Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/20—Organic compounds containing oxygen
  • C11D3/2068—Ethers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B08—CLEANING
  • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
  • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
  • B08B3/04—Cleaning involving contact with liquid
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B08—CLEANING
  • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
  • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
  • B08B3/04—Cleaning involving contact with liquid
  • B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
  • C11D1/667—Neutral esters, e.g. sorbitan esters
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
  • C11D1/72—Ethers of polyoxyalkylene glycols
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
  • C11D1/75—Amino oxides
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
  • C11D1/825—Mixtures of compounds all of which are non-ionic
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/88—Ampholytes; Electroneutral compounds
  • C11D1/92—Sulfobetaines ; Sulfitobetaines
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/88—Ampholytes; Electroneutral compounds
  • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/0005—Other compounding ingredients characterised by their effect
  • C11D3/0094—High foaming compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/26—Organic compounds containing nitrogen
  • C11D3/32—Amides; Substituted amides
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/43—Solvents
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
  • C11D2111/10—Objects to be cleaned
  • C11D2111/14—Hard surfaces
  • C11D2111/18—Glass; Plastics
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
  • C11D2111/40—Specific cleaning or washing processes
  • C11D2111/42—Application of foam or a temporary coating on the surface to be cleaned

Definitions

• the present invention relates to a liquid cleaning composition for tableware and / or a hard article around a kitchen, and a method for cleaning tableware and / or a hard article around a kitchen.
• BACKGROUND ART For washing dishes and cooking utensils, a method is generally used in which a detergent for tableware is soaked in a sponge containing water and foamed while squeezing several times to rub the object. .
• This method was considered as a process necessary for removing stubborn dirt such as oil-based fat and oil stains derived from foods, but was inconvenient when washing containers and instruments having fine gaps and depths that were not covered by sponges.
• a technique has been developed that has a high detergency by simply rinsing after leaving for a certain period of time without rubbing, by attaching a detergent for dishes to the object in the form of foam. That is, instead of a conventional method of scrubbing with a sponge, a method of spraying in the form of foam and leaving it without rubbing has been proposed.
• JP-A-2016-199754 proposes a cleaning method in which a liquid detergent composition containing a sulfosuccinic acid alkyl ester is brought into contact with a hard surface and then left without applying mechanical force.
• a WO emulsifying surfactant having a low HLB to a hard surface cleaning agent refer to JP-A-7-34092, JP-A-2017-2137, and JP-A-2008-111140. Can do.
• the present invention provides a liquid cleaning composition for tableware and / or a hard article around a kitchen, which has excellent detergency against liquid oil stains adhering to the tableware.
• the present invention includes (a) a nonionic surfactant having an HLB of 10.5 or less [hereinafter referred to as component (a)], (b) an amine oxide surfactant, an amphoteric surfactant, and an HLB of 11 or more.
• component (b) nonionic surfactants
• component (c) an organic solvent having a log Pow of 0 to 1.5
• the proportion of the component (a) in the total surfactant is 30% by mass or more and 85% by mass or less
• (C) / (a) which is a mass ratio of the content of the component (c) to the content of the component (a) is 1 or more and 10 or less
• the viscosity at 20 ° C. is 20 mPa ⁇ s or less
• the present invention relates to a liquid cleaning composition for hard articles around tableware and / or kitchens.
• the present invention provides the liquid detergent composition for a hard article around the tableware and / or kitchen of the present invention, in a foamed state, and a tableware and / or kitchen to which dirt containing liquid oil derived from food is attached.
• the present invention relates to a method for cleaning tableware and / or a hard article around a kitchen, which is brought into contact with the surrounding hard article.
• a liquid cleaning composition for tableware and / or a hard article around a kitchen which has excellent cleaning power against dirt containing liquid oil adhering to tableware and the like.
• the liquid detergent composition of the present invention can satisfactorily clean liquid oil stains adhering to an article made of a hydrophobic material such as plastic by a simple method.
• the component (a) is a nonionic surfactant having an HLB of 10.5 or less.
• the component HLB (a) is preferably 3 or more, more preferably 4 or more, still more preferably 5 or more, and preferably 10 or less, more preferably 9.5 or less, from the viewpoint of detergency against liquid oil stains. More preferably, it is 9 or less.
• the HLB of the component (a) is the HLB obtained by Griffin's method, and the HLB value of this method is obtained by the following formula in the case of a polyoxyalkylene type nonionic surfactant.
• HLB value 20 ⁇ (M H / M) [M H : Molecular weight of hydrophilic group part, M: Molecular weight]
• M Molecular weight
• the molecular weight of the hydrophilic group portion is determined using the average value of the added mole number.
• an ester type nonionic surfactant it is obtained by the following formula.
• HLB value 20 ⁇ (1-S / A) [S: saponification value of ester, A: acid value of fatty acid]
• the component (a) is a nonionic surfactant in which at least one of the HLBs determined by Griffin's method and the experimental method is 10.5 or less.
• HLB for a nonionic surfactant, it means HLB obtained by the above two methods unless otherwise specified.
• component (a) An average of 1 mole of an alkylene oxide having 2 or 3 carbon atoms to a fatty alcohol having 8 to 18 carbon atoms or a lower alcohol ester of a fatty acid having 8 to 18 carbon atoms (the lower alcohol has 1 to 3 carbon atoms) A nonionic surfactant added at 5 mol or less, a polyoxyalkylene type nonionic surfactant having an HLB of 10.5 or less (hereinafter referred to as component (a1)), (A2) A polyhydric alcohol ester type nonionic interface comprising an ester of a polyhydric alcohol having 2 to 10 hydroxy groups and a fatty acid having 8 to 18 carbon atoms and having an HLB of 10.5 or less Activator [hereinafter referred to as component (a2)], (A3) Mono- or dialkanolamide having an alkanoyl group having 8 to 18 carbon atoms (the alkanol group has 2 or 3 carbon atoms) or an alkylene oxide adduct thereof
• a nonionic surfactant having 2 or 3 carbon atoms of an amine having a hydrogen group and having an HLB of 10.5 or less (hereinafter referred to as component (a4)) 1 type or more of nonionic surfactant chosen from these is mentioned.
• At least one nonionic surfactant selected from the components (a1) and (a2) is preferable.
• the fatty alcohol or fatty acid constituting the component (a1) may be linear or branched.
• the carbon number of the fatty alcohol or fatty acid is preferably 10 or more, and preferably 16 or less, more preferably 14 or less.
• the polyoxyalkylene group as the component (a1) has an average addition mole number of preferably 2 or more and preferably 4 or less.
• the alkylene oxide is preferably an alkylene oxide having 2 carbon atoms and / or an alkylene oxide having 3 carbon atoms, that is, ethylene oxide and / or propylene oxide, and more preferably ethylene oxide.
• As the lower alcohol esters of fatty acids methyl esters and ethyl esters are preferred.
• a polyoxyethylene alkyl ether type nonionic surfactant obtained by adding an average of 1 mol to 4 mol of ethylene oxide to a linear fatty alcohol having 10 to 14 carbon atoms, 10 carbon atoms
• Nonionic surfactants added in a molar amount or less are listed.
• the number of hydroxy groups is preferably 3 or more and preferably 6 or less.
• the polyhydric alcohol constituting the component (a2) include glycerin, diglycerin, trimethylolpropane, pentaerythritol, sorbitan and the like.
• carbon number of the fatty acid which comprises (a2) component becomes like this. Preferably it is 10 or more, and 18 or less, Preferably it is 14 or less.
• component (a2) examples include glycerin mono or dilaurate, glycerin mono or distearate, trimethylolpropane mono or dilaurate, pentaerythritol mono or dilaurate, and sorbitan monolaurate.
• the carbon number of the alkanoyl group constituting the component (a3) is preferably 10 or more, and preferably 16 or less, more preferably 14 or less.
• the alkanol group (—ROH: R is an alkylene group having 2 or 3 carbon atoms) preferably has 2 carbon atoms. In the case of an alkylene oxide adduct, the average addition mole number is preferably 1 or more and 3 or less.
• the alkylene oxide is preferably an alkylene oxide having 2 carbon atoms and / or an alkylene oxide having 3 carbon atoms, that is, ethylene oxide and / or propylene oxide, and more preferably ethylene oxide.
• the carbon number of the hydrocarbon group constituting the component (a4) is preferably 10 or more, and preferably 16 or less, more preferably 14 or less.
• the hydrocarbon group of the component (a4) is preferably an alkyl group.
• the alkylene oxide is preferably an alkylene oxide having 2 carbon atoms and / or an alkylene oxide having 3 carbon atoms, that is, ethylene oxide and / or propylene oxide, and more preferably ethylene oxide.
• the average added mole number of alkylene oxide is preferably 1 or more and 4 or less.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention contains, as component (a), one or more nonionic surfactants selected from components (a1) to (a4). It is preferable. Further, the liquid detergent composition for tableware and / or hard articles around the kitchen of the present invention contains, as component (a), at least one nonionic surfactant selected from components (a1) to (a4). In the component (a), the proportion of one or more nonionic surfactants selected from the components (a1) to (a4) is 30% by mass or more, further 60% by mass or more, and further 90% by mass. % Or more is preferable. The upper limit of this ratio is 100% by mass or less, and may be 100% by mass.
• Component (b) is a surfactant selected from amine oxide surfactants, amphoteric surfactants, and nonionic surfactants having an HLB of 11 or more.
• amine oxide type surfactant a compound represented by the following general formula (b1) is suitable.
• R 1b represents a hydrocarbon group having 7 to 22 carbon atoms, preferably an alkyl group or an alkenyl group, more preferably an alkyl group, and R 2b and R 3b are the same or different and have 1 or more carbon atoms. 3 or less alkyl groups are shown.
• D represents an —NHC ( ⁇ O) — group or a —C ( ⁇ O) NH— group
• E represents an alkylene group having 1 to 5 carbon atoms.
• R 1b is preferably 9 to 18 carbon atoms from the viewpoint of detergency against dirt containing liquid oil derived from food.
• An alkyl group more preferably an alkyl group having 11 to 16 carbon atoms, still more preferably an alkyl group having 11 to 14 carbon atoms, and still more preferably an alkyl group having 11 carbon atoms.
• R 1b is preferably an alkyl group having 10 to 18 carbon atoms, more preferably, from the viewpoint of detergency against dirt containing liquid oil derived from food.
• R 2b and R 3b are preferably a methyl group having 1 carbon atom from the viewpoint of detergency against dirt containing liquid oil derived from food.
• amphoteric surfactant examples include one or more surfactants selected from betaine surfactants. Specific examples include one or more amphoteric surfactants selected from sulfobetaine and carbobetaine.
• the sulfobetaine is an N-alkyl-N, N-dimethyl-N-sulfopropylammonium sulfobetaine having an alkyl group with a carbon number of preferably 10 or more, preferably 18 or less, more preferably 14 or less, or a carbon number of an alkyl group.
• the number of carbon atoms of the alkanoyl group is preferably 10 or more N-alkanoylaminopropyl-N, N-dimethyl-N-sulfopropylammonium sulfobetaine, preferably 18 or less, more preferably 14 or less
• the alkanoyl group preferably has 10 or more carbon atoms, preferably 18 or less, more preferably Is 14 or less N-alkanoylaminopropy -N, include N- dimethyl-N-(2-hydroxy-sulfopropyl) ammonium sulfobetaine.
• N-alkyl-N, N-dimethyl-N-carboxymethylammonium betaine having an alkyl group of preferably 10 or more, preferably 18 or less, more preferably 14 or less, or the following general formula (b2)
• a compound represented by the following general formula (b2) is preferable from the viewpoint of detergency.
• R 4b represents an alkyl group or alkenyl group having 7 to 21 carbon atoms
• R 5b represents a propylene group
• R 6b and R 7b each independently represents an alkyl group having 1 to 3 carbon atoms. Indicates. ]
• R 4b is an alkyl group or an alkenyl group having a carbon number of preferably 9 or more, more preferably 11 or more, and preferably 15 or less, more preferably 13 or less.
• a decyl group, an undecyl group, a dodecyl group, and a tridecyl group are preferable.
• R 6b and R 7b are each independently preferably a methyl group.
• the alkyl group preferably has 8 or more carbon atoms, and Preferably, it is 18 or less, more preferably 14 or less, and the number of added moles of ethylene oxide and / or propylene oxide is preferably 5 or more, more preferably 6 or more, and preferably 10 or less, more preferably 8 or less.
• examples thereof include ethylene and / or polyoxypropylene alkyl ether type nonionic surfactants.
• the component (b) is preferably an amphoteric surfactant and one or more surfactants selected from polyoxyethylene and / or polyoxypropylene alkyl ether type nonionic surfactants, One or more surfactants selected from sulfobetaines and polyoxyethylene alkyl ether type nonionic surfactants are more preferred.
• the component (c) is an organic solvent having a log Pow of 0 or more and 1.5 or less.
• an organic solvent having 2 or more carbon atoms, 3 or more carbon atoms, 10 or less carbon atoms, and further 8 or less carbon atoms is preferable.
• an organic solvent selected from monohydric alcohols, polyhydric alcohols (such as glycol), and glycol ethers is preferable.
• the logPow of the component (c) is preferably 0.2 or more, more preferably 0.3 or more, and preferably 1.2 or less, more preferably 1 or less.
• the logPow value is a coefficient indicating the affinity of an organic compound for water and 1-octanol.
• 1-octanol / water partition coefficient P is a distribution equilibrium when a trace amount of a compound is dissolved as a solute in a two-liquid solvent of 1-octanol and water, and is a ratio of the equilibrium concentration of the compound in each solvent. It is common to show them in the form of their logarithmic logPow for base 10.
• the logPow values of many compounds have been reported, and many values are listed in databases available from Daylight Chemical Information Systems, Inc. (Daylight CIS), etc., which can be referred to.
• logPow When there is no measured logPow value, it can be calculated by a program “CLOGP” or the like available from Daylight CIS. This program outputs the value of “calculated logPow (ClogPow)” calculated by the Hansch, Leo fragment approach together with the measured logPow value, if any.
• the fragment approach is based on the chemical structure of the compound and takes into account the number of atoms and the type of chemical bond (cf. A. Leo, Comprehensive Medicinal Chemistry, Vol.4, C. Hansch, PG Sammens, JB Taylor and CA Ramsden, Eds., P.295, .Pergamon Press, 1990).
• This ClogPow value can be used in place of the actual logPow value when selecting a compound. In the present invention, if there is a measured value of logPow, the ClogPow value calculated by the program CLOGP v4.01 is used when there is no measured value.
• the component (c) includes (c-1) a monohydric alcohol having 1 to 3 carbon atoms, (c-2) a polyhydric alcohol having 2 to 4 carbon atoms, and (c-3) the carbon number of an alkylene glycol unit.
• a dialkyl or trialkylene glycol having 2 to 4 and (c-4) a monoalkyl (methyl, ethyl, propyl or butyl) of a mono, di, tri or tetraalkylene glycol having 2 to 4 carbon atoms in the alkylene glycol unit Mention may be made of monophenyl or monobenzyl ether.
• (c-1) is also referred to as ethanol, isopropyl alcohol, (c-2) as isoprene glycol, and (c-4) as propylene glycol monoethyl ether, diethylene glycol monobutyl ether (butyl diglycol, etc.).
• triethylene glycol monobutyl ether also called butyl triglycol
• phenoxyethanol phenoxytriethylene glycol
• phenoxyisopropanol an organic solvent selected from ethanol, dipropylene glycol monobutyl ether, diethylene glycol monobutyl ether, triethylene glycol monobutyl ether, phenoxyethanol, and phenoxyisopropanol is preferable.
• the component (c) preferably has an alkoxy group.
• the liquid detergent composition for hard articles around the tableware and / or kitchen according to the present invention is as a component (c) from the above (c-4) from the viewpoint of further enhancing the cleaning action of food-derived liquid oil stains. It is preferable to contain one or more selected, preferably one or more selected from diethylene glycol monobutyl ether and triethylene glycol monobutyl ether, and more preferably diethylene glycol monobutyl ether.
• the component (a) is a W / O type surfactant having the property of emulsifying and dispersing water in the oil component.
• the component (b) is an O / W type surfactant.
• component (a) When a W / O type surfactant such as component (a) is brought into contact with liquid oil adhering to a hydrophobic surface such as plastic, component (a) penetrates into the liquid oil in a state of emulsifying water, Since the interfacial energy between the hydrophobic surface and the liquid oil is significantly reduced, the liquid oil can be easily peeled off from the hydrophobic interface by the O / W type surfactant as the component (b).
• the composition of the present invention when the composition of the present invention is brought into contact with liquid oil in the form of a foam, it becomes possible to further improve the permeability of the component (a) and the detergency not depending on the external force of the component (b).
• the component (b) a surfactant having a high foaming property is employed. Furthermore, the component (c) having a specific logPow is considered to have an effect of enhancing the function of increasing the permeability of the component (a) to liquid oil.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention is preferably 0.5% by mass or more, more preferably 1% by mass, from the viewpoint of detergency against liquid oil stains. % Or more, more preferably 2% by mass or more, and preferably 10% by mass or less, more preferably 8% by mass or less, and still more preferably 6% by mass or less.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention preferably comprises component (b) from the viewpoints of cleanability of liquid oil stains not depending on external force and foamability of the composition. It is contained in an amount of 0.25% by mass or more, more preferably 1% by mass or more, further preferably 2% by mass or more, and preferably 10% by mass or less, more preferably 8% by mass or less, and still more preferably 6% by mass or less.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention is preferably 0.5% by mass or more, more preferably 1% by mass, from the viewpoint of detergency against liquid oil stains. % Or more, more preferably 4% by mass or more, and preferably 30% by mass or less, more preferably 20% by mass or less, and still more preferably 15% by mass or less.
• the proportion of the component (a) in the total surfactant is preferably 30% by mass or more, preferably from the viewpoint of detergency against liquid oil stains. Is at least 30.0% by mass, more preferably at least 35% by mass, even more preferably at least 40% by mass, even more preferably at least 50% by mass, even more preferably at least 55% by mass, even more preferably at least 60% by mass. And 85% by mass or less, preferably 75% by mass or less, more preferably 70% by mass or less.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention has a total proportion of the components (a) and (b) in the total surfactant from the viewpoint of detergency against liquid oil stains.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention is a mass ratio of the content of the component (c) to the content of the component (a) from the viewpoint of the detergency against liquid oil stains.
• (C) / (a) is 1 or more and 10 or less.
• the mass ratio of (c) / (a) is preferably 1.0 or more, and preferably 8 or less, more preferably 5 or less, still more preferably 4 or less, and still more preferably 3 or less.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention has a mass ratio of the content of the component (a) to the content of the component (b) from the viewpoint of the detergency against liquid oil stains.
• (A) / (b) is preferably 0.5 or more and 10 or less.
• the mass ratio of (a) / (b) is preferably 0.5 or more, more preferably 8 or less, and still more preferably 5 or less.
• a surfactant other than the component (a) and the component (b) can be contained, but it is necessary to use it within a range not impairing the effects of the present invention.
• an anionic surfactant hereinafter referred to as component (d)] may affect the permeability of component (a) to liquid oil, when it is contained, the content in the composition is preferably Is 5% by mass or less, more preferably 4% by mass or less, still more preferably 3% by mass or less, still more preferably 2% by mass or less, and still more preferably 1% by mass or less.
• component (d) examples include polyoxyethylene alkyl ether sulfates, alkyl sulfates, and alkylbenzene sulfonates.
• the content of one or more anionic surfactants selected from polyoxyethylene alkyl ether sulfates, alkyl sulfates and alkylbenzene sulfonates may be within the range of the content of component (d).
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention preferably has a total surfactant content of 0.5 mass% or more, more preferably 1 mass. % Or more, more preferably 3% by mass or more, and preferably 20% by mass or less, more preferably 15% by mass or less, and still more preferably 10% by mass or less.
• the total content of the surfactant is calculated based on the total amount of the component (a) and the component (b) and any other surfactant.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention is preferably brought into contact with an object in a foam state. Therefore, care must be taken when using a component that inhibits the foamability of the composition.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention may contain a solvent other than the component (c), but a hydrocarbon solvent such as paraffin or terpene hydrocarbon [hereinafter ( It is desirable to limit the content of “e) component” in order to reduce the foamability of the composition of the present invention.
• the composition of the present invention is (e) component / [(a) component + (b) component], which is a mass ratio of the content of (e) component to the total content of (a) component and (b) component.
• hydrocarbon solvent of component (e) examples include normal paraffins having 10 to 20 carbon atoms as paraffin solvents, isoparaffins having 10 to 20 carbon atoms, and limonene as terpenoid solvents. Terpenes, pinenes and the like.
• the paraffinic solvent and the terpenoid solvent are preferably used as the component (e), and the content thereof is preferably set to the mass ratio.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention may contain a solvent other than the component (c), but from the same viewpoint as described for the component (e), (e1 ) It is preferable that the content of the organic solvent [hereinafter referred to as (e1) component] having a log Pow of more than 1.5 is small. Although the use of a small amount of the component (e1) may contribute to the improvement of detergency, it is preferable to adjust the amount used in consideration of foaming properties.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention has a mass ratio of the content of the component (e1) to the content of the component (c) (e1) / (c). 0.5 or less, 0.3 or less, 0.1 or less, or 0. Normally, the component (e) is also the component (e1) because logPow exceeds 1.5.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention is an anti-gelling agent, a thickener such as polyacrylic acid, a fragrance, a dye, a pigment, a disinfectant, an antiseptic, a pH adjuster, etc.
• a thickener such as polyacrylic acid
• a fragrance such as polyacrylic acid
• a fragrance such as polyacrylic acid
• a dye such as polyacrylic acid
• a dye such as sodium sulfate
• a pigment such as sodium bicarbonate
• a disinfectant such as sodium bicarbonate
• an antiseptic such as sodium bicarbonate
• pH adjuster a thickener
• the component of this can be contained.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention contains water. That is, the balance other than the components (a) to (c) and the optional component is water.
• the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention is adjusted to a suitable viscosity, and from the viewpoint of sufficiently exhibiting the effects of the present invention, water is preferably 30% by mass or more, more Preferably 50% by mass or more, more preferably 60% by mass or more, still more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass or more, and preferably 99.5% by mass. Below, more preferably 99% by mass or less.
• As the water it is preferable to use ion exchange water, sterilized ion exchange water, or the like.
• the pH at 20 ° C. of the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention is preferably 2 or more, more preferably 4 or more, more preferably 5 or more, from the viewpoint of mildness to the hand. And, it is preferably 10 or less, more preferably 9 or less, still more preferably 8 or less.
• the pH is measured by a glass electrode method.
• the viscosity of the composition is an important factor for the purpose of obtaining a high detergency without applying external force to liquid oil stains.
• the viscosity of the composition is too high, the composition adheres to the dirt but hardly penetrates, so that sufficient cleaning cannot be performed unless external force is applied.
• the penetration of the components (a), (b) and (c) into the soil is promoted by the viscosity of the composition being in an appropriate range, a high detergency can be achieved without applying external force. Can show.
• the composition of the present invention is brought into contact with dirt in the form of foam, the detergency is more remarkably exhibited, so application with foam is a preferred embodiment.
• the viscosity of the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention at 20 ° C. is 20 mPa ⁇ s or less, preferably 15 mPa ⁇ s or less, more preferably 10 mPa ⁇ s or less, and even more preferably 7 mPa ⁇ s. s or less, more preferably 5 mPa ⁇ s or less.
• the lower limit of the viscosity is preferably 0.5 mPa ⁇ s or more, more preferably 1 mPa ⁇ s or more.
• the viscosity can be adjusted with a solvent or a hydrotrope. Here, the viscosity is measured by the following method.
• the liquid detergent composition for tableware and / or hard articles around the kitchen of the present invention is applied to tableware and hard articles around the kitchen with foam.
• the foam obtained from the composition of the present invention has a foam specific volume of preferably 30 ml / g or less, more preferably 20 ml / g or less, still more preferably 10 ml / g or less, and even more preferably 7 ml. / G or less.
• the lower limit of the foam specific volume is preferably 1 ml / g or more, more preferably 2 ml / g or more.
• the foam has a specific volume in this range after the production, after a certain period of time has elapsed, for example, 1 minute after the production.
• the foam obtained from the composition of the present invention is preferably 10 ml / g or more, more preferably 15 ml / g or more, from the viewpoint of convenience that can cover a wide range of objects and a feeling of detergency. More preferably, it is 20 ml / g or more.
• the upper limit of the foam specific volume is preferably 100 ml / g or less. From this viewpoint, it is preferable that the foam has a foam specific volume within this range immediately after production.
• the foam immediately after coming into contact with the tableware and / or the hard article around the kitchen that is, the foam immediately after the discharge, is preferred because it is preferred to have abundant foaming from the standpoint of aesthetic point of view and washing. It is preferable from the viewpoint of detergency that the foam volume becomes moderately small with the passage of time because the mobility of the component (a) to the liquid oil stain is good.
• the foam specific volume (mL / g) is preferably 10 or less, more preferably 7 or less in 1 minute after discharge, the mobility of the component (a) to the liquid oil is suitable, and the cleaning effect Will improve.
• (c) / (b), which is the mass ratio of the content of component (c) to the content of component (b), is preferably 0.5 or more, more preferably 1 More preferably, it is 1.2 or more, more preferably 1.5 or more, and preferably 7 or less, more preferably 5 or less.
• the method for cleaning hard articles around the tableware and / or kitchen of the present invention is derived from food in the form of foam without dilution of the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention.
• This is a cleaning method in which a soil containing liquid oil, for example, a composite soil of liquid oil and solid fat, and / or a hard article around the kitchen is contacted. This method is suitable for cleaning parts that are out of reach of hands and tools and details that are difficult to reach.
• liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention When the liquid detergent composition for hard articles around the tableware and / or kitchen of the present invention is brought into contact with soil containing liquid oil derived from food, the liquid oil is finely divided and the object (tableware and (Or hard articles around the kitchen). Therefore, in the cleaning method of the present invention, liquid oil stains can be easily cleaned by rinsing the object with water, for example, after standing for a predetermined time without applying external force such as scrubbing.
• the liquid cleaning composition is brought into contact with a tableware and / or a hard article around the kitchen, which is not diluted, in a foamed state, and attached with soil containing liquid oil derived from food. It is preferred to rinse without rubbing.
• the liquid detergent composition is made into a foam without diluting, and brought into contact with, for example, a tableware and / or a hard article around the kitchen to which oily soil containing liquid oil is adhered, mechanical force, etc. It is preferable to wash without applying external force.
• the liquid detergent composition is made into a foam without diluting, and brought into contact with, for example, a tableware and / or a hard article around the kitchen to which oily soil containing liquid oil is adhered, mechanical force, etc. It is preferable to leave and wash without applying external force.
• an operation for intentionally applying an external force for cleaning to the object is not performed. That is.
• the contacted composition naturally flows down the surface of the tableware and / or the hard article around the kitchen, or a vibration that is not intended for cleaning is transmitted to the tableware and / or the hard article around the kitchen.
• the hard article around the kitchen and / or the kitchen is washed without applying external force such as.
• Contacting the soiled dishes and / or hard articles around the kitchen with liquid oil derived from food without diluting the liquid detergent composition is intended to After dilution with water or the like, it is not allowed to come into contact with soiled dishes containing liquid oil derived from food and / or hard articles around the kitchen.
• the liquid cleaning composition is brought into contact with tableware and / or a hard article around the kitchen to which water droplets or the like are attached, or after the liquid cleaning composition is brought into contact with the tableware and / or a hard article around the kitchen.
• the liquid detergent composition is not diluted, and the dishes containing liquid oil derived from foods are attached to the dishes and / or around the kitchen. It can be understood that it is in contact with a hard article. After standing, the hard article is rinsed with water.
• external force physical force
• the liquid detergent composition is brought into contact with a dish and / or a hard article around the kitchen containing a liquid oil derived from a food product in a foam state, and is made of a flexible material.
• a cleaning method in which none of cleaning, cleaning with running water, and cleaning with ultrasonic waves is performed, and it is left as it is without applying external force such as mechanical force. That is, as the cleaning method of the present invention, the liquid cleaning composition is brought into contact with a dish and / or a hard article around the kitchen, which contains a liquid oil derived from food, and is attached in a foamed state, such as a sponge.
• a cleaning method in which a friction force by a flexible material, a flowing water force by a shower or the like in an automatic dishwasher, and a vibration by an ultrasonic wave are not used and an external force such as a mechanical force is not applied.
• the soil containing liquid oil derived from food may be a composite soil containing liquid oil and solid fat.
• the solid fat exhibits a solid at normal temperature (for example, 20 ° C.), for example.
• the form of the composite soil when contacting the liquid detergent composition may be a state in which liquid oil and solid fat are mixed.
• the soil targeted by the present invention may be an oily soil containing a large amount of liquid oil.
• the stock solution of the liquid detergent composition is used as it is, that is, without changing the composition, to a tableware and / or a hard article around the kitchen to which a soil containing liquid oil derived from food is attached in the form of foam. It is preferable to make it adhere.
• the liquid detergent composition is brought into contact with a dish and / or a hard article around the kitchen on which a soil containing liquid oil derived from food is adhered without being attached to a sponge containing water. Is preferred.
• the composition of the liquid detergent composition may vary. That is, the composition of the liquid detergent composition may be diluted or concentrated after contacting the tableware and / or the hard article around the kitchen.
• a concentrated composition containing the components (a), (b), and (c) of the present invention is prepared, and the concentrated composition is diluted with water to prepare a liquid detergent composition used in the present invention.
• the liquid detergent composition may be prepared and brought into contact with dishes and / or hard articles around the kitchen in a foamed state without diluting.
• a liquid detergent composition used in the present invention is prepared by diluting a concentrated composition containing the components (a), (b) and (c) of the present invention with water, and the liquid detergent composition Tableware and / or kitchen surroundings in which the product is brought into contact with soiled dishes and / or hard articles surrounding the kitchen containing liquid oil derived from food without dilution and without applying external force such as mechanical force
• the method for cleaning hard articles may be used.
• the liquid cleaning composition is brought into contact with a tableware and / or a hard article around the kitchen on which a soil containing liquid oil derived from food is attached without diluting the liquid cleaning composition. After that, it is preferably left without applying external force. That is, there is a cleaning method in which contact is made without using a flexible material such as sponge or fingers, and the device is left as it is without applying external force such as mechanical force. After standing, it is usually rinsed with water. When rinsing, an external force (physical force) may be applied by hand or the like, or simply rinsing with a water flow.
• the liquid detergent composition for a hard article around the tableware and / or kitchen of the present invention has a foam specific volume of 1 ml / g or more, preferably 2 ml / g or more and 100 ml / g or less.
• the foam specific volume can be calculated by the following equation.
• Foam specific volume (mL / g) foam volume (mL) / foam mass (g)
• the liquid detergent composition is a liquid oil derived from food with a foam specific volume (mL / g) of preferably 10 or more, more preferably 15 or more, and still more preferably 20 or more.
• a foam specific volume (mL / g) of preferably 10 or more, more preferably 15 or more, and still more preferably 20 or more.
• the foam specific volume (mL / g) after 1 minute of contact with the soil is preferably 30 or less, more preferably 20 Hereinafter, it is more preferably 10 or less, and even more preferably 7 or less.
• the foam immediately after coming into contact with the tableware and / or the hard article around the kitchen that is, the foam immediately after the discharge, is preferred because it is preferred to have abundant foaming from the standpoint of aesthetic point of view and washing. It is preferable from the viewpoint of detergency that the foam volume becomes moderately small with the passage of time because the mobility of the component (a) to the liquid oil stain is good.
• the foam specific volume (mL / g) becomes 10 or less, preferably 7 or less in 1 minute after discharge, the mobility of the component (a) to the liquid oil is suitable, and the cleaning effect is improved. .
• the effect of the component (c) is important, and it is preferable to adjust the relative content with respect to the component (b) which is a foaming surfactant.
• the mass ratio of the component (c) / the component (b) is preferably 0.5 or more, more preferably 1 or more, still more preferably 1.2 or more, and still more preferably 1 .5 or more, and preferably 7 or less, more preferably 5 or less.
• the liquid cleaning composition is preferably 0.1 g or more, more preferably 0.3 g or more, with respect to the area of 100 cm 2 of the tableware and / or the hard article around the kitchen as the object. More preferably, it is 0.4 g or more, and preferably 5 g or less, more preferably 3 g or less, still more preferably 2 g or less, and it is preferable to apply or spray in a foam state.
• the liquid cleaning composition is preferably contacted with tableware and / or a hard article around the kitchen, preferably 10 seconds or more, more preferably 20 seconds or more, and still more preferably. 30 seconds or more, more preferably 40 seconds or more, still more preferably 50 seconds or more, still more preferably 1 minute or more, and from the same viewpoint, preferably 60 minutes or less, more preferably 30 minutes or less, still more preferably Is left for 20 minutes or less, more preferably 10 minutes or less, still more preferably 5 minutes or less.
• the time when the composition in the foam state first contacts the tableware and / or the hard article around the kitchen may be set as the start of the standing.
• the temperature at the time of leaving is room temperature, for example, 10 degreeC or more and 30 degrees C or less.
• the liquid cleaning composition is brought into contact with a tableware and / or a hard article around the kitchen containing the liquid oil derived from food as a foamed state using a spray means. It is preferable to do so. It is preferable that the foam specific volume of the foam discharged from the spray means is in the above range, and it is more preferable that the foam specific volume immediately and after 1 minute is in the above range.
• a liquid detergent composition used in the present invention is used in a detergent product obtained by filling a container having a sprayer having a foam formation mechanism, and the liquid detergent composition is derived from food in the form of foam. More preferably, it is brought into contact with soiled dishes and / or hard articles around the kitchen containing liquid oil.
• the present invention provides a detergent article with a spray container, wherein the liquid detergent composition used in the present invention is filled in a container having a sprayer having a foam formation mechanism.
• Examples of the container including the sprayer include a manual spray device that does not use a propellant such as a trigger spray container and a pump spray container, and an aerosol that uses a propellant.
• the container having the sprayer is preferably a trigger spray that can be sprayed or applied in the form of foam, and more preferably a trigger spray provided with a foam forming mechanism (foam forming mechanism).
• the trigger type spray having a foam formation mechanism in the cleaning article containing the spray container preferably a liquid passage plate in which several rod-shaped protrusions are installed in a spin element and a circular space portion having a diameter of 4 to 8 mm.
• the spin element is a mechanism that applies a spin to the flow of the liquid substance through the spin element, and finally ejects the liquid from the nozzle, and the detailed structure thereof is disclosed in JP-A-8-332422 and JP-A-8-108102. 4B, FIG. 1 of JP-A-2002-68265, and the like can be referred to.
• the sprayed detergent article is preferably 0.5 mL or more, more preferably 1 mL or more, and preferably 30 mL or less, more preferably in one operation. Spray with 15 mL or less, more preferably 5 mL or less of the composition.
• the liquid passage plate which is another member of the foam formation mechanism, is preferably a circular space portion having a diameter of 5 to 7 mm, preferably having 3 to 8 rod-like protrusions.
• a rectangular bar-shaped protrusion having a width of 0.8 to 1.2 mm and a length of 2 to 4 mm is preferable.
• the area occupied by the rod-shaped protrusions with respect to the space portion excluding the rod-shaped protrusions is preferably 30 area% or more, more preferably 40 area% or more, and preferably 90 area% or less, more preferably 80 area% or less. More preferably, it is 70 area% or less, and by installing such a liquid passage plate, the adhesion and retention of bubbles to the vertical surface becomes good.
• a generally used container can be used as the container for the detergent article containing the spray container.
• polyethylene, polypropylene, or polyethylene terephthalate is obtained as a raw material, and can be manufactured by blow molding or the like.
• the wall thickness of the container may be different from the bottom and side surfaces, and is preferably 0.01 to 2 mm, and the capacity of the container is preferably 100 to 1000 mL.
• the amount of the liquid detergent composition filled in the container is desirably 200 to 500 mL for handling.
• the filling of the liquid is performed leaving a common sense gap.
• the cleaning method of the present invention targets dishes and / or hard articles around the kitchen, preferably dishes.
• Hard articles around the kitchen are articles used around the kitchen, specifically, (1) Refrigerator, cupboard and other food, tableware, cooking utensil storage location, (2) A food cooking place such as a drain, a cooking table, a range hood, a sink, a gas range, and a microwave oven, and (3) a floor or a wall around the storage place or the cooking place. In the present invention, these are referred to as “hard articles around the kitchen” for convenience.
• tableware specifically, (I) so-called tableware such as dishes and bowls, (Ii) Storage containers such as tappers and bottles, (Iii) Cooking utensils such as knives, cutting boards, pans, frying pans, grilled fish, (Iv) Examples include members and utensils that come into contact with foodstuffs such as food processors and cooking appliances such as mixers. In the present invention, these are referred to as “tableware” for convenience.
• the cleaning method of the present invention is preferably intended for articles selected from tableware, storage containers, cooking utensils, and cooking appliances. Further, dishes, bowls, tappers, bottles, kitchen knives, cutting boards, pans, pans, fish More preferably, articles selected from grilled grills, food processors, and mixers are targeted.
• the material of the tableware and / or the hard article around the kitchen targeted by the cleaning method of the present invention includes plastic (including silicone resin), metal, ceramics, wood, and combinations thereof. And the washing
• liquid oil adhering to a hydrophobic material such as plastic is a dirt that is difficult to remove, but in the present invention, it is also excellent against liquid oil adhering to plastic tableware and / or hard articles around the kitchen. Show a good cleaning effect.
• the present invention is suitable as a method for cleaning plastic tableware and / or hard articles around a kitchen.
• the plastic include polyolefin such as polypropylene and polyethylene, polymethacrylate, polycarbonate, ABS resin, polyethylene terephthalate, and the like.
• the liquid detergent composition used in the present invention is directly brought into contact with tableware and / or a hard article around the kitchen in a foam state without being diluted. And since it should just be left in the state which the said composition contacted, the operation
• Liquid oils derived from foods such as food, tableware, cooking utensils storage areas, cooking tables, range hoods, sinks, gas ranges, microwave ovens and other food cooking areas and surrounding kitchens such as floors and walls
• An article having a hard surface with extensive soiling (3) Hazardous items such as knives, peelers, graters, slicers, juicer blades, food processor blades, etc.
• the present invention can also be applied to an article that is difficult to clean using a flexible material such as a sponge, such as an article having a complicated shape.
• the tableware and / or the hard article around the kitchen may be washed without applying external force such as mechanical force, and then, if necessary, rubbed.
• the liquid detergent composition in the form of foam is applied to tableware and / or a hard article around the kitchen and left as it is, so that the composition is applied to the tableware and / or the hard article around the kitchen. Can be kept for a long time.
• the cleaning method of the present invention comprises a step of rinsing the tableware and / or the hard article around the kitchen with the liquid detergent composition, preferably with the tableware and / or the liquid detergent composition contacted.
• the process includes a step of rinsing the hard article around the kitchen with water after being left standing.
• the mass ratio of the content of the component (a) to the content of the component (a) / (b) is 0.5 or more and 10 or less, preferably 8 or less, more preferably 5 or less, ⁇ 1 > Liquid detergent composition for hard articles around tableware and / or kitchen.
• the HLB of the component (a) is preferably 3 or more, more preferably 4 or more, still more preferably 5 or more, and preferably 10 or less, more preferably 9.5 or less, still more preferably 9 or less, ⁇ 1 > Or ⁇ 2>
• component is (A1) An average of 1 mole of an alkylene oxide having 2 or 3 carbon atoms to a fatty alcohol having 8 to 18 carbon atoms or a lower alcohol ester of a fatty acid having 8 to 18 carbon atoms (the lower alcohol has 1 to 3 carbon atoms) A nonionic surfactant added at 5 mol or less, a polyoxyalkylene type nonionic surfactant having an HLB of 10.5 or less (hereinafter referred to as component (a1)), (A2) A polyhydric alcohol ester type nonionic interface comprising an ester of a polyhydric alcohol having 2 to 10 hydroxy groups and a fatty acid having 8 to 18 carbon atoms and having an HLB of 10.5 or less Activator [hereinafter referred to as component (a2)], (A3) Mono- or dialkanolamide having an alkanoyl group having 8 to 18 carbon atoms (the alkanol group has 2 or 3 carbon atoms) or an alkylene oxide
• a nonionic surfactant having 2 or 3 carbon atoms of an amine having a hydrogen group and having an HLB of 10.5 or less (hereinafter referred to as component (a4))
• component (a4) One or more nonionic surfactants selected from ⁇ 1>- ⁇ 3> The liquid cleaning composition for tableware and / or hard articles around a kitchen.
• the liquid cleaning composition for tableware and / or hard articles around a kitchen according to ⁇ 4> which contains, as component (a), one or more nonionic surfactants selected from component (a1) and component (a2) Stuff.
• ⁇ 6> (A1) The tableware according to ⁇ 4> or ⁇ 5>, wherein the fatty alcohol or fatty acid constituting the component preferably has 10 or more carbon atoms, and preferably 16 or less, more preferably 14 or less.
• the polyoxyalkylene group of the component (a1) has an average added mole number of preferably 2 or more and preferably 4 or less, and the tableware and / or kitchen surroundings according to any one of ⁇ 4> to ⁇ 6> A liquid detergent composition for hard articles.
• ⁇ 8> The tableware and / or kitchen according to any one of ⁇ 4> to ⁇ 7>, wherein the alkylene oxide of component (a1) is an alkylene oxide having 2 carbon atoms and / or an alkylene oxide having 3 carbon atoms, further ethylene oxide.
• Polyoxyethylene alkyl ether type nonionic surfactant in which ethylene oxide is added to alcohol in an average of 1 mol to 4 mol, and non-oxide in which ethylene oxide is added in an average of 2 mol to 5 mol in methyl esters of fatty acids having 10 to 14 carbon atoms The liquid cleaning composition for tableware and / or a hard article around a kitchen according to any one of ⁇ 4> to ⁇ 8>, which is a nonionic surfactant selected from ionic surfactants.
• the number of hydroxy groups of the polyhydric alcohol constituting the component (a2) is preferably 3 or more, and preferably 6 or less, the tableware and / or kitchen surroundings according to any one of ⁇ 4> to ⁇ 9>
• a liquid detergent composition for hard articles is preferably 3 or more, and preferably 6 or less, the tableware and / or kitchen surroundings according to any one of ⁇ 4> to ⁇ 9>.
• the polyhydric alcohol constituting the component (a2) is a polyhydric alcohol selected from glycerin, diglycerin, trimethylolpropane, pentaerythritol, and sorbitan.
• the number of carbon atoms of the fatty acid constituting the component is preferably 10 or more and 18 or less, preferably 14 or less.
• the component (a2) is a polyhydric alcohol ester type nonionic surfactant selected from glycerin mono or dilaurate, glycerin mono or distearate, trimethylolpropane mono or dilaurate, pentaerythritol mono or dilaurate, and sorbitan monolaurate
• the liquid detergent composition for a tableware and / or hard article around a kitchen according to any one of ⁇ 4> to ⁇ 12>.
• the component (a) contains at least one nonionic surfactant selected from the components (a1) to (a4), and the component (a) is selected from the components (a1) to (a4).
• the ratio of the nonionic surfactant of the species or more is 30% by mass or more, further 60% by mass or more, further 90% by mass or more, and 100% by mass or less, or 100% by mass, ⁇ 4> to ⁇ 13>
• the amine oxide type surfactant as the component is a compound of the following general formula (b1), and the liquid cleaner for tableware and / or hard articles around the kitchen according to any one of ⁇ 1> to ⁇ 14> Composition.
• R 1b represents a hydrocarbon group having 7 to 22 carbon atoms, preferably an alkyl group or an alkenyl group, more preferably an alkyl group, and R 2b and R 3b are the same or different and have 1 or more carbon atoms. 3 or less alkyl groups are shown.
• D represents an —NHC ( ⁇ O) — group or a —C ( ⁇ O) NH— group
• E represents an alkylene group having 1 to 5 carbon atoms.
• the (b) component amphoteric surfactant is one or more surfactants selected from betaine-type surfactants, and further one or more amphoteric surfactants selected from sulfobetaine and carbobetaine.
• the sulfobetaine is an N-alkyl-N, N-dimethyl-N-sulfopropylammonium sulfobetaine having an alkyl group of preferably 10 or more, preferably 18 or less, more preferably 14 or less, and the alkyl group has a carbon number of Preferably, the number of carbon atoms of the N-alkyl-N, N-dimethyl-N- (2-hydroxysulfopropyl) ammonium sulfobetaine, alkanoyl group is preferably 10 or more, preferably 10 or less, preferably 18 or less, more preferably 14 or less, Preferably, the number of carbon atoms in the N-alkanoylaminopropyl-N, N-dimethyl-N-sulfopropylammonium sulfobetaine of 18 or less, more preferably 14 or less, and the alkanoyl group is preferably 10 or more, preferably 18 or less, more
• Carbobetaine is an N-alkyl-N, N-dimethyl-N-carboxymethylammonium betaine having an alkyl group of preferably 10 or more, preferably 18 or less, more preferably 14 or less, and the following general formula (b2)
• R 4b represents an alkyl group or alkenyl group having 7 to 21 carbon atoms
• R 5b represents a propylene group
• R 6b and R 7b each independently represents an alkyl group having 1 to 3 carbon atoms. Indicates. ]
• the nonionic surfactant having an HLB of 11 or more is a polyoxyethylene and / or polyoxypropylene alkyl ether type nonionic surfactant, and the alkyl group preferably has 8 or more carbon atoms, And it is preferably 18 or less, more preferably 14 or less, and the number of added moles of ethylene oxide and / or propylene oxide is preferably 5 or more, more preferably 6 or more, and preferably 10 or less, more preferably 8 or less.
• the liquid cleaning composition for tableware and / or hard articles around a kitchen according to any one of ⁇ 1> to ⁇ 18>, which is a polyoxyethylene and / or polyoxypropylene alkyl ether type nonionic surfactant.
• ⁇ 20> (B) The tableware and / or kitchen according to any one of ⁇ 1> to ⁇ 19>, wherein the component is one or more surfactants selected from sulfobetaines and polyoxyethylene alkyl ether type nonionic surfactants Liquid cleaning composition for surrounding hard articles.
• the component is one or more surfactants selected from sulfobetaines and polyoxyethylene alkyl ether type nonionic surfactants Liquid cleaning composition for surrounding hard articles.
• ⁇ 22> Liquid cleaning for tableware and / or hard articles around a kitchen according to any one of ⁇ 1> to ⁇ 21>, wherein the component is an organic solvent selected from monohydric alcohols, polyhydric alcohols, and glycol ethers Agent composition.
• the component is an organic solvent selected from monohydric alcohols, polyhydric alcohols, and glycol ethers having 2 or more carbon atoms, 3 or more carbon atoms, 10 or less carbon atoms, and 8 or less carbon atoms.
• the liquid detergent composition for tableware and / or a hard article around a kitchen.
• the logPow of the component (c) is preferably 0.2 or more, more preferably 0.3 or more, and preferably 1.2 or less, more preferably 1 or less, any one of ⁇ 1> to ⁇ 23> 2.
• the component is (c-1) a monohydric alcohol having 1 to 3 carbon atoms, (c-2) a polyhydric alcohol having 2 to 4 carbon atoms, and (c-3) an alkylene glycol unit having carbon atoms.
• the liquid detergent composition for hard dishes around tableware and / or kitchens according to any one of ⁇ 1> to ⁇ 25>, which is an organic solvent selected from monophenyl or monobenzyl ether.
• Component (c) contains at least one selected from (c-4), and component (c) contains at least one selected from diethylene glycol monobutyl ether and triethylene glycol monobutyl ether, and further component (c) As a liquid cleaning composition for tableware and / or a hard article around a kitchen, according to ⁇ 26>, containing diethylene glycol monobutyl ether.
• the component (a) is preferably 0.5% by mass or more, more preferably 1% by mass or more, further preferably 2% by mass or more, and preferably 10% by mass or less, more preferably 8% by mass or less, still more preferably.
• the component (b) is preferably 0.25% by mass or more, more preferably 1% by mass or more, further preferably 2% by mass or more, and preferably 10% by mass or less, more preferably 8% by mass or less, still more preferably.
• the component (c) is preferably 0.5% by mass or more, more preferably 1% by mass or more, further preferably 4% by mass or more, and preferably 30% by mass or less, more preferably 20% by mass or less, still more preferably.
• the proportion of component (a) in the total surfactant is 30% by mass or more, preferably 30.0% by mass or more, more preferably 35% by mass or more, still more preferably 40% by mass or more, and still more preferably 50% by mass. % Or more, more preferably 55% by mass or more, still more preferably 60% by mass or more, and 85% by mass or less, preferably 75% by mass or less, more preferably 70% by mass or less, ⁇ 1> to ⁇ 30>
• the total proportion of the component (a) and the component (b) in the total surfactant is preferably 50% by mass or more, more preferably 60% by mass or more, still more preferably 70% by mass or more, and still more preferably 80% by mass. %, And preferably 100% by mass or less, or 100% by mass, the liquid detergent composition for tableware and / or hard articles around kitchens according to any one of ⁇ 1> to ⁇ 31>.
• the mass ratio of (c) / (a) is preferably 1.0 or more, and preferably 8 or less, more preferably 5 or less, still more preferably 4 or less, even more preferably 3 or less, ⁇ 1>
• ⁇ 34> (C) / (b), which is the mass ratio of the content of the component (c) to the content of the component (b), is preferably 0.5 or more, more preferably 1 or more, still more preferably 1.2 or more, Still more preferably 1.5 or more, and preferably 7 or less, more preferably 5 or less, the liquid for tableware and / or hard articles around the kitchen according to any one of ⁇ 1> to ⁇ 33> Cleaning composition.
• the total surfactant content is preferably 0.5% by mass or more, more preferably 1% by mass or more, still more preferably 3% by mass or more, and preferably 20% by mass or less, more preferably 15% by mass or less. More preferably, the liquid cleaning composition for tableware and / or hard articles around a kitchen according to any one of ⁇ 1> to ⁇ 34>, which is 10% by mass or less.
• Water is preferably at least 30% by mass, more preferably at least 50% by mass, more preferably at least 60% by mass, even more preferably at least 70% by mass, even more preferably at least 80% by mass, even more preferably at least 90% by mass.
• the (b) component] is preferably 0.5 or less, more preferably 0.3 or less, still more preferably 0.1 or less, and the tableware and / or kitchen according to any one of ⁇ 1> to ⁇ 36> Liquid cleaning composition for surrounding hard articles.
• the component (e) is a solvent selected from paraffinic solvents and terpenoid solvents, and further selected from normal paraffins having 10 to 20 carbon atoms, isoparaffins having 10 to 20 carbon atoms, limonene, terpenes, and pinene.
• the mass ratio of the content of the organic solvent (hereinafter referred to as the “(e1) component”) having a log Pow of more than 1.5 relative to the content of the component (e1) / (c) is 0.5 or less.
• the liquid detergent composition for tableware and / or hard articles around a kitchen according to any one of ⁇ 1> to ⁇ 38>, further 0.3 or less, further 0.1 or less, and further 0.
• the pH at 20 ° C. is preferably 2 or more, more preferably 4 or more, more preferably 5 or more, and preferably 10 or less, more preferably 9 or less, even more preferably 8 or less, ⁇ 1> to ⁇ 39 >
• the viscosity at 20 ° C. is preferably 15 mPa ⁇ s or less, more preferably 10 mPa ⁇ s or less, further preferably 7 mPa ⁇ s or less, and still more preferably 5 mPa ⁇ s or less, any one of ⁇ 1> to ⁇ 40> 2.
• ⁇ 42> The tableware according to any one of ⁇ 1> to ⁇ 41>, wherein the viscosity at 20 ° C. is preferably 0.5 mPa ⁇ s or more, more preferably 1 mPa ⁇ s or more, and / or liquid cleaning for hard articles around the kitchen. Agent composition.
• Foam preferably 30 ml / g or less, more preferably 20 ml / g or less, further preferably 10 ml / g or less, even more preferably 7 ml / g or less, and preferably 1 ml / g or more, more preferably 2 ml
• the tableware and / or the hard article around the kitchen according to any one of ⁇ 1> to ⁇ 42>, which is applied to the tableware and / or the hard article around the kitchen with a foam having a foam specific volume in the range of / g or more.
• Liquid detergent composition preferably 30 ml / g or less, more preferably 20 ml / g or less, further preferably 10 ml / g or less, even more preferably 7 ml / g or less, and preferably 1 ml / g or more, more preferably 2 ml
• the liquid detergent composition for tableware and / or a hard article around a kitchen has a foam specific volume in the range of 2 ml / g or more.
• liquid detergent composition for a tableware and / or hard article around a kitchen according to any one of ⁇ 1> to ⁇ 42>, which is applied to a hard article around a kitchen.
• the above-mentioned tableware and / or liquid detergent composition for hard articles around the kitchen is a tableware to which soil containing liquid oil derived from foods is attached in a foam state with a foam specific volume of 1 ml / g to 100 ml / g and The method for cleaning the tableware and / or the hard article around the kitchen according to ⁇ 47>, wherein the hard article is brought into contact with the hard article around the kitchen.
• the liquid detergent composition is preferably 0.1 g or more, more preferably 0.3 g or more, and still more preferably 0.4 g with respect to the area of 100 cm 2 of the tableware and / or the hard article around the kitchen as the object. Above, and preferably 5 g or less, more preferably 3 g or less, more preferably 2 g or less, and contact or spray in a foamed state, any one of ⁇ 47> to ⁇ 51> Cleaning method of tableware and / or hard article around kitchen.
• ⁇ 53> After contacting the liquid detergent composition with tableware and / or hard articles around the kitchen, preferably 10 seconds or more, more preferably 20 seconds or more, still more preferably 30 seconds or more, even more preferably 40 seconds or more, and even more. Preferably it is 50 seconds or more, more preferably 1 minute or more, and preferably 60 minutes or less, more preferably 30 minutes or less, still more preferably 20 minutes or less, even more preferably 10 minutes or less, and even more preferably 5 minutes.
• the method for cleaning the tableware and / or hard article around the kitchen according to any one of ⁇ 47> to ⁇ 52>, which is left to stand.
• Liquid cleaning compositions shown in Tables 1 to 4 were prepared using the following blending components, and the following items were evaluated. The results are shown in Tables 1 to 4.
• the liquid detergent compositions shown in Tables 1 to 4 were adjusted to pH 7 (20 ° C.) with citric acid and a 48% NaOH aqueous solution.
• the mass percentages of the blended components are all numerical values based on the effective content.
• surface is total content of (a) component, (b) component, and (d) component.
• the compositions in Tables 1 to 4 are liquid detergent compositions for hard articles around tableware and / or kitchens.
• component (a) component a-1 polyoxyethylene alkyl ether, alkyl group carbon number 13, ethylene oxide average addition mole number 3 (HLB 8.6), Softanol 33, Nippon Shokubai Co., Ltd.
• a-2 sorbitan Monolaurate (HLB 8.6), Emazole L-10V, Kao Corporation
• a-3 Glycerol monolaurate (HLB 5.3), LKT Laboratories, Inc.
• A-4 Palm kernel oil fatty acid diethanolamide (HLB5.5, HLB is a value determined by the above experimental method)
• Aminone PK-02S, Kao Corporation a-5 N-lauryl-N, N- Diethanolamine (HLB 6.3, HLB is a value determined by the above experimental method)
• Component (c) (Comparative compound of component (c)) C'-1: ethylene glycol (logPow -1.4)
• D-1 sodium polyoxyethylene alkyl ether sulfate, alkyl group having 12 to 16 carbon atoms, average number of moles of ethylene oxide added 4.0 (product name “ES-4K”, manufactured by Kao Corporation)
• Viscosity TOKIMEC INC The rotor type no. One equipped with one rotor was prepared.
• the liquid detergent composition shown in the table was filled in a beaker for viscosity measurement, and the temperature was sufficiently adjusted in a constant temperature water bath at 20 ° C.
• the beaker containing the composition was set in a viscometer, and the value after 60 seconds measured at a rotor rotational speed of 60 r / min was taken as the viscosity of the composition.
• the liquid detergent compositions of the examples were in contact with each other in the form of foam having a foam specific volume of 2.6 to 48.7 mL / g.
• the foam specific volume here considered that the foam specific volume measured by the said method (immediately) was the foam specific volume of the foam which contacted.
• the conditions of rinsing with running water were: the temperature of tap water was 25 ° C., the flow rate was about 4 L / min, and the diameter of the opening of the faucet was about 15 mm.
• Cleaning rate (%) ⁇ (y) ⁇ (z) ⁇ / ⁇ (y) ⁇ (x) ⁇ ⁇ 100

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