ZA200303456B - Ligand and complex for catalytically bleaching a substrate. - Google Patents
Ligand and complex for catalytically bleaching a substrate. Download PDFInfo
- Publication number
- ZA200303456B ZA200303456B ZA200303456A ZA200303456A ZA200303456B ZA 200303456 B ZA200303456 B ZA 200303456B ZA 200303456 A ZA200303456 A ZA 200303456A ZA 200303456 A ZA200303456 A ZA 200303456A ZA 200303456 B ZA200303456 B ZA 200303456B
- Authority
- ZA
- South Africa
- Prior art keywords
- alkyl
- bleaching composition
- composition according
- pyridin
- ligand
- Prior art date
Links
- 238000004061 bleaching Methods 0.000 title claims description 59
- 239000003446 ligand Substances 0.000 title claims description 49
- 239000000758 substrate Substances 0.000 title description 19
- 239000000203 mixture Substances 0.000 claims description 49
- 239000003054 catalyst Substances 0.000 claims description 26
- 229910052723 transition metal Inorganic materials 0.000 claims description 20
- 150000003624 transition metals Chemical class 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 125000000592 heterocycloalkyl group Chemical group 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 11
- 125000001072 heteroaryl group Chemical group 0.000 claims description 10
- -1 3-ethyl-pyridin-2-ylmethyl Chemical group 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 125000006514 pyridin-2-ylmethyl group Chemical group [H]C1=C([H])C([H])=C([H])C(=N1)C([H])([H])* 0.000 claims description 8
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 125000005842 heteroatom Chemical group 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 6
- 125000004429 atom Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 claims description 6
- 125000000041 C6-C10 aryl group Chemical group 0.000 claims description 5
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 4
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000969 carrier Substances 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- 125000000160 oxazolidinyl group Chemical group 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000003386 piperidinyl group Chemical group 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 3
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
- 125000003363 1,3,5-triazinyl group Chemical group N1=C(N=CN=C1)* 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims description 2
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical compound C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 claims description 2
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims description 2
- CRVQUYKCAULKGD-UHFFFAOYSA-N diethyl 7-benzyl-3-(2-hydroxyethyl)-9-oxo-2,4-dipyridin-2-yl-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate Chemical compound C1C(C2=O)(C(=O)OCC)C(C=3N=CC=CC=3)N(CCO)C(C=3N=CC=CC=3)C2(C(=O)OCC)CN1CC1=CC=CC=C1 CRVQUYKCAULKGD-UHFFFAOYSA-N 0.000 claims description 2
- QYDODLCXGSAOQP-UHFFFAOYSA-N dimethyl 9-oxo-2,4-dipyridin-2-yl-3,7-bis(pyridin-2-ylmethyl)-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate Chemical compound C1C(C2=O)(C(=O)OC)C(C=3N=CC=CC=3)N(CC=3N=CC=CC=3)C(C=3N=CC=CC=3)C2(C(=O)OC)CN1CC1=CC=CC=N1 QYDODLCXGSAOQP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002883 imidazolyl group Chemical group 0.000 claims description 2
- 125000001041 indolyl group Chemical group 0.000 claims description 2
- 125000000904 isoindolyl group Chemical group C=1(NC=C2C=CC=CC12)* 0.000 claims description 2
- 125000002183 isoquinolinyl group Chemical group C1(=NC=CC2=CC=CC=C12)* 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 125000002757 morpholinyl group Chemical group 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 229960005141 piperazine Drugs 0.000 claims description 2
- 125000004193 piperazinyl group Chemical group 0.000 claims description 2
- 125000003373 pyrazinyl group Chemical group 0.000 claims description 2
- 125000003226 pyrazolyl group Chemical group 0.000 claims description 2
- 125000002098 pyridazinyl group Chemical group 0.000 claims description 2
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- 125000000714 pyrimidinyl group Chemical group 0.000 claims description 2
- 125000000719 pyrrolidinyl group Chemical group 0.000 claims description 2
- 125000001422 pyrrolinyl group Chemical group 0.000 claims description 2
- 125000000168 pyrrolyl group Chemical group 0.000 claims description 2
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 125000003718 tetrahydrofuranyl group Chemical group 0.000 claims description 2
- 125000001412 tetrahydropyranyl group Chemical group 0.000 claims description 2
- 125000003507 tetrahydrothiofenyl group Chemical group 0.000 claims description 2
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 claims description 2
- 125000000335 thiazolyl group Chemical group 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 125000001425 triazolyl group Chemical group 0.000 claims description 2
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- KKBIDYUDILUCRS-UHFFFAOYSA-N 6-[1,5-bis(methoxycarbonyl)-7-methyl-9-oxo-2,4-dipyridin-2-yl-3,7-diazabicyclo[3.3.1]nonan-3-yl]hexanoic acid Chemical compound O=C1C2(C(=O)OC)CN(C)CC1(C(=O)OC)C(C=1N=CC=CC=1)N(CCCCCC(O)=O)C2C1=CC=CC=N1 KKBIDYUDILUCRS-UHFFFAOYSA-N 0.000 claims 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims 1
- PTMNLCONTSIMOX-UHFFFAOYSA-N diethyl 9-oxo-2,4-dipyridin-2-yl-7-(pyridin-2-ylmethyl)-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate Chemical compound C(C)OC(=O)C12C(NC(C(CN(C1)CC1=NC=CC=C1)(C2=O)C(=O)OCC)C1=NC=CC=C1)C1=NC=CC=C1 PTMNLCONTSIMOX-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 description 26
- 239000004753 textile Substances 0.000 description 17
- 229910052760 oxygen Inorganic materials 0.000 description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
- 239000001301 oxygen Substances 0.000 description 12
- 238000005406 washing Methods 0.000 description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000004744 fabric Substances 0.000 description 8
- 150000002431 hydrogen Chemical group 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 239000007844 bleaching agent Substances 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 7
- 229940097156 peroxyl Drugs 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000002609 medium Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 230000004913 activation Effects 0.000 description 4
- 239000012736 aqueous medium Substances 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000005108 dry cleaning Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000003094 microcapsule Substances 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000004076 pulp bleaching Methods 0.000 description 2
- 238000012552 review Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 125000000547 substituted alkyl group Chemical group 0.000 description 2
- 125000003107 substituted aryl group Chemical group 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 101100134922 Gallus gallus COR5 gene Proteins 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 238000006683 Mannich reaction Methods 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- QJXIPSUPIMSFIQ-UHFFFAOYSA-N dimethyl 7-benzyl-3-(2-hydroxyethyl)-9-oxo-2,4-dipyridin-2-yl-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate Chemical compound C1C(C2=O)(C(=O)OC)C(C=3N=CC=CC=3)N(CCO)C(C=3N=CC=CC=3)C2(C(=O)OC)CN1CC1=CC=CC=C1 QJXIPSUPIMSFIQ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000010952 in-situ formation Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000009896 oxidative bleaching Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 125000001567 quinoxalinyl group Chemical group N1=C(C=NC2=CC=CC=C12)* 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/08—Bridged systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0030673.8A GB0030673D0 (en) | 2000-12-15 | 2000-12-15 | Ligand and complex for catalytically bleaching a substrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200303456B true ZA200303456B (en) | 2004-08-13 |
Family
ID=9905193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200303456A ZA200303456B (en) | 2000-12-15 | 2003-05-06 | Ligand and complex for catalytically bleaching a substrate. |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US6818149B2 (zh) |
| EP (1) | EP1379618B1 (zh) |
| CN (1) | CN1246432C (zh) |
| AR (1) | AR031908A1 (zh) |
| AT (1) | ATE329993T1 (zh) |
| AU (2) | AU2002233187B2 (zh) |
| BR (1) | BR0116135B1 (zh) |
| CA (1) | CA2429629C (zh) |
| CZ (1) | CZ304488B6 (zh) |
| DE (1) | DE60120781T2 (zh) |
| ES (1) | ES2264707T3 (zh) |
| GB (1) | GB0030673D0 (zh) |
| HU (1) | HU229930B1 (zh) |
| MX (1) | MXPA03004887A (zh) |
| MY (1) | MY127232A (zh) |
| PL (1) | PL205956B1 (zh) |
| RU (1) | RU2283342C2 (zh) |
| WO (1) | WO2002048301A1 (zh) |
| ZA (1) | ZA200303456B (zh) |
Families Citing this family (83)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0030673D0 (en) * | 2000-12-15 | 2001-01-31 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| JP4104966B2 (ja) * | 2002-03-06 | 2008-06-18 | 花王株式会社 | 漂白触媒 |
| GB0212991D0 (en) * | 2002-06-06 | 2002-07-17 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0212995D0 (en) * | 2002-06-06 | 2002-07-17 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| EP1523482A1 (en) * | 2002-06-06 | 2005-04-20 | Unilever N.V. | Ligand and complex for catalytically bleaching a substrate |
| DE10257279A1 (de) * | 2002-12-07 | 2004-06-24 | Clariant Gmbh | Flüssige Bleichmittelkomponenten enthaltend amphiphile Polymere |
| MXPA05011353A (es) * | 2003-04-22 | 2005-11-28 | Anormed Inc | Compuestos heterociclicos que se unen al receptor de quimiocina con eficacia mejorada. |
| GB0323275D0 (en) * | 2003-10-04 | 2003-11-05 | Unilever Plc | Bleaching composition |
| GB0325430D0 (en) * | 2003-10-31 | 2003-12-03 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0325432D0 (en) * | 2003-10-31 | 2003-12-03 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0413058D0 (en) * | 2004-06-11 | 2004-07-14 | Unilever Plc | Bleaching composition |
| EP2009088B1 (en) | 2004-09-23 | 2010-02-24 | Unilever PLC | Laundry treatment compositions |
| EP1700904A1 (en) | 2005-03-11 | 2006-09-13 | Unilever N.V. | Liquid detergent composition |
| EP1700907A1 (en) | 2005-03-11 | 2006-09-13 | Unilever N.V. | Liquid bleaching composition |
| DE102005027619A1 (de) * | 2005-06-15 | 2006-12-28 | Clariant Produkte (Deutschland) Gmbh | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Verbindungen |
| WO2007051255A1 (en) * | 2005-11-04 | 2007-05-10 | The University Of Sydney | Process for the preparation of compounds containing an azacyclic ring system |
| ES2349082T3 (es) | 2006-07-07 | 2010-12-27 | Unilever Plc | Endurecimiento de un líquido. |
| EP2103735A1 (en) | 2008-03-18 | 2009-09-23 | Unilever PLC | Catalytic bleaching of substrates |
| CN101990464B (zh) | 2008-04-09 | 2013-10-23 | 巴斯夫欧洲公司 | 金属酰肼配位化合物作为氧化催化剂的用途 |
| DE102008024084A1 (de) * | 2008-05-17 | 2009-11-19 | Clariant International Ltd. | Wasch- und Reinigungsmittel |
| DE102008038376A1 (de) * | 2008-08-19 | 2010-02-25 | Clariant International Ltd. | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Verbindungen |
| DE102008045215A1 (de) | 2008-08-30 | 2010-03-04 | Clariant International Ltd. | Verwendung von Mangan-Oxalatenn als Bleichkatalysatoren |
| DE102008064009A1 (de) | 2008-12-19 | 2010-06-24 | Clariant International Ltd. | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metall-Komplexen |
| EP2228429A1 (en) | 2009-03-13 | 2010-09-15 | Unilever PLC | Shading dye and catalyst combination |
| EP2343336A1 (en) | 2010-01-06 | 2011-07-13 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Curing liquids |
| DE102010007058A1 (de) | 2010-02-06 | 2011-08-11 | Clariant International Limited | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metallkomplex-Lösungen |
| DE102010007059A1 (de) | 2010-02-06 | 2011-08-11 | Clariant International Limited | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metallkomplexen |
| BR112012024804B1 (pt) | 2010-03-30 | 2020-12-15 | Unilever N.V | Processo para a incorporação de microcápsulas com carga aniônica em um detergente líquido concentrado aquoso estruturado |
| CN101811068B (zh) * | 2010-03-31 | 2012-05-30 | 上海师范大学 | 哌嗪功能化有序介孔酚醛树脂固体碱催化剂的制备方法 |
| EP2553072B1 (en) | 2010-04-01 | 2015-05-06 | Unilever PLC | Structuring detergent liquids with hydrogenated castor oil |
| WO2011124282A1 (en) | 2010-04-08 | 2011-10-13 | Dsm Ip Assets B.V. | Unsaturated polyester resin or vinyl ester resin compositions |
| RU2572965C2 (ru) | 2010-06-16 | 2016-01-20 | Акцо Нобель Кемикалз Интернэшнл Б.В. | Раствор ускорителя и способ отверждения отверждаемых смол |
| KR101831472B1 (ko) | 2010-06-28 | 2018-02-22 | 바스프 에스이 | 금속 비함유 표백 조성물 |
| WO2012048815A1 (de) | 2010-10-11 | 2012-04-19 | Clariant International Ltd. | Verfahren zur herstellung von 3,7-diaza-bicyclo[3.3.1]nonan-metallkomplexen |
| EP2441820A1 (en) | 2010-10-14 | 2012-04-18 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Laundry detergent particles |
| CN103154220B (zh) | 2010-10-22 | 2015-11-25 | 荷兰联合利华有限公司 | 与洗衣产品有关的改进 |
| PT2652025T (pt) | 2010-12-15 | 2018-11-02 | Ppg Europe B V | Composição secante e a sua utilização |
| EP2474578A1 (en) | 2011-01-06 | 2012-07-11 | Rahu Catalytics Limited | Antiskinning compositions |
| BR112013019386B1 (pt) | 2011-01-31 | 2021-04-06 | Unilever Ip Holdings B.V. | Composição aquosa líquida detergente concentrada isotrópica alcalina |
| EP2495300A1 (en) | 2011-03-04 | 2012-09-05 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Structuring detergent liquids with hydrogenated castor oil |
| EP2476743B1 (en) | 2011-04-04 | 2013-04-24 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Method of laundering fabric |
| EP2522714A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
| CN103517975B (zh) | 2011-05-13 | 2015-11-25 | 荷兰联合利华有限公司 | 水性浓缩衣物洗涤剂组合物 |
| EP2522715A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
| US9145501B2 (en) | 2011-09-26 | 2015-09-29 | Ppg Europe Bv | Coating composition and use thereof |
| US20140298591A1 (en) | 2011-10-25 | 2014-10-09 | Basf Se | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
| BR112014010011A8 (pt) | 2011-10-25 | 2017-12-19 | Basf Se | Uso de um ou mais copolímeros de acrilato, método para impedir a redeposição de sujeira nos artigos têxteis e para a libertação da sujeira dos artigos têxteis, e, composições de detergente |
| CN103174008A (zh) * | 2011-11-24 | 2013-06-26 | 东华大学 | 二吡啶基四氮金属配合物在纺织品低温练漂助剂中的应用 |
| WO2013083632A1 (en) | 2011-12-06 | 2013-06-13 | Dsm Ip Assets B.V. | Multi-component system |
| US20140309378A1 (en) | 2011-12-06 | 2014-10-16 | Dsm Ip Assets B.V. | Resin composition |
| BR112014014724A8 (pt) | 2011-12-20 | 2017-07-04 | Unilever Nv | composição líquida detergente, método de branquear por ar uma superfície e uso da combinação |
| BR112014013942B1 (pt) | 2011-12-20 | 2021-03-02 | Unilever Ip Holdings B.V | composição detergente líquida isotrópica |
| WO2013171210A1 (en) | 2012-05-16 | 2013-11-21 | Unilever Plc | Laundry detergent compositions comprising polyalkoxylated polyethyleneimine |
| EP2912112B1 (en) | 2012-10-29 | 2019-12-18 | Ashland Licensing and Intellectual Property LLC | Resin compositions |
| CN104937090B (zh) | 2013-01-23 | 2018-10-09 | 荷兰联合利华有限公司 | 促进抗颗粒状污垢再沉积的未着色洗衣添加剂材料 |
| EP2770044A1 (en) | 2013-02-20 | 2014-08-27 | Unilever PLC | Lamellar gel with amine oxide |
| US9790452B2 (en) | 2013-03-27 | 2017-10-17 | Basf Se | Block copolymers as soil release agents in laundry processes |
| EP3024898B1 (en) | 2013-07-25 | 2017-11-08 | OMG UK Technology Limited | Encapsulated catalysts |
| ES2894685T3 (es) | 2013-08-16 | 2022-02-15 | Catexel Tech Limited | Composición |
| CN103602268B (zh) * | 2013-10-10 | 2015-09-02 | 中钞油墨有限公司 | 环保型催干剂及其油墨组合物 |
| MX2016006982A (es) | 2013-11-27 | 2017-01-09 | Basf Se | Copolimeros aleatorios como agentes de liberacion de suciedad en procesos de lavado. |
| CA2930749C (en) | 2013-12-03 | 2022-03-15 | Ppg Europe B.V. | Drier composition and use thereof |
| EP3277784A1 (en) | 2015-04-02 | 2018-02-07 | Unilever Plc. | Composition |
| AR104939A1 (es) | 2015-06-10 | 2017-08-23 | Chemsenti Ltd | Método oxidativo para generar dióxido de cloro |
| AR104940A1 (es) | 2015-06-10 | 2017-08-23 | Chemsenti Ltd | Método para generar dióxido de cloro |
| WO2017186480A1 (en) | 2016-04-26 | 2017-11-02 | Basf Se | Metal free bleaching composition |
| WO2017198574A1 (en) | 2016-05-17 | 2017-11-23 | Unilever Plc | Liquid laundry detergent compositions |
| AU2017267050B2 (en) | 2016-05-17 | 2020-03-05 | Unilever Global Ip Limited | Liquid laundry detergent compositions |
| WO2017202923A1 (en) | 2016-05-27 | 2017-11-30 | Unilever Plc | Laundry composition |
| EP3272823A1 (en) * | 2016-07-19 | 2018-01-24 | ALLNEX AUSTRIA GmbH | Drier compositions for alkyd resins |
| WO2018127390A1 (en) | 2017-01-06 | 2018-07-12 | Unilever N.V. | Stain removing composition |
| WO2019038186A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
| WO2019038187A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
| EP3818116A1 (en) | 2018-07-05 | 2021-05-12 | Catexel Technologies Limited | Oxidatively curable coating composition |
| WO2020008203A1 (en) | 2018-07-05 | 2020-01-09 | Catexel Limited | Liquids |
| US11518834B2 (en) | 2019-01-02 | 2022-12-06 | Polynt Composites USA, Inc. | Radically polymerizable compositions |
| CZ309741B6 (cs) | 2020-06-24 | 2023-09-06 | Univerzita Pardubice | Nátěrová hmota obsahující sikativy na bázi sloučenin vanadu s kompenzujícími anionty sulfonových kyselin |
| EP3967742A1 (en) | 2020-09-15 | 2022-03-16 | WeylChem Performance Products GmbH | Compositions comprising bleaching catalyst, manufacturing process thereof, and bleaching and cleaning agent comprising same |
| WO2023030700A1 (en) | 2021-08-30 | 2023-03-09 | Borchers Gmbh | Process for improving resin performance |
| WO2023052294A1 (en) | 2021-09-30 | 2023-04-06 | Borchers Gmbh | Process for improving resin performance using lewis acids |
| WO2023117421A1 (en) | 2021-12-22 | 2023-06-29 | Borchers Gmbh | Paints containing driers based on vanadium compounds bearing various acid anions |
| EP4299702A1 (en) * | 2022-06-27 | 2024-01-03 | The Procter & Gamble Company | A solid free-flowing particulate laundry detergent composition |
| EP4299704A1 (en) * | 2022-06-27 | 2024-01-03 | The Procter & Gamble Company | A method of laundering and drying fabric |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3278670D1 (en) | 1981-07-13 | 1988-07-21 | Procter & Gamble | Foaming surfactant compositions |
| GB8803036D0 (en) | 1988-02-10 | 1988-03-09 | Unilever Plc | Liquid detergents |
| GB8813978D0 (en) | 1988-06-13 | 1988-07-20 | Unilever Plc | Liquid detergents |
| US5194416A (en) * | 1991-11-26 | 1993-03-16 | Lever Brothers Company, Division Of Conopco, Inc. | Manganese catalyst for activating hydrogen peroxide bleaching |
| DK144192D0 (da) | 1992-12-01 | 1992-12-01 | Novo Nordisk As | Aktivering af enzymer |
| DK144392D0 (da) | 1992-12-01 | 1992-12-01 | Novo Nordisk As | Aktivering af enzymer |
| BR9307576A (pt) | 1992-12-01 | 1999-06-15 | Novo Nordisk As | Processo para oxidar um substrato com uma enzima peroxidase ou um composto atuando como peroxidase na presença de uma fonte de peróxido de hidrogênio aditivo detergente e composição detergente |
| AU6870096A (en) | 1995-09-19 | 1997-04-09 | Novo Nordisk A/S | Stain bleaching |
| CA2245951A1 (en) | 1996-02-20 | 1997-08-28 | Petrus Johannes Van Leeuwen | A cleaning composition comprising peroxidase |
| AU2287697A (en) * | 1996-04-10 | 1997-10-29 | Unilever Plc | Cleaning process |
| CA2257891A1 (en) * | 1996-06-19 | 1997-12-24 | Roelant Mathijs Hermant | Bleach activation by an iron catalyst comprising a polydentate ligand containing at least six heteroatoms |
| US5850086A (en) * | 1996-06-21 | 1998-12-15 | Regents Of The University Of Minnesota | Iron complexes for bleach activation and stereospecific oxidation |
| JP4472787B2 (ja) | 1997-02-26 | 2010-06-02 | ノボザイムス アクティーゼルスカブ | 微生物キシログルカン エンドトランスグリコシラーゼ（ｘｅｔ） |
| US20030017941A1 (en) * | 1997-03-07 | 2003-01-23 | The Procter & Gamble Company | Catalysts and methods for catalytic oxidation |
| CA2294925A1 (en) | 1997-06-23 | 1998-12-30 | The Procter & Gamble Company | Enzymatic detergent compositions |
| JP2002508027A (ja) | 1997-07-09 | 2002-03-12 | ザ、プロクター、エンド、ギャンブル、カンパニー | 特定オキシゲナーゼを含む洗剤組成物 |
| ES2185031T3 (es) | 1997-07-09 | 2003-04-16 | Procter & Gamble | Composiciones de limpieza que comprenden un citocromo. |
| AU3799897A (en) | 1997-07-09 | 1999-02-08 | Procter & Gamble Company, The | Cleaning compositions comprising a specific oxygenase |
| AU3667797A (en) | 1997-07-09 | 1999-02-08 | Procter & Gamble Company, The | Cleaning compositions comprising a specific oxygenase |
| WO1999023887A1 (en) | 1997-11-10 | 1999-05-20 | Novo Nordisk A/S | Antimicrobial activity of laccases |
| WO1999065905A1 (en) | 1998-06-15 | 1999-12-23 | Unilever Plc | Bleach catalysts and formulations containing them |
| PH11999002190B1 (en) | 1998-09-01 | 2007-08-06 | Unilever Nv | Composition and method for bleaching a substrate |
| PH11999002188B1 (en) * | 1998-09-01 | 2007-08-06 | Unilever Nv | Method of treating a textile |
| BR9915319A (pt) | 1998-11-13 | 2001-08-07 | Procter & Gamble | Composições alvejantes |
| US6117833A (en) * | 1998-12-16 | 2000-09-12 | Lever Brothers Company | Bleaching compositions and method for bleaching substrates directly with air |
| AU4061900A (en) * | 1999-04-01 | 2000-10-23 | Procter & Gamble Company, The | Transition metal bleaching agents |
| GB0005090D0 (en) * | 2000-03-01 | 2000-04-26 | Unilever Plc | Bleaching and dye transfer inhibiting composition and method for laundry fabrics |
| GB0030673D0 (en) * | 2000-12-15 | 2001-01-31 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0030877D0 (en) * | 2000-12-18 | 2001-01-31 | Unilever Plc | Enhancement of air bleaching catalysts |
-
2000
- 2000-12-15 GB GBGB0030673.8A patent/GB0030673D0/en not_active Ceased
-
2001
- 2001-11-15 CA CA2429629A patent/CA2429629C/en not_active Expired - Fee Related
- 2001-11-15 MX MXPA03004887A patent/MXPA03004887A/es unknown
- 2001-11-15 PL PL366179A patent/PL205956B1/pl unknown
- 2001-11-15 AU AU2002233187A patent/AU2002233187B2/en not_active Ceased
- 2001-11-15 EP EP01984742A patent/EP1379618B1/en not_active Expired - Lifetime
- 2001-11-15 CN CNB018205623A patent/CN1246432C/zh not_active Expired - Fee Related
- 2001-11-15 DE DE60120781T patent/DE60120781T2/de not_active Expired - Lifetime
- 2001-11-15 WO PCT/EP2001/013314 patent/WO2002048301A1/en active IP Right Grant
- 2001-11-15 HU HU0302768A patent/HU229930B1/hu not_active IP Right Cessation
- 2001-11-15 BR BRPI0116135-0A patent/BR0116135B1/pt not_active IP Right Cessation
- 2001-11-15 RU RU2003121409/04A patent/RU2283342C2/ru not_active IP Right Cessation
- 2001-11-15 CZ CZ2003-1655A patent/CZ304488B6/cs not_active IP Right Cessation
- 2001-11-15 AU AU3318702A patent/AU3318702A/xx active Pending
- 2001-11-15 ES ES01984742T patent/ES2264707T3/es not_active Expired - Lifetime
- 2001-11-15 AT AT01984742T patent/ATE329993T1/de not_active IP Right Cessation
- 2001-12-12 AR ARP010105769A patent/AR031908A1/es not_active Application Discontinuation
- 2001-12-13 MY MYPI20015688A patent/MY127232A/en unknown
- 2001-12-14 US US10/021,884 patent/US6818149B2/en not_active Expired - Lifetime
-
2003
- 2003-05-06 ZA ZA200303456A patent/ZA200303456B/en unknown
-
2004
- 2004-08-11 US US10/916,302 patent/US20050032662A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CZ304488B6 (cs) | 2014-05-28 |
| ES2264707T3 (es) | 2007-01-16 |
| EP1379618A1 (en) | 2004-01-14 |
| US20050032662A1 (en) | 2005-02-10 |
| CN1246432C (zh) | 2006-03-22 |
| RU2283342C2 (ru) | 2006-09-10 |
| CZ20031655A3 (cs) | 2003-12-17 |
| EP1379618B1 (en) | 2006-06-14 |
| PL366179A1 (en) | 2005-01-24 |
| US20020149000A1 (en) | 2002-10-17 |
| PL205956B1 (pl) | 2010-06-30 |
| WO2002048301A1 (en) | 2002-06-20 |
| HU229930B1 (hu) | 2015-01-28 |
| HUP0302768A3 (en) | 2012-10-29 |
| HUP0302768A2 (hu) | 2003-11-28 |
| BR0116135B1 (pt) | 2012-06-12 |
| ATE329993T1 (de) | 2006-07-15 |
| AU3318702A (en) | 2002-06-24 |
| GB0030673D0 (en) | 2001-01-31 |
| CA2429629A1 (en) | 2002-06-20 |
| DE60120781T2 (de) | 2007-01-25 |
| MXPA03004887A (es) | 2003-08-19 |
| BR0116135A (pt) | 2003-10-28 |
| AR031908A1 (es) | 2003-10-08 |
| CA2429629C (en) | 2011-05-31 |
| DE60120781D1 (de) | 2006-07-27 |
| CN1481435A (zh) | 2004-03-10 |
| AU2002233187B2 (en) | 2006-03-30 |
| US6818149B2 (en) | 2004-11-16 |
| MY127232A (en) | 2006-11-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ZA200303456B (en) | Ligand and complex for catalytically bleaching a substrate. | |
| AU2004285647B2 (en) | Bispidon-derivated ligands and complex for catalytically bleaching a substrate | |
| AU2002233187A1 (en) | Ligand and complex for catalytically bleaching a substrate | |
| US20030232732A1 (en) | Ligand and complex for catalytically bleaching a substrate | |
| EP1280794B1 (en) | Diazacycloalkane derivatives as bleach catalyst and composition and method for bleaching a substrate | |
| US20040014625A1 (en) | Ligand and complex for catalytically bleaching a substrate | |
| AU757351B2 (en) | Composition and method for bleaching a substrate | |
| CZ20013526A3 (cs) | Bělící prostředek | |
| WO2002081613A1 (en) | Composition and method for bleaching a substrate | |
| JP4260297B2 (ja) | 漂白活性化剤 | |
| CA2383935A1 (en) | Composition and method for bleaching a substrate | |
| AU6571600A (en) | Composition and method for bleaching a substrate | |
| AU7410400A (en) | Composition and method for bleaching a substrate | |
| ZA200106939B (en) | Composition and method for bleaching a substrate. | |
| US20030228994A1 (en) | Enhancement of bleaching catalysts |