WO2024004836A1 - 非水電解質二次電池 - Google Patents

非水電解質二次電池 Download PDF

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Publication number
WO2024004836A1
WO2024004836A1 PCT/JP2023/023233 JP2023023233W WO2024004836A1 WO 2024004836 A1 WO2024004836 A1 WO 2024004836A1 JP 2023023233 W JP2023023233 W JP 2023023233W WO 2024004836 A1 WO2024004836 A1 WO 2024004836A1
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Prior art keywords
negative electrode
mixture layer
electrode mixture
active material
electrode active
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PCT/JP2023/023233
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English (en)
French (fr)
Japanese (ja)
Inventor
晶大 加藤木
敬光 田下
幸代 金子
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Panasonic Energy Co Ltd
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Panasonic Energy Co Ltd
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Priority to JP2024530761A priority Critical patent/JPWO2024004836A1/ja
Priority to US18/876,872 priority patent/US20250372620A1/en
Priority to EP23831280.5A priority patent/EP4550442A4/en
Priority to CN202380048034.5A priority patent/CN119318025A/zh
Publication of WO2024004836A1 publication Critical patent/WO2024004836A1/ja
Anticipated expiration legal-status Critical
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the present disclosure relates to a non-aqueous electrolyte secondary battery.
  • Patent Document 1 discloses a technology in which the negative electrode mixture layer has a two-layer structure and the porosity of the negative electrode mixture layer on the positive electrode side is larger than that of the negative electrode mixture layer on the negative electrode current collector side, from the viewpoint of increasing capacity. Disclosed.
  • Patent Document 1 does not consider charge/discharge cycle characteristics, and there is room for improvement.
  • an object of the present disclosure is to provide a non-aqueous electrolyte secondary battery that can suppress deterioration of charge-discharge cycle characteristics.
  • a non-aqueous electrolyte secondary battery that is an embodiment of the present disclosure includes a positive electrode, a negative electrode, and a non-aqueous electrolyte, and the negative electrode includes a negative electrode current collector and a negative electrode formed on a surface of the negative electrode current collector.
  • the negative electrode mixture layer has a first negative electrode mixture layer disposed on the negative electrode current collector, and a second negative electrode mixture layer disposed on the first negative electrode mixture layer.
  • the first negative electrode mixture layer and the second negative electrode mixture layer include negative electrode active materials, and the negative electrode active materials in the first negative electrode mixture layer have two different volume average particle diameters.
  • the ratio (A2/A1) of the volume average particle size (A2) of the negative electrode active material M2 to the volume average particle size (A1) of the negative electrode active material M1 is 0.16. ⁇ 0.5, and the interparticle porosity (S2) of the negative electrode active material in the second negative electrode mixture layer is relative to the interparticle porosity (S1) of the negative electrode active material in the first negative electrode mixture layer.
  • the ratio (S2/S1) is in the range of 3.5 to 5.0.
  • nonaqueous electrolyte secondary battery that is one embodiment of the present disclosure, deterioration in charge/discharge cycle characteristics can be suppressed.
  • FIG. 1 is a cross-sectional view of a non-aqueous electrolyte secondary battery that is an example of an embodiment.
  • FIG. 2 is a cross-sectional view of a negative electrode that is an example of an embodiment.
  • FIG. 2 is a schematic diagram showing a cross section of particles of a negative electrode active material.
  • nonaqueous electrolyte secondary battery of the present disclosure is not limited to the embodiments described below. Further, the drawings referred to in the description of the embodiments are schematically illustrated.
  • FIG. 1 is a cross-sectional view of a nonaqueous electrolyte secondary battery that is an example of an embodiment.
  • the non-aqueous electrolyte secondary battery 10 shown in FIG. It includes arranged insulating plates 18 and 19 and a battery case 15 that accommodates the above-mentioned members.
  • the battery case 15 includes a case body 16 having a cylindrical shape with a bottom and a sealing body 17 that closes an opening of the case body 16.
  • the wound type electrode body 14 other forms of electrode bodies may be applied, such as a laminated type electrode body in which positive electrodes and negative electrodes are alternately laminated with separators interposed therebetween.
  • examples of the battery case 15 include metal exterior cans such as cylindrical, square, coin-shaped, button-shaped, etc., and pouch exterior bodies formed by laminating resin sheets and metal sheets.
  • the case body 16 is, for example, a metal exterior can with a bottomed cylindrical shape.
  • a gasket 28 is provided between the case body 16 and the sealing body 17 to ensure airtightness inside the battery.
  • the case main body 16 has an overhanging portion 22 that supports the sealing body 17 and has, for example, a part of a side surface overhanging inward.
  • the projecting portion 22 is preferably formed in an annular shape along the circumferential direction of the case body 16, and supports the sealing body 17 on its upper surface.
  • the sealing body 17 has a structure in which a filter 23, a lower valve body 24, an insulating member 25, an upper valve body 26, and a cap 27 are stacked in order from the electrode body 14 side.
  • Each member constituting the sealing body 17 has, for example, a disk shape or a ring shape, and each member except the insulating member 25 is electrically connected to each other.
  • the lower valve body 24 and the upper valve body 26 are connected to each other at their central portions, and an insulating member 25 is interposed between their respective peripheral portions.
  • the lower valve body 24 deforms and ruptures so as to push the upper valve body 26 toward the cap 27, and the lower valve body 24 and the upper valve body The current path between bodies 26 is interrupted.
  • the upper valve body 26 breaks and gas is discharged from the opening of the cap 27.
  • the positive electrode lead 20 attached to the positive electrode 11 extends toward the sealing body 17 side through the through hole of the insulating plate 18, and the negative electrode lead 21 attached to the negative electrode 12 is insulated. It passes through the outside of the plate 19 and extends to the bottom side of the case body 16.
  • the positive electrode lead 20 is connected by welding or the like to the lower surface of the filter 23, which is the bottom plate of the sealing body 17, and the cap 27, which is the top plate of the sealing body 17 and electrically connected to the filter 23, serves as a positive terminal.
  • the negative electrode lead 21 is connected to the bottom inner surface of the case body 16 by welding or the like, and the case body 16 serves as a negative electrode terminal.
  • FIG. 2 is a cross-sectional view of a negative electrode that is an example of an embodiment.
  • the negative electrode 12 includes a negative electrode current collector 30 and a negative electrode mixture layer 32 formed on the surface of the negative electrode current collector 30.
  • the negative electrode current collector 30 for example, a foil of a metal such as copper that is stable in the potential range of the negative electrode 12, a film having the metal disposed on the surface layer, or the like is used.
  • the thickness of the negative electrode current collector 30 is, for example, 5 ⁇ m to 30 ⁇ m.
  • the negative electrode mixture layer 32 includes a first negative electrode mixture layer 32a placed on the negative electrode current collector 30, and a second negative electrode mixture layer 32b placed on the first negative electrode mixture layer 32a.
  • the first negative electrode mixture layer 32a and the second negative electrode mixture layer 32b contain a negative electrode active material.
  • the negative electrode active material is not particularly limited as long as it is a material that can absorb and release lithium ions, and examples thereof include graphite such as natural graphite and artificial graphite, carbon materials such as non-graphitizable carbon, Examples include elements that can form an alloy with lithium or compounds containing the elements. Examples of elements capable of forming an alloy with lithium and compounds containing such elements include Si, alloys containing Si, Si oxides represented by SiO x (0.5 ⁇ x ⁇ 1.6), and Li 2y SiO ( Examples include Si-based materials such as Si-containing materials in which Si fine particles are dispersed in a lithium silicate phase represented by 2+y ) (0 ⁇ y ⁇ 2). Other examples include Sn, alloys containing Sn, Sn-based materials such as tin oxide, Ti-based materials such as lithium titanate, and the like.
  • the negative electrode active material included in the first negative electrode mixture layer 32a has two negative electrode active materials M1 and M2 having different volume average particle sizes, and the negative electrode active material M2 has a volume average particle size (A1) of the negative electrode active material M1.
  • the ratio (A2/A1) of the volume average particle diameter (A2) of is in the range of 0.16 to 0.5, preferably in the range of 0.3 to 0.5.
  • the ratio (S2/S1) of the interparticle porosity (S2) of the negative electrode active material in the second negative electrode mixture layer 32b to the interparticle porosity (S1) of the negative electrode active material in the first negative electrode mixture layer 32a is: It ranges from 3.5 to 5.0.
  • A2/A1 is in the range of 0.16 to 0.5, so that the surface area of the first negative electrode mixture layer 32a facing the second negative electrode mixture layer 32b is becomes larger, and the contact area between the second negative electrode mixture layer 32b and the first negative electrode mixture layer 32a increases.
  • the increase in the contact area between the second negative electrode mixture layer 32b and the first negative electrode mixture layer 32a improves the adhesion between the second negative electrode mixture layer 32b and the first negative electrode mixture layer 32a, which in turn improves the charge/discharge cycle characteristics. It is thought that this contributes to suppressing the decline in
  • the volume average particle size of the negative electrode active materials M1 and M2 is measured using a laser diffraction/scattering particle size distribution measuring device (manufactured by Microtrac Bell Co., Ltd., MT3000II).
  • the volume average particle diameter means the median diameter at which the volume integrated value is 50% in the particle diameter distribution measured by the device.
  • the interparticle porosity of the negative electrode active material is a two-dimensional value determined from the ratio of the area of the interparticle voids of the negative electrode active material to the cross-sectional area of the negative electrode mixture layer 32.
  • S2/S1 calculates the interparticle porosity S1 of the negative electrode active material in the first negative electrode mixture layer 32a and the interparticle porosity S2 of the negative electrode active material in the second negative electrode mixture layer 32b using the following procedure. This is what is required.
  • ⁇ Method for measuring interparticle porosity of negative electrode active material Expose the cross section of the negative electrode mixture layer 32.
  • a method for exposing the cross section for example, a method of cutting off a part of the negative electrode 12 and processing it with an ion milling device (for example, IM4000PLUS, manufactured by Hitachi High-Tech Corporation) to expose the cross section of the negative electrode mixture layer 32 can be mentioned.
  • an ion milling device for example, IM4000PLUS, manufactured by Hitachi High-Tech Corporation
  • a backscattered electron image of the cross section of the exposed negative electrode mixture layer 32 is taken for each of the first negative electrode mixture layer 32a and the second negative electrode mixture layer 32b.
  • the magnification when photographing the reflected electron image is, for example, 800 times.
  • FIG. 3 is a schematic diagram showing a particle cross section of the negative electrode active material.
  • the negative electrode active material 40 has, in the particle cross section, closed voids 42 that are not connected from the inside of the particle to the particle surface, and open voids 44 that are connected from the inside of the particle to the particle surface.
  • the closed void 42 in FIG. 3 is defined as the internal void of the negative electrode active material
  • the open void 44 is defined as the external void of the negative electrode active material.
  • Examples of methods for adjusting the interparticle porosity of the negative electrode active material in the first negative electrode mixture layer 32a and the second negative electrode mixture layer 32b include a method of adjusting the packing density of the negative electrode mixture layer 32, and a method of adjusting the packing density of the negative electrode active material. Examples include a method of adjusting internal porosity.
  • ⁇ Method of adjusting the packing density of the negative electrode mixture layer 32 For example, by making the volume average particle size of the negative electrode active material M1 contained in the first negative electrode mixture layer 32a equal to or smaller than the volume average particle size of the negative electrode active material contained in the second negative electrode mixture layer 32b, The packing density of the first negative electrode mixture layer 32a can be made higher than the packing density of the second negative electrode mixture layer 32b. And, thereby, S2/S1 can be increased.
  • the first negative electrode mixture layer 32a Since the negative electrode active material M2 having a smaller volume average particle size than the negative electrode active material M1 is packed into the gap between the negative electrode active materials M1, the packing density of the first negative electrode mixture layer 32a is equal to the packing density of the second negative electrode mixture layer 32b. becomes higher.
  • the volume average particle size of the negative electrode active material M1 is, for example, preferably in the range of 15 ⁇ m to 30 ⁇ m, more preferably in the range of 17 ⁇ m to 25 ⁇ m. Further, the volume average particle size of the negative electrode active material contained in the second negative electrode mixture layer 32b is preferably in the range of 15 ⁇ m to 30 ⁇ m, and more preferably in the range of 17 ⁇ m to 25 ⁇ m, for example.
  • the first negative electrode when rolling the negative electrode mixture layer 32 in manufacturing the negative electrode 12, by making the rolling force of the first negative electrode mixture layer 32a higher than the rolling force of the second negative electrode mixture layer 32b, the first negative electrode
  • the packing density of the mixture layer 32a can be made higher than the packing density of the second negative electrode mixture layer 32b.
  • S2/S1 can also be increased by such a method.
  • the internal porosity of the negative electrode active material contained in the second negative electrode mixture layer 32b is made smaller than that of the negative electrode active material (negative electrode active material M1 and negative electrode active material M2) contained in the first negative electrode mixture layer 32a. do. Thereby, S2/S1 can be increased.
  • the negative electrode active material in the second negative electrode mixture layer 32b is graphite particles in terms of ease of adjusting the internal porosity of the negative electrode active material.
  • the negative electrode active materials M1 and M2 in the first negative electrode mixture layer 32a are preferably graphite particles. It is preferable to control S2/S1 by adjusting the internal porosity of these graphite particles.
  • the negative electrode active materials M1 and M2 in the first negative electrode mixture layer 32a are preferably graphite particles with high internal porosity.
  • the internal porosity of the graphite particles is, for example, preferably 8% to 20%, more preferably 10% to 18%, particularly preferably 12% to 16%.
  • Graphite particles with high internal porosity can be produced, for example, as follows. Coke (precursor), which is the main raw material, is crushed into a predetermined size, aggregated with a binder, and then pressure-formed into a block shape, which is then fired at a temperature of 2,600° C. or higher to graphitize.
  • graphite particles of a desired size that is, negative electrode active materials M1 and M2 having different volume average particle diameters
  • the internal porosity of the graphite particles can be increased (for example, in the range of 8% to 20%).
  • the internal porosity of the graphite particles included in the first negative electrode mixture layer 32a is such that if part of the binder added to the coke (precursor) evaporates during firing, the binder can be used as a volatile component. can. Pitch is exemplified as such a binder.
  • the negative electrode active material contained in the second negative electrode mixture layer 32b preferably contains graphite particles with low internal porosity.
  • the internal porosity of the graphite particles is, for example, preferably 5% or less, more preferably 1% to 5%, particularly preferably 3% to 5%.
  • Graphite particles with low internal porosity can be produced, for example, as follows. Coke (precursor), which is the main raw material, is crushed into a predetermined size, agglomerated with a binder, fired at a temperature of 2,600°C or higher, graphitized, and then sieved to produce the desired material. Obtain graphite particles of size.
  • the internal porosity of the graphite particles can be adjusted by adjusting the particle size of the precursor after pulverization, the particle size of the agglomerated precursor, and the like. For example, by increasing the particle size of the precursor after pulverization or the particle size of the agglomerated precursor, the internal porosity of the graphite particles can be reduced (for example, to 5% or less).
  • the first negative electrode mixture layer 32a may contain graphite particles with a low internal porosity (for example, 5% or less), but it is preferably 20% by mass or less based on the total mass of the negative electrode active material, More preferably, it is 0%.
  • the second negative electrode mixture layer 32b may contain graphite particles with a high internal porosity (for example, 8% to 20%), but the content may be less than 50% by mass based on the total mass of the negative electrode active material. The content is preferably 35% by mass or less, and more preferably 35% by mass or less.
  • the interplanar spacing (d 002 ) of the (002) planes of graphite particles measured by X-ray wide-angle diffraction is, for example, preferably 0.3354 nm or more, more preferably 0.3357 nm or more, and 0.340 nm. It is preferably less than 0.338 nm, more preferably 0.338 nm or less.
  • the crystallite size (Lc(002)) of graphite particles determined by X-ray diffraction is preferably 5 nm or more, more preferably 10 nm or more, and preferably 300 nm or less.
  • the thickness is preferably 200 nm or less, and more preferably 200 nm or less.
  • the negative electrode active material preferably contains a Si-based material, for example, from the viewpoint of increasing the capacity of the battery.
  • the Si-based material contains SiO x (0.5 ⁇ x ⁇ 1.6) in terms of increasing the capacity of the battery, and has a SiO x (0.
  • the ratio of 5 ⁇ x ⁇ 1.6) is preferably 1% by mass to 10% by mass, more preferably 3% by mass to 7% by mass.
  • the negative electrode mixture layer 32 may contain a conductive agent.
  • the conductive agent include carbon materials such as carbon black (CB), acetylene black (AB), Ketjen black, graphite, and carbon nanotubes. These may be used alone or in combination of two or more.
  • the negative electrode mixture layer 32 may further include a binder.
  • binders include fluororesins, polyimide resins, acrylic resins, polyolefin resins, polyacrylonitrile (PAN), styrene-butadiene rubber (SBR), nitrile-butadiene rubber (NBR), and carboxymethyl cellulose (CMC).
  • PAN polyacrylonitrile
  • SBR styrene-butadiene rubber
  • NBR nitrile-butadiene rubber
  • CMC carboxymethyl cellulose
  • PAA polyacrylic acid
  • PAA-Na, PAA-K, etc. and may also be a partially neutralized salt
  • PVA polyvinyl alcohol
  • the thicknesses of the first negative electrode mixture layer 32a and the second negative electrode mixture layer 32b may be the same or different.
  • the ratio of the thickness of the second negative electrode mixture layer 32b to the thickness of the first negative electrode mixture layer 32a is preferably 2:8 to 5:5, more preferably 2:8 to 4:6.
  • the total thickness of the first negative electrode mixture layer and the second negative electrode mixture layer 32b is preferably in the range of 75 ⁇ m to 300 ⁇ m.
  • a method for manufacturing the negative electrode 12 of this embodiment will be described.
  • two negative electrode active materials M1 and M2 having different volume average particle diameters, a binder, and a solvent such as water are mixed to prepare a first negative electrode mixture slurry.
  • a second negative electrode mixture slurry is prepared by mixing a negative electrode active material, a binder, and a solvent such as water.
  • a first negative electrode mixture slurry is applied to both sides of the negative electrode current collector and dried, and then a second negative electrode mixture slurry is applied to both sides of the coating film of the first negative electrode mixture slurry and dried.
  • the negative electrode 12 in which the negative electrode mixture layer 32 is formed on the negative electrode current collector 30 can be manufactured.
  • the first negative electrode mixture slurry was applied and dried, and then the second negative electrode mixture slurry was applied.
  • the second negative electrode mixture slurry was applied and dried.
  • a slurry may also be applied.
  • a second negative electrode mixture slurry may be applied on the first negative electrode mixture layer 32a.
  • the packing density of each can be adjusted more freely. Note that even if the first negative electrode mixture layer 32a and the second negative electrode mixture layer 32b are rolled simultaneously as described above, the interparticle porosity of each negative electrode active material will not be the same. As described above, for example, by adjusting the volume average particle size and internal porosity of the negative electrode active materials used in the first negative electrode mixture layer 32a and the second negative electrode mixture layer 32b, the first negative electrode mixture layer 32a The interparticle porosity (S1, S2) of the negative electrode active material of the second negative electrode mixture layer 32b can be adjusted.
  • the positive electrode 11 is composed of a positive electrode current collector such as a metal foil, and a positive electrode mixture layer formed on the positive electrode current collector.
  • a positive electrode current collector such as a metal foil, and a positive electrode mixture layer formed on the positive electrode current collector.
  • the positive electrode current collector a metal foil such as aluminum that is stable in the positive electrode potential range, a film having the metal disposed on the surface layer, or the like can be used.
  • the positive electrode mixture layer includes, for example, a positive electrode active material, a binder, a conductive agent, and the like.
  • the positive electrode 11 is formed by coating a positive electrode mixture slurry containing a positive electrode active material, a binder, a conductive agent, etc. on a positive electrode current collector, drying it to form a positive electrode mixture layer, and then applying this positive electrode mixture layer. It can be produced by rolling.
  • positive electrode active materials include lithium transition metal oxides containing transition metal elements such as Co, Mn, and Ni.
  • lithium transition metal oxides include Li x CoO 2 , Li x NiO 2 , Li x MnO 2 , Li x Co y Ni 1-y O 2 , Li x Co y M 1-y O z , Li x Ni 1- y M y O z , Li x Mn 2 O 4 , Li x Mn 2-y M y O 4 , LiMPO 4 , Li 2 MPO 4 F (M; Na, Mg, Sc, Y, Mn, Fe, Co, Ni , Cu, Zn, Al, Cr, Pb, Sb, and B, and 0 ⁇ x ⁇ 1.2, 0 ⁇ y ⁇ 0.9, 2.0 ⁇ z ⁇ 2.3).
  • the positive electrode active materials are Li x NiO 2 , Li x Co y Ni 1-y O 2 , Li x Ni 1-y M y O z ( M; at least one of Na, Mg, Sc, Y, Mn, Fe, Co, Ni, Cu, Zn, Al, Cr, Pb, Sb, B, 0 ⁇ x ⁇ 1.2, 0 ⁇ y ⁇ 0 .9, 2.0 ⁇ z ⁇ 2.3) and the like.
  • Examples of the conductive agent include carbon-based particles such as carbon black (CB), acetylene black (AB), Ketjen black, carbon nanotube (CNT), graphene, and graphite. These may be used alone or in combination of two or more.
  • binder examples include fluororesins such as polytetrafluoroethylene (PTFE) and polyvinylidene fluoride (PVdF), polyimide resins, acrylic resins, polyolefin resins, and polyacrylonitrile (PAN). These may be used alone or in combination of two or more.
  • fluororesins such as polytetrafluoroethylene (PTFE) and polyvinylidene fluoride (PVdF)
  • PVdF polyvinylidene fluoride
  • PAN polyacrylonitrile
  • separator 13 for example, a porous sheet having ion permeability and insulation properties is used. Specific examples of porous sheets include microporous thin films, woven fabrics, and nonwoven fabrics. Suitable materials for the separator include olefin resins such as polyethylene and polypropylene, cellulose, and the like.
  • the separator 13 may be a laminate having a cellulose fiber layer and a thermoplastic resin fiber layer such as an olefin resin.
  • a multilayer separator including a polyethylene layer and a polypropylene layer may be used, or a separator 13 whose surface is coated with a material such as aramid resin or ceramic may be used.
  • the non-aqueous electrolyte is a liquid electrolyte (electrolyte solution) containing a non-aqueous solvent and an electrolyte salt dissolved in the non-aqueous solvent.
  • non-aqueous solvents examples include esters, ethers, nitriles such as acetonitrile, amides such as dimethylformamide, and mixed solvents of two or more of these.
  • the non-aqueous solvent may contain a halogen-substituted product in which at least a portion of hydrogen in these solvents is replaced with a halogen atom such as fluorine.
  • esters examples include cyclic carbonate esters such as ethylene carbonate (EC), propylene carbonate (PC), and butylene carbonate, dimethyl carbonate (DMC), ethylmethyl carbonate (EMC), diethyl carbonate (DEC), and methylpropyl carbonate. , chain carbonate esters such as ethylpropyl carbonate and methyl isopropyl carbonate, cyclic carboxylic acid esters such as ⁇ -butyrolactone and ⁇ -valerolactone, methyl acetate, ethyl acetate, propyl acetate, methyl propionate (MP), ethyl propionate, etc. and chain carboxylic acid esters.
  • cyclic carbonate esters such as ethylene carbonate (EC), propylene carbonate (PC), and butylene carbonate, dimethyl carbonate (DMC), ethylmethyl carbonate (EMC), diethyl carbonate (DEC), and methylpropyl carbonate
  • ethers examples include 1,3-dioxolane, 4-methyl-1,3-dioxolane, tetrahydrofuran, 2-methyltetrahydrofuran, propylene oxide, 1,2-butylene oxide, 1,3-dioxane, 1,4 - Cyclic ethers such as dioxane, 1,3,5-trioxane, furan, 2-methylfuran, 1,8-cineole, crown ether, 1,2-dimethoxyethane, diethyl ether, dipropyl ether, diisopropyl ether, dibutyl ether , dihexyl ether, ethyl vinyl ether, butyl vinyl ether, methyl phenyl ether, ethyl phenyl ether, butylphenyl ether, pentylphenyl ether, methoxytoluene, benzyl ethyl ether, diphenyl ether, dibenzyl
  • fluorinated cyclic carbonate esters such as fluoroethylene carbonate (FEC), fluorinated chain carbonate esters, fluorinated chain carboxylic acid esters such as methyl fluoropropionate (FMP), etc. .
  • the electrolyte salt is a lithium salt.
  • lithium salts include LiBF4 , LiClO4 , LiPF6 , LiAsF6 , LiSbF6 , LiAlCl4 , LiSCN, LiCF3SO3 , LiCF3CO2 , Li(P( C2O4 ) F4 ) , LiPF 6-x (C n F 2n+1 ) x (1 ⁇ x ⁇ 6, n is 1 or 2), LiB 10 Cl 10 , LiCl, LiBr, LiI, chloroborane lithium, lower aliphatic carboxylic acid lithium, Li 2 B 4 O 7 , borates such as Li(B(C 2 O 4 )F 2 ), LiN(SO 2 CF 3 ) 2 , LiN(C 1 F 2l+1 SO 2 )(C m F 2m+1 SO 2 ) ⁇ l , m is an integer of 1 or more ⁇ , and the like.
  • the lithium salts may be used alone or in combination
  • a powdered lithium transition metal oxide represented by LiCo 0.979 Zr 0.001 Mg 0.01 Al 0.01 O 2 was used as the positive electrode active material. 95 parts by mass of the above positive electrode active material, 2.5 parts by mass of acetylene black (AB) as a conductive agent, 2.5 parts by mass of polyvinylidene fluoride powder as a binder, and further mixed with N-methyl An appropriate amount of -2-pyrrolidone (NMP) was added to prepare a positive electrode mixture slurry.
  • NMP -2-pyrrolidone
  • This slurry is applied to both sides of a positive electrode current collector made of aluminum foil (thickness 15 ⁇ m) using a doctor blade method, and after the coating film is dried, the coating film is rolled with a rolling roller to coat both sides of the positive electrode current collector. A positive electrode on which a positive electrode mixture layer was formed was produced.
  • Graphite particles A Preparation of graphite particles M1 and M2
  • Coke was pulverized until the average particle size (D50) was 17 ⁇ m, and pitch as a binder was added to the pulverized coke to aggregate the coke. Isotropic pressure was applied to this aggregate to produce a block-shaped molded body having a density of 1.6 g/cm 3 to 1.9 g/cm 3 .
  • the graphitized block-shaped compact is crushed and sieved to produce graphite particles with a volume average particle diameter (D50) of 24 ⁇ m.
  • Graphite particles M1 and 12 ⁇ m graphite particles M2 were obtained.
  • Graphite particles M1 and graphite particles M2 were mixed at a mass ratio of 8:2. This was used as graphite particle A.
  • Graphite particles A and SiO were mixed at a mass ratio of 95:5 to form a first negative electrode active material. 100 parts by mass of the first negative electrode active material, 1 part by mass of sodium salt of carboxymethylcellulose (CMC-Na), and 1 part by mass of styrene-butadiene copolymer rubber (SBR) were mixed, and the mixture was poured into water. A first negative electrode mixture slurry was prepared.
  • CMC-Na carboxymethylcellulose
  • SBR styrene-butadiene copolymer rubber
  • the first negative electrode mixture slurry was applied to both sides of a negative electrode current collector made of copper foil by a doctor blade method and dried to form a first negative electrode mixture layer. Further, the second negative electrode mixture slurry described above was applied onto the first negative electrode mixture layer and dried to form a second negative electrode mixture layer.
  • a negative electrode was produced by rolling the first negative electrode mixture layer and the second negative electrode mixture layer using a rolling roller. The thickness ratio of the second negative electrode mixture layer and the first negative electrode mixture layer of the produced negative electrode was 3.5:6.5.
  • Non-aqueous electrolyte 1.0 parts of LiPF 6 was added to 100 parts by mass of a non-aqueous solvent in which ethylene carbonate (EC), propylene carbonate (PC), and ethyl methyl carbonate (EMC) were mixed in a volume ratio of 10:10:80. It was dissolved at a concentration of 0 mol/L and used as a non-aqueous electrolyte.
  • EC ethylene carbonate
  • PC propylene carbonate
  • EMC ethyl methyl carbonate
  • [Preparation of test cell] Attach an aluminum positive electrode lead to the positive electrode current collector and a nickel negative electrode lead to the negative electrode current collector. After winding the positive and negative electrodes in a spiral shape through a polyolefin separator, they are press-formed in the radial direction. Then, a flat wound electrode body was produced. This electrode body was housed in an exterior body made of an aluminum laminate sheet, and after injecting the above-mentioned non-aqueous electrolyte, the opening of the exterior body was sealed and a test was carried out with a height of 62 mm, a width of 35 mm, and a thickness of 3.6 mm. Got a cell.
  • Example 2 In the production of graphite particles A, a graphite block-shaped compact was crushed and sieved to obtain graphite particles M1 with a volume average particle diameter (D50) of 24 ⁇ m and graphite particles M2 with a volume average particle diameter (D50) of 8 ⁇ m. 2
  • a test cell was prepared in the same manner as in Example 1, except that mixed graphite in which 25 parts by mass of graphite particles A and 75 parts by mass of graphite particles B were mixed was used as the mixed graphite. Created.
  • Example 3 A test cell was prepared in the same manner as in Example 2, except that graphite particles A were not used in preparing the second negative electrode mixture slurry.
  • Example 4 In the production of graphite particles A, the graphite block-shaped compact was crushed and sieved to obtain graphite particles M1 with a volume average particle diameter (D50) of 24 ⁇ m and graphite particles M2 with a volume average particle size (D50) of 8 ⁇ m.
  • a test cell was prepared in the same manner as in Example 1.
  • Example 5 In the production of graphite particles A, the graphite block-shaped compact was crushed and sieved to obtain graphite particles M1 with a volume average particle diameter (D50) of 24 ⁇ m and graphite particles M2 with a volume average particle diameter (D50) of 4 ⁇ m.
  • a test cell was prepared in the same manner as in Example 1.
  • ⁇ Comparative example 1> In preparing the first negative electrode mixture slurry, mixed graphite obtained by mixing graphite particles M1 and graphite particles B with a volume average particle diameter (D50) of 24 ⁇ m at a mass ratio of 50:50 and SiO at a mass ratio of 95:5. In preparing the second negative electrode mixture layer slurry, graphite particles M1 and graphite particles B having a volume average particle diameter (D50) of 24 ⁇ m were used at a mass ratio of 50:50. A test cell was produced in the same manner as in Example 1, except that a second negative electrode active material containing mixed graphite and SiO mixed at a mass ratio of 95:5 was used.
  • a first negative electrode active material in which graphite particles M1 having a volume average particle diameter (D50) of 24 ⁇ m and SiO were mixed at a mass ratio of 95:5 was used;
  • mixed graphite which is a mixture of graphite particles M1 and graphite particles B with a volume average particle diameter (D50) of 24 ⁇ m at a mass ratio of 60:40, and SiO are mixed at a mass ratio of 95:5.
  • a test cell was produced in the same manner as in Example 1, except that the second negative electrode active material was used.
  • a first negative electrode active material in which graphite particles M1 having a volume average particle diameter (D50) of 24 ⁇ m and SiO were mixed at a mass ratio of 95:5 was used;
  • mixed graphite which is a mixture of graphite particles M1 and graphite particles B with a volume average particle diameter (D50) of 24 ⁇ m at a mass ratio of 34:66, and SiO are mixed at a mass ratio of 95:5.
  • a test cell was produced in the same manner as in Example 1, except that the second negative electrode active material was used.
  • a first negative electrode active material in which graphite particles M1 having a volume average particle diameter (D50) of 24 ⁇ m and SiO were mixed at a mass ratio of 95:5 was used;
  • mixed graphite which is a mixture of graphite particles M1 and graphite particles B with a volume average particle diameter (D50) of 24 ⁇ m at a mass ratio of 25:75, and SiO are mixed at a mass ratio of 95:5.
  • a test cell was produced in the same manner as in Example 1, except that the second negative electrode active material was used.
  • ⁇ Comparative example 5> In preparing the first negative electrode mixture slurry, a first negative electrode active material in which graphite particles M1 having a volume average particle diameter (D50) of 24 ⁇ m and SiO were mixed at a mass ratio of 95:5 was used; A test cell was prepared in the same manner as in Example 1, except that in preparing the agent layer slurry, a second negative electrode active material in which graphite particles B and SiO were mixed at a mass ratio of 95:5 was used.
  • D50 volume average particle diameter
  • the calculation of the interparticle porosity of the negative electrode active material in the present disclosure is performed on the negative electrode taken out from the battery before charging and discharging, or on the battery that has been charged and discharged for 1 to 5 cycles (in Examples and Comparative Examples, This test is performed on the negative electrode taken out from a battery that has been charged and discharged for 5 cycles.
  • the negative electrode was taken out from the test cell of each Example and each Comparative Example, and a 90 degree pull test was performed using a Tensilon universal material testing machine (RTG-1225) to determine whether the first negative electrode mixture layer and the second negative electrode were bonded together. The adhesion to the agent layer was measured.
  • Table 1 summarizes the results of the adhesion between the first negative electrode mixture layer and the second negative electrode mixture layer and the capacity retention rate of the test cell in each Example and each Comparative Example. Regarding adhesion, the results of Example 1 were set as 100 (reference value), and the results of other Examples and Comparative Examples were shown as relative values.
  • the ratio (A2/ A1) is in the range of 0.16 to 0.5
  • the interparticle porosity of the negative electrode active material in the second negative electrode mixture layer is relative to the interparticle porosity (S1) of the negative electrode active material in the first negative electrode mixture layer. It can be said that by setting the ratio (S2/S1) of (S2) in the range of 3.5 to 5.0, it is possible to suppress the deterioration of the charge/discharge cycle characteristics. This is considered to be because the permeability of the electrolytic solution into the negative electrode mixture layer was improved by setting A2/A1 and S2/S1 to the above ranges.
  • Comparative Example 7 has higher adhesion than Examples 4 and 5 in which the blending ratio of graphite particles in the negative electrode mixture layer is the same, but A2/A1 is too small and the permeability of the electrolyte is low. It is presumed that the capacity retention rate was lower than that of Examples 4 and 5 because of the poor performance.
  • a nonaqueous electrolyte secondary battery comprising a positive electrode, a negative electrode, and a nonaqueous electrolyte
  • the negative electrode has a negative electrode current collector and a negative electrode mixture layer formed on the surface of the negative electrode current collector,
  • the negative electrode mixture layer has a first negative electrode mixture layer disposed on the negative electrode current collector, and a second negative electrode mixture layer disposed on the first negative electrode mixture layer,
  • the first negative electrode mixture layer and the second negative electrode mixture layer include a negative electrode active material
  • the negative electrode active material in the first negative electrode mixture layer has two negative electrode active materials M1 and M2 having different volume average particle diameters, and the negative electrode active material has a ratio of the negative electrode active material to the volume average particle diameter (A1) of the negative electrode active material M1.
  • the ratio (A2/A1) of the volume average particle diameter (A2) of M2 is in the range of 0.16 to 0.5
  • the ratio (S2/S1) of the interparticle porosity (S2) of the negative electrode active material in the second negative electrode mixture layer to the interparticle porosity (S1) of the negative electrode active material in the first negative electrode mixture layer is:
  • the Si-based material contains SiO x (0.5 ⁇ x ⁇ 1.6), and the SiO x (0.5 ⁇ x ⁇ 1.
  • the non-aqueous electrolyte secondary battery according to (3) above, wherein the ratio of 6) is 1% by mass to 10% by mass.
  • Nonaqueous electrolyte secondary battery (7) The non-aqueous electrolyte according to any one of (1) to (6) above, wherein the total thickness of the first negative electrode mixture layer and the second negative electrode mixture layer is in the range of 75 ⁇ m to 300 ⁇ m. Secondary battery.
  • Nonaqueous electrolyte secondary battery 11 Positive electrode, 12 Negative electrode, 13 Separator, 14 Electrode body, 15 Battery case, 16 Case body, 17 Sealing body, 18, 19 Insulating plate, 20 Positive electrode lead, 21 Negative electrode lead, 22 Overhang part , 23 filter, 24 lower valve body, 25 insulating member, 26 upper valve body, 27 cap, 28 gasket, 30 negative electrode current collector, 32 negative electrode mixture layer, 40 negative electrode active material, 42, 44 void.

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