WO2015097488A1 - Procede de laminage a chaud - Google Patents
Procede de laminage a chaud Download PDFInfo
- Publication number
- WO2015097488A1 WO2015097488A1 PCT/IB2013/002865 IB2013002865W WO2015097488A1 WO 2015097488 A1 WO2015097488 A1 WO 2015097488A1 IB 2013002865 W IB2013002865 W IB 2013002865W WO 2015097488 A1 WO2015097488 A1 WO 2015097488A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- rolling
- friction
- coefficient
- parameters
- cage
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 47
- 238000005098 hot rolling Methods 0.000 title claims abstract description 18
- 238000005096 rolling process Methods 0.000 claims abstract description 51
- 230000001105 regulatory effect Effects 0.000 claims abstract description 10
- 238000004590 computer program Methods 0.000 claims abstract description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 14
- 239000010959 steel Substances 0.000 claims description 14
- 238000004364 calculation method Methods 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 10
- 239000007924 injection Substances 0.000 claims description 10
- 230000033228 biological regulation Effects 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 230000001050 lubricating effect Effects 0.000 claims description 7
- 238000005259 measurement Methods 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 230000001276 controlling effect Effects 0.000 claims description 2
- 239000000047 product Substances 0.000 claims 6
- 229910000922 High-strength low-alloy steel Inorganic materials 0.000 claims 1
- 229910000797 Ultra-high-strength steel Inorganic materials 0.000 claims 1
- 239000011265 semifinished product Substances 0.000 claims 1
- 238000005461 lubrication Methods 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 239000010687 lubricating oil Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 4
- 230000006870 function Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 241001061132 Eutaeniophorus sp. 033-Miya Species 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- MBYLVOKEDDQJDY-UHFFFAOYSA-N tris(2-aminoethyl)amine Chemical compound NCCN(CCN)CCN MBYLVOKEDDQJDY-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B37/00—Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B27/00—Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
- B21B27/06—Lubricating, cooling or heating rolls
- B21B27/10—Lubricating, cooling or heating rolls externally
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B2001/225—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length by hot-rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2265/00—Forming parameters
- B21B2265/12—Rolling load or rolling pressure; roll force
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2265/00—Forming parameters
- B21B2265/20—Slip
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2275/00—Mill drive parameters
- B21B2275/02—Speed
- B21B2275/04—Roll speed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2275/00—Mill drive parameters
- B21B2275/02—Speed
- B21B2275/06—Product speed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0239—Lubricating
- B21B45/0245—Lubricating devices
- B21B45/0248—Lubricating devices using liquid lubricants, e.g. for sections, for tubes
- B21B45/0251—Lubricating devices using liquid lubricants, e.g. for sections, for tubes for strips, sheets, or plates
Definitions
- the invention relates to the hot rolling of metallurgical products. More specifically, it relates to a method of controlling at least one parameter of the hot rolling process.
- hot-rolled steel strips are manufactured according to the following scheme:
- a finishing mill comprising a plurality of cages (for example six or seven) in which the strip is simultaneously present, so as to give it a thickness of 1, 5 to 10 mm, and then put of the web in the form of a reel.
- the hot-rolled strip thus obtained can then be subjected to heat or mechanical treatments which will give it its final properties, or undergo a cold rolling which will further reduce its thickness before the completion of the final heat or mechanical treatments.
- the steel strip is subjected to a specific thermal and mechanical path (reduction, temperature) which is influenced by the friction between the working rolls and the band in the gap between the rollers.
- This path has a major influence on the quality of the band (surface appearance and metallurgical properties).
- the regulation of the coefficient of friction is in particular ensured by the lubrication process.
- lubrication is generally carried out at each roll stand by injecting an emulsion composed of water and a lubricating fluid, usually oil, onto the cylinder at the gap, see for example the US-A-3605473.
- THR Very High Strength, generally between 450 and 900 MPa
- UHR Ultra High Strength, generally greater than 900 MPa
- new formats for example band thicknesses less than 3mm.
- these steels such as USIBOR® or Dual Phase steels are naturally harder and require the application of a greater rolling force, which reduces the capacity of the rolling mill.
- These steels may also have a surface composition such that it has less scale which usually acts as the first lubricating element.
- JP-A-2008264828 discloses a hot rolling method in which the working rolls are coated with a coating layer of specific composition to ensure a certain coefficient of friction value.
- JP-A-2005146094 discloses a hot rolling method wherein slip of the strip would be avoided by using a lubricating oil of particular composition.
- JPH-A-1156410 discloses a method in which the clamping force of the applied rolling rolls would be measured by sensor, then the amount of lubricating oil injected would be adjusted so that the measured rolling force is equal to a target value.
- This solution aims to adjust the coefficient of friction during the process but does not take into account all the parameters on which the coefficient of friction depends, which makes it inefficient.
- this solution involves significant risks of instabilities of the rolling process, such as. variations in speed or traction, if the amount of lubricant to be supplied to achieve the required force is important.
- the object of the invention is therefore to provide a rolling method in which the coefficient of friction is reliably and effectively controlled during production in order to avoid rolling incidents and to obtain optimum performance.
- the object of the invention is also preferably to provide a method reducing the instabilities of the rolling process and allowing lubrication over the entire length of the strip.
- the invention firstly relates to a control method according to claim 1.
- This control method may also include the features of claims 2 to 7, singly or in combination.
- the invention also relates to a rolling method according to claim 8.
- This rolling method may also include the features of claims 9 to 13, taken alone or in combination.
- the invention also relates to a hot rolling mill according to claim 14.
- This mill may also include the features of claim 15.
- the invention also relates to a computer program product according to claim 16.
- FIG. 1 represents a mill with two cages equipped with an embodiment of a regulating device according to the invention
- FIG. 2 represents the different variables used in one embodiment of a regulation method according to the invention
- FIG. 3 represents a control scheme according to a first embodiment of the invention
- FIG. 4 represents a control scheme according to a second embodiment of the invention
- FIG. 5 represents the start of oil injection and the engine torque as a function of time during a test using a control method according to the invention
- FIG. 6 represents the thickness of the rolled strip at the exit of the cage as a function of time during a test using a control method according to the invention
- FIG. 1 shows a metal strip B during rolling in a rolling mill comprising two cages 1, 2 in which the strip B is simultaneously under the influence, for example a finishing mill for the hot rolling of the steel strips.
- Rolling mills of this type generally have 5, 6 or 7 cages.
- Each of the cages 1, 2 comprises, conventionally, two working rolls 1a, 1a 'and 2a, 2a' and two support rollers b, 1b 'and 2b, 2b'.
- Each cage is activated by a motor torque C ⁇ C 2 (not shown).
- the distance between the two working cylinders, respectively 1a -1a 'and 2a-2a' is called the air gap S (not shown) and is adjusted by means of clamping screws 7.
- the lubrication of the cylinders is ensured at each of the cages by an injection device 3, such as for example projection nozzles for projecting an emulsion of oil and water.
- a speed measuring device 4 is disposed at the exit of the first cage in the running direction of the strip, this device 4 makes it possible to measure the speed of the strip at the exit of the strip.
- cage v SO rtie- This device can be, for example, an optical measuring device such as a laser velocimeter. This measurement of the speed makes it possible to calculate in real time the forward sliding (FWS for ForWard Slip ratio in English) from the following formula:
- - output is the speed of the band leaving the cage, for example measured using the device 4.
- R being the radius of the working cylinder and ⁇ the angular speed of the working cylinders measured for example by a pulse generator
- the velocities v SO rte and v cag e can be expressed in any unit of speed, provided both are expressed in that same unit. Similarly, the unit in which is expressed the angular velocity ⁇ to be consistent with that of VAC g e.
- a device 5 for measuring force to measure in real time the clamping force F of the working rolls is also provided at each cage.
- These devices may for example be strain gauges installed on the cage uprights or under the clamping screws 7.
- the measured data of clamping force F and of the speed of the web at the exit of the cage v SO rte are transmitted to a processing unit 6 which can then, according to these measurements and other parameters previously recorded, send instructions.
- a processing unit 6 which can then, according to these measurements and other parameters previously recorded, send instructions.
- a processing unit 6 for implementing a first embodiment of the regulation method according to the invention is described below with reference to FIG.
- the speed of the belt at the exit of the cage v SO rte and the angular velocity of the working cylinders ⁇ are measured in line and their values are sent to a first calculator 8.
- This first calculator 8 comprises at least one internal memory on which the value of the radius R of the working rolls is stored, which makes it possible to calculate the linear speed of the working rolls and then the value of the working ratio.
- forward slip FWS according to formula 1.
- the calculated value FWS is then transmitted to a second computer 9 which also receives as input the value of the clamping force F measured in real time by the sensor 5.
- This second computer comprises at least one internal memory on which are stored the parameters Pi. These parameters Pi depend on the model chosen for the calculation of the coefficient of friction ⁇ ⁇ ⁇ ⁇ ⁇ ⁇
- Orowan model As an example we will describe below the use for the purposes of the invention Orowan model, but other models known to those skilled in the art may be used, such as the model of SIMS or Bland & Ford.
- the general theory of each of these three models is described for example in "The calculation of roll pressure in hot and cold flat rolling", E.Orowan, Proceedings of the Institute of Mechanical Engineers, June 1943, vol.150, No. 1 140-167 for the Orowan model, "The calculation of roll and torque in hot rolling mills," RB Sims, Proceedings of the Institute of Mechanical Engineers, June 1954, vol.168, No. 1 191-200 for the Sims model, "The Calculation of Roll and Torque Force in Cold Rolling Strip with Tensions," DR Bland and H. Ford, Proceedings of the Institute of Mechanical Engineers, June 1948, vol.149, p.144, for the model of Bland & Ford.
- Pi model is an input thicknesses tree and output e SO rt of the strip, the input pull-in tree and G SO output of the band, these parameters being in the present example set at the beginning of rolling but can also be estimated or measured in real time. These parameters are illustrated in Figure 2. From these data the second computer 9 thus calculates the real coefficient of friction i given to a processor 10.
- the calculation time of Préei is less than or equal to 100ms and preferably less than or equal to 50ms.
- the input data processor 10 are p r IEE a target value of coefficient of friction C p j b ie determined from graphs or modeling, depending on the steel grade of the rolled strip, the number of kilometers of rolled strips on the installation in question, the wear of the rollers, the type of oil used, etc. as well as a parameter a 0 .
- This parameter is the initial value of the process parameter that will be used to regulate the SOE friction coefficient i.
- This parameter can be for example the injection rate Q hU iie of the lubricating oil.
- the initial value can be determined for example using charts or by modeling.
- the value of p r IEE friction coefficient is then compared with the target value of friction coefficient c i EU If the absolute value of the difference between these two values
- the injection flow rate Qhuiie of the lubricating oil can be reduced or increased. It is preferable to keep the flow of water in the emulsion constant for thermal considerations of cylinder cooling and smooth operation to ensure that the injected emulsion covers a large part of the cylinder.
- the time that elapses between the measurement of the output speed of the Vsortie band and the reception of the setpoint a n is less than or equal to 500 ms and preferably less than or equal to 150 ms.
- FIG. 4 represents a control scheme according to a second embodiment of the invention.
- the Orowan model parameters P 2 are the input thicknesses e en try and output e SO rt of the strip, the input pull-in tree and released SO rt of the web, the radius R of the rollers, which parameters are in this example set at the beginning of rolling, but can also be estimated or measured in real time.
- P2 also includes the milling module M of the mill stand considered. This module, generally expressed in t / mm, characterizes the elastic deformation of the cage related to the rolling force.
- the processor calculates for example the rolling force value F 'which should be applied to obtain the thickness e SO
- - F is the value of the rolling force measured by the sensor 5.
- the units of these three quantities must be coherent with each other and may for example be in Newton for the forces F and F 'and in N / mm for the curing module M.
- the processing units described above with reference to FIGS. 3 and 4 contain various elements such as computers or processors, but it would be possible to envisage a single processor making it possible to carry out the various calculation operations and instructions, or any other possible configuration enabling calculation steps and instructions.
- a hot rolling method according to the invention was made with a Drawn and Wall Ironed (DWI) steel strip, the lubricating oil used being a commercial standard oil.
- DWI Drawn and Wall Ironed
- the injection flow rate Qh U is zero during the rolling of the strip head. This is voluntary this test being mainly devoted to the lubrication of the tail of tape.
- FIG. 6 represents the thickness of the strip at the cage exit e SO as a function of the rolling time.
- This thickness e SO rt After 10 seconds, this decline corresponds to what has been explained above.
- the modification of the injected oil flow Qhuiie causes a change in the force F applied and in this case a significant decrease in the thickness e SO r of the band at the exit of the cage. Thanks to the regulation illustrated in FIG. 4, a new clamping force F 'is calculated and the air gap S modified accordingly in order to obtain an output thickness e SO that corresponds to the customer's expectations.
- the increase and the maintenance of the thickness e SO rce are visible in this figure 6.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Control Of Metal Rolling (AREA)
- Metal Rolling (AREA)
Abstract
Description
Claims
Priority Applications (18)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL13824153T PL3086889T3 (pl) | 2013-12-24 | 2013-12-24 | Sposób walcowania na gorąco, walcownia gorąca i program komputerowy do wykonywania takiego sposobu |
PCT/IB2013/002865 WO2015097488A1 (fr) | 2013-12-24 | 2013-12-24 | Procede de laminage a chaud |
AU2013409182A AU2013409182B2 (en) | 2013-12-24 | 2013-12-24 | Hot rolling method |
CA2935193A CA2935193C (fr) | 2013-12-24 | 2013-12-24 | Procede de laminage a chaud |
KR1020167019708A KR20160101153A (ko) | 2013-12-24 | 2013-12-24 | 열간 압연 방법 |
EP13824153.4A EP3086889B1 (fr) | 2013-12-24 | 2013-12-24 | Procédé de laminage à chaud, laminoir à chaud et produit programme d'ordinateur pour la mise en oeuvre d'un tel procédé |
CN201380081821.6A CN105916603B (zh) | 2013-12-24 | 2013-12-24 | 热轧方法 |
HUE13824153 HUE044992T2 (hu) | 2013-12-24 | 2013-12-24 | Meleghengerlési eljárás, meleghengersor és számítógépi program az eljárás végrehajtására |
MA39044A MA39044B1 (fr) | 2013-12-24 | 2013-12-24 | Procede de laminage a chaud |
KR1020177037905A KR102110645B1 (ko) | 2013-12-24 | 2013-12-24 | 열간 압연 방법 |
UAA201608117A UA117508C2 (uk) | 2013-12-24 | 2013-12-24 | Спосіб гарячої прокатки |
BR112016014762-6A BR112016014762B1 (pt) | 2013-12-24 | 2013-12-24 | Método de regulação de pelo menos um dos parâmetros alfa de um processo de laminação a quente, método de laminação a quente de um produto de metal semiacabado, laminador a quente e memória legível por computador |
MX2016008454A MX2016008454A (es) | 2013-12-24 | 2013-12-24 | Metodo de laminacion en caliente. |
JP2016542726A JP6342003B2 (ja) | 2013-12-24 | 2013-12-24 | 熱間圧延方法 |
RU2016130269A RU2670630C9 (ru) | 2013-12-24 | 2013-12-24 | Способ горячей прокатки |
ES13824153T ES2724456T3 (es) | 2013-12-24 | 2013-12-24 | Procedimiento de laminación en caliente, laminador en caliente y producto de programa informático para la implementación de tal procedimiento |
US15/108,132 US10870138B2 (en) | 2013-12-24 | 2013-12-24 | Hot rolling method |
ZA2016/03733A ZA201603733B (en) | 2013-12-24 | 2016-06-01 | Hot rolling method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IB2013/002865 WO2015097488A1 (fr) | 2013-12-24 | 2013-12-24 | Procede de laminage a chaud |
Publications (1)
Publication Number | Publication Date |
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WO2015097488A1 true WO2015097488A1 (fr) | 2015-07-02 |
Family
ID=50001027
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2013/002865 WO2015097488A1 (fr) | 2013-12-24 | 2013-12-24 | Procede de laminage a chaud |
Country Status (17)
Country | Link |
---|---|
US (1) | US10870138B2 (fr) |
EP (1) | EP3086889B1 (fr) |
JP (1) | JP6342003B2 (fr) |
KR (2) | KR20160101153A (fr) |
CN (1) | CN105916603B (fr) |
AU (1) | AU2013409182B2 (fr) |
BR (1) | BR112016014762B1 (fr) |
CA (1) | CA2935193C (fr) |
ES (1) | ES2724456T3 (fr) |
HU (1) | HUE044992T2 (fr) |
MA (1) | MA39044B1 (fr) |
MX (1) | MX2016008454A (fr) |
PL (1) | PL3086889T3 (fr) |
RU (1) | RU2670630C9 (fr) |
UA (1) | UA117508C2 (fr) |
WO (1) | WO2015097488A1 (fr) |
ZA (1) | ZA201603733B (fr) |
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EP3517228A1 (fr) * | 2018-01-29 | 2019-07-31 | Primetals Technologies Austria GmbH | Règles d'un processus de laminage |
JP7073983B2 (ja) | 2018-08-21 | 2022-05-24 | 日本製鉄株式会社 | 冷間圧延方法 |
IT201900005442A1 (it) * | 2019-04-09 | 2020-10-09 | Danieli Off Mecc | Processo di laminazione a freddo di un prodotto in alluminio e relativo impianto di laminazione a freddo |
US11793230B2 (en) | 2019-12-09 | 2023-10-24 | Nicoventures Trading Limited | Oral products with improved binding of active ingredients |
US11969502B2 (en) | 2019-12-09 | 2024-04-30 | Nicoventures Trading Limited | Oral products |
US11872231B2 (en) | 2019-12-09 | 2024-01-16 | Nicoventures Trading Limited | Moist oral product comprising an active ingredient |
US11826462B2 (en) | 2019-12-09 | 2023-11-28 | Nicoventures Trading Limited | Oral product with sustained flavor release |
CN114850428B (zh) * | 2022-05-09 | 2024-01-16 | 宝信软件(山西)有限公司 | 采用压下力补正立式连铸机拉矫主辊速度的方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3605473A (en) | 1969-03-21 | 1971-09-20 | Nat Steel Corp | Method and apparatus for hot rolling ferrous metal workpieces |
JPS60223601A (ja) * | 1984-04-19 | 1985-11-08 | Sumitomo Metal Ind Ltd | 薄鋼帯の冷間圧延方法 |
JPH01156410A (ja) | 1987-12-11 | 1989-06-20 | Nkk Corp | 高炉操業方法 |
JPH03151106A (ja) * | 1989-11-08 | 1991-06-27 | Kawasaki Steel Corp | 冷間圧延における先進率制御方法 |
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CN105032949A (zh) * | 2015-07-09 | 2015-11-11 | 首钢总公司 | 一种控制高线盘条尾部圈形的夹持方法 |
CN105032949B (zh) * | 2015-07-09 | 2017-02-01 | 首钢总公司 | 一种控制高线盘条尾部圈形的夹持方法 |
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US20160318080A1 (en) | 2016-11-03 |
US10870138B2 (en) | 2020-12-22 |
RU2670630C9 (ru) | 2018-11-26 |
HUE044992T2 (hu) | 2019-11-28 |
KR20180004332A (ko) | 2018-01-10 |
MX2016008454A (es) | 2016-10-14 |
BR112016014762B1 (pt) | 2022-03-15 |
BR112016014762A2 (fr) | 2017-08-08 |
ES2724456T3 (es) | 2019-09-11 |
CN105916603B (zh) | 2018-09-07 |
RU2016130269A (ru) | 2018-01-30 |
AU2013409182A1 (en) | 2016-07-14 |
MA39044B1 (fr) | 2018-11-30 |
CA2935193A1 (fr) | 2015-07-02 |
KR20160101153A (ko) | 2016-08-24 |
AU2013409182B2 (en) | 2017-08-31 |
ZA201603733B (en) | 2017-07-26 |
EP3086889B1 (fr) | 2019-02-06 |
RU2670630C2 (ru) | 2018-10-24 |
CA2935193C (fr) | 2018-12-04 |
PL3086889T3 (pl) | 2019-08-30 |
EP3086889A1 (fr) | 2016-11-02 |
JP2017500208A (ja) | 2017-01-05 |
UA117508C2 (uk) | 2018-08-10 |
JP6342003B2 (ja) | 2018-06-13 |
KR102110645B1 (ko) | 2020-05-14 |
CN105916603A (zh) | 2016-08-31 |
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