WO2018041884A2 - Composition, procédé et utilisation - Google Patents

Composition, procédé et utilisation Download PDF

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Publication number
WO2018041884A2
WO2018041884A2 PCT/EP2017/071746 EP2017071746W WO2018041884A2 WO 2018041884 A2 WO2018041884 A2 WO 2018041884A2 EP 2017071746 W EP2017071746 W EP 2017071746W WO 2018041884 A2 WO2018041884 A2 WO 2018041884A2
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WO
WIPO (PCT)
Prior art keywords
choco
aerated
micro
chocolate
gas
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PCT/EP2017/071746
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English (en)
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WO2018041884A3 (fr
Inventor
Jamey GERMAN
Josélio Batista VIEIRA
Jennifer Anne TICKNER
Original Assignee
Nestec Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Nestec Sa filed Critical Nestec Sa
Priority to CN201780033994.9A priority Critical patent/CN109195449A/zh
Priority to AU2017320784A priority patent/AU2017320784B2/en
Priority to RU2018142002A priority patent/RU2738415C2/ru
Priority to BR112018074693-2A priority patent/BR112018074693B1/pt
Priority to JP2018561508A priority patent/JP6990666B2/ja
Priority to MX2018014801A priority patent/MX2018014801A/es
Priority to CA3025871A priority patent/CA3025871A1/fr
Priority to EP17761239.7A priority patent/EP3451847A2/fr
Publication of WO2018041884A2 publication Critical patent/WO2018041884A2/fr
Publication of WO2018041884A3 publication Critical patent/WO2018041884A3/fr
Priority to ZA2018/08136A priority patent/ZA201808136B/en

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Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/50—Cocoa products, e.g. chocolate; Substitutes therefor characterised by shape, structure or physical form, e.g. products with an inedible support
    • A23G1/52—Aerated, foamed, cellular or porous products, e.g. gas expanded

Definitions

  • the present invention relates to the field of chocolate confectionery compositions that comprise gas bubbles therein (commonly known as aerated chocolate).
  • aerated chocolate commonly known as aerated chocolate
  • One preferred embodiment of the invention relates to micro-aerated chocolate having a combination of multiple enhanced properties.
  • Micro-aerated chocolate mass is very sensitive to any form of mechanical stress, which causes coalescence. A pressurized deposit, directly into the mould is therefore required to ensure optimal aeration quality. Until recently the focus has been to micro-aerate to low levels, primarily for cost reduction reasons.
  • micro-aerated chocolate compositions exhibit unexpected properties which are advantageous to the end consumer and also during manufacture. These advantages include improved stability of the matrix of aerated bubbles in the solid product and/or greater ease of removal from a mould and/or packaging. These properties make the product easier to manufacture and/or produce more desired and/or consistent organoleptic properties in the final confectionery product.
  • the invention provides for methods to prepare such micro-aerated chocolate compositions and different uses of such chocolate compositions.
  • micro-aerating chocolate to achieve high porosities would be difficult and expensive, with no added benefit leading to unstable and adversely tasting products. This is the reason that the few prior art micro-aerated products made in practise contain small amounts of gas micro-bubbles to achieve a porosity of at most 8%, often much lower.
  • the applicant has surprisingly found a method for preparing a novel micro-aerated chocolate where the chocolate contains much higher proportion of gas than incorporated heretofor and the micro-bubbles are characterised by optimum parameters (as described herein).
  • Such micro-aerated chocolate exhibits several beneficial properties which have never been appreciated before.
  • EP2298080 (Kraft) (also referred to herein as Kraft080) discloses a method and apparatus for making aerated food product which details the use of a microporous gas diffuser for the aeration of food products in a low shear mixing method. These products include, allegedly, chocolate, though the single example provided is a chocolate flavoured wafer filling and is not chocolate
  • the viscosity of the process medium before adding the gas through the microporous diffuser is typically in the range of from 1 to 200 Pa.s, and preferably within the range of 1 to 60 Pa.s. '
  • Paragraph [0027] states: 'The gas volume fraction incorporated into the food product depends on the specific application and is typically in the range of 5 to 75% vol., preferably 5 to 40% vol., and most preferably 10 to 30% vol. '
  • Microcellular generally implies gas cells of an average size of 100 [im or less.
  • the average cell size is less than 50 [im and most preferably, the average cell size falls within the range of 5 to 30 ⁇ im.
  • 90% of the cells have a size between W and 50 ⁇ m. ⁇
  • the product of the process according to the present invention typically contains 30% or less by volume of gas.
  • the gas volume fraction is less than 25% and most preferable it is in the range of 10 to 25%. The best results are obtained when the aforementioned preferred gas volumes and preferred cell sizes are realised in combination.
  • Kraft080 discloses a very broad range of viscosities (from 1 to 200 Pa.s) forfood media stated to be successfully aerated by this method. It is not credible that all food with such a broad range of viscosities can be aerated by the same method described in Kraft 080 and such statements must be considered highly speculative. For example chocolate masses used to prepare moulded chocolate products have typical plastic viscosities of from 1 to 20 Pa.s and high shear mixing would be required to provide homogenous aeration. The aeration method described in Kraft080 injects gas under low shear with a micro-diffuser. It is doubtful this method could aerate viscous chocolate masses, with viscosities in the high end of the claimed range.
  • Kraft080 also describes products aerated with very wide gas volume ranges (from 5 to 70%). There is no appreciation of the unique properties of chocolate. The applicant has found aerating chocolate with micro-bubbles at gas volumes above 20% increases the chocolate viscosity leading to difficulty in removing such chocolate from moulds. Therefore the micro-aerated chocolate described in Kraft080, even if was ever made, is far from satisfactory.
  • Haedelt2005 describes vacuum-induced bubble formation in liquid- tempered chocolate.
  • Haedelt2005 acknowledges (page E159, col. 2, lines 7 to 1 1 ) that:
  • the bubble sizes of the aerated chocolate prepared by Haedelt2005 are clearly macro-sized. This can be seen from Table 2 on page E161 which describes samples having a bubble size with mean diameter (mm) prepared at various gas pressures, namely 0.85 mm ⁇ 0.4 standard deviation (SD) (at 1000 Pa); 0.4 mm ⁇ 0.16 mm SD) (at 5000 Pa); and 0.37 mm ⁇ 0.19 mm SD (at 10,000 Pa).
  • SD standard deviation
  • Table 3 on page E161 describes samples having a bubble size with the following mean diameters (mm) prepared from chocolate with viscosity tempered at the given temperatures, namely: 0.4 mm ⁇ 0.19 mm SD (at 27°C); 0.41 mm ⁇ 0.16 mm SD) (at 30°C); and 0.49 mm ⁇ 0.19 mm SD ) (at 33°C).
  • Haedelt2007 investigated the sensory properties produced by using different gases to micro-aerate chocolate, namely carbon dioxide, nitrogen, nitrous oxide, and argon. Haedelt2007, does not consider or disclose the effect of varying any other parameters on the sensory properties of aerated chocolate.
  • WO2002-13618 (Danone) describes an apparatus for aerating a foodstuff including chocolate.
  • EP2543260 (also referred to herein as Kraft060) discloses use of a frozen cone process for micro-aerating a chocolate shell. Such thin shells are very different from thicker moulded chocolate products such as tablets. The use of a cold stamping process avoids challenges associated with flow characteristics of micro-aerated chocolate.
  • the aerated shell layer has a total gas content of at least 5%, the gas content being calculated using the following formula (1):
  • M1 is the mass of the aerated shell layer having volume V1
  • M2 is the mass of a non-aerated shell layer having volume V1 and being formed from the same edible liquid as the aerated shell layer and in the same manner as the aerated shell layer.
  • the aerated edible liquid to be deposited into the mould cavity in step (ii) suitably has a total gas content of at least 5%, the gas content being calculated using the following formula (2):
  • M3 is the mass of the aerated edible liquid having volume V2
  • M4 is the mass of the same volume of the edible liquid without aeration. This means that the mass of the edible liquid per unit volume (V2) is reduced by at least 5% upon aerating the liquid.
  • a gas content of at least 5% is advantageous in terms of providing a good texture and reducing the calorie content of the shell.
  • the gas content of the aerated edible liquid can be at least 10%, at least 15%, at least 20%, at least 25%, at least 30% or at least 40%, and in some embodiments the gas content is within the range 5-40%, 5-25% or 10-20 mass% so that there is not an excessive loss of gas from the liquid during cold-stamping.
  • a higher initial gas content leads to a greater degree of de-aeration relative to the initial gas content. This is because the gas bubbles have a greater chance of coalescing to form larger bubbles. Large bubbles quickly escape from the liquid due to the large difference between their densities and the density of the liquid.
  • the liquid contains no more than 14 vol%, no more than 18 vol% or no more than 22 vol% of gas.
  • a suitable minimum gas content is 10 vol%.
  • a gas content of 10-22 vol% is advantageous in terms of taste and mouthfeel.
  • the aerated liquid can have a density or no more than 1.10 g/cm 3 , no more than 1.05 g/cm 3 , no more than 1.00 g/cm3, or no more than 0.95 g/cm 3 .
  • a density within the range of 0.98-1.10 g/cm 3 is optimal in terms of taste and mouthfeel.
  • Kraft060 is more concerned in improving methods for making thin chocolate shells than aerating a large chocolate mass such as those used to produce chocolate tablets.
  • the method described in Kraft060 uses cold stamping form a thin shell.
  • Kraft060 does not suggest how to produce a controlled size distribution of small bubbles in a micro-aerated chocolate. This is due in part due to the rapid cooling associated with the cold stamping method, meaning less time for expansion and coalescence of the bubbles. Cooling times for a chocolate tablet are significantly longer due to the use of long cooling tunnels and a much larger mass of chocolate in the mould cavity.
  • the stamping process leads to bubble destruction through the physical force of the stamp impacting the aerated chocolate.
  • Kraft060 The problem of how to ensure uniform distribution of bubbles homogeneously within a solid chocolate product is not addressed by Kraft060 as for a thin shell this not an issue.
  • the method of Kraft060 is not designed for and would be unsuitable to use to aerate thicker moulded product such as tablets.
  • the process of Kraft060 is designed for the production of chocolate shells for the addition of a further component.
  • US2006-0057265A1 discloses a method for producing confectionary products having an outer shell made of a substance that is placed inside a mould into which a temperature controlled male die is subsequently introduced. The substance is placed under pressure after the male die is introduced.
  • EP201881 1 discloses an apparatus for moulding foodstuffs.
  • EP0589820 (Aasted-Mikroverk) discloses a method of moulding chocolate articles.
  • DE 102005018415 discloses a method for making candy products (and candy moulding station) that uses a cold stamp protected from an air by filling the chamber in which stamping occurs with a gas has such as helium that is less dense than air. A mixing zone is formed between the area with the protective gas and air.
  • WO2009-040530 (Cadbury) discloses an aerated centre filled confectionery composition.
  • EP0914774 (Aasted-Mikroverk) discloses a method, system and apparatus for producing shells of fat-containing chocolate like masses.
  • CH68041 1 (Lindt) describes a method of forming a semi-solid , fatty, aerated masses, especially chocolate and / or chocolate like masses and a device for its implementation.
  • US5238698 (Jacob Suchard) describes a product and process for producing a lower density milk chocolate composition, substantially free of sucrose and having the taste and mouthfeel of a traditional milk chocolate.
  • the milk chocolate composition is aerated with an inert gas under a pressure of about 1.2 about 8 bar at temperature of 27° C. to about 45° C.
  • EP0230763 (Morinaga) describes aerated chocolate composition with a gaseous continuous phase and the dispersed phase of fine grains of conglomerated solid chocolate.
  • the aerated chocolate has an apparent density of 0.23 to 0.48 g / cm 3 .
  • the composition is made by agitating a melted chocolate whilst cooling from 8 to 14 °C lower than the fat contained within the chocolate, to incorporate gas therein.
  • the apparent density of the composition is allowed to reach from 0.7 to 1.1 g / cm 3 and then the composition is exposed to a reduced pressure of 150 Torr or less to expand the composition and convert the gas and solid phases.
  • EP1346641 (Aasted-Mikroverk) discloses a method of making chocolate shells.
  • WO2001 -080660 (Effem Foods) describes a confectionery product comprising low density chocolate surrounded by a sugar based coating and a process for producing this product. The product is stated to be shelf stable even at elevated ambient temperatures.
  • GB1305520 (Abalo) describes a continuous process for making foamed candies having a continuous outer shell of non aerated chocolate shell and a foamed chocolate filling in the centre.
  • WO2000-078156 (APV) describes use of micro-aerated chocolate for enrobing
  • the lentils are analogous to products available commercially from Mars under the registered trademark M&M®.
  • the chocolate core is dispersed with gas bubbles having an average diameter of less than 25 microns. Typically the average diameter of the gas bubbles is less than about 17 microns.
  • the dispersion is preferably homogeneous throughout the core. ' These bubble sizes are very small and difficult to produce in a large chocolate mass than a core (e.g. to make chocolate tablets).
  • WO2013-143938 discloses how colorants can be added to ice cream coatings to counteract the impact of micro-aeration.
  • 80% of the cumulative area weighted size air bubble distribution is below 60 [im.
  • 95% of the cumulative area weighted size air bubble distribution is below 125 [im, preferably below 100 [im.
  • 99% of the cumulative area weighted size air bubble distribution is below 150 [im.
  • WO 2014-037910 (Barry Callebaut) describes a micro aerated chocolate used to limit exudation and fat bloom, in which the gas is present as a volume fraction of from 0.1 % to 4.5% of gas micro-bubbles having a diameter from 1 to 100 ⁇ .
  • the patent states on page 5 lines 1 to 10 (informal translation) that:
  • the preferred volume fraction of the gas micro-bubbles is greater than or equal to 0.2%, and more particularly greater than or equal to 0.5% or to 0.8%.
  • the preferred volume fraction of the gas micro-bubbles is less than or equal to 5.0%, and more particularly less than or equal to 4.5% or still to 4%.
  • the preferred volume fraction of the gas micro-bubbles is selected in the range from 0.2%) to 4.5%o, advantageously in the range from 0.3%> to 2.5%>.
  • the volume fraction of the gas micro-bubbles is selected in the range between 0.5%> to 2%.
  • the gas micro-bubbles present have a diameter less than or equal to 100 [im.
  • the diameter of the micro-bubbles may have a diameter from 1 ⁇ im to 100 [im, preferably a diameter from 1 ⁇ im to 30 [im and in a more preferred embodiment a diameter from 1 ⁇ im to 10 [im!
  • composition [is] a volume fraction from 0.1 to 5.0%o of gas micro-bubbles of diameter ranging from 1 ⁇ im to 100 [im.
  • EP2016836 (Mondelez) describes a method of producing a confectionery product includes the steps of: a) depositing into a mould an aerated confectionery mass (such as chocolate) such that the equipment keeps the mass under super atmospheric pressure and allows it to flow into the mold, b) depositing at least one particulate material in and/or on the confectionery mass; and c) repeating at least step a) at least once.
  • This method avoids applying shearing forces to the mass typical of extrusions method and thus allows the gas bubbles to be maintained in the final product.
  • the method is a one pass process that matches the aeration rate to the production of the chocolate so no aerated chocolate is wasted and reused.
  • the invention is more concerned with avoiding issues relating to over production of aerated mass in an online process there is no teaching that this process can be used to form bubbles with the narrow criteria as defined herein or that a particular level of micro-aeration in the final chocolate would be more desirable than any other level.
  • the filling comprises a fat system and has a solid fat content (SFC) of 35 to 65% at 0°C and 1 to 8% at 30°C.
  • SFC solid fat content
  • the fat system is prepared from palm oil mid fraction.
  • the filling is soft at low temperature so that it is palatable. However, it does not melt at ambient temperatures and therefore does not require refrigeration / freezing for storage or transport.
  • WO2015-101965 (Mondelez) describes a process for the preparation of a confectionery composition and compositions producible by the process.
  • the process comprises providing a first sheet (10) of edible film having a plurality of first recesses (12) therein and a second sheet (22) of edible film, optionally having a plurality of second recesses (24) therein.
  • a liquid filling (18) is supplied to the first recesses (12) and then sealed between the first and second sheets (10, 22) to form capsules (26).
  • Molten chocolate (14) may be applied to the first recesses and/or the second recesses before the liquid filling.
  • the capsules may be placed in a chocolate shell.
  • WO2015-072942 (Eti Gidan Sanayi) describes an industrial food product with high water activity and filler and free of preservative, colouring agent and emulsifier.
  • the invention is a production method for an industrial convenience food product with ready-to-eat, high water activity and filler, and free of preservative, colouring agent and emulsifier, comprising the process steps of a) preparation and cooking of the bakery products, b) in order to prepare the filler (2), obtaining by product by executing agitation-condensation-pasteurization- homogenization processes within a single unit, reducing the temperature of the by-product and fixing the same at a certain range (50-55°C), processing the by-product with fixed temperature in individual passages (K1 ,K2,K3,K4), and cooling down the same to a temperature (down to +8°C) far below the freezing point (15°C) without allowing crystallization (constant agitation), and execution of crystallization- aeration processes by
  • JP03-883479 (Meji) describes a method for making pneumatic combined oily confectionery comprising a shell of pneumatic oily confectionery and using a moulding method.
  • the method comprises pouring pneumatic combined oily confectionery dough into a mould where a thin layer of oily confectionery is formed, pressing the mould using a pressing pattern to make a doubled shell, and charging edible material as a centre stuffing inside the shell.
  • the method comprises the following process: directly pouring pneumatic combined oily confectionery dough into a heated mould to make its interfacial part melt, forming a thin layer on the interfacial part with the inner surface of the mould followed by pressing the dough using a cooled pressing pattern to make a shell, and charging edible material as a centre stuffing inside the shell.
  • Jacob's Club® The chocolate coated biscuit available commercially in the UK under the registered trade mark Jacob's Club® contained both aerated cream and chocolate and was believed to have been aerated intentionally. Interestingly a significant difference between the level of aeration on the top and sides parts of the product was observed, where the porosity of the chocolate forming the top coating was 8.5 % (average bubble size 281 microns ⁇ 31 1 ) whereas at the sides the chocolate porosity was 3.7% (average bubble size 202 microns ⁇ 184). It is worth noting that the average bubble size obtained for the Jacob's Club product is significantly larger than that which would typically be considered micro-aerated (100 microns or less) and the bubbles would be visible to the consumer by naked eye.
  • the Dove® milk chocolate had a porosity of 1 .8% and it is believed that this low porosity is much more likely to result from natural micro-aeration as a by-product of a conventional process rather than gas being incorporated intentionally.
  • the Mars® and M&M® eggs were more likely to be aerated deliberately possibly, as these eggs are quite large, as a means to reducing the amount of chocolate for cost saving whilst maintaining product size. They also appear to have been produced using a frozen cone/cold stamping method (perhaps similar to that described in Kraft060 above), where aeration stability is less of a concern due to the rapid cooling associated with this process.
  • the applicant has surprisingly found that a means to aerate choco-material to form a micro- aerated choc-material having a population of small bubbles having a narrow distribution of sizes and uniformly distributed within the material.
  • These choco-materials can readily moulded into micro-aerated choco products such as chocolate tablets, bars and other moulded chocolate confectionery such as moulded chocolate coated wafers (e.g. prepared using a wet filled mould).
  • the object of the present invention is to solve some or all of the problems or disadvantages (such as identified herein) with the prior art, including optionally overcoming the technical prejudice described above preventing the wide adoption of micro-aeration in choco- confectionery.
  • an aerated choco-material having a plastic viscosity before aeration as measured according to ICA method 46 (2000) of from 0.1 to 20 Pa.s, where:
  • composition has dispersed therein bubbles of an inert gas, the dispersed bubbles being characterised by the following parameters
  • a total bubble surface area also referred to herein as TSA of from 0.5 to 1 .2 m 2 per 100g of the aerated choc-material
  • parameters (a) and (b) are determined from X-ray tomography and/or confocal laser scanning microscopy (CLSM) and parameter (c); and where
  • the gas bubbles are homogenously distributed within the choco-material, having a homogeneity index of at least 0.8;
  • TSA may be determined by any suitable empirical method, well known to those skilled in the art and/or may be determined by calculation. In one preferred embodiment of the invention the TSA is determined from equation (1 ):
  • TSA total bubble surface area
  • P porosity of the aerated choco-material
  • m ac mass of aerated composition (g)
  • c/ ac density of aerated composition (g/cm 3 )
  • r is the radius of a bubble of mean size (cm).
  • the aerated choco-material of the invention is a chocolate mass.
  • the plastic viscosity of the pre-aerated choco-material of the invention is measured herein according to ICA method 46 (2000) under standard conditions unless otherwise stated and more preferably is from 0.1 to 10 Pa.s.
  • the micro-aerated choco-material of the invention described herein has a total bubble surface area (TSA) of from 0.5 to 1.2; preferably from 0.55 to 1 .10, more preferably from 0.6 to 1.0; most preferably from 0.65 to 0.90, for example from 0.7 to 0.8 m 2 per 100 g of the aerated choco-material.
  • TSA total bubble surface area
  • the term surface area or total surface area (TSA) referred to herein can be calculated from equation (1 ) herein and/or measured by any suitable apparatus or method known to those skilled in art.
  • the TSA is a specific surface area (SSA) and may be measured as described in the article 'Determination of Surface Area.
  • the choco-material is chocolate or compound, more usefully chocolate, most usefully dark and/or milk chocolate, for example milk chocolate such as a moulded milk chocolate tablet (optionally with inclusions and/or fillings therein).
  • the homogeneity index that measures how uniformly the bubbles are distributed within the composition may be determined by taking an image (from X-ray tomography and/or CLSM) and measuring the number of bubbles that intersect along at least 3 parallel horizontal lines of equal length (preferably at least 1 cm) located on the image to be equally spaced from each other and the image edges.
  • the ratio of the minimum number of bubbles on one of these lines to the maximum number of bubbles on one of these lines can be defined as a number bubble homogenous distribution index (NBHDI) which may be at least 0.8, preferably greater than or equal to 0.85, more preferably greater than or equal to 0.9, most preferably ⁇ 0.95, for example about 1.
  • NBHDI number bubble homogenous distribution index
  • the homogeneity index that measures how uniformly the bubbles are distributed may be determined by taking an image (from X-ray tomography and/or CLSM) and measuring along each of at least 3 parallel horizontal lines of equal length (preferably at least 1 cm) located on the image to be equally spaced from each other and the image edges, the length of each line that lies inside the void of a gas bubble.
  • the ratio of the minimum void length on one of these lines to the maximum void length on one of these lines can be defined as a void length bubble homogenous distribution index (VLBHDI) which may be at least 0.8, preferably greater than or equal to
  • Sweetness is an organoleptic attribute which some consumers may wish to be enhanced in choco-materials.
  • Bitterness is an organoleptic attribute which some consumers may wish to be diminished in choco-materials.
  • the applicant has surprisingly found the micro-aeration can be used to ehance sweetness perception and/or diminish bitterness perception in chocolate. Micro-aeration can also be used to maintain an acceptable and/or comparable level of sweetness and/or bitterness to non-aerated products whilst using less sugar.
  • Control A has the same recipe as Material 1 other than:
  • Control A contains more sugar than Material 1 (optionally at least 35% by weight).
  • Usefully Control A has an amount of sugar which is at least 5, more usefully at least 10, most usefully at least 15, weight percentage points higher than amount of sugar present in Material
  • the amount of sugar being independently measured in each case as a weight percent of sugar per total weight of each material.
  • Advantageously similar sweetness or bitterness perception denotes that the Material 1 has a Panel Score for sweetness perception within 0.5 points of (more advantageously no more than 0.5 points less than) the Panel Score of the Control A. More advantageously the Panel Score for sweetness perception of Material 1 is substantially the same as, most advantageously is the same as) the Panel Score of the Control A and yet the Material 1 has a lower amount of sugar.
  • a yet further embodiment of the present invention provides a micro-aerated choco-material (Material 2) of the invention as described herein comprising:
  • Control B has the same recipe as Material 2 other than:
  • Control B has a similar amount of sugar than Material 2.
  • Usefully Control B has an amount of sugar which is similar i.e. is no more than 5 (optionally 2) weight percentage points different from, more usefully is substantially the same as, most usefully is the same as the amount of sugar present in Material 2, the amount of sugar being independently measured in each case as a weight percent of sugar per total weight of each material.
  • the enhanced sweetness or diminished bitterness perception denotes that Material 2 has a Panel Score for sweetness perception of at least 0.5 points (more advantageously at least 0.7 points, most advantageously at least 1 .0 points) more than the Panel Score of Control B.
  • Softness is an organoleptic attribute which some consumers may wish to be enhanced in choco-materials.
  • the applicant has surprisingly found the micro-aeration can be used to enhance softness in chocolate. Micro-aeration can also be used to maintain an acceptable and/or comparable level of softness to non-aerated products whilst using less fat.
  • Softness can be measured by a panel and/or by physical testing. Often it is measured by the perception of its opposite hardness so that enhancement of softness can be also measured by a corresponding diminishing of hardness (whether as measured by a reduction in hardness perception as rated by a trained panel as described herein or by a lower value of a physical parameter that measures hardness in a suitable test) compared to a non aerated control.
  • softness (and its opposite hardness) may be determined by a physical parameters using a penetration test, which may any such test known to those skilled in the art that is suitable for testing chocolate.
  • a yet other embodiment of the present invention provides a micro-aerated choco-material (Material 1 ) of the invention as described herein comprising:
  • Control A has the same recipe as Material 1 other than:
  • Control A contains more fat than Material 1 (optionally at least 27% by weight).
  • Usefully Control A has an amount of fat which is at least 2, more usefully at least 5, most usefully at least 8, weight percentage points higher than the amount of fat present in Material 1 , the amount of fat being independently measured in each case as a weight percent of fat per total weight of each material.
  • Advantageously similar softness may denote (if measured by hardness perception) that the Material 1 has a Panel Score for hardness perception within 0.5 points of (more advantageously no more than 0.5 points less than) the Panel Score of the Control A. More advantageously the Panel Score for hardness perception of Material 1 is substantially the same as, most advantageously is the same as) the Panel Score of the Control A and yet the Material 1 has a lower amount of fat.
  • a yet further embodiment of the present invention provides a micro-aerated choco-material (Material 2) of the invention as described herein comprising:
  • Control B has the same recipe as Material 2 other than:
  • Control B has a similar amount of fat than Material 2.
  • Usefully Control B has an amount of fat which is similar i.e. is no more than 2, optionally no more than 1 weight percentage points different from, more usefully is substantially the same as, most usefully is the same as the amount of fat present in Material 2, the amount of fat being independently measured in each case as a weight percent of fat per total weight of each material.
  • the enhanced softness may denote (if measured by diminished hardness perception) that Material 2 has a Panel Score for hardness perception of at least 0.5 points (more advantageously at least 0.7 points, most advantageously at least 1.0 points) less than the Panel Score of Control B.
  • Milkiness is an organoleptic attribute which some consumers may wish to be enhanced in choco-materials.
  • Cocoa taste is an organoleptic attribute which some consumers may wish to be diminished in choco-materials.
  • the applicant has surprisingly found the micro-aeration can be used to enhance milkiness perception and/or diminish cocoa taste in chocolate.
  • Micro- aeration can also be used to maintain an acceptable and/or comparable level of milkiness to non-aerated products whilst using less sugar and/or milk.
  • Micro-aeration can also be used to maintain an acceptable and/or comparable level of cocoa taste to non-aerated products whilst using less milk. This especially the case for consumers who prefer the taste of milk rather than dark chocolate.
  • Preferred choc-materials used in all aspects of the present invention are milk chocolate (or equivalent for compound).
  • the milk content may be present in the form of whole milk, skimmed milk and/or milk fats and/or as a liquid or powder form.
  • a yet other embodiment of the present invention provides a micro-aerated choco-material (Material 1 ) of the invention as described herein comprising:
  • Control A has the same recipe as Material 1 other than:
  • Control A contains more milk than the Material 1 (optionally at least 15% by weight).
  • Material 1 has a low milk content of no more than 12%, more preferably no more than 10%, most preferably no more than 8% by weight of Material 1 .
  • Usefully Control A has an amount of milk which is at least 2, more usefully at least 5, most usefully at least 8, weight percentage points higher than amount of milk present in Material 1 , the amount of milk being independently measured in each case as a weight percent of milk per total weight of each material.
  • Advantageously similar milk or cocoa taste perception denotes that Material 1 has a Panel Score for milkiness within 0.5 points of (more advantageously no more than 0.5 points less than) the Panel Score of Control A. More advantageously the Panel Score for milkiness of the Material 1 is substantially the same as, most advantageously is the same as) the Panel Score of Control A and Material 1 has a lower amount of milk than Control A.
  • a yet further aspect of the present invention provides a micro-aerated choco-material (Material 2) having:
  • Control B an enhanced milk or diminished cocoa perception (as measured by a Panel Score for milkiness as described herein) to the milk perception of a control choco-material (Control B); where the Control B has the same recipe as Material 2 other than:
  • Control B has a similar amount of milk than the Material 2.
  • Usefully Control B has an amount of milk which is similar i.e. is no more than 2 (optionally 1 ) weight percentage points different from, more usefully is substantially the same as, most usefully is the same as the amount of milk present in Material 2, the amount of milk being independently measured in each case as a weight percent of milk per total weight of each material.
  • the enhanced milk or diminished cocoa perception denotes that Material 2 has a Panel Score for milkiness of at least 0.5 points (more advantageously at least 0.7 points, most advantageously at least 1 .0 points) more than the Panel Score of Control B.
  • the choco-material is other than a coating, (such as a bar or tablet, optionally solid or with inclusions) more preferably has a thickness of at least 2 mm, more preferably at least 5 mm.
  • the choco-material of the invention is demouldable.
  • De-mouldable as used herein means that when the choco-material of the invention is added to a mould using the beech bar test after solidification it can be consistently and reliably (i.e. a rate of 99% or more without error) be removed from said mould by finger pressure alone under standard conditions to form one test piece without any material being left in the mould and where the square vertices of the resultant test piece are not deformed.
  • Demouldablity of choco-material can also be assess by measuring the amount to which the choco-material contracts in the mould after solidification.
  • the present invention also provides a method of preparing a coated moulded baked grain foodstuff comprising micro-aerated chocolate, the method comprising the steps of:
  • micro-aerated chocolate is that as described elsewhere in this application.
  • a preferred application means in step b) is spray coating.
  • use of an initial spray coat means that surface appearance is comparable to the non-aerated reference product.
  • the fat based confectionery product, such as chocolate, used to form the thin layer in step b) is not micro- aerated, as the presence of a thin shell of chocolate which is not micro-aerated has been found to help ensure integrity of the coating, for example against moisture, and therefore maintain quality over shelf life.
  • the optional mould conditioning step may comprise heating the mould, for example to a temperature from 25 to 34°C, preferably from 29 to 32 °C for example about 30°C.
  • the mould is not heated, and optionally chilled, preferably to less than 10 °C so the layer on the mould sets more quickly. Chilling the mould may also make deposition of later ingredients easier.
  • the mould is neither heated nor chilled but can be used at ambient temperature which reduces the energy required to operate the process.
  • the thin layer applied for example by spray coating, removes the need to pre-condition the mould and so the mould conditioning step is unnecessary.
  • the application means is such that the layer of the fat based confectionery (preferably chocolate) in the mould has a mean thickness of from 0.1 mm to 1.5 mm, more usefully from 0.3 mm to 1 mm, most usefully from 0.5 mm to 0.8 mm.
  • the layer thickness may be measured using a micrometre in a conventional manner or preferably by using a microscope of a cross-section.
  • the coating layer is a chocolate layer applied to the mould is non-aerated chocolate, as this produces a more structurally robust shell and leads to a more even glossy coat of acceptable colour in the final product.
  • micro-aerated chocolate used in step c) to form the additional layer may have already been micro-aerated in a separate process and so the chocolate is deposited in situ is already micro-aerated.
  • the chocolate used in step c) may be deposited into the mould on the thin chocolate later and then micro-aerated in situ.
  • Micro-aeration may also comprise a step in the method of the present invention, in which case the chocolate used in step c) may be first micro-aerated just prior to being added to the mould layer, the micro- aeration may occur simultaneously with addition to the mould as a single step and/or the micro-aeration may occur in situ within the mould after the chocolate has been added and/or any combinations thereof.
  • the micro-aeration of the chocolate occurs before the chocolate is added to the mould layer in step c).
  • micro-aerated is meant that the material that is aerated comprises gas bubbles that have a mean diameter (assuming a spherical shape of bubble) formed with aerated material is from 100 nanometres (nm) to 1 micrometre, preferably from 200 nm to 500 nm, more preferably from 50 to 200 nm, most preferably from 75 to 150 nm).
  • at least 60% (preferably at least 70%, more preferably at least 80%) of the bubbles have a size within these ranges.
  • the bubbles have an particle size distribution which conveniently is unimodal and more conveniently the maximum peak of which lies within any of the preceding size ranges.
  • the bubbles are formed from an non-oxidative (e.g. inert) gas, but to produce micro- aerated chocolate any gas could be used which would be suitable for inclusion in a foodstuff.
  • suitable gases comprise nitrogen and/or carbon dioxide.
  • the gas bubbles do not comprise air or oxygen as this can lead to oxidative rancidity.
  • Nitrogen is the preferred gas for micro-aeration.
  • the bubble size may be usefully measured by X-ray tomography in a conventional manner.
  • an intermediate element that comprises a mould is coated with a thin layer (mean thickness from 0.1 to 0.5 mm or as given herein) of chocolate.
  • the process of the invention may be used to obtain a moulded product that substantially consists of chocolate, i.e. a thin shell of solid chocolate surrounding a core of micro-aerated chocolate.
  • a baked grain foodstuff is also added to the mould to produce a coated baked foodstuff.
  • the method comprises in additional to steps a) to c) above the steps of:
  • step c) adding a baked grain foodstuff (preferably a baked cereal foodstuff) to the coated mould comprising micro-aerated chocolate as prepared in step c);
  • fat based confectionery product preferably further chocolate
  • baked grain foodstuff preferably baked cereal foodstuff
  • a coated baked grain foodstuff preferably a chocolate coated baked cereal foodstuff.
  • step e) all the surfaces of the baked grain foodstuff are substantially completely coated in chocolate.
  • the baked grain foodstuff comprises one or more layers of a wafer, and where there are a plurality of wafer layers optionally the baked grain foodstuff comprises fillings between the interior surfaces of the wafers.
  • step b) applying to an interior surface of said mould a thin layer of chocolate using a spray; c) micro-aerating and depositing further chocolate to the thin layer in the mould to form a further layer; where the micro-aeration may occur before or simultaneously with deposition; d) adding a baked grain foodstuff to the micro-aerated chocolate as prepared in step c); e) applying further chocolate to coat the uncoated surfaces of the baked grain foodstuff adjacent the open side of the mould, and
  • step f) removing the foodstuff from step e) from the mould to obtain therefrom a chocolate coated baked grain foodstuff comprising micro-aerated chocolate.
  • the optional conditioning step a) may be performed by heating or chilling the mould to any suitable temperature less than or equal to 33°C.
  • the mould is heated to from 25 to 34 °C.
  • the mould is chilled to ⁇ 10 °C.
  • a foodstuff coated with micro-aerated chocolate obtained and/or obtainable by a method of the present invention.
  • Preferred foodstuffs of the invention comprises an interior which comprises a baked grain foodstuff, more preferably a baked cereal foodstuff, even more preferably a wafer layer, most preferably a plurality of laminated wafer layers.
  • a moulded product by spraying of thin layer of chocolate before micro-aerated chocolate is deposited thereon.
  • the product of the invention may also comprise additional conventional ingredients such as sugar, cocoa mass, cocoa butter, milk powder, cocoa fibre and/or emulsifiers (such as soya lecithin) as appropriate and these can be added at any suitable step, preferably during or after the chocolate in step c).
  • additional conventional ingredients such as sugar, cocoa mass, cocoa butter, milk powder, cocoa fibre and/or emulsifiers (such as soya lecithin) as appropriate and these can be added at any suitable step, preferably during or after the chocolate in step c).
  • the product of the invention has fewer calories than the same portion of an otherwise identical product where the chocolate in step c) has not been micro-aerated.
  • step b after the thin chocolate layer has been applied in step b), there is a pause (preferably from 0.5 minutes to 10 minutes) before adding the additional chocolate in step c).
  • a pause preferably from 0.5 minutes to 10 minutes
  • a test protocol was carried out using a generic mould design (also referred to as a 'Beech bar'), as shown in Figure 27.
  • the mould design was selected to have common design features of a tablet, the slightly angular design allowing assessment of flowability.
  • the choco-material (e.g. chocolate) to be tested was simply deposited into the mould (at 28°C), tapped gently (just enough to ensure a flat backing off) and allowed to cool in a fridge set at 10°C for 50 minutes before demoulding. It was possible to assess the following parameters, which define lower and upper limits to the properties of a choco-material which may be advantageously moulded.
  • the choco-material of the invention was found to satisfy both these criteria.
  • micro-aerating chocolate leads to enhanced desire from consumers to eat chocolate and/or enhanced satisfaction from consumers after consumption and/or more pleasurable and/or more mindful eating experience. This means that compared to a non-aerated chocolate less micro-chocolate need be consumed for the same benefit and/or that if the same amount of micro-aerated chocolate is consumed as a non-aerated chocolate the consumer experiences an enhanced benefit (such as satisfaction, desire, pleasure and/or mindfulness)
  • micro- aeration can be used to enhance satisfaction in chocolate. Micro-aeration can also be used to maintain an acceptable and/or comparable level of satisfaction to non-aerated products for example whilst using less fat.
  • a further aspect of the invention provides use of micro-aeration, preferably to achieve a porosity of from 1 1 % to 19%, to enhance satisfaction of a choco-material.
  • An aspect of the present invention provides a use of micro-aeration of a choco-material as described for to enhance satisfaction of a choco-material.
  • a yet other aspect of the present invention provides a micro-aerated choco-material (Material 1 ) having:
  • Control A has the same recipe as Material 1 other than:
  • Control A has more fat than Material 1 (optionally at least 27% by weight).
  • Usefully Control A has an amount of fat which is at least 2, more usefully at least 5, most usefully at least 8, weight percentage points higher than the amount of fat present in Material 1 , the amount of fat being independently measured in each case as a weight percent of fat per total weight of each material.
  • Advantageously similar satisfaction perception denotes that Material 1 has a Panel Score for satisfaction within 0.5 points of (more advantageously no more than 0.5 points less than) the Panel Score of Control A. More advantageously the Panel Score for satisfaction of Material 1 is substantially the same as, most advantageously is the same as) the Panel Score of Control A and Material 1 has a lower amount of fat.
  • a yet further aspect of the present invention provides a micro-aerated choco-material (Material 2) having:
  • Control B an enhanced satisfaction perception (for example as measured by a Panel Score for satisfaction as described herein) to the fat perception of a control choco-material (Control B); where Control B has the same recipe as Material 2 other than:
  • Control B has a similar amount of fat than Material 2.
  • Usefully Control B has an amount of fat which is similar i.e. is no more than 2, optionally no more than 1 weight percentage points different from, more usefully is substantially the same as, most usefully is the same as the amount of fat present in Material 2, the amount of fat being independently measured in each case as a weight percent of fat per total weight of each material.
  • the enhanced satisfaction denotes that Material 2 has a Panel Score for satisfaction of at least 0.5 points (more advantageously at least 0.7 points, most advantageously at least 1 .0 points) more than the Panel Score of Control B.
  • a method of providing an indicating means associated with a pack to indicate to a consumer enhanced satisfaction of a micro-aerated choco-material contained within said pack (optionally the choco-material comprising the whole or part of a confectionery product).
  • a method of providing an indicating means associated with a pack to indicate to a consumer enhanced satisfaction of a micro-aerated choco-material contained within said pack (optionally the choco-material comprising the whole or part of a confectionery product).
  • a yet still other aspect of the present invention provides a method of providing an indicating means associated with a pack to indicate to a consumer enhanced satisfaction of a micro- aerated choco-material contained within said pack (optionally the choco-material comprising the whole or part of a confectionery product), and where in a preferred embodiment optionally (i) the choco-material has dispersed therein bubbles of an inert gas characterised by the following parameters:
  • parameters (a) and (b) are determined from X-ray tomography and/or confocal laser scanning microscopy (CLSM);
  • the gas bubbles are homogenously distributed within the choco-material, having a homogeneity index of at least 0.8;
  • the enhanced satisfaction is compared to a non-aerated choco-material of the same recipe.
  • a pack comprising an aerated choco-material, with an indicating means associated with the pack to indicate to a consumer enhanced satisfaction of a micro-aerated choco-material contained within said pack (optionally the choco-material comprising the whole or part of a confectionery product).
  • a still another aspect of the present invention provides a pack comprising an aerated choco- material, with an indicating means associated with the pack to indicate to a consumer enhanced satisfaction of a choco-material contained within said pack, and where in a preferred embodiment optionally
  • parameters (a) and (b) are determined from X-ray tomography and/or confocal laser scanning microscopy (CLSM);
  • the gas bubbles are homogenously distributed within the choco-material, having a homogeneity index of at least 0.8;
  • the enhanced satisfaction is compared to an unaerated choco-material of the same recipe.
  • the method of providing indicating means and/or the pack comprises printing information onto an external surface of the pack.
  • a yet other aspect of the present invention provides a micro-aerated choco-material (Material 1 ) having an enhanced aeration stability (for example as measured by a Panel Score for aeration stability as described herein) which is more stable immediately after aeration that the aeration stability of a control choco-material (Control A); where
  • Control A has the same recipe as Material 1 other than:
  • Control A is macro-aerated with the same total volume of gas as in Material 1 .
  • Advantageously enhanced aeration stability denotes that Material 1 has a Panel Score for aeration stability of at least 0.5 points, more advantageously at least 0.7 points more than most advantageously at least 1 point more than, the Panel Score of Control A.
  • Organoleptic attributes of test samples of the invention are assessed quantitatively by a trained sensory panel who taste samples and rate organoleptic attributes on a 0 to 10 point scale for each attribute ranging from 0 (no attribute detected) to 10 (maximum attribute).
  • the sensory panel consists of at least 8 trained persons, preferably at least 10 trained persons. The panel is run at least twice and the ratings on the 10 point scale given by each panel member in each test are used to provide an average absolute score (Panel Score).
  • One or more test samples are also tested with respect to one or more control samples and a difference in Panel Score between the control(s) and test sample(s) for a given organoleptic attribute can also be determined.
  • LSD least significant difference
  • Bubble size may be measured from images obtained using suitable instruments and methods known to those skilled in the art.
  • Preferred methods comprise X-ray tomography and/or confocal laser scanning microscopy (CLSM), more preferably X-ray tomography. Both these methods are described more fully later herein.
  • micro-aerating a number of different chocolate recipes under different aeration conditions the applicant has found those optimal composition and/or process parameters of the invention which are selected to achieve corresponding and unexpectedly advantageous properties in the micro-aerated chocolate (as described herein). These parameters define aspects of the present invention. Without wishing to be bound by any theory, the applicant has observed that micro-aeration increases the viscosity of the aerated chocolate mass post deposit. It is believed that the small bubbles act analogously to small particles an increase the internal surface area for interactions to occur within the fluid chocolate mass.
  • the applicant has selected the parameters used to define the present invention as those such that the degree of aeration is enough to increase the viscosity of the aerated chocolate mass sufficiently to stabilise the gas bubbles and reduce or eliminate coalescence.
  • the micro-sized bubbles that are formed have a more uniform size (narrow size distribution) and are dispersed more homogeneously throughout the chocolate that in previous micro-aerated chocolates. This produces micro-aerated chocolate of high quality (e.g. as determined by the resultant advantageous properties described herein).
  • a suitable container is filled with the sample of chocolate, scraping the chocolate so that it is level with the top of the container. If the aeration is not stable then the chocolate will rise, as shown in the figures herein. Sometimes, particularly at lower levels of aeration, it is possible to see air bubbles visibly bursting at the surface.
  • the applicant has found a means to calculate a baseline figure of estimated porosity to gas flow (nitrogen) for a chocolate throughput of 1000 kg per hour. This is based on trials carried out on various apparatus at industrial scales.
  • step (II) passing the choco-material from step (I) through an injection zone located between two regions held at different pressures
  • P represents the porosity target of the micro-aerated choco-material in % measured under standard conditions, P being from 10 to 19%;
  • F v represents the nominal volumetric flow rate of the inert gas in normal litres per minute (NL / min.);
  • A, B and C are numerical constants (having the respective units to balance equation (2)); the numerical parts of each of these constants being:
  • the process produces a micro-aerated choco-material having dispersed therein bubbles of the inert gas, the dispersed bubbles being characterised by the following parameters (the choco-material being at a temperature of 20°C):
  • parameters (a) and (b) are determined from X-ray tomography and/or confocal laser scanning microscopy (CLSM) and parameter (c) (TSA) is measured empirically by any suitable method and/or is calculated from equation (1 ) herein; and where
  • the gas bubbles are homogenously distributed within the choco-material, having a homogeneity index of at least 0.8.
  • the regions of different pressure around the injection zone are formed by two pumps located outside the injection zone, preferably the pumps run at a differential pump speed of from 20% to 30%, more preferably the pumps are run at a constant differential pump speed of 25%.
  • Equation (2) allows a skilled person to achieve a desired target porosity in the final product by selecting given gas flow in step (II) within a fair approximation. Equation (2) also assumes that during gas dispersion in step (II) the choco-material passes by the gas depositing means in the injection zone at a nominal throughput of 1000 kg / hour.
  • the actual gas flow required should also be adjusted proportionally up or down from the value for the nominal flow rate (parameter F v ) calculated from equation (2) so the volume of inert gas injected into each kilogram of the choc-material per second remains constant.
  • Normal litres per minute is the amount of inert gas flow calculated as if the gas was under 'normal' conditions of zero degrees Celsius and one atmosphere (1 .01325 bar).
  • step (II) there exists a range of inert gas flow rates for use in step (II) that satisfy equation (2) within which the process can be operated to achieve the desired end results.
  • suitable values of specific gas flow rates F v that will achieve a desired porosity P in the final product can calculated by finding any solutions for quadratic equation (2), for example by selecting suitable specific values of constants A, B and C within the ranges stated herein (and adjusting for chocolate throughput if required).
  • the high shear mixing is performed at a shear rate of at least 300 s "1 , more preferably at least 400 s '
  • the high shear mixing is performed at a shear rate of no more than 1000 s "1 , more usefully no more than 800 s "1 , most usefully no more than 600 s "1 .
  • the high shear mixing is performed at a shear rate of from 200 to 1000 s "1 , more conveniently from 300 to 800 s “1 , even more conveniently from 400 to 600 s “1 , most conveniently from 400 to 500 s "1 , for example about 415 s "1 .
  • the high shear mixing in step (I) may be achieved using a beater mixer to mix the choco-material, with a beater speed of from 200 to 600 revolutions per minute (rpm), more optionally from 300 to 500 rpm, for example 400 rpm.
  • a beater mixer to mix the choco-material, with a beater speed of from 200 to 600 revolutions per minute (rpm), more optionally from 300 to 500 rpm, for example 400 rpm.
  • the porosity target y may be any porosity value given herein as desired for the choco-materials of the present invention.
  • A from 0.061 to 0.069; B from 2.01 to 2.04, and C from 3.71 to 3.79;
  • A from 0.062 to 0.067; B from 2.01 to 2.03, and C from 3.72 to 3.76;
  • A from 0.062 to 0.064; B from 2.01 to 2.02, and C from 3.73 to 3.74;
  • the gas depositing means is other than a micro-diffuser, more preferably is from one or more nozzles.
  • the nozzle(s) having a exit diameter of from 2 to 3.5 mm and/or an orifice length of from 6 to 12 mm.
  • Gas flow rate may be measured as volumetric flow rate denoted by the symbol 'F v ' and/or as a mass flow rate denoted by the symbol 'F m '.
  • a fluid e.g. gas
  • density 'p' rho
  • F v denotes the volumetric flow rate of inert gas in normal litres of gas per minute (NL / min);
  • F m denotes the mass flow rate of the inert gas in kilograms of gas per minute (kg / min); and
  • p (rho) denotes the density of the inert gas in kilograms per normal litre (kg / NL), i.e. measured under normal conditions (0°C and 1 atm.).
  • Gas mass flow rate F m can be calculated from gas volumetric flow rate F v and/or directly measured, independent of pressure and temperature effects, by any suitable means such as thermal mass flow meters, Coriolis mass flow meters and/or mass flow controllers.
  • the desired value of F m to achieve a desired porosity P can thus optionally be calculated from equations (2), (3) and/or (4).
  • the inert gas is dispersed into the choco- material at a gas mass flow rate ('m') which of preferably from 2.4 to 6 kilograms per minute, more preferably from 3.0 to 4.8 kg/min, most preferably from 3.6 to 4.2 kg/min.
  • the inert gas is may be dispersed into the choco-material at a gas pressure of from 2 to 30 bar, usefully from 4 to 15 bar, more usefully from 6 to 12 bar, most usefully from 8 to 1 1 bar, for example from 9 to 10 bar.
  • Adjusting gas flow (when held a constant temperature no higher than the exit temperature from the chocolate temperer) can control the amount of gas dispersed in a micro-aerated choco-material; the stability of the bubbles formed in the micro-aerated choco-material; and/or the degree to which the choco-material can be easily and cleanly removed from a mould (demoulding).
  • the gas flow temperature can be kept constant by control of beater speed (so it is not too fast to heat the choco-material significantly) and/or by use of a cooling jacket.
  • the equation (2) herein can thus be used to calculate the gas flow rate (F v or F m ) that used by the gas depositor in step (II) of the process of the invention will reliable and consistently produce micro-aerated choco-material with a given target porosity P and/or also other bubble parameters as described herein.
  • the applicant has also found that in a preferred embodiment of the present invention where the composition is mixed and/or beaten then it is preferably performed under high shear.
  • the term 'high shear' denotes a shear rate of at least 200 s "1 .
  • high shear rates of from 200 to 1000 s "1 are more preferred, high shear of from 300 to 500 s "1 are even more preferred.
  • mixing speed has a large impact on mean bubble size and standard deviation.
  • a further aspect of the present invention is the method for control of the aerating process of the present invention such that the gas flow rate remains substantially within a range (as calculated from equation (2)) to achieve a desired target porosity in the final micro-aerated chocolate.
  • control may be manual or automatic, for example using sensors to automatically adjust gas flow rate of the gas depositor in responses to changes in the process (for example changes in throughput of choco-material) and may be operated by a computer controlled apparatus and/or using a feedback loop.
  • gas bubbles are produced in the compositions of the invention using an aerating machine selected from one or more of the following machines and/or components thereof:
  • rotor stator mixers for example those having mixing heads with intermeshing pins, available commercially under the trade mark Mondomix® from Haas
  • a gas injector where preferably the composition is pumped by at least two pumps to pass an injection site being located between said pumps, and the inert gas is dispersed into the composition by injection at the injection site at high gas pressure, more usefully the gas pressure being less than or equal to 9 bar.
  • System pressure is 9 bar post gas injection.
  • Suitable gas injectors may comprise the Novae injector as defined herein and/or described in WO2005/063036); and/or
  • a jet depositor for depositing the composition onto a substrate under positive pressure (for example as described in WO2010/102716).
  • the aerating machine comprises a Novae injector and/or a jet depositor; even more preferably a Novae injector, most preferably where the gas is injected into the composition in between two pumps, usefully at a pressure of from 2 to 30 bar, more usefully from 4 to 15 bar, even more usefully from 6 to 12 bar, most usefully from 8 to 1 1 bar, for example 9 bar or 10 bar.
  • a rotor stator mixing head (that available from Haas under the trade mark Mondomix®) is shown in Figure 4 and 5 herein.
  • a modular mixing head with three different sets of rotor stators and referred to by the trade name Nestwhipper is shown in Figure 6 herein.
  • Any suitable gas injector especially those where the gas is injected into the composition at an injection site between two pumps, optionally capable of being operated at pressures from 2 to 30 bar.
  • the most preferred injectors are those denoted herein byjhe term 'Novae®' which refers to the injectors described in the applicant's patent application WO2005/063036 the contents of which are hereby incorporated by reference.
  • a Novae® gas injector comprises a two pumps with gas injected between them (as shown schematically in Figure 7).
  • gas injectors such as the Novae® offers several advantages:
  • injectors such as the Novae® can optionally operate at higher pressures compared to conventional rotor stator systems (9 bar is a typical operating pressure for the Novae® compared to 6 bar typical operating pressure for a Mondomix®).
  • this is additionally useful as higher flow rates can be delivered with consequent faster line speeds.
  • 'jet depositor refers to an apparatus for depositing a fluid food product (e.g. a liquid, semi-liquid or semi -solid food) under positive pressure (i.e. pressure above ambient pressure).
  • a preferred jet depositor comprises a reciprocating valve spindle to deposit the food and/or is as described in the applicant's patent application WO2010/102716 the contents of which are hereby incorporated by reference.
  • a yet other aspect of the present invention provides a process to produce a choco-material with improved aeration stability and/or ability to be removed from a mould; the process comprising the step of dispersing bubbles of an inert gas in said choco-material in an amount to produce a choco-material which when cooled to ambient temperature where the dispersed bubbles are characterised by the following parameters
  • parameters (a) and (b) are determined from X-ray tomography and/or confocal laser scanning microscopy (CLSM) and parameter (c); and where
  • the gas bubbles are homogenously distributed within the choco-material, having a homogeneity index of at least 0.8;
  • the composition is pumped by at least two pumps to pass an injection site being located between said pumps, where in step (a) the inert gas is dispersed into the composition by injection at the injection site at high gas pressure, more usefully the gas pressure being greater than or equal to 9 bar.
  • the gas bubbles are formed in the composition (preferably during step (a) using an aerating machine selected from one or more of the following machines and/or components thereof:
  • one or more rotor stator mixing heads for example those available under the trade designation Mondomix®
  • a gas injector where preferably the composition is pumped by at least two pumps to pass an injection site being located between said pumps, and the inert gas is dispersed into the composition by injection at the injection site at high gas pressure, more usefully the gas pressure being greater than or equal to 9 bar (for example the Novae® injector as defined herein and/or described in WO2005/063036); and/or
  • the two process parameters that impacted porosity and aeration quality to be most extent were gas flow and temperature.
  • the control of other parameters in the aeration process was found to have little or no effect.
  • the applicant believes that when producing micro-aerated chocolate the crystallisation of the fat is the main factor which holds the aerated structure. Micro-aerated chocolate is also stable over time.
  • step (a) the gas is dispersed into a molten choco-material at a mass flow rate of from 0.6 to 12 kg / min; more conveniently from 1 .2 to 9 kg / min; most conveniently from 2.4 to 6 kg / min.
  • the gas is dispersed into the composition when the composition is at a temperature of from 28 to 33°C, more usefully from 30 to 32°C, most preferably 31 °C.
  • a still another aspect of the present invention provides a micro-aerated choco-material with difference in colour compared to a control, the choco-material having a plastic viscosity before aeration as measured according to ICA method 46 (2000) of from 0.1 to 20 Pa.s, where:
  • composition has dispersed therein bubbles of an inert gas, the dispersed bubbles being characterised by the following parameters
  • a total bubble surface area also referred to herein as TSA of from 0.5 to 1 .2 m 2 per 10Og of the aerated choc-material
  • parameters (a) and (b) are determined from X-ray tomography and/or confocal laser scanning microscopy (CLSM) and parameter (c); and where
  • the gas bubbles are homogenously distributed within the choco-material, having a homogeneity index of at least 0.8;
  • AL (delta L) is zero or a positive number (being the difference between L values in the L a b colour space where a larger L value represents a lighter colour,) AL being defined from equation (2)
  • L * a denotes the absolute lightness value of the colour of the micro-aerated choco-material
  • L * c denotes is the absolute lightness value of the colour of a control sample - the non- aerated chocolate of the same recipe as the micro-aerated choco-material; where dark ingredients denote any ingredients that have a L * value before incorporation in a material of less than that of the material of which they comprise; and with the proviso that is
  • the TSA is determined from equation (1 ):
  • TSA total bubble surface area
  • P porosity of the aerated choco-material
  • m ac mass of aerated composition (g)
  • c/ ac density of aerated composition (g/cm 3 )
  • r is the radius of a bubble of mean size (cm) and the values for , P are from 1 1 to 19%.
  • dark ingredients denote any ingredients that have a L * value before incorporation in a material greater than that of the material of which they comprise;
  • Control A has the same recipe as Material 1 other than:
  • Control A contains a less amount of dark ingredients than Material 1.
  • the amount of dark ingredients in Material 1 is in an amount of at least 5% (preferably from 5 to 20%) by weight of the total amount of Material 1.
  • dark ingredients denote any ingredients that have a L * value before incorporation in a material of less than that of the material of which they comprise;
  • Control B has the same recipe as Material 2 other than:
  • Control B has a similar amount of dark ingredients to that in Material 2.
  • the amount of dark ingredients in Material 2 is in an amount of at least 5% (preferably from 5 to 20%) by weight of the total amount of Material 2.
  • Preferred dark ingredients are naturally sourced and compatible with the choco-material, such as cocoa nibs, cocoa shells and/or other dark cocoa products.
  • the colour lightening may denote (if measured by equation (2)) a AL (delta L) value of at least 0.5, more advantageously at least 0.7, most advantageously at least 1 .0, for example at least 1 .5.
  • a further aspect of the invention provides use of micro-aeration of the invention as described herein, preferably to achieve a porosity of from 1 1 % to 19%, for the purpose of one or more (preferably a plurality of) enhanced enhanced sweetness, softness, milkiness and/or mouth feel perception, diminished bitterness, hardness, cocoa taste and/or grittiness perception, enhanced aeration stability; colour difference (preferably lighten colour) and/or improved ability to be removed from a mould or pack of a choco-material contained within said mould or pack (optionally the choco-material comprising the whole or part of a confectionery product),
  • a still further aspect of the invention provides a method or process for micro-aeration of the invention as described herein , preferably to achieve a porosity of from 1 1 % to 19%, for the purpose of one or more (preferably a plurality of) enhanced enhanced sweetness, softness, milkiness and/or mouth feel perception, diminished bitterness, hardness, cocoa taste and/or grittiness perception, enhanced aeration stability; colour difference (preferably lighten colour) and/or improved ability to be removed from a mould or pack of a choco-material contained within said mould or pack (optionally the choco-material comprising the whole or part of a confectionery product),
  • a yet still other aspect of the present invention provides a method of providing an indicating means associated with a pack to indicate to a consumer one or more (preferably a plurality of) enhanced enhanced sweetness, softness, milkiness and/or mouth feel perception, diminished bitterness, hardness, cocoa taste and/or grittiness perception, enhanced aeration stability; colour difference (preferably lighten colour) and/or improved ability to be removed from a mould or pack of a choco-material contained within said mould or pack (optionally the choco-material comprising the whole or part of a confectionery product), where:
  • parameters (a) and (b) are determined from X-ray tomography and/or confocal laser scanning microscopy (CLSM);
  • a still another aspect of the present invention provides a pack comprising an aerated choco- material, the pack comprising an indicating means associated with the pack to indicate to a consumer one or more (preferably a plurality of) enhanced enhanced sweetness, softness, milkiness and/or mouth feel perception, diminished bitterness, hardness, cocoa taste and/or grittiness perception, enhanced aeration stability; colour difference (preferably lighten colour) /or improved ability to be removed from a mould or pack of a choco-material contained within said mould or pack (optionally the choco-material comprising the whole or part of a confectionery product), where:
  • parameters (a) and (b) are determined from X-ray tomography and/or confocal laser scanning microscopy (CLSM) and parameter (c; and
  • the method of providing indicating means and/or the pack comprises printing information onto an external surface of the pack.
  • the indicating means may or may not indicate the benefit of the composition or product without indicating the underlying mechanism for that benefit (for example that the composition is aerated or the nature of that aeration e.g. bubble size).
  • a still another aspect of the invention provides a method of testing the relative aeration stability of a plurality of aerated choco- materials, the method comprising the steps of:
  • a yet further aspect of the invention provides a method of optimising a recipe of a choco- material comprising the steps of:
  • step (ii) determining from the consumer preferences derived from step (i) a set of desired numerical parameters that define the choco-material;
  • step (iii) using micro-aeration to modify organoleptic or other properties of a choco-material to more closely match the desired range for the properties obtained from step (ii) (optionally the choco-material comprising the whole or part of a confectionery product);
  • choco-material properties are selected from one or more of those as described herein,
  • choco-material and related terms are defined later in this application, preferred choco-materials of the invention being chocolate and related compositions such as compound also defined later herein.
  • inert gas denotes a gas that is substantially unreactive with the components of a choco-material and are also food grade approved i.e. suitable to form part of a foodstuff which will be consumed by human beings.
  • inert gases will not contain components which might substantially oxidise the choco-material (or components thereof), for example gases which contain significant amounts of oxygen (such as air) are not inert gases as used herein.
  • the inert gas is selected from nitrogen, nitrous oxide and/or carbon dioxide; more preferably from nitrogen and/or carbon dioxide; most preferably is nitrogen.
  • the bubble size as defined by the parameters of the present invention is also referred to herein as micro-aerated.
  • the aerated choco-material has gas bubbles with a mean bubble size ⁇ 85 microns, usefully a mean bubble size ⁇ 60 microns.
  • the aerated choco-material has gas bubbles with a mean bubble size of ⁇ 5 microns, usefully a mean bubble size of ⁇ 10 microns, more usefully of ⁇ 20 microns and more usefully of ⁇ 30 microns. Accordingly, an embodiment of the present invention provides a range of ⁇ 5 microns to ⁇ 85 microns in respect of mean bubble size.
  • the aerated choco-material has gas bubbles with a mean bubble size with a standard deviation of ⁇ 30 microns, usefully with a standard deviation of ⁇ 25 microns. In an embodiment of the present invention, the aerated choco- material has gas bubbles with a mean bubble size with a standard deviation of ⁇ 10 microns
  • the amount of gas in the choco-material may optionally also be determined by the porosity of the choco-material when solid.
  • the amount of inert gas dispersed in the micro-aerated choco-material may be sufficient to produce a porosity (as defined herein) in the ranges and/or of the values described herein.
  • the amount of gas used to achieve the defined porosities can be for example using the flow rates and/or temperatures as described herein.
  • the micro-aerated choco-material of the invention may have a porosity (as defined herein) of greater than or equal to 10% usefully greater than or equal to 1 1 %, more usefully ⁇ 12%, even more usefully ⁇ 13%, most usefully ⁇ 14%.
  • the micro-aerated choco-material of the invention may have a porosity (as defined herein) less than or equal to 19%, conveniently ⁇ 18%, more conveniently ⁇ 17%, even more conveniently ⁇ 16%, most conveniently ⁇ 15%.
  • the micro-aerated choco-material of the invention may have a porosity (as defined herein) of from 1 1 % to 19%, advantageously from 12% to 18%, more advantageously from 13% to 17%, even more advantageously from 14% to 16%, most advantageously from 14.5% to 15.5%.
  • a further aspect of the invention provides a micro-aerated choco-material, fat based composition and/or confectionery product obtained and/or obtainable from a process of the present invention.
  • a yet other aspect of the invention broadly provides a foodstuff and/or confectionery product comprising a micro-aerated choco-material, composition of the present invention and/or component(s) thereof as described herein.
  • fat based and/or “fat based edible product' denotes a composition, preferably a choco-confectionery that comprises a matrix of edible hydrophobic material (e.g. fat) as the continuous phase and a dispersed phase comprising solid particles dispersed within the edible hydrophobic continuous phase.
  • edible hydrophobic material e.g. fat
  • fat denotes hydrophobic material which is also edible.
  • fats are edible material (preferably of food grade) that are substantially immiscible with water and which may comprise one or more solid fat(s), liquid oil(s) and/or any suitable mixture(s) thereof.
  • solid fat denotes edible fats that are solid under standard conditions and the term “oil” or “liquid oil” (unless the context indicates otherwise) both denote edible oils that are liquid under standard conditions.
  • Preferred fats are selected from one or more of the following: coconut oil, palm kernel oil, palm oil, cocoa butter (CB), cocoa butter equivalents (CBE), cocoa butter substitutes (CBS), cocoa butter replacers (CBR), butter oil, lard, tallow, oil / fat fractions such as lauric or stearic fractions, hydrogenated oils, and blends thereof as well as fats which are typically liquid at room temperature such as any vegetable or animal oil.
  • fats that are most preferred for use herein for use in preparing the micro-aerated choco-materials of the present invention are CB, CBE, CBS, CBR and/or any mixtures and/or combinations thereof.
  • the liquid oil may comprise mineral oils and/or organic oils (oils produced by plants or animals), in particular food grade oils.
  • oils include: sunflower oil, rapeseed oil, olive oil, soybean oil, fish oil, linseed oil, safflower oil, corn oil, algae oil, cottonseed oil, grape seed oil, nut oils such as hazelnut oil, walnut oil, rice bran oil, sesame oil, peanut oil, palm oil, palm kernel oil, coconut oil, and emerging seed oil crops such as 25 high oleic sunflower oil, high oleic rapeseed, high oleic palm, high oleic soybean oils & high stearin sunflower or combinations thereof.
  • the fat content in the product of the present invention may be provided by fats of any origin.
  • the fat content is intended to indicate the total fat content in the composition, comprising either the content coming from solid fats and/or the content of liquid oils and thus the oil content will also contribute to the total amount of fat content as described herein for a fat based confectionery composition.
  • 'fat based composition and/or mass' respectively identifies a fat-based composition and/or mass (including its recipe and ingredients) which is used for the preparation of the products of the invention.
  • the term 'fat based confectionery composition and/or mass' identifies a confectionery composition and/or mass (including its recipe and ingredients) which is used for the preparation of fat based confectionery products such as micro-aerated choco-material of the invention.
  • the present invention relates specifically to a confectionery product, composition and/or mass that that comprise choco-material (preferably chocolate and/or compound, more preferably chocolate) as defined herein as well as optionally other confectionery products and/or components thereof.
  • choco-material preferably chocolate and/or compound, more preferably chocolate
  • 'chocolate' denotes any product (and/or component thereof if it would be a product) that meets a legal definition of chocolate in any jurisdiction and also include product (and/or component thereof) in which all or part of the cocoa butter (CB) is replaced by cocoa butter equivalents (CBE) and/or cocoa butter replacers (CBR).
  • CBD cocoa butter equivalents
  • CBR cocoa butter replacers
  • 'chocolate compound' or 'compound' as used herein denote chocolate-like analogues characterized by presence of cocoa solids (which include cocoa liquor/mass, cocoa butter and cocoa powder) in any amount, notwithstanding that in some jurisdictions compound may be legally defined by the presence of a minimum amount of cocoa solids.
  • choco-material includes products that are based on chocolate and/or chocolate analogues, and thus for example may be based on dark, milk or white chocolate and/or compound.
  • any one choco-material may be used to replace any other choco-material and neither the term chocolate nor compound should be considered as limiting the scope of the invention to a specific type of choco-material.
  • Preferred choco-material comprises chocolate and/or compound, more preferred choco-material comprises chocolate, most preferred choco-material comprises chocolate as legally defined in a major jurisdiction (such as Brazil, EU and/or US).
  • 'choco-coating' denotes coatings made from any choco-material.
  • the terms 'chocolate coating' and 'compound coating' may be defined similarly by analogy.
  • the terms 'choco-composition, (or mass)', 'chocolate composition (or mass)' and 'compound composition (or mass)' denote compositions (or masses) that respectively comprise choco-material, chocolate and compound as component(s) thereof in whole or part. Depending on their component parts the definitions of such compositions and/or masses may of course overlap.
  • 'choco-confectionery' denotes any foodstuff which comprises choco- material and optionally also other ingredients and thus may refer to foodstuffs such confections, wafers, cakes and/or biscuits whether the choco-material comprises a choco- coating and/or the bulk of the product.
  • Choco-confectionery may comprise choco-material in any suitable form for example as inclusions, layers, nuggets, pieces and/or drops.
  • the confectionery product may further contain any other suitable inclusions such as crispy inclusions for example cereals (e.g. expanded and/or toasted rice) and/or dried fruit pieces.
  • the choco-material of the invention may be used to mould a tablet and/or bar, to coat confectionery items and/or to prepare more complex confectionery products.
  • inclusions according to the desired recipe may be added to the choco-material.
  • the product of the invention will have the same recipe and ingredients as the corresponding composition and/or mass while in other instances, particularly where inclusions are added or for more complex products, the final recipe of the product may differ from that of the composition and/or mass used to prepare it.
  • the choco-confectionery product comprises a substantially solid moulded choco-tablet, choco-bar and/or baked product surrounded by substantial amounts of choco-material.
  • These products are prepared for example by substantially filling a mould with choc-material and optionally adding inclusions and/or baked product therein to displace choc-material from the mould (so-called wet shelling processes), if necessary further topping up the mould with choco-material.
  • the choco-material forms a substantial or whole part of the product and/or a thick outside layer surrounding the interior baked product (such as a wafer and/or biscuit laminate).
  • Such solid products where a mould is substantially filled with chocolate are to be contrasted with products that comprise moulded thin chocolate shells which present different challenges.
  • a mould is coated with a thin layer of chocolate, the mould being inverted to remove excess chocolate and/or stamped with a cold plunger to define the shell shape and largely empty the mould.
  • the mould is thus coated with a thin layer of chocolate to which further ingredients and fillings may be added to form the interior body of the product.
  • the challenges to maintain a uniform and consistent level of micro-aeration throughout the body of a thick or solid chocolate product such as a tablet or bar are different from micro-aerating a thin chocolate shell.
  • Preferred choco-confectionery may comprise one or more choco-product(s) and/or choco- ingredients therefor, for example selected from the group consisting of: chocolate product(s). compound product(s), chocolate coating(s) and/or compound coating(s).
  • the products may comprise uncoated products such as choco-bar(s) and/or choco-tablet(s) with or without inclusions and/or products coated with choco-material such as coated biscuits, cakes, wafers and/or other confectionery items.
  • any of the aforementioned may comprise one or more cocoa butter replacer(s) (CBR), cocoa-butter equivalent(s) (CBE), cocoa-butter substitute(s) (CBS) and/or any suitable mixture(s) thereof.
  • CBR cocoa butter replacer
  • CBE cocoa-butter equivalent
  • CBS cocoa-butter substitute
  • Such products may generally comprise one or more fat(s) selected from the group consisting of: lauric fat(s) (e.g. cocoa butter substitute (CBS) obtained from the kernel of the fruit of palm trees); non-lauric vegetable fat(s) (e.g.
  • CBR cocoa butter replacer
  • CBE cocoa butter equivalent(s)
  • Some CBE, CBR and especially CBS may contain primarily saturated fats and very low levels of unsaturated omega three and omega six fatty acids (with health benefits). Thus in one embodiment in choco-confectionery of the invention such types of fat are less preferred than CB.
  • one aspect of the present invention may provide for a choco- confectionery composition, preferably which has a lower total fat content (at least 5 parts or 5% by weight) than previously obtainable from prior art choco-material.
  • One embodiment of the invention provides a multi-layer product optionally comprising a plurality of layers of baked foodstuff (preferably selected from one or more wafer and/or biscuit layers, and/or one or more fillings layers there between with at least one coating layer located around these layers foodstuff, the coating comprising a choco-material of or prepared according to the invention.
  • a multi-layer product optionally comprising a plurality of layers of baked foodstuff (preferably selected from one or more wafer and/or biscuit layers, and/or one or more fillings layers there between with at least one coating layer located around these layers foodstuff, the coating comprising a choco-material of or prepared according to the invention.
  • a further embodiment of the invention provides a choco-confectionery product, further coated with chocolate (or equivalents thereof, such as compound) for example a praline, chocolate shell product and/or chocolate coated wafer or biscuit any of which may or may not be layered.
  • chocolate or equivalents thereof, such as compound
  • the chocolate coating can be applied or created by any suitable means, such as enrobing or moulding.
  • the coating may comprise a choco-material of or prepared according to the invention.
  • Another embodiment of the invention provides a choco-confectionery product of and/or used in the present invention, that comprises a filling surrounded by an outer layer for example a praline, chocolate shell product.
  • the foodstuff comprises a multi-layer coated choco- product comprising a plurality of layers of wafer, choco-material, biscuit and/or baked foodstuff, with filling sandwiched between them, with at least one layer or coating being a choco-material (e.g. chocolate) of the invention.
  • the multi-layer product comprises a choco-confectionery product (e.g. as described herein) selected from sandwich biscuit(s), cookie(s), wafer(s), muffin(s), extruded snack(s) and/or praline(s).
  • An example of such a product is a multilayer laminate of baked wafer and/or biscuit layers sandwiched with filling(s) and coated with chocolate.
  • Baked foodstuffs used in the invention may be sweet or savoury.
  • Preferred baked foodstuffs may comprise baked grain foodstuffs which term includes foodstuffs that comprise cereals and/or pulses.
  • Baked cereal foodstuffs are more preferred, most preferably baked wheat foodstuffs such as wafer(s) and/or biscuit(s).
  • Wafers may be flat or shaped (for example into a cone or basket for ice-cream) and biscuits may have many different shapes, though preferred wafer(s) and/or biscuit(s) are flat so they can be usefully be laminated together with a confectionery filling of the invention (and optionally a fruit based filling).
  • More preferred wafers are non-savoury wafers, for example having a sweet or plain flavour.
  • a non-limiting list of those possible baked foodstuffs that may comprise choco-compositions that comprise choco-material of and/or used in the present invention are selected from: high fat biscuits, cakes, breads, pastries and/or pies; such as from the group consisting of: ANZAC biscuit, biscotti, flapjack, kurabiye, lebkuchen, leckerli, macroon, bourbon biscuit, butter cookie, digestive biscuit, custard cream, extruded snacks, florentine, garibaldi gingerbread, koulourakia, kourabiedes, Linzer torte, muffin, oreo, Nice biscuit, peanut butter cookie, polvoron, pizzelle, pretzel, croissant, shortbread, cookie, fruit pie (e.g. apple pie, cherry pie), lemon drizzle cake, banana bread, carrot cake, pecan pie, apple strudel, baklava, berliner, bichon au citron and/or similar products.
  • ANZAC biscuit biscotti, flapjack, kurabiy
  • micro-aerated choco-material of or prepared according to the invention may be suitable for use as (in whole or in part as a component) of one or more coatings and/or fillings.
  • the coating and/or filling may comprise a plurality of phases for example one or more solid and/or fluid phases such as fat and/or water liquid phases and/or gaseous phases such as emulsions, dispersions, creams and/or foams.
  • solid and/or fluid phases such as fat and/or water liquid phases and/or gaseous phases such as emulsions, dispersions, creams and/or foams.
  • a further aspect of the invention comprises a foodstuff comprising choco- material and/or choco-composition as described herein.
  • a yet further aspect of the invention broadly comprises use of a choco-material of or prepared according to the invention as a choco-confectionery product and/or as a filling and/or coating for a foodstuff of the invention as described herein.
  • the process may be performed in any type of equipment which is able to perform a mixing action at modulated speed.
  • this type of equipment are: vertical and horizontal mixers, turbo mixers, planetary and double planetary mixers, continuous mixers, inline mixers, extruders, screw mixers, high shear and ultra-high shear mixers, cone and double cone mixers, static and dynamic mixers, rotary and static drum mixers, rotopin mixer, ribbon blenders, paddle blenders, tumble blenders, solids/liquid injection manifold, dual-shaft and triple shaft mixers, high viscosity mixers, V blenders, vacuum mixers, jet mixers, dispersion mixers, mobile mixers and banbury mixers.
  • Such utility may be direct for example where a moiety has the required properties for the aforementioned uses and/or indirect for example where a moiety has use as a synthetic intermediate and/or diagnostic and/or other tool in preparing other moeity of direct utility.
  • these terms also denote that sub-entity of a whole (such as a component and/or ingredient) is compatible with producing effective, acceptable, active and/or suitable end products and/or compositions.
  • Preferred utility of the present invention comprises use as a food stuff, preferably as a confectionery product and/or intermediate in the manufacture thereof.
  • boundary value is included in the value for each parameter. It will also be understood that all combinations of preferred and/or intermediate minimum and maximum boundary values of the parameters described herein in various embodiments of the invention may also be used to define alternative ranges for each parameter for various other embodiments and/or preferences of the invention whether or not the combination of such values has been specifically disclosed herein.
  • substantially can be understood to mean quantitatively (in relation to whatever quantity or entity to which it refers in the context of the description) there comprises an proportion of at least 80%, preferably at least 85%, more preferably at least 90%, most preferably at least 95%, especially at least 98%, for example about 100% of the relevant whole.
  • substantially-free may similarly denote that quantity or entity to which it refers comprises no more than 20%, preferably no more than 15%, more preferably no more than 10%, most preferably no more than 5%, especially no more than 2%, for example about 0% of the relevant whole.
  • such percentages are by weight.
  • compositions of and/or used in the present invention may also exhibit improved properties with respect to known compositions that are used in a similar manner. Such improved properties may be (preferably as defined below) in at least one, preferably a plurality, more preferably three of more of those propert(ies) labelled 1 to 12 below. Preferred compositions of and/or used in the present invention, may exhibit comparable properties (compared to known compositions and/or components thereof ) in two or more, preferably three or more, most preferably in the rest of those properties labelled 1 to 12 below.
  • Improved properties as used herein means the value of the component and/or the composition of and/or used in the present invention is > +8% of the value of the known reference component and/or composition described herein, more preferably > +10%, even more preferably > +12%, most preferably > +15%.
  • Comparable properties as used herein means the value of the component and/or composition of and/or used in the present invention is within +/-6% of the value of the known reference component and/or composition described herein, more preferably +/- 5%, most preferably +/- 4%.
  • the percentage differences for improved and comparable properties herein refer to fractional differences between the component and/or composition of and/or used in the invention and the known reference component and/or composition described herein where the property is measured in the same units in the same way (i.e. if the value to be compared is also measured as a percentage it does not denote an absolute difference).
  • the aerated samples are filled to the brim in containers of the same size and the surface levelled off to be initially flush with the rim of the container. After the same amount of time at room temperature or higher but not above 30 degrees (a few minutes unless otherwise indicated) the containers are re-assessed visually.
  • the aeration is unstable the bubbles coalesce to from a large bubbles with a greater overall volume and this will create a dome on the test sample. The larger the dome that is formed on the sample the more unstable the aeration is.
  • Samples where the aerated matrix is stable do not change volume and do not form a dome, exhibiting an unchanged a flat surface at the container rim.
  • bubble size values given herein are measured by X-ray tomography and/or confocal laser scanning microscopy (CLSM) as described below.
  • Bubble size may be determined by measuring the volume distribution of the sample by plotting volume (%) versus size (microns) for example from images generated using the techniques described herein. Bubble size is then quoted as the linear dimension which corresponds to the diameter of an approximate spherical bubble having the same volume as the mean volume calculated from the measured volume distribution and is referred to herein as mean bubble size in microns.
  • a normal bubble size distribution (BSD) with single maximum peak (mono modal) is assumed in most cases for the bubbles generated in the present invention.
  • BSDs e.g. multimodal such as bimodal
  • the BSD is measured by the standard derivation from the mean bubble size also measured in microns.
  • d90 may also be used (also expressed in linear dimensions) which denotes the size of bubble below which 90% (by number) of the bubbles in a given aerated sample lie.
  • the parameter denoted by a symbol in the format XP, O is measured in units of length (e.g. microns) and denotes that bubble diameter for which P % of the total number of bubbles counted in the sample have a diameter smaller or equal to the length given for this parameter.
  • Xso.o 1 micron
  • Parameter X 5 o,o is commonly used to indicate number weighted diameter but analogously, parameters Xgo.o and Xio,o (the diameters below wich respectively 90 % and 10 % of all bubbles lie) may also be used.
  • SPAN (Q0) may be calculated for the number based bubble size distribution by determining the ratio of (X9o,o- Xio,o) / X5o,o. This is a measure to evaluate the width of the number weighted bubble size distribution.
  • a lower SPAN (Q0) value indicates a narrower bubble size distribution and with this a more homogenous and more stable foam structure.
  • the parameter denoted by the symbol in the format XP, 3 is measured in units of length (e.g. microns) and denotes that bubble diameter for which P % of the total volume taken by the bubbles in the sample have a diameter smaller or equal to the length given for this parameter.
  • Xso,3 1 micron
  • Parameter X 5 o,3 is commonly used to indicate volume weighted diameter but analogously, parameters X3 ⁇ 4),3 and Xio,3 (the diameters at which respectively 90 % and 10 % of the volume occupied by all bubbles lie) may also be used.
  • SPAN (Q3) was calculated for the volume weighted bubble size distribution by determining the ratio of (Xgo,3 - Xio,3) / Xso,3. This is a measure to evaluate the width of the volume weighted bubble size distribution.
  • a lower SPAN (Q3) value indicates a narrower bubble size distribution and with this a more homogenous and more stable foam structure.
  • a rotating sample is bombarded with polychromatic X-rays, and X-ray intensity resulting from interaction with the sample is spatially recorded by a pixelated planar detector which forms a two dimensional image of the projected absorption of the sample.
  • a three dimensional reconstruction of the sample is then performed from the collection of 2D projections using back projection algorithms. This is described in 'Principle of X-ray tomography', K.S Lim, M. Barigou, X-ray micro-computed tomography of cellular food products, Food Research International 37 (2004) 1001-1012.
  • X-ray tomography is non-invasive and is a powerful technique for mapping air voids embedded in a solid matrix (such as the bubbles in micro- aerated chocolate).
  • X-ray tomography has a high resolution of up to 1 ⁇ and no sample preparation is required, it provides an easy, quantitative means of evaluating bubble sizes from the images generated.
  • samples evaluated herein by X-ray tomography used the instrument MicroCT 35 available commercially from Scanco medical AG.
  • the samples (e.g. chocolate pieces) to be X-rayed were gently cut in the z-axis using razor blades and small cylinder like samples were trimmed and placed in sample holders.
  • CLSM complementary metal-oxide-semiconductor
  • samples evaluated herein by CLSM used the confocal microscope available commercially from Leica instrument under the trade designation LAS, Type DM6000.
  • the samples (e.g. chocolate pieces) to undergo CLSM were gently cut in the z-axis using razor blades and small cylinder like samples were trimmed and placed in sample holders. Then samples were then dyed for the confocal microscope using first Nile red then adding Fast green (as shown in the table below).
  • the Nile red signal is displayed in a red look-up-table and the Fast green one in a green look-up-table. The remaining dark areas having a circular shape are therefore assumed to be gas bubbles.
  • the sugar is represented by smaller black areas with irregular
  • bubble diameter can be measured using the scale which is integrated into the image software.
  • Porosity values (P) stated as a percentage were derived from computed tomography evaluation. Porosity describes the ratio of void fraction to the total volume of a sample. Hence porosity represents the ratio of the volume of gas VG within a sample to the total sample volume V s , hence VGA S. Porosity may also be estimated as otherwise described herein or calculated from Over-Run (OR) measurements (also stated as a percentage) in standardized plastic cups using the following equations.
  • Foamed confectionary samples were stored below 5 °C until analysis.
  • the samples may be analyzed using a CT 35 (Scanco Medical, Brijttisellen, Switzerland) operated in a climate chamber set to 15 °C.
  • the bubble detection resolution of the device is 6 micron.
  • Cumulative bubble size distributions Q(x) (characterized by: Xso,3 X3 ⁇ 4),3 Xio,3 and Xso.o ⁇ , ⁇ Xio,o), VG and Vs, may be measured by computer X-ray tomography and extracted by image analysis. From the bubble sizes Xso,3 ⁇ ,3 Xio,3 and Xso.o ⁇ , ⁇ XIO,O the size distribution widths SPAN(Q3), SPAN(QO) can also be derived.
  • standard conditions e.g. for defining a solid fat or liquid oil
  • atmospheric pressure e.g., a relative humidity of 50% ⁇ 5%
  • ambient temperature 22°C ⁇ 2°
  • air flow less than or equal to 0.1 m/s. Unless otherwise indicated all the tests herein are carried out under standard conditions as defined herein.
  • Texture of foodstuffs is perceived as a composite of many different characteristics comprising various combinations of physical properties (such as mechanical and/or geometrical properties) and/or chemical properties (such as fat and/or moisture content).
  • the composition texture can be related to the viscosity of the composition as a fluid when subjected to shear stress.
  • apparent viscosity can be used herein as a guide to indicate texture.
  • viscosity refers to the apparent viscosity of a fluid as measured by conventional methods known to those skilled in the art but in particular the method described herein is preferred. Some fluids display non-Newtonian rheology and cannot be totally characterized by a single rheological measurement point. Despite this apparent viscosity is a simple measure of viscosity useful for the evaluation of such fluids.
  • the viscosity of the compositions according to the invention and/or prepared by a method of the invention, as well as comparative examples, can be characterized by two measurements, one at about 5s "1 for low flow situations to approximate to the yield value and a second one at 20s "1 for higher flow rates. (See Beckett 4th edition, chapter 10.3).
  • the yield value of viscosity is used to determine texture measured at a low flow rate of 5s "1 .
  • the preferred method for measuring the yield value for viscosity uses an instrument denoted by the trade designation RVA 4500 (available commercially from Rapid Viscosity Analyzer, Newport Scientific, Australia) measured under standard conditions (unless otherwise indicated) and at a rate of 5s "1 .
  • RVA 4500 available commercially from Rapid Viscosity Analyzer, Newport Scientific, Australia
  • 10 grams of the sample composition are added to the canister supplied with the RVA instrument and then measurement is performed using the following profile: a constant temperature of 35°C, mixing vigorously at 950 rpm for 10 seconds then at 160 rpm for the duration of the test which is 30 minutes.
  • the test is done in duplicates or triplicates to ensure repeatability.
  • the final viscosity is used for comparison as well as the quality of the RVA viscosity curve.
  • Figure 1 is a photograph of a cross section of comparative chocolate of the invention (Comp A) which was aerated with nitrogen to achieve a porosity of 5%. As can been many larger bubbles are formed with overall a wider size distribution of bubbles due to coalescence of the initially smaller bubbles when a low amount of gas is initially dispersed into the chocolate mass.
  • Figure 2 is a photograph showing the difference in stability between chocolate aerated to from left to right Comp B (porosity of 10%), Example 1 (porosity of 12.5%) and Example 2 (porosity 15%).
  • Figure 3 is a photograph showing the instability of chocolate aerated at a higher level (from left to right Comp C (porosity 20%) and Comp D (porosity 25%)
  • Figure 4 shows the mixer head of a rotor stator mixer available commercially from Hass under the trade mark Monodmix®
  • Figure 5 shows the mixer blades from the mixer head of a rotor stator mixer available commercially from Hass under the trade mark Monodmix®
  • Figure 6 shows the modular mixer head of a rotor stator mixer used by Nestle under the trade mark Nestwhipper®
  • Figure 7 is a schematic drawing of the gas injector referred to herein as Novae (as described in WO2005-063036) combined with a jet depositor system (as described in WO2010/102716).
  • Figure 8 shows a prior art micro-aerated chocolate sample - Comp E (micro-aerated to 12% porosity) which has been tested in the aeration test described herein, the sample surface having risen due to instability of the incorporated gas.
  • Figure 9 shows a micro-aerated chocolate sample of the invention - Example 3 - (micro- aerated to 15% porosity, simply by increasing the gas flow slightly compared to Comp E shown in Figure 8), where there is no dome formed at the sample surface when tested in the aeration test described herein, indicating the aeration becomes stable at a level of 15% porosity.
  • Figure 10 shows a micro-aerated chocolate tablet micro-aerated to 10% porosity using and formed in an angular mould, i.e. where the vertices form sharp corners. In the tablet shown in Figure 10 bubbles are clearly visible on the surface of the angular mould, and also appear consistently at the same position on each pip. The appearance of the tablet is aesthetically undesirable.
  • Figure 1 1 shows a micro-aerated chocolate tablet made from a micro-aerated chocolate mass aerated to 10% porosity using the same chocolate and process conditions as for the tablet shown in Figure 10, but formed in a mould having rounded vertices, i.e. the only difference in the tablets shown in Figures 10 or 1 1 being the mould design. As can been seen the visual appearance of this tablet compared to that of Figure 10 is more homogenous and aesthetically is much improved.
  • Figure 12 to 16 herein show tablets produced using the same chocolate mass, all temper and mini Novae parameters being kept constant, apart from the gas flow which was adjusted to give the desired porosity level. It is particularly interesting to note the fact that at lower aeration levels, not only is the aeration visible but also the de-moulding properties are impacted. The reason behind this impact on de-moulding is not understood but impacts most masses that have been tested.
  • Figure 12 shows a micro-aerated dark chocolate with 5% porosity (Nestle, Brazil). Please note the visible bubbles and also marks resulting from poor de-moulding.
  • Figure 13 shows a micro-aerated dark chocolate with 10% porosity: good de-moulding and invisible bubbles. The mass did rise during the cup test, showing some signs of instability.
  • Figure 14 shows a micro-aerated dark chocolate with 15% porosity: good homogeneous aeration and de-moulding properties. The 'cup' test showed the aeration to be very stable.
  • Figure 15 shows a micro-aerated dark chocolate with 20% porosity: bubbles have started to coalesce and are clearly visible inside the bar.
  • Figure 16 shows a micro-aerated dark chocolate with 23% porosity: bubbles have started to coalesce and are clearly visible inside and at the surface of the bar. It was not possible to increase the porosity any further than 23% by just adjusting the gas flow alone.
  • Figures 17, 18 and 19 are images of a micro-aerated sample of the chocolate mass used (when unaerated) to prepare the confectionery product sold by the applicant in Brazil as chocolate tablets under the trade mark Garoto® (see Example 5 and Table 2 herein), where Figure 17 was generated with X-ray tomography, Figure 18 with confocal microscopy (CLSM) and Figure 19 is a 3D visualization of the micro-aerated Garoto® chocolate.
  • Figures 20 to 25 show data supporting enhanced satisfaction of consumers eating micro- aerated chocolate compared to non-aerated chocolate
  • Figure 26 is a photo of milk chocolate samples Example 9 and Comp H.
  • Figure 27 is a generic mould design (also referred to herein as a 'Beech bar') used in the test protocol to assess contraction of micro-aerated chocolate in a mould.
  • Figure 28 shows a first step in which a mould is conditioned at a typical temperature of from 29 to 32 °C.
  • Figure 29 shows a second step from the same process as shown in Figure 28 , in which chocolate is sprayed onto the mould inner surfaces in an amount to create a thin (0.1 mm to 0.5 mm) layer thereon.
  • the total thickness of the chocolate layer surrounding the wafer insert is from 0.6 to 2 mm.
  • Figure 30 shows a third step from the same process as shown in Figures 28 and 29 in which a suitable amount of micro aerated chocolate (up to 15% micro-aeration) is deposited onto the shell formed within the mould in step two .
  • Figure 31 shows a fourth step from the same process as shown Figures 28, 29 and 30 in which wafer fingers are placed into the mould.
  • Figure 32 shows a fifth step from the same process as shown Figures 28, 29, 30 and 31 in which further chocolate is applied to wafer to coat entire product.
  • Figure 33 is a colour photograph of a cross-section of two chocolate bars to illustrate the difference between the conventional way of producing a known macro-aerated product with an shell (shown on the left) and a product of the present invention (shown on the right).
  • the conventional prior art product shown on the left has a thick visible layer of a chocolate shell whereas in the present invention shown on the right side of the photograph the micro-aeration present in the chocolate layer surrounding the wafer core of the product is almost invisible.
  • Figure 34 is a closer view of a cross-section of the product of the invention shown to the right in Figure 33.
  • Figure 35 shows two wafer fingers.
  • the finger on the right is a known wafer which was coated with micro-aerated chocolate only.
  • the finger of the left was prepared according to the invention prepared with a combination of micro-aerated chocolate coating also formed in a mould pre-sprayed with chocolate.
  • the colour of the wafer of the present invention is much closer to a conventional chocolate wafer and so is acceptable to the consumer but has much less calories than a conventional wafer coated conventionally with chocolate.
  • Comparative example A is a chocolate aerated with nitrogen to achieve a porosity of 5%.
  • Figure 1 photograph of a cross section
  • Comp A contains many large bubbles (some of which are very visible to the naked eye) and overall exhibits a wide distribution of bubble sizes. Without wishing to be bound by any theory the applicant believes that this may be due to coalescence of the small bubbles initially formed when a low amount of the nitrogen gas was dispersed into the chocolate mass.
  • Figure 2 is a photograph showing these examples (respectively from left to right Comp B, Example 1 and Example 2) after undergoing the aeration stability test as described herein.
  • Figure 3 is a photograph showing the instability of these samples (left to right Comp C and D) after they have undergone the aeration stability test as described herein. Visible aeration can be seen on the surface of the chocolate especially for Comp D.
  • Comp C and D were also found to exhibit too large a viscosity to be easily handled especially in an industrial process under the normal temperatures at which moulding and demoulding occurs. For example these samples were found to be too viscous to readily flow into moulds to provide good surface definition.
  • the resultant moulded products made from Comp C or Comp D were also very difficult to be removed from a mould (demould) without damage to the product. So surprisingly the applicant has found that there is an upper limit to micro- aerating chocolate. Adding gas to chocolate as small bubbles (micro-aeration) to achieve porosity levels of 20% or above has been shown to be impractical.
  • the optimal porosity range is believed to be from 12.5% - 15% for the micro-aerated chocolate masses tested. Surprisingly these porosities were found to gives a workable viscosity and a stable and homogeneous micro-aeration (invisible bubbles to the naked eye) as seen in the profile of bubble size distribution. For micro-aerated chocolate with porosities above 15%, viscosity starts to become a challenge, before significant coalescence occurs at porosity above 20%. Micro-aerated chocolate prepared with much lower porosity (e.g. see Comp A oft 5% porosity) also forms inhomogeneous bubbles which is both visually unappealing and effects the organoleptic properties of the chocolate.
  • the following product recipe for a chocolate mass (sold by the applicant in Mexico as a chocolate tablet under the registered trademark Carlos V) was aerated with Nitrogen
  • the bubble size and BSD present in various samples of conventional chocolate masses, which were then micro-aerated at different levels) were evaluated using two methods of bubble measurement, X-ray tomography and CLSM.
  • KitKat® Micro-aerated samples of the chocolate mass used (when unaerated) to coat the confectionery product sold under the trade mark KitKat®, referred to in Table 2 as KitKat®. It can be seen that a low levels of aeration (Comp E), the bubbles coalesce and are thus have a larger mean size (> 200 microns) and broader BSD. The larger bubbles are noticeable to the naked eye. At higher levels of aeration surprisingly both the mean bubble size and standard deivation decreases (narrower BSD, i.e more uniform, smaller bubble size).
  • Pictures of micro-aerated Garoto obtained with X-ray tomography are shown in Figure 17 and confocal microscopy (CLSM) in Figure 18.
  • a 3D visualization of micro-aerated Garoto chocolate is shown in Figure 19 where the different colours represent the different depths and highlight the presence of bubbles as described herein.
  • a micro-aerated dark chocolate (Example 7) was tested against the same conventional non aerated dark chocolate (Comp F, the dark chocolate tablet sold under the trademark Nestle Classic® in Brazil). Data for micro-aerated dark chocolate shows improved texture in mouth leading to a more pleasurable and mindful eating experience. This is shown in Figures 20 and 21 herein. Consumers eat a smaller amount of micro-aerated chocolate than a classic chocolate tablet as shown in Figure 21 Consumers were more satisfied with a micro-aerated chocolate tablet at each eating occasion, and overall. Micro-aerated solid structures also produces improved texture, e.g. dynamics of hardness, softness, crispness and dryness, better mouthfeel, pleasure and intake. Eating behaviours for example eating duration, sucking versus biting and mouthful frequency are also enhanced. In mouth transformation for example dynamic of bolus transformation is enhanced in micro-aerated chocolate
  • Example 8 A micro-aerated dark chocolate (Example 8) was tested against a conventional non aerated dark chocolate (Comp G, the dark chocolate tablet sold under the trademark Nestle Classic® in Brazil). The same dark chocolate recipe and the same mould (24 squares) was used for both Example 8 and Comp G. The degree of aeration of Example 8 was between 10 to 15% micro-aerated. Consumer tests for dark and milk chocolate are shown below. The extent to which the consumer desire to eat chocolate has been satisfied was shown in Figure 22 and 23.
  • Example 9 A micro-aerated milk chocolate (Example 9) was tested against the same conventional non aerated milk chocolate (Comp H, the milk chocolate table sold under the trademark Orion® in the Czech Republic). The same milk chocolate recipe and the same mould (24 squares) was used for both Example 9 and Comp H. The degree of aeration of Example 9 was 14% micro-aerated. Consumer tests milk chocolate are shown below The extent to which the consumer desire to eat chocolate has been satisfied was shown in Figure 24 and 25 and a photo of the two samples (Ex 9 and Comp H) is shown in Figure 26.
  • a two fingered wafer bar coated with chocolate was prepared conventionally from a mould with the addition of a micro-aeration and a mould spray coating step.
  • Wafer fingers 6.3 g

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Abstract

La présente invention concerne du chocolat micro-aéré dans lequel sont dispersées des micro-bulles d'un gaz inerte (par exemple, de l'azote) et caractérisé par les paramètres suivants ; (a) une taille de bulle moyenne inférieure ou égale à 100 micromètres, (b) une dérivation standard de taille de bulle inférieure ou égale à 60 micromètres ; (c) une surface de bulle totale comprise entre 0,5 et 0,9 m2 pour 100 g de chocolat et (ii) les bulles de gaz étant réparties de manière homogène à l'intérieur du chocolat, présentant un indice d'homogénéité d'au moins 0,8. La présente invention concerne également un procédé d'aération de chocolat. Ledit procédé comprend les étapes consistant à : (I) mélanger du chocolat sous un cisaillement élevé d'au moins 1 000 s-1 présentant une viscosité avant l'aération (dans des conditions standard) de 0,1 à 10 Pa.s, éventuellement à l'aide d'un mélangeur rotatif à une vitesse de 100 à 300 tours/minute ; et (II) disperser un gaz inerte dans le chocolat facultativement par l'intermédiaire d'une ou de plusieurs buses de gaz à un débit de 2,4 à 12 kg/min et/ou une pression de gaz de 2 à 30 bars, pour produire le chocolat micro-aéré selon l'invention.
PCT/EP2017/071746 2016-08-30 2017-08-30 Composition, procédé et utilisation WO2018041884A2 (fr)

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CN201780033994.9A CN109195449A (zh) 2016-08-30 2017-08-30 微充气巧克力物质
AU2017320784A AU2017320784B2 (en) 2016-08-30 2017-08-30 Micro-aerated choco-material
RU2018142002A RU2738415C2 (ru) 2016-08-30 2017-08-30 Композиция, способ и применение
BR112018074693-2A BR112018074693B1 (pt) 2016-08-30 2017-08-30 Material de chocolate moldado microaerado, seu processo de produção, e uso de microaeração em um material de chocolate moldado
JP2018561508A JP6990666B2 (ja) 2016-08-30 2017-08-30 マイクロエアレーションされたチョコ材料
MX2018014801A MX2018014801A (es) 2016-08-30 2017-08-30 Composicion, proceso y uso.
CA3025871A CA3025871A1 (fr) 2016-08-30 2017-08-30 Matiere de chocolat microaeree
EP17761239.7A EP3451847A2 (fr) 2016-08-30 2017-08-30 Composition, procédé et utilisation
ZA2018/08136A ZA201808136B (en) 2016-08-30 2018-11-30 Micro-aerated choco-material

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JP2021168692A (ja) 2021-10-28
RU2738415C2 (ru) 2020-12-14
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ZA201808136B (en) 2022-05-25
EP3451847A2 (fr) 2019-03-13
JP7220258B2 (ja) 2023-02-09
AU2017320784A1 (en) 2018-11-22
PE20190053A1 (es) 2019-01-11
CL2018003427A1 (es) 2019-01-25
WO2018041884A3 (fr) 2018-04-12
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RU2020139220A (ru) 2021-01-20
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