AR045679A1 - Derivados insecticidas de dihidrobenzopiran y dihidrobenzofuran sustituidos con (dihalopropenil)fenilalquilo - Google Patents

Derivados insecticidas de dihidrobenzopiran y dihidrobenzofuran sustituidos con (dihalopropenil)fenilalquilo

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Publication number
AR045679A1
AR045679A1 ARP040101472A ARP040101472A AR045679A1 AR 045679 A1 AR045679 A1 AR 045679A1 AR P040101472 A ARP040101472 A AR P040101472A AR P040101472 A ARP040101472 A AR P040101472A AR 045679 A1 AR045679 A1 AR 045679A1
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AR
Argentina
Prior art keywords
alkyl
optionally substituted
hydrogen
haloalkyl
alkoxy
Prior art date
Application number
ARP040101472A
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English (en)
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Fmc Corp
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Application filed by Fmc Corp filed Critical Fmc Corp
Publication of AR045679A1 publication Critical patent/AR045679A1/es

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/18—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D211/20—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by singly bound oxygen or sulphur atoms
    • C07D211/22—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by singly bound oxygen or sulphur atoms by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
    • C07D307/79—Benzo [b] furans; Hydrogenated benzo [b] furans with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
    • C07D307/82—Benzo [b] furans; Hydrogenated benzo [b] furans with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
    • C07D307/83—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/10—Spiro-condensed systems

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Health & Medical Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Fertilizers (AREA)
  • Furan Compounds (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

Se revelan composiciones que contienen una cantidad eficaz de insecticida de al menos un compuesto de la fórmula (1), y los métodos para controlar los insectos mediante la aplicación de dichas composiciones en un sitio donde se observa la presencia de insectos o donde dicha presencia es de esperar. Reivindicación 1: Un compuesto de fórmula (1), donde -R y R3 se seleccionan independientemente de hidrógeno, halógeno, hidroxi, alquilo C1-3, cicloalquilo C3-6, alquenilo C2-5, alquinilo C2-5, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, haloalquiltio C1-3, alquilsulfonilo C1-3, haloalquilsulfonilo C1-3, ciano, nitro; amino opcionalmente substituido donde el substituyente opcional se selecciona de alquilo C1-4,alquilcarbonilo C1-3 y alcoxicarbonilo C1-3; imidazolilo opcionalmente substituido, imidazolinilo opcionalmente substituido, oxazolinilo opcionalmente substituido, oxazolilo opcionalmente substituido, oxadiazolilo opcionalmente substituido, tiazolilo opcionalmente substituido, pirazolilo opcionalmente substituido, triazolilo opcionalmente substituido, furanilo opcionalmente substituido, tetrahidrofuranilo opcionalmente substituido, dioxolanilo opcionalmente substituido, dioxanilo opcionalmente substituido, -C(=J)-K, y -C(R12)-Q-R13, donde el substituyente opcional se selecciona de alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, alcoxi C1-4 alquilo C1-4, cicloalquilo C3-6, alquenilo C2-5, alquenilo C2-5, ciano, nitro, y arilo; donde J se selecciona de O, S, NR14, y NOR14, donde R14 es hidrógeno, alquilo C1-4, haloalquilo C1-4, arilo y arilalquilo C1-4; K se selecciona de hidrógeno, alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, alquilamino C1-3 y dialquilamino C1-3; Q está seleccionada desde O, S, y NR14, donde R14 es como se describió anteriormente; R12 y R13 se selecciona independientemente de hidrógeno, alquilo C1-4 y haloalquilo C1-4, y R12 y R13 pueden tomarse juntos con -T(CHR14)m-, donde m es un entero de 2 a 4; T se selecciona de O, S, y NR14, donde R14 es como se describió; -R1 y R2 se seleccionan independientemente de hidrógeno, halógeno y alquilo C1-3; -R4 es hidrógeno; -R5' se selecciona independientemente de halógeno; -E se selecciona de CH2, O, S y NR15 donde R15 se selecciona de hidrógeno, alquilo C1-3, alcoxi C1-3 alquilo C1-3, arilalquilo C1-3, alquenilo C2-4 alquilo C1-3, haloalquenilo C2-4 alquilo C1-3, dialquilfosfonato C1-3, alquilcarbonilo C1-3, halo(C1- C3) alquilcarbonilo C1-3, alcoxi C1-3 alquilcarbonilo C1-3, arilcarbonilo y alquilsulfonilo C1-3; -G se selecciona de O, S, CH2O* y (CH2)n donde el asterisco indica unión con E, y n es un entero seleccionado de 1 y 2 siempre que E y G no sean simultáneamente O ó S; -x es un entero seleccionado desde 0 o 1;y cuando x es 1,-A se selecciona de O, S(O)p, y NR15, donde, p es un entero seleccionado de 0, 1 o 2 y R15 es como se describió; -B es un grupo puente, * -(CR16R17)q-(CR18R19)r-(CR20R21)s-Lt-(CR22R23)u-(CR24R25)v-(CR26R27)w-, donde el asterisco indica unión en A; q, r, s, u, v y w son enteros independientemente seleccionados de 0, 1 y 2; y donde q, r, s, u, v y w son 1 ó 2, R16 a R27, inclusive, se seleccionan independientemente de hidrógeno, alquilo C1-3, haloalquilo C1-3 o alcoxi C1-3alquilo C1-3 o cicloalquilo C3-6; t es un entero seleccionado de 0 ó 1; y donde t es 1, L se selecciona de CH=CH; O, S(O)p, OS(O)2, S(O)2O, NR28; N(óxido)R28; NR28SO2, NR28C(=O)NR29; Si(CH3)2; C(=O), OC(=O), NHC(=O); ON=CH; HC=NO; C(=O)O; C(=O)NH; C(=NOR14) y [CR30R31]z, donde p es como se describió, R28 y R29 se seleccionan independientemente de hidrógeno, aluqilo C1-3, alquilsulfonilo C1-3, alquilcarbonilo C1-3, alquenilo C2-5, y alquinilo C2-5; z es un entero seleccionado de 1 ó 2 y R30 y R31 se seleccionan independientemente de hidrógeno y alquilo C1-3; y es un entero seleccionado de 0 ó 1 y cuando y es 1, D se selecciona de O; S(O)p; y NR15, donde p y R15 son como se describió, donde D está unido a la fracción anular fusionada a benzo establecida en la fórmula (1) en cualquiera de las posiciones designadas 1-, 2-, 3- ó 4-; fórmula (2), R6, R7, R8 y R9 se seleccionan independientemente de hidrógeno, halógeno, alquilo C1-4, cicloalquilo C3-6, alquenilo C2-5, alquinilo C2-5, haloalquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, haloalquiltio C1-4, alquilsulfonilo C1-4, haloalquilsulfonilo C1-4, ciano, nitro, arilo, alquilcarbonilamino, arilcarbonilamino y alcoxi C1-4carbonilamino; R10 y R11 se seleccionan independientemente de hidrógeno, halógeno, hidroxilo, alquilo, haloalquilo, alcoxi, o R10 y R11 juntos son un grupo carbonilo =O; o -OCH2CH2O- o -SCH2CH2S-forman un grupo cetal o tiocetal; o NOR15 forma una oxima, donde R15 es como se describió; M se selecciona de *C(R32R33) y *C(R32R33)C(R34R35) donde el asterisco indica unión a O y donde R32 a R35 se seleccionan de halógeno, alquilo C1-4, alcoxi C1-4alquilo C1-4 y haloalquilo C1-4; y sales agriculturalmente aceptablesde los mismos.
ARP040101472A 2003-04-30 2004-04-29 Derivados insecticidas de dihidrobenzopiran y dihidrobenzofuran sustituidos con (dihalopropenil)fenilalquilo AR045679A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US46667403P 2003-04-30 2003-04-30

Publications (1)

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AR045679A1 true AR045679A1 (es) 2005-11-09

Family

ID=33418411

Family Applications (4)

Application Number Title Priority Date Filing Date
ARP040101474A AR044138A1 (es) 2003-04-30 2004-04-29 Derivados plaguicidas de benzodioxol y benzodioxolano sustituidos con (dihalopropenilo) fenilalquilo
ARP040101472A AR045679A1 (es) 2003-04-30 2004-04-29 Derivados insecticidas de dihidrobenzopiran y dihidrobenzofuran sustituidos con (dihalopropenil)fenilalquilo
ARP040101473A AR044137A1 (es) 2003-04-30 2004-04-29 Derivados plaguicidas de benzotiazol y benzoxazol sustituidos con (dihalopropenil) fenilalquilo
ARP040101471A AR045678A1 (es) 2003-04-30 2004-04-29 Derivados ciclicos fenil substituidos

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ARP040101474A AR044138A1 (es) 2003-04-30 2004-04-29 Derivados plaguicidas de benzodioxol y benzodioxolano sustituidos con (dihalopropenilo) fenilalquilo

Family Applications After (2)

Application Number Title Priority Date Filing Date
ARP040101473A AR044137A1 (es) 2003-04-30 2004-04-29 Derivados plaguicidas de benzotiazol y benzoxazol sustituidos con (dihalopropenil) fenilalquilo
ARP040101471A AR045678A1 (es) 2003-04-30 2004-04-29 Derivados ciclicos fenil substituidos

Country Status (16)

Country Link
US (5) US6987194B2 (es)
EP (4) EP1620401A4 (es)
JP (4) JP2006525336A (es)
KR (4) KR20060003055A (es)
CN (4) CN100381431C (es)
AR (4) AR044138A1 (es)
AT (2) ATE434612T1 (es)
AU (4) AU2004237745A1 (es)
BR (4) BRPI0409684A (es)
CA (4) CA2523191A1 (es)
DE (2) DE602004021689D1 (es)
MX (4) MXPA05011323A (es)
TW (4) TW200512203A (es)
UA (1) UA82875C2 (es)
WO (4) WO2004099145A2 (es)
ZA (4) ZA200508622B (es)

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KR100836172B1 (ko) * 2007-07-26 2008-06-09 한국생명공학연구원 아졸계 화합물을 유효성분으로 하는 살충제 조성물
US8580709B2 (en) * 2009-11-27 2013-11-12 Syngenta Crop Protection, Llc Plant growth regulation
CN102464612B (zh) * 2010-11-19 2014-12-24 中国中化股份有限公司 含哌嗪氨基甲酸酯的二卤丙烯醚类化合物与应用
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JP2022533023A (ja) 2019-04-30 2022-07-21 カリコ ライフ サイエンシーズ エルエルシー 統合的ストレス経路の調節剤としての置換シクロアルキル
CN111812229B (zh) * 2020-06-19 2023-08-01 广电计量检测(合肥)有限公司 一种气相色谱-质谱测定土壤/沉积物中2-甲基苯并噻唑的分析方法
CN113004260B (zh) * 2021-03-11 2023-12-26 西华大学 2-(2-呋喃甲酰氨基)苯并吡喃类化合物及其在农药中的用途
CN113024528B (zh) * 2021-03-11 2024-01-09 西华大学 2-(2-噻吩甲酰氨基)苯并吡喃类化合物及其在农药中的用途
CN113912592B (zh) * 2021-11-03 2023-03-10 西北农林科技大学 一种和厚朴酚并二氢呋喃酯类衍生物、制备方法及其应用

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