AR082212A1 - Particula para suministro beneficioso, proceso para preparar dicha particula, composiciones que comprenden la citada particula y un metodo para tratar sustratos - Google Patents
Particula para suministro beneficioso, proceso para preparar dicha particula, composiciones que comprenden la citada particula y un metodo para tratar sustratosInfo
- Publication number
- AR082212A1 AR082212A1 ARP110102531A ARP110102531A AR082212A1 AR 082212 A1 AR082212 A1 AR 082212A1 AR P110102531 A ARP110102531 A AR P110102531A AR P110102531 A ARP110102531 A AR P110102531A AR 082212 A1 AR082212 A1 AR 082212A1
- Authority
- AR
- Argentina
- Prior art keywords
- cover
- particle
- beneficial agent
- chain growth
- particulate
- Prior art date
Links
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/70—Fixation, conservation, or encapsulation of flavouring agents
- A23L27/72—Encapsulation
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P10/00—Shaping or working of foodstuffs characterised by the products
- A23P10/30—Encapsulation of particles, e.g. foodstuff additives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/18—In situ polymerisation with all reactants being present in the same phase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/08—Processes in which the treating agent is applied in powder or granular form
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/56—Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/65—Characterized by the composition of the particulate/core
- A61K2800/654—The particulate/core comprising macromolecular material
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Textile Engineering (AREA)
- Nutrition Science (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Polymerisation Methods In General (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Fats And Perfumes (AREA)
- Medicinal Preparation (AREA)
Abstract
Una partícula de suministro del agente beneficioso que tiene un diámetro promedio de menos de 50 mm que comprende lo siguiente: a) Al menos una cubierta formada por una reacción de polimerización por crecimiento en etapas, que incluye, con preferencia, un monómero de isocianato, más preferentemente un uretano y/o una urea. b) Interior a dicha cubierta, al menos una región obtenida por una reacción de polimerización por crecimiento de cadena (con preferencia, una polimerización por radicales libres) la cual no incluye un isocianato. c) Opcionalmente, un agente beneficioso interior a dicha cubierta y/o un auxiliar de deposición exterior a dicha cubierta. La presente proporciona, además, un proceso para la preparación de dichas partículas, en la cual la cubierta se obtiene antes de la polimerización por crecimiento de cadena de una región interior de la cubierta -al menos una- donde, preferentemente, la cubierta se obtiene a una temperatura en la cual se inhibe la reacción por crecimiento de cadena. La presente también proporciona productos formulados integralmente, con preferencia, líquidos y geles, los cuales contienen dichas partículas de suministro del agente beneficioso y un método para el tratamiento de los sustratos que hacen uso de dichos productos.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB1011905.5A GB201011905D0 (en) | 2010-07-15 | 2010-07-15 | Benefit delivery particle,process for preparing said particle,compositions comprising said particles and a method for treating substrates |
Publications (1)
Publication Number | Publication Date |
---|---|
AR082212A1 true AR082212A1 (es) | 2012-11-21 |
Family
ID=42734985
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP110102531A AR082212A1 (es) | 2010-07-15 | 2011-07-14 | Particula para suministro beneficioso, proceso para preparar dicha particula, composiciones que comprenden la citada particula y un metodo para tratar sustratos |
Country Status (13)
Country | Link |
---|---|
US (2) | US20130122070A1 (es) |
EP (1) | EP2593072B1 (es) |
JP (2) | JP6274859B2 (es) |
CN (1) | CN103002861B (es) |
AR (1) | AR082212A1 (es) |
BR (1) | BR112013000856A2 (es) |
CL (1) | CL2013000111A1 (es) |
EA (1) | EA201390123A1 (es) |
ES (1) | ES2485370T3 (es) |
GB (1) | GB201011905D0 (es) |
MX (1) | MX2013000430A (es) |
WO (1) | WO2012007438A1 (es) |
ZA (1) | ZA201300069B (es) |
Families Citing this family (64)
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US9321987B2 (en) | 2012-11-19 | 2016-04-26 | Conopco, Inc. | Encapsulated benefit agents |
CN104812447B (zh) * | 2012-11-23 | 2017-08-25 | 荷兰联合利华有限公司 | 有益剂递送颗粒、包含所述颗粒的组合物和处理基体的方法 |
US10188589B2 (en) * | 2013-02-21 | 2019-01-29 | Dow Global Technologies Llc | Deposition of hydrophobic actives in the presence of surfactants |
WO2015014603A2 (en) | 2013-07-30 | 2015-02-05 | Unilever Plc | Benefit delivery particle |
BR112016027653B1 (pt) * | 2014-05-28 | 2020-11-17 | Unilever N.V | uso de uma partícula para absorver e reter compostos odoríferosos |
US9714396B2 (en) | 2014-10-16 | 2017-07-25 | Encapsys Llc | Controlled release dual walled microcapsules |
US10485739B2 (en) * | 2014-10-16 | 2019-11-26 | Encapsys Llc | High strength microcapsules |
US9714397B2 (en) | 2014-10-16 | 2017-07-25 | Encapsys Llc | Controlled release microcapsules |
JP7154761B2 (ja) | 2015-01-23 | 2022-10-18 | フイルメニツヒ ソシエテ アノニム | メラミンホルムアルデヒドを有さないマイクロカプセルの製造方法 |
US20180154328A1 (en) * | 2015-05-01 | 2018-06-07 | Conopco, Inc., D/B/A Unilever | Polymer shell microcapsules with deposition polymer |
KR101893636B1 (ko) * | 2015-08-28 | 2018-08-31 | 롯데첨단소재(주) | 실리콘계 고무 입자, 이를 포함하는 열가소성 엘라스토머 조성물, 및 이를 이용한 성형품 |
CA2996668C (en) * | 2015-10-27 | 2023-09-26 | Encapsys, Llc | Encapsulation |
BR112018007644B1 (pt) * | 2015-11-17 | 2021-05-11 | Unilever Ip Holdings B.V. | microcápsula, processo para a fabricação das microcápsulas e composição para os cuidados do cabelo |
US11786447B2 (en) | 2016-06-30 | 2023-10-17 | The Procter & Gamble Company | Conditioner composition comprising a chelant |
US20180000715A1 (en) | 2016-06-30 | 2018-01-04 | The Procter & Gamble Company | Hair Care Compositions For Calcium Chelation |
US20180000706A1 (en) * | 2016-06-30 | 2018-01-04 | The Procter & Gamble Company | Conditioner Composition Comprising a Chelant |
US11246816B2 (en) | 2016-06-30 | 2022-02-15 | The Procter And Gamble Company | Shampoo compositions comprising a chelant |
US20180000705A1 (en) | 2016-06-30 | 2018-01-04 | The Procter & Gamble Company | Shampoo Compositions Comprising a Chelant |
JP7151070B2 (ja) * | 2016-09-30 | 2022-10-12 | 味の素株式会社 | 粒子およびその製造方法 |
CN106860032B (zh) * | 2016-10-25 | 2021-04-09 | 咏达生医材料股份有限公司 | 一种气态皮肤供氧美白产品及其应用 |
CN110191637B (zh) | 2017-01-10 | 2022-01-14 | 联合利华知识产权控股有限公司 | 携带非挥发性功能材料的生物膜靶向微囊 |
US10624860B2 (en) | 2017-03-21 | 2020-04-21 | International Business Machines Corporation | Method to generate microcapsules with hexahydrotriazine (HT)-containing shells |
US11198106B2 (en) | 2017-08-24 | 2021-12-14 | Kagoshima University | Method for producing microcapsules or beads |
WO2019173062A1 (en) * | 2018-03-07 | 2019-09-12 | Trucapsol, Llc | Reduced permeability microcapsules |
US20200406218A1 (en) | 2018-03-19 | 2020-12-31 | Firmenich Sa | Process for the preparation of microcapsules |
JP2021088505A (ja) * | 2018-03-23 | 2021-06-10 | 富士フイルム株式会社 | マイクロカプセル含有組成物 |
US11344502B1 (en) | 2018-03-29 | 2022-05-31 | Trucapsol Llc | Vitamin delivery particle |
EP3587467A1 (de) * | 2018-06-25 | 2020-01-01 | Rudolf GmbH | Funktionelle mehrwandige kern-schale-partikel |
WO2020066159A1 (ja) * | 2018-09-28 | 2020-04-02 | 富士フイルム株式会社 | マイクロカプセル及びマイクロカプセル含有組成物 |
US11794161B1 (en) | 2018-11-21 | 2023-10-24 | Trucapsol, Llc | Reduced permeability microcapsules |
WO2020131855A1 (en) * | 2018-12-18 | 2020-06-25 | International Flavors & Fragrances Inc. | Guar gum microcapsules |
BR112021011438A2 (pt) | 2018-12-19 | 2021-08-31 | Firmenich Sa | Processo para preparar microcápsulas de poliamida |
WO2020127743A1 (en) | 2018-12-19 | 2020-06-25 | Firmenich Sa | Polyamide microcapsules |
JP2022522468A (ja) | 2019-02-28 | 2022-04-19 | エコラボ ユーエスエー インコーポレイティド | エッジ硬化を改善するための硬度添加剤および硬度添加剤を含有するブロック洗剤 |
US11571674B1 (en) | 2019-03-28 | 2023-02-07 | Trucapsol Llc | Environmentally biodegradable microcapsules |
US11542392B1 (en) | 2019-04-18 | 2023-01-03 | Trucapsol Llc | Multifunctional particle additive for enhancement of toughness and degradation in biodegradable polymers |
MX2021008159A (es) | 2019-05-21 | 2021-08-11 | Firmenich & Cie | Microcapsulas de poli(ester urea). |
SG11202106938VA (en) | 2019-05-21 | 2021-07-29 | Firmenich & Cie | Process for preparing microcapsules |
WO2021023647A1 (en) | 2019-08-05 | 2021-02-11 | Firmenich Sa | Poly(amide-ester) microcapsules |
CN113573804A (zh) | 2019-08-05 | 2021-10-29 | 弗门尼舍有限公司 | 可裂解的多醇基微胶囊 |
CN110734534B (zh) * | 2019-10-31 | 2021-11-16 | 广州同欣体育股份有限公司 | 透明运动面层及其制备方法、运动铺材 |
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EP4164783A1 (en) | 2020-06-16 | 2023-04-19 | Firmenich SA | Polyamide microcapsules |
MX2023002141A (es) | 2020-12-21 | 2023-03-16 | Firmenich & Cie | Proceso de preparacion de microcapsulas de poliester. |
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US20240157322A1 (en) | 2021-03-30 | 2024-05-16 | Firmenich Sa | Crosslinked core-shell microcapsules |
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JP2024523140A (ja) | 2021-06-28 | 2024-06-28 | フイルメニツヒ ソシエテ アノニム | ポリアミドベースのマイクロカプセル |
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-
2010
- 2010-07-15 GB GBGB1011905.5A patent/GB201011905D0/en not_active Ceased
-
2011
- 2011-07-11 US US13/809,447 patent/US20130122070A1/en not_active Abandoned
- 2011-07-11 MX MX2013000430A patent/MX2013000430A/es active IP Right Grant
- 2011-07-11 EA EA201390123A patent/EA201390123A1/ru unknown
- 2011-07-11 ES ES11738424.8T patent/ES2485370T3/es active Active
- 2011-07-11 CN CN201180035296.5A patent/CN103002861B/zh not_active Expired - Fee Related
- 2011-07-11 WO PCT/EP2011/061782 patent/WO2012007438A1/en active Application Filing
- 2011-07-11 JP JP2013519061A patent/JP6274859B2/ja not_active Expired - Fee Related
- 2011-07-11 EP EP11738424.8A patent/EP2593072B1/en not_active Revoked
- 2011-07-14 AR ARP110102531A patent/AR082212A1/es not_active Application Discontinuation
- 2011-07-17 BR BR112013000856A patent/BR112013000856A2/pt not_active IP Right Cessation
-
2013
- 2013-01-03 ZA ZA2013/00069A patent/ZA201300069B/en unknown
- 2013-01-11 CL CL2013000111A patent/CL2013000111A1/es unknown
-
2014
- 2014-09-10 US US14/482,545 patent/US9993401B2/en not_active Expired - Fee Related
-
2016
- 2016-03-04 JP JP2016042526A patent/JP6082143B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN103002861B (zh) | 2015-07-01 |
ES2485370T3 (es) | 2014-08-13 |
JP6082143B2 (ja) | 2017-02-15 |
CL2013000111A1 (es) | 2013-08-09 |
WO2012007438A1 (en) | 2012-01-19 |
US9993401B2 (en) | 2018-06-12 |
EA201390123A1 (ru) | 2013-11-29 |
JP6274859B2 (ja) | 2018-02-07 |
JP2016148042A (ja) | 2016-08-18 |
JP2013538882A (ja) | 2013-10-17 |
GB201011905D0 (en) | 2010-09-01 |
BR112013000856A2 (pt) | 2016-05-24 |
EP2593072B1 (en) | 2014-06-04 |
CN103002861A (zh) | 2013-03-27 |
MX2013000430A (es) | 2013-02-21 |
US20130122070A1 (en) | 2013-05-16 |
US20140378369A1 (en) | 2014-12-25 |
ZA201300069B (en) | 2014-03-26 |
EP2593072A1 (en) | 2013-05-22 |
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