WO2013089085A1 - 導電シート及びタッチパネル - Google Patents
導電シート及びタッチパネル Download PDFInfo
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- WO2013089085A1 WO2013089085A1 PCT/JP2012/082030 JP2012082030W WO2013089085A1 WO 2013089085 A1 WO2013089085 A1 WO 2013089085A1 JP 2012082030 W JP2012082030 W JP 2012082030W WO 2013089085 A1 WO2013089085 A1 WO 2013089085A1
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- Prior art keywords
- conductive sheet
- electrode
- electrode pattern
- electrode terminal
- pattern
- Prior art date
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
- G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
- G06F3/044—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
- G06F3/0445—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means using two or more layers of sensing electrodes, e.g. using two layers of electrodes separated by a dielectric layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
- G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
- G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
- G06F3/044—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
- G06F3/0446—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means using a grid-like structure of electrodes in at least two directions, e.g. using row and column electrodes
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/0274—Optical details, e.g. printed circuits comprising integral optical means
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/0296—Conductive pattern lay-out details not covered by sub groups H05K1/02 - H05K1/0295
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F2203/00—Indexing scheme relating to G06F3/00 - G06F3/048
- G06F2203/041—Indexing scheme relating to G06F3/041 - G06F3/045
- G06F2203/04103—Manufacturing, i.e. details related to manufacturing processes specially suited for touch sensitive devices
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F2203/00—Indexing scheme relating to G06F3/00 - G06F3/048
- G06F2203/041—Indexing scheme relating to G06F3/041 - G06F3/045
- G06F2203/04111—Cross over in capacitive digitiser, i.e. details of structures for connecting electrodes of the sensing pattern where the connections cross each other, e.g. bridge structures comprising an insulating layer, or vias through substrate
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F2203/00—Indexing scheme relating to G06F3/00 - G06F3/048
- G06F2203/041—Indexing scheme relating to G06F3/041 - G06F3/045
- G06F2203/04112—Electrode mesh in capacitive digitiser: electrode for touch sensing is formed of a mesh of very fine, normally metallic, interconnected lines that are almost invisible to see. This provides a quite large but transparent electrode surface, without need for ITO or similar transparent conductive material
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/09218—Conductive traces
- H05K2201/09245—Crossing layout
Definitions
- the present invention relates to a conductive sheet and a touch panel, for example, a conductive sheet and a touch panel used in a projected capacitive touch panel.
- the touch panel is attracting attention.
- the touch panel is mainly applied to a small size such as a PDA (personal digital assistant) or a mobile phone, but it is considered that the touch panel will be increased in size by being applied to a display for a personal computer.
- PDA personal digital assistant
- ITO indium tin oxide
- ITO has a problem that the resistance increases and the transmission speed of the current between the electrodes decreases as the application size increases, and the response speed (the time from when the fingertip is touched until the position is detected) is delayed.
- Patent Documents 3 to 9 are known as touch panels using metal fine wires as electrodes.
- the sensing electrode of the touch panel has an electrode pattern in which at least a touch area is formed of a thin metal wire, and an electrode terminal electrically connected to an end portion of the electrode pattern.
- the electrode terminal is a thick terminal (solid terminal) in order to have high conductivity. Therefore, when the display and the touch panel are operated in combination, in the sensing area (electrode pattern), since the electrode terminal blocks the light emitted from the display, a darkened portion appears in the vicinity of the electrode terminal in the sensing area, making it difficult to see the display. Sometimes.
- the present invention has been made in consideration of such problems, and an object thereof is to provide a conductive sheet and a touch panel that do not impair visibility in the vicinity of electrode terminals in a sensing region.
- the first conductive sheet of the present invention is a conductive sheet having an electrode pattern composed of fine metal wires and an electrode terminal electrically connected to an end portion of the electrode pattern, and transmitting the electrode pattern
- the transmittance is 83% or more and the transmittance of the electrode pattern is expressed as a%
- the transmittance of the electrode terminal is (a-20)% or more and (a-3)% or less.
- a first conductive sheet according to another aspect of the present invention is a conductive sheet having an electrode pattern composed of a thin metal wire and an electrode terminal electrically connected to an end of the electrode pattern,
- the aperture ratio of the electrode pattern is 90% or more and the aperture ratio of the electrode pattern is expressed as b%
- the aperture ratio of the electrode terminal is (b-20)% or more and (b-0.1)% or less. is there.
- the electrode terminal includes a mesh shape made of a grid composed of fine metal wires, the fine metal wires have a line width of 30 ⁇ m or less, and the fine metal wires are opaque materials. Consists of.
- the first touch panel of the present invention includes an electrode pattern provided in a sensing area and configured by a thin metal wire, and an electrode terminal provided outside the sensing area and electrically connected to an end of the electrode pattern.
- the transmittance of the electrode pattern is 83% or more, and when the transmittance of the electrode pattern is expressed as a%, the transmittance of the electrode terminal is (a -20)% or more and (a-3)% or less.
- a first touch panel is provided in a sensing region, and is provided with an electrode pattern composed of a thin metal wire, and provided outside the sensing region, and is electrically connected to an end of the electrode pattern.
- the electrode terminal has a conductive sheet provided with an opening ratio of the electrode pattern when the opening ratio of the electrode pattern is 90% or more and the opening ratio of the electrode pattern is expressed as b%. The rate is not less than (b-20)% and not more than (b-0.1)%.
- the second conductive sheet of the present invention is a conductive sheet having an electrode pattern composed of fine metal wires, and an electrode terminal electrically connected to an end of the electrode pattern, the electrode terminal comprising: Includes a frame shape made of fine metal wires.
- the line width of the thin line of the electrode pattern is a ( ⁇ m)
- the line width b ( ⁇ m) of the frame shape of the electrode terminal is b ⁇ 2a, Or, b ⁇ a + 5 ( ⁇ m) is satisfied.
- the line width a ( ⁇ m) of the thin line of the electrode pattern is preferably 30 ⁇ m or less.
- a mesh shape including a lattice shape constituted by the fine metal wires is further provided inside the frame shape constituted by the fine metal wires of the electrode terminals.
- the second touch panel of the present invention is provided with an electrode pattern provided in a sensing region and configured by a fine metal wire, and an electrode terminal provided outside the sensing region and electrically connected to an end of the electrode pattern.
- the electrode terminal includes a frame shape made of a thin metal wire.
- the third conductive sheet of the present invention is a conductive sheet having an electrode pattern composed of fine metal wires and an electrode terminal electrically connected to an end of the electrode pattern, the electrode terminal being a metal It includes a mesh shape consisting of a grid composed of fine lines.
- the electrode pattern has a mesh shape made of a lattice
- the mesh-shaped pitch made of the electrode terminal lattice has a mesh shape made of the electrode pattern lattice. It is denser than the pitch.
- the mesh-shaped pitch formed of the electrode terminal lattice is more preferably 3/4 or less, further preferably 2/3 or less, and more preferably 1/2 of the mesh-shaped pitch formed of the electrode pattern lattice.
- the pitch of the mesh shape of a specific electrode terminal is 50 ⁇ m or more and 300 ⁇ m or less, and more preferably 50 ⁇ m or more and 250 ⁇ m or less.
- the electrode terminal is provided with a frame shape made of a fine metal wire on a mesh-shaped outer frame made of a lattice of the electrode terminals.
- the third conductive sheet of the present invention preferably has a surface resistance value of the electrode terminal of 4 ⁇ / sq. Or more and 80 ⁇ / sq. Or less.
- the third touch panel of the present invention is provided with an electrode pattern provided in a sensing area and configured by a thin metal wire, and an electrode terminal provided outside the sensing area and electrically connected to an end of the electrode pattern.
- the electrode terminal includes a mesh shape made of a grid made of fine metal wires.
- the conductive sheet and the touch panel of the present invention visibility can be prevented from being impaired in the vicinity of the electrode terminals in the sensing region.
- the disassembled perspective view which omits and shows the conductive sheet for touch panels partially (the 1).
- FIG. 4 is a plan view showing an example of a second electrode pattern formed on the second conductive sheet.
- ⁇ indicating a numerical range is used as a meaning including numerical values described before and after the numerical value as a lower limit value and an upper limit value.
- the conductive sheet 10 for the first touch panel includes an electrode pattern 16A (16B) made of fine metal wires and end portions of the electrode pattern 16A (16B).
- the electrode terminal 60A (60B) electrically connected with the electrode pattern 16A (16B) has a transmittance of 83% or more.
- the transmittance of 16A (16B) is expressed as a%
- the transmittance of the electrode terminal 60A (60B) is configured to be (a-20)% or more and (a-3)% or less.
- the conductive sheet 10 for the first touch panel is electrically connected to the electrode pattern 16A (16B) made of fine metal wires, and the end of the electrode pattern 16A (16B).
- the aperture ratio of the electrode pattern 16A (16B) is 90% or more, and the electrode pattern 16A (16B) ) Is expressed as b%, the electrode terminal 60A (60B) is configured so that the aperture ratio is (b-20)% or more and (b-0.1)% or less.
- the conductive sheet 10 for the second touch panel includes an electrode pattern 16A (16B) made up of fine metal wires, and end portions of the electrode pattern 16A (16B).
- the conductive sheet 12A (12B) having the electrode terminal 60A (60B) electrically connected to the electrode terminal 60A (60B), and the electrode terminal 60A (60B) is configured to include a frame shape 64 made of a thin metal wire.
- the conductive sheet 10 for the third touch panel includes an electrode pattern 16A (16B) composed of fine metal wires and an end portion of the electrode pattern 16A (16B).
- the conductive sheet 10 for touch panels which concerns on this Embodiment is comprised by laminating
- the first conductive sheet 12A has a first electrode pattern 16A formed on one main surface of the first transparent substrate 14A (see FIG. 5A), as shown in FIGS. 4A, 4B and 6A.
- the first electrode pattern 16A is composed of a number of grids made of fine metal wires.
- Each of the first electrode patterns 16A extends in the first direction (x direction) and is arranged in a second direction (y direction) perpendicular to the first direction, and each of the two or more first conductive patterns 18A, A first non-conductive pattern 20A that electrically isolates the first conductive pattern 18A.
- a plurality of disconnected portions 22A are formed in addition to the intersections of the fine metal wires.
- Each first conductive pattern 18A is electrically separated by the plurality of disconnected portions 22A.
- the fine metal wires constituting the first electrode pattern 16A have a line width of 30 ⁇ m or less, preferably 15 ⁇ m or less, more preferably 10 ⁇ m or less, more preferably 9 ⁇ m or less, and even more preferably 7 ⁇ m or less.
- the lower limit of the line width is preferably 1 ⁇ m.
- the first conductive pattern 18A and the first non-conductive pattern 20A have substantially the same line width. In FIG. 6A, the first conductive pattern 18A and the first non-conductive pattern 20A are shown in order to clarify the first conductive pattern 18A and the first non-conductive pattern 20A.
- the line width of the conductive pattern 18A is widened, and the line width of the first non-conductive pattern 20A is narrowed and exaggerated.
- the line width of the first conductive pattern 18A and the line width of the first non-conductive pattern 20A may be the same or different. Preferably, both line widths are the same. The reason is that the visibility may deteriorate if the line width is different.
- the fine metal wires of the first electrode pattern 16A are made of a metal material such as gold, silver, copper, or a conductive material such as a metal oxide, and are made of an opaque conductive material.
- the first electrode pattern 16A includes a plurality of grids 24A composed of intersecting fine metal wires.
- the lattice 24A includes an opening region surrounded by fine metal wires.
- the grating 24A has a grating pitch Pa of 300 ⁇ m to 800 ⁇ m, preferably 400 ⁇ m to 600 ⁇ m.
- the grid 24A of the first conductive pattern 18A and the grid 24A of the first non-conductive pattern 20A have substantially the same size.
- the grid 24A of the first non-conductive pattern 20A has a broken portion 22A in addition to the intersecting portion of the fine metal wires. It is not necessary for all the grids 24A constituting the first non-conductive pattern 20A to have the disconnection portions 22A. It is only necessary that the first non-conductive pattern 20A can achieve electrical separation between the adjacent first conductive patterns 18A.
- the length of the disconnection portion 22A is preferably 60 ⁇ m or less.
- the lower limit of the length of the disconnection portion 22A is preferably 10 ⁇ m, more preferably 15 ⁇ m, and even more preferably 20 ⁇ m.
- the upper limit value of the length of the disconnected portion 22A is preferably 50 ⁇ m, more preferably 40 ⁇ m, and even more preferably 30 ⁇ m.
- a preferable range is 10 ⁇ m or more and 50 ⁇ m or less, and 15 ⁇ m or more and 30 ⁇ m or less.
- the range in which the disconnection portion 22A is formed can be expressed by, for example, variation in linear density.
- the variation of the line density is the variation of the total fine line length in the unit small lattice, and can be defined as ⁇ (total line length maximum value ⁇ total line length minimum value) / total line length average value / 2 (%).
- the range in which the disconnection portion 22A is formed is preferably ⁇ 15%, more preferably ⁇ 10%, due to variations in cotton density.
- the grid 24A has a substantially rhombus shape.
- the substantially rhombus shape means a parallelogram whose diagonal lines are substantially orthogonal.
- other polygonal shapes may be used.
- the shape of one side may be a curved shape or a circular arc shape in addition to a linear shape.
- an arc shape for example, two opposing sides may be outwardly convex arc shapes, and the other two opposing sides may be inwardly convex arc shapes.
- the shape of each side may be a wavy shape in which an outwardly convex arc and an inwardly convex arc are continuous.
- the shape of each side may be a sine curve.
- Each of the first conductive patterns 18A is a so-called diamond pattern having wide portions and narrow portions alternately arranged along the first direction (x direction).
- each first non-conductive pattern 20A includes wide portions and narrow portions that are alternately arranged along the first direction (x direction).
- the order of the wide portion and the narrow portion of the first conductive pattern 18A is opposite to the order of the wide portion and the narrow portion of the first non-conductive pattern 20A.
- Each first conductive pattern 18A is not limited to the diamond pattern, but may be a strip shape having a predetermined width (stripe shape), a zigzag shape having a predetermined width, or the like. Examples of the patterning include an electrode shape applied with an existing ITO transparent conductive film.
- each first conductive pattern 18A is electrically connected to the first external wiring 62A via the first electrode terminal 60A.
- the other end of each first conductive pattern 18A is an open end.
- the other end portion of each first conductive pattern 18A may have a pattern shape or a shape having a terminal similar to the one end portion, except that it is not electrically connected to the external wiring.
- the second conductive sheet 12B has a second electrode pattern 16B formed on one main surface of the second transparent base 14B (see FIG. 5A).
- the second electrode pattern 16B is composed of a number of grids made of fine metal wires.
- Each of the second electrode patterns 16B extends in the second direction (y direction) and is arranged in a first direction (x direction) orthogonal to the second direction.
- a second non-conductive pattern 20B that electrically isolates the second conductive pattern 18B.
- a plurality of disconnected portions 22B are formed in addition to the intersections of the fine metal wires.
- the second conductive patterns 18B are electrically separated by the plurality of disconnected portions 22B.
- the fine metal wires constituting the second electrode pattern 16B have substantially the same line width as the fine metal wires constituting the first electrode pattern 16A.
- the second conductive pattern 18B and the second non-conductive pattern 20B have substantially the same line width.
- the second conductive pattern 18B and the second non-conductive pattern 20B are shown in order to clarify the second conductive pattern 18B and the second non-conductive pattern 20B.
- the line width of the conductive pattern 18B is widened and the line width of the second non-conductive pattern 20B is narrowed and exaggerated.
- the line width of the second conductive pattern 18B and the line width of the second non-conductive pattern 20B may be the same or different. Preferably, both line widths are the same. The reason is that the visibility may deteriorate if the line width is different.
- the fine metal wire of the second electrode pattern 16B is made of the same conductive material as the fine metal wire of the first electrode pattern 16A.
- the second electrode pattern 16B includes a plurality of grids 24B made up of intersecting fine metal wires.
- the lattice 24B includes an opening region surrounded by fine metal wires.
- the grating 24B has a grating pitch Pb of 300 ⁇ m or more and 800 ⁇ m or less, preferably 400 ⁇ m or more and 600 ⁇ m or less.
- the grid 24B of the second conductive pattern 18B and the grid 24B of the second non-conductive pattern 20B have substantially the same size.
- the grid 24B of the second non-conductive pattern 20B has a disconnected portion 22B in addition to the intersecting portion of the thin metal wires. It is not necessary for all the lattices 24B constituting the second non-conductive pattern 20B to have the disconnected portion 22B. It is only necessary that the second non-conductive pattern 20B can achieve electrical separation between the adjacent second conductive patterns 18B.
- the length of the disconnected portion 22B is preferably 60 ⁇ m or less.
- the lower limit of the length of the disconnection portion 22A is preferably 10 ⁇ m, more preferably 15 ⁇ m, and even more preferably 20 ⁇ m.
- the upper limit value of the length of the disconnected portion 22A is preferably 50 ⁇ m, more preferably 40 ⁇ m, and even more preferably 30 ⁇ m.
- a preferable range is 10 ⁇ m or more and 50 ⁇ m or less, and 15 ⁇ m or more and 30 ⁇ m or less.
- the range in which the disconnection portion 22B is formed can be expressed by, for example, variation in linear density.
- the variation of the line density is the variation of the total fine line length in the unit small lattice, and can be defined as ⁇ (total line length maximum value ⁇ total line length minimum value) / total line length average value / 2 (%).
- the range in which the disconnection portion 22B is formed is preferably ⁇ 15%, more preferably ⁇ 10%, due to variations in cotton density.
- the lattice 24B has a substantially rhombus shape.
- the substantially rhombus shape means a parallelogram whose diagonal lines are substantially orthogonal.
- other polygonal shapes may be used.
- the shape of one side may be a curved shape or a circular arc shape in addition to a linear shape.
- an arc shape for example, two opposing sides may be outwardly convex arc shapes, and the other two opposing sides may be inwardly convex arc shapes.
- the shape of each side may be a wavy shape in which an outwardly convex arc and an inwardly convex arc are continuous.
- the shape of each side may be a sine curve.
- Each second conductive pattern 18B includes wide portions and narrow portions that are alternately arranged along the second direction (y direction).
- each second non-conductive pattern 20B includes wide portions and narrow portions that are alternately arranged along the second direction (y direction).
- the order of the wide portion and the narrow portion of the second conductive pattern 18B is opposite to the order of the wide portion and the narrow portion of the second non-conductive pattern 20B.
- each second conductive pattern 18B is electrically connected to the second external wiring 62B through the second electrode terminal 60B.
- the other end of each second conductive pattern 18B is an open end.
- the first electrode pattern 16A and the second electrode pattern 16B overlap as shown in FIG. Not arranged.
- the narrow portion of the first conductive pattern 18A and the narrow portion of the second conductive pattern 18B face each other, and the narrow portion of the first conductive pattern 18A and the second conductive pattern 18B intersect.
- the first electrode pattern 16A and the second electrode pattern 16B are disposed.
- the combination pattern 70 is formed by the first electrode pattern 16A and the second electrode pattern 16B. Note that the line widths of the first electrode pattern 16A and the second electrode pattern 16B are substantially the same.
- the sizes of the lattice 24A and the lattice 24B are substantially the same.
- the line width of the first electrode pattern 16A is displayed wider than the line width of the second electrode pattern 16B. is doing.
- a small lattice is formed by the lattice 24A and the lattice 24B in a top view. That is, the intersection of the grating 24A is arranged in the opening area of the grating 24B.
- the small lattice has a lattice pitch Ps of 150 ⁇ m or more and 400 ⁇ m or less, preferably 200 ⁇ m or more and 300 ⁇ m or less, which is half of the lattice pitches Pa and Pb of the lattice 24A and the lattice 24B.
- the disconnected portion 22A of the first non-conductive pattern 20A is formed at a portion other than the intersection of the lattice 24A
- the disconnected portion 22B of the second non-conductive pattern 20B is formed at a portion other than the intersection of the lattice 24B.
- the fine metal wires of the second conductive pattern 18B are arranged at positions facing the disconnection portion 22A.
- a fine metal wire of the first conductive pattern 18A is disposed at a position facing the disconnection portion 22B.
- the fine metal wire of the second conductive pattern 18B masks the disconnection portion 22A, and the fine metal wire of the first conductive pattern 18A masks the disconnection portion 22B. Therefore, in the combination pattern 70, the disconnection portion 22A and the disconnection portion 22B are hardly visually recognized in a top view, and thus visibility can be improved.
- the length of the disconnected portion 22A and the line width of the thin metal wire of the second conductive pattern 18B satisfy the relational expression of line width ⁇ 1 ⁇ disconnected portion ⁇ line width ⁇ 10.
- the length of the disconnection portion 22B and the line width of the thin metal wire of the first conductive pattern 18A satisfy the relational expression of line width ⁇ 1 ⁇ disconnection portion ⁇ line width ⁇ 10.
- the first external wiring 62A derived from a large number of first conductive patterns 18A of the first conductive sheet 12A and the second external wiring 62B derived from a large number of second conductive patterns 18B of the second conductive sheet 12B include, for example, It is connected to an IC circuit that controls scanning.
- each connection portion between the first conductive pattern 18A and the first external wiring 62A is preferably linear so that the area of the outer peripheral region that is removed from the display screen of the liquid crystal display device is minimized.
- the connecting portions between the second conductive pattern 18B and the second external wiring 62B are arranged in a straight line.
- the capacitance between the first conductive pattern 18A and the second conductive pattern 18B facing the fingertip changes.
- the IC circuit detects the amount of change and calculates the position of the fingertip based on the amount of change. This calculation is performed between the first conductive pattern 18A and the second conductive pattern 18B. Therefore, it is possible to detect the position of each fingertip even if two or more fingertips are brought into contact with each other at the same time.
- the response speed can be increased because the surface resistance is small.
- the touch panel can be increased in size.
- the electrode terminals 60A and 60B are thick terminals (solid terminals) because they have high conductivity.
- the sensing region electrode pattern
- the electrode terminal blocks the light emitted from the display, a darkened portion appears in the vicinity of the electrode terminal in the sensing region, and the display at that portion may be difficult to see.
- the present invention has been made to be conductive sheets for the first to third touch panels described below.
- the conductive sheet for the first touch panel according to the present invention includes an electrode pattern 16A (16B) made of fine metal wires, and an electrode terminal 60A (60B) electrically connected to the end of the electrode pattern 16A (16B).
- the transmittance of the electrode pattern 16A (16B) is 83% or more, and the transmittance of the electrode pattern 16A (16B) is expressed as a%.
- the transmittance of the electrode terminal 60A (60B) was set to be (a-20)% or more and (a-3)% or less. More preferably, it is (a-15)% or more and (a-3)% or less, more preferably (a-10) or more and (a-3) or less, and most preferably (a-5). ) To (a-3).
- the electrode pattern 16A (16B) made of fine metal wires and the end of the electrode pattern 16A (16B) were electrically connected.
- the aperture ratio of the electrode pattern 16A (16B) is 90% or more, and the aperture ratio of the electrode pattern 16A (16B). Is expressed as b%, the aperture ratio of the electrode terminal 60A (60B) is set to be (b-20)% or more and (b-0.1)% or less. More preferably, it is not less than (b-10) and not more than (b-0.3), and more preferably not less than (b-5) and not more than (b-0.3).
- FIG. 1 shows a case where the electrode terminal 60A (60B) has a frame shape 64 made of fine metal wires.
- the line width of the thin line of the electrode pattern 16A (16B) is A ( ⁇ m)
- the frame-shaped line width B ( ⁇ m) of the electrode terminal 60A (60B) is B ⁇ 2A or B ⁇ A + 5. ( ⁇ m) is preferably satisfied.
- the line width a ( ⁇ m) of the thin line of the electrode pattern is preferably 30 ⁇ m or less.
- the electrode terminal 60A (60B) has a frame shape 64 made of fine metal wires, whereby the transmittance of the electrode pattern 16A (16B) is 83% or more, and the electrode pattern 16A (16B) When the transmittance is expressed as a%, the transmittance of the electrode terminal 60A (60B) can be set to be (a-20)% or more and (a-3)% or less.
- the aperture ratio of the electrode pattern 16A (16B) is 90% or more, and the aperture ratio of the electrode pattern 16A (16B) is b %,
- the aperture ratio of the electrode terminal 60A (60B) can be (b-20)% or more and (b-0.1)% or less.
- the electrode terminal 60A (60B) into a frame shape 64 composed of fine metal wires, unlike the conventional thick terminal (solid terminal), the electrode terminal emits light emitted from the display in the sensing area (electrode pattern) of the touch panel. Since it is difficult to shield the light, a darkened portion does not appear near the electrode terminal in the sensing region. Therefore, the visibility is not impaired near the electrode terminals in the sensing region.
- FIG. 2 shows that the electrode terminal 60A (60B) has a mesh shape 66 composed of a lattice 68 made of fine metal wires.
- the pitch of the mesh shape 66 of the electrode terminal 60A (60B) is preferably denser than the pitch of the electrode pattern 16A (16B), more preferably 3/4 or less of the pitch of the electrode pattern 16A (16B). 2/3 or less is more preferable, and 1/2 is more preferable.
- the pitch of the mesh shape 66 of the specific electrode terminal 60A (60B) is 50 ⁇ m or more and 300 ⁇ m or less, and more preferably 50 ⁇ m or more and 250 ⁇ m or less. Note that the pitch of the electrode patterns 16A (16B) is substantially equal to the length of one side of the lattice 24A (24B).
- the electrode terminal 60A (60B) is made into a mesh shape 66 composed of a lattice 68 in which the electrode terminal 60A (60B) is made of a thin metal wire, so that the transmittance of the electrode pattern 16A (16B) is 83%.
- the transmittance of the electrode pattern 16A (16B) is expressed as a%
- the transmittance of the electrode terminal 60A (60B) is set to be (a-20)% or more and (a-3)% or less. be able to.
- the aperture ratio of the electrode pattern 16A (16B) is 90% or more,
- the aperture ratio of the electrode terminal 60A (60B) is set to be (b-20)% or more and (b-0.1)% or less. it can.
- the electrode terminal 60A (60B) into a mesh shape 66 composed of thin metal wires, unlike the conventional thick terminal (solid terminal), the electrode terminal emits light emitted from the display in the sensing area (electrode pattern) of the touch panel. Since it is difficult to shield the light, a darkened portion does not appear near the electrode terminal in the sensing region. Therefore, the visibility is not impaired near the electrode terminals in the sensing region.
- FIG. 3 shows that the electrode terminal 60A (60B) is composed of a frame shape 64 made up of fine metal wires and a mesh shape 66 made up of a lattice 68 made up of fine metal wires.
- the electrode terminal 60A (60B) is composed of a frame shape 64 made up of fine metal wires and a mesh shape 66 made up of a grid 68 made up of fine metal wires, so that the electrode pattern 16A (16B).
- the transmittance of the electrode pattern 16A (16B) is expressed as a%
- the transmittance of the electrode terminal 60A (60B) is (a-20)% or more (a-3)%. It can be as follows.
- the electrode terminal 60A (60B) is composed of a frame shape 64 made of fine metal wires and a mesh shape 66 made of a lattice 68 made of fine metal wires, so that the aperture ratio of the electrode pattern 16A (16B) is increased.
- the aperture ratio of the electrode pattern 16A (16B) is expressed as b%
- the aperture ratio of the electrode terminal 60A (60B) is (b-20)% or more and (b-0.1)% or less. Can be.
- the electrode terminal 60A (60B) is composed of a frame shape 64 made of fine metal wires and a mesh shape 66 made of a lattice 68 made of fine metal wires, which is different from a conventional thick terminal (solid terminal).
- the electrode terminals are less likely to block the light emitted from the display, so that a darkened portion does not appear near the electrode terminals in the sensing area. Therefore, the visibility is not impaired near the electrode terminals in the sensing region.
- the lattice 68 has a substantially rhombus shape.
- the substantially rhombus shape means a parallelogram whose diagonal lines are substantially orthogonal.
- other polygonal shapes may be used.
- the shape of one side may be a curved shape or a circular arc shape in addition to a linear shape.
- two opposing sides may be outwardly convex arc shapes, and the other two opposing sides may be inwardly convex arc shapes.
- the shape of each side may be a wavy shape in which an outwardly convex arc and an inwardly convex arc are continuous.
- the shape of each side may be a sine curve.
- the resistance between the part electrically connected to the electrode pattern and the external wiring 62A (62B) is preferably in the range of 1 to 100 ⁇ . 2 and 3, when the electrode terminal 60A (60B) includes the mesh shape 66, the surface resistance value of the electrode terminal 60A (60B) is in the range of 4 ⁇ / sq. To 80 ⁇ / sq. Preferably, it is in the range of 10 ⁇ / sq. To 40 ⁇ / sq.
- the aperture ratio is the ratio of the translucent portion of the electrode terminal 60A (60B) excluding the thin metal wires to the whole.
- the aperture ratio of the square lattice 68 having a line width of 15 ⁇ m and a pitch of 300 ⁇ m is 90%. It is.
- the conductive sheet for the second touch panel according to the present invention includes an electrode pattern 16A (16B) made of a fine metal wire, and an electrode terminal 60A (60B) electrically connected to the end of the electrode pattern 16A (16B).
- the electrode terminal 60A (60B) includes a frame shape 64 made of a thin metal wire.
- FIG. 1 shows a case where the electrode terminal 60A (60B) has a frame shape 64 made of fine metal wires.
- the frame-shaped line width B ( ⁇ m) of the electrode terminal 60A (60B) is B ⁇ 2A or B ⁇ A + 5. ( ⁇ m) is preferably satisfied. More preferably, the range is 50 ⁇ m ⁇ B ⁇ 10 ⁇ m, and still more preferably the range is 30 ⁇ m ⁇ B ⁇ 15 ⁇ m.
- the frame shape 64 has a substantially rectangular shape, and its horizontal width is substantially the same as the maximum horizontal width of the electrode pattern, but may be smaller than the maximum horizontal width of the electrode pattern. In addition, since electrical resistance will become large if it is too smaller than the maximum width of an electrode pattern, the width is preferably 1/3 or more of the maximum width of an electrode pattern, and more preferably 1/2 or more.
- the electrode terminal 60A 60B
- the electrode terminal 60A 60B
- the electrode terminal 60A 60B
- the electrode terminal 60A 60B
- the electrode terminal 60A 60B
- the frame shape 64 made of fine metal wires, so that a display is emitted in the sensing area (electrode pattern) of the touch panel, unlike the conventional thick terminal (solid terminal). Since it becomes difficult for the electrode terminal to block light, a darkened portion does not appear near the electrode terminal in the sensing region. Therefore, the visibility is not impaired near the electrode terminals in the sensing region.
- FIG. 3 shows that the electrode terminal 60A (60B) is composed of a frame shape 64 made up of fine metal wires and a mesh shape 66 made up of a lattice 68 made up of fine metal wires.
- the pitch of the mesh shape 66 of the electrode terminal 60A (60B) is preferably denser than the pitch of the electrode pattern 16A (16B), more preferably 3/4 or less of the pitch of the electrode pattern 16A (16B). 2/3 or less is more preferable, and 1/2 is more preferable.
- the pitch of the mesh shape 66 of the specific electrode terminal 60A (60B) is 50 ⁇ m or more and 300 ⁇ m or less, and more preferably 50 ⁇ m or more and 250 ⁇ m or less. Note that the pitch of the electrode patterns 16A (16B) is substantially equal to the length of one side of the lattice 24A (24B).
- the electrode terminal 60A (60B) is composed of a frame shape 64 made up of fine metal wires and a mesh shape 66 made up of a grid 68 made up of fine metal wires.
- the electrode terminal in the sensing area (electrode pattern) of the touch panel, the electrode terminal does not easily shield the light emitted from the display, so that a darkened portion does not appear in the vicinity of the electrode terminal in the sensing area. Therefore, the visibility is not impaired near the electrode terminals in the sensing region.
- the lattice 68 has a substantially rhombus shape.
- the substantially rhombus shape means a parallelogram whose diagonal lines are substantially orthogonal.
- other polygonal shapes may be used.
- the shape of one side may be a curved shape or a circular arc shape in addition to a linear shape.
- two opposing sides may be outwardly convex arc shapes, and the other two opposing sides may be inwardly convex arc shapes.
- the shape of each side may be a wavy shape in which an outwardly convex arc and an inwardly convex arc are continuous.
- the shape of each side may be a sine curve.
- the resistance between the part electrically connected to the electrode pattern and the external wiring 62A (62B) is preferably in the range of 1 to 100 ⁇ .
- the surface resistance value of the electrode terminal 60A (60B) may be in the range of 4 ⁇ / sq. Or more and 80 ⁇ / sq. Preferably, it is in the range of 10 ⁇ / sq. Or more and 40 ⁇ / sq. Or less.
- the aperture ratio is the ratio of the translucent portion of the electrode terminal 60A (60B) excluding the thin metal wires to the whole.
- the aperture ratio of the square lattice 68 having a line width of 15 ⁇ m and a pitch of 300 ⁇ m is 90%. It is.
- the electrode terminal 60A (60B) when the transmittance of the electrode pattern 16A (16B) is 83% or more and the transmittance of the electrode pattern 16A (16B) is expressed as a%, the electrode terminal 60A (60B)
- the transmittance is preferably (a-20)% or more and (a-3)% or less.
- the electrode terminal 60A (60B) ) Is preferably (b-20)% or more and (b-0.1)% or less.
- the aperture ratio is the ratio of the translucent portion of the electrode terminal 60A (60B) excluding the thin metal wires to the whole.
- the aperture ratio of the square lattice 68 having a line width of 15 ⁇ m and a pitch of 300 ⁇ m is 90%.
- the conductive sheet for the third touch panel includes an electrode pattern 16A (16B) made of fine metal wires, and an electrode terminal 60A (60B) electrically connected to the end of the electrode pattern 16A (16B).
- the electrode terminal 60A (60B) includes a mesh shape 66 composed of a lattice 68 made of fine metal wires.
- FIG. 2 shows that the electrode terminal 60A (60B) has a mesh shape 66 composed of a lattice 68 made of fine metal wires.
- the pitch of the mesh shape 66 of the electrode terminal 60A (60B) is preferably denser than the pitch of the electrode pattern 16A (16B), more preferably 3/4 or less of the pitch of the electrode pattern 16A (16B). 2/3 or less is more preferable, and 1/2 is more preferable.
- the pitch of the mesh shape 66 of the specific electrode terminal 60A (60B) is 50 ⁇ m or more and 300 ⁇ m or less, and more preferably 50 ⁇ m or more and 250 ⁇ m or less. Note that the pitch of the electrode patterns 16A (16B) is substantially equal to the length of one side of the lattice 24A (24B).
- the electrode terminal 60A (60B) is changed to a mesh shape 66 composed of a lattice 68 in which the electrode terminal 60A (60B) is made of a thin metal wire, so that a touch panel is different from a conventional thick terminal (solid terminal).
- a touch panel is different from a conventional thick terminal (solid terminal).
- the sensing region electrode pattern
- a darkened portion does not appear near the electrode terminal in the sensing region. Therefore, the visibility is not impaired near the electrode terminals in the sensing region.
- FIG. 3 shows that the electrode terminal 60A (60B) of FIG. 2 has a mesh shape 66 made of a grid 68 made of fine metal wires, and an outer frame of the mesh shape 66 made of a grid 68 of electrode terminals, A frame shape 64 composed of thin lines is provided. That is, the electrode terminal 60A (60B) is shown to have a frame shape 64 made of fine metal wires and a mesh shape 66 made of a lattice 68 made of fine metal wires.
- the line width of the thin line of the electrode pattern 16A (16B) is A ( ⁇ m)
- the line width B ( ⁇ m) of the frame shape 64 of the electrode terminal 60A (60B) is B ⁇ 2A or B ⁇ It is preferable to satisfy A + 5 ( ⁇ m).
- the electrode terminal 60A (60B) is composed of a frame shape 64 made up of fine metal wires and a mesh shape 66 made up of a grid 68 made up of fine metal wires.
- the sensing region electrode pattern
- the lattice 68 has a substantially rhombus shape.
- the substantially rhombus shape means a parallelogram whose diagonal lines are substantially orthogonal.
- the resistance between the part electrically connected to the electrode pattern and the external wiring 62A (62B) is preferably in the range of 1 to 100 ⁇ .
- the surface resistance value of the electrode terminal 60A (60B) is preferably in the range of 4 ⁇ / sq. To 80 ⁇ / sq. More preferably, it is in the range of 40 ⁇ / sq.
- the transmittance of the electrode pattern 16A (16B) when the transmittance of the electrode pattern 16A (16B) is 83% or more and the transmittance of the electrode pattern 16A (16B) is expressed as a%, the transmittance of the electrode terminal 60A (60B) is ( It is preferable that the content is a-20)% or more and (a-3)% or less.
- the aperture ratio of the electrode terminal 60A (60B) is It is preferably (b-20)% or more and (b-0.1)% or less.
- the aperture ratio is the ratio of the translucent portion of the electrode terminal 60A (60B) excluding the thin metal wires to the whole.
- the aperture ratio of the square lattice 68 having a line width of 15 ⁇ m and a pitch of 300 ⁇ m is 90%.
- the present invention it is possible to prevent a darkened portion from appearing in the vicinity of the electrode terminal in the sensing region.
- the conductive sheet 12A (12B) is manufactured by a method by exposure described below. In this case, there is an effect that it is possible to prevent the metal thin wire near the electrode terminal in the sensing region from becoming thicker than the intended line width.
- the conventional electrode terminal is a thick terminal (solid terminal) in order to have high conductivity, a large amount of light is irradiated to the part that becomes the electrode terminal by exposure.
- the line width of the electrode pattern is very small and is transmitted to the portion that becomes the electrode pattern in the vicinity of the electrode terminal, and the fine metal wire in the vicinity of the electrode terminal becomes thicker than the intended line width.
- the transmittance or aperture ratio of the electrode terminal 60A (60B) as in the present invention, a portion that becomes the electrode terminal by exposure is not irradiated with a large amount of light, and in the vicinity of the electrode terminal in the sensing region. It is possible to prevent the metal fine wire from becoming thicker than the intended line width.
- the touch panel using the conductive sheet according to the present invention When the touch panel using the conductive sheet according to the present invention is operated by touching with a finger, the response speed is fast and the detection sensitivity is excellent. In addition, even if two or more points are touched and operated, good results can be obtained in the same manner, and multi-touch can be handled.
- the first conductive sheet 12A and the second conductive sheet 12B When manufacturing the first conductive sheet 12A and the second conductive sheet 12B, for example, a photosensitive material having an emulsion layer containing a photosensitive silver halide salt on the first transparent substrate 14A and the second transparent substrate 14B is exposed.
- the first electrode pattern 16A and the second electrode pattern 16B are formed by forming a metal silver portion (metal fine line) and a light transmissive portion (opening region) in the exposed portion and the unexposed portion, respectively. You may do it. In addition, you may make it carry
- the photoresist film on the copper foil formed on the first transparent substrate 14A and the second transparent substrate 14B is exposed and developed to form a resist pattern, and the copper foil exposed from the resist pattern is etched.
- the first electrode pattern 16A and the second electrode pattern 16B may be formed.
- the first electrode pattern 16A and the second electrode pattern 16B are formed by printing a paste containing metal fine particles on the first transparent substrate 14A and the second transparent substrate 14B and performing metal plating on the paste. Also good.
- the present invention prevents the metal thin wire near the electrode terminal in the sensing region from becoming thicker than the intended line width. There is also an effect that it is possible.
- the first electrode pattern 16A and the second electrode pattern 16B may be printed and formed on the first transparent substrate 14A and the second transparent substrate 14B by a screen printing plate or a gravure printing plate. Alternatively, the first electrode pattern 16A and the second electrode pattern 16B may be formed by inkjet on the first transparent substrate 14A and the second transparent substrate 14B.
- the first electrode pattern 16A is formed on one main surface of the first transparent substrate 14A and the second electrode pattern 16B is formed on the other main surface of the first transparent substrate 14A
- a normal manufacturing method is used. Accordingly, if a method of exposing one principal surface first and then exposing the other principal surface is employed, the first electrode pattern 16A and the second electrode pattern 16B having a desired pattern may not be obtained. .
- the following production method can be preferably employed.
- the photosensitive silver halide emulsion layer formed on both surfaces of the first transparent substrate 14A is collectively exposed to form the first electrode pattern 16A on one main surface of the first transparent substrate 14A.
- a second electrode pattern 16B is formed on the other main surface of the transparent substrate 14A.
- the photosensitive material includes a first transparent substrate 14A, a photosensitive silver halide emulsion layer (hereinafter referred to as a first photosensitive layer) formed on one main surface of the first transparent substrate 14A, and the other of the first transparent substrate 14A.
- a light-sensitive silver halide emulsion layer (hereinafter referred to as a second photosensitive layer) formed on the main surface.
- the photosensitive material is exposed.
- the first photosensitive layer is irradiated with light toward the first transparent substrate 14A to expose the first photosensitive layer along the first exposure pattern
- the second photosensitive layer is exposed.
- a second exposure process is performed in which light is irradiated toward the first transparent substrate 14A to expose the second photosensitive layer along the second exposure pattern (double-sided simultaneous exposure).
- the first photosensitive layer is irradiated with the first light (parallel light) through the first photomask
- the second photosensitive layer is irradiated with the second light (parallel light).
- the first light is obtained by converting the light emitted from the first light source into parallel light by the first collimator lens in the middle
- the second light is obtained by converting the light emitted from the second light source in the middle of the first light. It is obtained by being converted into parallel light by a two-collimator lens.
- the case where two light sources (the first light source and the second light source) are used is shown, but the light emitted from one light source is divided through the optical system, and the first light and the second light are divided.
- the first photosensitive layer and the second photosensitive layer may be irradiated as light.
- the exposed photosensitive material is developed to produce a touch panel conductive sheet 10 as shown in FIG. 4B, for example.
- the touch panel conductive sheet 10 includes a first transparent substrate 14A, a first electrode pattern 16A along a first exposure pattern formed on one main surface of the first transparent substrate 14A, and the other of the first transparent substrate 14A. And a second electrode pattern 16B along the second exposure pattern formed on the main surface.
- the preferable numerical range should be determined unconditionally. However, the exposure time and the development time are adjusted so that the development rate becomes 100%.
- the first exposure process includes, for example, arranging a first photomask on the first photosensitive layer in close contact with the first light source arranged opposite to the first photomask.
- the first photosensitive layer is exposed by irradiating the first light toward one photomask.
- the first photomask is composed of a glass substrate formed of transparent soda glass and a mask pattern (first exposure pattern) formed on the glass substrate. Accordingly, the first exposure process exposes a portion of the first photosensitive layer along the first exposure pattern formed on the first photomask.
- a gap of about 2 ⁇ m or more and 10 ⁇ m or less may be provided between the first photosensitive layer and the first photomask 146a.
- a second photomask is disposed in close contact with the second photosensitive layer, and the second light source disposed opposite to the second photomask is secondly directed toward the second photomask.
- the second photosensitive layer is exposed by irradiating light.
- the second photomask is composed of a glass substrate made of transparent soda glass and a mask pattern (second exposure pattern) formed on the glass substrate. Therefore, the second exposure process exposes a portion of the second photosensitive layer along the second exposure pattern formed on the second photomask. In this case, a gap of about 2 ⁇ m or more and 10 ⁇ m or less may be provided between the second photosensitive layer and the second photomask.
- the emission timing of the first light from the first light source and the emission timing of the second light from the second light source may be made simultaneously or different from each other.
- the first photosensitive layer and the second photosensitive layer can be exposed simultaneously by one exposure process, and the processing time can be shortened.
- the manufacturing method of the first conductive sheet 12A and the second conductive sheet 12B according to the present embodiment includes the following three modes depending on the type of photosensitive material and the development process.
- a photosensitive silver halide black-and-white photosensitive material that does not contain physical development nuclei and an image-receiving sheet having a non-photosensitive layer that contains physical development nuclei are overlapped and transferred to develop a non-photosensitive image-receiving sheet. Form formed on top.
- the above aspect (1) is an integrated black-and-white development type, and a light-transmitting conductive film such as a light-transmitting conductive film is formed on the photosensitive material.
- the resulting developed silver is chemically developed silver or heat developed silver, and is highly active in the subsequent plating or physical development process in that it is a filament with a high specific surface.
- the light-transmitting conductive film such as a light-transmitting conductive film is formed on the photosensitive material by dissolving silver halide grains close to the physical development nucleus and depositing on the development nucleus in the exposed portion.
- a characteristic film is formed.
- This is also an integrated black-and-white development type. Although the development action is precipitation on the physical development nuclei, it is highly active, but developed silver is a sphere with a small specific surface.
- the silver halide grains are dissolved and diffused in the unexposed area and deposited on the development nuclei on the image receiving sheet, whereby a light transmitting conductive film or the like is formed on the image receiving sheet.
- a conductive film is formed. This is a so-called separate type in which the image receiving sheet is peeled off from the photosensitive material.
- either negative development processing or reversal development processing can be selected (in the case of the diffusion transfer method, negative development processing is possible by using an auto-positive type photosensitive material as the photosensitive material).
- first transparent substrate 14A and the second transparent substrate 14B examples include a plastic film, a plastic plate, and a glass plate.
- PET is preferable from the viewpoints of light transmittance and processability.
- the silver salt emulsion layer that becomes the first electrode pattern 16A of the first conductive sheet 12A and the second electrode pattern 16B of the second conductive sheet 12B contains additives such as a solvent and a dye in addition to the silver salt and the binder.
- Examples of the silver salt used in the present embodiment include inorganic silver salts such as silver halide and organic silver salts such as silver acetate. In the present embodiment, it is preferable to use silver halide having excellent characteristics as an optical sensor.
- Silver coating amount of silver salt emulsion layer is preferably from 1 g / m 2 or more 30 g / m 2 or less in terms of silver, 1 g / m, more preferably 2 or more 25 g / m 2 or less, 5g / M 2 or more and 20 g / m 2 or less is more preferable.
- amount of coated silver in the above range, a desired surface resistance can be obtained when the conductive sheet 10 for a touch panel is used.
- binder used in this embodiment examples include gelatin, polyvinyl alcohol (PVA), polyvinyl pyrrolidone (PVP), starch and other polysaccharides, cellulose and derivatives thereof, polyethylene oxide, polyvinyl amine, chitosan, polylysine, and polyacryl.
- PVA polyvinyl alcohol
- PVP polyvinyl pyrrolidone
- starch and other polysaccharides, cellulose and derivatives thereof, polyethylene oxide, polyvinyl amine, chitosan, polylysine, and polyacryl.
- acid polyalginic acid, polyhyaluronic acid, carboxycellulose and the like. These have neutral, anionic, and cationic properties depending on the ionicity of the functional group.
- the content of the binder contained in the silver salt emulsion layer of the present embodiment is not particularly limited and can be appropriately determined as long as dispersibility and adhesion can be exhibited.
- the binder content in the silver salt emulsion layer is preferably 1 ⁇ 4 or more, more preferably 1 ⁇ 2 or more in terms of the silver / binder volume ratio.
- the silver / binder volume ratio is preferably 100/1 or less, and more preferably 50/1 or less. Further, the silver / binder volume ratio is more preferably 1/1 or more and 4/1 or less. Most preferably, it is 1/1 to 3/1.
- the silver / binder volume ratio is converted from the amount of silver halide / binder amount (weight ratio) of the raw material to the amount of silver / binder amount (weight ratio), and the amount of silver / binder amount (weight ratio) is further converted to the amount of silver. / It can obtain
- the solvent used for forming the silver salt emulsion layer is not particularly limited.
- water organic solvents (for example, alcohols such as methanol, ketones such as acetone, amides such as formamide, dimethyl sulfoxide, etc. Sulphoxides such as, esters such as ethyl acetate, ethers, etc.), ionic liquids, and mixed solvents thereof.
- the content of the solvent used in the silver salt emulsion layer of the present embodiment is in the range of 30 to 90% by mass with respect to the total mass of silver salt and binder contained in the silver salt emulsion layer, and 50 to 80%. It is preferably in the range of mass%.
- the various additives used in the present embodiment are not particularly limited, and known ones can be preferably used.
- a protective layer (not shown) may be provided on the silver salt emulsion layer.
- the “protective layer” means a layer made of a binder such as gelatin or a high molecular polymer, and is provided on a silver salt emulsion layer having photosensitivity in order to exhibit the effect of preventing scratches and improving mechanical properties. It is formed.
- the thickness is preferably 0.5 ⁇ m or less.
- the coating method and forming method of the protective layer are not particularly limited, and a known coating method and forming method can be appropriately selected.
- An undercoat layer for example, can be provided below the silver salt emulsion layer.
- This embodiment includes the case where the first electrode pattern 16A and the second electrode pattern 16B are applied by a printing method, but the first electrode pattern 16A and the second electrode pattern 16B are formed by exposure and development, etc., except for the printing method.
- exposure is performed on a photosensitive material having a silver salt-containing layer provided on the first transparent substrate 14A and the second transparent substrate 14B or a photosensitive material coated with a photolithography photopolymer.
- the exposure can be performed using electromagnetic waves. Examples of the electromagnetic wave include light such as visible light and ultraviolet light, and radiation such as X-rays.
- a light source having a wavelength distribution may be used for exposure, or a light source having a specific wavelength may be used.
- a method through a glass mask or a pattern exposure method by laser drawing is preferable.
- development processing is further performed.
- the development processing can be performed by a normal development processing technique used for silver salt photographic film, photographic paper, printing plate-making film, photomask emulsion mask, and the like.
- the development process in the present embodiment can include a fixing process performed for the purpose of removing and stabilizing the silver salt in the unexposed part.
- a fixing process technique used for silver salt photographic film, photographic paper, film for printing plate making, emulsion mask for photomask, and the like can be used.
- the light-sensitive material that has been subjected to development and fixing processing is preferably subjected to a film hardening process, a water washing process, and a stabilization process.
- the mass of the metallic silver contained in the exposed portion after the development treatment is preferably a content of 50% by mass or more, and 80% by mass or more with respect to the mass of silver contained in the exposed portion before exposure. More preferably. If the mass of silver contained in the exposed portion is 50% by mass or more based on the mass of silver contained in the exposed portion before exposure, it is preferable because high conductivity can be obtained.
- the conductive sheet is obtained through the above steps, but the surface resistance of the obtained conductive sheet is 100 ohm / sq.
- the following is preferable, and 80 ohm / sq.
- the following is more preferable, and 60 ohm / sq.
- the following is more preferable, and 40 ohm / sq.
- the lower limit of the surface resistance is preferably as low as possible, but is generally 0.01 ohm / sq. Is sufficient, 0.1 ohm / sq. And 1 ohm / sq. However, it can be used depending on the application.
- the position can be detected even with a large touch panel having an area of 10 cm ⁇ 10 cm or more.
- the conductive sheet after the development process may be further subjected to a conductivity improving process such as a calendar process or a steam process, and the desired surface resistance can be adjusted by the calendar process.
- the conductive metal particles may be supported on the metallic silver portion by only one of physical development and plating treatment, or the conductive metal particles are supported on the metallic silver portion by combining physical development and plating treatment. May be.
- the thing which performed the physical development and / or the plating process to the metal silver part is called "conductive metal part".
- Oxidation treatment it is preferable to subject the metallic silver portion after the development treatment and the conductive metal portion formed by physical development and / or plating treatment to oxidation treatment.
- oxidation treatment for example, when a metal is slightly deposited on the light transmissive portion, the metal can be removed and the light transmissive portion can be made almost 100% transparent.
- the line width of the fine metal wires of the first electrode pattern 16A and the second electrode pattern 16B of the present embodiment can be selected from 30 ⁇ m or less.
- the lower limit of the thin metal wire width The value is preferably 0.7 ⁇ m, more preferably 1 ⁇ m, still more preferably 2 ⁇ m.
- the upper limit of the line width of the fine metal wire is preferably 15 ⁇ m, more preferably 9 ⁇ m, and even more preferably 7 ⁇ m.
- a conventional electrode terminal is a thick terminal (solid terminal) in order to have high conductivity, and a large amount of light is irradiated to a portion that becomes an electrode terminal by exposure.
- the line width of the electrode pattern is very small as described above, and may be affected by the large amount of light. In particular, when the line width is 9 ⁇ m or less, further 7 ⁇ m or less, the influence becomes remarkable, and there is a problem that the metal thin wire near the electrode terminal becomes thicker than the intended line width.
- the line spacing is preferably 100 ⁇ m or more and 400 ⁇ m or less, more preferably 200 ⁇ m or more and 300 ⁇ m or less. Further, the thin metal wire may have a portion wider than 200 ⁇ m for the purpose of ground connection or the like.
- the “light transmissive part” in the present embodiment means a part having translucency other than the first electrode pattern 16A and the second electrode pattern 16B in the first conductive sheet 12A and the second conductive sheet 12B.
- the transmittance in the light transmissive portion is the transmission indicated by the minimum value of the transmittance in the wavelength region of 380 to 780 nm excluding the contribution of light absorption and reflection of the first transparent substrate 14A and the second transparent substrate 14B.
- the rate is 83% or more, preferably 85% or more, more preferably 90% or more, still more preferably 93% or more, and most preferably 99% or more.
- the thickness of the first transparent substrate 14A and the second transparent substrate 14B in the first conductive sheet 12A and the second conductive sheet 12B according to the present embodiment is preferably 5 ⁇ m or more and 350 ⁇ m or less, and is 30 ⁇ m or more and 150 ⁇ m or less. More preferably. If it is in the range of 5 ⁇ m or more and 350 ⁇ m or less, a desired visible light transmittance can be obtained and handling is easy.
- the thickness of the metallic silver portion provided on the first transparent substrate 14A and the second transparent substrate 14B depends on the coating thickness of the silver salt-containing layer coating applied on the first transparent substrate 14A and the second transparent substrate 14B. Can be determined as appropriate.
- the thickness of the metallic silver part can be selected from 0.001 mm or more and 0.2 mm or less, preferably 30 ⁇ m or less, more preferably 20 ⁇ m or less, and 0.01 ⁇ m or more and 9 ⁇ m or less. More preferably, it is 0.05 ⁇ m or more and 5 ⁇ m or less.
- a metal silver part is pattern shape.
- the metallic silver part may be a single layer or a multilayer structure of two or more layers.
- the metallic silver portion When the metallic silver portion is patterned and has a multilayer structure of two or more layers, different color sensitivities can be imparted so as to be sensitive to different wavelengths. Thereby, when the exposure wavelength is changed and exposed, a different pattern can be formed in each layer.
- the thickness of the conductive metal part is preferably as the thickness of the touch panel is thinner because the viewing angle of the display panel is wider, and a thin film is also required for improving the visibility.
- the thickness of the layer made of the conductive metal carried on the conductive metal part is preferably less than 9 ⁇ m, more preferably 0.1 ⁇ m or more and less than 5 ⁇ m, and more preferably 0.1 ⁇ m or more. More preferably, it is less than 3 ⁇ m.
- the thickness of the layer made of conductive metal particles is formed by controlling the coating thickness of the silver salt-containing layer described above to form a metallic silver portion having a desired thickness, and further by physical development and / or plating treatment. Therefore, even the first conductive sheet 12A and the second conductive sheet 12B having a thickness of less than 5 ⁇ m, preferably less than 3 ⁇ m can be easily formed.
- the conductive sheet and the touch panel according to the present invention are not limited to the above-described embodiments, but can of course have various configurations without departing from the gist of the present invention. Further, it can be used in appropriate combination with the techniques disclosed in JP 2011-113149, JP 2011-129501, JP 2011-129112, JP 2011-134311, JP 2011-175628, and the like.
- the transmittance or aperture ratio was measured to evaluate the visibility.
- K 3 Rh 2 Br 9 and K 2 IrCl 6 were added so as to have a concentration of 10 ⁇ 7 (mol / mol silver), and silver bromide grains were doped with Rh ions and Ir ions. .
- the coating amount of silver was 10 g / m 2.
- the coating was applied on the first transparent substrate 12A and the second transparent substrate 12B (both here are polyethylene terephthalate (PET)). At this time, the volume ratio of Ag / gelatin was 2/1.
- a 30 cm wide PET support was applied for 20 m in a width of 25 cm, and both ends were cut off by 3 cm so as to leave a central portion of the coating, and a roll-shaped silver halide photosensitive material was obtained.
- the pattern of exposure is the pattern shown in FIGS. 1 and 3 for the first conductive sheet 12A, the pattern shown in FIGS. 4A, 4B, and 6B for the second conductive sheet 12B, and is A4 size (210 mm ⁇ 297 mm). It went to the first transparent substrate 14A and the second transparent substrate 14B.
- the exposure was performed using parallel light using a high-pressure mercury lamp as a light source through the photomask having the above pattern.
- the electrode terminals 60A and the electrode terminals 60B of the first conductive sheet 12A and the second conductive sheet 12B were respectively prepared with all the patterns shown in FIGS.
- Example 1 (Sample 1-1)
- Example The transmittance of the conductive portions (the first electrode pattern 16A and the second electrode pattern 16B) of the manufactured first conductive sheet 12A and second conductive sheet 12B is 83%.
- the electrode terminal 60A and the electrode terminal 60B of the produced first conductive sheet 12A and second conductive sheet 12B have the pattern shown in FIG. 1, and the transmittance is 63%.
- Example 1-2 Example The same procedure as in Sample 1-1 was performed, except that the transmittance of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 80%.
- Example 1-3 Comparative Example Same as Sample 1-1, except that the transmittance of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 60%.
- Example 1-4 Comparative Example Samples were manufactured in the same manner as Sample 1-1 except that the transmittance of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 83%.
- Example 1-5 Example The transmittance of the conductive portions (the first electrode pattern 16A and the second electrode pattern 16B) of the produced first conductive sheet 12A and second conductive sheet 12B is 90%.
- the electrode terminal 60A and the electrode terminal 60B of the produced first conductive sheet 12A and second conductive sheet 12B have the pattern shown in FIG. 1, and the transmittance is 70%.
- Example A sample was manufactured in the same manner as Sample 1-5 except that the transmittance of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 87%.
- Example 1--7 Comparative Example Samples were manufactured in the same manner as Sample 1-5 except that the transmittances of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B were 67%.
- Example 1-8 Comparative Example Sample 1-8 was manufactured in the same manner as Sample 1-5 except that the transmittance of electrode terminal 60A and electrode terminal 60B of first conductive sheet 12A and second conductive sheet 12B was 90%.
- Example 1 Example The transmittance of the conductive portions (the first electrode pattern 16A and the second electrode pattern 16B) of the produced first conductive sheet 12A and second conductive sheet 12B is 83%.
- the electrode terminals 60A and the electrode terminals 60B of the produced first conductive sheet 12A and second conductive sheet 12B have the pattern shown in FIG. 2, and the transmittance is 63%.
- Example A sample was manufactured in the same manner as Sample 1-9 except that the transmittances of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B were 80%.
- Example 1-11 Comparative Example Samples were manufactured in the same manner as Sample 1-9 except that the transmittance of electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 60%.
- Example 1-12 Comparative Example Sample 1-12 was made the same as Sample 1-9 except that the transmittance of electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 83%.
- Example 1-13 Example The transmittance of the conductive portions (the first electrode pattern 16A and the second electrode pattern 16B) of the manufactured first conductive sheet 12A and second conductive sheet 12B is 83%.
- the electrode terminal 60A and the electrode terminal 60B of the manufactured first conductive sheet 12A and second conductive sheet 12B have the pattern of FIG. 3, and the transmittance is 63%.
- Example A sample was manufactured in the same manner as Sample 1-13 except that the transmittances of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B were 80%.
- Example 1-15 Comparative Example Samples were manufactured in the same manner as Sample 1-7, except that the transmittance of electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 60%.
- Example 1-16 Comparative Example Samples were manufactured in the same manner as Sample 1-13, except that the transmittances of electrode terminals 60A and 60B of manufactured first conductive sheet 12A and second conductive sheet 12B were 83%.
- the total light transmittance of the first conductive sheet 12A and the second conductive sheet 12B was measured using a photometer.
- the photometer was measured using TC-HIIIDPK manufactured by Tokyo Denshoku.
- a projected capacitive touch panel was produced using each of the laminated conductive sheets according to the samples described above.
- the touch panel was installed on a rotating disk and the liquid crystal display device was driven to display white, it was confirmed with the naked eye whether a shadow (a darkened portion) could be confirmed in the vicinity of the electrode terminal in the sensing area.
- reaction rate was evaluated as A, the reaction rate as good as B, the practicality as the response speed was not a problem as C, and the response speed as slow as the detection sensitivity was evaluated as D.
- Example 2 (Sample 2-1)
- the aperture ratio of the conductive portions (the first electrode pattern 16A and the second electrode pattern 16B) of the manufactured first conductive sheet 12A and second conductive sheet 12B is 90%.
- the electrode terminals 60A and electrode terminals 60B of the produced first conductive sheet 12A and second conductive sheet 12B have the pattern shown in FIGS. 5A and 5B, and the aperture ratio is 70%.
- Example 2-2 Example Same as Sample 2-1, except that the aperture ratio of the electrode terminal 60A and the electrode terminal 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 89.9%. did.
- Example 2-3 Comparative Example Samples were made in the same manner as Sample 2-1, except that the aperture ratios of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B were set to 68%.
- Example 2-4 Comparative Example Same as Sample 2-1, except that the transmittance of electrode terminal 60A and electrode terminal 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 90%.
- Example 2-5 Example The aperture ratio of the conductive portions (the first electrode pattern 16A and the second electrode pattern 16B) of the manufactured first conductive sheet 12A and second conductive sheet 12B is 97%.
- the electrode terminals 60A and electrode terminals 60B of the produced first conductive sheet 12A and second conductive sheet 12B have the pattern shown in FIGS. 5A and 5B, and the aperture ratio is 77%.
- Example 2-6 Example Same as Sample 2-5 except that the aperture ratio of the electrode terminal 60A and the electrode terminal 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 96.9%. did.
- Example 2--7 Comparative Example Samples were manufactured in the same manner as Sample 2-5, except that the aperture ratio of electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 75%.
- Example 2-8 Comparative Example Samples were manufactured in the same manner as Sample 2-5 except that the aperture ratios of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B were set to 97%.
- Example 2-9 Example The aperture ratio of the conductive portions (the first electrode pattern 16A and the second electrode pattern 16B) of the manufactured first conductive sheet 12A and second conductive sheet 12B is 90%.
- the electrode terminals 60A and electrode terminals 60B of the produced first conductive sheet 12A and second conductive sheet 12B have the pattern shown in FIGS. 6A and 6B, and the aperture ratio is 70%.
- Example 2-10 Example Same as Sample 2-9 except that the aperture ratio of the electrode terminal 60A and the electrode terminal 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 89.9%. did.
- Example 2-11 Comparative Example Samples were manufactured in the same manner as Sample 2-9 except that the aperture ratios of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B were 68%.
- Example 2-12 Comparative Example Samples were manufactured in the same manner as Sample 2-9, except that the transmittance of electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 90%.
- Example 2-13 Example The aperture ratio of the conductive portions (the first electrode pattern 16A and the second electrode pattern 16B) of the manufactured first conductive sheet 12A and second conductive sheet 12B is 90%.
- the electrode terminal 60A and the electrode terminal 60B of the produced first conductive sheet 12A and second conductive sheet 12B have the pattern of FIG. 7, and the aperture ratio is 70%.
- Example 2-14 Example Same as Sample 2-13, except that the aperture ratio of the electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 89.9%. did.
- Example 2-15) Comparative Example Samples were manufactured in the same manner as Sample 2-13 except that the aperture ratios of electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B were 68%.
- Example 2-16 Comparative Example Samples were manufactured in the same manner as Sample 2-13, except that the transmittance of electrode terminals 60A and 60B of the produced first conductive sheet 12A and second conductive sheet 12B was 90%.
- the first conductive sheet 12A and the second conductive sheet 12B were measured under the condition of 3000 times using a microscope VHX-200 manufactured by Keyence Corporation.
- a projected capacitive touch panel was produced using each of the laminated conductive sheets according to the samples described above.
- the touch panel was installed on a rotating disk and the liquid crystal display device was driven to display white, it was confirmed with the naked eye whether a shadow (a darkened portion) could be confirmed in the vicinity of the electrode terminal in the sensing area.
- reaction rate was evaluated as A, the reaction rate as good as B, the practicality as the response speed was not a problem as C, and the response speed as slow as the detection sensitivity was evaluated as D.
- the conductive sheet and the touch panel according to the present invention are not limited to the above-described embodiments, but can of course have various configurations without departing from the gist of the present invention.
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Abstract
Description
(第一のタッチパネル用の導電シート)
本発明に係る第一のタッチパネル用の導電シートは、金属細線で構成された電極パターン16A(16B)と、電極パターン16A(16B)の端部と電気的に接続された電極端子60A(60B)と、が基体14Aに設けられた上記の導電シート12A(12B)において、電極パターン16A(16B)の透過率が83%以上であり、電極パターン16A(16B)の透過率をa%と表したとき、電極端子60A(60B)の透過率が(a-20)%以上(a-3)%以下であるようにした。なお、より好ましくは、(a-15)%以上(a-3)%以下であり、さらに好ましくは、(a-10)以上(a-3)以下であり、最も好ましくは、(a-5)以上(a-3)以下の範囲である。
(第二のタッチパネル用の導電シート)
本発明に係る第二のタッチパネル用の導電シートは、金属細線で構成された電極パターン16A(16B)と、電極パターン16A(16B)の端部と電気的に接続された電極端子60A(60B)と、が基体14Aに設けられた上記の導電シート12A(12B)において、電極端子60A(60B)は、金属細線で構成された枠形状64を含むようにした。
(第三のタッチパネル用の導電シート)
本発明に係る第三のタッチパネル用の導電シートは、金属細線で構成された電極パターン16A(16B)と、電極パターン16A(16B)の端部と電気的に接続された電極端子60A(60B)と、が基体14Aに設けられた上記の導電シート12A(12B)において、電極端子60A(60B)は金属細線で構成された格子68からなるメッシュ形状66を含むようにした。
第1透明基体14A及び第2透明基体14Bとしては、プラスチックフィルム、プラスチック板、ガラス板等を挙げることができる。特に、光透過性や加工性等の観点から、PETが好ましい。
第1導電シート12Aの第1電極パターン16A及び第2導電シート12Bの第2電極パターン16Bとなる銀塩乳剤層は、銀塩とバインダーの他、溶媒や染料等の添加剤を含有する。
銀塩乳剤層の形成に用いられる溶媒は、特に限定されるものではないが、例えば、水、有機溶媒(例えば、メタノール等のアルコール類、アセトン等のケトン類、ホルムアミド等のアミド類、ジメチルスルホキシド等のスルホキシド類、酢酸エチル等のエステル類、エーテル類等)、イオン性液体、及びこれらの混合溶媒を挙げることができる。
本実施の形態に用いられる各種添加剤に関しては、特に制限はなく、公知のものを好ましく用いることができる。
銀塩乳剤層の上に図示しない保護層を設けてもよい。本実施の形態において「保護層」とは、ゼラチンや高分子ポリマーといったバインダーからなる層を意味し、擦り傷防止や力学特性を改良する効果を発現するために感光性を有する銀塩乳剤層上に形成される。その厚みは0.5μm以下が好ましい。保護層の塗布方法及び形成方法は特に限定されず、公知の塗布方法及び形成方法を適宜選択することができる。また、銀塩乳剤層よりも下に、例えば下塗り層を設けることもできる。
本実施の形態では、第1電極パターン16A及び第2電極パターン16Bを印刷方式によって施す場合を含むが、印刷方式以外は、第1電極パターン16A及び第2電極パターン16Bを露光と現像等によって形成する。すなわち、第1透明基体14A及び第2透明基体14B上に設けられた銀塩含有層を有する感光材料又はフォトリソグラフィ用フォトポリマーを塗工した感光材料への露光を行う。露光は、電磁波を用いて行うことができる。電磁波としては、例えば、可視光線、紫外線等の光、X線等の放射線等が挙げられる。さらに露光には波長分布を有する光源を利用してもよく、特定の波長の光源を用いてもよい。
本実施の形態では、乳剤層を露光した後、さらに現像処理が行われる。現像処理は、銀塩写真フイルムや印画紙、印刷製版用フイルム、フォトマスク用エマルジョンマスク等に用いられる通常の現像処理の技術を用いることができる。
本実施の形態では、前記露光及び現像処理により形成された金属銀部の導電性を向上させる目的で、前記金属銀部に導電性金属粒子を担持させるための物理現像及び/又はめっき処理を行ってもよい。本発明では物理現像又はめっき処理のいずれか一方のみで導電性金属粒子を金属性銀部に担持させてもよく、物理現像とめっき処理とを組み合わせて導電性金属粒子を金属銀部に担持させてもよい。なお、金属銀部に物理現像及び/又はめっき処理を施したものを含めて「導電性金属部」と称する。
本実施の形態では、現像処理後の金属銀部、並びに、物理現像及び/又はめっき処理によって形成された導電性金属部には、酸化処理を施すことが好ましい。酸化処理を行うことにより、例えば、光透過性部に金属が僅かに沈着していた場合に、該金属を除去し、光透過性部の透過性をほぼ100%にすることができる。
本実施の形態の第1電極パターン16A及び第2電極パターン16Bの金属細線の線幅は、30μm以下から選択可能であるが、タッチパネルの材料としての用途である場合、金属細線の線幅の下限値は0.7μmが好ましく、1μmがより好ましく、2μmがさらに好ましい。金属細線の線幅の上限値は15μmが好ましく、9μmがより好ましく、7μmがさらに好ましい。
本実施の形態における「光透過性部」とは、第1導電シート12A及び第2導電シート12Bのうち第1電極パターン16A及び第2電極パターン16B以外の透光性を有する部分を意味する。光透過性部における透過率は、前述のとおり、第1透明基体14A及び第2透明基体14Bの光吸収及び反射の寄与を除いた380~780nmの波長領域における透過率の最小値で示される透過率が83%以上、好ましくは85%以上、さらに好ましくは90%以上であり、さらにより好ましくは93%以上であり、最も好ましくは99%以上である。
本実施の形態に係る第1導電シート12A及び第2導電シート12Bにおける第1透明基体14A及び第2透明基体14Bの厚さは、5μm以上350μm以下であることが好ましく、30μm以上150μm以下であることがさらに好ましい。5μm以上350μm以下の範囲であれば所望の可視光の透過率が得られ、且つ、取り扱いも容易である。
水媒体中のAg150gに対してゼラチン10.0gを含む、球相当径平均0.1μmの沃臭塩化銀粒子(I=0.2モル%、Br=40モル%)を含有する乳剤を調製した。
露光のパターンは、第1導電シート12Aについては図1及び図3に示すパターンで、第2導電シート12Bについては図4A、図4B及び図6Bに示すパターンで、A4サイズ(210mm×297mm)の第1透明基体14A及び第2透明基体14Bに行った。露光は上記パターンのフォトマスクを介して高圧水銀ランプを光源とした平行光を用いて露光した。なお、第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bは、図1~3に示した全てのパターンでそれぞれサンプルを作成した。
・現像液1L処方
ハイドロキノン 20 g
亜硫酸ナトリウム 50 g
炭酸カリウム 40 g
エチレンジアミン・四酢酸 2 g
臭化カリウム 3 g
ポリエチレングリコール2000 1 g
水酸化カリウム 4 g
pH 10.3に調整
・定着液1L処方
チオ硫酸アンモニウム液(75%) 300 ml
亜硫酸アンモニウム・1水塩 25 g
1,3-ジアミノプロパン・四酢酸 8 g
酢酸 5 g
アンモニア水(27%) 1 g
pH 6.2に調整
上記処理剤を用いて露光済み感材を、富士フイルム社製自動現像機 FG-710PTSを用いて処理条件:現像35℃ 30秒、定着34℃ 23秒、水洗 流水(5L/分)の20秒処理で行った。
(サンプル1-1)実施例
作製した第1導電シート12A及び第2導電シート12Bの導電部(第1電極パターン16A、第2電極パターン16B)の透過度は83%である。作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bは図1のパターンであり、透過度は63%である。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を80%とした点以外は、サンプル1-1と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を60%とした点以外は、サンプル1-1と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を83%とした点以外は、サンプル1-1と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの導電部(第1電極パターン16A、第2電極パターン16B)の透過度は90%である。作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bは図1のパターンであり、透過度は70%である。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を87%とした点以外は、サンプル1-5と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を67%とした点以外は、サンプル1-5と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を90%とした点以外は、サンプル1-5と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの導電部(第1電極パターン16A、第2電極パターン16B)の透過度は83%である。作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bは図2のパターンであり、透過度は63%である。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を80%とした点以外は、サンプル1-9と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を60%とした点以外は、サンプル1-9と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を83%とした点以外は、サンプル1-9と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの導電部(第1電極パターン16A、第2電極パターン16B)の透過度は83%である。作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bは図3のパターンであり、透過度は63%である。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を80%とした点以外は、サンプル1-13と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端
子60Bの透過度を60%とした点以外は、サンプル1-7と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を83%とした点以外は、サンプル1-13と同様にした。
第1導電シート12A及び第2導電シート12Bを、測光機を用いて全光線透過率を測定した。測光機は、東京電色社製のTC-HIIIDPKを用いて計測した。
上述したサンプルに係る積層導電性シートを用いてそれぞれ投影型静電容量方式のタッチパネルを作製した。タッチパネルを回転盤に設置し、液晶表示装置を駆動して白色を表示させた際に、センシング領域の電極端子近傍において影(暗くなる部分)が確認できるかどうかを肉眼で確認した。
反応速度が優れるものをA、反応速度が良好なものをB、実用性上応答速度で問題にならないものをC、応答速度が遅く検出感度が悪いものをDと評価した。
表1からわかるように、サンプル1-1~16のうち本発明に係る透過度の範囲にあるものにおいては、視認性が良好であった。また、サンプル1-1~16のうち本発明に係る透過度の範囲にあるものにおいては、タッチパネルを指で触れて操作したところ、応答速度が速く、検出感度に優れることがわかった。また2点以上をタッチして操作したところ、同様に良好な結果が得られ、マルチタッチにも対応できることが確認できた。
(サンプル2-1)実施例
作製した第1導電シート12A及び第2導電シート12Bの導電部(第1電極パターン16A、第2電極パターン16B)の開口率は90%である。作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bは図5A及び図5Bに示すパターンであり、開口率は70%である。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの開口率を89.9%とした点以外は、サンプル2-1と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの開口率を68%とした点以外は、サンプル2-1と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を90%とした点以外は、サンプル2-1と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの導電部(第1電極パターン16A、第2電極パターン16B)の開口率は97%である。作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bは図5A及び図5Bに示すパターンであり、開口率は77%である。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの開口率を96.9%とした点以外は、サンプル2-5と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの開口率を75%とした点以外は、サンプル2-5と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの開口率を97%とした点以外は、サンプル2-5と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの導電部(第1電極パターン16A、第2電極パターン16B)の開口率は90%である。作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bは図6A及び図6Bに示すパターンであり、開口率は70%である。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの開口率を89.9%とした点以外は、サンプル2-9と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの開口率を68%とした点以外は、サンプル2-9と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を90%とした点以外は、サンプル2-9と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの導電部(第1電極パターン16A、第2電極パターン16B)の開口率は90%である。作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bは図7のパターンであり、開口率は70%である。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの開口率を89.9%とした点以外は、サンプル2-13と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの開口率を68%とした点以外は、サンプル2-13と同様にした。
作製した第1導電シート12A及び第2導電シート12Bの電極端子60A及び電極端子60Bの透過度を90%とした点以外は、サンプル2-13と同様にした。
第1導電シート12A及び第2導電シート12Bを、キーエンス社製のマイクロスコープVHX-200を用い、3000倍の条件で計測した。
上述したサンプルに係る積層導電性シートを用いてそれぞれ投影型静電容量方式のタッチパネルを作製した。タッチパネルを回転盤に設置し、液晶表示装置を駆動して白色を表示させた際に、センシング領域の電極端子近傍において影(暗くなる部分)が確認できるかどうかを肉眼で確認した。
反応速度が優れるものをA、反応速度が良好なものをB、実用性上応答速度で問題にならないものをC、応答速度が遅く検出感度が悪いものをDと評価した。
表2からわかるように、サンプル2-1~16のうち本発明に係る開口率の範囲にあるものにおいては、視認性が良好であった。また、サンプル2-1~16のうち本発明に係る開口率の範囲にあるものにおいては、タッチパネルを指で触れて操作したところ、応答速度が速く、検出感度に優れることがわかった。また2点以上をタッチして操作したところ、同様に良好な結果が得られ、マルチタッチにも対応できることが確認できた。
Claims (19)
- 金属細線で構成された電極パターンと、該電極パターンの端部と電気的に接続された電極端子と、を有する導電シートであって、
前記電極パターンの透過率が83%以上であり、前記電極パターンの透過率をa%と表したとき、前記電極端子の透過率が(a-20)%以上(a-3)%以下である導電シート。 - 金属細線で構成された電極パターンと、該電極パターンの端部と電気的に接続された電極端子と、を有する導電シートであって、
前記電極パターンの開口率が90%以上であり、前記電極パターンの開口率をb%と表したとき、前記電極端子の開口率が(b-20)%以上(b-0.1)%以下である導電シート。 - 前記電極端子は金属細線で構成された格子からなるメッシュ形状を含む請求項1又は2に記載の導電シート。
- 前記金属細線は30μm以下の線幅である請求項3に記載の導電シート。
- 前記金属細線は不透明な材料で構成される請求項3又は4に記載の導電シート。
- センシング領域に設けられ、金属細線で構成された電極パターンと、前記センシング領域の外側に設けられ、該電極パターンの端部と電気的に接続された電極端子と、が設けられた導電シートを有するタッチパネルであって、
前記電極パターンの透過率が83%以上であり、前記電極パターンの透過率をa%と表したとき、前記電極端子の透過率が(a-20)%以上(a-3)%以下であるタッチパネル。 - センシング領域に設けられ、金属細線で構成された電極パターンと、前記センシング領域の外側に設けられ、該電極パターンの端部と電気的に接続された電極端子と、が設けられた導電シートを有するタッチパネルであって、
前記電極パターンの開口率が90%以上であり、前記電極パターンの開口率をb%と表したとき、前記電極端子の開口率が(b-20)%以上(b-0.1)%以下であるタッチパネル。 - 金属細線で構成された電極パターンと、該電極パターンの端部と電気的に接続された電極端子と、を有する導電シートであって、
前記電極端子は、金属細線で構成された枠形状を含む導電シート。 - 前記電極パターンの細線の線幅をa(μm)としたとき、前記電極端子の枠形状の線幅b(μm)は、b≧2a、又は、b≧a+5(μm)を満たす請求項8に記載の導電シート。
- 前記電極パターンの細線の線幅a(μm)は、30μm以下である請求項9に記載の導電シート。
- 前記電極端子の金属細線で構成された枠形状の内部には、さらに、金属細線で構成された格子形状からなるメッシュ形状が設けられている請求項9又は10に記載の導電シート。
- センシング領域に設けられ、金属細線で構成された電極パターンと、前記センシング領域の外側に設けられ、該電極パターンの端部と電気的に接続された電極端子と、が設けられた導電シートを有するタッチパネルであって、
前記電極端子は、金属製の細線で構成された枠形状を含むタッチパネル。 - 金属細線で構成された電極パターンと、該電極パターンの端部と電気的に接続された電極端子と、を有する導電シートであって、
前記電極端子は金属細線で構成された格子からなるメッシュ形状を含む導電シート。 - 前記電極パターンは、格子からなるメッシュ形状であるとともに、
前記電極端子の格子からなるメッシュ形状のピッチは、前記電極パターンの格子からなるメッシュ形状のピッチよりも密である請求項13に記載の導電シート。 - 前記電極端子の格子からなるメッシュ形状のピッチは、前記電極パターンの格子からなるメッシュ形状のピッチの3/4以下である請求項14に記載の導電シート。
- 前記電極端子の格子からなるメッシュ形状のピッチは、50μm以上300μm以下である請求項13~15の何れか1に記載の導電シート。
- 前記電極端子には、前記電極端子の格子からなるメッシュ形状の外枠に、さらに、金属細線で構成された枠形状が設けられている請求項13~16の何れか1に記載の導電シート。
- 前記電極端子の表面抵抗値が4Ω/sq.以上80Ω/sq.以下である請求項13~17の何れか1に記載の導電シート。
- センシング領域に設けられ、金属細線で構成された電極パターンと、前記センシング領域の外側に設けられ、該電極パターンの端部と電気的に接続された電極端子と、が設けられた導電シートを有するタッチパネルであって、
前記電極端子は金属細線で構成された格子からなるメッシュ形状を含むタッチパネル。
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US11179915B2 (en) | 2013-10-22 | 2021-11-23 | Fujifilm Corporation | Touch panel electrode comprising two or more first electrode patterns, and two or more second electrode patterns, touch panel, and display device |
US10303292B2 (en) * | 2014-01-13 | 2019-05-28 | Lg Innotek Co., Ltd. | Touch window and touch device including the same |
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KR101451075B1 (ko) | 2014-10-15 |
US9055680B2 (en) | 2015-06-09 |
US9078364B2 (en) | 2015-07-07 |
CN103984461A (zh) | 2014-08-13 |
EP2781996A2 (en) | 2014-09-24 |
TWI537779B (zh) | 2016-06-11 |
TWI585631B (zh) | 2017-06-01 |
EP2781996A3 (en) | 2015-03-04 |
CN103907082A (zh) | 2014-07-02 |
US20140238730A1 (en) | 2014-08-28 |
EP2781996B1 (en) | 2019-12-04 |
EP2765490B1 (en) | 2017-06-07 |
BR112014010102A2 (pt) | 2017-06-13 |
CN103907082B (zh) | 2016-09-21 |
EP2765490A4 (en) | 2015-05-06 |
EP2765490A1 (en) | 2014-08-13 |
BR112014010102A8 (pt) | 2017-06-20 |
KR20140063900A (ko) | 2014-05-27 |
TW201432527A (zh) | 2014-08-16 |
CN103984461B (zh) | 2017-09-15 |
US20140231120A1 (en) | 2014-08-21 |
KR20140090176A (ko) | 2014-07-16 |
TW201327315A (zh) | 2013-07-01 |
KR101645828B1 (ko) | 2016-08-04 |
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