AR059595A1 - Cetoenoles ciclicos sustituidos con cicloalquil- fenilo. composiciones plaguicidas - Google Patents

Cetoenoles ciclicos sustituidos con cicloalquil- fenilo. composiciones plaguicidas

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Publication number
AR059595A1
AR059595A1 ARP070100728A ARP070100728A AR059595A1 AR 059595 A1 AR059595 A1 AR 059595A1 AR P070100728 A ARP070100728 A AR P070100728A AR P070100728 A ARP070100728 A AR P070100728A AR 059595 A1 AR059595 A1 AR 059595A1
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AR
Argentina
Prior art keywords
substituted
alkyl
cycloalkyl
halogen
appropriate
Prior art date
Application number
ARP070100728A
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English (en)
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Bayer Cropscience Ag
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Publication of AR059595A1 publication Critical patent/AR059595A1/es

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00Carboxylic acid amides
    • C07C233/01Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/45Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups
    • C07C233/46Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/51Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to an acyclic carbon atom of a carbon skeleton containing six-membered aromatic rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46N-acyl derivatives
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/46Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings and other rings, e.g. cyclohexylphenylacetic acid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/612Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
    • C07C69/616Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety polycyclic
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D207/00Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36Oxygen or sulfur atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D209/00Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/54Spiro-condensed
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/54Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings condensed with carbocyclic rings or ring systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/60Two oxygen atoms, e.g. succinic anhydride
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/02Systems containing only non-condensed rings with a three-membered ring

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Pyrrole Compounds (AREA)
  • Indole Compounds (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

Procedimientos y productos intermedios para su preparacion y a su uso como plaguicida y/o herbicida. Además la presente se refiere a agentes herbicidas selectivos, que contienen por un lado cetoenoles cíclicos sustituidos con cicloalquil-fenilo y un compuesto de mejora de la tolerancia por las plantas de cultivo por otro lado. La presente se refiere además al aumento del efecto de agentes plaguicidas que contienen compuestos de formula (1) mediante la adicion de sales de amonio o de fosfonio y dado el caso de facilitadores de la penetracion. Reivindicacion 1: Compuestos de formula (1) en la que J representa cicloalquilo dado el caso sustituido, que puede estar interrumpido dado el ceso con heteroátomos, X representa hidrogeno, alquilo, halogeno, halogenoalquilo, alcoxi o halogenoalcoxi, Y representa hidrogeno, alquilo, halogenoalquilo, halogeno, alcoxi o halogenoalcoxi, m representa un numero 1, 2 o 3, con la condicion de que al menos uno de los restos J, X o Y se encuentre en la posicion 2 del resto de fenilo y sea a este respecto distinto de hidrogeno, CKE representa uno de los grupos (1) a (10) en los que A representa hidrogeno, alquilo, alquenilo, alcoxialquilo, alquiltioalquilo respectivamente sustituido dado el caso con halogeno, cicloalquilo dado el caso sustituido, saturado o insaturado, en el que dado el caso al menos un átomo del anillo está reemplazado por un heteroátomo, o representa arilo, arilalquilo o hetarilo respectivamente sustituido dado el caso con halogeno, alquilo, halogenoalquilo, alcoxi, halogenoalcoxi, ciano o nitro, B representa hidrogeno, alquilo o alcoxialquilo, o A y B junto con el átomo de carbono al que están unidos representan un ciclo no sustituido o sustituido, saturado o insaturado, que contiene dado el caso al menos un heteroátomo, D representa hidrogeno o un resto dado el caso sustituido del grupo de alquilo, alquenilo, alquinilo, alcoxialquilo, cicloalquilo saturado o insaturado, en el que dado el caso uno o varios miembros del anillo están reemplazados por heteroátomos, representa arilalquilo, arilo, hetarilalquilo o hetarilo o A y D junto con los átomos a los que están unidos representan un ciclo no sustituido o sustituido en la parte A, D, saturado o insaturado y que contiene dado el caso al menos un heteroátomo (en el caso de CKE = 8 uno más), o A y Q1 juntos representan alcanodiílo o alquenodiílo dado el caso interrumpidos con un grupo carbonilo o heteroátomos, respectivamente sustituidos dado el caso con halogeno, hidroxi, alquilo, alcoxi, alquiltio, cicloalquilo, benciloxi o arilo respectivamente sustituidos dado el caso, en los que dado el caso dos átomos de carbono no directamente adyacentes forman un ciclo adicional dado el caso sustituido, que dado el caso puede estar interrumpido con heteroátomos o D y Q1 junto con los átomos a los que están unidos representan un ciclo no sustituido o sustituido en la parte D, Q1, saturado o insaturado y que contiene dado el caso al menos un heteroátomo, Q1 representa hidrogeno, alquilo, alcoxialquilo, cicloalquilo dado el caso sustituido (en el que está reemplazado dado el caso un grupo metileno con oxigeno o azufre) o fenilo dado el caso sustituido, Q2, Q4, Q5 y Q6 representan independientemente unos de otros hidrogeno o alquilo, Q3 representa hidrogeno, representa alquilo, alcoxialquilo, alquiltioalquilo dado el caso sustituidos, cicloalquilo dado el caso sustituido (en el que está reemplazado dado el caso un grupo metileno por oxigeno o azufre) o fenilo dado el caso sustituido, o Q1 y Q2 representan con el átomo de carbono a! que están unidos un ciclo no sustituido o sustituido que contiene dado el caso un heteroátomo, o Q3 y Q4 junto con el átomo de carbono al que están unidos representan un ciclo no sustituido o sustituido, saturado o insaturado, que contiene dado el caso un heteroátomo, G representa hidrogeno (a) o uno de los grupos (b) a (g), en los que E representa un equivalente de ion metálico o un ion de amonio, L representa oxígeno o azufre, M representa oxígeno o azufre, R1 representa alquilo, alquenilo, alcoxialquilo, alquiltioalquilo, polialcoxialquilo respectivamente sustituido dado e! caso con halogeno o cicloalquilo sustituido dado el caso con halogeno, alquilo o alcoxi, que puede estar interrumpido por a! menos un heteroátomo, fenilo, fenilalquilo, hetarilo, fenoxialquilo o hetariloxialquilo respectivamente sustituidos dado el caso, R2 representa alquilo, alquenilo, alcoxialquilo, polialcoxialquilo respectivamente sustituidos dado el caso con halogeno o representa cicloalquilo, fenilo o bencilo respectivamente sustituidos dado el caso, R3, R4 y R5 representan independientemente uno de otro alquilo, alcoxi, alquilamino, dialquilamino, alquiltio, alqueniltio, cicloalquiltio respectivamente sustituido dado el caso con halogeno, o representan fenilo, bencilo, fenoxi o feniltio respectivamente sustituido dado el caso, R6 y R7 representan independientemente uno de otro hidrogeno, alquilo, cicloalquilo, alquenilo, alcoxi, alcoxialquilo respectivamente sustituido dado el caso con halogeno, fenilo sustituido dado el caso, bencilo sustituido dado el caso, o junto con el átomo de N al que están unidos representan un ciclo interrumpido dado el caso por oxígeno o azufre.
ARP070100728A 2006-02-21 2007-02-21 Cetoenoles ciclicos sustituidos con cicloalquil- fenilo. composiciones plaguicidas AR059595A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102006007882A DE102006007882A1 (de) 2006-02-21 2006-02-21 Cycloalkyl-phenylsubstituierte cyclische Ketoenole

Publications (1)

Publication Number Publication Date
AR059595A1 true AR059595A1 (es) 2008-04-16

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ARP070100728A AR059595A1 (es) 2006-02-21 2007-02-21 Cetoenoles ciclicos sustituidos con cicloalquil- fenilo. composiciones plaguicidas

Country Status (14)

Country Link
US (2) US8013172B2 (es)
EP (4) EP2184275A1 (es)
JP (2) JP5268657B2 (es)
KR (1) KR20080094947A (es)
CN (1) CN101421218B (es)
AR (1) AR059595A1 (es)
AU (1) AU2007218300A1 (es)
BR (1) BRPI0708115B1 (es)
CA (1) CA2642787A1 (es)
DE (1) DE102006007882A1 (es)
EA (1) EA200801864A1 (es)
ES (1) ES2423896T3 (es)
WO (1) WO2007096058A1 (es)
ZA (1) ZA200807013B (es)

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DE102010008643A1 (de) 2010-02-15 2011-08-18 Bayer Schering Pharma Aktiengesellschaft, 13353 Zyklische Ketoenole zur Therapie
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US20120178927A1 (en) 2012-07-12
EA200801864A1 (ru) 2009-02-27
US8541617B2 (en) 2013-09-24
BRPI0708115A2 (pt) 2011-05-17
JP2009527513A (ja) 2009-07-30
JP5268657B2 (ja) 2013-08-21
JP2013100310A (ja) 2013-05-23
EP2184275A1 (de) 2010-05-12
AU2007218300A1 (en) 2007-08-30
CN101421218B (zh) 2012-12-19
ZA200807013B (en) 2009-12-30
CA2642787A1 (en) 2007-08-30
DE102006007882A1 (de) 2007-08-30
KR20080094947A (ko) 2008-10-27
WO2007096058A1 (de) 2007-08-30
EP1989162B1 (de) 2013-07-03
US20090305891A1 (en) 2009-12-10
EP1989162A1 (de) 2008-11-12
US8013172B2 (en) 2011-09-06
BRPI0708115B1 (pt) 2017-01-17
CN101421218A (zh) 2009-04-29
EP2186805A1 (de) 2010-05-19
EP2186791A1 (de) 2010-05-19
ES2423896T3 (es) 2013-09-25

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