AR047334A1 - Fenilalanina-amidas sustituidas por benzoilo - Google Patents

Fenilalanina-amidas sustituidas por benzoilo

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Publication number
AR047334A1
AR047334A1 ARP040104766A ARP040104766A AR047334A1 AR 047334 A1 AR047334 A1 AR 047334A1 AR P040104766 A ARP040104766 A AR P040104766A AR P040104766 A ARP040104766 A AR P040104766A AR 047334 A1 AR047334 A1 AR 047334A1
Authority
AR
Argentina
Prior art keywords
alkyl
alkoxy
aminocarbonyl
phenyl
alkoxycarbonyl
Prior art date
Application number
ARP040104766A
Other languages
English (en)
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of AR047334A1 publication Critical patent/AR047334A1/es

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    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/28—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton
    • C07C237/42—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton having nitrogen atoms of amino groups bound to the carbon skeleton of the acid part, further acylated
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/48—Nitro-carboxylic acids; Derivatives thereof
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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    • C07C233/82—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/87—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom of a carbon skeleton containing six-membered aromatic rings
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    • C07C237/22—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton having nitrogen atoms of amino groups bound to the carbon skeleton of the acid part, further acylated
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    • C07C255/58—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the carbon skeleton
    • C07C255/60—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the carbon skeleton at least one of the singly-bound nitrogen atoms being acylated
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    • C07C271/06—Esters of carbamic acids
    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
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    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/12—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
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    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/26—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring
    • C07C271/28—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring to a carbon atom of a non-condensed six-membered aromatic ring
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    • C07C275/04—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms
    • C07C275/20—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms of an unsaturated carbon skeleton
    • C07C275/24—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing six-membered aromatic rings
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    • C07C275/42—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by carboxyl groups
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    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
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    • C07C311/06—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the sulfonamide groups bound to hydrogen atoms or to acyclic carbon atoms to acyclic carbon atoms of hydrocarbon radicals substituted by carboxyl groups
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    • C07C311/08—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atom of at least one of the sulfonamide groups bound to a carbon atom of a six-membered aromatic ring
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    • C07C311/53—X and Y not being nitrogen atoms, e.g. N-sulfonylcarbamic acid
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    • C07C311/52—Y being a hetero atom
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Abstract

Sales utiles en la agricultura, procedimientos y productos intermedios para su preparacion, así como el uso de estos compuestos o de productos que contienen estos compuestos para combatir plantas indeseadas. Reivindicacion 1: Fenilalanina-amidas sustituidas por benzoilo caracterizada porque tienen la formula (1) en la que las variables tienen los significados siguientes: R1 es halogeno, ciano, alquilo C1-6, halogenoalquilo C1-6, halogenoalcoxi C1-6, nitro, hidroxicarbonilo, alcoxicarbonilo C1-6, halogenoalquiltio C1-6 o fenilo; R2, R3, R4; R5 significan H, halogeno, ciano, alquilo C1-6, halogenoalquilo C1-6, alcoxi C1-6, halogenoalcoxi C1-6, nitro, amino, alquilamino C1-6, di(alquil C1-6)amino, alquiltio C1-6 o alcoxicarbonilo C1-6; R6, R7 significan H, hidroxi o alcoxi C1-6; R8 es alquilo C1-6, cianoalquilo C1-4 o halogenoalquilo C1-6; R9 es OR16, SR17 o NR18R19; R10 es H o alquilo C1-6; R11, R12 significan H, halogeno, ciano, alquilo C1-6, halogenoalquilo C1-6, hidroxi, alcoxi C1-6, halogenoalcoxi C1-6, hidroxi, nitro, hidroxi-alquilo C1-4, alcoxi C1-6-alquilo C1-4, tri(alquil C1-6)sililoxi-alquilo C1-4, alquiltio 1-4, (hidroxicarbonil)alquilo C1-6, alcoxicarbonil C1-6-alquilo C1-6, (hidroxicarbonil)-alquenilo C2- 6, alcoxicarbonil C1-6-alquenilo C2-6, (hidroxicarbonil)-alcoxi C1-4, alcoxicarbonil C1-4-alcoxi C1-4, alcoxicarbonil C1-4oxi-alquilo C1-4, hidroxicarbonil C1-4-alcoxi-C1-4-alquilo, (alquilsulfonil C1-4)oxi-alquilo C1-4, alquil C1-4-O-C(O)-[alquil C1-4-O]3-alquilo C1-4, carbamoiloxi-alquilo C1-4, (alquilaminocarbonil C1-4)oxi-alquilo C1-4, [di(alquil C1-4)aminocarbonil]oxi-alquilo C1-4, [(halogenoalquilsulfonil C1-4)-aminocarbonil]oxi-alquilo C1-4, benciloxi, pudiendo el anillo fenilo estar sustituido por 1 a 3 radicales del grupo: halogeno y alquilo C1-4, amino, alquilamino C1-4, di(alquil C1-4)amino, alquilsulfonil C1-4-amino, halogenoalquilsulfonilamino C1-4, alquilcarbonilamino C1-4, carbamoilamino, alquilamino C1-4-carbonilamino, [di(alquil C1-4)-amino]carbonilamino, [(halogenoalquilsulfonil C1-4)aminocarbonil]-amino, fenilo o heterociclilo, pudiendo el radical fenilo y el radical heterociclilo de los dos ultimos sustituyentes mencionados llevar uno a tres radicales del grupo siguiente: halogeno, nitro, alquilo C1-4, halogenoalquilo C1-4, hidroxicarbonilo y alcoxicarbonilo C1-6; R13, R14, R15 significan H, halogeno, ciano, alquilo C1-6, halogenoalquilo C1-6, alcoxi C1-6, halogenoalcoxi C1-6, hidroxi, nitro, alquiltio C1-6 o benciloxi; R16, R17, R17 significan H, alquilo C1-6, tri(alquil C1-6)sililo, cicloalquilo C3-6, alquenilo C3-6, alquinilo C3-6, halogenoalquenilo C3-6, halogenoalquinilo C3-6, formilo, alquilcarbonilo C1-6, cicloalquilcarbonilo C3- 6, alquenilcarbonilo C2-6, alquinilcarbonilo C2-6, alcoxicarbonilo C1-6, alqueniloxicarbonilo C3-6, alquiniloxicarbonilo C3-6, alquilamino C1-6-carbonilo, alquenilaminocarbonilo C3-6, alquinilaminocarbonilo C3-6, alquilsulfonilaminocarbonilo C1-6, halogenoalquilsulfonilamino C1-6-carbonilo, di(alquil C1-6)-aminocarbonilo, N-(alquenil C3-6)-N-(alquil C1-6)-aminocarbonilo, N-(alquinil C3-6)-N-(alquil C1-6)-aminocarbonilo, N-(alcoxi C1-6)-N-(alquil C1-6)-amino-carbonilo, N-(alquenil C3-6)-N- (alcoxi C1-6)-aminocarbonilo, N-(alquinil C3-6)-N-(alcoxi C1-6)-aminocarbonilo, di-(alquil C1-6)-aminotiocarbonilo, alquilcarbonil C1-6-alquilo C1-6, alcoxiimino C1-6-alquilo C1-6, N-(alquilamino C1-6)-imino-alquilo C1-6 o N-(di-alquilamino C1-6)- imino-alquilo C1-6, pudiendo los mencionados radicales alquilo, cicloalquilo y alcoxi estar parcial o completamente halogenados y/o llevar uno a tres de los grupos siguientes: ciano, hidroxi, cicloalquilo C3-6, alcoxi C1-4, alquiltio C1-4, di- (alquil C1-4)-amino, alquilcarbonilo C1-4, hidroxicarbonilo, alcoxicarbonilo C1-4, aminocarbonilo, alquilaminocarbonilo C1-4, di-(alquil C1-4)-aminocarbonilo o alquilcarboniloxi C1-4; fenilo, fenil-alquilo C1-6, fenilcarbonilo, fenilcarbonil-alquilo C1-6, fenoxicarbonilo, fenilaminocarbonilo, fenilsulfonilaminocarbonilo, N-(alquil c1-6)-N-(fenil)-aminocarbonilo. fenil-alquilcarbonilo C1-6, heterociclilo, heterociclil-alquilo C1-6, heterociclilocarbonilo, heterociclilocarbonil-alquilo C1-6, heterocicliloxicarbonilo, heterocicliloaminocarbonilo, heterociclilosulfonilaminocarbonilo, N-(alquil C1-6)-N-(heterociclil)-aminocarbonilo o heterociclil-alquilcarbonilo C1-6, pudiendo el radical fenilo o el radical heterociclilo de los 17 ultimos sustituyentes mencionados estar parcial o completamente halogenado y/o llevar uno a tres de los grupos siguientes: nitro, ciano, alquilo C1-4, halogenoalquilo C1-4, alcoxi C1-4 o halogenoalcoxi C1-4; SO2R20; -C(O)-alquil C1-4-O]3-alquilo C1-4; o - C(O)-O-alquil C1-4-O-fenilo, pudiendo el radical fenilo estar, opcionalmente, sustituido por uno a tres radicales del grupo: halogeno y alquilo C1-4; R19 es H, alquilo C1-6, cicloalquilo C3-6, alquenilo C3-6, alquinilo C3-6, halogenoalquenilo C3-6, halogenoalquinilo C3-6, pudiendo los mencionados radicales alquilo y cicloalquilo estar parcial o completamente halogenados y/o llevar uno a tres de los grupos siguientes: ciano, hidroxi, cicloalquilo C3-6, alcoxi C1-4, alquiltio C1-4, di-(alquil C1- 4)-amino, alquilcarbonilo C1-4, hidroxicarbonilo, alcoxicarbonilo C1-4, aminocarbonilo, alquilaminocarbonilo C1-4, di-(alquil C1-4)-aminocarbonilo o alquilcarboniloxi C1-4; o fenilo, fenil-alquilo C1-6, heterociclilo o heterociclil-alquilo C1-6, pudiendo el radical fenilo o el radical heterociclilo de los 4 ultimos sustituyentes mencionados estar parcial o completamente halogenado y/o llevar uno a tres de los grupos siguientes: nitro, ciano, alquilo C1-4, halogenoalquilo C1-4, alcoxi C1-4 o halogenoalcoxi C1-4; R20 es alquilo C1-6, halogenoalquilo C1-6 o fenilo, pudiendo el radical fenilo estar parcial o completamente halogenado y/o llevar uno a tres de los grupos siguientes; alquilo C1-6, halogeno-alquilo C1-6 o alcoxi C1-6; así como sus sales utiles en la agricultura.
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CR8475A (es) 2006-12-07
UY28683A1 (es) 2005-08-31
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BRPI0417780B1 (pt) 2016-03-01
UA81568C2 (en) 2008-01-10
JP4541363B2 (ja) 2010-09-08
PE20051058A1 (es) 2006-01-19
EP1697309A2 (de) 2006-09-06
JP2007534648A (ja) 2007-11-29
EP1697309B1 (de) 2014-04-23
KR20060123344A (ko) 2006-12-01
IL175884A0 (en) 2006-10-05
CO5700811A2 (es) 2006-11-30
WO2005061443A2 (de) 2005-07-07
ZA200605927B (en) 2008-05-28
CN1894202A (zh) 2007-01-10
AU2004303492A1 (en) 2005-07-07
US20070142230A1 (en) 2007-06-21
US7687435B2 (en) 2010-03-30
WO2005061443A3 (de) 2005-12-22
CA2548442A1 (en) 2005-07-07

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