YU4099A - Postupak za selektivnu proizvodnju sirćetne kiseline i za to pogodni katalizatori - Google Patents
Postupak za selektivnu proizvodnju sirćetne kiseline i za to pogodni katalizatoriInfo
- Publication number
- YU4099A YU4099A YU4099A YU4099A YU4099A YU 4099 A YU4099 A YU 4099A YU 4099 A YU4099 A YU 4099A YU 4099 A YU4099 A YU 4099A YU 4099 A YU4099 A YU 4099A
- Authority
- YU
- Yugoslavia
- Prior art keywords
- acetic acid
- elements
- preparation process
- oxygen
- selective preparation
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 9
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 229910052758 niobium Inorganic materials 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 229910052714 tellurium Inorganic materials 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6525—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Pronalazak se odnosi na postupak za selektivnu proizvodnju sirćetne kiseline od gasovite sirovine za reaktor od etana, etilena ili njihovih smeša, kao i kiseonika na povišenoj temperaturi, pri čemu se gas za dovodjenje u reaktor dovodi u kontakt sa katalizatorom, koji sadrži elemente Mo, Pd, X i Y u odnosu u gramatomima a:b:c:d u kombinaciji sa kiseonikom prema formuli (I) MoaPdbXcYd, i simboli X i Y imaju sledeće značenje: X predstavlja jedan ili više elemenata iz grupe Cr, Mn, Nb, Ta, Ti, V, Te i/ili W; naročito Nb, V i W; Y predstavlja jedan ili više elemenata iz grupe B, Al, Ga, In, Pt, Zn, Cd, Bi, Ce, Co, Rh, Ir, Cu, Ag, Au, Fe, Ru, Os, K, Rb, Cs, Mg, Ca, Sr, Ba, Zr, Hf, Ni, P, Pb, Sb, Si, Sn, Tl i U, naročito Ca, Sb, Te ili Li. Pronalazak se odnosi i na katalizator za selektivnu proizvodnju sirćetne kiseline, koji sadrži elemente Mo, Pd, X i Y u odnosu izraženom u gramatomima a:b:c:d u kombinaciji sa kiseonikom. Oznake a, b, c i d predstavljaju odnose odgovarajućih elemenata u gramatomima, pri čemu je a = 1, b > 0, c > 0 i d = 0,05 do 2.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19630832A DE19630832A1 (de) | 1996-07-31 | 1996-07-31 | Verfahren zur selektiven Herstellung von Essigsäure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| YU4099A true YU4099A (sh) | 1999-12-27 |
| RS49592B RS49592B (sr) | 2007-06-04 |
Family
ID=7801332
Country Status (28)
| Country | Link |
|---|---|
| US (2) | USRE39074E1 (sh) |
| EP (1) | EP0915821B1 (sh) |
| JP (1) | JP3992112B2 (sh) |
| KR (1) | KR100554189B1 (sh) |
| CN (1) | CN100360493C (sh) |
| AR (2) | AR008101A1 (sh) |
| AT (1) | ATE209175T1 (sh) |
| AU (1) | AU716609B2 (sh) |
| BG (1) | BG103119A (sh) |
| BR (1) | BR9710906B1 (sh) |
| CA (1) | CA2261894C (sh) |
| CZ (1) | CZ294658B6 (sh) |
| DE (2) | DE19630832A1 (sh) |
| DK (1) | DK0915821T3 (sh) |
| ES (1) | ES2167781T3 (sh) |
| ID (1) | ID18000A (sh) |
| MY (1) | MY120427A (sh) |
| NO (1) | NO323890B1 (sh) |
| NZ (1) | NZ333950A (sh) |
| PL (1) | PL188010B1 (sh) |
| RS (1) | RS49592B (sh) |
| RU (1) | RU2198869C2 (sh) |
| SI (1) | SI9720051A (sh) |
| TR (1) | TR199900162T2 (sh) |
| TW (1) | TW427971B (sh) |
| UA (1) | UA55420C2 (sh) |
| WO (1) | WO1998005619A1 (sh) |
| ZA (1) | ZA976793B (sh) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7189377B1 (en) * | 1996-08-07 | 2007-03-13 | Bp Chemicals Limited | Apparatus for performing integrated process for reproduction of vinyl acetate and/or acetic acid using a fluidized bed |
| DE19745902A1 (de) * | 1997-10-17 | 1999-04-22 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
| US6030920A (en) * | 1997-12-24 | 2000-02-29 | Saudi Basic Industries Corporation | Catalysts for producing acetic acid from ethane oxidation, processes of making same and method of using same |
| GB9807142D0 (en) | 1998-04-02 | 1998-06-03 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
| US6087297A (en) * | 1998-06-29 | 2000-07-11 | Saudi Basic Industries Corporation | Catalysts for gas phase production of acetic acid from ethane, processes of making the same and methods of using same |
| US6028221A (en) | 1998-06-29 | 2000-02-22 | Saudi Basic Industries Corporation | Catalyst systems for the one step gas phase production of acetic acid from ethylene and methods of making and using the same |
| GB9819221D0 (en) * | 1998-09-04 | 1998-10-28 | Bp Chem Int Ltd | Process for the production of acetic acid |
| US6114278A (en) * | 1998-11-16 | 2000-09-05 | Saudi Basic Industries Corporation | Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same |
| US6060421A (en) * | 1998-12-23 | 2000-05-09 | Saudi Basic Industries Corporation | Catalysts for the oxidation of ethane to acetic acid, methods of making and using the same |
| GB9907704D0 (en) | 1999-04-01 | 1999-05-26 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
| US6143921A (en) | 1999-05-14 | 2000-11-07 | Saudi Basic Industries Corporation | Method for producing vinyl acetate monomer from ethane or ethylene oxidation |
| JP4809532B2 (ja) * | 1999-11-15 | 2011-11-09 | サウディ ベーシック インダストリーズ コーポレイション | プロパンのアクリル酸への接触酸化用触媒、その製造法及び使用法 |
| US6531631B1 (en) | 2000-04-28 | 2003-03-11 | Saudi Basic Industries Corporation | Oxidation of ethane to acetic acid and ethylene using molybdenum and vanadium based catalysts |
| US6441227B1 (en) * | 2000-06-23 | 2002-08-27 | Saudi Basic Industries Corporation | Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hydrocarbons |
| DE10055810A1 (de) * | 2000-11-10 | 2002-05-23 | Aventis Res & Tech Gmbh & Co | Verfahren zur Herstellung von Essigsäure |
| US6841699B2 (en) * | 2001-04-25 | 2005-01-11 | Rohm And Haas Company | Recalcined catalyst |
| KR20030035896A (ko) | 2001-10-26 | 2003-05-09 | 롬 앤드 하스 캄파니 | 혼합 금속 산화물 촉매의 처리 |
| TWI225426B (en) * | 2002-05-01 | 2004-12-21 | Rohm & Haas | Supported mixed metal oxide catalyst |
| UA79540C2 (uk) | 2003-01-27 | 2007-06-25 | Бп Кемікалз Лімітед | Каталітична композиція окиснення, її одержання та спосіб селективного окиснення |
| KR100806263B1 (ko) * | 2004-03-29 | 2008-02-22 | 쇼와 덴코 가부시키가이샤 | 산소 함유 화합물 제조용 팔라듐, 텅스텐 및 지르코늄계촉매, 그 촉매의 제조 방법, 및 그 촉매를 사용한 산소함유 화합물의 제조 방법 |
| EP1993727A4 (en) * | 2006-02-07 | 2012-07-04 | Celanese Int Corp | USE OF A CHEMICAL REACTION TO SEPARATE ETHYLENE FROM ETHANE IN ETHANE-BASED PROCESSES FOR THE PRODUCTION OF ACETIC ACID |
| JP5305699B2 (ja) * | 2007-03-19 | 2013-10-02 | 株式会社東芝 | 触媒、触媒の製造方法、膜電極複合体及び燃料電池 |
| MX2009011896A (es) * | 2007-05-04 | 2009-11-12 | Bp Corp North America Inc | Proceso y catalizador para oxidar compuestos aromaticos. |
| WO2008136857A1 (en) * | 2007-05-04 | 2008-11-13 | Bp Corporation North America Inc. | Process for the production of non-aromatic carboxylic acids |
| CN101058072B (zh) * | 2007-05-16 | 2010-06-23 | 天津兴新催化反应技术研究与开发有限责任公司 | Co和h2直接合成乙烯催化剂及其工艺 |
| JP2011522699A (ja) * | 2008-06-10 | 2011-08-04 | エルジー・ケム・リミテッド | 炭化水素の気相接触酸化用触媒、その製造方法、及びこれを利用した炭化水素の気相酸化方法 |
| US20110178332A1 (en) * | 2008-06-10 | 2011-07-21 | Lg Chem, Ltd | Catalyst for gas-phase contact oxidation of hydrocarbon, preparation method thereof and gas-phase oxidation method of hydrocarbon using the same |
| US8105971B2 (en) * | 2009-04-02 | 2012-01-31 | Lummus Technology Inc. | Process for making catalysts useful for the conversion of paraffins to olefins |
| US8105972B2 (en) * | 2009-04-02 | 2012-01-31 | Lummus Technology Inc. | Catalysts for the conversion of paraffins to olefins and use thereof |
| US8921257B2 (en) * | 2011-12-02 | 2014-12-30 | Saudi Basic Industries Corporation | Dual function partial oxidation catalyst for propane to acrylic acid conversion |
| WO2013148006A1 (en) | 2012-03-28 | 2013-10-03 | Rohm And Haas Company | Process for making ethylene and acetic acid |
| US9409156B2 (en) | 2012-10-19 | 2016-08-09 | Instituto Mexicano Del Petroleo | Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process |
| US11883798B2 (en) | 2018-09-17 | 2024-01-30 | Sabic Global Technologies B.V. | Selective oxidation catalyst and a method for oxidizing C2 hydrocarbons in the presence of the selective oxidation catalyst |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1481039A (en) * | 1973-11-26 | 1977-07-27 | Nippon Zeon Co | Process for preparing unsaturated carboxylic acids and catalyst for use therein |
| US3970697A (en) * | 1974-07-01 | 1976-07-20 | National Distillers And Chemical Corporation | Oxidation of ethylene to acetic acid |
| NL7909142A (nl) | 1978-12-26 | 1980-06-30 | Halcon Res & Dev | Katalysator en werkwijze voor de bereiding van methacrylzuur. |
| US4499301A (en) | 1979-04-20 | 1985-02-12 | National Distillers And Chemical Corporation | Process for the preparation of unsaturated aldehydes and carboxylic acids |
| US4298531A (en) | 1979-12-31 | 1981-11-03 | E. I. Du Pont De Nemours And Company | Oxidation of butadiene to furan |
| EP0113156B1 (en) | 1983-01-05 | 1987-03-04 | Mitsubishi Rayon Co., Ltd. | Process for the calcination of phosphorus-molybdenum catalyst |
| US5162578A (en) * | 1987-06-12 | 1992-11-10 | Union Carbide Chemicals & Plastics Technology Corporation | Acetic acid from ethane, ethylene and oxygen |
| EP0608838B1 (en) * | 1993-01-28 | 1997-04-16 | Mitsubishi Chemical Corporation | Method for producing an unsaturated carboxylic acid |
| TW295579B (sh) * | 1993-04-06 | 1997-01-11 | Showa Denko Kk | |
| JP3343982B2 (ja) | 1993-04-06 | 2002-11-11 | 昭和電工株式会社 | 酢酸の製造法 |
| US6043184A (en) * | 1998-01-05 | 2000-03-28 | Sunoco, Inc. (R&M) | Heteropoly acids supported on polyoxometallate salts and their preparation |
| US6060419A (en) * | 1998-01-05 | 2000-05-09 | Sunoco, Inc. (R&M) | Wells-Dawson type heteropolyacids, their preparation and use as oxidation catalysts |
| US6087297A (en) * | 1998-06-29 | 2000-07-11 | Saudi Basic Industries Corporation | Catalysts for gas phase production of acetic acid from ethane, processes of making the same and methods of using same |
-
1996
- 1996-07-31 DE DE19630832A patent/DE19630832A1/de not_active Withdrawn
-
1997
- 1997-07-16 CA CA002261894A patent/CA2261894C/en not_active Expired - Fee Related
- 1997-07-16 RU RU99104401/04A patent/RU2198869C2/ru not_active IP Right Cessation
- 1997-07-16 RS YUP-40/99A patent/RS49592B/sr unknown
- 1997-07-16 JP JP50751398A patent/JP3992112B2/ja not_active Expired - Fee Related
- 1997-07-16 WO PCT/EP1997/003809 patent/WO1998005619A1/de not_active Application Discontinuation
- 1997-07-16 ES ES97937492T patent/ES2167781T3/es not_active Expired - Lifetime
- 1997-07-16 DK DK97937492T patent/DK0915821T3/da active
- 1997-07-16 PL PL33137497A patent/PL188010B1/pl not_active IP Right Cessation
- 1997-07-16 BR BRPI9710906-1A patent/BR9710906B1/pt not_active IP Right Cessation
- 1997-07-16 CZ CZ1999316A patent/CZ294658B6/cs not_active IP Right Cessation
- 1997-07-16 NZ NZ333950A patent/NZ333950A/xx not_active IP Right Cessation
- 1997-07-16 TR TR1999/00162T patent/TR199900162T2/xx unknown
- 1997-07-16 AU AU40105/97A patent/AU716609B2/en not_active Ceased
- 1997-07-16 CN CNB971968837A patent/CN100360493C/zh not_active Expired - Lifetime
- 1997-07-16 DE DE59706053T patent/DE59706053D1/de not_active Expired - Lifetime
- 1997-07-16 KR KR1019997000816A patent/KR100554189B1/ko not_active IP Right Cessation
- 1997-07-16 EP EP97937492A patent/EP0915821B1/de not_active Expired - Lifetime
- 1997-07-16 SI SI9720051A patent/SI9720051A/sl unknown
- 1997-07-16 US US10/006,424 patent/USRE39074E1/en not_active Expired - Lifetime
- 1997-07-16 UA UA99021119A patent/UA55420C2/uk unknown
- 1997-07-16 US US09/230,553 patent/US6194610B1/en not_active Ceased
- 1997-07-16 AT AT97937492T patent/ATE209175T1/de active
- 1997-07-28 ID IDP972613A patent/ID18000A/id unknown
- 1997-07-29 TW TW086110810A patent/TW427971B/zh not_active IP Right Cessation
- 1997-07-29 AR ARP970103425A patent/AR008101A1/es active IP Right Grant
- 1997-07-30 ZA ZA9706793A patent/ZA976793B/xx unknown
- 1997-07-30 MY MYPI97003483A patent/MY120427A/en unknown
-
1999
- 1999-01-26 NO NO19990363A patent/NO323890B1/no not_active IP Right Cessation
- 1999-01-27 BG BG103119A patent/BG103119A/bg unknown
-
2004
- 2004-09-28 AR ARP040103517A patent/AR045953A2/es active IP Right Grant
Also Published As
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