B1 (de) |
EP (1) | EP1242477B1 (de) |
JP (1) | JP3760130B2 (de) |
AT (1) | ATE304560T1 (de) |
AU (1) | AU766273B2 (de) |
BR (1) | BR0015237B1 (de) |
CA (1) | CA2387900C (de) |
DE (1) | DE60022678T2 (de) |
WO (1) | WO2001030863A1 (de) |
Families Citing this family (62)
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---|---|---|---|---|
EP1311558A1 (de) | 2000-08-02 | 2003-05-21 | Univation Technologies LLC | Verfahren zur herstellung von hochproduktiven geträgerten ionischen katalysatoren für die gasphasenpolymerisation |
US6593267B2 (en) * | 2000-12-18 | 2003-07-15 | Univation Technologies, Llc | Method for preparing a supported catalyst system and its use in a polymerization process |
US7439312B2 (en) * | 2002-10-24 | 2008-10-21 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
US20040132935A1 (en) * | 2002-10-24 | 2004-07-08 | Palanisamy Arjunan | Branched crystalline polypropylene |
US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
US20050182210A1 (en) | 2004-02-17 | 2005-08-18 | Natarajan Muruganandam | De-foaming spray dried catalyst slurries |
TW200631965A (en) * | 2004-12-07 | 2006-09-16 | Fina Technology | Random copolymers and formulations useful for thermoforming and blow molding applications |
US7081285B1 (en) | 2005-04-29 | 2006-07-25 | Fina Technology, Inc. | Polyethylene useful for blown films and blow molding |
US20060247394A1 (en) * | 2005-04-29 | 2006-11-02 | Fina Technology, Inc. | Process for increasing ethylene incorporation into random copolymers |
US7220806B2 (en) * | 2005-04-29 | 2007-05-22 | Fina Technology, Inc. | Process for increasing ethylene incorporation into random copolymers |
US7645834B2 (en) * | 2005-04-29 | 2010-01-12 | Fina Technologies, Inc. | Catalyst system for production of polyolefins |
US7282546B2 (en) * | 2005-06-22 | 2007-10-16 | Fina Technology, Inc. | Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations |
US7683002B2 (en) | 2006-04-04 | 2010-03-23 | Fina Technology, Inc. | Transition metal catalyst and formation thereof |
US20070299222A1 (en) | 2006-04-04 | 2007-12-27 | Fina Technology, Inc. | Transition metal catalysts and formation thereof |
US20070235896A1 (en) * | 2006-04-06 | 2007-10-11 | Fina Technology, Inc. | High shrink high modulus biaxially oriented films |
US7893181B2 (en) * | 2006-07-11 | 2011-02-22 | Fina Technology, Inc. | Bimodal film resin and products made therefrom |
US20080051538A1 (en) * | 2006-07-11 | 2008-02-28 | Fina Technology, Inc. | Bimodal pipe resin and products made therefrom |
US7449529B2 (en) * | 2006-07-11 | 2008-11-11 | Fina Technology, Inc. | Bimodal blow molding resin and products made therefrom |
US7514510B2 (en) | 2006-07-25 | 2009-04-07 | Fina Technology, Inc. | Fluorenyl catalyst compositions and olefin polymerization process |
US7470759B2 (en) * | 2006-07-31 | 2008-12-30 | Fina Technology, Inc. | Isotactic-atactic polypropylene and methods of making same |
US20080061468A1 (en) * | 2006-09-07 | 2008-03-13 | Frank Li | Fiber processing of high ethylene level propylene-ethylene random copolymers by use of nucleators |
US7538167B2 (en) * | 2006-10-23 | 2009-05-26 | Fina Technology, Inc. | Syndiotactic polypropylene and methods of preparing same |
US20080114130A1 (en) * | 2006-11-10 | 2008-05-15 | John Ashbaugh | Resin composition for production of high tenacity slit film, monofilaments and fibers |
MX2009003414A (es) | 2006-12-15 | 2009-04-09 | Fina Technology | Pelicula soplada de polipropileno. |
CN101573388A (zh) * | 2006-12-29 | 2009-11-04 | 弗纳技术股份有限公司 | 用于制备聚丙烯薄膜级树脂的使用正丁基甲基二甲氧基硅烷的含琥珀酸酯的聚合催化剂体系 |
JP5072951B2 (ja) | 2007-02-23 | 2012-11-14 | 三井化学株式会社 | アルキル化芳香族化合物の製造方法 |
US8859084B2 (en) * | 2008-01-29 | 2014-10-14 | Fina Technology, Inc. | Modifiers for oriented polypropylene |
US8003741B2 (en) | 2008-02-07 | 2011-08-23 | Fina Technology, Inc. | Ziegler-Natta catalyst |
US20090202770A1 (en) * | 2008-02-08 | 2009-08-13 | Fengkui Li | Polypropylene/polyisobutylene blends and films prepared from same |
US7740070B2 (en) * | 2008-06-16 | 2010-06-22 | Halliburton Energy Services, Inc. | Wellbore servicing compositions comprising a density segregation inhibiting composite and methods of making and using same |
US8545971B2 (en) * | 2008-06-30 | 2013-10-01 | Fina Technology, Inc. | Polymeric compositions comprising polylactic acid and methods of making and using same |
US8268913B2 (en) * | 2008-06-30 | 2012-09-18 | Fina Technology, Inc. | Polymeric blends and methods of using same |
US8759446B2 (en) | 2008-06-30 | 2014-06-24 | Fina Technology, Inc. | Compatibilized polypropylene and polylactic acid blends and methods of making and using same |
US9334342B2 (en) | 2008-10-01 | 2016-05-10 | Fina Technology, Inc. | Polypropylene for reduced plate out in polymer article production processes |
US20100087602A1 (en) * | 2008-10-08 | 2010-04-08 | Fina Technology, Inc. | Long chain branched polypropylene for cast film applications |
US9090000B2 (en) | 2009-03-26 | 2015-07-28 | Fina Technology, Inc. | Injection stretch blow molded articles and random copolymers for use therein |
US8653198B2 (en) | 2009-03-26 | 2014-02-18 | Fina Technology, Inc. | Method for the preparation of a heterophasic copolymer and uses thereof |
US20100247887A1 (en) | 2009-03-26 | 2010-09-30 | Fina Technology, Inc. | Polyolefin films for in-mold labels |
US9174384B2 (en) | 2009-09-01 | 2015-11-03 | Fina Technology, Inc. | Multilayer polypropylene films and methods of making and using same |
KR101050791B1 (ko) * | 2009-10-19 | 2011-07-20 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 혼성 담지 메탈로센 촉매 |
US8592535B2 (en) | 2010-01-11 | 2013-11-26 | Fina Technology, Inc. | Ziegler-natta catalyst systems and polymers formed therefrom |
US10351640B2 (en) | 2010-04-22 | 2019-07-16 | Fina Technology, Inc. | Formation of Ziegler-Natta catalyst using non-blended components |
US8278403B2 (en) | 2010-07-08 | 2012-10-02 | Fina Technology, Inc. | Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers |
US20120046429A1 (en) | 2010-08-23 | 2012-02-23 | Fina Technology, Inc. | Sequential Formation of Ziegler-Natta Catalyst Using Non-blended Components |
US10711077B2 (en) | 2011-02-07 | 2020-07-14 | Fina Technology, Inc. | Ziegler-natta catalyst composition with controlled morphology |
US8586192B2 (en) | 2011-02-15 | 2013-11-19 | Fina Technology, Inc. | Compatibilized polymeric compositions comprising polyolefin-polylactic acid copolymers and methods of making the same |
US9382347B2 (en) | 2011-02-16 | 2016-07-05 | Fina Technology Inc | Ziegler-Natta catalysts doped with non-group IV metal chlorides |
US8628718B2 (en) | 2011-02-18 | 2014-01-14 | Fina Technology, Inc. | Modified polylactic acid, polymeric blends and methods of making the same |
CA2742461C (en) * | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Modified phosphinimine catalysts for olefin polymerization |
US9243092B2 (en) | 2011-06-09 | 2016-01-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9127106B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9568400B2 (en) * | 2011-08-09 | 2017-02-14 | Streamline Automation Llc | Sampling adapter |
US8580893B2 (en) | 2011-12-22 | 2013-11-12 | Fina Technology, Inc. | Methods for improving multimodal polyethylene and films produced therefrom |
US9206293B2 (en) | 2014-01-31 | 2015-12-08 | Fina Technology, Inc. | Polyethyene and articles produced therefrom |
EP3154937B1 (de) | 2014-06-11 | 2024-05-22 | Fina Technology, Inc. | Chlorbeständige polyolethylenzusammensetzungen und daraus hergestellte artikel |
US9650448B2 (en) | 2014-06-13 | 2017-05-16 | Fina Technology, Inc. | Formation of a Ziegler-Natta catalyst |
US9624321B2 (en) | 2014-06-13 | 2017-04-18 | Fina Technology, Inc. | Formation of a Ziegler-Natta catalyst |
CN109890615B (zh) | 2016-10-28 | 2023-04-21 | 弗纳技术股份有限公司 | 降低用于bopp应用的聚丙烯的结晶度的试剂的用途 |
EP3810667A1 (de) * | 2018-06-22 | 2021-04-28 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung heterogener polyethylengranulate |
WO2020056119A1 (en) | 2018-09-14 | 2020-03-19 | Fina Technology, Inc. | Polyethylene and controlled rheology polypropylene polymer blends and methods of use |
MX2021006769A (es) | 2019-02-20 | 2021-07-15 | Fina Technology | Composiciones de polimero con baja distorsion. |
CA3214562A1 (en) | 2021-04-26 | 2022-11-03 | Michael Mcleod | Thin single-site catalyzed polymer sheets |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4897455A (en) * | 1985-06-21 | 1990-01-30 | Exxon Chemical Patents Inc. | Polymerization process |
US4808561A (en) * | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4912075A (en) * | 1987-12-17 | 1990-03-27 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
US4937217A (en) * | 1987-12-17 | 1990-06-26 | Exxon Chemical Patents Inc. | Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst |
US4937301A (en) * | 1987-12-17 | 1990-06-26 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
US5147949A (en) * | 1988-03-29 | 1992-09-15 | Exxon Chemical Patents Inc. | Polymerization process using a silica gel supported metallocene-alumoxane catalyst |
US5008228A (en) * | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
US5086025A (en) * | 1988-03-29 | 1992-02-04 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
US4935397A (en) * | 1988-09-28 | 1990-06-19 | Exxon Chemical Patents Inc. | Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same |
US4914253A (en) * | 1988-11-04 | 1990-04-03 | Exxon Chemical Patents Inc. | Method for preparing polyethylene wax by gas phase polymerization |
NO903931L (no) * | 1989-09-11 | 1991-03-12 | Union Carbide Chem Plastic | Etylen/propylen/etylidennorbornen-gummier. |
DE69222317T2 (de) * | 1991-11-25 | 1998-02-12 | Exxon Chemical Patents Inc | Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung |
US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
US5238892A (en) * | 1992-06-15 | 1993-08-24 | Exxon Chemical Patents Inc. | Supported catalyst for 1-olefin(s) (co)polymerization |
US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
US5473020A (en) * | 1994-06-30 | 1995-12-05 | Phillips Petroleum Company | Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use |
US5643847A (en) * | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
PT830395E (pt) | 1995-05-09 | 2001-10-30 | Fina Research | Processo para a preparacao e utilizacao de um catalisador de metaloceno-alumoxano com suporte |
US5914289A (en) * | 1996-02-19 | 1999-06-22 | Fina Research, S.A. | Supported metallocene-alumoxane catalysts for the preparation of polyethylene having a broad monomodal molecular weight distribution |
US5739368A (en) * | 1996-05-10 | 1998-04-14 | Albemarle Corporation | Use of heat treated alumoxanes in preparing supported catalysts |
DE19622207A1 (de) * | 1996-06-03 | 1997-12-04 | Hoechst Ag | Chemische Verbindung |
US5965477A (en) | 1997-02-21 | 1999-10-12 | Council Of Scientific & Industrial Research | Process for the preparation of supported metallocene catalyst |
CN1279694A (zh) * | 1997-10-22 | 2001-01-10 | 智索公司 | 负载型金属茂催化剂、其制备方法及烯烃聚合物的生产方法 |
-
1999
- 1999-10-22 US US09/426,779 patent/US6346586B1/en not_active Expired - Lifetime
-
2000
- 2000-10-02 JP JP2001533859A patent/JP3760130B2/ja not_active Expired - Fee Related
- 2000-10-02 EP EP00968550A patent/EP1242477B1/de not_active Expired - Lifetime
- 2000-10-02 AU AU78443/00A patent/AU766273B2/en not_active Ceased
- 2000-10-02 AT AT00968550T patent/ATE304560T1/de not_active IP Right Cessation
- 2000-10-02 CA CA002387900A patent/CA2387900C/en not_active Expired - Fee Related
- 2000-10-02 DE DE60022678T patent/DE60022678T2/de not_active Expired - Lifetime
- 2000-10-02 WO PCT/US2000/027085 patent/WO2001030863A1/en active IP Right Grant
- 2000-10-02 BR BRPI0015237-4A patent/BR0015237B1/pt not_active IP Right Cessation
-
2001
- 2001-12-21 US US10/026,171 patent/US20020103076A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
JP2003513116A (ja) | 2003-04-08 |
US6346586B1 (en) | 2002-02-12 |
BR0015237B1 (pt) | 2011-06-14 |
WO2001030863A1 (en) | 2001-05-03 |
US20020103076A1 (en) | 2002-08-01 |
CA2387900C (en) | 2009-06-23 |
BR0015237A (pt) | 2002-07-23 |
ATE304560T1 (de) | 2005-09-15 |
EP1242477B1 (de) | 2005-09-14 |
DE60022678T2 (de) | 2006-06-29 |
AU7844300A (en) | 2001-05-08 |
EP1242477A1 (de) | 2002-09-25 |
CA2387900A1 (en) | 2001-05-03 |
AU766273B2 (en) | 2003-10-16 |
JP3760130B2 (ja) | 2006-03-29 |
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