WO2018180513A1 - 染毛料組成物 - Google Patents
染毛料組成物 Download PDFInfo
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- WO2018180513A1 WO2018180513A1 PCT/JP2018/010097 JP2018010097W WO2018180513A1 WO 2018180513 A1 WO2018180513 A1 WO 2018180513A1 JP 2018010097 W JP2018010097 W JP 2018010097W WO 2018180513 A1 WO2018180513 A1 WO 2018180513A1
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- dye composition
- hair dye
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Definitions
- the present invention relates to a hair dye composition.
- This application claims the priority of Japanese Patent Application No. 2017-066641 for which it applied to Japan on March 29, 2017, and uses the content here.
- Patent Document 2 discloses a technique for providing a hair dye composition that is excellent in hair dyeing power to hair and has little background stain by combining an acid dye, an ester compound, and an ester hydrolase.
- Patent Document 3 contains a basic dye and glyceryl caprylate, and contains 0.1 to 20 parts by mass of glyceryl caprylate with respect to 0.3 parts by mass of the basic dye. Is disclosed.
- any of the hair dyes disclosed in the patent literature is not sufficiently studied for thickening the nonionic blue dye.
- Patent Document 2 discloses an acid dye and the like
- Patent Document 3 discloses a basic dye, but none of these documents focus on a nonionic blue dye. Also, it is not a study of deep dyeing. For this reason, the present condition is that the hair dye composition which is excellent in the deep dyeing effect of a nonionic blue dye is desired.
- an object of the present invention is to provide a hair dye composition that is excellent in the deep dyeing effect of a nonionic blue dye.
- this invention provides the hair dye composition containing the following component A and the following component B.
- Component A HC Blue 2
- Component B Glyceryl caprate
- the mass ratio [component B / component A] of the content of the component B to the content of the component A is 0.1 or more.
- the content of the component A is preferably 0.1 to 3.0% by mass, and the content of the component B is preferably 0.01 to 3.0% by mass.
- the hair dye composition is preferably a color rinse or a color treatment.
- the hair dye composition of the present invention is excellent in the deep dyeing effect of the nonionic blue dye. And hair can be dyed deeply by using the hair dye composition of this invention. For this reason, when used as a color shampoo, color rinse or color treatment, the hair can be dyed deeply with a small number of uses and a short standing time, and the hair dyeing property is excellent.
- the result of the concentration dyeing experiment (lightness evaluation) of the aqueous solution system by the combination of HC Blue 2 and various additives is shown.
- the result of the concentration dyeing experiment (lightness evaluation) of the aqueous solution system by the combination of HC Blue 2 and various additives is shown.
- the result of the cream type darkening experiment (lightness evaluation) by the combination of HC Blue 2 and glyceryl caprate is shown.
- the result of the thickening experiment (lightness evaluation) of the aqueous solution system by the combination of HC Blue 2 and glyceryl caprate is shown.
- the result of the color shampoo darkening experiment (lightness evaluation) by the combination of HC Blue 2 and glyceryl caprate is shown.
- the result of the thickening experiment (lightness evaluation) of the color rinse (or color treatment) by the combination of HC Blue 2 and glyceryl caprate is shown.
- the result of the thickening experiment (lightness evaluation) of an aqueous solution system in which glyceryl caprate is combined with HC Blue 2 plus basic blue 75 is shown.
- the hair dye composition of the present invention is a composition used as a hair dye.
- the hair dye include color rinse, color treatment, hair manicure, and color shampoo.
- the hair dye composition of the present invention is a color rinse, a color treatment, or a color shampoo from the viewpoint that hair can be easily dyed and has the advantage that the treatment time per time is short. It is preferable.
- the hair dye composition of the present invention is excellent in the effect of deep dyeing even in the form of color rinse or color treatment or color shampoo.
- the hair dye composition of the present invention contains at least HC Blue 2 and glyceryl caprate.
- the “HC blue 2” may be referred to as “component A”
- the “glyceryl caprate” may be referred to as “component B”.
- the hair dye composition of the present invention may further contain components other than component A and component B, which are essential components, depending on the application.
- the hair dye composition of the present invention is further selected from the group consisting of a cationic surfactant, a cationic polymer, and a silicone oil. It is preferable to include one or more components.
- the hair dye composition of the present invention may further contain components (other components) other than those listed above.
- components other components
- One or more of the above components for example, component A; component B; one or more components selected from the group consisting of a cationic surfactant, a cationic polymer, and silicone oil; Or two or more of them may be used.
- each component (component A; component B; one or more components selected from the group consisting of a cationic surfactant, a cationic polymer, and silicone oil) contained in the hair dye composition of the present invention;
- the content of (other components) can be appropriately selected from the range described so that the total content in the hair dye composition is 100% by mass or less.
- component A and component B which are essential components of the hair dye composition of the present invention, will be described.
- Component A is HC Blue 2.
- the HC Blue 2 is an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 16th edition, Volume 2, 2016, p. 1494): HC BLUE NO. 2,2 ′-[[4-[(2-hydroxyethyl) amino] -3-nitrophenyl] imino] bisethanol: 2,2 ′-[[4-[(2 -Hydroxyethyl) amino] -3-nitrophenyl] imino] bisethanol.
- HC Blue 2 can be a commercially available product.
- a trade name “COLOREX HCB2” manufactured by Telka Co., Ltd. may be mentioned.
- Component B is glyceryl caprate, and is a component represented by the following formula (1).
- Component B is a compound represented by the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 16th edition, Volume 1, 2016, p. 1422): GLYCERYL CAPRATE, 2,3-dihydroxypropyl decanoate: 2, 3-Dihydroxypropylate decanoate.
- Component B can be a commercially available product.
- Examples of commercially available products of Component B include “Sunsoft 760-C” manufactured by Taiyo Kagaku Co., Ltd.
- the mass ratio [component B / component A] of the content of component B to the content of component A in the hair dye composition of the present invention is not particularly limited, but is 0.1 or more from the viewpoint of the deep dyeing effect. Preferably, it is 0.2 or more, more preferably 0.4 or more.
- the content of Component A in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 0.1 to 3.0% by mass, more preferably 0.2 to 1.5% by mass. More preferably 0.2 to 1.0% by mass. It is preferable for the content to be 0.1% by mass or more because hair dyeing properties are improved. It is preferable for the content to be 3.0% by mass or less because safety and formulation stability are further improved. Moreover, since the color transfer to the towel, clothes, etc. by the dye which melt
- the content of component B in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 0.01 to 3.0% by mass, more preferably 0.03 to 2.0% by mass. is there.
- the content is 0.01% by mass or more, the deep dyeing effect is further improved, which is preferable.
- the content is 3.0% by mass or less, safety is further improved, which is preferable.
- the hair dye composition of the present invention may contain an ester compound (referred to as “other ester compound”) in which the fatty acid moiety other than Component B has 12 or less carbon atoms.
- ester compound referred to as “other ester compound”
- examples of the other ester compounds include caprylic acid ester, cetyl 2-ethylhexanoate, and isononyl isononanoate.
- the hair dye composition of the present invention may contain other nonionic dyes or basic dyes in addition to component A, if necessary.
- non-ionic dyes such as HC yellow 2, HC yellow 4, HC yellow 5, HC red 1, HC red 3, HC orange 1; basic blue 75, basic blue 99, basic blue 124, basic yellow 57, basic yellow 87, basic brown 16, basic brown 17, basic red 51, basic red 76, basic orange 31, HC blue 16, and the like within the range where the object of the present invention is not hindered Can be appropriately blended.
- the deep dyeing effect of the hair dye composition of the present invention can be expressed using a lightness difference ( ⁇ L * ).
- ⁇ L * a lightness difference
- 1 g of the hair dye composition is applied to a yak hair bundle, adjusted to the whole hair bundle for 1 minute, allowed to stand at 30 ° C. and 70% RH for 10 minutes, then washed off from the hair bundle and dried.
- the brightness is measured using the evaluation hair bundle.
- the lightness when dyeing with the hair dye composition (L * value after darkening) is the lightness when dyeing with a hair dye composition not containing glyceryl caprate (standard L *)
- standard L * the higher the absolute value of the lightness difference ( ⁇ L * ), the higher the dark dyeing effect.
- the lightness difference ( ⁇ L * ) of the hair dye composition of the present invention is not particularly limited, but is preferably ⁇ 0.5 or less, more preferably ⁇ 1.0 or less, and further preferably ⁇ 2.0 or less. is there.
- the lightness difference ( ⁇ L * ) is a lightness difference in the L * a * b color system, and can be measured, for example, using a spectrocolorimeter under the conditions described in the examples.
- the brightness difference ( ⁇ L * ) is calculated by (L * value after darkening) ⁇ (Reference L * value).
- the hair dye composition of the present invention is a color rinse or a color treatment
- it is selected from the group consisting of a cationic surfactant, a cationic polymer, and a silicone oil from the viewpoint of improving the effect of reducing the squeaky feeling when washed with water. It is preferable to contain the above components.
- Examples of the cationic surfactant include monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, trialkyl quaternary ammonium salts, monoalkyl ether quaternary ammonium salts, alkylamines, and fatty acid amidoamines. Can be mentioned.
- Examples of the monoalkyl quaternary ammonium salt include lauryltrimethylammonium chloride, myristyltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, alkyl (16,18) trimethylammonium chloride, Examples thereof include alkyl (20-22) trimethylammonium chloride, stearyldimethylbenzylammonium chloride, myristyldimethylbenzylammonium chloride, tri (polyoxyethylene) stearylammonium chloride, and di (polyoxyethylene) oleylmethylammonium chloride.
- fatty acid amide amine examples include myristic acid dimethylaminoethylamide, myristic acid dimethylaminopropylamide, myristic acid diethylaminoethylamide, myristic acid diethylaminopropylamide, palmitic acid dimethylaminoethylamide, palmitic acid dimethylaminopropylamide, and palmitic acid.
- the fatty acid amidoamine is preferably used as a salt with an organic acid and / or an inorganic acid.
- the organic acid include lactic acid, malic acid, citric acid, tartaric acid, and acetic acid.
- the inorganic acid include phosphoric acid, hydrochloric acid, sulfuric acid and the like. Of these, lactic acid and citric acid are preferred.
- the content of the organic acid and the inorganic acid is not particularly limited as long as it can neutralize the fatty acid amidoamine to be blended.
- cationic surfactants monoalkyl quaternary ammonium salts and fatty acid amidoamines are preferable, and stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, alkyl chloride are more preferable. (16,18) trimethylammonium, alkyl (20-22) trimethylammonium chloride, stearic acid dimethylaminopropylamide.
- cationic polymer examples include quaternary nitrogen-containing cellulose ether derivatives such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl chloride chloride; O- [2-hydroxy chloride] Quaternary nitrogen-containing guar gum derivatives such as -3- (trimethylammonio) propyl] guar gum; cationic starch, diallyl quaternary ammonium salt polymer, diallyl quaternary ammonium salt / acrylamide copolymer, quaternization Examples thereof include polyvinylpyrrolidone derivatives, polyglycol polyamine condensates, adipic acid / dimethylaminohydroxypropylethylenetriamine copolymer, and cationized dextran.
- quaternary nitrogen-containing cellulose ether derivatives such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl chloride chloride
- O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride, diallyl quaternary ammonium salt polymer, diallyl quaternary ammonium salt / acrylamide copolymer are preferable, and more preferable.
- Polydimethylmethylenepiperidinium chloride is preferable, and more preferable.
- silicone oil examples include, for example, methyl polysiloxane, highly polymerized methyl polysiloxane having an average degree of polymerization of 650 to 7000, chain silicone such as methyl phenyl polysiloxane, methyl hydrogen polysiloxane, and dimethiconol; methyl cyclopolysiloxane, Cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane; aminopropylmethylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylmethyl Amino-modified silicone such as siloxane / dimethylsiloxane copolymer, carboxy-modified silicone, fatty acid-modified silicone, alcohol-modified
- the hair dye composition of the present invention contains one or more components selected from the group consisting of a cationic surfactant, a cationic polymer, and a silicone oil
- the cationic composition in 100% by mass of the hair dye composition of the present invention.
- the content of one or more components selected from the group consisting of a surfactant, a cationic polymer, and a silicone oil is not particularly limited, but is preferably 0.5 to 10.0% by mass, more preferably 1.0 to 5.0% by mass. It is preferable for the content to be 0.5% by mass or more since the squeaky feeling is further reduced during washing with water. When the content exceeds 10.0% by mass, the components are accumulated in the hair by continuous use, and the hair may become stiff.
- the content of one or more components selected from the group consisting of the above-mentioned cationic surfactant, cationic polymer, and silicone oil is the cationic surfactant, cationic polymer, and silicone in the hair dye composition of the present invention. It is the total content of all the one or more components selected from the group consisting of oil.
- the hair dye composition of the present invention preferably contains a polyhydric alcohol.
- the polyhydric alcohol include ethylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, glucose, maltose, maltitol, sucrose, and mannitol. Sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and the like.
- the content of the polyhydric alcohol in 100% by mass of the hair dye composition of the present invention is not particularly limited, but it is 0 from the viewpoint of the solubility of the dye. 0.5 to 10.0% by mass is preferable, and 1.0 to 5.0% by mass is more preferable.
- the content of the polyhydric alcohol is the total content of all the polyhydric alcohols in the hair dye composition of the present invention.
- the hair dye composition of the present invention preferably contains a higher alcohol.
- the higher alcohol include alcohols having 16 to 22 carbon atoms, such as cetyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecanol, oleyl alcohol, and behenyl alcohol.
- the content of the higher alcohol in 100% by mass of the hair dye composition of the present invention is not particularly limited, but from the viewpoint of stability over time, 1.
- the content is preferably 0 to 10.0% by mass, more preferably 3.0 to 8.0% by mass.
- the content of the higher alcohol is the total content of all the higher alcohols in the hair dye composition of the present invention.
- the hair dye composition of the present invention preferably contains a hydrocarbon oil.
- the hydrocarbon oil include ⁇ -olefin oligomer, light isoparaffin, light liquid isoparaffin, squalane, synthetic squalane, vegetable squalane, liquid isoparaffin, liquid paraffin, and the like.
- the hair dye composition of the present invention contains a hydrocarbon oil
- the content of the hydrocarbon oil in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is familiar to the hair dye composition at the time of application. From the viewpoint of ease, 0.5 to 10.0% by mass is preferable, and 1.0 to 5.0% by mass is more preferable.
- the content of the hydrocarbon oil is a total content of all the hydrocarbon oils in the hair dye composition of the present invention.
- the hair dye composition of the present invention may contain a nonionic surfactant (nonionic surfactant) from the viewpoint of stability over time.
- a nonionic surfactant include polyoxyethylene fatty acid, glycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, polyoxy Examples include ethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyglycerin alkyl ether, polyoxyethylene (cured) castor oil, and fatty acid alkylolamide.
- the content of the nonionic surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is stable over time. In view of the above, 0.5 to 10.0% by mass is preferable, and 1.0 to 5.0% by mass is more preferable.
- the content of the nonionic surfactant is the total content of all the nonionic surfactants in the hair dye composition of the present invention.
- the hair dye composition of the present invention contains water.
- the water is not particularly limited, but purified water is preferable.
- the content of water in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 50.0-90.0% by mass, more preferably 60.0-80.0% by mass. .
- the hair dye composition of the present invention when the hair dye composition of the present invention is a color rinse or a color treatment, the hair dye composition of the present invention includes a refreshing agent such as l-menthol, 1,8-cineole and camphor; a preservative such as phenoxyethanol; an olive oil and a macadamia nut Oils, vegetable oils such as argan oil; hygroscopic agents such as silica; hyaluronic acid or derivatives thereof, collagen or derivatives thereof, amino acids or derivatives thereof, antioxidants, sequestering agents, vitamins, animal and plant extracts, pearling agents, coloring An agent, a fragrance
- a refreshing agent such as l-menthol, 1,8-cineole and camphor
- a preservative such as phenoxyethanol
- an olive oil and a macadamia nut Oils vegetable oils such as argan oil
- hygroscopic agents such as silica
- the hair dye composition of the present invention is a color shampoo
- the hair dye composition of the present invention is a color shampoo
- the hair dye composition of the present invention is an anionic surfactant (anionic surfactant), a cationic surfactant, a nonionic interface from the viewpoint of detergency.
- 1 or more surfactants (at least 1 surfactant) chosen from the group which consists of an active agent and an amphoteric surfactant are included.
- nonionic surfactants and / or amphoteric surfactants are preferable from the viewpoint of improving the washability while maintaining dyeability.
- the content of the surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited, but from the viewpoint of dyeability and detergency,
- the content is preferably 1.0 to 20.0% by mass, more preferably 5.0 to 15.0% by mass.
- the content of the surfactant is the total content of all the surfactants in the hair dye composition of the present invention.
- anionic surfactant examples include sodium sulfate lauryl sulfate, triethanolamine lauryl sulfate, sodium myristyl sulfate, sodium stearyl sulfate, sodium oleyl sulfate and sodium cetyl sulfate; polyoxyethylene lauryl ether sulfate sodium; Polyoxyethylene alkyl ether sulfates such as sodium polyoxyethylene myristyl sulfate; ⁇ -olefin sulfonates such as sodium tetradecenesulfonate; sodium myristoyl methyl taurate, sodium palmitoyl methyl taurine, sodium stearoyl methyl taurine, oleoyl methyl N-acylmethyl taurine salts such as sodium taurine and palm oil fatty acid methyl taurine sodium; Sulfosuccinic acid alkyl salts such as dioctyl sodium succinate and disodium lauryl sulfo
- anionic surfactants derived from amino acids such as N-acyl-N-methyl- ⁇ -alanine salt and N-acyl glutamate are preferred from the viewpoint of dyeability.
- the content of the anionic surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited. In view of the above, 0.5 to 5.0% by mass is preferable, and 0.5 to 2.0% by mass is more preferable.
- the content of the anionic surfactant is the total content of all anionic surfactants in the hair dye composition of the present invention.
- amphoteric surfactant examples include alkylamide betaine type amphoteric surfactants such as lauric acid amidopropyl betaine and coconut oil fatty acid amidopropyl betaine; alkylglycine salt, carboxymethylglycine salt, N-acylaminoethyl-N- Glycine-type amphoteric surfactants such as 2-hydroxyethylglycine salt; Aminopropionic acid-type amphoteric surfactants such as alkylaminopropionate and alkyliminodipropionate; alkyldimethylaminoacetic acid betaine, alkylamidopropyldimethylaminoacetic acid Aminoacetic acid betaine-type amphoteric surfactants such as betaine and alkyldihydroxyethylaminoacetic acid betaine; N-alkyl-N, N-dimethylammonium-N-propylsulfonate, N-alkyl-N, N-di
- alkylamide betaine type amphoteric surfactants are preferable from the viewpoint of detergency.
- the content of the amphoteric surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited, but from the viewpoint of detergency, 1 It is preferably 0.0 to 20.0% by mass, more preferably 5.0 to 15.0% by mass.
- the content of the amphoteric surfactant is the total content of all amphoteric surfactants in the hair dye composition of the present invention.
- nonionic surfactant examples include nonionic surfactants exemplified as optional components when the hair dye composition of the present invention is a color rinse or a color treatment.
- fatty acid alkylolamide is preferable from the viewpoint of imparting viscosity.
- the content of the nonionic surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited, but it is a viewpoint of imparting viscosity. Therefore, 0.5 to 10.0% by mass is preferable, and 1.0 to 5.0% by mass is more preferable.
- the content of the nonionic surfactant is the total content of all the nonionic surfactants in the hair dye composition of the present invention.
- the cationic surfactant examples include the above-described cationic surfactants. Of these, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, alkyl (16,18) trimethylammonium chloride, and alkyl (20-22) trimethylammonium chloride are preferable from the viewpoint of improving the texture of the hair after use.
- the hair dye composition of the present invention contains a cationic surfactant
- the content of the cationic surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited. From the viewpoint of texture, it is preferably 0.1 to 5.0% by mass, more preferably 0.5 to 3.0% by mass.
- the content of the cationic surfactant is the total content of all the cationic surfactants in the hair dye composition of the present invention.
- the hair dye composition of the present invention contains water.
- the water is not particularly limited, but purified water is preferable.
- the content of water in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 50.0-90.0% by mass, more preferably 60.0-80.0% by mass. .
- the hair dye composition of the present invention when the hair dye composition of the present invention is a color shampoo, the hair dye composition of the present invention includes a refreshing agent such as l-menthol, 1,8-cineole and camphor; a preservative such as phenoxyethanol; olive oil, macadamia nut oil, argan Vegetable oils such as oil; hygroscopic agents such as silica; hyaluronic acid or derivatives thereof, collagen or derivatives thereof, amino acids or derivatives thereof, antioxidants, sequestering agents, vitamins, animal and plant extracts, pearling agents, coloring agents, flavoring agents Etc. may be included.
- a refreshing agent such as l-menthol, 1,8-cineole and camphor
- a preservative such as phenoxyethanol
- olive oil macadamia nut oil, argan Vegetable oils
- hygroscopic agents such as silica
- the method for producing the hair dye composition of the present invention is not particularly limited, and can be produced according to a conventional method. Specific examples include the following methods. For example, in the case of color rinse or color treatment, gradually add an oil phase heated to 70-90 ° C. to an aqueous phase sufficiently heated to 70-90 ° C. and stir well for 5 minutes to emulsify. Do. After emulsification, the mixture is cooled to 20 to 40 ° C., and a dye dissolved in purified water is added thereto. After sufficiently uniformly stirring, a pH adjuster is added and sufficiently uniformly stirred to obtain a creamy hair dye composition.
- the pH of the hair dye composition of the present invention is not particularly limited, but is preferably 4.0 to 8.0, more preferably 4.0 to 7.0 from the viewpoint of dyeability. Furthermore, from the viewpoint of the stability of the hair dye composition, the pH is preferably 6.5 or less. In particular, when the hair dye composition of the present invention is a color rinse, a color treatment, or a color shampoo, the pH is preferably 4.0 to 6.5.
- the dosage form of the hair dye composition of the present invention is not particularly limited, and examples thereof include liquid, viscous liquid, gel, emulsion, and cream. Among these, cream is preferable from the viewpoint of dyeability and texture.
- the hair dye composition of the present invention can dye hair in gray, black, brown, green, blue-violet, etc. by combining with other nonionic dyes or basic dyes. More preferably, they are gray, black, and brown. For this reason, it can be used as a hair dye composition for white hair dyeing, fashion dyeing and the like, and from the viewpoint of color tone, it is preferably a hair dye composition for dyeing white hair.
- the hair dye composition of the present invention is preferably a color rinse, a color treatment, or a color shampoo.
- the above color shampoo is a hair cleaning agent used for shampooing, and can dye hair simultaneously with shampooing.
- the color shampoo is applied to the hair and foamed to wash the hair, and then used after washing.
- the above-mentioned color rinse and color treatment are hair treatment agents that are generally used during shampooing and are used after being washed and washed off.
- the color rinse and the color treatment are used in such a usage method that after washing the hair with a shampoo, the color rinse or the color treatment is applied to the hair, and immediately after the application or for 3 to 10 minutes, the hair is conditioned.
- the color rinse and color treatment may be used before washing the hair. In that case, the color rinse and color treatment should be applied to dry or wet hair, rinsed immediately after application or after 3 to 10 minutes of hair conditioning, and then washed with shampoo. Used in the usage method of washing hair.
- Example 1-1 Comparative Examples 1-1 to 1-5 According to the composition described in Table 1, each hair dye composition (aqueous solution system) was prepared and subjected to the evaluation test of Test 1 below.
- Test 1 Evaluation of dark dyeing effect As a test hair bundle, a yak hair bundle (manufactured by Beaulux, length 10 cm, weight 1 g) was used.
- the evaluation hair bundle dyed with the hair dye composition of Example 1-1 was clearly more than the reference hair bundle (evaluation hair bundle dyed with the hair dye composition of Comparative Example 1-4). It was heavily dyed.
- the evaluation hair bundle dyed with the hair dye composition of Comparative Example 1-5 was dyed slightly darker than the reference hair bundle (evaluation hair bundle dyed with the hair dye composition of Comparative Example 1-4). However, the dark dyeing effect was insufficient.
- the evaluation hair bundle dyed in Comparative Example 1-2 and Comparative Example 1-3 was dyed in the same manner as the reference hair bundle (evaluation hair bundle dyed with the hair dye composition of Comparative Example 1-1). The condition was not so strong.
- Example 2-1 and Comparative Examples 2-1 and 2-2 According to the composition described in Table 2, each hair dye composition (aqueous solution system) was prepared and subjected to the evaluation test of Test 2 below. The evaluation results are shown in FIG.
- Test 2 Lightness evaluation An evaluation hair bundle was prepared by the same method as the evaluation hair bundle preparation method of Test 1 (evaluation of dark dyeing effect).
- the lightness evaluation was performed by using a spectrocolorimeter CM-3610d (manufactured by Konica Minolta Japan Co., Ltd.), a main light source D65, a visual field of 10 °, reflected light measurement, and SCE.
- the lightness (L * value) of each dyed hair was measured under the condition of a measurement diameter of 8 mm.
- the software used was CM-S100w SpectraMagic NX (manufactured by Konica Minolta Japan Co., Ltd.).
- the L * a * b color system was used. In addition, it shows that it is dye
- Example 2-1 the combination of HC Blue 2 and glyceryl caprate (Example 2-1) had the lowest L * value. Compared to the combination of HC Blue 2 and glyceryl caprylate (Comparative Example 2-2), it was shown that the effect of deep dyeing was remarkably excellent.
- Example 3-1 Comparative examples 3-1 to 3-4
- each hair dye composition (aqueous solution system) was prepared according to the composition described in Table 3 and subjected to the evaluation test of Test 2 above. The evaluation results are shown in FIG.
- Example 3-1 As shown in FIG. 2, the combination of HC Blue 2 and glyceryl caprate (Example 3-1) had the lowest L * value. On the other hand, when an ester compound having a long carbon chain (Comparative Examples 3-2 and 3-3) is used, the L * value is higher than that of the reference (Comparative Example 3-1), and the dark dyeing effect is not exhibited. It became clear.
- Example 4-1 Comparative example 4-1.
- each hair dye composition (cream system) was prepared according to the composition described in Table 4 and subjected to the evaluation test of Test 2 described above. The evaluation results are shown in FIG.
- Example 6-1 and Comparative Example 6-1 Color Shampoo Each hair dye composition was prepared according to the composition shown in Table 6 and subjected to the evaluation test of Test 2 above. The evaluation results are shown in FIG.
- Example 7-1 Comparative example 7-1: Color rinse (or color treatment) According to the composition described in Table 7, each hair dye composition was prepared and subjected to the evaluation test of Test 2 above. The evaluation results are shown in FIG.
- Example 8-1 and Comparative Example 8-1 In accordance with the composition described in Table 8, each hair dye composition was prepared and subjected to the evaluation test of Test 2 in order to verify the blending change with other dyes. The evaluation results are shown in FIG.
- the hair dye composition of the present invention is a composition used as a hair dye.
- the hair dye include color rinse, color treatment, hair manicure, and color shampoo.
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Abstract
Description
成分A:HC青2
成分B:カプリン酸グリセリル
成分Aは、HC青2である。上記HC青2は、INCI名(International Cosmetic Ingredient Dictionary and Handbook,第16版,第2巻,2016年,p.1494):HC BLUE NO.2で表記される化合物であり、2,2’-[[4-[(2-ヒドロキシエチル)アミノ]-3-ニトロフェニル]イミノ]ビスエタノール:2,2’-[[4-[(2-Hydroxyethyl)amino]-3-nitrophenyl]imino]bisethanolである。
なお、実施例及び比較例の各染毛料組成物のpHは、pHメーター(株式会社堀場製作所製、商品名「卓上型pHメーター F-74」)を用いて測定した。
表1に記した組成に従い、各染毛料組成物(水溶液系)を調製し、下記試験1の評価試験に供した。
試験用毛束として、ヤク毛毛束(株式会社ビューラックス製、長さ10cm、重さ1g)を用いた。
上記試験用毛束に、製造直後の実施例及び比較例で得られた各染毛料組成物1gを塗布し、1分間クシを用いて毛束全体に馴染ませた。次いで、アルミホイルで包んで、30℃70%RHの恒温恒湿器(タバイエスペック株式会社製、商品名「LHL-113」)中に10分間放置した。その後、水道水で毛束から染毛料組成物を十分に洗い流し、タオルドライを行った後、ドライヤーを用いて十分に乾燥させ、評価用毛束(各染毛料組成物で染毛した毛束)を調製した。
表2に記した組成に従い、各染毛料組成物(水溶液系)を調製し、下記試験2の評価試験に供した。評価結果を図1に示す。
試験1(濃染効果の評価)の評価用毛束の調製方法と同一の方法にて評価用毛束を調製した。
カプリン酸グリセリルと他のエステル化合物の濃染効果の差を検証するため、表3に記した組成に従い、各染毛料組成物(水溶液系)を調製し、上記試験2の評価試験に供した。評価結果を図2に示す。
クリーム系での濃染効果を確認するため、表4に記した組成に従い、各染毛料組成物(クリーム系)を調製し、上記試験2の評価試験に供した。評価結果を図3に示す。
表5に記した組成に従い、各染毛料組成物(水溶液系)を調製し、上記試験2の評価試験に供した。評価結果を図4に示す。なおΔL*値は、表中の基準(比較例5-1)に対する明度差を示す。
表6に記した組成に従い、各染毛料組成物を調製し、上記試験2の評価試験に供した。評価結果を図5に示す。
表7に記した組成に従い、各染毛料組成物を調製し、上記試験2の評価試験に供した。評価結果を図6に示す。
表8に記した組成に従い、他の染料との配合変化を検証するため、各染毛料組成物を調製し、上記試験2の評価試験に供した。評価結果を図7に示す。
塩基性青75:保土谷化学工業株式会社製、商品名「AHC BLUE SP」
HC青2:テルカ社製、商品名「COLOREX HCB2」
ポリオキシエチレンセチルエーテル(5E.O.):青木油脂工業株式会社製、商品名「ブラウノン CH-305」
ポリオキシエチレンセチルエーテル(20E.O.):青木油脂工業株式会社製、商品名「ブラウノン CH-320L」
ステアリン酸PEG-5グリセリル:日光ケミカルズ株式会社製、商品名「NIKKOL TMGS-5V」
ステアリン酸PEG-15グリセリル:日光ケミカルズ株式会社製、商品名「NIKKOL TMGS-15V」
ヤシ油脂肪酸PEG-7グリセリル:ミヨシ油脂株式会社製、商品名「Mファインオイル COG-7M」
塩化アルキルトリメチルアンモニウム液(80%):クラリアントジャパン株式会社製、商品名「GENAMIN KDMP-J」、純分80質量%
ステアリン酸ジメチルアミノプロピルアミド:日光ケミカルズ株式会社製、商品名「NIKKOL アミドアミンMPS」
流動パラフィン:Sonneborn Inc製、商品名「CARNATION」
ジプロピレングリコール:旭硝子株式会社製、商品名「ジプロピレングリコール DPG-FC」
2-エチルヘキセン酸セチル:日本サーファクタント工業株式会社製、商品名「CIO-N」
ラウロイルメチル-β-アラニンナトリウム液(30%):川研ファインケミカル株式会社製、商品名「アラノンALE」、純分30質量%
ラウリン酸アミドプロピルベタイン液(30%):新日本理化株式会社製、商品名「リカビオン B-300」、純分30質量%
ヤシ油脂肪酸N-メチルエタノールアミド:花王株式会社製、商品名「アミノーンC-11S」
塩化O-[2-ヒドロキシ-3-(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロース:東邦化学工業株式会社製、商品名「カチナール HC-100」
塩基性青124 0.1質量%
塩基性茶17 1.0質量%
HC黄4 0.08質量%
HC青2 1.2質量%
セタノール 6.0質量%
ポリオキシエチレンセチルエーテル(5E.O.) 2.0質量%
ポリオキシエチレンセチルエーテル(20E.O.) 2.0質量%
流動パラフィン 5.0質量%
ジプロピレングリコール 3.0質量%
カプリン酸グリセリル 2.0質量%
ポリ塩化ジメチルメチレンピペリジニウム液(純分40質量%)
1.0質量%
アミノエチルアミノプロピルシロキサン・ジメチルシロキサン
共重合体エマルション(純分40質量%) 1.5質量%
クエン酸 適量(pH5に調整)
クエン酸ナトリウム 適量(pH5に調整)
安息香酸ナトリウム 0.5質量%
ヒアルロン酸ヒドロキシプロピルトリモニウム 0.5質量%
シリカ 0.2質量%
海藻エキス(1) 0.1質量%
l-メントール 0.1質量%
精製水 残量
合計 100質量%
塩基性青124 0.05質量%
塩基性茶16 0.2質量%
HC黄4 0.2質量%
HC青2 1.5質量%
ラウロイルメチル-β-アラニンナトリウム液(純分30質量%)
5.0質量%
ラウリン酸アミドプロピルベタイン液(純分30質量%) 30.0質量%
ヤシ油脂肪酸N-メチルエタノールアミド 2.0質量%
塩化O-[2-ヒドロキシ-3-(トリメチルアンモニオ)
プロピル]ヒドロキシエチルセルロース 0.2質量%
ジプロピレングリコール 3.0質量%
カプリン酸グリセリル 1.0質量%
モノラウリン酸ポリグリセリル 0.1質量%
高重合メチルポリシロキサン(1) 0.1質量%
メチルポリシロキサン 0.4質量%
クエン酸 適量(pH5に調整)
クエン酸ナトリウム 適量(pH5に調整)
フェノキシエタノール 0.5質量%
水溶性コラーゲン(3) 0.1質量%
ホホバ油 0.1質量%
精製水 残量
合計 100質量%
Claims (4)
- 下記成分Aと下記成分Bを含有する染毛料組成物。
成分A:HC青2
成分B:カプリン酸グリセリル - 前記成分Aの含有量に対する、前記成分Bの含有量の質量割合[成分B/成分A]が、0.1以上である、請求項1に記載の染毛料組成物。
- 前記染毛料組成物中の、前記成分Aの含有量は0.1~3.0質量%であり、前記成分Bの含有量は0.01~3.0質量%である、請求項1又は2に記載の染毛料組成物。
- カラーリンス又はカラートリートメントである、請求項1~3のいずれか1項に記載の染毛料組成物。
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JP7213533B2 (ja) | 2018-12-27 | 2023-01-27 | 日本メナード化粧品株式会社 | 染毛料組成物 |
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