WO2023050806A1 - Matériau d'électrode positive à base de phosphate ferrique de sodium dopé, son procédé de préparation et son application - Google Patents
Matériau d'électrode positive à base de phosphate ferrique de sodium dopé, son procédé de préparation et son application Download PDFInfo
- Publication number
- WO2023050806A1 WO2023050806A1 PCT/CN2022/090072 CN2022090072W WO2023050806A1 WO 2023050806 A1 WO2023050806 A1 WO 2023050806A1 CN 2022090072 W CN2022090072 W CN 2022090072W WO 2023050806 A1 WO2023050806 A1 WO 2023050806A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sodium
- phosphate
- nickel
- cobalt
- preparation
- Prior art date
Links
- 239000011734 sodium Substances 0.000 title claims abstract description 31
- 229910052708 sodium Inorganic materials 0.000 title claims abstract description 30
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000007774 positive electrode material Substances 0.000 title claims abstract description 18
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 title abstract description 13
- 239000005955 Ferric phosphate Substances 0.000 title abstract description 12
- 229940032958 ferric phosphate Drugs 0.000 title abstract description 12
- 229910000399 iron(III) phosphate Inorganic materials 0.000 title abstract description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 99
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 47
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 claims abstract description 45
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 33
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000010941 cobalt Substances 0.000 claims abstract description 16
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 16
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910001415 sodium ion Inorganic materials 0.000 claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 14
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 9
- 239000010452 phosphate Substances 0.000 claims abstract description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 9
- 229910000152 cobalt phosphate Inorganic materials 0.000 claims abstract description 3
- ZBDSFTZNNQNSQM-UHFFFAOYSA-H cobalt(2+);diphosphate Chemical compound [Co+2].[Co+2].[Co+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZBDSFTZNNQNSQM-UHFFFAOYSA-H 0.000 claims abstract description 3
- 229910000159 nickel phosphate Inorganic materials 0.000 claims abstract description 3
- AWRQDLAZGAQUNZ-UHFFFAOYSA-K sodium;iron(2+);phosphate Chemical compound [Na+].[Fe+2].[O-]P([O-])([O-])=O AWRQDLAZGAQUNZ-UHFFFAOYSA-K 0.000 claims description 45
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000010406 cathode material Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 13
- 238000002386 leaching Methods 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 11
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 10
- 229910052744 lithium Inorganic materials 0.000 claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 8
- 239000001488 sodium phosphate Substances 0.000 claims description 8
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 8
- 235000011008 sodium phosphates Nutrition 0.000 claims description 8
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 8
- 239000002270 dispersing agent Substances 0.000 claims description 7
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 6
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 6
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 6
- 239000001509 sodium citrate Substances 0.000 claims description 6
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- MULYSYXKGICWJF-UHFFFAOYSA-L cobalt(2+);oxalate Chemical compound [Co+2].[O-]C(=O)C([O-])=O MULYSYXKGICWJF-UHFFFAOYSA-L 0.000 claims description 5
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000004254 Ammonium phosphate Substances 0.000 claims description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 3
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 3
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 3
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 3
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000004280 Sodium formate Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 229910021446 cobalt carbonate Inorganic materials 0.000 claims description 2
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 claims description 2
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 claims description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 2
- 235000019800 disodium phosphate Nutrition 0.000 claims description 2
- 229910001386 lithium phosphate Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- JOCJYBPHESYFOK-UHFFFAOYSA-K nickel(3+);phosphate Chemical compound [Ni+3].[O-]P([O-])([O-])=O JOCJYBPHESYFOK-UHFFFAOYSA-K 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 229940005657 pyrophosphoric acid Drugs 0.000 claims description 2
- 239000001632 sodium acetate Substances 0.000 claims description 2
- 235000017281 sodium acetate Nutrition 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 2
- 235000019254 sodium formate Nutrition 0.000 claims description 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- 235000019983 sodium metaphosphate Nutrition 0.000 claims description 2
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 claims description 2
- 229940039790 sodium oxalate Drugs 0.000 claims description 2
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 claims description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical compound [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 claims 1
- 235000011083 sodium citrates Nutrition 0.000 claims 1
- 229940048086 sodium pyrophosphate Drugs 0.000 claims 1
- 150000005846 sugar alcohols Polymers 0.000 claims 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims 1
- 238000009831 deintercalation Methods 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 5
- 239000013078 crystal Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 238000007599 discharging Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 230000001351 cycling effect Effects 0.000 abstract 2
- 229910015818 MPO4 Inorganic materials 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 24
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 20
- 239000000243 solution Substances 0.000 description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 12
- 229910000863 Ferronickel Inorganic materials 0.000 description 11
- 229910000805 Pig iron Inorganic materials 0.000 description 11
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 238000001704 evaporation Methods 0.000 description 8
- 239000002699 waste material Substances 0.000 description 7
- 239000012300 argon atmosphere Substances 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 6
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 6
- 238000005979 thermal decomposition reaction Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 235000002639 sodium chloride Nutrition 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- -1 fluorine Aluminum Chemical compound 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 229940116007 ferrous phosphate Drugs 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910000155 iron(II) phosphate Inorganic materials 0.000 description 3
- SDEKDNPYZOERBP-UHFFFAOYSA-H iron(ii) phosphate Chemical compound [Fe+2].[Fe+2].[Fe+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O SDEKDNPYZOERBP-UHFFFAOYSA-H 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- HIDACJPWCRPEDW-UHFFFAOYSA-K P(=O)([O-])([O-])[O-].[Ni+2].[Co+2] Chemical compound P(=O)([O-])([O-])[O-].[Ni+2].[Co+2] HIDACJPWCRPEDW-UHFFFAOYSA-K 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 1
- 229910016569 AlF 3 Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- OOIOHEBTXPTBBE-UHFFFAOYSA-N [Na].[Fe] Chemical compound [Na].[Fe] OOIOHEBTXPTBBE-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000006182 cathode active material Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- FPNCFEPWJLGURZ-UHFFFAOYSA-L iron(2+);sulfite Chemical compound [Fe+2].[O-]S([O-])=O FPNCFEPWJLGURZ-UHFFFAOYSA-L 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/582—Halogenides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the invention belongs to the technical field of battery materials, and in particular relates to a doped sodium iron phosphate cathode material and a preparation method and application thereof.
- LIBs lithium-ion batteries
- NIBs sodium-ion batteries
- the cathode material is the key to the technology of sodium-ion batteries. It is difficult for the existing cathode active materials to achieve stable deintercalation of sodium ions, which limits the engineering application of sodium-ion batteries.
- the present invention aims to solve at least one of the technical problems in the above-mentioned prior art.
- the present invention provides a doped sodium iron phosphate positive electrode material and its preparation method and application.
- the doped sodium iron phosphate positive electrode material introduces nickel and cobalt to dope sodium iron phosphate.
- the ratio improves the phase transition in the process of sodium ion deintercalation, and plays a role in improving the cycle stability of the sodium iron phosphate crystal structure.
- the present invention adopts the following technical solutions:
- a doped sodium iron phosphate cathode material the chemical formula is xAlF 3 -MPO 4 , M is NaNi a Co b Fe, 0 ⁇ x ⁇ 0.2, 0 ⁇ a ⁇ 1, 0 ⁇ b ⁇ 0.5.
- a preparation method of a doped sodium iron phosphate positive electrode material comprising the following steps:
- the ferrous nickel mixed hydroxide is mixed with phosphate-containing substances, sodium source, cobalt source, dispersant, aluminum fluoride, ball milled, and roasted to obtain a doped sodium iron phosphate positive electrode material.
- the preparation step of the aluminum fluoride is: using ammonium hexafluoroaluminate to decompose by heating.
- ammonium hexafluoroaluminate can be prepared by reacting aluminum chloride and ammonium fluoride in the presence of water.
- ammonium hexafluoroaluminate is prepared from aluminum powder recovered from waste lithium batteries as an aluminum source.
- the preparation process of the ammonium hexafluoroaluminate can specifically be: add hydrochloric acid to the aluminum powder, react to obtain an aluminum chloride solution, add ammonium fluoride to obtain ammonium hexafluoroaluminate, heat and decompose it to obtain fluorine Aluminum.
- the aluminum powder is obtained by crushing and sieving waste lithium batteries.
- the aluminum powder and hydrochloric acid are reacted at a molar ratio of Al to HCl of 10:(30-100).
- the molar ratio of aluminum chloride and ammonium fluoride is 10:(40-150).
- the method further includes evaporating the ammonium hexafluoroaluminate before heating and decomposing, and the evaporation temperature is 90-120°C.
- the thermal decomposition temperature is 200-380°C, and the thermal decomposition time is 0.5h-6h.
- the decomposition reaction formula of ammonium hexafluoroaluminate is: (NH 4 ) 3 AlF 6 ⁇ AlF 3 +3HF+3NH 3 .
- the nickel-containing alloy is ground into powder by adding a grinding aid before acid leaching;
- the grinding aid is one of sodium sulfate, sodium chloride or sodium phosphate.
- the nickel-containing alloy is one of nickel-iron and nickel-containing pig iron.
- the nickel content in ferronickel is ⁇ 15.0%.
- the nickel content in the nickel-containing pig iron is ⁇ 4.0%.
- the acid is at least one of phosphoric acid, sulfuric acid, hydrochloric acid or nitric acid.
- the solid-to-liquid ratio of the nickel-containing alloy to the acid is 1: (3-30) g/ml.
- the H + content in the acid is 2-15 mol/L.
- step (1) further comprising evaporating the leaching solution obtained after acid leaching to remove acid, and the evaporation temperature is 100-400°C.
- adding water for dissolution is also included after the evaporation to obtain a ferronickel salt solution.
- the solid-to-liquid ratio of the nickel-iron salt and water is (1-10): (30-100) kg/L.
- the reducing agent is one of iron powder, iron sulfite and sodium sulfite.
- the alkali is an aqueous solution of alkali metal and alkaline earth metal.
- the alkali metal is one of lithium, sodium and potassium; the alkaline earth metal is one of calcium and magnesium.
- the aqueous solution of alkali metal is sodium hydroxide, and the concentration of sodium hydroxide is 0.1-10 mol/L.
- step (1) the pH is adjusted to 7.0-9.0 to recover ferrous nickel hydroxide.
- the pH is adjusted to 7.5-8.0.
- the phosphate-containing substance is phosphoric acid, pyrophosphoric acid, metaphosphoric acid, sodium phosphate, sodium monohydrogen phosphate, sodium dihydrogen phosphate, iron phosphate, nickel phosphate, lithium phosphate, ammonium phosphate, At least one of ammonium dihydrogen phosphate or ammonium hydrogen phosphate.
- the phosphate-containing substance is at least one of ammonium phosphate, ammonium dihydrogen phosphate or ammonium hydrogen phosphate.
- the sodium source is sodium hydroxide, sodium carbonate, sodium bicarbonate, sodium phosphate, sodium hydrogen phosphate, sodium dihydrogen phosphate, sodium acetate, sodium oxalate, sodium formate, sodium citrate, coke At least one of sodium phosphate or sodium metaphosphate.
- the sodium source is sodium phosphate.
- the cobalt source is at least one of cobalt hydroxide, cobalt oxalate, cobalt phosphate or cobalt carbonate.
- the dispersant is at least one of polyalkylene oxide, phenolic resin, polyvinylpyrrolidone, N-methylpyrrolidone, methanol, ethanol, polyol or polyolamine.
- the general chemical formula of the polyol is C n H 2n+2-x (OH) x (X>2).
- the polyol is polypropylene glycol.
- the polymeric alcohol amine is triethanolamine.
- the dispersant is at least one of polyalkylene oxide, methanol, ethanol or polypropylene glycol.
- step (2) mixture A is obtained after mixing the ferrous nickel mixed hydroxide with phosphate-containing substances, sodium source, and cobalt source, and in the mixture A, sodium, ferrous, nickel, cobalt
- the molar ratio is (0.01 ⁇ 150):(0.01 ⁇ 150):(0 ⁇ 100):(0 ⁇ 50).
- the mass ratio of the mixture A, dispersant, and aluminum fluoride is 100:(10-200):(0-20).
- the particle size of the ball mill output is ⁇ 20 ⁇ m, and the ball mill is performed at 100-1200 r/min for 1-12 hours.
- the firing atmosphere is one of nitrogen atmosphere, neon atmosphere, argon atmosphere, and helium atmosphere.
- the temperature of the calcination is 500-1000° C., and the calcination time is 1-24 hours.
- the present invention also provides a sodium ion battery, comprising the doped sodium iron phosphate cathode material.
- the doped sodium iron phosphate positive electrode material prepared by the present invention introduces nickel and cobalt to dope sodium iron phosphate, which can improve the phase transition in the process of sodium ion deintercalation by increasing the ratio of nickel and cobalt, and improve the crystallinity of sodium iron phosphate.
- the role of structural cycle stability by coating aluminum fluoride on the surface of doped sodium iron phosphate, it can reduce the surface loss of sodium ion deintercalation during charge and discharge, inhibit the growth of Na dendrites, improve the cycle stability of the surface of sodium iron phosphate, and improve the performance of sodium iron phosphate.
- the electrical conductivity of the surface enhances the electrochemical performance of sodium iron phosphate.
- the present invention utilizes nickel-containing alloys, solves the problem of selecting iron and doping metals in sodium iron phosphate, and achieves the purpose of synthesizing nickel-cobalt-doped sodium iron phosphate.
- nickel-containing alloys iron accounts for the largest proportion, followed by nickel. Therefore, iron is separated to synthesize ferrous phosphate, nickel and cobalt are separated to synthesize nickel-cobalt phosphate, and nickel-cobalt is introduced for doping.
- the present invention can be improved by adjusting the ratio of nickel-cobalt phosphate
- the phase transition during the deintercalation of sodium ions plays a role in improving the cycle stability of the sodium iron phosphate crystal structure.
- aluminum recovered from waste lithium batteries is used for secondary utilization to prepare aluminum fluoride, and aluminum fluoride enhances the electrical properties of sodium iron phosphate.
- the by-product aluminum recovered from waste lithium batteries is prepared as aluminum powder, and the aluminum powder is dissolved in acid and ammonium fluoride is added to prepare ammonium hexafluoroaluminate.
- the aluminum fluoride obtained by thermal decomposition of ammonium hexafluoroaluminate has high stability and Good conductivity, coating aluminum fluoride on the surface of sodium iron phosphate can reduce the surface loss of sodium ion deintercalation during charge and discharge, improve the cycle stability of the surface of sodium iron phosphate, and lead to the reduction of iron-based phosphate on the surface The resistance is improved and the electrochemical performance of sodium iron phosphate is enhanced.
- Fig. 1 is the SEM figure of the doped type sodium iron phosphate cathode material prepared in embodiment 1;
- the doped sodium iron phosphate cathode material in this embodiment has a chemical formula of 0.015AlF 3 -NaNi 0.089 Co 0.064 FePO 4 .
- Nickel-containing pig iron (Ni content 11.7%, iron content 82.6%) dissolution: crush 0.382kg of nickel-containing pig iron, add 7.2g of sodium sulfate to grind into nickel-containing pig iron powder, and send the nickel-containing pig iron powder to the airtight
- Fig. 1 is the SEM figure of the nickel-cobalt-doped type sodium iron phosphate coated with positive electrode material aluminum fluoride prepared in Example 1
- Fig. 2 is the SEM figure of the nickel-cobalt-doped type sodium iron phosphate prepared in Comparative Example 1
- the nickel-cobalt-doped type in Example 1 is basically covered by aluminum fluoride, and there is a coating layer>10nm on the outside, so the overall is relatively blurred, while the nickel-cobalt-doped sodium iron phosphate prepared in Comparative Example 1
- the exterior is clear with no cladding visible.
- the doped sodium iron phosphate cathode material in this example has a chemical formula of 0.011AlF 3 -NaNi 0.087 Co 0.066 FePO 4 .
- the doped sodium iron phosphate cathode material in this example has a chemical formula of 0.043AlF 3 -NaNi 0.38 Co 0.087 FePO 4 .
- the preparation method of the sodium iron phosphate cathode material of this comparative example comprises the following concrete steps:
- Sodium citrate and ferrous phosphate are mixed at a molar ratio of 1:1, then mixed with 320mL of ethanol by ultrasound, ball milled for 7h14min, then roasted in an argon atmosphere and a tube furnace at 730°C for 8h7min, and the temperature is lowered to obtain ferric phosphate Sodium NaFePO 4 cathode material.
- the preparation method of the sodium iron phosphate cathode material of this comparative example comprises the following specific steps:
- Sodium citrate and ferrous phosphate were mixed at a molar ratio of 1:1, and then mixed with 320mL of ethanol by ultrasound, ball milled for 6h49min, then roasted in an argon atmosphere and a tube furnace at 780°C for 8h7min, and cooled to obtain NaFePO 4 Cathode material.
- Embodiment 1-3 and comparative example 1-2 analyze:
- Doped sodium iron phosphate, conductive agent, and polytetrafluoroethylene were formulated into a slurry at a mass ratio of 85:10:5, and then coated on copper foil, and the pole pieces were dried in a drying oven at 80°C for 6 hours.
- the die is stamped into a disc. Cut the sodium sheet into an electrode pole piece with a diameter of about 6mm, add 1.5mol/L sodium hexafluorophosphate to propylene carbonate to prepare the electrolyte, use Celgard2400 as the separator, and assemble the battery in a vacuum glove box under an argon atmosphere.
- the cycle performance is tested with an electrochemical workstation, the charge and discharge range is 1.5-3.0V, and the test is performed at a rate of 2C.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2310302.1A GB2618695A (en) | 2021-09-30 | 2022-04-28 | Doped sodium ferric phosphate positive electrode material, preparation method therefor and application thereof |
DE112022003502.1T DE112022003502T5 (de) | 2021-09-30 | 2022-04-28 | Dotiertes natriumeisen(iii)phosphatmaterial für die positive elektrode, verfahren zu dessen herstellung und dessen verwendung |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111161800.8 | 2021-09-30 | ||
CN202111161800.8A CN113948697B (zh) | 2021-09-30 | 2021-09-30 | 掺杂型磷酸铁钠正极材料及其制备方法和应用 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2023050806A1 true WO2023050806A1 (fr) | 2023-04-06 |
Family
ID=79329002
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2022/090072 WO2023050806A1 (fr) | 2021-09-30 | 2022-04-28 | Matériau d'électrode positive à base de phosphate ferrique de sodium dopé, son procédé de préparation et son application |
Country Status (4)
Country | Link |
---|---|
CN (1) | CN113948697B (fr) |
DE (1) | DE112022003502T5 (fr) |
GB (1) | GB2618695A (fr) |
WO (1) | WO2023050806A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113948697B (zh) * | 2021-09-30 | 2023-07-07 | 广东邦普循环科技有限公司 | 掺杂型磷酸铁钠正极材料及其制备方法和应用 |
CN114695862A (zh) * | 2022-03-25 | 2022-07-01 | 广东邦普循环科技有限公司 | 一种氟铝共掺杂的钴酸锂正极材料及其制备方法 |
CN114824205B (zh) * | 2022-04-15 | 2022-11-29 | 宁波市稻禾科技有限公司 | 一种钛基快离子导体改性磷酸铁钠正极材料及其制备方法和正极材料制备的电池 |
CN115064678A (zh) * | 2022-06-28 | 2022-09-16 | 天津巴莫科技有限责任公司 | 一种高镍低钴正极材料、其制备方法及应用 |
CN115849335A (zh) * | 2022-11-30 | 2023-03-28 | 浙江新安化工集团股份有限公司 | 一种金属掺杂磷酸铁钠及制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20150125749A1 (en) * | 2012-01-20 | 2015-05-07 | Ningbo Institute of Materials & Engineering, Chinese Academy of Sciences | Novel Phosphate Based Composite Anode Material, Preparation Method and Use Thereof |
US20160013478A1 (en) * | 2013-02-28 | 2016-01-14 | Sanyo Electric Co., Ltd. | Positive electrode for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery that uses the positive electrode |
JP2016184568A (ja) * | 2015-03-26 | 2016-10-20 | 太平洋セメント株式会社 | 二次電池用正極活物質及びその製造方法 |
JP2016186932A (ja) * | 2015-03-27 | 2016-10-27 | 太平洋セメント株式会社 | 二次電池用正極活物質及びその製造方法 |
WO2018117771A1 (fr) * | 2016-12-23 | 2018-06-28 | 주식회사 포스코 | Procédé de récupération de nickel et de cobalt à partir de matière première contenant du nickel, du fer et du cobalt |
US20180316044A1 (en) * | 2015-10-21 | 2018-11-01 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Method for producing a sodium-ion battery |
CN113948697A (zh) * | 2021-09-30 | 2022-01-18 | 广东邦普循环科技有限公司 | 掺杂型磷酸铁钠正极材料及其制备方法和应用 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109755565A (zh) * | 2017-11-08 | 2019-05-14 | 中国科学院大连化学物理研究所 | 过渡金属掺杂的钠离子电池用正极材料及其制备和应用 |
CN110611080B (zh) * | 2018-06-15 | 2021-03-12 | 中南大学 | 一种过渡金属掺杂的磷酸钛锰钠/碳复合正极材料及其制备和在钠离子电池中的应用 |
CN108832112B (zh) * | 2018-06-26 | 2020-07-03 | 东北大学秦皇岛分校 | 一种钴掺杂氟磷酸亚铁钠正极材料的制备方法 |
CN108899538A (zh) * | 2018-07-19 | 2018-11-27 | 东北大学秦皇岛分校 | 一种三元钠离子电池正极材料、其制备方法以及钠离子电池 |
CN111525130A (zh) * | 2020-05-11 | 2020-08-11 | 金国辉 | 一种改性Na3V2(PO4)2F3的钠离子电池正极材料及其制法 |
CN111933899B (zh) * | 2020-06-22 | 2021-11-26 | 武汉大学 | 一种复合氧化物电极材料及其制备方法 |
-
2021
- 2021-09-30 CN CN202111161800.8A patent/CN113948697B/zh active Active
-
2022
- 2022-04-28 DE DE112022003502.1T patent/DE112022003502T5/de active Pending
- 2022-04-28 GB GB2310302.1A patent/GB2618695A/en active Pending
- 2022-04-28 WO PCT/CN2022/090072 patent/WO2023050806A1/fr active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20150125749A1 (en) * | 2012-01-20 | 2015-05-07 | Ningbo Institute of Materials & Engineering, Chinese Academy of Sciences | Novel Phosphate Based Composite Anode Material, Preparation Method and Use Thereof |
US20160013478A1 (en) * | 2013-02-28 | 2016-01-14 | Sanyo Electric Co., Ltd. | Positive electrode for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery that uses the positive electrode |
JP2016184568A (ja) * | 2015-03-26 | 2016-10-20 | 太平洋セメント株式会社 | 二次電池用正極活物質及びその製造方法 |
JP2016186932A (ja) * | 2015-03-27 | 2016-10-27 | 太平洋セメント株式会社 | 二次電池用正極活物質及びその製造方法 |
US20180316044A1 (en) * | 2015-10-21 | 2018-11-01 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Method for producing a sodium-ion battery |
WO2018117771A1 (fr) * | 2016-12-23 | 2018-06-28 | 주식회사 포스코 | Procédé de récupération de nickel et de cobalt à partir de matière première contenant du nickel, du fer et du cobalt |
CN113948697A (zh) * | 2021-09-30 | 2022-01-18 | 广东邦普循环科技有限公司 | 掺杂型磷酸铁钠正极材料及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
DE112022003502T5 (de) | 2024-05-02 |
GB202310302D0 (en) | 2023-08-16 |
CN113948697A (zh) | 2022-01-18 |
CN113948697B (zh) | 2023-07-07 |
GB2618695A (en) | 2023-11-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2023050806A1 (fr) | Matériau d'électrode positive à base de phosphate ferrique de sodium dopé, son procédé de préparation et son application | |
CN101081696B (zh) | 锂离子动力电池用磷酸铁锂材料及其制备方法 | |
CN101941685B (zh) | 一种球形磷酸铁锂材料制备和采用该材料的锂离子电池 | |
WO2018120147A1 (fr) | Procédé de préparation d'un composite graphène/matériau ternaire destiné à être utilisé dans des batteries au lithium-ion et son produit | |
CN102208641A (zh) | 一步法合成空心球结构Fe3O4/C锂离子电池负极材料 | |
CN104993121A (zh) | 一种镍锰掺混锂离子电池正极材料及其制备方法 | |
CN112186145A (zh) | 一种镁还原碳包覆氧化亚硅材料及其制备方法、应用 | |
CN104218235A (zh) | 一种双掺杂富锂固溶体正极复合材料及其制备方法、锂离子电池正极片和锂离子电池 | |
WO2022002057A1 (fr) | Matériau d'électrode négative composite silicium-oxygène, batterie ion-lithium, et leurs procédés de préparation | |
WO2023071396A1 (fr) | Matériau d'électrode positive pour batterie sodium-ion, son procédé de préparation et son application | |
WO2023226554A1 (fr) | Matériau d'électrode positive d'oxyde de lithium-nickel-cobalt-manganèse à haute tension, sa méthode de préparation et son utilisation | |
CN115385380B (zh) | 钠离子电池正极材料的制备方法 | |
CN110504447A (zh) | 一种氟掺杂的镍钴锰前驱体及其制备方法与应用 | |
CN109802127B (zh) | 一种银掺杂四氧化三铁纳米复合材料的制备方法 | |
CN110085854B (zh) | 一种磷酸钒锂正极材料及其制备方法 | |
CN108630922B (zh) | 一种磷酸锰锂/碳复合正极材料、其制备方法和锂离子电池 | |
CN112331852B (zh) | 一种氮自掺杂碳包覆氧化亚硅负极材料及其制备方法和应用 | |
CN110660975A (zh) | 一种锇掺杂的LiAlSiO4包覆镍钴锰酸锂正极材料及其制备方法和应用 | |
Zhang et al. | Cation doping method for the restoration of spent LiNi1/3Co1/3Mn1/3O2 cathode material properties | |
CN115744857B (zh) | 废旧磷酸铁锂电池定向循环制取磷酸铁锂正极材料的方法 | |
CN111747449A (zh) | 片状碳基质内部均匀桥接超细MoO2纳米颗粒的电极材料及其制备方法和应用 | |
TWI392134B (zh) | Nickel - cobalt - manganese multicomponent lithium - ion battery cathode material and its preparation method | |
WO2023060992A1 (fr) | Procédé de synthèse d'un matériau d'électrode positive de haute sécurité par recyclage de matériaux d'électrode positive à électrode positive, et application | |
CN111485278A (zh) | 一种电极活性材料单晶的固相反应合成方法 | |
JP2009242121A (ja) | リチウムマンガン酸化物粉体粒子及びその製造方法、並びにそれを正極活物質として用いたリチウム二次電池 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 22874204 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 202310302 Country of ref document: GB Kind code of ref document: A Free format text: PCT FILING DATE = 20220428 |
|
WWE | Wipo information: entry into national phase |
Ref document number: P202390248 Country of ref document: ES |
|
WWE | Wipo information: entry into national phase |
Ref document number: 112022003502 Country of ref document: DE |