ATE236080T1 - Kristalline molekularsiebe - Google Patents

Kristalline molekularsiebe

Info

Publication number
ATE236080T1
ATE236080T1 AT99936791T AT99936791T ATE236080T1 AT E236080 T1 ATE236080 T1 AT E236080T1 AT 99936791 T AT99936791 T AT 99936791T AT 99936791 T AT99936791 T AT 99936791T AT E236080 T1 ATE236080 T1 AT E236080T1
Authority
AT
Austria
Prior art keywords
crystalline molecular
molecular sieves
suspension
molecular sieve
lev
Prior art date
Application number
AT99936791T
Other languages
English (en)
Inventor
Johannes P Verduijn
Machteld M Mertens
Wilfried J Mortier
Marcel J G Janssen
Oorschot Cornelius W M Van
David E W Vaughan
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9816505.3A external-priority patent/GB9816505D0/en
Priority claimed from GBGB9816508.7A external-priority patent/GB9816508D0/en
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE236080T1 publication Critical patent/ATE236080T1/de

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/04—Aluminophosphates [APO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7026—MFS-type, e.g. ZSM-57
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0292—Phosphates of compounds other than those provided for in B01J20/048
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7011—MAZ-type, e.g. Mazzite, Omega, ZSM-4 or LZ-202
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7023—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/26—Mordenite type
    • C01B39/265—Mordenite type using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C01B39/445—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G3/00—Compounds of copper
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/62—Synthesis on support in or on other molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT99936791T 1998-07-29 1999-07-28 Kristalline molekularsiebe ATE236080T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB9816505.3A GB9816505D0 (en) 1998-07-29 1998-07-29 Process for manufacture of molecular sieves
GBGB9816508.7A GB9816508D0 (en) 1998-07-29 1998-07-29 Molecular sieves and processes for their manufacture
PCT/GB1999/002468 WO2000006494A1 (en) 1998-07-29 1999-07-28 Crystalline molecular sieves

Publications (1)

Publication Number Publication Date
ATE236080T1 true ATE236080T1 (de) 2003-04-15

Family

ID=26314135

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99936791T ATE236080T1 (de) 1998-07-29 1999-07-28 Kristalline molekularsiebe

Country Status (16)

Country Link
US (2) US6974889B1 (de)
EP (2) EP1105347B1 (de)
JP (2) JP4693239B2 (de)
KR (2) KR20010079583A (de)
CN (2) CN1311757A (de)
AT (1) ATE236080T1 (de)
AU (2) AU750576B2 (de)
BR (1) BR9912472A (de)
CA (2) CA2337505A1 (de)
DE (1) DE69906545T2 (de)
DK (1) DK1105348T3 (de)
ES (1) ES2194490T3 (de)
ID (1) ID28170A (de)
NO (1) NO20010463L (de)
RU (1) RU2001104888A (de)
WO (2) WO2000006493A1 (de)

Families Citing this family (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9816508D0 (en) * 1998-07-29 1998-09-23 Exxon Chemical Patents Inc Molecular sieves and processes for their manufacture
DK0999182T3 (da) * 1998-11-02 2003-07-14 Inst Francais Du Petrole Fremgangsmåde til fremstilling af en zeolit af strukturtypen EUO ved hjælp af kim af zeolitiske materialer og anvendelse heraf som katalysator til isomerisering af aromatiske forbindelser med otte carbonatomer
ZA997664B (en) * 1998-12-23 2001-06-14 Inst Francais Du Petrole Euo zeolite comprising crystals and aggregates of crystals with specific granulometrys and its use as a catalyst in the isomerisation of C8 aromatic compounds.
FR2808519B1 (fr) * 2000-05-05 2002-08-02 Inst Francais Du Petrole Zeolithe de type structural euo de faible rapport si/al et son utilisation en tant que catalyseur d'isomerisation des coupes c8 aromatiques
US7011810B2 (en) 2001-09-28 2006-03-14 Exxonmobil Chemical Patents Inc. Crystalline molecular sieves
US6773688B2 (en) 2001-11-29 2004-08-10 Exxonmobil Chemical Patents Inc. Process for manufacture of molecular sieves
US6696032B2 (en) * 2001-11-29 2004-02-24 Exxonmobil Chemical Patents Inc. Process for manufacturing a silicoaluminophosphate molecular sieve
JP4552071B2 (ja) * 2002-08-15 2010-09-29 三菱化学株式会社 鉄アルミノフォスフェートの製造方法
US7009086B2 (en) 2002-10-29 2006-03-07 Exxonmobil Chemical Patents Inc. Use of molecular sieves for the conversion of oxygenates to olefins
US7375050B2 (en) 2003-04-28 2008-05-20 Exxonmobil Chemical Patents Inc. Synthesis and use of aluminophosphates and silicoaluminophosphates
JP4842143B2 (ja) * 2003-12-23 2011-12-21 エクソンモービル・ケミカル・パテンツ・インク カバサイト含有モレキュラーシーブ、その合成及びオイシジェネートからオレフィンへの変換におけるその使用
EA010769B1 (ru) * 2003-12-23 2008-10-30 Эксонмобил Кемикэл Пейтентс Инк. Молекулярное сито типа шабазита, его синтез и его применение при конверсии оксигенатов в олефины
CN100569646C (zh) * 2004-10-28 2009-12-16 中国石油化工股份有限公司 一种ael结构分子筛的合成方法
JP2008520536A (ja) * 2004-11-19 2008-06-19 エージェンシー フォー サイエンス，テクノロジー アンド リサーチ 結晶性酸化物材料およびその合成
US7547812B2 (en) 2005-06-30 2009-06-16 Uop Llc Enhancement of molecular sieve performance
US7678955B2 (en) 2005-10-13 2010-03-16 Exxonmobil Chemical Patents Inc Porous composite materials having micro and meso/macroporosity
JP5537813B2 (ja) 2006-02-14 2014-07-02 エクソンモービル・ケミカル・パテンツ・インク Ｍｃｍ−２２型モレキュラーシーブの製造方法
US7846418B2 (en) 2006-02-14 2010-12-07 Exxonmobil Chemical Patents Inc. MCM-22 family molecular sieve composition
CN101384361A (zh) * 2006-02-14 2009-03-11 埃克森美孚化学专利公司 用于制备mfs结构型分子筛的方法及其应用
US8859836B2 (en) 2006-02-14 2014-10-14 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion process using molecular sieve of MFS framework type
EP1996327A1 (de) 2006-02-14 2008-12-03 ExxonMobil Chemical Patents Inc. Molekularsiebzusammensetzung
CN102527428B (zh) 2006-02-14 2014-11-26 埃克森美孚化学专利公司 制备分子筛组合物的方法
EP1996329B1 (de) 2006-02-14 2016-08-03 ExxonMobil Chemical Patents Inc. Hochdurchsatzverfahren zur herstellung von molekularsieben
US8383079B2 (en) 2006-04-17 2013-02-26 Exxonmobil Chemical Patents Inc. Molecular sieves having micro and mesoporosity, their synthesis and their use in the organic conversion reactions
WO2007134094A2 (en) 2006-05-15 2007-11-22 The Regents Of The University Of Colorado, A Body Corporate High flux and selectivity sapo-34 membranes for co2/ch4 separations
WO2007145724A1 (en) 2006-06-09 2007-12-21 Exxonmobil Chemical Patents Inc. Treatment of cha-type molecular sieves and their use in the conversion of oxygenates to olefins
CN101121533B (zh) * 2006-08-08 2010-05-19 中国科学院大连化学物理研究所 具有微孔、中孔结构的sapo-34分子筛及合成方法
CN101121145B (zh) * 2006-08-08 2010-10-20 中国科学院大连化学物理研究所 一种含氧化合物转化制烯烃微球催化剂及其制备方法
EP2117702B1 (de) * 2007-02-27 2020-11-11 BASF Corporation Bifunktionelle katalysatoren für selektive ammoniakoxidation
KR101358482B1 (ko) * 2007-02-27 2014-02-05 바스프 카탈리스트 엘엘씨 구리 ｃｈａ 제올라이트 촉매
US7998423B2 (en) 2007-02-27 2011-08-16 Basf Corporation SCR on low thermal mass filter substrates
WO2008112520A1 (en) 2007-03-09 2008-09-18 The Regents Of The University Of Colorado, A Body Corporate Synthesis of zeolites and zeolite membranes using multiple structure directing agents
CA2939726C (en) 2007-04-26 2019-06-18 Johnson Matthey Public Limited Company Transition metal/zeolite scr catalysts
US10052610B1 (en) * 2007-12-13 2018-08-21 University Of Puerto Rico Removal of carbon dioxide from gas mixtures using ion-exchanged silicoaluminophosphates
US20090196812A1 (en) * 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
ES2465004T3 (es) 2008-05-21 2014-06-04 Basf Se Procedimiento de síntesis directa de zeolitas que contienen Cu que tienen una estructura de CHA
US8313727B2 (en) * 2008-07-25 2012-11-20 Exxonmobil Chemical Patents Inc. Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
US20100087610A1 (en) * 2008-10-06 2010-04-08 Vaughn Stephen N Method Of Preparing And Using A Molecular Sieve
US8524185B2 (en) 2008-11-03 2013-09-03 Basf Corporation Integrated SCR and AMOx catalyst systems
US10583424B2 (en) * 2008-11-06 2020-03-10 Basf Corporation Chabazite zeolite catalysts having low silica to alumina ratios
EP2192807B1 (de) * 2008-12-01 2012-10-03 Vodafone Holding GmbH Zugriffssteuerung für M2M ("machine-to-machine") - Vorrichtungen in einem mobilen Kommunikationsnetzwerk
SG178331A1 (en) 2009-08-28 2012-03-29 Exxonmobil Chem Patents Inc Method of making and use of molecular sieve of mfs framework type with controllable average size
RU2600565C2 (ru) * 2009-10-14 2016-10-27 Басф Се СОДЕРЖАЩЕЕ МЕДЬ МОЛЕКУЛЯРНОЕ СИТО ИЗ ЛЕВИНА ДЛЯ СЕЛЕКТИВНОГО ВОССТАНОВЛЕНИЯ NOx
US8470293B2 (en) * 2009-12-18 2013-06-25 Exxonmobil Chemical Patents Inc. Method of preparing a molecular sieve and its use in the conversion of oxygenates to olefins
US8293198B2 (en) 2009-12-18 2012-10-23 Basf Corporation Process of direct copper exchange into Na+-form of chabazite molecular sieve, and catalysts, systems and methods
US8293199B2 (en) * 2009-12-18 2012-10-23 Basf Corporation Process for preparation of copper containing molecular sieves with the CHA structure, catalysts, systems and methods
US8679227B2 (en) 2010-04-29 2014-03-25 The Regents Of The University Of Colorado High flux SAPO-34 membranes for CO2/CH4 separation and template removal method
US8293182B2 (en) 2010-05-05 2012-10-23 Basf Corporation Integrated SCR and AMOx catalyst systems
MY163935A (en) 2010-05-05 2017-11-15 Basf Corp Catalyzed soot filter and emissions treatment systems and methods
US9114991B2 (en) * 2010-06-18 2015-08-25 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the LEV-type structure
US20110313226A1 (en) * 2010-06-18 2011-12-22 Tokyo Institute Of Technology Zeolitic Materials of the LEV-Type Structure And Methods For Their Production
CN103118981B (zh) * 2010-06-18 2015-08-19 巴斯夫欧洲公司 Lev型结构的沸石材料的无碱合成
CN103068732B (zh) * 2010-06-18 2015-03-18 巴斯夫欧洲公司 制备lev型结构的沸石材料的无有机模板合成法
JP6034286B2 (ja) * 2010-06-18 2016-11-30 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Ｌｅｖ型構造ゼオライト系材料のアルカリフリー合成
JP5351216B2 (ja) * 2010-07-01 2013-11-27 日本化学工業株式会社 ゼオライトの製造方法
JP5609345B2 (ja) * 2010-07-12 2014-10-22 トヨタ自動車株式会社 プロピレンの製造方法
US8722000B2 (en) 2011-03-29 2014-05-13 Basf Corporation Multi-component filters for emissions control
US9174849B2 (en) 2011-08-25 2015-11-03 Basf Corporation Molecular sieve precursors and synthesis of molecular sieves
CN103917492B (zh) * 2011-09-09 2016-08-17 巴斯夫欧洲公司 使用再循环母液的无有机模板合成制备沸石材料的方法
WO2013035077A1 (en) 2011-09-09 2013-03-14 Basf Se Process for the organotemplate-free synthetic production of a zeolitic material using recycled mother liquor
EP2755915A4 (de) 2011-09-16 2015-07-01 Basf Se Verfahren zur herstellung von kern7hülle- zeolithmaterial mit cha-struktur
KR102032584B1 (ko) * 2011-11-11 2019-10-15 바스프 에스이 Cha-형 구조의 제올라이트 물질을 생성시키기 위한 무-유기 템플레이트 합성 방법
US9527751B2 (en) * 2011-11-11 2016-12-27 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure
JP5810967B2 (ja) * 2012-02-23 2015-11-11 東ソー株式会社 微結晶チャバザイト型ゼオライト及びその製造方法並びにその用途
EP2676728A1 (de) 2012-06-18 2013-12-25 ExxonMobil Chemical Patents Inc. Synthese von kristallinen EUO Molekularsieben
CN102838131B (zh) * 2012-09-17 2015-02-18 神华集团有限责任公司 Sapo-34分子筛及其制备方法
KR102186666B1 (ko) 2012-10-19 2020-12-04 바스프 코포레이션 혼합된 금속 8-고리 소 공극 분자체 촉매 조성물, 촉매성 물품, 시스템 및 방법
MX2015004814A (es) 2012-10-19 2015-10-22 Basf Corp Tamiz molecular de poro pequeño de 8 anillos con promotor para mejorar el rendimiento a bajas temperaturas.
KR102134127B1 (ko) 2012-10-19 2020-07-15 바스프 코포레이션 고온 ｓｃｒ 촉매로서의 8-고리 소공극 분자체
US20150118151A1 (en) * 2012-12-10 2015-04-30 Exxonmobil Research And Engineering Company Seeded synthesis of aluminosilicate molecular sieves
JP2016515039A (ja) * 2013-03-08 2016-05-26 ビーピー ケミカルズ リミテッドＢｐ Ｃｈｅｍｉｃａｌｓ Ｌｉｍｉｔｅｄ カルボニル化触媒およびプロセス
RU2015143694A (ru) 2013-03-14 2017-04-20 Басф Корпорейшн Каталитическая система селективного каталитического восстановления
JP6594292B2 (ja) 2013-03-14 2019-10-23 ビーエーエスエフ コーポレーション 選択的な触媒作用の還元触媒系
CA2928547C (en) * 2013-10-24 2022-05-10 W. R. Grace & Co.-Conn. Method for synthesizing silicoaluminophosphate-34 molecular sieves
CA2961232A1 (en) 2014-10-21 2016-04-28 Basf Corporation Emissions treatment systems with twc catalysts and scr-hct catalysts
US10752511B2 (en) 2015-03-20 2020-08-25 Basf Corporation Zeolite materials and methods of manufacture
US11213789B2 (en) 2015-09-04 2022-01-04 Basf Corporation Integrated SCR and ammonia oxidation catalyst systems
CN105692643B (zh) * 2016-01-21 2018-02-27 嘉兴学院 利用zsm‑57沸石晶种的模板效应合成其它结构沸石晶体的方法
KR20180114238A (ko) 2016-03-08 2018-10-17 바스프 코포레이션 감소된 n2o 배출을 나타내는 이온-교환된 분자체 촉매
BR112019008207A2 (pt) 2016-10-24 2019-07-09 Basf Corp sistemas de tratamento de gases de exaustão, método para o tratamento de uma corrente de exaustão e artigo catalítico
JP6856895B2 (ja) * 2016-11-22 2021-04-14 国立大学法人広島大学 Ｌｅｖ型ゼオライト
RU2019128036A (ru) 2017-02-08 2021-03-09 Басф Корпорейшн Каталитические изделия
CN110678632B (zh) 2017-04-04 2022-10-04 巴斯夫公司 氢在车上产生和在排气料流中的使用
US11125133B2 (en) 2017-04-04 2021-09-21 Basf Corporation Hydrogen-assisted integrated emission control system
CN110662890A (zh) 2017-04-04 2020-01-07 巴斯夫公司 用于NOx排放控制的氨生成系统
KR102470847B1 (ko) 2017-04-04 2022-11-25 바스프 코포레이션 차량 내장식 암모니아 및 수소 생성
CN110709591A (zh) 2017-04-04 2020-01-17 巴斯夫公司 用于催化性污染治理的氢气还原剂
WO2018185666A1 (en) 2017-04-04 2018-10-11 Basf Corporation Integrated emissions control system
CN109485067B (zh) * 2017-09-13 2021-12-17 中国科学院大连化学物理研究所 一种Beta-FER共晶分子筛的合成方法
US11524281B2 (en) 2017-10-31 2022-12-13 China Petroleum & Chemical Corporation Phosphorus-containing molecular sieve, its preparation and application thereof
CN108083292B (zh) * 2018-01-31 2020-12-29 吉林大学 一种磷掺杂cha分子筛、制备方法及其应用
EP3755891A4 (de) 2018-02-19 2021-12-01 BASF Corporation Abgasbehandlungssystem mit vorgeschaltetem scr-katalysator
US12053768B2 (en) 2018-08-22 2024-08-06 Basf Corporation Advanced NOx reduction catalysts
US10899627B2 (en) 2019-06-19 2021-01-26 Exxonmobil Chemical Patents Inc. Process for making molecular sieves
EP4182078A1 (de) 2020-07-16 2023-05-24 ExxonMobil Chemical Patents Inc. Verfahren zur synthese eines mww-rahmenmolekularsiebs
CN112194151B (zh) * 2020-09-03 2021-08-27 河南神马催化科技股份有限公司 一种sapo-34分子筛的制备方法
CN114644347B (zh) * 2020-12-17 2023-07-04 中国石油化工股份有限公司 一种sapo-20分子筛及其制备方法
JP2024509153A (ja) 2021-03-03 2024-02-29 エクソンモービル ケミカル パテンツ インコーポレイテッド Ｍｗｗ骨格型の分子ふるいを合成する方法
CN113979443B (zh) * 2021-12-01 2023-11-24 郑州大学 一种纳米sapo-34分子筛的制备方法
CN114713278B (zh) * 2022-03-30 2023-10-27 中触媒新材料股份有限公司 一种全结晶zsm-35分子筛的制备方法及其在烯烃异构反应中的应用
WO2024133298A1 (en) 2022-12-21 2024-06-27 Basf Corporation Ammonia oxidation catalyst with zoned scr inlet and pgm outlet for gasoline applications
CN116273147B (zh) * 2023-03-27 2024-06-28 中安联合煤化有限责任公司 一种磷掺杂改性zsm-35分子筛催化剂及其制备方法和应用

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1062064A (en) 1964-05-13 1967-03-15 British Petroleum Co Synthetic zeolite production
US4166099A (en) 1974-04-20 1979-08-28 W. R. Grace & Co. Preparation of zeolites
DE2437914A1 (de) 1974-08-07 1976-02-19 Bayer Ag Verfahren zur herstellung von synthetischem zeolith mit faujasitstruktur
GB1567948A (en) 1976-07-22 1980-05-21 Ici Ltd Zeolite synthesis
DE2719425C2 (de) 1977-04-30 1984-04-12 Hoechst Ag, 6230 Frankfurt Verfahren zur Abtrennung von Zeolithkristallen
US4173622A (en) 1978-01-03 1979-11-06 Fmc Corporation Zeolite A crystals of uniformly small particle size and the manufacture thereof
US4177653A (en) 1978-10-20 1979-12-11 Chevron Research Company Slush filtration method
US4340573A (en) 1979-01-03 1982-07-20 W. R. Grace & Co. Preparation of zeolites
US4247524A (en) 1979-10-01 1981-01-27 Atlantic Richfield Company Preparation of zeolite A by hydrothermal treatment of clinoptilolite
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
CA1204718A (en) * 1982-09-27 1986-05-20 Edward J. Rosinski Zeolite
NZ206295A (en) * 1982-11-22 1986-09-10 Mobil Oil Corp Preparation of zeolites
US4495303A (en) 1983-11-29 1985-01-22 Mobil Oil Corporation Process for making zeolite ZSM-45 with a dimethyldiethylammonium directing agent
US4650655A (en) 1984-07-26 1987-03-17 Mobil Oil Corporation Crystallization of ZSM-5 from reaction mixtures containing zeolite beta
BR8506248A (pt) 1985-12-13 1987-06-30 Petroleo Brasileiro Sa Processo de preparacao de zeolito tipo zsm-5
US4814316A (en) * 1987-06-04 1989-03-21 Uop Novel catalyst composition, and processes for making and using same
SU1503221A1 (ru) 1987-11-30 1991-10-23 Институт общей и неорганической химии АН БССР Способ получени цеолита со структурой феррьерита
FR2656292B1 (fr) 1989-12-21 1992-05-07 Inst Francais Du Petrole Zeolithe de type levyne et son procede de preparation.
GB9122498D0 (en) 1991-10-23 1991-12-04 Exxon Chemical Patents Inc Process for preparing uniform mfitype zeolite crystals
JP3172246B2 (ja) 1992-04-17 2001-06-04 出光興産株式会社 排ガス中の炭化水素類浄化用吸着材の製造方法
US5863516A (en) * 1992-09-02 1999-01-26 Exxon Chemical Patent Inc. Micro particles
SG48109A1 (en) 1993-04-23 1998-04-17 Exxon Chemical Ltd Molecular sieve layers and processes for their manufacture
US5370851A (en) * 1993-05-27 1994-12-06 Uop Crystalline silicoalumino phosphates: SAPO-36 and SAPO-56
US5501848A (en) 1994-02-08 1996-03-26 Chevron U.S.A. Inc. Method for preparing crystalline aluminophosphate materials using azapolycyclic templating agents
CA2199536A1 (en) 1995-07-10 1997-01-30 Johannes Petrus Verduijn Zeolites and processes for their manufacture
EP0753485A1 (de) 1995-07-10 1997-01-15 Exxon Chemical Patents Inc. Zeolithe und Verfahren zu ihrer Herstellung
AU724793B2 (en) 1995-07-10 2000-09-28 Exxon Chemical Patents Inc. Zeolites and processes for their manufacture
MX9701812A (es) 1995-07-10 1997-11-29 Exxon Chemical Patents Inc Zeolitas y proceso para su fabricacion.
EP0753484A1 (de) 1995-07-10 1997-01-15 Exxon Chemical Patents Inc. Zeolithe und Verfahren zu ihrer Herstellung
EP0753483A1 (de) 1995-07-10 1997-01-15 Exxon Chemical Patents Inc. Zeolithe und Verfahren zu ihrer Herstellung
NO304108B1 (no) * 1996-10-09 1998-10-26 Polymers Holding As En mikroporos silikoaluminofosfat-sammensetning, katalytisk materiale som omfatter denne sammensetningen og fremgangsmate for fremstilling derav, og bruken av disse for a fremstille olefiner fra metanol
CN1104402C (zh) * 1996-10-17 2003-04-02 埃克森美孚化学专利公司 使用大晶体沸石催化剂的烃转化方法
ZA979264B (en) * 1996-10-17 1998-12-29 Exxon Chemical Patents Inc Synthesis of large crystal zeolites
US6150293A (en) * 1997-12-03 2000-11-21 Exxon Chemical Patents Inc. Preparation of zeolite bound by MFI structure type zeolite and use thereof
US5912393A (en) * 1997-12-09 1999-06-15 Uop Llc Metallo aluminophosphate molecular sieve with novel crystal morphology and methanol to olefin process using the sieve
GB9816508D0 (en) * 1998-07-29 1998-09-23 Exxon Chemical Patents Inc Molecular sieves and processes for their manufacture

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US7264789B1 (en) 2007-09-04
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BR9912472A (pt) 2001-04-17
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