RU2005114479A - Катализатор на основе смешанных оксидов металлов - Google Patents
Катализатор на основе смешанных оксидов металлов Download PDFInfo
- Publication number
- RU2005114479A RU2005114479A RU2005114479/04A RU2005114479A RU2005114479A RU 2005114479 A RU2005114479 A RU 2005114479A RU 2005114479/04 A RU2005114479/04 A RU 2005114479/04A RU 2005114479 A RU2005114479 A RU 2005114479A RU 2005114479 A RU2005114479 A RU 2005114479A
- Authority
- RU
- Russia
- Prior art keywords
- composition according
- sub
- catalyst
- elements
- catalytic composition
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
- B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Claims (11)
1. Каталитическая композиция для окисления этана и/или этилена до уксусной кислоты, которая включает в сочетании с кислородом элементы молибден, ванадий, ниобий и золото в отсутствии палладия в соответствии с эмпирической формулой MoaWbAucVdNbeYf (I), в которой Y обозначает один или несколько элементов, выбранных из группы, включающей Cr, Mn, Та, Ti, В, Al, Ga, In, Pt, Zn, Cd, Bi, Ce, Co, Rh, Ir, Cu, Ag, Fe, Ru, Os, K, Rb, Cs, Mg, Ca, Sr, Ba, Zr, Hf, Ni, P, Pb, Sb, Si, Sn, T1, U, Re, Те и La, a a, b, c, d, e и f обозначают такие грамм-атомные соотношения элементов, при которых 0<а≤1;0≤b<1 и а+b=1; 10-5<c≤0,02; 0,4≤d≤0,865; 0,135≤e≤0,23; и 0,55≤d+e≤1; и 0≤f≤2.
2. Каталитическая композиция по п.1, выбранная из группы, включающей MoaWbAucVdNbeYf; MoaAucVdNbeYf; MoaWbAucVdNbe и MoaAucVdNbe.
3. Каталитическая композиция по п.1 или 2, в которой а>0,01, 0,0001<с≤0,002, 0,425≤d≤0,8, 0,14≤e≤0,20, 0,6≤d+e≤0,95 и f≤0,2.
4. Каталитическая композиция по п.3, в которой 0,0005<с≤0,001, 0,45≤d≤0,7, e≥0,15, d+e≤0,9 и f≤0,02.
5. Каталитическая композиция по п.4, в которой d≥0,5, e≤0,18 и d+e≥0,7.
6. Каталитическая композиция по п.5, в которой d+е≥0,8.
7. Каталитическая композиция по п.1 или 2, в которой а=1.
8. Каталитическая композиция по п.1 или 2, в которой Y имеет значения, выбранные из группы, включающей Sn, Sb, Cu, Pt, Ag, Fe и Re.
9. Каталитическая композиция по п.1, отвечающая формуле, выбранной из группы, включающей: Mo1,00V0,455Nb0,200Au0,0008Oy; Mo1,00V0,547Nb0,163Au0,0009Oy и Mo1,000V0,661Nb0,174Au0,0009Oy, где у обозначает число, которое соответствует валентностям элементов в композиции для кислорода.
10. Способ селективного получения уксусной кислоты из газообразной смеси, содержащей этан и/или этилен, который включает контактирование газообразной смеси с содержащим молекулярный кислород газом при повышенной температуре в присутствии каталитической композиции по одному из предыдущих пунктов.
11. Способ по п.10, в котором катализатор используют в форме псевдоожиженного слоя.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0223681.8 | 2002-10-10 | ||
| GBGB0223681.8A GB0223681D0 (en) | 2002-10-10 | 2002-10-10 | Catalyst and process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2005114479A true RU2005114479A (ru) | 2006-01-20 |
| RU2350385C2 RU2350385C2 (ru) | 2009-03-27 |
Family
ID=9945751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2005114479/04A RU2350385C2 (ru) | 2002-10-10 | 2003-09-23 | Катализатор на основе смешанных оксидов металлов |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US20070185349A1 (ru) |
| EP (1) | EP1549432B1 (ru) |
| JP (1) | JP2006501993A (ru) |
| KR (1) | KR100978775B1 (ru) |
| CN (1) | CN100352543C (ru) |
| AT (1) | ATE521410T1 (ru) |
| AU (1) | AU2003267593A1 (ru) |
| BR (1) | BR0315236B1 (ru) |
| CA (1) | CA2501050C (ru) |
| GB (1) | GB0223681D0 (ru) |
| MY (1) | MY145211A (ru) |
| NO (1) | NO20052174L (ru) |
| RS (1) | RS20050277A (ru) |
| RU (1) | RU2350385C2 (ru) |
| SG (1) | SG157227A1 (ru) |
| TW (1) | TW200408446A (ru) |
| UA (1) | UA79643C2 (ru) |
| WO (1) | WO2004033090A1 (ru) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4922758B2 (ja) * | 2003-08-21 | 2012-04-25 | ビーピー ケミカルズ リミテッド | 触媒組成物およびエタン酸化におけるその使用 |
| RU2462307C1 (ru) * | 2011-05-30 | 2012-09-27 | Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН | Катализатор и способ получения уксусной кислоты или смеси уксусной кислоты и этилацетата |
| DE102011109816B4 (de) * | 2011-08-09 | 2017-04-06 | Clariant Produkte (Deutschland) Gmbh | Katalysatormaterial für die Oxidation von Kohlenwasserstoffen |
| DE102011109774B4 (de) * | 2011-08-09 | 2017-04-20 | Clariant Produkte (Deutschland) Gmbh | Katalysatormaterial für die Oxidation von Kohlenwasserstoffen |
| CA2871853C (en) * | 2012-05-04 | 2021-09-21 | Friso DE ROOIJ | Catalyst for alkane oxidative dehydrogenation and/or alkene oxidation |
| CN104649893B (zh) * | 2013-11-19 | 2016-07-13 | 中国石油天然气股份有限公司 | 一种制备不饱和酸的方法 |
| CN104649894B (zh) * | 2013-11-19 | 2017-06-06 | 中国石油天然气股份有限公司 | 丙烯醛选择性氧化制备丙烯酸的方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9807142D0 (en) * | 1998-04-02 | 1998-06-03 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
| DE19823052A1 (de) * | 1998-05-22 | 1999-11-25 | Consortium Elektrochem Ind | Schalenkatalysator zur Herstellung von Essigsäure durch Gasphasenoxidation von gesättigten und/oder ungesättigten C4-Kohlenwasserstoffen |
| GB9819221D0 (en) * | 1998-09-04 | 1998-10-28 | Bp Chem Int Ltd | Process for the production of acetic acid |
| GB9907704D0 (en) * | 1999-04-01 | 1999-05-26 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
| JP2001033149A (ja) * | 1999-07-19 | 2001-02-09 | Fujitsu General Ltd | 冷蔵庫 |
| DE10024437A1 (de) * | 2000-05-19 | 2001-11-29 | Aventis Res & Tech Gmbh & Co | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
| US6407280B1 (en) * | 2000-09-28 | 2002-06-18 | Rohm And Haas Company | Promoted multi-metal oxide catalyst |
-
2002
- 2002-10-10 GB GBGB0223681.8A patent/GB0223681D0/en not_active Ceased
-
2003
- 2003-09-23 UA UAA200504372A patent/UA79643C2/uk unknown
- 2003-09-23 SG SG200702541-4A patent/SG157227A1/en unknown
- 2003-09-23 RU RU2005114479/04A patent/RU2350385C2/ru not_active IP Right Cessation
- 2003-09-23 US US10/530,715 patent/US20070185349A1/en not_active Abandoned
- 2003-09-23 KR KR1020057005976A patent/KR100978775B1/ko not_active IP Right Cessation
- 2003-09-23 AU AU2003267593A patent/AU2003267593A1/en not_active Abandoned
- 2003-09-23 JP JP2004542603A patent/JP2006501993A/ja not_active Ceased
- 2003-09-23 CA CA2501050A patent/CA2501050C/en not_active Expired - Fee Related
- 2003-09-23 EP EP03748285A patent/EP1549432B1/en not_active Expired - Lifetime
- 2003-09-23 RS YUP-2005/0277A patent/RS20050277A/sr unknown
- 2003-09-23 AT AT03748285T patent/ATE521410T1/de not_active IP Right Cessation
- 2003-09-23 BR BRPI0315236-7A patent/BR0315236B1/pt not_active IP Right Cessation
- 2003-09-23 CN CNB038239736A patent/CN100352543C/zh not_active Expired - Fee Related
- 2003-09-23 WO PCT/GB2003/004060 patent/WO2004033090A1/en active Application Filing
- 2003-09-26 TW TW092126694A patent/TW200408446A/zh unknown
- 2003-10-07 MY MYPI20033826A patent/MY145211A/en unknown
-
2005
- 2005-05-03 NO NO20052174A patent/NO20052174L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CN100352543C (zh) | 2007-12-05 |
| EP1549432B1 (en) | 2011-08-24 |
| MY145211A (en) | 2012-01-13 |
| BR0315236B1 (pt) | 2013-02-05 |
| CN1688389A (zh) | 2005-10-26 |
| AU2003267593A1 (en) | 2004-05-04 |
| CA2501050C (en) | 2011-06-14 |
| BR0315236A (pt) | 2005-08-23 |
| GB0223681D0 (en) | 2002-11-20 |
| CA2501050A1 (en) | 2004-04-22 |
| SG157227A1 (en) | 2009-12-29 |
| WO2004033090A1 (en) | 2004-04-22 |
| ATE521410T1 (de) | 2011-09-15 |
| RU2350385C2 (ru) | 2009-03-27 |
| EP1549432A1 (en) | 2005-07-06 |
| KR20050049527A (ko) | 2005-05-25 |
| US20070185349A1 (en) | 2007-08-09 |
| KR100978775B1 (ko) | 2010-08-30 |
| JP2006501993A (ja) | 2006-01-19 |
| NO20052174L (no) | 2005-05-03 |
| RS20050277A (en) | 2007-06-04 |
| TW200408446A (en) | 2004-06-01 |
| UA79643C2 (en) | 2007-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2000107895A (ru) | Катализатор окисления и способ, осуществляемый с его применением | |
| ID25432A (id) | Katalis oksidasi dan proses yang menggunakan katalis tersebut | |
| ATE234804T1 (de) | Verfahren zur selektiven herstellung von essigsäure durch katalytische oxidation von ethan | |
| YU4099A (sh) | Postupak za selektivnu proizvodnju sirćetne kiseline i za to pogodni katalizatori | |
| UA66848C2 (ru) | Каталитическая композиция для селективного окисления этана и/или этилена до уксусной кислоты (варианты) | |
| MXPA02011419A (es) | Metodo para la produccion selectiva de acido acetico a traves de la oxidacion catalitica de etano y/o etileno. | |
| NO20052174L (no) | Blandet metalloksidkatalysator og fremgangsmate for fremstilling av eddiksyre | |
| RU2002134460A (ru) | Способ селективного получения уксусной кислоты каталитическим окислением этана и/или этилена | |
| RU2004115326A (ru) | Катализатор окисления этана и способ, в котором исрользуют этот катализатор | |
| RU2006100032A (ru) | Композиция катализатора и способ селективного окисления этана и/или этилена до уксусной кислоты |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20150924 |