WO2022215614A1 - Mélange maître de nanocellulose et son procédé de production - Google Patents

Mélange maître de nanocellulose et son procédé de production Download PDF

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WO2022215614A1
WO2022215614A1 PCT/JP2022/015808 JP2022015808W WO2022215614A1 WO 2022215614 A1 WO2022215614 A1 WO 2022215614A1 JP 2022015808 W JP2022015808 W JP 2022015808W WO 2022215614 A1 WO2022215614 A1 WO 2022215614A1
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nanocellulose
rubber
mass
styrene
latex
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PCT/JP2022/015808
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English (en)
Japanese (ja)
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真幸 川添
臣将 北村
智行 酒井
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横浜ゴム株式会社
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Priority to CN202280023234.0A priority Critical patent/CN117083333A/zh
Publication of WO2022215614A1 publication Critical patent/WO2022215614A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
    • Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction 

Definitions

  • the present invention relates to a nanocellulose masterbatch, a method for producing the same, and a rubber composition using the nanocellulose masterbatch.
  • Rubber compositions that make up tires and the like are required to have excellent properties such as elastic modulus (elongation) and hardness (hardness).
  • a technique is known in which a filler such as carbon black or silica is blended into the rubber composition.
  • nanocellulose has the property of being easily aggregated and bundled in the process of removing moisture such as coagulation and drying. In some cases, it is difficult to maintain the state of dispersing to the nano level and defibrating to the nano level. In addition, the viscosity of the resulting nanocellulose masterbatch may increase, making it difficult to mix with other materials (particularly other rubber components). Therefore, it is useful to obtain a nanocellulose masterbatch in which nanocellulose is uniformly dispersed and fibrillated to the nano level so that a rubber composition excellent in both tensile stress and elongation can be obtained.
  • the object of the present invention is to provide a nanocellulose masterbatch capable of obtaining a rubber composition in which nanocellulose is homogeneously dispersed, viscosity increase is suppressed, and both tensile stress and elongation are excellent.
  • the rubber component contains natural rubber or styrene-butadiene copolymer rubber as a main component, and 0.3 to 60 parts by mass of nanocellulose and 0.5 to 35 parts by mass of a dispersant per 100 parts by mass of the rubber component.
  • nanocellulose masterbatch enables a rubber composition in which nanocellulose is uniformly dispersed, viscosity increase is suppressed, and both tensile stress and elongation are excellent, and the present invention has been completed.
  • the present invention is the following ⁇ 1> to ⁇ 13>.
  • ⁇ 1> A nanocellulose masterbatch containing a rubber component, a resol-type and/or novolak-type resorcin-formaldehyde initial condensate, nanocellulose surface-treated with formaldehyde, and a dispersant, wherein the rubber component is , Natural rubber or styrene-butadiene copolymer rubber as a main component, and 0.3 to 60 parts by mass of the nanocellulose and 0.5 to 35 parts by mass of the dispersant per 100 parts by mass of the rubber component.
  • nanocellulose Nanocellulose masterbatch containing Contains 0.03 to 1.2 parts by weight of the resol-type and/or novolac-type resorcin-formaldehyde initial condensate and 0.02 to 0.8 parts by weight of the formaldehyde with respect to 1 part by weight of the nanocellulose Nanocellulose masterbatch containing.
  • the dispersant is a fatty acid derivative mixture and contains 0.5 to 10 parts by mass of the dispersant with respect to 100 parts by mass of the rubber component.
  • the dispersant is a low molecular weight diene-based liquid polymer having a weight average molecular weight of 2000 or more and 60000 or less, and contains 1 to 35 parts by mass of the dispersant per 100 parts by mass of the rubber component.
  • Nanocellulose masterbatch according to. ⁇ 4> The dispersant is one or more selected from the group consisting of oil, alkylphenol-based resin, petroleum resin, rosin, rosin-modified resin, coumarone-indene resin, terpene-based resin, and lignin, and 100 mass of the rubber component.
  • the nanocellulose masterbatch according to ⁇ 1> which contains 1 to 30 parts by mass of the dispersant per part.
  • ⁇ 5> The method for producing a nanocellulose masterbatch according to any one of ⁇ 1> to ⁇ 4>, comprising rubber latex of natural rubber or styrene-butadiene copolymer rubber, and styrene-butadiene copolymer RF latex consisting of rubber and/or styrene-butadiene-vinylpyridine terpolymer latex, resol-type and/or novolac-type resorcinol-formaldehyde precondensate, and formaldehyde, nanocellulose, and dispersing agent are mixed.
  • ⁇ 6> The method for producing a nanocellulose masterbatch according to any one of ⁇ 1> to ⁇ 4>, comprising rubber latex of natural rubber or styrene-butadiene copolymer rubber, and styrene-butadiene copolymer RF latex composed of rubber and/or styrene-butadiene-vinylpyridine terpolymer latex, resole-type and/or novolac-type resorcin-formaldehyde precondensate, and formaldehyde, and nanocellulose are mixed to disperse raw materials.
  • a step of obtaining a liquid a step of coagulating the raw material dispersion to obtain a coagulate and then mixing a dispersant, and drying the coagulate mixed with the dispersant to obtain a dried product.
  • a method for producing a nanocellulose masterbatch A method for producing a nanocellulose masterbatch.
  • ⁇ 7> The method for producing a nanocellulose masterbatch according to any one of ⁇ 1> to ⁇ 4>, comprising rubber latex of natural rubber or styrene-butadiene copolymer rubber, and styrene-butadiene copolymer RF latex composed of rubber and/or styrene-butadiene-vinylpyridine terpolymer latex, resole-type and/or novolac-type resorcin-formaldehyde precondensate, and formaldehyde, and nanocellulose are mixed to disperse raw materials.
  • a method for producing a nanocellulose masterbatch comprising a step of obtaining a liquid, a step of coagulating the raw material dispersion to obtain a coagulate, and a step of drying the coagulate to obtain a dried product and then mixing a dispersant.
  • ⁇ 8> The method for producing a nanocellulose masterbatch according to any one of ⁇ 1> to ⁇ 4>, comprising a styrene-butadiene copolymer rubber and/or a styrene-butadiene-vinylpyridine terpolymer latex, a resol type and/or novolak type resorcin-formaldehyde initial condensate, and an RF latex composed of formaldehyde, nanocellulose, and a dispersant to obtain a mixed liquid, adding natural rubber or A nanocellulose masterbatch, comprising a step of coagulating a raw material dispersion obtained by mixing a rubber latex of a styrene-butadiene copolymer rubber to obtain a coagulate, and a step of drying the coagulate to obtain a dried product.
  • ⁇ 9> The method for producing a nanocellulose masterbatch according to any one of ⁇ 1> to ⁇ 4>, comprising a styrene-butadiene copolymer rubber and/or a styrene-butadiene-vinylpyridine terpolymer latex, resol type and/or novolak type resorcin-formaldehyde initial condensate, RF latex composed of formaldehyde, and nanocellulose to obtain a mixed solution, adding natural rubber or styrene-butadiene to the mixed solution.
  • a nanocellulose masterbatch comprising a step of coagulating a raw material dispersion obtained by mixing a rubber latex of a polymer rubber and a dispersant to obtain a coagulate, and a step of drying the coagulate to obtain a dried product. Production method.
  • ⁇ 10> The method for producing a nanocellulose masterbatch according to any one of ⁇ 1> to ⁇ 4>, comprising a styrene-butadiene copolymer rubber and/or a styrene-butadiene-vinylpyridine terpolymer latex, resol type and/or novolak type resorcin-formaldehyde initial condensate, RF latex composed of formaldehyde, and nanocellulose to obtain a mixed solution, adding natural rubber or styrene-butadiene to the mixed solution.
  • a method for producing a nanocellulose masterbatch comprising the step of obtaining ⁇ 11>
  • a method for producing a cellulose masterbatch A rubber composition obtained by using the nanocellulose masterbatch according to any one of ⁇ 1> to ⁇ 4> and a rubber component, wherein out of 100 parts by mass of the total rubber component, 25 parts by mass or more of natural rubber and/or isoprene rubber, and further, 0.3 to 60 parts by weight of nanocellulose and 30 to 200 parts by mass of carbon black and/or silica with respect to 100 parts by mass of the total rubber component
  • a rubber composition comprising: ⁇ 13> A rubber composition obtained by using the nanocellulose masterbatch according to any one of ⁇ 1> to ⁇ 4> and a rubber component, wherein out of 100 parts by mass of the total rubber component, 35 parts by mass or more of a styrene-butadiene copolymer rubber and/or a styrene-butadiene
  • nanocellulose masterbatch in which nanocellulose is homogeneously dispersed, viscosity increase is suppressed, and a rubber composition excellent in both tensile stress and elongation is obtained.
  • FIG. 2 is a schematic diagram schematically showing the state of a rubber component (large round shape) and nanocellulose (linear shape) in a nanocellulose masterbatch produced in an example.
  • (a) is a schematic diagram of C1-6
  • (b) is a schematic diagram of E1-1.
  • the present invention contains a rubber component, a resol-type and/or novolac-type resorcin-formaldehyde initial condensate and nanocellulose surface-treated with formaldehyde, and a dispersant, wherein the rubber component is natural rubber or styrene-butadiene.
  • Copolymer rubber as a main component, 0.3 to 60 parts by mass of nanocellulose and 0.5 to 35 parts by mass of a dispersant per 100 parts by mass of the rubber component, and 1 part by mass of nanocellulose
  • the nanocellulose masterbatch of the present invention the method for producing the nanocellulose masterbatch of the present invention
  • the rubber composition of the present invention the rubber composition of the present invention.
  • the numerical range represented by using “ ⁇ ” is the lower limit of the numerical value described before “ ⁇ ”, and the numerical value described after “ ⁇ ”, unless otherwise specified. Denotes a numerical range that is the upper limit.
  • Nanocellulose masterbatch of the present invention First, the raw materials, component composition, etc. of the nanocellulose masterbatch of the present invention will be described.
  • the nanocellulose masterbatch of the present invention is produced using at least predetermined rubber latex, RF latex, nanocellulose, and dispersant as raw materials. Each will be described in detail below.
  • the nanocellulose masterbatch of the present invention uses rubber latex of natural rubber (NR) or styrene-butadiene copolymer rubber (SBR) as a raw material.
  • latex is an aqueous dispersion in which a rubber component is dispersed in water in a colloidal form.
  • the rubber component of the rubber latex is the rubber component to be blended in the rubber composition of the present invention. They are preferably the same.
  • the nanocellulose masterbatch of the present invention uses natural rubber latex as the rubber latex.
  • the nanocellulose masterbatch of the present invention is a styrene-butadiene copolymer rubber as a rubber latex. of latex.
  • the weight average molecular weight of the above natural rubber or styrene-butadiene copolymer rubber is preferably 50,000 to 3,000,000, more preferably 100,000 to 2,000,000.
  • the "weight average molecular weight" in the present invention means that measured by gel permeation chromatography (GPC) using tetrahydrofuran as a solvent in terms of standard polystyrene. This GPC measurement is carried out at 40° C. using a column (MIXED-B manufactured by Polymer Laboratories) as a measuring instrument. The same applies to the following.
  • the nanocellulose masterbatch of the present invention is produced using this rubber latex as a main raw material (a raw material that accounts for 60% by mass or more of the solid content of all raw materials), it is included in the nanocellulose masterbatch of the present invention.
  • the rubber component to be used contains natural rubber or styrene-butadiene copolymer rubber as a main component. That is, in the nanocellulose masterbatch of the present invention, when natural rubber latex is used as the rubber latex, the rubber component contained contains natural rubber as the main component, and the rubber latex is styrene-butadiene copolymer rubber. When the latex of is used, the included rubber component contains styrene-butadiene copolymer rubber as the main component.
  • the term "contained as a main component” means that the rubber component is contained in an amount of 60% by mass or more of the rubber components contained in the nanocellulose masterbatch of the present invention, and the ratio is 70% by mass or more. is preferably 80% by mass or more, more preferably 90% by mass or more, still more preferably 95% by mass or more, and even more preferably 98% by mass or more.
  • the nanocellulose masterbatch of the present invention further uses RF latex as a raw material.
  • the RF latex is made from a styrene-butadiene copolymer rubber and/or a styrene-butadiene-vinylpyridine terpolymer latex, a resol-type and/or novolac-type resorcin-formaldehyde precondensate (RF resin), and formaldehyde.
  • This "resorcin/formaldehyde initial condensate” is a condensate (oligomer) obtained by condensation reaction of resorcin, which is a phenolic resin, and formaldehyde in the presence of a catalyst, and its degree of polymerization is about 5 to 15. is preferred.
  • This resorcin/formaldehyde initial condensate may contain unreacted resorcin and/or formaldehyde.
  • a condensate having a methylol group is a resol-type resorcin-formaldehyde initial condensate obtained by condensation reaction at a molar ratio of resorcin/formaldehyde of 1/1 to 3 in the presence of an alkali catalyst such as sodium hydroxide or sodium carbonate.
  • an alkali catalyst such as sodium hydroxide or sodium carbonate.
  • the condensate having no methylol group obtained by the condensation reaction of 9 is a novolac-type resorcin-formaldehyde initial condensate (condensate represented by the following formula (2) (m in the formula is the degree of polymerization)).
  • the initial condensate of resorcin/formaldehyde may be either resole type or novolac type, and preferred embodiment is novolac type.
  • the nanocellulose masterbatch of the present invention contains natural rubber or styrene-butadiene copolymer rubber as a main component as a rubber component.
  • Rubber components other than natural rubber and styrene-butadiene copolymer rubber such as diene rubber components other than natural rubber and styrene-butadiene copolymer rubber
  • the rubber component may be contained in the above-described rubber latex or RF latex, or may be a latex of another rubber component used as a raw material.
  • the content of rubber components other than natural rubber and styrene-butadiene copolymer rubber is preferably less than 30% by mass of the total rubber components contained in the nanocellulose masterbatch of the present invention, and less than 20% by mass. is more preferably less than 10% by mass, more preferably less than 5% by mass, and even more preferably less than 2% by mass.
  • Nanocellulose The nanocellulose masterbatch of the present invention further uses nanocellulose as a raw material.
  • nanocellulose means ultrafine fibers made of cellulose microfibrils and having an average fiber diameter of 1 to 1000 nm, and cellulose nanofibers (CNF) including amorphous having an average fiber length of 0.5 to 5 ⁇ m, It includes crystalline cellulose nanocrystals (CNC) with an average fiber length of 0.1 to 0.5 ⁇ m.
  • nanocellulose is surface-treated with the RF resin and formaldehyde contained in the RF latex by mixing the nanocellulose with the RF latex described above. Nanocellulose surface-treated with RF resin and formaldehyde may also be simply referred to as "nanocellulose.”
  • the average fiber diameter of this nanocellulose is 1 to 1000 nm as described above, and preferably 1 to 200 nm.
  • the average aspect ratio (average fiber length/average fiber diameter) of this nanocellulose is preferably 10-1000, more preferably 50-500.
  • the average fiber diameter is less than the above range and/or the average aspect ratio exceeds the above range, the dispersibility of nanocellulose tends to decrease. Further, when the average fiber diameter exceeds the above range and/or the average aspect ratio is below the above range, the reinforcing performance of nanocellulose tends to decrease.
  • the "average fiber diameter” and “average fiber length” of nanocellulose in the present invention are obtained by electron microscope images by setting an appropriate magnification according to the size of the constituent fibers by TEM observation or SEM observation. It means the average value of the fiber diameter and fiber length measured in at least 50 fibers in this image. Then, the average aspect ratio is calculated from the average fiber length and average fiber diameter thus obtained.
  • the cellulose used as the raw material for this nanocellulose may be either wood-derived or non-wood-derived (bacteria, algae, cotton, etc.), and is not particularly limited.
  • a method for producing nanocellulose for example, water is added to cellulose as a raw material, treated with a mixer or the like to prepare a slurry in which cellulose is dispersed in water, and this is processed by a high-pressure or ultrasonic device. There is a method of defibrating by directly applying mechanical shearing force, and this slurry is subjected to chemical treatments such as oxidation treatment, alkali treatment, and acid hydrolysis to denature cellulose to make it easier to fibrillate, and then use a disperser or the like.
  • a method of defibrating by applying a mechanical shearing force is exemplified.
  • cellulose By defibrating after chemical treatment in this way, cellulose can be defibrated more finely and homogeneously with low energy, and chemically modified nanocellulose (chemically modified nanocellulose) can be easily obtained.
  • the chemical treatment includes, for example, 2,2,6,6-tetramethylpiperidine-1-oxyl (hereinafter referred to as "TEMPO"), 4-acetamido-TEMPO, 4-carboxy-TEMPO, 4-amino-TEMPO, Treatment with chemical treating agents such as 4-hydroxy-TEMPO, 4-phosphonooxy-TEMPO, phosphate esters, periodic acid, alkali metal hydroxides and carbon disulfide can be mentioned.
  • TEMPO 2,2,6,6-tetramethylpiperidine-1-oxyl
  • 4-acetamido-TEMPO 4-carboxy-TEMPO
  • 4-amino-TEMPO Treatment with chemical treating agents such as 4-hydroxy-TEMPO,
  • the chemical treatment may be performed after the mechanical fibrillation of cellulose.
  • the chemical treatment mentioned above in order to further increase the affinity with rubber components, etc., it is also possible to perform cellulase treatment, carboxymethylation, esterification, treatment with a cationic polymer, etc. after the fibrillation process. can.
  • a carboxyl group a phosphate group, a phosphite group, a xanthate group, a sulfone group, a sulfate group, and a thiolate group, since affinity with RF resins and the like is further enhanced.
  • Chemically modified nanocellulose having one or more types for example, oxidized cellulose nanofibers in which some of the hydroxyl groups are oxidized to polar groups such as carboxy groups, aldehyde groups, phosphoric acid groups, phosphorous groups, and xanthate groups
  • the nanocellulose masterbatch of the present invention further uses a dispersant as a raw material.
  • This dispersant is a component that enhances the dispersibility of RF resin and formaldehyde-treated nanocellulose in the rubber component.
  • Dispersants include, but are not limited to, fatty acid derivatives or mixtures of fatty acid derivatives, low-molecular-weight diene-based liquid polymers having a weight-average molecular weight of 2,000 to 60,000, and oils, alkylphenol-based resins, petroleum resins, and rosin. , rosin-modified resins, coumarone-indene resins, terpene-based resins, and one or more selected from the group consisting of lignin.
  • the fatty acid derivative mixture is not limited as long as it is a mixture of a plurality of compounds containing one or more fatty acid derivatives, but from the viewpoint of improving the dispersibility of nanocellulose, it is more preferable to use a fatty acid derivative mixture containing metal soap as a main component.
  • a fatty acid derivative mixture containing metal soap as a main component.
  • examples include those containing calcium soap as a main component and those containing zinc soap as a main component.
  • those containing fatty acid amides and fatty acid esters are also preferable, and fatty acid derivative mixtures containing two or more of such fatty acid derivatives are more preferable.
  • fatty acid derivatives such as metal soaps, fatty acid amides and fatty acid esters may be used alone.
  • the fatty acid forming this fatty acid derivative may be a saturated fatty acid or an unsaturated fatty acid.
  • containing a metallic soap as a main component means that the metallic soap is contained in an amount of 60% by mass or more, preferably 70% by mass or more, more preferably 80% by mass or more. More preferably, it is 90% by mass or more.
  • the low-molecular-weight diene-based liquid polymer having a weight-average molecular weight of 2000 or more and 60000 or less is not particularly limited as long as it is a liquid diene-based polymer having a weight-average molecular weight within the above range.
  • examples include liquid polyisoprene, liquid polybutadiene, and liquid styrene-butadiene copolymer.
  • It may be one whose terminal is modified (for example, one whose terminal group is a hydroxyl group, a carboxy group, an amino group, or a methacryl group), particularly a low-molecular-weight diene-based A liquid polymer or a low-molecular-weight diene-based liquid polymer having hydroxyl or carboxyl terminal groups is preferable.
  • the oil include aromatic oil, paraffinic oil, naphthenic oil, and the like.
  • Alkylphenol-based resins include those having 1 carbon atoms obtained from cresol, isopropylphenol, t-butylphenol, amylphenol, para-octylphenol (t-octylphenol), nonylphenol, dodecylphenol, allylphenol, cyclohexylphenol, 4,6-dioctylresorcinol, and the like.
  • Preferable examples include phenols having an alkyl group of 18 or less, and phenol resins using various derivatives such as methylol derivatives and halogenated derivatives thereof.
  • Preferred petroleum resins include C5 fraction petroleum resins, C9 fraction petroleum resins, C5/C9 fraction petroleum resins, and DCPD (dicyclopentadiene) petroleum resins.
  • Terpene-based resins include terpene resins, aromatic modified terpene resins, terpene phenol resins, hydrogenated terpene resins, hydrogenated terpene phenol resins, and the like.
  • rosin is a type of natural resin, also known as rosin.
  • a rosin-modified resin is a resin modified with this rosin.
  • the coumarone-indene resin is a resin obtained by polymerizing coumarone and indene.
  • lignin is an aromatic polymer that is a major constituent of plants.
  • the oil or resin described above more easily exhibits its function as a dispersant, it is preferable that its softening point is 60 to 150°C.
  • the softening point of this oil or resin is measured by a method conforming to JIS K6220-1:2015.
  • composition The composition of each component in the nanocellulose masterbatch of the present invention produced using the raw materials as described above is as follows. First, 0.3 to 60 parts by mass, preferably 0.5 to 55 parts by mass, more preferably 1 to 50 parts by mass, more preferably 1 to 50 parts by mass of nanocellulose as a solid content of nanocellulose is added to 100 parts by mass of the rubber component. contains 3 to 45 parts by mass, more preferably 5 to 40 parts by mass. If the nanocellulose content is too low, there is a high possibility that the mechanical properties of the rubber composition obtained using the nanocellulose masterbatch cannot be sufficiently enhanced.
  • the nanocellulose may not be uniformly dispersed, and furthermore, the cost of the resulting nanocellulose masterbatch may increase. Furthermore, the viscosity of the resulting nanocellulose masterbatch may increase, making it difficult to mix with other materials.
  • 0.5 to 35 parts by mass, preferably 0.8 to 35 parts by mass, more preferably 1 to 30 parts by mass, and even more preferably 1 to 20 parts by mass of a dispersant with respect to 100 parts by mass of the rubber component More preferably, it is contained in an amount of 1 to 10 parts by mass.
  • a fatty acid derivative or a mixture of fatty acid derivatives is used as a dispersant, it is preferably contained in an amount of 0.5 to 10 parts by mass, more preferably 1 to 5 parts by mass, per 100 parts by mass of the rubber component. be.
  • the dispersant When a low-molecular-weight diene-based liquid polymer having a weight average molecular weight of 2000 or more and 60000 or less is used as the dispersant, the dispersant should be 1 to 35 parts by mass, preferably 5 to 25 parts by mass with respect to 100 parts by mass of the rubber component. is preferably contained in Furthermore, when using one or more selected from the group consisting of oil, alkylphenol-based resin, petroleum resin, rosin, rosin-modified resin, coumarone-indene resin, terpene-based resin, and lignin as a dispersant, 100 parts by mass of the rubber component It is preferable to contain 1 to 30 parts by mass, more preferably 3 to 20 parts by mass, based on the weight.
  • “100 parts by mass of the rubber component” means the mass (solid content) of natural rubber or styrene-butadiene copolymer rubber derived from rubber latex contained in the nanocellulose masterbatch of the present invention, and the mass (solid content) derived from RF latex.
  • the mass (solid content) of the styrene-butadiene copolymer rubber and/or the styrene-butadiene-vinylpyridine terpolymer, and the mass (solid content) of the rubber component when the other rubber components mentioned above are included.
  • the RF resin and formaldehyde are based on the mass of nanocellulose (solid content).
  • the RF resin is 0.03 to 1.2 parts by mass, preferably 0 .05 to 0.8 parts by weight, more preferably 0.06 to 0.6 parts by weight, more preferably 0.08 to 0.4 parts by weight, and 0.02 to 0.8 parts by weight of formaldehyde , preferably 0.03 to 0.5 parts by mass, more preferably 0.04 to 0.4 parts by mass, still more preferably 0.05 to 0.3 parts by mass.
  • the RF resin contains unreacted formaldehyde as described above, this unreacted formaldehyde is also included in the formaldehyde content. If these are too small, the surface treatment of nanocellulose cannot be performed sufficiently, and the dispersibility of nanocellulose may decrease. Moreover, if there are too many of them, the mechanical properties of the rubber composition obtained from the nanocellulose masterbatch may not be sufficiently enhanced.
  • the RF latex used as the raw material described above is styrene-butadiene copolymer rubber and/or styrene-butadiene-vinyl It is preferable that the solid content of the pyridine terpolymer is 70 to 95 mass %, the RF resin is 4 to 24 mass %, and the formaldehyde is 1 to 6 mass %.
  • Method for producing nanocellulose masterbatch of the present invention is performed using the above-described rubber latex, RF latex, nanocellulose, and dispersant as raw materials. to VII. Each will be described in detail below.
  • the rubber latex of natural rubber or styrene-butadiene copolymer rubber, the RF latex, the nanocellulose, and the dispersant are all put into a mixer or the like at the same time and mixed.
  • the solid content of the rubber latex and RF latex at this time is preferably 60% by mass or less, more preferably 50% by mass or less.
  • nanocellulose is preferably introduced and mixed as a nanocellulose aqueous dispersion, and the nanocellulose content of this nanocellulose aqueous dispersion (nanocellulose solid content) is preferably 0.1 to 10% by mass, more preferably 0.1 to 5% by mass.
  • cellulose nanofibers are easily formed into an aqueous dispersion, it is preferable to use a cellulose nanofiber aqueous dispersion as the nanocellulose aqueous dispersion.
  • the compounding amount of each component is such that the resulting nanocellulose masterbatch of the present invention is in the range described above, that is, the nanocellulose is 0.3 to 60 mass as a solid content with respect to 100 mass parts of the rubber component. part, and a dispersing agent in a blending amount of 0.5 to 35 parts by mass, and with respect to 1 part by mass of nanocellulose, 0.03 to 1.2 parts by mass of RF resin and 0.02 to 0.02 parts by mass of formaldehyde.
  • the blending amount is set to 0.8 parts by mass.
  • the solid content concentration of this raw material dispersion is preferably 60% by mass or less, more preferably 2 to 50% by mass, and even more preferably 5 to 50% by mass. If this solid content concentration exceeds 60% by mass, the stability of the raw material dispersion may be lowered. The same applies to the following manufacturing methods II to VII.
  • a coagulant is added while stirring this raw material dispersion to coagulate the polymer component, the coagulate and water are generally separated by filtration or the like, and the coagulant is washed as necessary to remove the coagulant. I do. Further, the resulting coagulum is dried (for example, dried at 50 to 100° C. for 0.5 to 30 hours) to obtain a dried product. Through these steps, the nanocellulose masterbatch of the present invention is obtained.
  • inorganic salts sodium chloride, potassium chloride, etc.
  • unsaturated fatty acid metal salts metal acrylate, metal methacrylate, etc.
  • a coagulant is added while stirring the obtained raw material dispersion to coagulate the polymer component, the coagulate and water are generally separated by filtration or the like, and the coagulate is washed as necessary to remove the coagulant. removal. Then, a dispersant is added to the obtained coagulate and mixed. Further, the coagulum mixed with the dispersant is dried (eg, dried at 50 to 100° C. for 0.5 to 30 hours) to obtain a dry product. Through these steps, the nanocellulose masterbatch of the present invention is obtained. The amount of the dispersant compounded is adjusted to be the same as in production method I. Also, preferred examples of the coagulant are the same as in the production method I.
  • Rubber latex of natural rubber or styrene-butadiene copolymer rubber, RF latex, and nanocellulose are put into a mixer or the like at the same timing.
  • the solid content of the rubber latex and RF latex, the nanocellulose content when the nanocellulose aqueous dispersion is used, and the blending amounts of each component are the same as those in the manufacturing method I. Then, they are mixed by a mixer or the like to obtain a raw material dispersion liquid in a slurry state.
  • a coagulant is added while stirring the obtained raw material dispersion to coagulate the polymer component, the coagulate and water are generally separated by filtration or the like, and the coagulate is washed as necessary to remove the coagulant. removal. Then, the resulting coagulum is dried (for example, dried under conditions of 50 to 100 ° C. for 0.5 to 30 hours) to obtain a dried product, and then a dispersant is added to the dried product and mixed. do. Through these steps, the nanocellulose masterbatch of the present invention is obtained.
  • the amount of the dispersant compounded is adjusted to be the same as in production method I. Also, preferred examples of the coagulant are the same as in the production method I.
  • rubber latex of natural rubber or styrene-butadiene copolymer rubber is added to the obtained mixed solution and mixed to obtain a raw material dispersion in a slurry state, and a coagulant is added while stirring the raw material dispersion.
  • the high-molecular weight component is coagulated, the coagulate and water are generally separated by filtration or the like, and the coagulant is removed by washing the coagulate as necessary. Further, this coagulum is dried (for example, dried at 50 to 100° C. for 0.5 to 30 hours) to obtain a dried product.
  • the nanocellulose masterbatch of the present invention is obtained.
  • the solid content of the rubber latex and the blending amount of each component are adjusted to be the same as in production method I. Also, preferred examples of the coagulant are the same as in the production method I.
  • a rubber latex of natural rubber or styrene-butadiene copolymer rubber and a dispersing agent are added to the resulting mixed solution and mixed to obtain a raw material dispersion in a slurry state.
  • a rubber latex of natural rubber or styrene-butadiene copolymer rubber and a dispersing agent are added to the resulting mixed solution and mixed to obtain a raw material dispersion in a slurry state.
  • the coagulate and water are generally separated by filtration or the like, and the coagulant is removed by washing the coagulate as necessary.
  • the resulting coagulum is dried (for example, dried at 50 to 100° C. for 0.5 to 30 hours) to obtain a dried product.
  • the nanocellulose masterbatch of the present invention is obtained.
  • the solid content of the rubber latex and the blending amount of each component are adjusted to be the same as in production method I.
  • preferred examples of the coagulant are the same as in the production method I.
  • rubber latex of natural rubber or styrene-butadiene copolymer rubber is added to the obtained mixed solution and mixed to obtain a raw material dispersion in a slurry state, and a coagulant is added while stirring the raw material dispersion.
  • the high-molecular weight component is coagulated, the coagulate and water are generally separated by filtration or the like, and the coagulant is removed by washing the coagulate as necessary.
  • a dispersant is added to the obtained coagulate and mixed.
  • the coagulum mixed with the dispersant is dried (eg, dried at 50 to 100° C. for 0.5 to 30 hours) to obtain a dried product.
  • the nanocellulose masterbatch of the present invention is obtained.
  • the solid content of the rubber latex and the blending amount of each component are adjusted to be the same as in production method I. Also, preferred examples of the coagulant are the same as in the production method I.
  • rubber latex of natural rubber or styrene-butadiene copolymer rubber is added to the obtained mixed solution and mixed to obtain a raw material dispersion in a slurry state, and a coagulant is added while stirring the raw material dispersion.
  • the high-molecular weight component is coagulated, the coagulate and water are generally separated by filtration or the like, and the coagulant is removed by washing the coagulate as necessary.
  • the obtained coagulum is dried (for example, a treatment of drying for 0.5 to 30 hours under conditions of 50 to 100 ° C.) to obtain a dried product, and then a dispersant is added to the dried product and mixed. do.
  • the solid content of the rubber latex and the blending amount of each component are adjusted to be the same as in production method I. Also, preferred examples of the coagulant are the same as in the production method I.
  • any of these production methods I to VII it is necessary to add and mix RF latex and nanocellulose at the same timing.
  • the nanocellulose is surface-treated with the RF resin and formaldehyde contained in the RF latex.
  • the RF resin or the like adheres to at least part of the surface of the nanocellulose.
  • the RF resin is proximate to the styrene-butadiene copolymer rubber and/or styrene-butadiene-vinylpyridine terpolymer contained in the RF latex.
  • the affinity between the rubber component of the rubber latex and the styrene-butadiene copolymer rubber and/or the styrene-butadiene-vinylpyridine terpolymer located close to the RF resin As a result, the affinity between the rubber component of the rubber latex and the surface-treated nanocellulose increases, and the nanocellulose is uniformly dispersed in the rubber component of the rubber latex in a nano-level defibrated state.
  • All of the nanocellulose masterbatch production methods I to VII of the present invention include optional steps related to rubber masterbatch production, other than the steps described above, within a range that does not affect the effects of the present invention. good too.
  • it may include a step of mixing a raw material other than the above with the raw material dispersion, coagulate, dried material, or the like.
  • the nanocellulose masterbatch of the present invention thus obtained, not only is the nanocellulose uniformly dispersed in the rubber component, but also the increase in viscosity is suppressed (viscosity is kept low). ) is characteristic.
  • the nanocellulose masterbatch of the present invention described above, a rubber component, and carbon black and / or silica as a filler are used as raw materials, and if necessary, a silane coupling agent, zinc oxide (zinc oxide), stearin Acids, adhesive resins, adhesives, peptizers, antioxidants, waxes, processing aids, aroma oils, lecithin, liquid polymers, terpene resins, thermosetting resins, vulcanizing agents (e.g. sulfur),
  • the rubber composition of the present invention can be obtained by blending appropriate amounts of various additives generally used in rubber compositions, such as vulcanization accelerators and vulcanization accelerator auxiliaries, and mixing and kneading them by known methods. .
  • the rubber composition of the present invention includes at least a rubber component, RF resin and formaldehyde-treated nanocellulose, a dispersant, carbon black and/or silica. At least some of the additives other than the vulcanizing agent, the vulcanization accelerator, and the vulcanization accelerator aid are added and mixed with the raw material dispersion or the like when producing the nanocellulose masterbatch of the present invention. , may be included in the nanocellulose masterbatch of the present invention.
  • the content of carbon black and/or silica in the rubber composition of the present invention is 30 to 200 parts by mass, more preferably 40 to 150 parts by mass, more preferably 50 to 100 parts by mass, based on 100 parts by mass of the total rubber component. Parts by mass are more preferred.
  • the content of nanocellulose (nanocellulose derived from the nanocellulose masterbatch of the present invention) in the rubber composition of the present invention is 0.3 to 60 parts by mass with respect to 100 parts by mass of the total rubber component. It is more preferably 5 to 40 parts by mass, even more preferably 1 to 20 parts by mass, even more preferably 2 to 10 parts by mass.
  • the content of RF resin and formaldehyde may be the same as described above with respect to the mass of nanocellulose.
  • this "total rubber component 100 parts by mass” means that the total mass of the rubber component derived from the nanocellulose masterbatch of the present invention and the rubber component used other than the nanocellulose masterbatch of the present invention is 100 parts by mass. means if The same applies to the following.
  • silicon in the present invention means a particulate substance composed of silicon dioxide (SiO 2 ) or containing silicon dioxide as a main component (for example, containing 80% by mass or more, further 90% by mass or more), “Carbon black” means fine carbon particles having a diameter of about 3 to 500 nm, manufactured under industrial quality control.
  • the silica and carbon black are not particularly limited, and any known silica and carbon black blended in rubber compositions can be used.
  • specific examples of silica include wet silica, dry silica, fumed silica, diatomaceous earth, etc. Among them, wet silica is preferably used.
  • carbon black various grades such as SAF-HS, SAF, ISAF-HS, ISAF, ISAF-LS, IISAF-HS, HAF-HS, HAF, HAF-LS, and FEF are used. be able to. And this silica and carbon black may be used individually by 1 type, or may be used in combination of 2 or more types.
  • components other than carbon black and silica such as clay, aluminum hydroxide, calcium carbonate, mica, talc, aluminum oxide, titanium oxide, barium sulfate, lecithin, etc., are used as fillers. You may These can be blended singly or in combination.
  • the rubber component to be blended into the rubber composition of the present invention together with the nanocellulose masterbatch of the present invention is preferably a diene rubber.
  • This diene rubber is a rubber component having a double bond in the polymer main chain, and specifically includes natural rubber (NR), butadiene rubber (BR), styrene-butadiene copolymer rubber (SBR), and acrylonitrile.
  • NBR -butadiene copolymer rubber
  • CR chloroprene rubber
  • IR isoprene rubber
  • styrene-isoprene copolymer rubber isoprene-butadiene copolymer rubber
  • styrene-butadiene-vinylpyridine terpolymer etc.
  • diene rubbers can be used singly or in combination of two or more.
  • the rubber composition of the present invention preferably contains 25 parts by mass or more of natural rubber and/or isoprene rubber out of 100 parts by mass of all rubber components. That is, out of 100 parts by mass of all rubber components contained in the rubber composition of the present invention, a composition containing 25 parts by mass or more of natural rubber, a composition containing 25 parts by mass or more of isoprene rubber, or a total of natural rubber and isoprene rubber It is preferable to have any one of the configurations containing 25 parts by mass or more.
  • the lower limit may be 30 parts by mass or more, 40 parts by mass or more, or 50 parts by mass or more.
  • the nanocellulose masterbatch of the present invention to be blended with the rubber composition of the present invention is prepared using natural rubber latex as the rubber latex (the rubber component contained is natural rubber as the main component). ) is preferred.
  • styrene-butadiene copolymer rubber and/or a styrene-butadiene-vinylpyridine terpolymer as a rubber component to be blended with the nanocellulose masterbatch of the present invention.
  • the rubber composition of the present invention contains 35 parts by mass or more of styrene-butadiene copolymer rubber and/or styrene-butadiene-vinylpyridine terpolymer out of 100 parts by mass of the total rubber component, and It is preferable that the rubber component has the highest mass ratio of the styrene-butadiene copolymer rubber and/or the styrene-butadiene-vinylpyridine terpolymer.
  • the mass ratio of either the styrene-butadiene-vinylpyridine terpolymer or the total of the styrene-butadiene copolymer rubber and the styrene-butadiene-vinylpyridine terpolymer is maximized.
  • the nanocellulose masterbatch of the present invention to be blended with the rubber composition of the present invention is prepared using a latex of styrene-butadiene copolymer rubber as the rubber latex (the rubber component contained is styrene - containing butadiene copolymer rubber as a main component).
  • the rubber composition of the present invention may be configured to contain only those derived from the nanocellulose masterbatch of the present invention as a rubber component. That is, the rubber composition of the present invention may be produced without using a material containing a rubber component other than the nanocellulose masterbatch of the present invention.
  • the nanocellulose masterbatch of the present invention has a suppressed increase in viscosity and can be easily mixed with other rubber components. It is very easy to produce a rubber composition of
  • the method for producing the rubber composition of the present invention is not particularly limited as long as it follows a conventional method.
  • the nanocellulose masterbatch of the present invention, a rubber component, carbon black and / or silica, and optionally other components are mixed with a kneader such as a Banbury mixer, a kneader, or a roll.
  • the rubber composition of the present invention can be produced by kneading and mixing a predetermined amount at normal temperature or high temperature.
  • vulcanization system components sulfur, vulcanization accelerator, vulcanization accelerator aid, etc.
  • other components are first mixed at a high temperature, and after cooling, vulcanization system components are added. Mixing is preferred.
  • the nanocellulose derived from the nanocellulose masterbatch of the present invention is uniformly dispersed in the rubber component, and the state of fibrillation to the nano level is maintained. , tensile stress and elongation are both excellent.
  • the nanocellulose masterbatch of the present invention used in the rubber composition of the present invention can be easily mixed with other materials, and the rubber composition of the present invention can be produced very easily.
  • Example 1 Preparation and evaluation of nanocellulose masterbatch 1
  • Rubber latex of natural rubber (HYTEX HA, high ammonia type, solid content concentration 60% by mass, manufactured by SIME DARBY PLANTATION SDN BHD), novolac-type resorcinol formaldehyde initial condensate (RF resin (Sumikanol (registered trademark) 700S), Sumitomo Kagaku Kogyo Co., Ltd.) and formaldehyde aqueous solution (37% solution, Kanto Kagaku Co., Ltd.) mixed with latex of styrene-butadiene copolymer rubber (Nipol LX112, solid content concentration 40.5% by mass, Nippon Zeon Co., Ltd.)
  • RF Latex an aqueous dispersion of oxidized cellulose nanofibers (CNF; Cellenpia, manufactured by Nippon Paper Industries Co., Ltd.) (solid content: 1.0% by mass), and a dispersant are shown
  • Mixing and dispersing were performed by changing the timing of adding the rubber latex or the timing of adding the dispersant so as to obtain each raw material dispersion in a slurry state having a solid content concentration of 60% by mass or less.
  • the RF latex was mixed so that the solid content of the styrene-butadiene copolymer rubber was 90% by mass, and the solid content of the RF resin and formaldehyde was 10% by mass.
  • each raw material dispersion is coagulated by salting out using sodium chloride as a coagulant, and the coagulate is recovered, washed and dried, and dispersed in any one of these steps if necessary.
  • the agents were added and mixed to obtain nanocellulose masterbatches of E1-1 to E1-11 and C1-1 to C1-7.
  • the washing was repeated five times by sprinkling distilled water over the surface of the coagulum to wash off the sodium chloride while filtering under reduced pressure using a Buchner funnel.
  • the drying was carried out by spreading the washed coagulum on a vat and placing it in a constant temperature dryer at 70° C. for 24 hours.
  • the Mooney viscosity was measured according to JIS K6300-1:2013. Specifically, an L-type rotor (38.1 mm diameter, 5.5 mm thickness) was used with a Mooney viscometer, and the Mooney viscosity was measured under the conditions of 1 minute of preheating, 4 minutes of rotor rotation, 100°C, and 2 rpm. It was measured. Further, each nanocellulose masterbatch after coagulation and drying was observed under a transmission electron microscope (TEM) at an appropriate magnification to obtain an electron microscope image to confirm the state of the rubber component and nanocellulose.
  • TEM transmission electron microscope
  • the results are shown in the lower part of Table 1 below.
  • the Mooney viscosity is shown as a relative value (index display (%)) when the data of the C1-1 nanocellulose masterbatch is set to 100.
  • Dispersant 1 a mixture of calcium soap, saturated fatty acid amide, and saturated fatty acid ester (Structol HT204, manufactured by Structol) - Dispersant 2: Fatty acid derivative mixture containing zinc soap as a main component (Structol EF44, manufactured by Structol) Dispersant 3: a mixture of saturated fatty acid zinc salt, aliphatic hydrocarbon, and inorganic filler (Actiplast ST, manufactured by Lanxess) *All are fatty acid derivative mixtures containing metallic soap as the main component ⁇ Timing of adding rubber latex> ⁇ Same as CNF: Rubber latex, CNF aqueous dispersion, and RF latex are added at the same timing and mixed.
  • CNF Rubber latex, CNF aqueous dispersion, and RF latex are added at the same timing and mixed.
  • FIG. (a) is C1-6 and (b) is E1-1, showing linear nanocellulose (NC), large circles rubber component, and small circles dispersant.
  • Example 2 Preparation and evaluation of rubber composition 1
  • a rubber composition having the composition shown in Table 2 below was prepared. Specifically, using each nanocellulose masterbatch (MB) obtained in Example 1, sulfur, a vulcanization accelerator, and vulcanization are added so that the solid content is the mass ratio shown in the upper part of Table 2 below. The ingredients except the sulfur accelerator were kneaded in a closed Banbury mixer, and after a predetermined time had passed, the mixture was discharged from the mixer and allowed to cool to room temperature. Next, using an open roll, sulfur, a vulcanization accelerator, and a vulcanization accelerator aid are mixed and kneaded, and this is pressed in a mold of 15 cm ⁇ 15 cm ⁇ 0.2 cm at 160 ° C.
  • vulcanized rubber test pieces Rubber compositions
  • Example 3 Preparation and evaluation of nanocellulose masterbatch 2
  • the rubber latex of natural rubber, the RF latex, and the aqueous dispersion of oxidized cellulose nanofiber are the same as in Example 1, and the mass ratio of these to the dispersant is shown in the upper part of Table 3 below as the solid content.
  • mixing and dispersing were performed by changing the timing of adding the rubber latex or the timing of adding the dispersant, and each raw material dispersion in a slurry state having a solid content concentration of 60% by mass or less was obtained.
  • each raw material dispersion was coagulated and dried in the same manner as in Example 1 to obtain nanocellulose masterbatches of E3-1 to E3-11 and C3-1 to C3-7.
  • the Mooney viscosity was measured in the same manner as in Example 1. The results are shown in the lower part of Table 3 below. The Mooney viscosity is shown as a relative value (index display (%)) when the data of the C3-1 nanocellulose masterbatch is set to 100.
  • Dispersant 4 Liquid polyisoprene with a weight average molecular weight of 47000 (Kuraprene LIR-50, manufactured by Kuraray Co., Ltd.) - Dispersant 5: liquid polybutadiene having a weight average molecular weight of 3900 (RICON 150, manufactured by Clay Valley) Dispersant 6: maleic acid-modified liquid polybutadiene with a weight average molecular weight of 3100 (RICON130MA20, manufactured by Clay Valley) *Low-molecular-weight diene-based liquid polymer with a weight-average molecular weight of 2,000 to 60,000
  • Example 4 Preparation and evaluation of rubber composition 2
  • Example 5 Preparation and evaluation of nanocellulose masterbatch 3
  • the rubber latex of natural rubber, the RF latex, and the aqueous dispersion of oxidized cellulose nanofibers were the same as in Example 1, and the solid content of these and the dispersant was adjusted so that the mass ratio shown in the upper part of Table 5 below was obtained. Then, the rubber latex was added at different timings or the dispersant was added at different timings to obtain each raw material dispersion in a slurry state having a solid content concentration of 60% by mass or less.
  • each raw material dispersion was coagulated and dried in the same manner as in Example 1 to obtain nanocellulose masterbatches of E5-1 to E5-11 and C5-1 to C5-7.
  • the Mooney viscosity was measured in the same manner as in Example 1. The results are shown in the lower part of Table 3 below. The Mooney viscosity is shown as a relative value (index display (%)) when the data of the C5-1 nanocellulose masterbatch is set to 100.
  • Dispersant 7 Aroma oil (Extract No. 4 S, manufactured by Showa Shell Sekiyu K.K.)
  • Dispersant 8 Rosin resin (pine resin (China rosin WW), manufactured by Arakawa Chemical Industries, Ltd.)
  • Dispersant 9 coumarone-indene resin (Nit Resin G-90, manufactured by Nikko Kagaku Co., Ltd.)
  • Example 6 Preparation and evaluation of rubber composition 3
  • Example 7 Preparation and evaluation of nanocellulose masterbatch 4
  • Rubber latex of styrene-butadiene copolymer rubber (Nipol LX112, solid content concentration 40.5% by mass, manufactured by Nippon Zeon Co., Ltd.), novolac-type resorcinol-formaldehyde initial condensate (RF resin (Sumikanol (registered trademark) 700S), Sumitomo Chemical Co., Ltd.) and formaldehyde aqueous solution (37% solution, Kanto Kagaku Co., Ltd.) were mixed with latex of styrene-butadiene copolymer rubber (Nipol LX112, solid content concentration 40.5% by mass, Nippon Zeon Co., Ltd.).
  • RF latex an aqueous dispersion of oxidized cellulose nanofiber (CNF; Cellenpia, manufactured by Nippon Paper Industries Co., Ltd.) (solid content 1.0% by mass), and a dispersant are shown in the upper row of Table 7 below as solid content.
  • Mixing and dispersing were performed by changing the timing of adding the rubber latex or the timing of adding the dispersant so as to obtain each raw material dispersion in a slurry state having a solid content concentration of 60% by mass or less.
  • the RF latex was mixed so that the solid content of the styrene-butadiene copolymer rubber was 90% by mass, and the solid content of the RF resin and formaldehyde was 10% by mass.
  • each raw material dispersion is coagulated by salting out using sodium chloride as a coagulant, and the coagulate is recovered, washed and dried, and dispersed in any one of these steps if necessary.
  • the agents were added and mixed to obtain nanocellulose masterbatches of E7-1 to E7-11 and C7-1 to C7-7. The washing and drying were performed in the same manner as in Example 1.
  • the Mooney viscosity was measured in the same manner as in Example 1 for each nanocellulose masterbatch thus obtained. The results are shown in the lower part of Table 7 below. The Mooney viscosity is shown as a relative value (index display (%)) when the data of the C7-1 nanocellulose masterbatch is set to 100. Further, the details of the dispersant, the timing of adding the rubber latex, and the timing of adding the dispersant in Table 7 below are the same as in Example 1.
  • Example 8 Preparation and evaluation of rubber composition 4
  • a rubber composition having the composition shown in Table 8 below was prepared. Specifically, using each nanocellulose masterbatch (MB) obtained in Example 7, sulfur, a vulcanization accelerator, and vulcanization are added so that the solid content is the mass ratio shown in the upper part of Table 8 below. The ingredients except the sulfur accelerator were kneaded in a closed Banbury mixer, and after a predetermined time had passed, the mixture was discharged from the mixer and allowed to cool to room temperature. Next, using an open roll, sulfur, a vulcanization accelerator, and a vulcanization accelerator aid are mixed and kneaded, and this is pressed in a mold of 15 cm ⁇ 15 cm ⁇ 0.2 cm at 160 ° C.
  • vulcanized rubber test pieces Rubber compositions of E8-1 to E8-12 and C8-1 to C8-7.
  • Styrene-butadiene copolymer rubber Nipol 1502 (manufactured by Nippon Zeon Co., Ltd.)
  • Carbon black Show Black N339 (manufactured by Gabot Japan)
  • Silica Zeosil 1165MP (manufactured by Rhodia)
  • Silane coupling agent Si69 (bis (3-triethoxysilylpropyl) tetrasulfide, manufactured by Evonik Degussa)
  • Zinc oxide ZnO (manufactured by Seido Chemical Industry Co., Ltd.)
  • Steparic acid bead stearic acid (manufactured by NOF Corporation)
  • Anti-aging agent SANTOFLEX 6PPD (manufactured by Flexis)
  • ⁇ Wax Paraffin wax (manufactured by Ouchi Shinko Kagaku Kogyo Co.
  • Example 9 Preparation and evaluation of nanocellulose masterbatch 5
  • the rubber latex of styrene-butadiene copolymer rubber, the RF latex, and the aqueous dispersion of cellulose oxide nanofibers were the same as in Example 7, and the solid content of these and the dispersant is shown in the upper row of Table 9 below.
  • Mixing and dispersing were carried out by changing the timing of adding the rubber latex or the timing of adding the dispersant so as to achieve the mass ratio, and each raw material dispersion in a slurry state having a solid content concentration of 60% by mass or less was obtained.
  • each raw material dispersion was coagulated and dried in the same manner as in Example 7 to obtain nanocellulose masterbatches of E9-1 to E9-11 and C9-1 to C9-7.
  • the Mooney viscosity was measured in the same manner as in Example 1 for each nanocellulose masterbatch thus obtained. The results are shown in the lower part of Table 9 below. The Mooney viscosity is shown as a relative value (index display (%)) when the data of the C9-1 nanocellulose masterbatch is set to 100. Further, the detailed contents of the dispersant, the timing of adding the rubber latex, and the timing of adding the dispersant in Table 9 below are the same as in Example 3.
  • Example 10 Preparation and evaluation of rubber composition 5
  • Example 11 Preparation and evaluation of nanocellulose masterbatch 6
  • the rubber latex of styrene-butadiene copolymer rubber, the RF latex, and the aqueous dispersion of cellulose oxide nanofibers were the same as in Example 7, and the solid content of these and the dispersant is shown in the upper row of Table 11 below.
  • Mixing and dispersing were carried out by changing the timing of adding the rubber latex or the timing of adding the dispersant so as to achieve the mass ratio, and each raw material dispersion in a slurry state having a solid content concentration of 60% by mass or less was obtained.
  • each raw material dispersion was coagulated and dried in the same manner as in Example 7 to obtain nanocellulose masterbatches of E11-1 to E11-11 and C11-1 to C11-7.
  • the Mooney viscosity was measured in the same manner as in Example 1 for each nanocellulose masterbatch thus obtained. The results are shown in the lower part of Table 11 below. The Mooney viscosity is shown as a relative value (index display (%)) when the data of the C11-1 nanocellulose masterbatch is set to 100. Further, the details of the dispersant, the timing of adding the rubber latex, and the timing of adding the dispersant in Table 11 below are the same as in Example 5.
  • Example 12 Preparation and evaluation of rubber composition 6

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Abstract

La présente invention aborde le problème de la fourniture d'un mélange maître de nanocellulose pouvant donner lieu à une composition de caoutchouc dans laquelle de la nanocellulose est dispersée uniformément, qui est inhibée en ce qui concerne l'augmentation de la viscosité et qui présente à la fois une excellente contrainte de traction et un excellent allongement. Le problème peut être résolu par un mélange maître de nanocellulose comprenant un composé de caoutchouc, une nanocellulose dont la surface est traitée avec un condensat initial de résorcinol-formaldéhyde de type résol et/ou de type novolaque et du formaldéhyde, ainsi qu'un agent de dispersion, le composé de caoutchouc contenant un caoutchouc naturel ou un caoutchouc à base de copolymère de styrène-butadiène en tant que composé principal, la nanocellulose étant contenue dans une quantité de 0,3 à 60 parties en masse et l'agent de dispersion étant contenu dans une quantité de 0,5 à 35 parties en masse, chacun par rapport à 100 parties en masse du composé de caoutchouc, et le condensat initial de résorcinol-formaldéhyde de type résol et/ou de type novolaque étant contenu dans une quantité de 0,03 à 1,2 partie en masse et le formaldéhyde étant contenu dans une quantité de 0,02 à 0,8 partie en masse, chacun par rapport à 1 partie en masse de la nanocellulose.
PCT/JP2022/015808 2021-04-07 2022-03-30 Mélange maître de nanocellulose et son procédé de production WO2022215614A1 (fr)

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