ZA200409847B - Method for dying with sulphur and sulphur vat dyes - Google Patents
Method for dying with sulphur and sulphur vat dyes Download PDFInfo
- Publication number
- ZA200409847B ZA200409847B ZA200409847A ZA200409847A ZA200409847B ZA 200409847 B ZA200409847 B ZA 200409847B ZA 200409847 A ZA200409847 A ZA 200409847A ZA 200409847 A ZA200409847 A ZA 200409847A ZA 200409847 B ZA200409847 B ZA 200409847B
- Authority
- ZA
- South Africa
- Prior art keywords
- dyeing
- dye
- dyebath
- electrolytic cell
- sulfur
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 46
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title description 8
- 239000000984 vat dye Substances 0.000 title description 4
- 239000005864 Sulphur Substances 0.000 title 2
- 238000004043 dyeing Methods 0.000 claims abstract description 72
- 239000000988 sulfur dye Substances 0.000 claims abstract description 36
- 230000002829 reductive effect Effects 0.000 claims abstract description 16
- 239000002657 fibrous material Substances 0.000 claims abstract description 11
- 230000001172 regenerating effect Effects 0.000 claims abstract description 4
- 239000000975 dye Substances 0.000 claims description 48
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 7
- 239000012528 membrane Substances 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 235000002639 sodium chloride Nutrition 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- 239000012298 atmosphere Substances 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 239000012670 alkaline solution Substances 0.000 claims description 3
- 239000003792 electrolyte Substances 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- -1 alkali metal salts Chemical class 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 235000011118 potassium hydroxide Nutrition 0.000 claims 1
- 235000017550 sodium carbonate Nutrition 0.000 claims 1
- 229940001593 sodium carbonate Drugs 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 238000010016 exhaust dyeing Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000007254 oxidation reaction Methods 0.000 description 8
- 230000001590 oxidative effect Effects 0.000 description 7
- PGYZAKRTYUHXRA-UHFFFAOYSA-N 2,10-dinitro-12h-[1,4]benzothiazino[3,2-b]phenothiazin-3-one Chemical compound S1C2=CC(=O)C([N+]([O-])=O)=CC2=NC2=C1C=C1SC3=CC=C([N+](=O)[O-])C=C3NC1=C2 PGYZAKRTYUHXRA-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000003638 chemical reducing agent Substances 0.000 description 6
- 238000005868 electrolysis reaction Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- 239000000080 wetting agent Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000005341 cation exchange Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910021607 Silver chloride Inorganic materials 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 3
- 238000009970 yarn dyeing Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010014 continuous dyeing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005518 electrochemistry Effects 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 230000002101 lytic effect Effects 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 241000272470 Circus Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052977 alkali metal sulfide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000002844 continuous effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 125000002228 disulfide group Chemical group 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 238000009981 jet dyeing Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009976 warp beam dyeing Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/243—Polyamides; Polyurethanes using vat or sulfur dyes, indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
- D06P1/221—Reducing systems; Reducing catalysts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/523—Polyesters using vat or sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/6025—Natural or regenerated cellulose using vat or sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2016—Application of electric energy
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
- Treatment Of Fiber Materials (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10234825A DE10234825A1 (de) | 2002-07-31 | 2002-07-31 | Verfahren zum Färben mit Schwefel- und Schwefelküpenfarbstoffen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200409847B true ZA200409847B (en) | 2006-07-26 |
Family
ID=30469240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200409847A ZA200409847B (en) | 2002-07-31 | 2004-12-06 | Method for dying with sulphur and sulphur vat dyes |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20050257327A1 (pt) |
| EP (1) | EP1527228B1 (pt) |
| JP (1) | JP2005534820A (pt) |
| KR (1) | KR20050026542A (pt) |
| CN (1) | CN100351459C (pt) |
| AT (1) | ATE430831T1 (pt) |
| AU (1) | AU2003250143A1 (pt) |
| BR (1) | BR0312606B1 (pt) |
| DE (1) | DE10234825A1 (pt) |
| ES (1) | ES2326315T3 (pt) |
| MX (1) | MXPA05001097A (pt) |
| TW (1) | TWI276722B (pt) |
| WO (1) | WO2004013406A1 (pt) |
| ZA (1) | ZA200409847B (pt) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004040601A1 (de) * | 2004-08-21 | 2006-03-02 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Neuartige flüssige Chinonimin-Schwefelfarbstoff-Zusammensetzungen sowie Verfahren zu ihrer Herstellung und ihre Verwendung zum Färben von cellulosehaltigem Material |
| CN108708100A (zh) * | 2018-05-24 | 2018-10-26 | 武汉纺织大学 | 一种电化学还原染色装置及方法 |
| CN108642760A (zh) * | 2018-05-24 | 2018-10-12 | 武汉纺织大学 | 一种石墨烯电化学还原染色装置及方法 |
| CN108716138A (zh) * | 2018-05-24 | 2018-10-30 | 武汉纺织大学 | 一种单溶质间接电化学还原靛蓝的染液及染色方法 |
| CN108642780A (zh) * | 2018-05-24 | 2018-10-12 | 武汉纺织大学 | 一种以纱线染色辊为阴极的电化学染色装置及方法 |
| CN108754915A (zh) * | 2018-05-24 | 2018-11-06 | 武汉纺织大学 | 电化学染料染色装置及方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1906083A1 (de) * | 1969-02-07 | 1970-08-13 | Cassella Farbwerke Mainkur Ag | Verfahren zur Herstellung reduzierter Schwefelfarbstoffe |
| GB1359275A (en) * | 1972-11-30 | 1974-07-10 | Bombay Textile Research Ass | Vat dye reduction process |
| DE2263138C3 (de) * | 1972-12-22 | 1978-06-29 | The Bombay Textile Research Association, Bombay (Indien) | Verfahren zum Färben von Textilmaterial mit Küpenfarbstoffen und Vorrichtung hierfür |
| JPS5239951B2 (pt) * | 1974-05-28 | 1977-10-07 | ||
| AT398316B (de) * | 1989-06-01 | 1994-11-25 | Verein Zur Foerderung Der Fors | Verfahren zur reduktion von farbstoffen |
| US5632782A (en) * | 1994-09-01 | 1997-05-27 | Clariant Finance (Bvi) Ltd. | Exhaust dyeing process for sulphur dyes |
| JPH1136173A (ja) * | 1997-07-15 | 1999-02-09 | Nishie Denimu:Kk | 着色衣料の脱色方法 |
| AT408455B (de) * | 1997-09-04 | 2001-12-27 | Basf Ag | Verfahren zur reduktion von schwefelfarbstoffen |
| AU1146500A (en) * | 1998-11-24 | 2000-06-13 | Otmar Dossenbach | Method and apparatus for reducing vat and sulfur dyes |
| DE19962155A1 (de) * | 1999-12-22 | 2001-06-28 | Basf Ag | Verfahren zur elektrochemischen Reduktion von Küpenfarbstoffen |
| DE10010059A1 (de) * | 2000-03-02 | 2001-09-06 | Dystar Textilfarben Gmbh & Co | Mediatorsysteme auf Basis gemischter Metallkomplexe zur Reduktion von Farbstoffen |
-
2002
- 2002-07-31 DE DE10234825A patent/DE10234825A1/de not_active Withdrawn
-
2003
- 2003-07-23 KR KR1020057001695A patent/KR20050026542A/ko not_active Application Discontinuation
- 2003-07-23 CN CNB038160072A patent/CN100351459C/zh not_active Expired - Fee Related
- 2003-07-23 BR BRPI0312606-4A patent/BR0312606B1/pt not_active IP Right Cessation
- 2003-07-23 AT AT03766263T patent/ATE430831T1/de not_active IP Right Cessation
- 2003-07-23 AU AU2003250143A patent/AU2003250143A1/en not_active Abandoned
- 2003-07-23 MX MXPA05001097A patent/MXPA05001097A/es active IP Right Grant
- 2003-07-23 JP JP2004525286A patent/JP2005534820A/ja active Pending
- 2003-07-23 US US10/521,917 patent/US20050257327A1/en not_active Abandoned
- 2003-07-23 EP EP03766263A patent/EP1527228B1/de not_active Expired - Lifetime
- 2003-07-23 ES ES03766263T patent/ES2326315T3/es not_active Expired - Lifetime
- 2003-07-23 WO PCT/EP2003/008050 patent/WO2004013406A1/de active Application Filing
- 2003-07-29 TW TW092120699A patent/TWI276722B/zh not_active IP Right Cessation
-
2004
- 2004-12-06 ZA ZA200409847A patent/ZA200409847B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE10234825A1 (de) | 2004-02-19 |
| JP2005534820A (ja) | 2005-11-17 |
| KR20050026542A (ko) | 2005-03-15 |
| BR0312606B1 (pt) | 2012-11-27 |
| MXPA05001097A (es) | 2005-05-27 |
| ATE430831T1 (de) | 2009-05-15 |
| EP1527228A1 (de) | 2005-05-04 |
| CN1665983A (zh) | 2005-09-07 |
| ES2326315T3 (es) | 2009-10-07 |
| AU2003250143A1 (en) | 2004-02-23 |
| EP1527228B1 (de) | 2009-05-06 |
| US20050257327A1 (en) | 2005-11-24 |
| BR0312606A (pt) | 2005-04-19 |
| CN100351459C (zh) | 2007-11-28 |
| WO2004013406A1 (de) | 2004-02-12 |
| TWI276722B (en) | 2007-03-21 |
| TW200407485A (en) | 2004-05-16 |
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