WO2013131211A1 - 一种硅钢常化基板的生产方法 - Google Patents
一种硅钢常化基板的生产方法 Download PDFInfo
- Publication number
- WO2013131211A1 WO2013131211A1 PCT/CN2012/000367 CN2012000367W WO2013131211A1 WO 2013131211 A1 WO2013131211 A1 WO 2013131211A1 CN 2012000367 W CN2012000367 W CN 2012000367W WO 2013131211 A1 WO2013131211 A1 WO 2013131211A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- furnace
- section
- zone
- heating furnace
- silicon steel
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1261—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
- C21D1/28—Normalising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/34—Methods of heating
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
- C21D1/76—Adjusting the composition of the atmosphere
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
- C21D8/1222—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
- C21D8/1233—Cold rolling
Definitions
- the invention relates to a method for producing a high quality silicon steel normalized substrate. Background technique
- Silicon steel production methods include steel making, hot rolling, normalizing, pickling, cold rolling, and subsequent annealing.
- the purpose of the normalization treatment of non-oriented silicon steel is to obtain a coarse grain structure before cold rolling of the hot rolled sheet, and to obtain a high strength Ovw texture when the cold rolled sheet is annealed.
- Oriented silicon steel products are adjusted in grain size and texture, controlled by hard phase, producing free C, N, and precipitated ALN.
- the normalization process is not well controlled. That is, in the actual production process, if the energy input rate is not effectively controlled, the excess coefficient cannot achieve stable control of ⁇ 1.0, and the actual excess coefficient will be > 1.0, which will be rich in the furnace.
- the collection of excess oxygen does not ensure a reducing atmosphere throughout the entire furnace section of the non-oxidizing heating section.
- the local excess oxygen reacts with Si, Al, Mn, etc., forming a layer of dense oxide which is very difficult to remove Si, Al, Mn, etc. on the surface of the substrate.
- These oxides adhering to the surface of the substrate are very difficult to remove during subsequent shot blasting and pickling processes. After cold rolling, a dust-like point-like feel-free substance adheres to the surface of the rolled hard plate or the entire plate width. .
- Japan's silicon steel production technology is at the world's leading level, and Japanese related patents such as the cited Gazette No. 48-19048 focus on how to remove the dense oxide that has been produced, and how to remove it as much as possible by strengthening the pickling process.
- the domestically published literature "Electrical Steel” edited by He Zhongzhi also describes how to eliminate oxides adhering to the surface of the substrate. The specific contents are as follows: The annealed steel sheet is pickled in concentrated hydrochloric acid containing 10% HF or 70% hydrazine in 1-2% HF + 6 % HN03 acid, or chemically polished or electrolytically polished by H3P04 + HF. After the substrate in which the oxide is completely removed is subjected to the subsequent processing of the silicon steel product, the iron loss is remarkably lowered.
- High quality refers to a dense oxide that cannot be removed by subsequent pickling after the substrate is normalized by this method.
- the method of the present invention can successfully prevent the formation of dense oxides during the normalization process, thereby improving the quality of the normalized substrate of the silicon steel.
- the subsequent process of normalization is simple and the cost is reduced.
- the invention provides a method for producing a high quality silicon steel normalized substrate, which comprises a steel making, hot rolling, and normalizing step, wherein the normalization step uses a normalizing furnace having a non-oxidizing heating furnace section, and the non-oxidizing heating furnace section Including three or more furnace zones, wherein an energy input rate of the furnace zone put into use in the non-oxidation heating furnace section is adjusted to control the excess coefficient ⁇ of the non-oxidation heating furnace section in a range of 0.8 ⁇ 1.0
- the energy input rate refers to the ratio of the actual combustion load power of the burner used in the furnace zone to the full load power of the burner used in the furnace zone
- the excess coefficient refers to the actual amount of combustion air and the theoretical amount of combustion air. Ratio.
- the energy input rate of the furnace zone to be used in the non-oxidation heating furnace section is adjusted to be in the range of 15% to 95%.
- the energy input rate of the furnace zone to be used is adjusted by closing at least one furnace zone of the non-oxidation heating furnace section.
- the energy input rate of the furnace zone to be used is adjusted by adjusting the amount of input of the burner in the furnace zone to be used in the non-oxidation heating furnace section.
- the energy input rate of the furnace zone to be used is adjusted by adjusting the heating rate of the heating process of the non-oxidizing heating furnace section.
- the method of the present invention can successfully prevent the formation of dense oxides during the normalization process, thereby improving the quality of the normalized substrate of the silicon steel.
- the subsequent process of normalization is simple and the cost is reduced.
- Figure 1 is the effect of the energy input rate of the furnace zone without oxidation heating furnace section on the actual excess coefficient in the normalized furnace.
- FIG. 2 is a schematic view showing the burner input and shutdown of the fourth furnace zone (NOF4) of the non-oxidation heating furnace section in the normalizing furnace, wherein the burner is distributed on the operation side and the upper or lower part of the transmission side of the normalizing furnace, indicating the burner Input, X indicates that the burner is off.
- NOF4 fourth furnace zone
- a method for producing a silicon steel normalized substrate comprising a steelmaking, hot rolling, and normalizing step.
- the normalizing furnace along the running direction of the strip includes a preheating section, an oxidation-free heating section, and a furnace throat (furnace height) suddenly low), subsequent processing of each furnace section, outlet sealing chamber.
- the non-oxidation heating furnace section may include two furnace zones, preferably including more than three furnace zones.
- each furnace section comprises at least one furnace section selected from the group consisting of a heating/cooling section of the radiation tube, a heating section of the electric/radiation tube, and a cooling section of the radiant tube/water jacket, and the subsequent normalizing treatment of each furnace Segments can be arranged in any order.
- the heating before the throat is the oxidation-free heating of the direct flame combustion, and the protection atmosphere N 2 is filled between the throat and the outlet sealing chamber (including the throat and the outlet sealing chamber).
- the normalizing furnace functions include preheating, heating, soaking and cooling.
- the invention adjusts the energy input rate (heating load) of the furnace zone in which the non-oxidation heating furnace section is put into use, and controls the excess coefficient ⁇ of the non-oxidation heating furnace section to be 0.8 ⁇ ⁇ ⁇ 1.0, thereby realizing the stability of the reducing atmosphere.
- the weight percentage of the main elements of silicon steel is 0.5 ⁇ Si ⁇ 6.5%, 0.05 ⁇ Mn ⁇ 0.55 %, 0.05 ⁇ AL ⁇ 0.7%, C ⁇ 0.05%, P ⁇ 0.03 %, S ⁇ 0.03 %, the rest is Fe and some are inevitable Impurity element.
- This is only a general chemical composition of silicon steel, and the present invention is not limited thereto, and may include other chemical components.
- the energy input rate is the ratio of the actual combustion load power of the burners used in the furnace zone to the full load power of the burners used in the furnace zone.
- the excess coefficient is the ratio of the actual amount of combustion air to the amount of theoretical combustion air.
- the burners of the non-oxidizing heating furnace section generally have a stable combustion capacity with a residual coefficient set between 0.80 and 1.0 under a certain combustion load. The inventors found through research that the ability to achieve stable control of the actual excess coefficient on a large-scale normalizing furnace is related to the specific structure of the furnace and the arrangement of the burners, in addition to the burner itself.
- the purpose of energy input rate control is to ensure that the burner is burned at the optimal energy input rate, and the stable combustion under the condition of excess coefficient of 0.8-1.0 is realized in the production process.
- the burning flue gas contacts the strip, the air has passed through the fuel.
- the excess coefficient is set at 0.8-1.0, the actual excess coefficient will be greater than 1, and partial peroxidation occurs in the furnace, so that oxygen is generated to form a dense oxide, thereby ensuring that the entire furnace cannot be ensured.
- the reducing atmosphere is to ensure that the burner is burned at the optimal energy input rate, and the stable combustion under the condition of excess coefficient of 0.8-1.0 is realized in the production process.
- the energy input rate of the furnace zone in which the non-oxidation heating furnace section is put into use is less than 15%, the airflow disturbance in the furnace is increased, and the load requirement for ensuring stable combustion of the burner is not achieved, and the gas combustion is insufficient and partially appears.
- Peroxidation When the energy input rate of the furnace zone where the non-oxidation heating furnace section is put into use is greater than 95%, the flow regulating valve (especially the butterfly valve) enters the regulation insensitive zone, the flow control is unstable, and finally the excess coefficient cannot be realized. Control, severe peroxidation occurs locally in the non-oxidation heating section.
- the energy input rate of the furnace zone in which the non-oxidation heating furnace section is put into use is between 15 and 95%, in order to control the non-oxidation heating furnace section.
- the range of excess coefficient ⁇ is 0.8 ⁇ ct ⁇ 1.0, which ultimately ensures that the entire furnace section is in reducing In the atmosphere, the source of oxygen necessary for the formation of oxides is completely cut off, and a high-quality silicon steel normalization plate is produced, which is subjected to shot blasting, pickling, cold rolling and subsequent annealing to produce a high quality silicon steel product.
- the energy input rate of the furnace zone to be used can be adjusted by closing at least one furnace zone of the non-oxidation heating furnace section. Closing a certain furnace zone of the non-oxidation heating furnace section means that all the valves of the furnace zone are shut off, and no air or gas enters the furnace of the furnace zone of the non-oxidation heating furnace section, according to the energy input rate.
- Definition that is, the ratio of the actual combustion load power of the burner used in the furnace zone to the full load power of the burner used in the furnace zone, because the heat required to heat the strip from the normal temperature to the target set temperature is fixed, close In a certain furnace area, for other unclosed furnace areas, the heat required to heat the strip is fixed, which will result in an increase in the actual combustion load of the unclosed furnace area, that is, the burnt in the furnace area that is put into use.
- the actual combustion load power of the mouth is increased, and the full load power of the burner designed in each furnace zone is unchanged, thus realizing the redistribution of the energy input rate of the original furnace zone in other unclosed furnace zones.
- the adjustment of the energy input rate of the furnace zone to be used is achieved by closing at least one furnace zone of the non-oxidation heating furnace section.
- the number of furnace zones that need to be closed can be determined according to the range required for the excess coefficient of the oxidation-free heating furnace section.
- the energy input rate of the furnace zone to be used by adjusting the number of burners used in the furnace zone to be used in the non-oxidation heating furnace section, and the furnace is defined according to the definition of the energy input rate.
- the energy input rate of the furnace zone to be used is adjusted by turning off at least one burner in the furnace zone of the non-oxidation heating furnace section.
- the number of furnace burners that need to be closed can be determined according to the range required for the excess coefficient of the oxidation-free heating furnace section.
- the energy input rate of the furnace zone is also possible to adjust the energy input rate of the furnace zone to be used by adjusting the heating rate of the heating process in the non-oxidation heating furnace section, and the energy input is also changed as the heating rate changes, thereby adjusting The energy input rate of the furnace zone that is put into use.
- the range of the excess coefficient ⁇ of the non-oxidation heating furnace section is controlled by the adjustment of the energy input rate (heating load) of the furnace zone put into use in the non-oxidation heating furnace section, so that no The oxidizing heating furnace section can realize the stable control of the reducing atmosphere of the whole furnace section, thereby cutting off the source of oxygen necessary for forming dense oxides in the whole furnace section, realizing the production of strontium quality silicon steel normalized board, and then blasting and acidizing. After washing, cold rolling and annealing coating treatment, a better quality silicon steel product is formed.
- the production method of hot rolled steel coil including steel making and hot rolling steps, is as follows:
- Hot rolling process It contains different temperature heating, rough rolling, finish rolling, laminar cooling and coiling for the different steel slabs in step 1.
- the hot rolling process independently developed by Baosteel can effectively save energy and obtain A high-yield, high-quality, high-performance hot coil that meets the superior performance and quality requirements of the final product.
- the chemical composition of the prepared hot rolled steel coil is as follows: 0.5 ⁇ Si ⁇ 6.5%, 0.05 ⁇ Mn ⁇ 0.55%, 0.05 ⁇ AL ⁇ 0.7%, C ⁇ 0.05%, P ⁇ 0.03 %, S ⁇ 0.03 %, and the rest is Fe And some inevitable impurity elements.
- Hot-rolled steel coil with chemical composition C 0.0074%, Si: 3.24%, Mn: 0.08 %, P: 0.005 %, S ⁇ 0.007 %, after normalization by different methods, pickling, surface quality of the product after cold rolling Table 1 shows:
- NOF1-6 refers to the first to sixth furnace zones of the non-oxidizing heating section in the normalizing furnace
- the first two furnace zones of the non-oxidation heating furnace section are closed, and the energy input rate of the other four furnace zones of the non-oxidation heating furnace section is adjusted to a range of 15% to 95%, and the oxidation-free heating is controlled.
- the excess coefficient a of each furnace zone of the furnace section ranges from 0.8 ⁇ ⁇ ⁇ 1.0, so that the non-oxidation heating furnace section can achieve stable control of the reducing atmosphere of the entire furnace section, thereby cutting off the formation of dense oxides in the whole furnace section.
- the source of oxygen Therefore, after pickling, there is no oxide residue on the substrate.
- Figure 1 shows the effect of the energy input rate of Example 1 and Comparative Example 1 on the actual excess coefficient.
- the first two furnace zones of the non-oxidation heating furnace section are closed, and the energy input rate of the other four furnace zones of the non-oxidation heating furnace section is adjusted to a range of 15% to 95%, thereby controlling the oxidation-free heating.
- the actual excess coefficient ⁇ of each furnace zone of the furnace section ranges from 0.8 ⁇ ⁇ ⁇ 1.0.
- Comparative Example 1 since the energy input rates of the last two furnace zones of the non-oxidation heating furnace section are all less than 15%, the actual excess coefficient fluctuation range is large, and the range of the excess coefficient a cannot be controlled within the range of 0.8 ⁇ ⁇ ⁇ 1.0.
- Inside. Has a chemical composition of C: 0.0028%, Si: 2.75% Mn : 0.09 0 /.
- the energy input rate of the fourth furnace zone (NOF4) of the non-oxidation heating furnace section was less than 15%, so the excess coefficient ⁇ of the fourth furnace zone of the non-oxidation heating furnace section could not be stably controlled at 0.8 ⁇ ⁇ 1.0, the airflow disturbance in the furnace is increased, and the load requirement for ensuring stable combustion of the burner is not achieved, the gas combustion is insufficient, and partial peroxidation occurs, so that the stable control of the reducing atmosphere of the furnace section cannot be achieved, thereby The segment cannot cut off the source of oxygen necessary to form a dense oxide. Since the product needs to pass through all the furnace zones, as long as one furnace zone does not meet the requirements, there will be oxide residues on the substrate after pickling.
- the energy input rate of each furnace zone of the non-oxidizing heating furnace section is adjusted to a range of 15% to 95%, and the non-oxidizing heating furnace is controlled.
- the excess coefficient ⁇ of each furnace zone is in the range of 0.8 ⁇ ⁇ ⁇ 1.0, so that the oxidation-free heating furnace section can achieve stable control of the reducing atmosphere of the entire furnace section, thereby cutting off the oxygen necessary for forming a dense oxide in the whole furnace section. origin of. Therefore, after pickling, there is no oxide residue on the substrate.
- the production method of the high quality silicon steel normalized substrate of the invention can successfully prevent the formation of dense oxide during the normalization process, thereby improving the quality of the normalized substrate of the silicon steel.
- the method of the invention has the characteristics of simple subsequent process and low cost, and can be used for mass production of high quality silicon steel normalized substrates.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Thermal Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Power Engineering (AREA)
- Electromagnetism (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Manufacturing Of Steel Electrode Plates (AREA)
- Silicon Compounds (AREA)
- Furnace Details (AREA)
- Soft Magnetic Materials (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2014132738/02A RU2591097C2 (ru) | 2012-03-09 | 2012-03-26 | Способ получения листа из нормализованной кремнистой стали |
IN1787MUN2014 IN2014MN01787A (zh) | 2012-03-09 | 2012-03-26 | |
KR1020147023550A KR101612939B1 (ko) | 2012-03-09 | 2012-03-26 | 규소강 노멀라이징 기판 생산방법 |
JP2014560206A JP2015511995A (ja) | 2012-03-09 | 2012-03-26 | 焼ならし珪素鋼基板の製造方法 |
US14/379,777 US9822423B2 (en) | 2012-03-09 | 2012-03-26 | Method for producing silicon steel normalizing substrate |
MX2014010514A MX2014010514A (es) | 2012-03-09 | 2012-03-26 | Metodo para producir sustratos normalizados de acero al silicio. |
EP12870516.7A EP2824193A4 (en) | 2012-03-09 | 2012-03-26 | METHOD FOR PRODUCING A SILICON STEEL NORMALIZATION SUBSTRATE |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210062502.8A CN103305745B (zh) | 2012-03-09 | 2012-03-09 | 一种高质量硅钢常化基板的生产方法 |
CN201210062502.8 | 2012-03-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013131211A1 true WO2013131211A1 (zh) | 2013-09-12 |
Family
ID=49115843
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2012/000367 WO2013131211A1 (zh) | 2012-03-09 | 2012-03-26 | 一种硅钢常化基板的生产方法 |
Country Status (9)
Country | Link |
---|---|
US (1) | US9822423B2 (zh) |
EP (1) | EP2824193A4 (zh) |
JP (1) | JP2015511995A (zh) |
KR (1) | KR101612939B1 (zh) |
CN (1) | CN103305745B (zh) |
IN (1) | IN2014MN01787A (zh) |
MX (1) | MX2014010514A (zh) |
RU (1) | RU2591097C2 (zh) |
WO (1) | WO2013131211A1 (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104017964A (zh) * | 2014-06-12 | 2014-09-03 | 鞍钢股份有限公司 | 一种硅钢热处理方法 |
CN105779731A (zh) * | 2014-12-23 | 2016-07-20 | 鞍钢股份有限公司 | 提高低牌号无取向电工钢电磁性能的热轧板常化工艺 |
US10288963B2 (en) * | 2015-09-21 | 2019-05-14 | Apple Inc. | Display having gate lines with zigzag extensions |
JP6748375B2 (ja) | 2016-10-19 | 2020-09-02 | Jfeスチール株式会社 | Si含有熱延鋼板の脱スケール方法 |
EP3635094A4 (en) * | 2017-06-05 | 2021-03-17 | Mayo Foundation for Medical Education and Research | PROCESSES AND MATERIALS FOR THE CULTURE, PROLIFERATION AND DIFFERENTIATION OF STEM CELLS |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4819048B1 (zh) | 1969-09-03 | 1973-06-11 | ||
JPS62120427A (ja) * | 1985-11-20 | 1987-06-01 | Kawasaki Steel Corp | けい素鋼熱延板の焼鈍方法 |
JPH02149622A (ja) * | 1988-11-29 | 1990-06-08 | Sumitomo Metal Ind Ltd | 磁気特性の良好な無方向性電磁鋼板の製造法 |
JPH05202419A (ja) * | 1992-01-27 | 1993-08-10 | Kawasaki Steel Corp | けい素鋼熱延板の脱スケール方法 |
CN2471440Y (zh) * | 2000-07-13 | 2002-01-16 | 武汉钢铁(集团)公司 | 新型硅钢热轧板常化退火炉 |
CN101812571A (zh) * | 2009-02-24 | 2010-08-25 | 宝山钢铁股份有限公司 | 电工钢热轧带钢常化处理中防止内氧化层的方法 |
Family Cites Families (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2669442A (en) * | 1948-08-24 | 1954-02-16 | Crown Cork & Seal Co | Annealing apparatus |
US3105782A (en) * | 1960-10-10 | 1963-10-01 | Gen Electric | Method of producing magnetic material |
US3307981A (en) * | 1963-11-14 | 1967-03-07 | Inland Steel Co | Continuous bluing and annealing process |
US3778221A (en) * | 1969-02-26 | 1973-12-11 | Allegheny Ludlum Ind Inc | Annealing furnace and method for its operation |
US3756868A (en) * | 1971-05-04 | 1973-09-04 | Allegheny Ludlum Ind Inc | Method of annealing steel coils moving through a furnace |
JPS54160514A (en) * | 1978-06-09 | 1979-12-19 | Nippon Steel Corp | Decarburization and annealing method for directional electromagnetic steel plate |
JPS55128530A (en) * | 1979-03-24 | 1980-10-04 | Nippon Steel Corp | Method and apparatus for controlling atmosphere of direct fire heating type deoxidizing furnace |
JPS55138024A (en) * | 1979-04-12 | 1980-10-28 | Kawasaki Steel Corp | Method of annealing directional silicon steel plate to flatten it |
JPS5613430A (en) * | 1979-07-14 | 1981-02-09 | Nisshin Steel Co Ltd | Annealing method of steel |
JPS61190056A (ja) * | 1985-02-18 | 1986-08-23 | Nippon Steel Corp | 耐熱性と高温強度にすぐれた溶融アルミメツキTi含有鋼板の製造法 |
JPS6240312A (ja) * | 1985-08-15 | 1987-02-21 | Kawasaki Steel Corp | 炉内における雰囲気制御方法 |
JPH0756545B2 (ja) * | 1985-09-06 | 1995-06-14 | 松下電器産業株式会社 | 液晶マトリツクス表示パネルの駆動法 |
JPS63262417A (ja) * | 1987-04-21 | 1988-10-28 | Sumitomo Metal Ind Ltd | 直火式連続加熱炉の無酸化加熱方法 |
JPS6452025A (en) * | 1987-08-20 | 1989-02-28 | Nippon Steel Corp | Direct fire reduction heating method for steel strip |
JPH0230720A (ja) * | 1988-07-16 | 1990-02-01 | Kobe Steel Ltd | 鋼板の加熱方法 |
JPH0441623A (ja) * | 1990-06-07 | 1992-02-12 | Nippon Steel Corp | 鋼帯の直火加熱炉 |
JPH04202623A (ja) * | 1990-11-30 | 1992-07-23 | Kawasaki Steel Corp | けい素鋼熱延板の脱スケール方法 |
US5354389A (en) * | 1991-07-29 | 1994-10-11 | Nkk Corporation | Method of manufacturing silicon steel sheet having grains precisely arranged in Goss orientation |
JPH0758140B2 (ja) * | 1991-11-26 | 1995-06-21 | 株式会社ノーリツ | 風呂釜装置における浴槽水の循環判定方法 |
JP2733885B2 (ja) * | 1992-07-02 | 1998-03-30 | 新日本製鐵株式会社 | 鋼帯の連続熱処理方法 |
US5302213A (en) * | 1992-12-22 | 1994-04-12 | Air Products And Chemicals, Inc. | Heat treating atmospheres from non-cryogenically generated nitrogen |
US5807441A (en) * | 1993-11-02 | 1998-09-15 | Sumitomo Metal Industries, Ltd. | Method of manufacturing a silicon steel sheet having improved magnetic characteristics |
US5620533A (en) * | 1995-06-28 | 1997-04-15 | Kawasaki Steel Corporation | Method for making grain-oriented silicon steel sheet having excellent magnetic properties |
DE69840740D1 (de) * | 1997-04-16 | 2009-05-28 | Nippon Steel Corp | Unidirektionales elektromagnetisches stahlblech mit hervorragenden film- und magnetischen eigenschaften, herstellungsverfahren und entkohlungsglühungskonfiguration dafür |
JPH10306328A (ja) * | 1997-04-28 | 1998-11-17 | Nippon Steel Corp | 連続焼鈍炉 |
RU2139944C1 (ru) * | 1998-05-27 | 1999-10-20 | Открытое акционерное общество "Череповецкий сталепрокатный завод" | Способ отопления печи с камерами предварительного и окончательного нагрева металла и печь для его осуществления |
US6612154B1 (en) * | 1998-12-22 | 2003-09-02 | Furnace Control Corp. | Systems and methods for monitoring or controlling the ratio of hydrogen to water vapor in metal heat treating atmospheres |
US6180933B1 (en) * | 2000-02-03 | 2001-01-30 | Bricmont, Inc. | Furnace with multiple electric induction heating sections particularly for use in galvanizing line |
DE60144270D1 (de) * | 2000-08-08 | 2011-05-05 | Nippon Steel Corp | Verfahren zur Herstellung eines kornorientierten Elektrobleches mit hoher magnetischer Flussdichte |
BE1014997A3 (fr) * | 2001-03-28 | 2004-08-03 | Ct Rech Metallurgiques Asbl | Procede de recuit en continu de bandes en acier en vue de leur galvanisation au trempe et four pour sa mise en oeuvre. |
RU2217509C2 (ru) * | 2001-08-09 | 2003-11-27 | Открытое акционерное общество "Новолипецкий металлургический комбинат" | Способ производства изотропной электротехнической стали |
JP4413549B2 (ja) * | 2002-08-08 | 2010-02-10 | 独立行政法人 日本原子力研究開発機構 | 高温強度に優れたマルテンサイト系酸化物分散強化型鋼の製造方法 |
JP3753248B2 (ja) * | 2003-09-01 | 2006-03-08 | 核燃料サイクル開発機構 | 残留α粒を有する高温強度に優れたマルテンサイト系酸化物分散強化型鋼の製造方法 |
FR2867991B1 (fr) * | 2004-03-25 | 2007-05-04 | Ugine Et Alz France Sa | Bandes en acier inoxydable austenitique d'aspect de surface mat |
RU2262540C1 (ru) * | 2004-10-12 | 2005-10-20 | Липецкий Государственный Технический Университет (Лгту) | Способ производства изотропной электротехнической стали с фосфором |
UA28503U (en) * | 2007-08-13 | 2007-12-10 | Vinnytsia Pyrohov Nat Medical | Attachment for apparatus for vibromassage of palatine tonsils |
CN101643881B (zh) * | 2008-08-08 | 2011-05-11 | 宝山钢铁股份有限公司 | 一种含铜取向硅钢的生产方法 |
MX2012008097A (es) * | 2010-01-11 | 2012-07-30 | Kolene Corp | Acondicionamiento de incrustacion de superficie de metal. |
JP5375653B2 (ja) * | 2010-02-17 | 2013-12-25 | 新日鐵住金株式会社 | 無方向性電磁鋼板の製造方法 |
CN102373366A (zh) * | 2010-08-26 | 2012-03-14 | 宝山钢铁股份有限公司 | 一种改善无取向硅钢表面粗晶的方法 |
RU2562182C2 (ru) * | 2011-01-12 | 2015-09-10 | Ниппон Стил Энд Сумитомо Метал Корпорейшн | Лист из электротехнической стали с ориентированной зеренной структурой и способ его получения |
JP6188671B2 (ja) * | 2014-12-12 | 2017-08-30 | 株式会社Ssテクノ | 水蒸気リフロー装置及び水蒸気リフロー方法 |
-
2012
- 2012-03-09 CN CN201210062502.8A patent/CN103305745B/zh active Active
- 2012-03-26 RU RU2014132738/02A patent/RU2591097C2/ru active
- 2012-03-26 US US14/379,777 patent/US9822423B2/en active Active
- 2012-03-26 EP EP12870516.7A patent/EP2824193A4/en not_active Ceased
- 2012-03-26 WO PCT/CN2012/000367 patent/WO2013131211A1/zh active Application Filing
- 2012-03-26 KR KR1020147023550A patent/KR101612939B1/ko active IP Right Grant
- 2012-03-26 JP JP2014560206A patent/JP2015511995A/ja active Pending
- 2012-03-26 MX MX2014010514A patent/MX2014010514A/es active IP Right Grant
- 2012-03-26 IN IN1787MUN2014 patent/IN2014MN01787A/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4819048B1 (zh) | 1969-09-03 | 1973-06-11 | ||
JPS62120427A (ja) * | 1985-11-20 | 1987-06-01 | Kawasaki Steel Corp | けい素鋼熱延板の焼鈍方法 |
JPH02149622A (ja) * | 1988-11-29 | 1990-06-08 | Sumitomo Metal Ind Ltd | 磁気特性の良好な無方向性電磁鋼板の製造法 |
JPH05202419A (ja) * | 1992-01-27 | 1993-08-10 | Kawasaki Steel Corp | けい素鋼熱延板の脱スケール方法 |
CN2471440Y (zh) * | 2000-07-13 | 2002-01-16 | 武汉钢铁(集团)公司 | 新型硅钢热轧板常化退火炉 |
CN101812571A (zh) * | 2009-02-24 | 2010-08-25 | 宝山钢铁股份有限公司 | 电工钢热轧带钢常化处理中防止内氧化层的方法 |
Non-Patent Citations (2)
Title |
---|
See also references of EP2824193A4 * |
WANG, LU: "Application of the Digital Pulse Combustion Control System in the Cold Strip Annealing Furnace", BAO-STEEL TECHNOLOGY, vol. 1, February 2010 (2010-02-01), pages 76 - 80, XP008174753 * |
Also Published As
Publication number | Publication date |
---|---|
JP2015511995A (ja) | 2015-04-23 |
KR20140115367A (ko) | 2014-09-30 |
EP2824193A1 (en) | 2015-01-14 |
RU2014132738A (ru) | 2016-04-27 |
EP2824193A4 (en) | 2016-01-27 |
RU2591097C2 (ru) | 2016-07-10 |
CN103305745B (zh) | 2016-04-27 |
MX2014010514A (es) | 2014-10-14 |
CN103305745A (zh) | 2013-09-18 |
US9822423B2 (en) | 2017-11-21 |
KR101612939B1 (ko) | 2016-04-18 |
US20150013847A1 (en) | 2015-01-15 |
IN2014MN01787A (zh) | 2015-07-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI472626B (zh) | 方向性電磁鋼板的製造方法及方向性電磁鋼板的再結晶退火設備 | |
JP6808735B2 (ja) | 方向性電磁鋼板の製造方法 | |
US20130224064A1 (en) | Non-oriented electrical steel plate without corrugated fault and production method thereof | |
TWI448566B (zh) | 方向性電磁鋼板的製造方法 | |
US10428403B2 (en) | Method for manufacturing grain-oriented electrical steel sheet | |
CN101812571B (zh) | 电工钢热轧带钢常化处理中防止内氧化层的方法 | |
CN102575314B (zh) | 低铁损、高磁通密度、取向电工钢板及其制造方法 | |
WO2013131211A1 (zh) | 一种硅钢常化基板的生产方法 | |
WO2014047757A1 (zh) | 一种高磁感普通取向硅钢的制造方法 | |
JP2003096520A (ja) | 皮膜特性と高磁場鉄損に優れる高磁束密度一方向性電磁鋼板の製造方法 | |
CN107858494A (zh) | 低温高磁感取向硅钢的生产方法 | |
CN111417737B (zh) | 低铁损取向性电磁钢板及其制造方法 | |
CN103305744B (zh) | 一种高质量硅钢常化基板的生产方法 | |
KR950013286B1 (ko) | 무방향성 전자 강스트립의 제조방법 | |
CN111719078B (zh) | 一种消除瓦楞状缺陷的无取向硅钢生产方法 | |
JP3931842B2 (ja) | 無方向性電磁鋼板の製造方法 | |
CN114717480B (zh) | 一种b8≥1.90t中温普通取向硅钢及制造方法 | |
RU2407808C1 (ru) | Способ производства анизотропной электротехнической стали с низкими удельными потерями на перемагничивание | |
JP4277529B2 (ja) | 下地被膜を有しない方向性電磁鋼板の製造方法 | |
JP6228956B2 (ja) | 低鉄損高磁束密度方向性電気鋼板及びその製造方法 | |
JP2002161313A (ja) | 磁性焼鈍後の磁気特性に優れた無方向性電磁鋼板の製造方法 | |
CN106011655A (zh) | 一种高效硅钢常化基板的生产方法 | |
JPS61104025A (ja) | 任意の磁束密度をもつ鉄損の低い一方向性電磁鋼板の製造法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 12870516 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14379777 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 20147023550 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: MX/A/2014/010514 Country of ref document: MX |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2012870516 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 2014560206 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2014132738 Country of ref document: RU Kind code of ref document: A |