AR097138A1 - Compuestos plaguicidas - Google Patents

Compuestos plaguicidas

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AR097138A1
AR097138A1 ARP140102601A ARP140102601A AR097138A1 AR 097138 A1 AR097138 A1 AR 097138A1 AR P140102601 A ARP140102601 A AR P140102601A AR P140102601 A ARP140102601 A AR P140102601A AR 097138 A1 AR097138 A1 AR 097138A1
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Argentina
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alkyl
alkoxy
nrbrc
alkylene
cycloalkyl
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ARP140102601A
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Basf Se
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    • AHUMAN NECESSITIES
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    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
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    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • A01N43/86Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
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    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/20N-Aryl derivatives thereof
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    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/48Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —S—C≡N groups
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    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/54Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings condensed with carbocyclic rings or ring systems
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    • C07DHETEROCYCLIC COMPOUNDS
    • C07D235/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
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    • C07D235/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C07D235/04Benzimidazoles; Hydrogenated benzimidazoles
    • C07D235/06Benzimidazoles; Hydrogenated benzimidazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
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    • C07DHETEROCYCLIC COMPOUNDS
    • C07D249/00Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/16Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • C07D249/22Naphthotriazoles
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    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • C07D491/02Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
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    • C07D495/04Ortho-condensed systems

Abstract

Compuestos útiles para combatir o controlar plagas de invertebrados, en particular, plagas de artrópodos y nematodos. También un método para controlar plagas de invertebrados mediante el uso de estos compuestos, materiales de propagación vegetal y una composición agrícola y veterinaria que comprende dichos compuestos. Reivindicación 1: Un compuesto de la fórmula (1) en donde C¹ es C o CH; C² es C o CH; A¹ es N o C; A² es N, C(R²), N(R³), O, S o C(R⁴,R⁵); y A³ es N, O, S, N(R⁶), C(R⁷) o C(R⁸,R⁹); en donde uno o dos enlaces no adyacentes en el anillo de 5 miembros formado por C¹, C², A¹, A² y A³ son enlaces dobles, mientras que los otros son enlaces simples, siempre que el enlace entre A¹ y A², el enlace entre A¹ y C¹, el enlace entre A² y A³, el enlace entre C¹ y C² o el enlace entre A³ y C² sea un enlace doble, también siempre que al menos uno de A¹, A² y A³ sea N, N(R³) o N(R⁶), y en donde R², R⁷ independientemente entre sí, se seleccionan del grupo que consiste en hidrógeno, halógeno, N₃, OH, CN, NO₂, -SCN, -SF₅, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₂₋₆-alquenilo, tri-C₁₋₆-alquilsililo, C₂₋₆-alquinilo, C₁₋₆ alcoxi-C₁₋₄-alquilo, C₁₋₆-alcoxi-C₁₋₄-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-cicloalcoxi, C₃₋₆-cicloalquil-C₁₋₄-alquilo, C₃₋₆-cicloalcoxi-C₁₋₄-alquilo, en donde las partes alquilo, cicloalquilo, cicloalcoxi y alcoxi de los últimos 6 radicales mencionados son no sustituidas o parcial o completamente halogenadas, C(O)-ORᵃ, NRᵇRᶜ, C₁₋₆-alquilen-NRᵇRᶜ, O-C₁₋₆-alquilen-NRᵇRᶜ, C₁₋₆-alquilen-CN, NH-C₁₋₆-alquilen-NRᵇRᶜ, C(O)-NRᵇRᶜ, C(O)-Rᵈ, SO₂NRᵇRᶜ y S(=O)ₘRᵉ; R³, R⁶ independientemente entre sí, se seleccionan del grupo que consiste en hidrógeno, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₁₋₆ alcoxi-C₁₋₄-alquilo, C₁₋₆-alcoxi-C₁₋₄-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-cicloalcoxi, C₃₋₆-cicloalquil-C₁₋₄-alquilo, C₃₋₆-cicloalcoxi-C₁₋₄-alquilo, en donde las partes alquilo, cicloalquilo, cicloalcoxi y alcoxi de los últimos 6 radicales mencionados son no sustituidas o parcial o completamente halogenadas, C(O)-ORᵃ, NRᵇRᶜ, C₁₋₆-alquilen-NRᵇRᶜ, O-C₁₋₆,-alquilen-NRᵇRᶜ, C₁₋₆-alquilen-CN, NH-C₁₋₆-alquilen-NRᵇRᶜ, C(O)-NRᵇRᶜ, C(O)-Rᵈ, SO₂NRᵇRᶜ, S(=O)ₘRᵉ, fenilo y bencilo, en donde el anillo de fenilo, en los últimos 2 radicales, es no sustituido o tiene 1, 2, 3, 4 ó 5 radicales Rᶠ; R⁴, R⁵ independientemente entre sí, se seleccionan del grupo que consiste en hidrógeno, halógeno, CN, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₁₋₄-alcoxi, C₁₋₄-haloalcoxi, C₁₋₄-alquiltio y C₁₋₄-haloalquiltio o C(R⁴,R⁵) puede ser un grupo carbonilo o un grupo tiocarbonilo; R⁸, R⁹ independientemente entre sí, se seleccionan del grupo que consiste en hidrógeno, halógeno, CN, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₁₋₄-alcoxi, C₁₋₄-haloalcoxi, C₁₋₄-alquiltio y C₁₋₄-haloalquiltio o C(R⁸,R⁹) puede ser un grupo carbonilo o un grupo tiocarbonilo; Ar es fenilo o hetarilo de 5 ó 6 miembros, que son no sustituidos o tienen 1, 2, 3 ó 4 radicales RAʳ, que son idénticos o diferentes, en donde RAʳ, independientemente entre sí, se seleccionan del grupo que consiste en halógeno, N₃, OH, CN, NO₂, -SCN, -SF₅, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₂₋₆-alquenilo, tri-C₁₋₆-alquilsililo, C₂₋₆-alquinilo, C₁₋₆-alcoxi-C₁₋₄-alquilo, C₁₋₆-alcoxi-C₁₋₄-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-cicloalcoxi, C₃₋₆-cicloalquil-C₁₋₄-alquilo, C₃₋₆-cicloalcoxi-C₁₋₄-alquilo, en donde las partes alquilo, cicloalquilo, cicloalcoxi y alcoxi de los últimos 6 radicales mencionados son no sustituidas o parcial o completamente halogenadas, C(O)-ORᵃ, NRᵇRᶜ, C₁₋₆-alquilen-NRᵇRᶜ, O-C₁₋₆-alquilen-NRᵇRᶜ, C₁₋₆-alquilen-CN, NH-C₁₋₆-alquilen-NRᵇRᶜ, C(O)-NRᵇRᶜ, C(O)-Rᵈ, SO₂NRᵇRᶜ y S(=O)ₘRᵉ, un radical también puede ser fenilo, fenoxi, fenilcarbonilo, feniltio o bencilo, en donde el anillo de fenilo, en los últimos 5 radicales, es no sustituido o tiene 1, 2, 3, 4 ó 5 radicales Rᶠ; Q es -O-, -S-, -S(=O)-, -S(=O)₂-, -C(RQ²ᵃRQ²ᵇ)-, -N(RQ¹)-, -N(RQ²)-C(=O)-, -O-C(=O)-, -C(RQ³)=C(RQ⁴)-, -C(RQ³ᵃRQ³ᵇ)-C(RQ⁴ᵃRQ⁴ᵇ)-, -C(RQ³ᵃRQ³ᵇ)-C(=O)-, -O-C(RQ⁴ᵃRQ⁴ᵇ)-, -S(=O)ₙ-C(RQ⁴ᵃRQ⁴ᵇ)- o -N(RQ²)-C(RQ⁴ᵃRQ⁴ᵇ)-, en donde n es 0, 1 ó 2; RQ¹ RQ² independientemente entre sí, se seleccionan del grupo que consiste en hidrógeno, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₁₋₆-alcoxi-C₁₋₄-alquilo, C₁₋₆-alcoxi-C₁₋₄-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-cicloalcoxi, C₃₋₆-cicloalquil-C₁₋₄-alquilo, C₃₋₆-cicloalcoxi-C₁₋₄-alquilo, en donde las partes alquilo, cicloalquilo, cicloalcoxi y alcoxi de los últimos 6 radicales mencionados son no sustituidas o parcial o completamente halogenadas, C(O)-ORᵃ, NRᵇRᶜ, C₁₋₆-alquilen-NRᵇRᶜ, C₁₋₆-alquilen-CN, C(O)-NRᵇRᶜ, C(O)-Rᵈ, SO₂NRᵇRᶜ, S(=O)ₘRᵉ, fenilo y bencilo, en donde el anillo de fenilo en los últimos 2 radicales es no sustituido o tiene 1, 2, 3, 4 ó 5 radicales Rᶠ; RQ³ RQ⁴ independientemente entre sí, se seleccionan del grupo que consiste en hidrógeno, halógeno, OH, CN, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₁₋₄-alcoxi, C₁₋₆-haloalcoxi, C(O)-ORᵃ, NRᵇRᶜ, C₁₋₆-alquilen-NRᵇRᶜ, O-C₁₋₆-alquilen-NRᵇRᶜ, C₁₋₆-alquilen-CN, NH-C₁₋₆-alquilen-NRᵇRᶜ, C(O)-NRᵇRᶜ, C(O)-Rᵈ, SO₂NRᵇRᶜ y S(=O)ₘRᵉ; RQ²ᵃ, RQ²ᵇ independientemente entre sí, se seleccionan del grupo que consiste en hidrógeno, halógeno, CN, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₁₋₄-alcoxi, C₁₋₄-haloalcoxi, C₁₋₄-alquiltio y C₁₋₄-haloalquiltio o -C(RQ²ᵃRQ²ᵇ)- es C=O o C=S; RQ³ᵃ, RQ³ᵇ independientemente entre sí, se seleccionan del grupo que consiste en hidrógeno, halógeno, CN, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₁₋₄-alcoxi, C₁₋₄-haloalcoxi, C₁₋₄-alquiltio y C₁₋₄-haloalquiltio; RQ⁴ᵃ, RQ⁴ᵇ independientemente entre sí, se seleccionan del grupo que consiste en hidrógeno, halógeno, CN, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₁₋₄-alcoxi, C₁₋₄-haloalcoxi, C₁₋₄-alquiltio y C₁₋₄-haloalquiltio; R¹ es una porción de la fórmula -X-Y-Z-R¹¹, en donde R¹¹ se selecciona del grupo que consiste en C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₁₋₆-alcoxi-C₁₋₄-alquilo, C₃₋₆-cicloalquilo, C₃₋₆-cicloalquil-C₁₋₄-alquilo, C₃₋₆-cicloalcoxi-C₁₋₄-alquilo, en donde las partes alquilo, cicloalquilo, cicloalcoxi y alcoxi de los últimos 4 radicales mencionados son no sustituidas o parcial o completamente halogenadas,
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CN105531265A (zh) 2016-04-27
BR112016000869A2 (pt) 2017-07-25
BR112016000869B1 (pt) 2021-07-06
JP2016529234A (ja) 2016-09-23
EP3022185A1 (en) 2016-05-25
AU2014292164B2 (en) 2018-03-15
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