AR044667A1 - Cetoenoles ciclicos, n-heterociclil-fenilsubstituidos - Google Patents

Cetoenoles ciclicos, n-heterociclil-fenilsubstituidos

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Publication number
AR044667A1
AR044667A1 ARP040102018A ARP040102018A AR044667A1 AR 044667 A1 AR044667 A1 AR 044667A1 AR P040102018 A ARP040102018 A AR P040102018A AR P040102018 A ARP040102018 A AR P040102018A AR 044667 A1 AR044667 A1 AR 044667A1
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AR
Argentina
Prior art keywords
substituted
appropriate
alkyl
mean
halogen
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Application number
ARP040102018A
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English (en)
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Bayer Cropscience Ag
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Publication of AR044667A1 publication Critical patent/AR044667A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing aromatic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18—One oxygen or sulfur atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/28—Two oxygen or sulfur atoms
    • C07D231/30—Two oxygen or sulfur atoms attached in positions 3 and 5
    • C07D231/32—Oxygen atoms
    • C07D231/36—Oxygen atoms with hydrocarbon radicals, substituted by hetero atoms, attached in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/10—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/10—Spiro-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/10—Spiro-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/10—Spiro-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D513/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00
    • C07D513/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00 in which the condensed system contains two hetero rings
    • C07D513/04—Ortho-condensed systems

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente se refiere a cetoenoles cíclicos, varios procedimientos y a productos intermedios para su obtención y a su empleo como agentes pesticidas y/o herbicidas y/o microbicidas. Se refiere, además, a agentes herbicidas selectivos, que contienen los cetoenoles cíclicos N-heterociclil-fenil sustituidos por un lado y, por otro lado, un compuesto mejorador de la compatibilidad para con las plantas de cultivo. Reivindicación 1: Compuestos de la fórmula (1) en la que X significa halógeno, alquilo, alquenilo, alquinilo, alcoxi, alqueniloxi, alquiltio, alquilsulfinilo, alquilsulfonilo, halógenoalquilo, halógenoalcoxi, halógenoalqueniloxi, nitro, ciano o significa fenilo, fenoxi, feniltio, fenilalcoxi o fenilalquiltio sustituidos respectivamente, en caso dado, W e Y significan, independientemente entre sí, H, halógeno, alquilo, alquenilo, alquinilo, alcoxi, alqueniloxi, halógenoalquilo, halógenoalcoxin, halógenoalqueniloxi, nitro o ciano; Z significa un heterociclo respectivamente saturado o insaturado en caso dado, insustituido en caso dado, enlazado a través de un átomo de N sobre el anillo de fenilo, que puede estar interrumpido por uno hasta dos grupos carbonilo; CKE significa uno de los grupos de fórmulas (2) a (9) donde A significa H, alquilo, alquenilo, alcoxialquilo, alquiltioalquilo sustituidos, respectivamente, en caso dado por halógeno, cicloalquilo saturado o insaturado, sustituido en caso dado, en el cual está reemplazado, en caso dado, al menos un átomo del anillo por un heteroátomo, o significa arilo, arilalquilo o hetarilo sustituidos respectivamente, en caso dado, por halógeno, por alquilo, por halógenoalquilo, por alcoxi, por halógenoalcoxi, por ciano o por nitro; B significa H, alquilo o alcoxialquilo, o A y B significan junto con el átomo de C, con el que están enlazados, un ciclo saturado o insaturado, insustituido o sustituido, que contiene en caso dado al menos un heteroátomo; D significa H o significa un resto sustituido en caso dado de la serie formada por alquilo, alquenilo, alquinilo, alcoxialquilo, cicloalquilo saturado o insaturado, en el cual están reemplazados, en caso dado uno o varios miembros del anillo por heteroátomos, arilalquilo, arilo, hetarilalquilo o hetarilo o A y D significan, junto con los átomos, con los que están enlazados, un ciclo saturado o insaturado, insustituido o sustituido en la parte A, D, y que contiene, en caso dado, al menos un heteroátomo (en el caso de CKE = 9 otro heteroátomos), o bien A y Q1 significan conjuntamente alquenodiilo sustituido, en caso dado, por halógeno o por hidroxi, o significa alcanodiilo o alquenodiilo sustituidos, en caso dado, por alquilo, por alcoxi, por alquiltio, por cicloalquilo, por benciloxi o por arilo sustituido respectivamente, en caso dado o Q1 significa H o alquilo; Q2, Q4, Q5 y Q6 significan, independientemente entre sí, H o alquilo; Q3 significa H, significa alquilo, alcoxialquilo, alquiltioalquilo sustituidos en caso dado, cicloalquilo sustituido en caso dado (estando reemplazado en caso dado un grupo metileno por O ó por S) o significa fenilo sustituido en caso dado, o Q3 y Q4 significan, junto con el átomo de C, con el que están enlazados, un ciclo saturado o insaturado, insustituido o sustituido, que contiene, en caso dado, un heteroátomo; G significa hidrógeno, E o significa uno de los grupos de fórmulas (10), donde E significa un equivalente de ión metálico o un ión amonio, L significa O ó S; M significa O ó S; R1 significa alquilo, alquenilo, alcoxialquilo, alquiltioalquilo, polialcoxialquilo, sustituidos respectivamente, en caso dado, por halógeno o significa ciclo-alquilo sustituido, en caso dado, por halógeno, por alquilo o por alcoxi, que puede estar interrumpido al menos por un heteroátomo, significa fenilo, fenilalquilo, hetarilo, fenoxialquilo o hetariloxialquilo sustituidos, respectivamente, en caso dado; R2 significa alquilo, alquenilo, alcoxialquilo, polialcoxialquilo sustituidos respectivamente, en caso dado, por halógeno o significa cicloalquilo, fenilo o bencilo sustituidos respectivamente, en caso dado; R3, R4 y R5 significan, independientemente entre sí, alquilo, alcoxi, alquilamino, dialquilamino, alquiltio, alqueniltio, cicloalquiltio sustituidos respectivamente, en caso dado, por halógeno o significan fenilo, bencilo, fenoxi o feniltio sustituidos respectivamente, en caso dado; R6 y R7 significan, independientemente entre sí, H,. alquilo, cicloalquilo, alquenilo, alcoxi, alcoxialquilo sustituido respectivamente, en caso dado por halógeno, significan fenilo sustituido en caso dado, significan bencilo sustituido en caso dado, o junto con el átomo de N, con el que están enlazados, significan un ciclo interrumpido, en caso dado, por O ó por S.
ARP040102018A 2003-06-12 2004-06-10 Cetoenoles ciclicos, n-heterociclil-fenilsubstituidos AR044667A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10326386A DE10326386A1 (de) 2003-06-12 2003-06-12 N-Heterocyclyl-phenylsubstituierte cyclische Ketoenole

Publications (1)

Publication Number Publication Date
AR044667A1 true AR044667A1 (es) 2005-09-21

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ARP040102018A AR044667A1 (es) 2003-06-12 2004-06-10 Cetoenoles ciclicos, n-heterociclil-fenilsubstituidos

Country Status (18)

Country Link
US (2) US7776791B2 (es)
EP (1) EP1638957B1 (es)
JP (1) JP4937739B2 (es)
KR (1) KR101106124B1 (es)
CN (2) CN102190621A (es)
AR (1) AR044667A1 (es)
AT (1) ATE482949T1 (es)
AU (1) AU2004247370B2 (es)
BR (1) BRPI0411339A (es)
CA (1) CA2528888A1 (es)
CO (1) CO5700823A2 (es)
DE (2) DE10326386A1 (es)
ES (1) ES2351601T3 (es)
MX (1) MXPA05013259A (es)
PL (1) PL1638957T3 (es)
UA (1) UA86942C2 (es)
WO (1) WO2004111042A1 (es)
ZA (1) ZA200510008B (es)

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HU229958B1 (hu) 1999-09-07 2015-03-30 Syngenta Participations Ag Herbicid vegyületek, ezeket tartalmazó készítmények, eljárás a vegyületek előállítására, valamint eljárás gyomnövények irtására
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HU228800B1 (en) 1999-09-07 2013-05-28 Syngenta Participations Ag Synergistic herbicidal composition and use thereof
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DE19946625A1 (de) 1999-09-29 2001-04-05 Bayer Ag Trifluormethylsubstituierte spirocyclische Ketoenole
DE10016544A1 (de) 2000-04-03 2001-10-11 Bayer Ag C2-phenylsubstituierte Ketoenole
CN1266112C (zh) 2001-04-24 2006-07-26 麻省理工学院 铜－催化的碳－杂原子键和碳－碳键的形成
DE10139465A1 (de) * 2001-08-10 2003-02-20 Bayer Cropscience Ag Selektive Herbizide auf Basis von substituierten, cayclischen Ketoenolen und Safenern
EP1429600B1 (en) 2001-09-24 2008-12-31 Evotec AG An invertebrate animal model with alzheimer-like pathology for screening and testing molecules
RU2004125878A (ru) 2002-01-22 2005-05-27 Зингента Партисипейшнс Аг (Ch) Фенилзамещенные гетероциклические соединения, пригодные для применения в качестве гербицидов
DE10231333A1 (de) 2002-07-11 2004-01-22 Bayer Cropscience Ag Cis-Alkoxysubstituierte spirocyclische 1-H-Pyrrolidin-2,4-dion-Derivate
DE10239479A1 (de) 2002-08-28 2004-03-04 Bayer Cropscience Ag Substituierte spirocyclische Ketoenole

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JP4937739B2 (ja) 2012-05-23
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CA2528888A1 (en) 2004-12-23
US7776791B2 (en) 2010-08-17
US20100267964A1 (en) 2010-10-21
ATE482949T1 (de) 2010-10-15
DE10326386A1 (de) 2004-12-30
JP2006527224A (ja) 2006-11-30
CN102190621A (zh) 2011-09-21
ZA200510008B (en) 2007-03-28
AU2004247370A1 (en) 2004-12-23
CN1832938A (zh) 2006-09-13
EP1638957A1 (de) 2006-03-29
PL1638957T3 (pl) 2011-03-31
CN1832938B (zh) 2011-05-25
EP1638957B1 (de) 2010-09-29
KR101106124B1 (ko) 2012-01-20
BRPI0411339A (pt) 2006-07-11
CO5700823A2 (es) 2006-11-30
MXPA05013259A (es) 2006-03-09
WO2004111042A1 (de) 2004-12-23
US20060166829A1 (en) 2006-07-27
KR20060015740A (ko) 2006-02-20
ES2351601T3 (es) 2011-02-08

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