WO2016010334A1 - 자동차용 내장재 및 이의 제조방법 - Google Patents
자동차용 내장재 및 이의 제조방법 Download PDFInfo
- Publication number
- WO2016010334A1 WO2016010334A1 PCT/KR2015/007285 KR2015007285W WO2016010334A1 WO 2016010334 A1 WO2016010334 A1 WO 2016010334A1 KR 2015007285 W KR2015007285 W KR 2015007285W WO 2016010334 A1 WO2016010334 A1 WO 2016010334A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- polyurethane dispersion
- interior materials
- water dispersible
- coating layer
- Prior art date
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Images
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/308—Heat stability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/003—Interior finishings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Definitions
- It relates to a vehicle interior and a method of manufacturing the same.
- resin molded parts are used for automobile console boxes and panels around instrument panels as interior and exterior materials of automobiles, and resin molded articles are widely used in home appliances such as cases and covers of electric rice cookers.
- dashboards In particular, various controls and convenience devices are installed in dashboards, audio decks, gear transmissions, airbags, door locks, and window openings and the like, which are mounted around the driver's seat and the passenger seat inside the vehicle.
- interior finishing panel In the gap between the interior of the interior and the interior material is installed interior finishing panel to finish the interior material, such interior material has become an important factor to determine the appearance of the interior of the vehicle.
- the interior material for automobiles has a considerable influence on the aesthetics of the interior of the vehicle, and thus the aesthetic demand in appearance is gradually increasing in the current trend in which the automobile is individualized.
- One embodiment of the present invention includes a coating layer on the veneer layer, and provides an automotive interior material which is an injection molded article including a back layer or a front layer on both sides of the coating layer.
- Another embodiment of the present invention provides a method for manufacturing the automotive interior.
- a vehicle interior including a coating layer on both sides of the veneer layer, a back layer on the coating layer on one surface of the veneer layer, and a front layer on the coating layer on the back surface of the veneer layer.
- the coating layer may be formed from the water dispersible polyurethane dispersion or the water dispersible acrylic polyurethane dispersion.
- the water dispersible polyurethane dispersion or the water dispersible acrylic polyurethane dispersion may comprise about 10 wt% to about 40 wt% solids.
- the water dispersible polyurethane dispersion or the water dispersible acrylic polyurethane dispersion may further include a silica compound.
- the water dispersible polyurethane dispersion or the water dispersible acrylic polyurethane dispersion may include 5 to 30 parts by weight of the silica compound relative to 100 parts by weight of solids.
- the thickness of the coating layer may be about 5um to about 50um.
- the thickness of the veneer layer may be about 100um to about 600um.
- the front and back layers are each selected from the group consisting of acrylic resins, polycarbonate resins, acrylonitrile-butadiene-styrene copolymers (ABS) resins, polyester resins, polymethylmethacrylate (PMMA) resins, and combinations thereof It may include one or more thermoplastic resins.
- providing a veneer layer Forming a coating layer by coating and drying a water dispersible polyurethane dispersion or a water dispersible acrylic polyurethane dispersion on both sides of the veneer layer; Preforming a real wood film layer having a coating layer formed on both surfaces of the veneer layer; Forming a rear layer by injection molding a first insert into the coating layer on one surface of the veneer layer; And forming a front layer by injecting a second insert into the coating layer on the back surface of the veneer layer.
- the water dispersible polyurethane dispersion or may further comprise the step of adding a silica compound to the water dispersible acrylic polyurethane dispersion.
- the silica compound may be formed by a sol-gel process.
- the preforming may be performed in a time of about 20 seconds to about 120 seconds at a temperature of 100 °C to 150 °C.
- the automotive interior manufacturing method may further include cutting an unnecessary portion of the realwood film layer after the preforming.
- the primary insert injection and the secondary insert injection may be performed simultaneously.
- the first insert injection and the second insert injection may be performed at a temperature of about 200 °C to about 250 °C.
- the interior materials for automobiles are excellent in heat resistance, adhesion and formability, and can realize a luxurious texture in appearance.
- the automobile interior manufacturing method can improve the high defect rate due to the high process cost and complexity of the manufacturing process and can reduce the manufacturing cost.
- Figure 1 shows a cross section of the interior material for automobiles which is an embodiment of the present invention.
- FIG. 2 is a schematic diagram illustrating a method for manufacturing a vehicle interior material which is another embodiment of the present invention.
- a vehicle interior including a coating layer on both sides of the veneer layer, a back layer on the coating layer on one surface of the veneer layer, and a front layer on the coating layer on the back surface of the veneer layer.
- the interior design of the car can be advanced, and it has been used for the crash pad or the door garnish.
- the manufacturing process of the interior material including the real wood is complicated, and due to the high manufacturing cost has been difficult to expand to the automotive market.
- the automotive interior material is manufactured by the manufacturing method described below, thereby improving the high defect rate due to the high process cost and complexity of the manufacturing process, and can reduce the manufacturing cost, heat resistance, adhesion and molding due to the veneer layer and coating layer It is excellent in appearance and can realize a luxurious texture in appearance.
- the vehicle interior material 100 includes a coating layer 20 on both sides of a veneer layer 10, and one surface of the veneer layer.
- the coating layer 20 of the back layer 40, the coating layer on the back of the veneer layer may include a front layer 30.
- the automotive interior material is to ensure heat resistance, adhesion and formability by including the coating layer 20 on both sides of the veneer layer 10, it is possible to form a realwood film layer by including a coating layer on both sides of the veneer layer.
- the coating layer may be formed from a water dispersible polyurethane dispersion or a water dispersible acrylic polyurethane dispersion, and the water dispersible polyurethane dispersion or the water dispersible acrylic polyurethane dispersion may be water dispersible acrylic polyurethane resin particles or water dispersible polyurethane resin, respectively. It refers to a solution in which particles are uniformly dispersed.
- the coating layer may include a water dispersible polyurethane resin or a water dispersible acrylic polyurethane resin, and the water dispersible polyurethane resin or the water dispersible acrylic polyurethane resin may improve thermal resistance of the coating layer to thermal stability in a preforming step. It can be maintained, and during the injection can ensure improved adhesion and formability, can be pressed to the veneer layer can reinforce the disadvantages of the veneer layer.
- the water-dispersible polyurethane resin is formed by synthesizing a polyol compound and an isocyanate compound.
- a polyol compound For example, polycarbonate diol, isophorone diisocinate and dimethylol propionic acid may be synthesized. remind The water-dispersible polyurethane resin can penetrate the surface of the veneer layer containing a lot of hydrophilic groups and pores smoothly to impart elasticity to the veneer layer having low formability, and molding of the veneer layer according to preforming and injection molding. Can be easily implemented.
- the water-dispersible acrylic polyurethane resin may be formed by adding an acrylic monomer compound to the water-dispersible polyurethane resin, for example, the acrylic monomer compound may include methyl methacrylate.
- the water-dispersible acrylic polyurethane resin like the water-dispersible polyurethane resin, penetrates smoothly into the pores and surfaces of the veneer layer containing a lot of hydrophilic groups to impart elasticity to the veneer layer having low moldability and is preformed. And molding of the veneer layer according to the injection molding can be easily implemented.
- the water dispersible polyurethane resin dispersion or the water dispersible acrylic polyurethane resin dispersion may include about 10 wt% to about 40 wt% solids.
- the solid content is less than about 10% by weight, sufficient resin may not penetrate into the surface and the pores of the veneer layer, and thus moldability may be reduced.
- the content is more than about 40% by weight, the thickness of the coating layer is increased. Since the shape according to the molding can be restored without maintaining, it is advantageous to secure the formability of the veneer layer to maintain the solid content in the above range.
- the coating layer may further include a silica compound.
- the silica compound refers to a compound containing silica as a main component, and may improve heat resistance of the coating layer due to the silica compound. That is, the water dispersible polyurethane dispersion or the water dispersible acrylic polyurethane dispersion for forming the coating layer may further include a silica compound.
- the water dispersible polyurethane dispersion or the water dispersible acrylic polyurethane dispersion may include about 5 to about 30 parts by weight of the silica compound, based on 100 parts by weight of solids, for example, about 5 to about 20 parts by weight. can do.
- the silica compound is included in the content of the above range, it is possible to improve the heat resistance of the coating layer, it is possible to improve the heat dispersion and heat resistance of the veneer layer, the veneer layer by the heat transferred from the mold during preforming and injection molding The burning phenomenon of can be suppressed.
- the thickness of the coating layer may be about 5um to about 50um. If the thickness of the coating layer is less than about 5um may formability of the veneer layer may be lowered, and if the thickness exceeds about 50um there is a problem that can be restored without maintaining the shape according to the molding, to maintain the range Form can be maintained.
- the veneer layer means real wood, and the appearance of the veneer layer is higher than that of conventional veneer plywood, plastic plywood, and the like, thereby imparting sophistication and aesthetics to the interior of an automobile.
- the thickness of the veneer layer may be about 100um to about 600um, for example, 150um to about 250um.
- the veneer layer may include a coating layer on both sides to form a real wood film layer, but may not be distorted even though the thickness is thin.
- the veneer layer real wood may include a single natural wood layer, and the natural wood layer may include veneers thinly laminated with cypress, walnut, aplomocia, and buzzeye trees. It may include.
- the veneer layer may include a natural wood layer formed on the base material
- the base material may include kraft paper, paper made of pulp, etc., minimizing cracking and cracking of the natural wood layer can do.
- the backing layer 40 may be included in the coating layer on one surface of the veneer layer, and the front layer 30 may be included in the coating layer on the back surface of the veneer layer.
- the front layer and the rear layer is a layer formed by injecting the thermoplastic resin into one or the back of the coating layer to serve as a support for durability and shape maintenance of the automotive interior material, the front layer can also implement the interior effect. .
- the front and back layers are each selected from the group consisting of acrylic resins, polycarbonate resins, acrylonitrile-butadiene-styrene copolymers (ABS) resins, polyester resins, polymethylmethacrylate (PMMA) resins, and combinations thereof It may include one or more thermoplastic resins.
- the thickness of the front layer and the back layer may be about 1mm to about 3mm, respectively.
- Another embodiment of the invention providing a veneer layer; Forming a coating layer by coating and drying a water dispersible polyurethane dispersion or a water dispersible acrylic polyurethane dispersion on both sides of the veneer layer; Preforming a real wood film layer having a coating layer formed on both surfaces of the veneer layer; Forming a rear layer by injection molding a first insert into the coating layer on one surface of the veneer layer; And forming a front layer by injecting a second insert into the coating layer on the back surface of the veneer layer.
- FIG 2 is a schematic diagram of a method for manufacturing a vehicle interior material, which is another embodiment of the present invention, referring to Figure 2, the method for manufacturing a vehicle interior material, forming a coating layer on both sides of the veneer layer, preforming, back injection and By including the front injection step can be manufactured for automotive interior material injection molding.
- the coating layers formed on both sides of the veneer layer are for securing heat resistance at the time of preforming, and for securing adhesion at the time of injection molding, and the water-dispersed polyurethane dispersion or the water-dispersed acrylic containing about 10% by weight to about 40% by weight of solids.
- Polyurethane dispersion may be formed by applying a thickness of about 20um to about 50um with a bar coater (Mayer Bar coater) on both sides of the veneer layer, and dried for about 2 minutes to about 5 minutes in an oven of about 100 °C to about 150 °C .
- the water dispersible polyurethane dispersion or may further comprise the step of adding a silica compound to the water dispersible acrylic polyurethane dispersion.
- the silica compound may be added to increase the heat resistance of the coating layer, and may be added in an amount of about 5 parts by weight to about 30 parts by weight based on 100 parts by weight of the solid content of the water dispersible polyurethane dispersion or the water dispersible acrylic polyurethane dispersion.
- the silica compound may be formed by a sol-gel process.
- the sol-gel process is a process of forming a compound through a gel in a sol obtained by hydrolysis, and the silica compound may be a silica sol formed by the sol-gel process.
- the coating layer may be formed on both sides, and then the pre-formation of the veneer layer, that is, the real wood film layer, on which the coating layer is formed may be included.
- the preforming is a process that proceeds to secure a suitable form before the injection molding proceeds, the preforming may be performed in a time of about 20 seconds to about 120 seconds at a temperature of about 100 °C to about 150 °C.
- the real wood film layer having the coating layers formed on both surfaces of the veneer layer may be formed in a suitable shape to be applied to injection molding, and the real wood film layer may be formed by performing the preforming within the range of temperature and time. Minimization of cracking and folding can be minimized.
- the automotive interior manufacturing method may further include cutting an unnecessary portion of the realwood film layer after the preforming.
- unnecessary parts not included in the molded article may occur, and at this time, the unnecessary parts may be cut.
- the cutting may be performed through a known cutting process such as laser cutting, knife cutting.
- the final molded product By performing the first insert injection or the second insert injection to the coating layer on one side or the back side of the preformed realwood film layer, the final molded product can be secured, and the molded product can be used as interior materials for automobiles.
- the back layer may be formed through the first insert injection, and the front layer may be formed through the second insert injection.
- the first insert injection and the second insert injection may be performed separately or simultaneously.
- the first insert injection and the second insert injection may be performed at a temperature of about 200 °C to about 250 °C.
- the temperature at which the insert injection is performed may be controlled according to the thermoplastic resin provided, and the thermoplastic resin may be an acrylic resin, a polycarbonate resin, an acrylonitrile-butadiene-styrene copolymer (ABS) resin, a polyester resin, or a polymethyl It may include one or more selected from the group consisting of methacrylate (PMMA) resin and combinations thereof.
- ABS acrylonitrile-butadiene-styrene copolymer
- PMMA methacrylate
- the temperature is less than about 200 °C the flowability of the thermoplastic resin is lowered may not be smooth to form the front layer and the back layer, if it exceeds about 250 °C soot occurs in the realwood film layer, or the film The layer may stick to the mold.
- the front layer may be formed through a polyurethane casting molding process, a spray process, a powder coating process, or the like.
- a 150 um thick veneer layer was prepared using a buzzeye tree. On both sides of the veneer layer, silica particles containing 10% by weight relative to solids and water-dispersible acrylic polyurethane dispersions containing 25% by weight of solids are coated with a bar coater and dried in an oven at 130 ° C. for 4 minutes. To form a coating layer having a thickness of 20um.
- the real wood film layer having a coating layer formed on both surfaces of the veneer layer was preformed in a form suitable for injection molding at a temperature of 130 ° C. for 100 seconds, and cut unnecessary portions in the finished form.
- a polycarbonate resin is inserted into the coating layer on one surface of the real wood film layer at 200 ° C. to 230 ° C. to form a rear layer, and the polymethyl methacrylate resin is 200 ° C. to the coating layer on the back side of the real wood film layer.
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- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Description
Claims (15)
- 베니어층 양면에 코팅층을 포함하고,상기 베니어층 일면의 코팅층에 배면층, 상기 베니어층 이면의 코팅층에 전면층을 포함하는자동차용 내장재.
- 제1항에 있어서,상기 코팅층은 수분산성 폴리우레탄 분산액 또는 수분산성 아크릴 폴리우레탄 분산액으로부터 형성되는자동차용 내장재.
- 제2항에 있어서,상기 수분산성 폴리우레탄 분산액 또는 상기 수분산성 아크릴 폴리우레탄 분산액은 10중량% 내지 40중량%의 고형분을 포함하는자동차용 내장재.
- 제2항에 있어서,상기 수분산성 폴리우레탄 분산액 또는 상기 수분산성 아크릴 폴리우레탄 분산액은 실리카 화합물을 더 포함하는자동차용 내장재.
- 제4항에 있어서,상기 수분산성 폴리우레탄 분산액 또는 상기 수분산성 아크릴 폴리우레탄 분산액은 고형분 100 중량부 대비 상기 실리카 화합물을 5 내지 30 중량부 포함하는자동차용 내장재.
- 제1항에 있어서,상기 코팅층의 두께는 5㎛ 내지 50㎛인자동차용 내장재.
- 제1항에 있어서,상기 베니어층의 두께는 100㎛내지 600㎛인자동차용 내장재.
- 제1항에 있어서,상기 전면층 및 배면층은 각각 아크릴 수지, 폴리카보네이트 수지, 아크로니트릴-부타디엔-스티렌 공중합체(ABS)수지, 폴리에스테르 수지, 폴리메틸메타 아크릴레이트(PMMA) 수지 및 이들의 조합으로 이루어진 군으로부터 선택된 하나 이상의 열가소성 수지를 포함하는자동차용 내장재.
- 베니어층을 마련하는 단계;상기 베니어층 양면에 수분산성 폴리우레탄 분산액 또는 수분산성 아크릴 폴리우레탄 분산액을 도포 및 건조하여 코팅층을 형성하는 단계;상기 베니어층 양면에 코팅층이 형성된 리얼우드 필름층을 예비성형하는 단계;상기 베니어층 일면의 코팅층에 1차 인서트 사출하여 배면층을 형성하는 단계; 및상기 베니어층 이면의 코팅층에 2차 인서트 사출하여 전면층을 형성하는 단계를 포함하는자동차용 내장재 제조방법.
- 제9항에 있어서,상기 코팅층을 형성하는 단계에서, 상기 수분산성 폴리우레탄 분산액 또는 상기 수분산성 아크릴 폴리우레탄 분산액에 실리카 화합물을 더 첨가하는 단계를 포함하는자동차용 내장재 제조방법.
- 제10항에 있어서,상기 실리카 화합물은 졸-겔 공법에 의해 형성되는자동차용 내장재 제조방법.
- 제9항에 있어서,상기 예비성형은 100℃ 내지 150℃의 온도에서 20초 내지 120초의 시간 내에 수행되는자동차용 내장재 제조방법.
- 제9항에 있어서,상기 예비성형 후에, 상기 리얼우드 필름층의 불필요한 부분을 절단하는 단계를 더 포함하는자동차용 내장재 제조방법.
- 제9항에 있어서,상기 1차 인서트 사출 및 상기 2차 인서트 사출이 동시에 수행되는자동차용 내장재 제조방법.
- 제9항에 있어서,상기 1차 인서트 사출 및 상기 2차 인서트 사출은 200℃ 내지 250℃의 온도에서 수행되는자동차용 내장재 제조방법.
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CN201580038518.7A CN106573582B (zh) | 2014-07-15 | 2015-07-14 | 汽车用内装部件及其制造方法 |
JP2017501661A JP6608420B2 (ja) | 2014-07-15 | 2015-07-14 | 自動車用内装材及びその製造方法 |
US15/325,915 US10137669B2 (en) | 2014-07-15 | 2015-07-14 | Vehicle interior material and manufacturing method therefor |
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KR10-2014-0088793 | 2014-07-15 | ||
KR1020140088793A KR101935515B1 (ko) | 2014-07-15 | 2014-07-15 | 자동차용 내장재 및 이의 제조방법 |
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US (1) | US10137669B2 (ko) |
JP (1) | JP6608420B2 (ko) |
KR (1) | KR101935515B1 (ko) |
CN (1) | CN106573582B (ko) |
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US10322521B2 (en) * | 2015-12-14 | 2019-06-18 | Hyundai Mobis Co., Ltd. | Realwood film, manufacturing method thereof, and articles comprising the same |
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US10350862B1 (en) * | 2011-03-21 | 2019-07-16 | Argent International, Inc. | Combination vehicle interior trim component and anti-shatter self-adhesive tape member to prevent fragmentation or shattering of the component during an air-bag deployment, and methods of making and using same |
KR102100669B1 (ko) * | 2016-09-27 | 2020-05-27 | (주)엘지하우시스 | 차량용 내장재의 제조방법 및 차량용 내장재 |
KR102185795B1 (ko) * | 2018-12-07 | 2020-12-02 | 인탑스 주식회사 | 액상 반응 경화 공법을 이용한 복합층을 구비한 리얼 소재 제품의 제조방법 |
FR3096301B1 (fr) * | 2019-05-21 | 2021-09-03 | Smrc Automotive Holdings Netherlands Bv | Procédé d’habillage de pièces intérieures de véhicules, pièces habillées et véhicules associés |
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JP2017522217A (ja) | 2017-08-10 |
KR101935515B1 (ko) | 2019-01-07 |
US20170173922A1 (en) | 2017-06-22 |
US10137669B2 (en) | 2018-11-27 |
CN106573582B (zh) | 2019-08-20 |
KR20160009123A (ko) | 2016-01-26 |
CN106573582A (zh) | 2017-04-19 |
JP6608420B2 (ja) | 2019-11-20 |
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