WO2014185454A1 - Composition d'agent de traitement liquide pour article en fibres - Google Patents

Composition d'agent de traitement liquide pour article en fibres Download PDF

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Publication number
WO2014185454A1
WO2014185454A1 PCT/JP2014/062855 JP2014062855W WO2014185454A1 WO 2014185454 A1 WO2014185454 A1 WO 2014185454A1 JP 2014062855 W JP2014062855 W JP 2014062855W WO 2014185454 A1 WO2014185454 A1 WO 2014185454A1
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Prior art keywords
composition
component
fragrance
mass
group
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PCT/JP2014/062855
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English (en)
Japanese (ja)
Inventor
侑里 安達
直行 江川
英史 小倉
友彦 天谷
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ライオン株式会社
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Application filed by ライオン株式会社 filed Critical ライオン株式会社
Priority to JP2015517110A priority Critical patent/JP6444300B2/ja
Priority to KR1020157033324A priority patent/KR102204710B1/ko
Priority to GB1519894.8A priority patent/GB2534454B/en
Publication of WO2014185454A1 publication Critical patent/WO2014185454A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D06M13/13—Unsaturated aldehydes, e.g. acrolein; Unsaturated ketones; Ketenes ; Diketenes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/175—Unsaturated ethers, e.g. vinylethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols

Definitions

  • the present invention relates to a liquid treatment composition for textiles, and more particularly to a liquid treatment composition for textiles suitable for use in textiles such as clothing. More specifically, the present invention relates to a liquid treatment composition for textiles that is excellent in an effect of suppressing a change in fragrance tone and an effect of improving a remaining scent.
  • Japanese Patent Application Laid-Open No. 2009-144306 discloses a technique that can impart a low ClogP fragrance to a fabric, but it is necessary to synthesize a specific polymer and use it together with the low ClogP fragrance, and the process is complicated. is there. In addition, this technique is not a technique intended to suppress the change in the scent. As mentioned above, it is the fragrance with a low ClogP that is highly concerned about the change in fragrance, but in textile processing agents, the problem of fragrance change exists for the entire fragrance including the fragrance with a high ClogP It is.
  • JP-A-2011-127260 discloses a fiber product treating agent composition containing a specific silicate compound.
  • a perfume silicate compound having a log P of 1 or more and less than 15 it is necessary to mix a perfume silicate compound having a log P of 1 or more and less than 15, and a perfume silicate compound having a log P of 15 or more and less than 50. Therefore, the process for making a fragrance
  • an object of the present invention is to provide a liquid treatment agent composition for textiles which is excellent in the effect of suppressing change in fragrance tone and the effect of improving the remaining scent.
  • the present inventors blended a specific glucan called a highly branched cyclic dextrin with a fragrance, so that the fragrance, particularly even a fragrance having a low ClogP, is treated on the treated cloth. It was found that a large amount of fragrance can be left, the change in fragrance tone can be suppressed and the remaining fragrance can be improved.
  • the present invention has been completed based on such novel findings.
  • the present invention (A) perfume composition, (B) A glucan having an inner branched cyclic structure portion and an outer branched structure portion and having a polymerization degree in the range of 50 to 10,000, wherein the inner branched cyclic structure portion is ⁇ -1,4-glucoside A glucan which is a cyclic structure portion formed by a bond and an ⁇ -1,6-glucoside bond, and the outer branched structure portion is an acyclic structure portion bonded to the inner branched cyclic structure portion, and (C) Provided is a liquid treatment composition for textiles, which comprises a cationic surfactant.
  • the component (A) contains a fragrance component having a ClogP value of 5 or less or a fragrance component having a cyclic structure in the structure.
  • the component (C) is an amine compound having 1 to 3 hydrocarbon groups having 10 to 26 carbon atoms which may be separated by an ester group or an amide group, a salt thereof, or a salt thereof Selected from quaternized products.
  • the fragrance is a fragrance having a low ClogP by blending the fragrance as the component (A) and the highly branched cyclic dextrin as the component (B).
  • a large amount can be left on the treated cloth, and the change in the fragrance can be suppressed and the remaining fragrance can be improved.
  • Component (A)] (A) component contained in the liquid processing agent composition for textiles of this invention is a fragrance
  • the fragrance composition used in the present invention is a fragrance composition containing at least one fragrance component generally used in a textile product treating agent composition, for example, a textile product finish composition or a softener composition. is there.
  • Specific examples of the perfume component are not particularly limited and may be appropriately selected depending on the purpose. For example, aldehydes, phenols, alcohols, ethers, esters, hydrocarbons, ketones, lactones , Musks, fragrances having a terpene skeleton, natural fragrances, animal fragrances, and the like.
  • the aldehydes are not particularly limited and may be appropriately selected depending on the intended purpose.
  • undecylenaldehyde lauryl aldehyde, aldehyde C-12MNA, miracaldehyde, ⁇ -amylcinnamic aldehyde, cyclamenaldehyde, citral , Citronellal, ethyl vanillin, heliotropin, anisaldehyde, ⁇ -hexylcinnamic aldehyde, octanal, ligustral, lyial, rilal, tripral, vanillin, helional and the like.
  • eugenol eugenol, isoeugenol, etc.
  • the alcohol is not particularly limited and may be appropriately selected depending on the intended purpose.
  • bacdanol, citronellol, dihydromyrcenol, dihydrolinalool, geraniol, linalool, nerol, sandalol, santarex examples include terpineol, tetrahydrolinalol, and phenylethyl alcohol.
  • ether there is no restriction
  • the esters are not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include cis-3-hexenyl acetate, cis-3-hexenyl propionate, cis-3-hexenyl salicylate, p-cresate.
  • the hydrocarbons are not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include d-limonene, ⁇ -pinene, ⁇ -pinene and myrcene.
  • the ketones are not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include ⁇ -ionone, ⁇ -ionone, methyl- ⁇ -naphthyl ketone, ⁇ -damascon, ⁇ -damascon, and ⁇ -damascon.
  • the lactone is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include ⁇ -decalactone, ⁇ -undecalactone, ⁇ -nonalactone, ⁇ -dodecalactone, coumarin, and ambroxan. It is done.
  • musk there is no restriction
  • the fragrance having the terpene skeleton is not particularly limited and may be appropriately selected depending on the intended purpose.For example, geraniol (gelaniol), nerol, linalool, citral, citronellol, menthol, mint, citronellal, myrcene, pinene, Examples include limonene, terpineol, carvone, yonon, camphor, and borneol.
  • the natural perfume is not particularly limited and may be appropriately selected depending on the intended purpose.
  • flavor According to the objective, it can select suitably, For example, a scent, a ghost
  • the perfume component may be contained in an amount of 10% by mass or more, more preferably 30% by mass or more, still more preferably 50% by mass or more, and particularly preferably 70% by mass or more based on the total mass of the perfume composition.
  • a fragrance composition containing a fragrance component having a cyclic structure in the structure as the component (A).
  • the perfume component may be contained in an amount of 10% by mass or more, more preferably 20% by mass or more, still more preferably 35% by mass or more, and particularly preferably 60% by mass or more based on the total mass of the perfume composition. More preferably, in the liquid treatment composition for textiles of the present invention, a fragrance composition having a ClogP value of 5 or less and containing a fragrance component having a cyclic structure is used.
  • a fragrance composition having a ClogP value of 5 or less and a fragrance component having a cyclic structure of 20% by mass or more, particularly preferably a ClogP value is A perfume composition containing 40% by mass or more of a perfume component having a cyclic structure of 5 or less is used.
  • the cyclic structure referred to here may be, for example, a hydrocarbon ring structure or a heterocyclic structure, which may be monocyclic or polycyclic, and may be a condensed polycyclic structure, a bridged ring structure, a spiro structure, or the like. It may be a ring structure, a saturated ring structure or an unsaturated ring structure.
  • hetero atom contained in the heterocycle examples include O, S, N, and P.
  • Specific examples of the cyclic structure include monocyclic compounds such as benzene and condensed ring compounds such as naphthalene.
  • the element forming the cyclic structure may be a carbocyclic compound or a heterocyclic compound.
  • the ring size may be a 5-membered ring compound such as cyclopentane or furan, a 6-membered ring compound such as cyclohexane or benzene, or the like.
  • a fragrance component in the component (A) that is preferably used, specifically, ISOE Super (ClogP4.7, with a cyclic structure), ethyl vanillin ( ClogP1.8, with cyclic structure), ⁇ -undecalactone (ClogP3.8, with cyclic structure), eugenol (ClogP2.4, with cyclic structure), ⁇ Damascon (ClogP4.7, with cyclic structure), Helional (ClogP1.4, with a cyclic structure), benzyl salicylate (ClogP4.2, with a cyclic structure), cachemelan (ClogP4.0, with a cyclic structure), coumarin (ClogP1.4, with a cyclic structure), dimethyl Benzylcarbinyl acetate (ClogP1.9, with cyclic structure), terpineol (ClogP2.6, with cyclic structure), damasenone (ClogP4.3, with cyclic structure
  • iso-Esuper ethyl vanillin, ⁇ -undecalactone, eugenol, ⁇ -damascone, helional, and benzyl salicylate. More preferred are eugenol, ⁇ damascone, helional, and benzyl salicylate.
  • the ClogP value is a value representing a 1-octanol / water partition coefficient P representing a ratio of equilibrium concentrations in 1-octanol and in water in the form of logarithmic logP with respect to the base 10 for a chemical substance.
  • the ClogP value can be determined by decomposing the chemical structure of a compound into its constituents by the f-value method (hydrophobic fragment constant method) and integrating the hydrophobic fragment constants and f values possessed by each fragment (for example, Clog 3 Reference Manual Daylight Software 4.34, Albert Leo, David Weininger, Version 1, March 1994).
  • the fragrance composition containing more fragrance components having a smaller ClogP value is more hydrophilic than the fragrance composition containing more fragrance components having a larger ClogP value.
  • a fragrance component having a ClogP value of 1.0 or more and 8.0 or less is used with respect to the total mass of the fragrance composition from the viewpoint of a fresh fragrance and a preference. 30% by mass or more, more preferably 45% by mass or more, further preferably 50% by mass or more, particularly preferably 80% by mass or more, and still more preferably 90% by mass or more.
  • a solvent generally used for a textile product treating agent composition for example, a textile product finishing composition or a softener composition
  • the fragrance solvent include acetin (triacetin), MMB acetate (3-methoxy-3-methylbutyl acetate), sucrose diacetate hexaisobutyrate, ethylene glycol dibutyrate, hexylene glycol, dibutyl sebacate, and deltile extra ( Isopropyl myristate), methyl carbitol (diethylene glycol monomethyl ether), carbitol (diethylene glycol monoethyl ether), TEG (triethylene glycol), benzyl benzoate (BB), propylene glycol, diethyl phthalate, tripropylene glycol, aborin ( Dimethyl phthalate), deltyl prime (isopropyl palmitate), dipropylene glycol (DPG), farnesene, dioct
  • fragrance composition 1,3-butylene glycol and the like.
  • solvents are blended in the fragrance composition, for example, in an amount of 0.1 to 30% by mass, preferably 1 to 20% by mass.
  • the amount of component (A) is not particularly limited, but when used as a softener composition, it is preferably 0.01 to 5 mass with respect to the total mass of the entire composition. %, More preferably 0.1 to 5% by mass, still more preferably 0.5 to 3% by mass.
  • it is preferably 0.001 to 1% by mass, more preferably 0.005 to 1% by mass, and still more preferably 0.01 to 0.5% by mass, based on the total mass of the composition.
  • the blending amount of the component (A) is less than 0.001% by mass, the aroma is weak, and it is difficult to understand the effect of suppressing the change in fragrance and the effect of improving the remaining scent.
  • the blending amount of the component (A) is more than 5% by mass, the storage stability at high temperature may be lowered.
  • the component (B) contained in the liquid treating agent composition for textiles of the present invention is a glucan having an inner branched cyclic structure portion and an outer branched structure portion and having a polymerization degree in the range of 50 to 10,000,
  • the inner branched cyclic structure portion is a cyclic structure portion formed by an ⁇ -1,4-glucoside bond and an ⁇ -1,6-glucoside bond, and the outer branched structure portion is the inner branched cyclic structure.
  • Such a glucan is also called highly branched cyclic dextrin or cluster dextrin, and the component (B) is also referred to as “highly branched cyclic dextrin” in this specification.
  • the highly branched cyclic dextrin contained in the liquid treatment composition for textiles of the present invention has a molecular weight of about 30,000 to 1,000,000, has one cyclic structure in the molecule, and a large number of glucans in the cyclic portion. It mainly contains dextrin having a weight average degree of polymerization of about 2500 with chains attached.
  • the highly branched cyclic dextrin of the highly branched cyclic dextrin contained in the liquid product composition for textiles of the present invention is composed of about 10 to 100 glucoses.
  • the outer branched structure portion consisting of the branched glucan chain is bound.
  • the degree of polymerization of the highly branched cyclic dextrin contained in the liquid treatment composition for textiles of the present invention is in the range of 50 to 5000.
  • the polymerization degree of the inner branched cyclic structure portion of the highly branched cyclic dextrin contained in the liquid treatment composition for textiles of the present invention is in the range of 10-100.
  • the degree of polymerization of the outer branched structure portion of the highly branched cyclic dextrin contained in the liquid treatment composition for textile products of the present invention is 40 or more.
  • the degree of polymerization of each unit chain of the outer branched structure portion of the highly branched cyclic dextrin contained in the liquid treating agent composition for textiles of the present invention is 10 to 20 on average.
  • the highly branched cyclic dextrin contained in the liquid treatment composition for textiles of the present invention is produced, for example, by using starch as a raw material and acting on an enzyme called a branching enzyme.
  • Starch which is a raw material, is composed of amylose in which glucose is linearly linked by ⁇ -1,4-glucoside bonds and amylopectin having a structure that is complicatedly branched by ⁇ -1,6-glucoside bonds. It is a macromolecule with many connected structures.
  • Branching enzyme an enzyme used, is a glucan chain transferase widely distributed in animals, plants, and microorganisms. It acts on the seam portion of the cluster structure of amylopectin and catalyzes the reaction of cyclizing it.
  • the highly branched cyclic dextrin contained in the liquid treatment composition for textiles of the present invention has an inner branching cyclic structure portion and an outer branching structure portion described in JP-A-8-134104. Is a glucan in the range of 50 to 10,000. In the present specification, the highly branched cyclic dextrin can be understood in consideration of the description in JP-A-8-134104.
  • “Cluster Dextrin” registered trademark of Glico Nutrition Foods Co., Ltd. may be mentioned.
  • the blending amount of the component (B) is not particularly limited, but when used as a softener composition, it is preferably 0.01 to the total mass of the entire composition. It is 10% by mass, more preferably 0.03 to 5% by mass, and still more preferably 0.05 to 3% by mass.
  • the blending amount of the component (B) is more than 0.01% by mass, an excellent effect of suppressing change in fragrance tone and an effect of improving the remaining scent can be exhibited.
  • the amount of component (B) is preferably 0.01 to 5% by mass, more preferably 0.03 to 3% by mass, and still more preferably based on the total mass of the entire composition. Is 0.05 to 1% by mass.
  • the blending amount of the component (B) is more than 0.01% by mass, an excellent effect of suppressing change in fragrance tone and an effect of improving the remaining scent can be exhibited.
  • the mass ratio of the component (A) / (B) is not particularly limited, but when used as a softener composition, both when used as a spray-type fiber treatment composition.
  • the ratio is preferably 1/100 to 20, more preferably 1/10 to 5, and still more preferably 1/5 to 1.
  • the fragrance especially the fragrance with a low ClogP value
  • feels different when comparing the odor of the liquid treatment composition for textile products and the treated cloth is not necessarily clear, but the following reasons Can be considered.
  • a fragrance component having a low ClogP value hydrophilic fragrance component
  • the fragrance component having a low ClogP value flows out into the rinsing liquid when softened in the washing process, and is difficult to be adsorbed on the cloth.
  • flavor component with a low ClogP value exists on a process cloth and it reduces from the ratio in a softening agent composition, an incense tone changes and it is felt.
  • a fragrance component having a low ClogP value is not easily taken into the micelle formed by the cationic surfactant and is likely to exist in the bulk when the composition is produced. Accordingly, when sprayed on the cloth, the fragrance having a low ClogP value is easily volatilized because it is put on the cloth in a state where it is not taken into the micelle. Therefore, since the fragrance
  • a fragrance component having a low ClogP value is difficult to be incorporated into the cationic surfactant and easily exists in the bulk. Difficult to place.
  • a highly branched cyclic dextrin is blended, and the highly branched cyclic dextrin dissolved in the bulk takes a helical structure, whereby a fragrance is included in the helical structure. It is thought that the inclusion body adsorbs on the cloth.
  • the perfume component Since the highly branched cyclic dextrin does not maintain a helical structure on the fiber, the perfume component is gradually released from the clathrate adsorbed on the cloth. Therefore, it is thought that the fragrance of the fragrance
  • Component (C)] (C) component contained in the liquid processing agent composition for textiles of this invention is a cationic surfactant.
  • the cationic surfactant used as the component (C) in the present invention is a hydrocarbon group having 10 to 26 carbon atoms (hereinafter referred to as “long-chain hydrocarbon group”) which may be separated by an ester group or an amide group. May be at least one compound selected from the group consisting of amine compounds having 1 to 3 thereof in the molecule, salts thereof and quaternized products thereof.
  • a tertiary amine acid salt or a quaternized product thereof having at least one hydrocarbon group having a total carbon number of 10 to 26 which may be separated by an ester group or an amide group in the molecule is preferable.
  • the component (C) is a hydrocarbon group having 10 to 26 carbon atoms which may be separated by an ester group or an amide group. It is preferably at least one compound selected from the group consisting of 1 to 3 amine compounds in the molecule, salts thereof and quaternized products thereof.
  • the carbon number of the long-chain hydrocarbon group is 10 to 26, preferably 17 to 26, and more preferably 19 to 24.
  • the component (C) is a hydrocarbon group having 10 to 14 carbon atoms which may be separated by an ester group or an amide group.
  • amine compounds having two hydrocarbon groups having 10 to 14 carbon atoms which may be separated by an ester group or an amide group in the molecule, salts thereof and quaternized products thereof are particularly preferable.
  • the long chain hydrocarbon group may be saturated or unsaturated. When the long chain hydrocarbon group is unsaturated, the position of the double bond may be anywhere, but when there is one double bond, the position of the double bond is the long chain carbonization.
  • the center of the hydrogen group is preferably distributed around the median.
  • the long chain hydrocarbon group may be a chain hydrocarbon group or a hydrocarbon group containing a ring in the structure, and is preferably a chain hydrocarbon group.
  • the chain hydrocarbon group may be linear or branched. As the chain hydrocarbon group, an alkyl group or an alkenyl group is preferable, and an alkyl group is more preferable.
  • the long chain hydrocarbon group may be separated by an ester group (—COO—) or an amide group (—NHCO—).
  • the long-chain hydrocarbon group has at least one kind of splitting group selected from the group consisting of an ester group and an amide group in the carbon chain, and the carbon chain is split by the splitting group. May be. Having the splitting group is preferable from the viewpoint of improving biodegradability.
  • the number of the dividing groups which one long-chain hydrocarbon group has may be one, or may be two or more. That is, the long chain hydrocarbon group may be divided at one place by a dividing group, or may be divided at two or more places.
  • each splitting group may be the same or different.
  • the carbon atom which a splitting group shall count to carbon number of a long-chain hydrocarbon group.
  • the long-chain hydrocarbon group is usually an unhydrogenated fatty acid derived from beef tallow, which is used industrially, a fatty acid obtained by hydrogenation or partial hydrogenation of an unsaturated part, palm-derived palm oil, oil palm-derived It is introduced by using a hydrogenated fatty acid or fatty acid ester, or a fatty acid or fatty acid ester obtained by hydrogenation or partial hydrogenation of an unsaturated portion.
  • amine compound in the component (C) contained in the liquid treatment composition for textiles of the present invention a secondary amine compound or a tertiary amine compound is preferable, and a tertiary amine compound is more preferable. More specifically, examples of the amine compound in the component (C) include compounds represented by the following general formula (C1).
  • R 1 to R 3 are each independently a hydrocarbon group having 10 to 26 carbon atoms, —CH 2 CH (Y) OCOR 4 (Y is a hydrogen atom or CH 3 , and R 4 is 7 carbon atoms) -(CH 2 ) n NHCOR 5 (n is 2 or 3, R 5 is a hydrocarbon group having 7 to 21 carbon atoms), hydrogen atom, carbon number An alkyl group having 1 to 4 carbon atoms, —CH 2 CH (Y) OH, or — (CH 2 ) n NH 2 , and at least one of R 1 to R 3 is a hydrocarbon group having 10 to 26 carbon atoms. , —CH 2 CH (Y) OCOR 4 , or — (CH 2 ) n NHCOR 5 . ]
  • the carbon number of the hydrocarbon group having 10 to 26 carbon atoms in R 1 to R 3 is preferably 17 to 26, and more preferably 19 to 24.
  • the hydrocarbon group may be saturated or unsaturated.
  • the hydrocarbon group is preferably an alkyl group or an alkenyl group.
  • Y is a hydrogen atom or CH 3 , and a hydrogen atom is particularly preferable.
  • R 4 is a hydrocarbon group having 7 to 21 carbon atoms, preferably 15 to 19 carbon atoms. When R 4 is more present in the formula may be R 4 of said plurality of mutually identical, may be different.
  • Hydrocarbon group R 4 is a residue obtained by removing a carboxy group from a fatty acid having 8 to 22 carbon atoms (R 4 COOH) (fatty acid residues), R 4 Nomoto become fatty (R 4 COOH) is Saturated fatty acids or unsaturated fatty acids may be used, and straight-chain fatty acids or branched fatty acids may be used. Of these, saturated or unsaturated linear fatty acids are preferred. In order to impart good water absorption to the soft-treated garment, the saturated / unsaturated ratio (mass ratio) of the fatty acid serving as the R 4 is preferably 90/10 to 0/100, more preferably 80/20 to 0 / 100 is more preferable.
  • R 4 is an unsaturated fatty acid residue
  • a cis isomer and a trans isomer exist, and the mass ratio of cis isomer / trans isomer is preferably 40/60 to 100/0, and 70/30 to 90/10. Particularly preferred.
  • fatty acids used as R 4 include stearic acid, palmitic acid, myristic acid, lauric acid, oleic acid, elaidic acid, linoleic acid, partially hydrogenated palm oil fatty acid (iodine value 10 to 60), partial Examples include hydrogenated beef tallow fatty acid (iodine value 10 to 60).
  • the ratio (mass ratio) of saturated fatty acid / unsaturated fatty acid is 90/10 to 0/100, more preferably 80/20 to 0/100.
  • the cis / trans ratio (mass ratio) is 40/60 to 100/0, more preferably 70/30 to 90/10.
  • the fatty acid having 18 carbon atoms is 60% by mass or more, preferably 80% by mass or more, the fatty acid having 20 carbon atoms is less than 2% by mass, and the fatty acid having 21 to 22 carbon atoms is less than 1% by mass. .
  • R 5 is a hydrocarbon group having 7 to 21, preferably 15 to 19 carbon atoms. When R 5 is more present in the formula may be R 5 of said plurality of mutually identical, may be different. Examples of R 5 include the same as R 4 . At least one of R 1 to R 3 is a long-chain hydrocarbon group (that is, a hydrocarbon group having 10 to 26 carbon atoms, —CH 2 CH (Y) OCOR 4 , or — (CH 2 ) n NHCOR 5 ). It is preferable that two are long-chain hydrocarbon groups.
  • R 1 to R 3 When one or two of R 1 to R 3 are long-chain hydrocarbon groups, the remaining two or one is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, —CH 2 CH (Y) OH or — (CH 2 ) n NH 2 , preferably an alkyl group having 1 to 4 carbon atoms, —CH 2 CH (Y) OH, or — (CH 2 ) n NH 2 .
  • the alkyl group having 1 to 4 carbon atoms a methyl group or an ethyl group is preferable, and a methyl group is particularly preferable.
  • Y in —CH 2 CH (Y) OH is the same as Y in —CH 2 CH (Y) OCOR 4 .
  • N in — (CH 2 ) n NH 2 is the same as n in — (CH 2 ) n NHCOR 5 .
  • Preferable examples of the compound represented by the general formula (C1) include compounds represented by the following general formulas (C1-1) to (C1-8). [Wherein, R 7 and R 8 are each independently a hydrocarbon group having 10 to 26 carbon atoms. R 9 and R 10 are each independently a hydrocarbon group having 7 to 21 carbon atoms. ]
  • Examples of the hydrocarbon group for R 7 and R 8 include the same hydrocarbon groups as those having 10 to 26 carbon atoms for R 1 to R 3 .
  • Examples of the hydrocarbon group having 7 to 21 carbon atoms in R 9 and R 10 include the same groups as the hydrocarbon group having 7 to 21 carbon atoms in R 4 .
  • R 9 is more present in the formula, R 9 of the plurality of may be the same as each other, it may be different.
  • the salt of an amine compound is obtained by neutralizing an amine compound with an acid.
  • the acid used for neutralization of the amine compound may be an organic acid or an inorganic acid, and examples thereof include hydrochloric acid, sulfuric acid, and methyl sulfuric acid. Neutralization of the amine compound can be performed by a known method.
  • a quaternized product of an amine compound is obtained by reacting the amine compound with a quaternizing agent.
  • the quaternizing agent used for the quaternization of the amine compound include alkyl halides such as methyl chloride and dialkyl sulfates such as dimethyl sulfate.
  • alkyl halides such as methyl chloride
  • dialkyl sulfates such as dimethyl sulfate.
  • the alkyl group introduced by the quaternizing agent is preferably an alkyl group having 1 to 4 carbon atoms, more preferably a methyl group or an ethyl group, and particularly preferably a methyl group.
  • the quaternization of the amine compound can be performed by a known method.
  • the component (C) contained in the liquid treating agent composition for textiles of the present invention includes at least one selected from the group consisting of the compound represented by the general formula (C1), a salt thereof, and a quaternized product thereof.
  • at least one selected from the group consisting of the general formulas (C1-1) to (C1-8), a salt thereof and a quaternized product thereof is more preferable, (C1-4) to (C1-6), More preferred is at least one selected from the group consisting of a salt and a quaternized product thereof.
  • a commercially available product may be used, or a product produced by a known method may be used.
  • a compound represented by the general formula (C1-2) (hereinafter “compound (C1-2)”) and a compound represented by the general formula (C1-3) (hereinafter “compound (C1-3)”) are:
  • the fatty acid composition, or a fatty acid methyl ester composition obtained by replacing the fatty acid in the fatty acid composition with a methyl ester of the fatty acid, and methyldiethanolamine can be synthesized.
  • the abundance ratio represented by “compound (C1-2) / compound (C1-3)” is synthesized such that the mass ratio is 99/1 to 50/50. It is preferable to do.
  • the quaternized product when used, it is more preferable to use dimethyl sulfate as a quaternizing agent.
  • the abundance ratio represented by “a quaternized compound (C1-2) / a quaternized compound (C1-3)” was 99/1 to 50/50 by mass ratio. It is preferable to synthesize.
  • Compound represented by general formula (C1-4) (hereinafter “compound (C1-4)”), compound represented by general formula (C1-5) (hereinafter “compound (C1-5)”), general formula
  • the compound represented by (C1-6) (hereinafter “compound (C1-6)”) can be synthesized by a condensation reaction of the above fatty acid composition or fatty acid methyl ester composition and triethanolamine. At that time, the content ratio of each component to the total mass of the compounds (C1-4), (C1-5), and (C1-6) is 1 to 60 masses of the compound (C1-4) from the viewpoint of flexibility.
  • the compound (C1-5) is 5 to 98% by mass
  • the compound (C1-6) is 0.1 to 40% by mass
  • the compound (C1-4) is 30 to 60% by mass
  • C1-5) is 10 to 55% by mass
  • compound (C1-6) is 5 to 35% by mass.
  • dimethyl sulfate it is more preferable to use dimethyl sulfate as a quaternizing agent in that the quaternization reaction proceeds sufficiently.
  • the abundance ratios of the quaternized compounds (C1-4), (C1-5) and (C1-6) are mass ratios from the viewpoint of flexibility, and the quaternized compounds (C1-4) are 1 to 4 It is preferable that the quaternized product of the compound (C1-5) is 60 to 50% by mass, the quaternized product of the compound (C1-6) is 0.1 to 40% by mass, and the compound (C1-4) ) Is 30 to 60% by mass, the quaternized compound (C1-5) is 10 to 55% by mass, and the quaternized compound (C1-6) is 5 to 35% by mass. preferable.
  • esteramine that is not quaternized generally remains after the quaternization reaction.
  • the ratio of “quaternized product / non-quaternized ester amine” is preferably in the range of a mass ratio of 70/30 to 99/1.
  • the compound represented by the general formula (C1-7) (hereinafter “compound (C1-7)”) and the compound represented by the general formula (C1-8) (hereinafter “compound (C1-8)”) are as described above.
  • compound (C1-7) and the compound represented by the general formula (C1-8) (hereinafter “compound (C1-8)”) are as described above.
  • compound (C1-7) N-methylethanolamine and acrylonitrile, JOrg. Chem. , 26, 3409 (1960)
  • N- (2-hydroxyethyl) -N-methyl-1,3-propylenediamine synthesized by a known method.
  • it is preferable to synthesize so that the abundance ratio represented by “compound (C1-7) / compound (C1-8)” is 99/1 to 50/50 by mass ratio.
  • methyl chloride As a quaternizing agent, which is expressed as “a quaternized compound (C1-7) / a quaternized compound (C1-8)”. It is preferable to synthesize so that the abundance ratio is 99/1 to 50/50 by mass ratio.
  • the component (C) has an action of enhancing the adsorption of the component (A) and the component (B), and is blended to impart flexibility to the treated cloth.
  • the amount of component (C) is not particularly limited, but is preferably 0.01 to 30% by mass relative to the total mass of the entire composition.
  • the amount of component (C) is not particularly limited, but is preferably 5 to 30% by mass with respect to the total mass of the entire composition. More preferably, it is 5 to 25% by mass, and further preferably 8 to 22% by mass.
  • the compounding quantity of (C) component is although it does not specifically limit, Preferably it is 0.8 with respect to the total mass of the whole composition.
  • the content is from 01 to 10% by mass, more preferably from 0.03 to 8% by mass, and still more preferably from 0.05 to 5% by mass.
  • the mass ratio of the component (B) / (C) is not particularly limited, but when used as a softener composition, it is preferably 1/300 to 2/3, more Preferably it is 1/25 to 2/3, more preferably 1/15 to 2/3.
  • the mass ratio of the component (B) / (C) is not particularly limited, but when used as a softener composition, it is preferably 1/300 to 2/3, more Preferably it is 1/25 to 2/3, more preferably 1/15 to 2/3.
  • it is preferably 1/1000 to 1000, more preferably 1/80 to 200. More preferably, it is 1/10 to 100.
  • the liquid treatment composition for textiles of the present invention may contain components other than the above components (A) to (C) as necessary, as long as the effects of the present invention are not impaired.
  • a well-known component can be suitably mix
  • water, water-soluble solvents, nonionic surfactants, silicones, dyes and / or pigments, preservatives, ultraviolet absorbers, antibacterial agents and the like can be contained.
  • the liquid treatment composition for textiles of the present invention is preferably an aqueous composition and preferably contains water.
  • water any of tap water, ion exchange water, pure water, distilled water, and the like can be used. Of these, ion-exchanged water is preferred.
  • the nonionic surfactant can be preferably used mainly for the purpose of improving the emulsion dispersion stability of the oil-soluble component in the emulsion when the fiber product treating agent composition of the present invention is an emulsion.
  • a nonionic surfactant when blended, a sufficient level of freeze / restoration stability is easily secured in terms of commercial value.
  • the nonionic surfactant for example, those derived from higher alcohols, higher amines or higher fatty acids can be used.
  • polyoxyethylene alkyl ethers and polyoxyethylene fatty acid alkyls having an alkyl group or alkenyl group having 10 to 22 carbon atoms and an average addition mole number of ethylene oxide of 10 to 100 mol (carbon of the alkyl) 1 to 3) ester; polyoxyethylene alkylamine having an average addition mole number of ethylene oxide of 10 to 100 mole, alkyl polyglucoside having an alkyl group or alkenyl group having 8 to 18 carbon atoms, and an average addition mole number of ethylene oxide
  • Examples include hydrogenated castor oil that is 10 to 100 mol.
  • the content of the nonionic surfactant in the fiber product treatment composition of the present invention can be determined according to the desired function, and is preferably 0.01 to 10% by mass, more preferably 0.1 to 10% by mass. It is 8% by mass, more preferably 0.5 to 5% by mass.
  • the content of the nonionic surfactant is equal to or higher than the lower limit, the emulsion dispersion stability of the oil-soluble component in the emulsion and the freeze recovery stability of the emulsion are further improved. If it is below an upper limit, the raise of the viscosity of the processing agent composition for liquid fiber products can be suppressed, and it can be made favorable in terms of usability.
  • the molecular structure of the silicone compound may be linear, branched, or cross-linked.
  • the silicone compound may be a modified silicone compound, and the modified silicone compound may be modified with one organic functional group or modified with two or more organic functional groups. It may be.
  • the silicone compound can be used in the state of oil, and can also be used in the state of an emulsion dispersed by any emulsifier. Specific examples of the silicone compound include, for example, dimethyl silicone, polyether modified silicone, methylphenyl silicone, alkyl modified silicone, higher fatty acid modified silicone, methyl hydrogen silicone, fluorine modified silicone, epoxy modified silicone, carboxy modified silicone, carbinol.
  • modified silicone and amino-modified silicone examples thereof include modified silicone and amino-modified silicone.
  • polyether-modified silicone, amino-modified silicone, dimethyl silicone and the like are preferable from the viewpoint of versatility and deodorizing and deodorizing effect, and polyether-modified silicone and amino are particularly preferable from the viewpoint of effect and handling during production. Modified silicone is preferred.
  • the polyether-modified silicone include, for example, a copolymer of alkylsiloxane and polyoxyalkylene.
  • the carbon number of the alkyl group of the alkylsiloxane is preferably 1 to 3, and the carbon number of the alkylene group of the polyoxyalkylene is preferably 2 to 5.
  • the polyether-modified silicone is preferably a copolymer of dimethylsiloxane and polyoxyalkylene (polyoxyethylene, polyoxypropylene, a random or block copolymer of ethylene oxide and propylene oxide, etc.).
  • M, N, a, and b represent the average degree of polymerization, and R represents hydrogen or an alkyl group.
  • M is preferably 10 to 10,000, and more preferably 100 to 300.
  • N is preferably 1 to 1,000, and more preferably 1 to 100.
  • a is preferably 2 to 100, and more preferably 2 to 50.
  • b is preferably from 0 to 50, more preferably from 0 to 10.
  • R is preferably hydrogen or an alkyl group having 1 to 4 carbon atoms.
  • the polyether-modified silicone represented by the general formula (I) generally has an organohydrogenpolysiloxane having a Si—H group and a carbon-carbon double bond such as polyoxyalkylene allyl ether at the terminal. It can be produced by addition reaction of polyoxyalkylene alkyl ether with a platinum catalyst. Therefore, the polyether-modified silicone may contain a slight amount of unreacted polyoxyalkylene alkyl ether or organohydrogenpolysiloxane having a Si—H group. Since the organohydrogenpolysiloxane having a Si—H group has high reactivity, the abundance in the polyether-modified silicone is preferably 30 ppm or less (as the amount of Si—H).
  • A, B, h, and i are average polymerization degrees
  • R represents an alkyl group
  • R ′ represents hydrogen or an alkyl group.
  • A is preferably 5 to 10,000
  • B is preferably 2 to 10,000
  • h is preferably 2 to 100
  • i is preferably 0 to 50
  • R is preferably an alkyl group having 1 to 5 carbon atoms.
  • R ′ is preferably hydrogen or an alkyl group having 1 to 4 carbon atoms.
  • the linear polysiloxane-polyoxyalkylene block copolymer represented by the general formula (II) has a polyoxyalkylene compound having a reactive terminal group and a terminal group that reacts with the reactive terminal group of the compound.
  • Such polyether-modified silicone has a longer side chain polyoxyalkylene chain, and the higher the degree of polymerization of the polysiloxane chain, the higher the viscosity. Therefore, it is easy to improve workability during production and blend into aqueous compositions. Therefore, it is preferable to use it in the form of a premix with a water-soluble organic solvent.
  • the water-soluble organic solvent include ethanol, dipropylene glycol, butyl carbitol and the like.
  • examples of the polyether-modified silicone include SH3772M, SH3775M, FZ-2166, FZ-2120, L-720, SH8700, L-7002, L-manufactured by Toray Dow Corning Co., Ltd. 7001, SF8410, FZ-2164, FZ-2203, FZ-2208, manufactured by Shin-Etsu Chemical Co., Ltd., KF352A, KF615A, X-22-6191, X-22-4515, KF-6012, KF-6004, etc.
  • Examples include TSF4440, TSF4441, TSF4445, TSF4450, TSF4446, TSF4452, and TSF4460 manufactured by Momentive Performance Materials Japan GK.
  • the amino-modified silicone is a silicone oil in which an amino group is introduced into the terminal or side chain of the dimethyl silicone skeleton, and a substituent such as a hydroxyl group, an alkyl group, or a phenyl group may be substituted in addition to the amino group.
  • a substituent such as a hydroxyl group, an alkyl group, or a phenyl group
  • the form of oil may be sufficient
  • the form of the amino modified silicone emulsion which emulsified the nonionic surfactant or the cationic surfactant as an emulsifier may be sufficient.
  • a preferred amino-modified silicone oil or base oil in the case of an emulsion is represented by the following general formula (III).
  • R 1 and R 6 may be the same as or different from each other and each represents a methyl group, a hydroxyl group, or hydrogen.
  • R 2 represents any one of — (CH 2 ) n —A 1 and — (CH 2 ) n —NHCO— (CH 2 ) m —A 1 .
  • a 1 represents any one of —N (R 3 ) (R 4 ) and —N + (R 3 ) (R 4 ) (R 5 ) ⁇ X ⁇ .
  • R 3 to R 5 may be the same as or different from each other, and are any of a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, a phenyl group, and — (CH 2 ) n —NH 2 .
  • X ⁇ represents any one of fluorine ion, chlorine ion, bromine ion, iodine ion, methyl sulfate ion, and ethyl sulfate ion.
  • the values of m and n may be the same as or different from each other, and represent an integer of 0 to 12.
  • the values of p and q represent the degree of polymerization of the polysiloxane, and may be the same or different from each other.
  • the kinematic viscosity at 25 ° C. is preferably 50 to 20000 mm 2 / s, and more preferably 100 to 10,000 mm 2 / s. .
  • the kinematic viscosity is in this range, a high texture imparting effect is exhibited, manufacturability is good, and the composition is easy to handle, which is preferable.
  • amino-modified silicones can be used.
  • amino-modified silicone oils sold by Toray Dow Corning Co., Ltd. as SF-8417, BY16-892, BY16-890. From Shin-Etsu Chemical Co., Ltd., KF-864, KF-860, KF-8004, KF-8002, KF-8005, KF-867, KF-861, KF-880, KF-867S and the like can be mentioned.
  • the amino-modified silicone emulsion type is sold by Toray Dow Corning Co., Ltd. as SM8904, BY22-079, FZ-4671, FZ-4672, and sold by Shin-Etsu Chemical Co., Ltd. in the Polon series.
  • the kinematic viscosity of the dimethyl silicone is not particularly limited, is preferably 1 ⁇ 100,000,000mm 2 / s, more preferably 10 ⁇ 10,000,000mm 2 / s, 100 ⁇ 1,000,000mm 2 / s Is more preferable. Further, it may be an oil or an emulsion.
  • the liquid processing agent composition for textiles of this invention contains a water-soluble solvent in addition to water.
  • the water-soluble solvent is preferably one or more selected from the group consisting of lower (C1-4) alcohols, glycol ether solvents, and polyhydric alcohols. Specifically, ethanol, isopropanol, glycerin, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, hexylene glycol, polyoxyethylene phenyl ether, dipropylene glycol monomethyl ether, and water represented by the following general formula (X) It is preferable to mix
  • R 11 is an alkyl or alkenyl group having 1 to 6 carbon atoms, preferably 2 to 4 carbon atoms.
  • y and z are the average number of moles added, y is 1 to 10, preferably 2 to 5, and z is 0 to 5, preferably 0 to 2.
  • water-soluble solvents ethanol, ethylene glycol, butyl carbitol, propylene glycol, diethylene glycol monobutyl ether, and dipropylene glycol monomethyl ether are preferable.
  • the water-soluble solvent is preferably blended in the liquid treatment composition for textiles of the present invention in an amount of 0 to 30% by mass, more preferably 0.01 to 25% by mass, and still more preferably 0.1 to 20% by mass.
  • the dye and / or pigment can be blended for the purpose of improving the appearance of the liquid treating agent composition for textiles of the present invention.
  • it is one or more of red, blue, yellow or purple water-soluble dyes selected from acid dyes, direct dyes, basic dyes, reactive dyes, and mordant / acid mordant dyes.
  • red, blue, yellow or purple water-soluble dyes selected from acid dyes, direct dyes, basic dyes, reactive dyes, and mordant / acid mordant dyes.
  • specific examples of the dyes that can be added are described in the Dye Handbook (edited by the Society of Synthetic Organic Chemistry, published on July 20, 1970, Maruzen Co., Ltd.).
  • the composition has at least one functional group selected from a hydroxyl group, a sulfonic acid group, an amino group, and an amide group in the molecule.
  • Acid dyes, direct dyes, and reactive dyes are preferred, and the blending amount thereof is preferably 1 to 50 ppm, more preferably 1 to 30 ppm, based on the entire composition.
  • Examples of the dye used in the liquid treatment composition for textile products of the present invention include JP-A-6-128301, JP-A-6-122302, JP-A-7-18573, JP-A-8-27669, The dyes described in JP-A-9-250085, JP-A-10-77576, JP-A-11-43865, JP-A-2001-181972, or JP-A-2001-348784 can also be used. it can.
  • the preservative can be used mainly in the treatment composition for textiles of the present invention in order to enhance the antiseptic power and sterilizing power and maintain the antiseptic property during long-term storage.
  • the preservative include isothiazolone organic sulfur compounds, benzisothiazolone organic sulfur compounds, benzoic acids, and 2-bromo-2-nitro-1,3-propanediol.
  • isothiazolone-based organic sulfur compounds include 5-chloro-2-methyl-4-isothiazoline-3-one, 2-n-butyl-3-isothiazolone, 2-benzyl-3-isothiazolone, 2-phenyl-3-isothiazolone 2-methyl-4,5-dichloroisothiazolone, 5-chloro-2-methyl-3-isothiazolone, 2-methyl-4-isothiazoline-3-one, or a mixture thereof.
  • 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one are preferred, and 5-chloro-2-methyl-4-isothiazolin-3-one and 2- A mixture with methyl-4-isothiazolin-3-one is more preferred, and a mixture of about 77% by weight of the former and about 23% by weight of the latter is particularly preferred.
  • the benzisothiazolone organic sulfur compound include 1,2-benzisothiazolin-3-one, 2-methyl-4,5-trimethylene-4-isothiazolin-3-one, and dithio-2,2-bis ( Benzmethylamide) or a mixture thereof.
  • 1,2-benzisothiazolin-3-one is particularly preferable.
  • benzoic acids include benzoic acid or a salt thereof, parahydroxybenzoic acid or a salt thereof, methyl paraoxybenzoate, ethyl paraoxybenzoate, propyl paraoxybenzoate, butyl paraoxybenzoate, benzyl paraoxybenzoate, and the like.
  • the preservative content is preferably 0.0001 to 1% by mass relative to the total amount of the textile treatment composition. When the blending amount of the preservative is less than the lower limit, it is difficult to obtain the effect of adding the preservative, and when it exceeds the upper limit, the storage stability may be lowered.
  • An ultraviolet absorber is a chemical
  • the ultraviolet absorber include aminobenzoic acid derivatives such as p-aminobenzoic acid, ethyl p-aminobenzoate, glyceryl p-aminobenzoate, and amyl p-dimethylaminobenzoate; ethylene glycol salicylate, dipropylene glycol salicylate , Salicylic acid derivatives such as octyl salicylate, myristyl salicylate; methyl diisopropylcinnamate, ethyl p-methoxycinnamate, isopropyl p-methoxycinnamate, 2-ethylhexyl p-methoxycinnamate, p-methoxycinnamic acid
  • the antibacterial agent is a component having an effect of suppressing the growth of bacteria on the fiber and further suppressing the generation of an unpleasant odor derived from the degradation product of the microorganism.
  • Antibacterial agents include, for example, cationic bactericides such as quaternary ammonium salts (benzalkonium chloride), diclosan, triclosan, bis- (2-pyridylthio-1-oxide) zinc, polyhexamethylene biguanidine hydrochloride, Examples include 8-oxyquinoline and polylysine.
  • a shrinkage inhibitor such as polyvinylpyrrolidone, polymer dispersant, stain remover, scum dispersant, 4,4-bis (2-sulfostyryl) biphenyl disodium (Cino Pearl CBS manufactured by Ciba Specialty Chemicals) X) fluorescent whitening agents, dye fixing agents, anti-fading agents such as 1,4-bis (3-aminopropyl) piperazine, stain removers, fiber surface modifiers such as cellulase, amylase, protease, lipase, keratinase, etc.
  • dye transfer inhibitor such as polyvinylpyrrolidone, polymer dispersant, stain remover, scum dispersant, 4,4-bis (2-sulfostyryl) biphenyl disodium (Cino Pearl CBS manufactured by Ciba Specialty Chemicals) X) fluorescent whitening agents, dye fixing agents, anti-fading agents such as 1,4-bis (3-aminopropyl) piperaz
  • Silk protein powders and surface modified products that can give silk texture and functions such as There are emulsified dispersions, specifically K-50, K-30, K-10, A-705, S-702, L-710, FP series (Idemitsu Petrochemical), hydrolyzed silk liquid (upper hair) Anti-contamination of SILKGEN G Solvel S (Ichimaru Falcos), alkylene terephthalate and / or nonionic polymer compounds comprising alkylene isophthalate units and polyoxyalkylene units, such as FR627 from Kyoyo Chemical Industry, SRC-1 from Clariant Japan An agent or the like can be blended.
  • emulsified dispersions specifically K-50, K-30, K-10, A-705, S-702, L-710, FP series (Idemitsu Petrochemical), hydrolyzed silk liquid (upper hair) Anti-contamination of SILKGEN G Solvel S (Ichimaru Falcos), alkylene terephthalate and / or nonionic polymer compounds compris
  • the pH of the liquid treating agent composition for textile products of the present invention is not particularly limited, but in the case of a liquid softening agent composition, it is 25 from the viewpoint of suppressing hydrolysis of the component (C) accompanying storage aging.
  • the pH at 0 ° C. is preferably in the range of 1 to 6, and more preferably in the range of 2 to 4.
  • the pH at 25 ° C. is preferably 5 to 11, from the viewpoint of enhancing the stability of the aroma, 10 is more preferable.
  • hydrochloric acid, sulfuric acid, phosphoric acid, alkyl sulfuric acid, benzoic acid, p-toluenesulfonic acid, citric acid, malic acid, succinic acid, lactic acid, glycolic acid, hydroxyethane diphosphonic acid, phytin PH adjusting agents such as acids, short-chain amine compounds such as ethylenediaminetetraacetic acid and dimethylamine, alkali metal hydroxides such as sodium hydroxide, alkali metal carbonates and alkali metal silicates can be used.
  • the viscosity of the liquid treatment composition for textiles of the present invention is preferably less than 1000 mPa ⁇ s (B-type viscometer, manufactured by TOKIMEC, 25 ° C., the same applies hereinafter). . Considering the increase in viscosity due to storage aging, the viscosity immediately after production is more preferably less than 800 mPa ⁇ s, and further preferably less than 500 mPa ⁇ s. When it is in such a range, the usability such as handling property at the time of loading into the washing machine is good.
  • the viscosity at 25 ° C. is preferably 10 mPa ⁇ s or less from the viewpoint of handling properties, and is 5 mPa ⁇ s or less. It is more preferable that The viscosity can be adjusted by component (B), the amount of water blended, and the like.
  • the preparation method of the liquid processing agent composition for textiles of this invention is not specifically limited.
  • a liquid softening agent composition it can be produced by a known method, for example, a method similar to the conventional method for producing a liquid softening agent composition using a cationic surfactant as a main agent.
  • (A) component, (C) component, the oil phase containing nonionic surfactant, and the aqueous phase containing (B) component are mixed and emulsified under temperature conditions more than melting
  • the product can be prepared, and then, if necessary, it can be produced by adding and mixing other components to the obtained emulsion.
  • the oil phase can be prepared by mixing the component (A), the component (C), a nonionic surfactant, and an optional component as necessary at a temperature equal to or higher than the melting point of the component (C).
  • An aqueous phase can be prepared by mixing water, (B) component, and an arbitrary component as needed.
  • a spray-type fiber treatment agent composition it is not particularly limited and can be prepared according to a conventional method. For example, it can prepare by mixing each said component with water as needed.
  • the use of the liquid treatment agent composition for textiles of this invention is not specifically limited, It can apply to a cleaning composition, a bleaching agent composition, a liquid softening agent composition, a spray type fiber treatment agent, etc. Especially, it is preferable to apply as a liquid softening agent composition or a spray type fiber treatment agent.
  • the method for treating textiles such as clothing with the liquid treating composition for textiles of the present invention is not particularly limited, and conventionally known detergents, finishing agents (softeners, glues, etc.), spray fibers It can process like a processing agent etc.
  • the liquid treatment composition for textile products of the present invention is not particularly limited in the case of a liquid softener composition, but for example, the composition of the present invention is dissolved in rinsing water at the rinsing stage of washing.
  • the bath ratio weight ratio of the treatment liquid to the textile product
  • the bath ratio is preferably 3 to 100 times, more preferably 5 to 50 times.
  • the flexible treatment when it is performed, it is preferably used in such an amount that the concentration of the component (C) is 0.01 ppm to 1000 ppm with respect to the total amount of water used, and more preferably 0.1 ppm to 300 ppm. Is used in such an amount.
  • the method of use is not particularly limited.
  • the treatment composition can be used as a trigger spray container or a dispenser type pump. It can be carried out by placing in a spray container and spraying directly on the textile. After spraying, you may perform a drying process as needed.
  • the fiber product is not particularly limited, and examples thereof include clothing, curtains, sofas, carpets, towels, handkerchiefs, sheets, and macula covers.
  • the coating amount of the treating agent composition on the fiber product is preferably 0.5 to 10 g and more preferably 1 to 5 g per 100 g of the fiber product.
  • the spray type fiber treatment agent is preferably contained in a trigger type spray container (hereinafter referred to as trigger container).
  • the trigger container is not particularly limited, and is generally the same as the trigger container used for the fiber treatment product used for imparting a scent or deodorizing effect to a textile product such as clothing. Can be used.
  • an accumulator type trigger container is preferable from the viewpoints of good spray properties and spray pattern and no occurrence of afterdraw. Further, the amount of spraying once is 0 from the viewpoint of preventing the fiber product sprayed with the treating agent composition from causing stains and giving a preferable effect without giving the hand excessive fatigue. It is preferably 2 to 0.6 g.
  • the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.
  • the component blending amounts are all expressed by mass% (in terms of pure content, unless otherwise specified).
  • Component (B)] B-1 Cluster dextrin (registered trademark, manufactured by Glico Nutrition Foods Co., Ltd.)
  • the main component of Cluster Dextrin has a molecular weight of about 30,000 to 1,000,000, has one cyclic structure in the molecule, and a weight average polymerization degree of 2500 having many glucan chains bonded to the cyclic portion.
  • the cyclic structure portion is composed of about 16 to 100 glucoses, and a large number of acyclic branched glucan chains are bonded to the cyclic structure.
  • B-2 comparativative example
  • B-3 comparativative example: ⁇ cyclodextrin
  • C-1 Cationic surfactant (cationic surfactant described in Example 4 of JP-A-2003-12471)
  • C-2 Cationic surfactant (cationic surfactant described in Example 1 of JP-A-2002-167366)
  • C-3 Didecyldimethylammonium salt (trade name: ARCARD 210, Lion Akzo)
  • D-1 ⁇ Primary isotridecyl alcohol ethylene oxide 60 mol adduct: 2% ⁇ Calcium chloride (trade name: granular calcium chloride, Tokuyama Corporation): 0.5% -Isothiazolone solution (trade name: Caisson CG-ICP, Dow Chemical): 100 ppm *
  • D-2 Polyoxyethylene lauryl ether ethylene oxide 8 mol adduct (trade name: New Coal 1100, Japanese emulsifier): 0.2% ⁇ Isothiazolone solution (trade name: Caisson CG-ICP, Dow Chemical) 100 ppm * * The amount of isothiazolone solution is shown as it is.
  • the amount of each component was adjusted as described in Tables 2 and 3 below, and a liquid softener composition was prepared by the following procedure.
  • the liquid softening agent composition was prepared by the following procedure using a glass container having an inner diameter of 100 mm and a height of 150 mm and a stirrer (Agitator SJ type, manufactured by Shimadzu Corporation).
  • the (A) component, the (C) component, and the optional primary isotridecyl alcohol ethylene oxide 60 mol adduct were mixed and stirred to obtain an oil phase mixture.
  • (B) component and the isothiazolone liquid which is an arbitrary component were dissolved in the balance purified water to obtain an aqueous phase mixture.
  • the mass of the ion-exchange water for balance is equivalent to the balance obtained by subtracting the total mass of the oil phase mixture and (B) from 980 g.
  • the oil phase mixture heated above the melting point of the component (C) is placed in a glass container and stirred, and the aqueous phase mixture heated above the melting point of the component (C) is added in two portions. And stirred.
  • the division ratio of the aqueous phase mixture was 30:70 (mass ratio), and the stirring was performed at a rotational speed of 1,000 rpm for 3 minutes after the first aqueous phase mixture addition and for 2 minutes after the second aqueous phase mixture addition. It was.
  • a liquid softener composition was prepared by the following procedure. Using a 500 ml beaker, ion-exchanged water in which (A) component solution and (B) component aqueous solution are mixed in ethanol, which is optional component, and (C) component and optional component are dissolved therein (Adjust the amount of ion-exchanged water so that the total amount becomes 400 g) was added under stirring conditions to obtain the desired spray type fiber treating agent composition.
  • Softener treatment in the rinsing process at the time of washing The following criteria are used by 15 panelists to determine the smell of the cotton knitted fabric after washing and drying using the softener composition prepared as described above, and the smell of the softener composition. And sensory evaluation. In terms of product value, a value of ⁇ or more was considered acceptable. In addition, the fragrance of the dried cotton knitted fabric was sensory-evaluated according to the following criteria by 15 panelists using the 6-step odor intensity method. In terms of product value, a value of ⁇ or more was considered acceptable.
  • Spraying treatment by spraying The spray-type fiber treatment agent composition prepared as described above was filled in a trigger container, sprayed and dried, and the smell of the cotton knitted fabric and the smell of the spray-type fiber treatment agent composition were treated by the panel 15 Sensory evaluation was performed by a person according to the following criteria. In terms of product value, a value of ⁇ or more was considered acceptable. In addition, the fragrance of the dried cotton knitted fabric was sensory-evaluated according to the following criteria by 15 panelists using the 6-step odor intensity method. In terms of product value, a value of ⁇ or more was considered acceptable.
  • a commercially available clothing care product trade name “Style Guard wrinkles and odors are refreshing spray”, manufactured by Lion Co., Ltd.
  • Table 2 Composition of softener composition (numerical value of composition is% by mass) * For the fragrance composition, the blending amount is shown.
  • Table 3 Composition of softener composition (numerical value of composition is% by mass) * For the fragrance composition, the blending amount is shown.
  • Table 4 Composition of spray type fiber treating agent composition (numerical value of composition is mass%) * For the fragrance composition, the blending amount is shown.
  • Table 5 Composition of spray type fiber treating agent composition (numerical value of composition is mass%) * For the fragrance composition, the blending amount is shown.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

L'invention fournit une composition d'agent de traitement liquide pour article en fibres qui contient : (A) une composition de parfum ; (B) un glucane qui possède une portion structurelle cyclique ramifiée interne et une portion structurelle ramifiée externe, dont le degré de polymérisation est compris dans une plage de 50 à 10000, la portion structurelle cyclique ramifiée interne étant une portion structurelle cyclique formée par une liaison α-1,4-glucoside et une liaison α-1,6-glucoside, et la portion structurelle ramifiée externe étant une portion structurelle non cyclique liée à la portion structurelle cyclique ramifiée interne ; et (C) un agent tensio-actif cationique.
PCT/JP2014/062855 2013-05-14 2014-05-14 Composition d'agent de traitement liquide pour article en fibres WO2014185454A1 (fr)

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JP2015517110A JP6444300B2 (ja) 2013-05-14 2014-05-14 繊維製品用液体処理剤組成物
KR1020157033324A KR102204710B1 (ko) 2013-05-14 2014-05-14 섬유제품용 액체 처리제 조성물
GB1519894.8A GB2534454B (en) 2013-05-14 2014-05-14 Liquid treatment composition for textile product

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JP2017025422A (ja) * 2015-07-16 2017-02-02 ライオン株式会社 繊維処理剤組成物
JP2017025443A (ja) * 2015-07-24 2017-02-02 ライオン株式会社 液体柔軟剤組成物
WO2017164321A1 (fr) * 2016-03-23 2017-09-28 ライオン株式会社 Composition d'adoucissant liquide
JP2019178436A (ja) * 2018-03-30 2019-10-17 ライオン株式会社 繊維処理剤組成物

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JPH05507499A (ja) * 1990-05-09 1993-10-28 ザ、プロクター、エンド、ギャンブル、カンパニー シクロデキストリン複合体用の非破壊性キャリア
JP2003238376A (ja) * 2002-02-08 2003-08-27 Kanebo Ltd 香水コロン組成物
JP2003238375A (ja) * 2002-02-08 2003-08-27 Kanebo Ltd 香料組成物及び化粧料
JP2004067962A (ja) * 2002-08-09 2004-03-04 Ezaki Glico Co Ltd 新規な高分岐環状デキストリンを含有する粉末香料及びその製造方法及びそれを利用した飲食物
JP2007113137A (ja) * 2005-10-19 2007-05-10 Kao Corp 繊維製品への花粉付着抑制方法
JP2009203177A (ja) * 2008-02-27 2009-09-10 Tsumura Lifescience Co Ltd 入浴剤組成物
WO2011123739A1 (fr) * 2010-04-01 2011-10-06 The Procter & Gamble Company Compositions contenant des organosilicones
JP2012029637A (ja) * 2010-07-30 2012-02-16 Japan Tobacco Inc 喫煙物品
JP2013006967A (ja) * 2011-06-24 2013-01-10 Lion Corp 香料組成物及びそれを含む繊維製品用処理剤組成物
WO2013176288A1 (fr) * 2012-05-25 2013-11-28 ライオン株式会社 Composition d'agent de traitement pour article en fibres

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017025422A (ja) * 2015-07-16 2017-02-02 ライオン株式会社 繊維処理剤組成物
JP2017025443A (ja) * 2015-07-24 2017-02-02 ライオン株式会社 液体柔軟剤組成物
WO2017164321A1 (fr) * 2016-03-23 2017-09-28 ライオン株式会社 Composition d'adoucissant liquide
JP2019178436A (ja) * 2018-03-30 2019-10-17 ライオン株式会社 繊維処理剤組成物
JP7051538B2 (ja) 2018-03-30 2022-04-11 ライオン株式会社 繊維処理剤組成物

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KR20160010468A (ko) 2016-01-27
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HK1220998A1 (zh) 2017-05-19
GB2534454B (en) 2021-07-07
GB2534454A (en) 2016-07-27
KR102204710B1 (ko) 2021-01-19
JPWO2014185454A1 (ja) 2017-02-23

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