WO2013018805A1 - Fragrance destinée à supprimer les odeurs fécales, fragrance encapsulée dans des microcapsules utilisant celle-ci, textile pouvant supprimer les odeurs fécales, pastilles destinées à supprimer les odeurs fécales, pulvérisation d'une fragrance encapsulée dans des microcapsules, et dispositif de pulvérisation d'un parfum destiné à supprimer les odeurs fécales - Google Patents

Fragrance destinée à supprimer les odeurs fécales, fragrance encapsulée dans des microcapsules utilisant celle-ci, textile pouvant supprimer les odeurs fécales, pastilles destinées à supprimer les odeurs fécales, pulvérisation d'une fragrance encapsulée dans des microcapsules, et dispositif de pulvérisation d'un parfum destiné à supprimer les odeurs fécales Download PDF

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Publication number
WO2013018805A1
WO2013018805A1 PCT/JP2012/069489 JP2012069489W WO2013018805A1 WO 2013018805 A1 WO2013018805 A1 WO 2013018805A1 JP 2012069489 W JP2012069489 W JP 2012069489W WO 2013018805 A1 WO2013018805 A1 WO 2013018805A1
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WIPO (PCT)
Prior art keywords
fragrance
odor
component
scent
modulated
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PCT/JP2012/069489
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English (en)
Japanese (ja)
Inventor
芳邦 山本
誠司 戸塚
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山本香料株式会社
株式会社シバタ
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Publication of WO2013018805A1 publication Critical patent/WO2013018805A1/fr

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12—Processes in which the treating agent is incorporated in microcapsules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01K—ANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00—Housing animals; Equipment therefor
    • A01K1/015—Floor coverings, e.g. bedding-down sheets ; Stable floors
    • A01K1/0152—Litter
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/22—Phase substances, e.g. smokes, aerosols or sprayed or atomised substances
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/08—Processes in which the treating agent is applied in powder or granular form

Definitions

  • the present invention relates to a scent for suppressing stool odor, a microencapsulated fragrance using the scent, a fiber product with a stool odor suppressing function, a pellet for suppressing stool odor, a microencapsulated fragrance spray and a spray for suppressing stool odor.
  • disposable diapers are worn on the human body, it is almost impossible to always isolate them completely from third parties.
  • there are often scenes where the user goes out with the diaper attached but in this case, a bad odor is leaked at the place where the user moves, leading to a mental burden on the parties.
  • disposable diapers are provided with expansion / contraction gathers to prevent leakage at sites where they are in contact with the waist and the base of the foot, but there is a limit to the sealing force, and diapers with breathability are also available. The bad smell that leaks through the material cannot be prevented.
  • colostomy makers so-called ostomates.
  • a bag (pouch) for collecting the discharged feces is always attached to the constructed anus discharge port, but the anus constructed on the body side can be easily replaced.
  • the collection pouch will be replaced exclusively. If the pouch is incompletely installed, fecal odor is likely to leak.
  • the mounting base on the colostomy side will be worn or damaged, and the fitting seal with the pouch mounting port will be reduced, making fecal odor more likely to leak out. is there.
  • the methods (2) and (3) described above are employed as a method for suppressing fecal odor.
  • the chemical method (2) it may take a long time to completely decompose the stool odor component, or the decomposition reaction may not proceed uniformly, and the effect may be insufficient.
  • the stool odor is basically eliminated, there is also an aspect in which a refreshing feeling due to aroma cannot be obtained although there is a problem of preference.
  • the masking method in (3) only makes the stool odor unobtrusive due to the strong fragrance, and the overall scent of the mixed fragrance and stool odor is not always comfortable. Not always. Fecal odor is a peculiar bad odor that is inseparably linked to the daily life of human life, and it is easy to be aware of the presence of the odor behind the fragrant fragrance. There is.
  • Patent Document 1 This technology is related to body odor control. Specifically, 2-nonen-1-al, which is said to be a causative substance of body odor, is wrapped in a cassis green scent and converted into a good scent. .
  • the characteristic point of this effect is to select a fragrance that harmonizes with the bad odor of “body odor” and not to forcibly suppress the bad odor, but to incorporate the bad odor as one of the components of the “good fragrance” that is ultimately imagined. In that point.
  • this effect is referred to as the “harmonage effect”, and shampoos, rinses, body soaps, soaps, etc. using this effect are manufactured and sold.
  • paragraph 0004 it is also permitted as an option to adopt “a specific perfume alone” in order to enjoy such a harmony effect.
  • paragraph 0004 of the same document suggests the possibility of adopting a combination of a plurality of fragrances, but in this case, it is obvious that the establishment of a fragrance prescription becomes more difficult due to the multiple fragrances. It is. The essence is that the design concept of a perfume formulation necessary for realizing a harmony effect with body odor is not disclosed in the document.
  • Patent Document 1 discloses only a fragrance formulation having an effect for suppressing body odor, and this fragrance is effective for suppressing stool odor, and particularly for suppressing stool odor based on the harmony effect. No prescription is disclosed.
  • the masking effect is defined as “an effect that antagonizes the odor and makes it difficult to feel the odor” in paragraph 0011, and the harmony effect is “harmonized well with the odor and makes it feel uncomfortable.
  • effect the essence of harmony effect is not to suppress the bad smell (bad smell) with a strong fragrance (masking) but to incorporate it as one of the components of “good fragrance” in harmony with the bad smell. It is.
  • “antagonizing” and “harmonizing” with respect to the odor are completely opposite to each other, and there is a significance of the harmony effect as means for suppressing the odor that cannot be solved by the masking effect.
  • the object of the present invention is to incorporate fecal odor as one of the scent components, and to convert it into a high-grade fragrance that could not be realized with conventional fragrances, etc.
  • An object of the present invention is to provide a scent for suppressing stool odor, a microencapsulated fragrance using the scent, a fiber product with a stool odor suppressing function, a pellet for suppressing stool odor, a microencapsulated fragrance spray, and a spray for suppressing stool odor.
  • a basic fragrance component having a floral fragrance A modulated fragrance component comprising an animal fragrance having an animal odor or oily fragrance, modulating a floral fragrance based on the basic fragrance component in a direction in harmony with human skin odor, and forming a modulated plant fragrance,
  • the difference which excludes only the emphasized fragrance ingredient from the target prescription of the fragrance for the plant body which consists of the animal fragrance which has the smell of the fecal odor system, and which further enhances the fragrance of the modulated plant odor.
  • the fragrance of the modulated plant-based fragrance is weakened alone than the plant-based fragrance according to the target prescription
  • the odor of the stool odor system is superimposed
  • the odor of the stool odor system is incorporated as an alternative component of the emphasized fragrance component. It is characterized by a scent with an emphasis on the modulated plant fragrance.
  • a basic fragrance component having a floral fragrance is used, and the final scent when the stool odor is superimposed is assembled with the floral (flower) scent as an axis.
  • floral fragrance is also used as a main component of fragrances that are directly applied to human skin, such as perfume, but as a perfume for the human body, it promotes harmony with human skin odor and increases the depth and depth of the fragrance. In order to give it, it is effective to add an animal fragrance having an animal odor or oily fragrance.
  • the present inventors from the above-described basic fragrance component having a floral fragrance, a modulated fragrance component comprising an animal fragrance having an animal odor or oily fragrance, and an animal fragrance having a fecal odor
  • the target of the plant-based fragrance for plant fragrance assembled with the emphasized fragrance component is the final stool fragrance-based emphasized fragrance component and the real stool odor that is the object of suppression of the present invention I thought that there might be mutual substitution. Therefore, when the fragrance was formulated based on the differential prescription excluding only the emphasized fragrance component from the above target prescription, and superimposed on the odor of the fecal odor system, it was almost the same quality as the fragrance normally formulated according to the target prescription.
  • the present invention has been completed by finding that it is converted into an elegant and noble scent.
  • the fragrance for faecal odor suppression according to the present invention compared with a plant body fragrance based on the original target prescription, excludes the emphasized fragrance component, so that the modulated plant fragrance is weakened alone. It smells.
  • the fecal odor-type malodor is superimposed on this, the fecal odor-type malodor is incorporated as an alternative to the emphasized fragrance component, and the modulated plant-type fragrance is emphasized in the same way as a fragrance normally formulated according to the target prescription. Scented.
  • the fecal odor can be suppressed in a form that is converted to an elegant and noble scent deeper than the floral fragrance of the basic fragrance component.
  • the modulated fragrance component having an animal odor or oily fragrance alone is excellent in both affinity as a fragrance to human skin and fusion with a floral fragrance. As a result, it has the property that it can be easily adapted to fecal odor, which is the same animal odor.
  • the modulated fragrance component like a surfactant that blends water and oil, mediates between the floral fragrance and fecal odor, which are inherently easy to separate from each other. And make an essential contribution to the appearance of a different, high-grade fragrance that cannot be achieved with floral fragrance alone.
  • the fragrance finally obtained when superposed on the fecal odor is very different from the quality of the floral fragrance obsolete with the toilet fragrance or the like.
  • the memory of fecal odor imprinted on the parties as a subconscious is less likely to be evoked.
  • the above-mentioned fragrance formulation has three components each having a clear fragrance as a target formulation, that is, a basic fragrance component of a floral fragrance, and a modulated fragrance component having an animal odor or oily fragrance.
  • the final fragrance image is assembled based on the emphasized fragrance component having a fecal odor-based odor, and only the emphasized fragrance component is extracted therefrom to obtain a differential prescription. That is, it is also important that a perfume formulation can be easily established without being so deeply conscious of whether the floral fragrance employed itself is excellent in harmony with fecal odor alone.
  • Patent Document 1 there is no need to search for a single fragrance or a combination of multiple fragrances that harmonize with fecal odor, and the labor and cost of fragrance development can be greatly reduced and adopted.
  • the types of possible floral aromas, and thus the final scent variations (when superimposed on the fecal odor), can be greatly increased.
  • the differential prescription further includes a harmonious fragrance component that adjusts the floral fragrance to a direction that shifts the floral fragrance to a green or herbal system (including a spice system as a concept), and a modulated fragrance.
  • a component can be set as what modulates the floral-type fragrance which shifted to the green type or the herb type by the harmony fragrance
  • the final fragrance in which the modulated fragrance component and the harmonious fragrance component and the floral fragrance are fused may be able to easily identify the fragrance of the base flower
  • the scent may be separated from the scent of flowers.
  • it can be a forest-like scent or a meadow-like scent, which will be described later, or a clean and refreshing soap-like scent, based on the scent of flowers.
  • the preferable blending ratio of the basic fragrance component, the modulated fragrance component and the harmonious fragrance component constituting the differential prescription varies greatly depending on the type of fragrance to be used and the strength of the fragrance, for example, the weight content ratio It is possible that a perfume component contained only in a small amount in the above formula is felt as a scent more strongly than other components in the formulation.
  • the preferable blending ratio of each component is as follows.
  • Basic fragrance component 10% to 95% by mass, desirably 25% to 90% by mass
  • Modulated fragrance component 1% to 60% by mass, desirably 3% to 58% by mass
  • Basic fragrance component It can be omitted.
  • the modulation fragrance component can be specifically composed of one or more of musk fragrance, amber fragrance and leather odor fragrance (for example, castrium fragrance).
  • the present inventors use the target plant formula as an enhanced fragrance component, and the modulated plant-based fragrance possessed by the differential formulation is extremely high.
  • the fragrance based on the differential prescription is superimposed on the stool odor, a high-quality scent tone equivalent to the fragrance based on the target prescription when civet is used can be obtained, and the fecal odor suppression effect is remarkable.
  • the modulated fragrance component is configured so that the musk-like fragrance is blended as the maximum component.
  • the basic fragrance component is one or more of jasmine fragrance, mugue fragrance, balsam fragrance, lily fragrance, rose fragrance, violet fragrance and lilac fragrance. Is preferably used.
  • the modulated fragrance component consisting of one or more of the above musk fragrance, amber fragrance and leather odor fragrance is a harmonious fragrance component that shifts the floral fragrance to green or herbal.
  • High compatibility That is, the floral fragrance shifted to green or herb is particularly enhanced in the effect of harmonizing with human skin odor by the above-mentioned modulated fragrance component.
  • the effect becomes more prominent when the harmonious fragrance component contains a citrus fragrance or a woody fragrance (including an earthy fragrance as a concept) in addition to the green or herb fragrance.
  • the final fragrance is separated from the pure floral fragrance by using in combination with the above-mentioned modulated fragrance ingredients. It can be transformed into various desirable scents. Although the specific structure is illustrated below, this invention is not limited to these.
  • the obtained modulated plant fragrance can be made to be a grassy fragrance.
  • Basic tone fragrance component Jasmine fragrance is blended as the maximum component, and four components of Lily fragrance, Rose fragrance, Mugue fragrance and balsam fragrance are added, and the total content of these four components is jasmine. It mix
  • Harmonic perfume ingredients Herb-based perfumes, woody perfumes and citrus perfumes are blended so that the total of any two of these three components does not fall below the content of the remaining components.
  • Modulated perfume ingredient Musk perfume is blended as the maximum component.
  • the grassy aroma obtained in this way can be expressed as a positive scent that, in particular, gives a bright and refreshing wind atmosphere, and the sweetness of the flowers blends into the fragrance of the somewhat blue-smelling grass.
  • the scent of the grassland-like scent has a floral (ground) base, and is a high-class elegance with depth and depth added by animal-based modulated fragrance ingredients. And even when fecal odor is superimposed, the balance of fragrance is not lost and stable, and it is hard to believe that the fragrance is partly derived from fecal odor.
  • the point of obtaining the grassy scent with the above prescription is based on jasmine fragrance so that the scent of specific flowers does not pop out, and further added lily, rose, mugue and balsam.
  • citrus fragrances are used as harmonious fragrance ingredients in order to be blended with at least 5 floral fragrances and to harmonize with musk-like modulated fragrance ingredients. Is a point.
  • the citrus fragrance it is particularly preferable to blend a lime fragrance and a bergamot fragrance.
  • flavor component it is also possible to mix
  • the blending ratio of each component desirable for obtaining the grassy flavor is, for example, generally as follows, but is not limited thereto.
  • Basic tone fragrance ingredients 50 mass% to 75 mass% (jasmine fragrance: 20 mass% to 35 mass%, Lily fragrance, rose fragrance, Muge fragrance and balsam fragrance total: 21 mass% More than 40 mass%).
  • Harmonic fragrance ingredient 10% by mass or more and 16% by mass or less.
  • Modulated perfume ingredient 10% by mass or more and 20% by mass or less (musk perfume: 8% by mass or more and 20% by mass or less).
  • the obtained modulated plant fragrance can be made into a forest-like fragrance.
  • Basic tone fragrance component While blended with jasmine fragrance as the maximum component, Lily fragrance is then blended as a component with a high content.
  • Harmonic fragrance ingredients Herbal fragrance, woody fragrance and green fragrance are blended so that the total of any two of these three ingredients does not fall below the content of the remaining ingredients. It contains more citrus fragrance than the total of fragrance and green fragrance.
  • Modulated fragrance component The modulated fragrance component is blended more than the basic fragrance component, and the amber fragrance is blended as the modulated fragrance component, with the musk fragrance as the maximum component.
  • the forest-like aroma obtained in this way is reminiscent of the scent of the above-mentioned grassland, and is reminiscent of leaves, trees, etc.
  • a profound fragrance should be described. Similar to the grassy scent described above, it has a floral (flower) base while adding depth and depth to the animal-based modulated fragrance ingredients, and the scent balance when faecal odor is superimposed is also good. It becomes the content which makes it forget that it is the fragrance derived from the part feces smell.
  • the key to obtaining a forest-like aroma with the above formula is based on jasmine-like fragrance, and a considerable amount of lily-like fragrance is blended with it to form a unique tone rather than in the case of grassland
  • the harmonious fragrance component essential for the green system and the amber fragrance with a submerged scent are indispensably blended to produce a deep forest spirit.
  • green fragrance is co-blended with herbal fragrance and woody fragrance with content competing with this so that the blue odor of green fragrance does not jump out excessively, and citrus fragrance is also used here.
  • citrus fragrance it is desirable to blend a lemon fragrance, a lime fragrance and a bergamot fragrance.
  • the blending ratio of each component desirable for obtaining a forest-like aroma is, for example, generally as follows, but is not limited thereto.
  • Basic tone fragrance component 25% by mass or more and 45% by mass or less (jasmine fragrance: 12% by mass or more and 30% by mass or less, Lily fragrance: 5% by mass or more and 15% by mass or less).
  • Harmonic fragrance component 7% by mass or more and 20% by mass or less (total of herb fragrance, woody fragrance and green fragrance: 2% by mass or more and 5% by mass or less, citrus fragrance: 5% by mass or more and 15% by mass or less)
  • Modulated fragrance component 35% by mass or more and 68% by mass or less (musk fragrance: 25% by mass or more and 45% by mass or less, amber fragrance: 10% by mass or more and 30% by mass or less).
  • the obtained modulated plant fragrance can be used as a soap-like fragrance.
  • Basic tone fragrance component Both jasmine fragrance and rose fragrance are blended so that one of them becomes the maximum component, and at least one of violet fragrance and lilac fragrance is blended.
  • Modulated fragrance component Musk fragrance or amber fragrance is blended as a maximum component.
  • Soap is originally made from fats and oils, and has been devised based on the scent of flowers for a long time on the premise that it is applied to human skin.
  • the base of the scent mixed with fats and flowers is pronounced of the smell of soap, especially jasmine fragrance and rose fragrance become familiar as soap fragrances. ing.
  • a highly durable fragrance such as musk or amber is blended to form a generally recognized soap odor image.
  • the basic fragrance component it is possible to further blend at least one of Lily fragrance and Mugue fragrance in order to give sweetness to the scent. Further, it is of course possible to blend at least one of herbal fragrances and woody fragrances as the harmonious fragrance ingredients. In this case, when it is desired to prevent the herb-based fragrance and the woody fragrance from becoming too sharp, it is preferable to further blend a citrus-based fragrance as a harmony fragrance component.
  • the blending ratio of each component desirable for obtaining a soap-like aroma is, for example, generally as follows, but is not limited thereto.
  • Basic tone fragrance component 65% by mass or more and 90% by mass or less (total of jasmine fragrance and rose tone fragrance: 30% by mass or more and 75% by mass or less (some of these, for example, up to 20% by mass, Lily fragrance and Mugue tone) And can be replaced with at least one of the fragrances), the total of the violet fragrance and the lilac fragrance: 2 mass% to 15 mass%).
  • Harmonic fragrance ingredient 15% by mass or less (can be omitted)
  • Modulated fragrance component 2% by mass or more and 25% by mass or less.
  • perfume ingredients that can be used in the present invention are listed below, but are not limited thereto.
  • the jasmine flavoring include benzyl acetate, 2-n-hexyl-3-phenyl-2-propenal ( ⁇ -hexylcinnamic aldehyde), methyl dihydrojasmonate (trade name: MDJ Super), methyl jasmonate, 3- Methyl-2- (cis-2-penten-1-yl) -2-cyclopenten-1-one (cisjasmon), 3-phenylpropionaldehyde (hydrocinnamaldehyde), benzyl formate, 2-n-pentyl-3- Those selected from phenylpropenal (jasmine aldehyde), benzyl propionate and the like can be used alone or in combination of two or more.
  • the Muguet flavor is 4-methyl-2- (2-methylpropyl) tetrahydro-2H-pyran-4-ol (trade name: Florol), ⁇ - (p-tert-butylphenyl) - ⁇ -methylpropionaldehyde ( Product name: Lilyal), 2-methyl-3- (p-isopropylphenyl) propionaldehyde (cyclamenaldehyde), 3,7-dimethyl-1,7-octanediol (hydroxycitronellol), 3,7-dimethyl-7- Hydroxyoctanal (hydroxycitronellal), 4 (3)-(4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde (lyral), 3,7-dimethyl-3-octanol (tetrahydrolinalool) ), 4- (1-methylethyl) cyclohexanemethanol, isosorbide These can be used alone or in combination of two or more.
  • the balsam tone fragrance is selected from n-hexyl salicylate, 3-phenyl-1-propanol (hydrocinnamyl alcohol), benzoin resinoid, benzyl cinnamate, cinnamic acid, balsam peru or balsam toru alone, Alternatively, two or more kinds can be used in combination.
  • Lily-like fragrance is composed of 3,7-dimethyl-1,6-octadien-3-ol (linalool: sometimes used as Mugue-like), 3,7-dimethyl-1,6-octadien-3-yl acetate Those selected from (linalyl acetate) and 3,7-dimethyl-1,6-nonadien-3-ol (ethyl linalool) can be used alone or in combination of two or more.
  • Rose flavors include ⁇ -phenylethyl alcohol (trade name: Rose P), 3,7-dimethyl-6-octen-1-ol (citronellol), cis-3,7-dimethyl-2,6-octadiene-1 -Ol (nerol), trans-3,7-dimethyl-2,6-octadien-1-ol (geraniol), 4-methyl-2- (2-methyl-1-propenyl) hetrahydro-2H-pyran (rose oxide) ), 3,7-dimethyloctanol (tetrahydrogeraniol), 3-methyl-5-phenyl-1-pentanol (phenoxanol), 1- (2,6,6-trimethyl-1-cyclohexenyl) -2- Buten-1-one ( ⁇ -damascone), ⁇ -phenylethyl phenylacetate, decyl acetate, geranyl benzoate, 2-phenylethyl acetate 3,7-
  • lilac fragrance one selected from dimethylbenzyl carbinol, 1-methyl-4-isopropyl-1-cyclohexen-8-ol ( ⁇ -terpineol) and the like may be used alone or in combination of two or more. it can.
  • Violet flavors include 4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-buten-2-one ( ⁇ -ionone), 4- (2,6,6-trimethyl-1 -Cyclohexen-1-yl) -3-buten-2-one ( ⁇ -ionone), methylionone, etc. can be used alone or in combination of two or more.
  • Herbal flavors are 1,2-dimethoxy-4- (1-propenyl) benzene (isoeugenol), dodecahydro-3a, 6,6,9a-tetramethylnaphtho [2.1-b] Furan (ambroxan), 1- (5,5-dimethylcyclohexen-1-yl) -4-penten-1-one (Dinascon), 4-allyl-2-methoxyphenol, formic acid ⁇ , 3,3-trimethylcyclohexane Methyl (Afermat), Guiac Wood, Nutmeg Oil, Eucalyptus Oil, Lavender Oil, Anethole (Anise), Estragole (Anise), d-Carvone (Caraway), Perilaldehyde (Perilla), 4- ( 4-hydroxy-3-methoxyphenyl) -2-butanone (ginger-like), l-menthol (mint-like), Tilvanillin (vanilla), vanillin
  • Green fragrances are cis-3-hexenyl acetate, cis-3-hexenol, dimethyltetrahydrobenzaldehyde (triplar), p-ethyl-2,2-dimethylhydrocinnamaldehyde (trade name: florarozone), ethyl benzoate, bornyl acetate , Farnesol, d- ⁇ -pinene and the like can be used alone or in combination of two or more.
  • Woody perfume (including earthy tone) is 3,3-dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol (trade name: Polysanthol ), 2-methyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol (trade name: Santalinol), olivenum oil, patchouli oil, etc.
  • a thing can be used individually or in combination of 2 or more types.
  • Fruity flavors are 2-methyl-1,3-dioxolane-2-ethyl acetate, (trade name: fructon), 2-tert-butylcyclohexyl acetate, 3-methyl-2-butenyl acetate, isoamyl butyrate, ethyl caprylate , Ethyl selected from tricyclo [5.2.1.0 2.6 ] decane-2-carboxylate and the like can be used alone or in combination of two or more.
  • aldehyde flavoring agent one selected from n-hexanal, n-heptanal, n-octanal, n-nonanal, n-decanal, n-undecanal, etc. may be used alone or in combination of two or more. it can.
  • Lactone tone fragrances include coumarin, ⁇ -hexalactone, ⁇ -heptalactone, ⁇ -heptalactone, ⁇ -octalactone, ⁇ -octalactone, ⁇ -nanolactone, ⁇ -nanolactone, ⁇ -decalactone, ⁇ -decalactone, ⁇
  • One selected from undecalactone, ⁇ -dodecalactone and the like can be used alone or in combination of two or more.
  • Citrus flavors are 2,6-dimethyl-7-octen-2-ol (lime tone, dihydromyrcenol), 3,7-dimethyl-2,6-octadien-1-al (lemon tone, citral), Lime oil, bergamot (natural bergamot), lemon oil, orange oil, limonene (orange, lemon tone), octylaldehyde (orange tone), diphenylmethane (orange tone), methylheptenone (green, fruit tone), geranial (lemon tone) ), Dipentene (lemon tone), ⁇ -terpinene (lemon tone), neral (lemon tone), linalyl acetate (citrus fruit tone), rosinal (citrus tone), decylaldehyde (citrus tone with fatty odor), tarpinyl acetate ( Bergamot, lavender-like) etc. alone or in combination of two or more You are possible to use Te.
  • Animal odor-based fragrances can typically be musk-like fragrances. That is, musk or a synthetic product thereof, specifically, cyclopentadecenolide (trade name: havanolide), 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8 -Hexamethylcyclopenta- ⁇ -2-benzopyran (trade name: galaxolide), 1- (5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthalenyl) ethane -1-one (trade name: tonalide), ethylene brush rate (trade name: musk T), 4,4a, 5,9b-tetrahydroindeno [1.2-d] -1,3-dioxin (trade name: Indoflor), 2- [1- (3,3-dimethylcyclohexyl) ethoxy] -2-methylpropionate 1-propyl (trade name: Helvetolide), ⁇ -penta
  • amber flavor is amber or a synthetic product thereof, specifically 2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydro-2-acetonaphthene ( Product name: Iso-e super (amber fleur)), isoamyl benzoate (amber odor), methylnonylacetaldehyde (amber odor), etc. may be used alone or in combination of two or more. it can.
  • the leather odor-based fragrance one selected from castorium or a synthetic product thereof, isobutylquinoline and the like can be used alone or in combination of two or more. Any of the fragrances may be diluted with a solvent such as dipropylene glycol, benzyl benzoate, or ethanol.
  • the first is characterized in that the fragrance for suppressing stool odor of the present invention is used as a core material, and has a capsule wall material that encloses the core material so that excrement (a fragrance for suppressing stool odor flows out when in contact with stool).
  • a microencapsulated fragrance is made by encapsulating the fragrance in the capsule wall material, so that the fragrance volatilization is suppressed at all times and the odor control ability can be preserved for a long time.
  • the capsule wall material breaks and the inner core material, that is, the scent fragrance of the present invention flows out and mixes with the stool odor, resulting in a comfortable scent close to the target prescription.
  • This can be converted to quickly and comfortably suppress the odor, and because it is microencapsulated, It can be easily applied by mixing for various substrates, spraying or coating such contact is expected with.
  • a fiber product with a fecal odor suppressing function having the microencapsulated fragrance of the present invention and a fibrous base material on which the microencapsulated fragrance is fixed can be configured. According to this configuration, the effect of suppressing fecal odor can be imparted very easily by fixing the microencapsulated fragrance of the present invention to a textile product predicted to come into contact with feces.
  • the toilet part of a paper diaper or a cloth diaper can be composed of the above fibrous base material.
  • the fiber base material with the microencapsulated fragrance of the present invention to the receiving part of disposable diapers or cloth diapers worn by babies and care recipients, the odor derived from feces leaking into the diaper is greatly increased. Can be reduced.
  • the pouch cover which covers the pouch of an artificial anus can also be comprised with said fiber base material. In this case, odor derived from feces discharged into the pouch can be greatly reduced.
  • users with handicap related to defecation such as elderly people, people who need nursing care, or ostomate, wear such textile products on human body parts that are expected to come into contact with feces, thereby suppressing fecal odor.
  • the fragrance fragrance on which the fecal odor is superimposed becomes close to the image of cosmetics due to the action of the modulated fragrance component for harmony with human skin.
  • the final scent incorporating the fecal odor is recognized as the scent of the cosmetic used by the user, and a natural and uncomfortable odor environment can be created.
  • production of fecal odor can be reduced significantly.
  • the fibrous base material can also be configured as a deodorizing sheet or deodorizing pellet that absorbs pet urine.
  • deodorant sheets and deodorant pellets are used for pet toilets when keeping pets indoors, and are filled with the microencapsulated fragrance of the present invention to fill the room.
  • the smell of pet excrement can be converted into a pleasant fragrance, which can increase discomfort and cleanliness.
  • the microencapsulated fragrance of the present invention and ceramic pellets to which the microencapsulated fragrance is fixed can be configured. In this case, the same effect can be obtained if used in a pet toilet. .
  • pellets are not limited to pet toilets, and can be used without limitation as long as they are sources of fecal odor, such as in a draw-up type toilet or a barn, and can enjoy the fecal odor suppression effect. it can.
  • a microencapsulated fragrance spray can be constructed by filling the spray container with the microencapsulated fragrance of the present invention together with a capsule dispersant made of a liquid that does not dissolve the capsule wall material.
  • a capsule dispersant made of a liquid that does not dissolve the capsule wall material.
  • a fixing agent for fixing the capsule wall material to the surface of the material to be sprayed may be filled in the spray container together with the microcapsules.
  • the sprayed compressed gas medium may be filled into the spray container together with the microcapsules (further, the fixing agent).
  • a stool for suppressing stool odor can be configured by filling the spray container with the fragrance for suppressing stool odor according to the present invention (which is liquid, not microencapsulated).
  • the fragrance for suppressing stool odor according to the present invention which is liquid, not microencapsulated.
  • a sprayed compressed gas medium may be filled in a spray container together with a faecal odor suppressing fragrance.
  • the schematic diagram of the microencapsulation fragrance of this invention The schematic diagram which shows the concept of the textiles with a feces smell suppression function of this invention.
  • Sectional drawing which shows an example of the deodorizing sheet for pets which is one Embodiment of the textiles with a feces smell suppression function of this invention.
  • the top view which shows an example of the paper diaper which is one Embodiment of the textiles with a feces smell suppression function of this invention.
  • the front view which shows an example of the pouch cover for artificial anus which is one Embodiment of the textiles with a feces smell suppression function of this invention.
  • Sectional schematic diagram showing the first embodiment of the pellet for suppressing fecal odor of the present invention The cross-sectional schematic diagram which shows 2nd embodiment of the pellet for feces smell suppression of this invention.
  • Sectional drawing which shows 1st embodiment of the spray for feces smell suppression of this invention.
  • the fragmentary sectional view which shows 2nd embodiment of the spray for feces smell suppression of this invention.
  • the fragmentary sectional view which shows 3rd embodiment of the spray for feces suppression of this invention.
  • FIG. 1 is a schematic cross-sectional view showing a configuration example of the microencapsulated fragrance of the present invention.
  • the microencapsulated fragrance 1 uses the scent for suppressing stool odor according to the present invention as a core material 1c, and encapsulates the core material 1c so that the scent for suppressing stool scent flows out when it comes into contact with excrement (feces and urine). Material 1w.
  • the material of the capsule wall material 1w examples include water-soluble polymer materials such as gelatin, agar, starch, dextrin, polyvinyl alcohol, carboxymethylcellulose, various natural gelling agents, glycerin, and the like. As long as it can be dissolved by the moisture contained in the water and the core material 1c inside can be discharged, it is not limited thereto.
  • the structure of the microcapsule is not particularly limited, and for example, a simple mononuclear structure can be exemplified.
  • the shape of the microcapsule is not particularly limited.
  • the size of the microcapsule is not particularly limited, and is usually 0.1 ⁇ m or more and 1000 ⁇ m or less, preferably 1 ⁇ m or more and 50 ⁇ m or less.
  • the microencapsulated fragrance 1 can be fixed on a fibrous base material 2 to constitute the fiber product with a fecal odor suppressing function of the present invention.
  • the material of the fibrous base material is not particularly limited, but it is desirable to employ natural plant fibers such as cotton and pulp and hydrophilic synthetic fibers such as vinylon.
  • the fixing material may be the same material as the capsule wall material 1w, and the capsule wall material 1w itself can be used as a fixing agent by applying an appropriate amount of moisture.
  • the form of the fibrous base material may be a woven form, a non-woven form, or a form of a paper-like pulp sheet or pulp pellet.
  • FIG. 3 shows a structural example of a deodorizing sheet using the above-mentioned fibrous base material, which is used by laying on the bottom of a pet toilet or the like.
  • the deodorizing sheet 3 includes a liquid permeable liquid permeable front side sheet 3c, a liquid impermeable back side sheet 3d, and an absorber interposed between the two sheets 3c and 3d. 3a, and the periphery of the front surface side sheet 3c and the back surface side sheet 3d is liquid-tightly sealed.
  • the material of the surface side sheet 3c may be any material that exhibits liquid permeability, and examples thereof include a porous or non-porous nonwoven fabric and a porous plastic sheet.
  • the nonwoven fabric is not particularly limited as to what the raw fiber is.
  • olefins such as polyethylene (PE) and polypropylene (PP), polyesters, polyamides, etc., synthetic fibers such as rayon and cupra, natural fibers such as cotton, etc. are used.
  • the mixed fibers can be exemplified.
  • the absorbent body 3a for example, a fluffy pulp fiber aggregate (laminated pulp) in which a granular absorbent polymer is mixed can be exemplified.
  • a fluffy pulp fiber aggregate laminated pulp
  • an absorptive polymer what absorbs and hold
  • examples include starch-based, cellulose-based, synthetic polymer-based, starch-acrylic acid (salt) graft copolymers, saponified starch-acrylonitrile copolymers, cross-linked sodium carboxymethylcellulose, An acrylic acid (salt) polymer or the like can be used.
  • the shape of the absorbent polymer a generally used granular material is suitable, but other shapes can also be used.
  • the quantitative arrangement and density distribution of the absorbent polymer with respect to the piled pulp should be uniform for the purpose of general purpose, but depending on the purpose when the purpose is to exhibit special absorption characteristics. Can be biased.
  • the raw material of the piled pulp is not particularly limited.
  • known materials such as cotton-like pulp and synthetic pulp can be exemplified.
  • the raw material fiber of a pulp is not specifically limited, For example, the cellulose fiber obtained from woods, such as a mechanical pulp, a chemical pulp, and a dissolving pulp, Artificial cellulose fibers, such as rayon and an acetate, etc. can be illustrated.
  • wood which is a raw material for cellulose fibers, is preferable in terms of function and price because conifers have a longer fiber length than hardwoods.
  • the microencapsulated fragrance 1 shown in FIG. 1 is fixed to the absorber 3a side, the surface side sheet 3c side, or both of them in the deodorizing sheet 3 shown in FIG.
  • the wall material 1w of the microencapsulated fragrance 1 of FIG. 1 is dissolved by the moisture, and the feces odor control of the present invention constituting the inner core material 1c is provided. Fragrance leaks and suppresses fecal odor.
  • FIG. 4 shows an example of a paper diaper using the present invention.
  • the paper diaper 4 includes a liquid-permeable front side sheet 111, a liquid-impermeable back side sheet 112, and an absorber 103 interposed between the two sheets 111 and 112.
  • the surface side sheet 111 is obtained by laminating a top sheet 101, a second sheet 104, and a surface portion 132A of a cover sheet 1032 described later in this order.
  • the back side sheet 112 is formed by laminating the back side 132B of the covering sheet 1032 and the back sheet 102 in this order.
  • the back sheet 102 may be composed of one sheet (one layer), or may be composed of two, three, four, or more sheets.
  • As a form comprised by two sheets the form by which the liquid-impermeable waterproof sheet and the liquid-permeable exterior sheet were laminated
  • the waterproof sheet can be disposed only in the area where the absorber 103 exists, for example.
  • the absorber 103 is covered with a covering sheet 1032, and the absorber 103 is configured.
  • the shape of the absorber 103 is maintained by the covering sheet 1032.
  • the absorbent body 103 can have a planar hourglass shape with a narrow central portion in the front-rear direction.
  • the top sheet 101 and the back sheet 102 have the same shape as the planar outer shape of the disposable diaper 4, and the front and rear end portions and both side portions extend forward and rearward or laterally from the front and rear end edges or both side edges of the absorbent body 103. Yes.
  • the lateral extension of the top sheet 101 and the back sheet 102 is particularly long at the front and rear ends.
  • a fastening material such as a fastening tape (not shown) can be attached to the long extending portion (hereinafter also simply referred to as “extending portion”).
  • top sheet 101 and the back sheet 102 are joined at the extending portion.
  • the bonding method is not particularly limited. For example, hot melt bonding, ultrasonic sealing, heat sealing (thermal fusion), heat pressing (thermocompression bonding), or a combination thereof can be used.
  • the above-described microencapsulated fragrance 1 of the present invention (see FIG. 1) is applied to the urine receiving part (the part where the paper diaper 4 is urinated) and the toilet part (the part where the paper diaper 4 is defecation), respectively.
  • the urine receiving part the part where the paper diaper 4 is urinated
  • the toilet part the part where the paper diaper 4 is defecation
  • the abdominal side from a crotch region corresponds to a urine receiving part
  • a back side from a crotch region corresponds to a toilet part.
  • the microencapsulated fragrance 1 may fall off or cause rough skin according to this embodiment.
  • the surface 103a of the absorber 103 in this embodiment, between the absorber 103 and the surface portion 132A of the covering sheet 1032.
  • the urine storage recess 106A and the stool storage recess 106B are formed on the surface 103a (surface layer) of the absorber 103. It is also possible to provide the microencapsulated fragrance 1 in the recesses 106A and 106B.
  • a hot melt adhesive or the like is used to prevent the microencapsulated fragrance 1 from moving to the surface 103a of the absorbent body 103. It can be fixed with.
  • urine guide ports 107A and 107A and stool guidance leading to the concave portion 106A (the urine receiving portion of the absorber 103) and the concave portion 106B (the stool receiving portion of the absorber 103) are formed on the surface side sheet 111.
  • the ports 107B and 107B can also be formed.
  • urine can be separately stored in the urine storage recess 106A and stool can be stored in the stool storage recess 106B.
  • the surface side sheet 111 on which the guide ports 107A and 107B are formed becomes the surface portion 132A of the top sheet 101, the second sheet 104, and the covering sheet 1032 in the illustrated example.
  • the top sheet 101 only needs to have liquid permeability, and the same material as that of the surface side sheet 3c in FIG. 3 can be adopted.
  • it may be manufactured by any processing and manufactured by a known method such as a spunlace method, a spunbond method, a thermal bond method, a melt blown method, a needle punch method, etc. Can be exemplified.
  • the spun lace method is a preferable processing method for obtaining flexibility and drapeability
  • the thermal bond method is for obtaining bulkiness and softness.
  • the top sheet 101 may be composed of a single sheet or a laminated sheet obtained by bonding two or more sheets.
  • the top sheet 101 may be composed of one sheet or two or more sheets in the planar direction.
  • the second sheet 104 has a property of diffusing and transmitting body fluid. Therefore, the material of the second sheet 104 is sufficient if it exhibits this body fluid diffusion / permeability, and examples thereof include the same material as the top sheet 101. Among these, for example, spunlace, pulp non-woven fabric, mixed sheet of pulp and rayon, point bond or crepe paper are particularly preferable.
  • the second sheet 104 is particularly preferably one having better body fluid permeability than the top sheet 101 and having a fiber density lower than that of the top sheet 101, such as polypropylene, polyethylene, polyethylene terephthalate, polyamide, nylon, rayon, vinylon.
  • a non-woven fabric made of acrylic or the like is preferable.
  • the material of the covering sheet 1032 may be any material as long as it has liquid permeability, and the type thereof is not particularly limited.
  • the same material as exemplified as the top sheet 101 can be used.
  • a body fluid permeable sheet such as a crepe paper, a nonwoven fabric, or a perforated sheet can be used.
  • the back sheet 102 has liquid impermeability, and is substantially impermeable, for example, by interposing an olefin resin such as polyethylene or polypropylene, a laminated nonwoven fabric in which a nonwoven fabric is laminated on a polyethylene sheet, or a waterproof sheet.
  • olefin resin such as polyethylene or polypropylene
  • Non-woven fabrics such as exterior sheets that ensure liquid permeability (in this case, a liquid-impermeable back sheet 102 is composed of a waterproof sheet and non-woven fabrics such as exterior sheets).
  • materials having liquid impermeability and moisture permeability which have been used and used in recent years from the viewpoint of preventing stuffiness, can also be exemplified.
  • the sheet of the material having liquid impermeability and moisture permeability for example, a sheet is formed by kneading an inorganic filler in an olefin resin such as polyethylene or polypropylene, and then stretched in a uniaxial or biaxial direction.
  • an olefin resin such as polyethylene or polypropylene
  • FIG. 10 shows an example in which the fibrous base material 2 of FIG. 2 is configured as a cover for a colostomy pouch.
  • a resinous pouch 55 is mounted on a well-known mounting portion 56 to an artificial anus (not shown) built on the ostomate side, and the discharged feces are collected in the pouch 54.
  • the cover 5 has an opening formed on the upper side, and a cover main body 53 that accommodates the pouch 54 from the lower side (a notch 54 is formed to avoid interference with the mounting portion 56).
  • the flexible long members 51 and 52 each having one end coupled to the upper edge of the cover main body 53 are coupled to each other.
  • the cover body 53 is made of, for example, a cloth material made of hydrophilic fibers (for example, a work cloth or a nonwoven fabric made of cotton), and the microencapsulated fragrance 1 shown in FIG. 1 is fixed thereto.
  • the flexible long members 51 and 52 are also made of a fiber material (which may be made of hydrophilic fiber, but is not necessarily hydrophilic).
  • the pouch 54 When using, after attaching the pouch 54 to the colostomy, the pouch 54 is accommodated in the cover main body 53, and the flexible long members 51 and 52 are wound around the body of the ostomate to complete the attachment.
  • the joining method of both ends of the flexible long members 51 and 52 may be a joining method, or a detachable joining mechanism such as a hook-and-loop fastener. Even if the odor of feces discharged into the pouch 54 leaks out of the pouch 54, the discomfort of the odor is greatly reduced by the action of the scent control fragrance of the present invention fixed to the cover body 53. Can be suppressed.
  • FIG. 11 shows an embodiment of the pellet for suppressing stool odor according to the present invention.
  • the pellet 6 for suppressing stool odor has a porous ceramic pellet 61 as a base material.
  • the porous ceramic pellet 61 is a ceramic fired body such as alumina, for example, and the impregnation layer 3R of the fecal odor suppressing fragrance of the present invention is formed on the surface layer portion.
  • the porous ceramic pellet 61 has a large number of pores 62 communicating with the surface thereof.
  • a coating layer 63 of a faecal odor suppressing fragrance is formed on the inner surface of the pores 62 together with the surface of the pellet 61. Has been.
  • the fecal odor suppressing fragrance is in a liquid state and can be produced by immersing the porous ceramic pellet 61 in a solution obtained by dissolving it in a solvent such as alcohol and evaporating the solvent.
  • the porous ceramic pellet 61 is used by being filled in a pet toilet or the like, and mixed with the fecal odor suppression fragrance retained in the pores 62 when the stool is sprinkled, the malodor is suppressed.
  • the microencapsulated fragrance 1 is fixed on the surface of a ceramic pellet 71 (which may be porous or dense). This is also used by being filled in a pet toilet or the like, and when the manure is sprinkled, the core material in the microencapsulated fragrance 1 flows out and is mixed with the fecal odor suppressing fragrance, thereby suppressing the malodor.
  • FIG. 13 shows an example of a stool for suppressing stool odor, in which a scent for suppressing stool odor is filled in a spray container together with a compressed gas medium for spraying.
  • reference numeral 201 denotes a sealed container made of aluminum or a tin can.
  • the container 201 is provided with a bottomed cylindrical container body 201a and an inverted funnel-shaped upper part 201b integrally provided thereabove while the inner surface 201c is subjected to rust prevention treatment.
  • a push button type aerosol valve device 202 for atomizing the filled aerosol composition to the outside is provided in the upper central portion.
  • the upper part 201b may have a canopy structure that is generally well known. Further, the shape of the container 201 is not limited to the illustrated example.
  • the aerosol valve device 202 has a nozzle 203 that is movable up and down and is provided above the upper part of the push button 204, and an orifice and a main orifice provided below the push button 204 and above the inside of the container. And a well-known tilt action fixed quantity ejection valve 205 having the above.
  • a tube 206 is connected to the main orifice 205 a side of the valve 205.
  • the vertically moving structure of the push button 204 and the valve structure in which the stem orifice associated therewith opens and closes are well known.
  • the container 201 is filled with a fragrance 200A for suppressing stool odor according to the present invention and a compressed gas medium for spraying (for example, LPG / isopentane mixed injection gas) 200B.
  • the nozzle 203 is sprayed in the atomized state while the fragrance 200A for suppressing stool odor is entrained in the compressed gas medium 200B for spraying inside. It can act directly on feces and suppress its malodor.
  • the microencapsulated fragrance 1 may be filled together with the compressed gas medium 200C for spraying as shown in FIG.
  • the microencapsulated fragrance 1 can be sprayed toward the object.
  • a fixing agent for example, dextrin
  • a fixing agent for example, dextrin
  • for fixing the capsule wall material 1w on the surface of the material to be sprayed may be filled together with the microencapsulated fragrance 1 and the compressed gas medium 200C for spraying.
  • the bottle body 92 is filled with a liquid agent 9A (a liquid fragrance or a solvent dilution thereof, or a dispersion of microencapsulated fragrance) containing a stool for suppressing stool odor.
  • the pump nozzle head 91 is fitted to the upper portion of the bottle body 92 while the suction tube 93 is submerged in the bottle body 92. When the pump nozzle head 91 is pressed in this state, the liquid agent is sprayed from the nozzle by a known pump suction mechanism.
  • Table 1 summarizes the perfume composition by component attribute that characterizes the present invention for each perfume formulation used in Examples 1 to 12 and Comparative Examples 1 and 2 below.
  • Example 1 According to the formulation shown in Table 2, a scent for suppressing fecal odor (fragrance) according to the present invention, in which a grassy-like modulated plant aroma was obtained, was prepared.
  • Table 3 shows the detailed composition of the apple base in Table 2.
  • fecal odor model dimethylsulfide (0.1%), isovaleric acid (0.2%), dimethyldisulfide (0.2%), butyric acid (0.3%), indole ( 0.5%) and a mixture of dipropylene glycol (98.7%).
  • the fecal odor model is based on that described in the chapter on feces and urine in the book “Odor Odorology (Human Body)” (author: Takashi Suzuki, East Press, Inc., 2000).
  • flavor) for the fecal odor suppression of the grassy-like scent of Table 2 is prepared, and the 1% ethanol solution (fecal odor solution) of the fecal odor model is included in each solution in various proportions.
  • the solution was put in an atomizer and sprayed twice on commercial kitchen paper cut into 6 cm square.
  • 15 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor ceased, and compared with the presence or absence of the masking effect on the stool odor and the modulation effect (the scent without adding the stool odor) And whether or not it has transformed into a deep, elegant and noble fragrance).
  • the results are shown in Table 4.
  • the masking effect whether or not the fecal odor was felt
  • the determination results of each subject are individually shown.
  • the modulation effect the determination result with the largest number of subjects is shown as a representative.
  • the fragrance of Example 1 not only has an excellent masking effect even when the concentration of the stool odor solution is as high as 30% or more, but is clear when the concentration of the stool odor solution is 10% or more. It can be seen that the modulation effect is recognized. If the concentration of the stool odor solution is too high, the presence of a stool odor is clearly felt even if the modulation effect by the fragrance is taken into consideration. Conversely, if the concentration of the stool odor solution is too low, Since the odor level itself is low, the masking effect by the fragrance becomes excessive, and the fragrance itself is felt excessively strong. By the way, when the concentration of the fecal odor solution was 10%, many subjects commented that the change in scent was clearly felt.
  • Example 2 The fragrance (fragrance
  • a 10% ethanol solution of a fragrance (fragrance) for suppressing fecal odor with a forest-like scent in Table 5 was prepared, and a 1% ethanol solution (fecal odor solution) of the same fecal odor model as in Example 1 was added to each solution. After mixing at various ratios, the solution was placed in an atomizer and sprayed twice onto commercial kitchen paper cut into 6 cm squares. Then, 15 subjects sniff the scent remaining on the sprayed paper when the ethanol odor ceased, and conduct sensory evaluation judgments on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. The results are shown in Table 6.
  • the fragrance of Example 2 not only has an excellent masking effect in a wide range of the stool odor solution concentration of 1% to 40%, but is also clear when the stool odor solution concentration is 5% or more. It can be seen that the modulation effect is recognized. In particular, when the concentration of the stool odor solution was 10%, many subjects commented that the change in scent was clearly felt.
  • Example 3 The fragrance (fragrance
  • a 10% ethanol solution of the fragrance for faecal odor control (fragrance) with a soap-like scent in Table 7 was prepared, and a 1% ethanol solution (fecal odor solution) of the same fecal odor model as in Example 1 was added to each solution. After mixing at various ratios, the solution was placed in an atomizer and sprayed twice onto commercial kitchen paper cut into 6 cm squares. And 9 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor disappeared, and sensory evaluation judgment was performed on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. Table 8 shows the above results.
  • the fragrance of Example 3 has an excellent masking effect when the concentration of the fecal odor solution is in the range of 1% to 20%. It can also be seen that a relatively good modulation effect is observed when the concentration of the fecal odor solution is in the range of 2.5% to 20%.
  • Example 4 According to the formulation shown in Table 9, a scent for suppressing fecal odor (fragrance) according to the present invention, in which a soap-like modulated vegetable aroma different from Example 3 was obtained, was prepared.
  • a 10% ethanol solution of the scent of scent of faecal scent with a soap-like scent (fragrance) in Table 9 was prepared, and a 1% ethanol solution (fecal odor solution) of the same stool model as in Example 1 was added to each solution. After mixing at various ratios, the solution was placed in an atomizer and sprayed twice onto commercial kitchen paper cut into 6 cm squares. And 9 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor disappeared, and sensory evaluation judgment was performed on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. Table 10 shows the above results.
  • the fragrance of Example 4 has an excellent masking effect when the concentration of the fecal odor solution is in the range of 1% to 10%. It can also be seen that a relatively good modulation effect is observed when the concentration of the fecal odor solution is in the range of 2.5% to 30%.
  • Example 5 The fragrance (fragrance
  • the detailed composition of the jasmine base in Table 11 is shown in Table 12, and the detailed composition of the rose base is shown in Table 13, respectively.
  • this prescription does not contain the harmony fragrance
  • a 10% ethanol solution of the scent of faecal odor with a soap-like fragrance (fragrance) in Table 11 was prepared, and a 1% ethanol solution (fecal odor solution) of the same stool odor model as in Example 1 was added to each solution. After mixing at various ratios, the solution was placed in an atomizer and sprayed twice onto commercial kitchen paper cut into 6 cm squares. And 9 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor disappeared, and sensory evaluation judgment was performed on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. The above results are shown in Table 14.
  • the fragrance of Example 5 has an excellent masking effect when the concentration of the fecal odor solution is in the range of 1% to 20%. It can also be seen that a relatively good modulation effect is observed when the concentration of the fecal odor solution is in the range of 2.5% to 20%.
  • Example 6 The fragrance (fragrance
  • a 10% ethanol solution of the scent of scent with the soapy scent of this table 15 (fragrance) was prepared, and a 1% ethanol solution (fecal odor solution) of the same stool model as in Example 1 was added to each solution. After mixing at various ratios, the solution was placed in an atomizer and sprayed twice onto commercial kitchen paper cut into 6 cm squares. And 9 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor disappeared, and sensory evaluation judgment was performed on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. The above results are shown in Table 16.
  • the fragrance of Example 6 has an excellent masking effect when the concentration of the fecal odor solution is in the range of 1% to 20%. It can also be seen that a relatively good modulation effect is observed when the concentration of the fecal odor solution is in the range of 5% to 30%.
  • Example 7 The fragrance (fragrance
  • a 10% ethanol solution of a scent for suppressing stool odor (fragrance) in Table 17 was prepared, and 1% ethanol solution (stool scent solution) of the same stool odor model as in Example 1 was mixed in each solution in various proportions. Then, the solution was put in an atomizer and sprayed twice on a commercial kitchen paper cut into 6 cm square. And 9 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor disappeared, and sensory evaluation judgment was performed on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. The above results are shown in Table 18.
  • the fragrance of Example 7 has an excellent masking effect in the range of the fecal odor solution concentration from 1% to 10%. It can also be seen that a relatively good modulation effect is observed when the concentration of the fecal odor solution is in the range of 5% to 10%.
  • Example 8 The fragrance (fragrance
  • a 10% ethanol solution of a scent for suppressing stool odor (fragrance) in Table 19 was prepared, and 1% ethanol solution (stool odor solution) of the same stool odor model as in Example 1 was mixed in each solution in various proportions. Then, the solution was put in an atomizer and sprayed twice on a commercial kitchen paper cut into 6 cm square. And 9 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor disappeared, and sensory evaluation judgment was performed on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. The results are shown in Table 20.
  • the fragrance of Example 8 has an excellent masking effect when the concentration of the fecal odor solution is in the range of 1% to 10%. It can also be seen that a relatively good modulation effect is observed when the concentration of the fecal odor solution is in the range of 5% to 20%.
  • Example 9 The fragrance (fragrance
  • a 10% ethanol solution of the scent for suppressing fecal odor (fragrance) in Table 21 was prepared, and 1% ethanol solution (fecal odor solution) of the same fecal odor model as in Example 1 was mixed in each solution in various proportions. Then, the solution was put in an atomizer and sprayed twice on a commercial kitchen paper cut into 6 cm square. And 9 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor disappeared, and sensory evaluation judgment was performed on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. Table 22 shows the above results.
  • the fragrance of Example 9 has an excellent masking effect when the concentration of the fecal odor solution is in the range of 1% to 20%. It can also be seen that a relatively good modulation effect is observed when the concentration of the fecal odor solution is in the range of 5% to 10%.
  • Example 10 The fragrance (fragrance
  • a 10% ethanol solution of the scent for suppressing fecal odor (fragrance) in Table 23 was prepared, and 1% ethanol solution (fecal odor solution) of the same fecal odor model as in Example 1 was mixed in each solution in various proportions. Then, the solution was put in an atomizer and sprayed twice on a commercial kitchen paper cut into 6 cm square. And 9 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor disappeared, and sensory evaluation judgment was performed on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. The results are shown in Table 24.
  • the fragrance of Example 10 has an excellent masking effect when the concentration of the fecal odor solution is in the range of 1% to 30%. It can also be seen that although the concentration of the fecal odor solution is in a narrow range around 5%, a relatively good modulation effect is observed.
  • Example 11 The fragrance (fragrance
  • a 10% ethanol solution of the scent for suppressing stool odor (fragrance) in Table 25 was prepared, and 1% ethanol solution (stool scent solution) of the same stool odor model as in Example 1 was mixed in each solution in various proportions. Then, the solution was put in an atomizer and sprayed twice on a commercial kitchen paper cut into 6 cm square. And 9 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor disappeared, and sensory evaluation judgment was performed on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. The results are shown in Table 26.
  • the fragrance of Example 11 has an excellent masking effect when the concentration of the fecal odor solution is in the range of 1% to 20%. It can also be seen that although the concentration of the fecal odor solution is in a narrow range around 5%, a relatively good modulation effect is observed.
  • Example 12 The fragrance (fragrance
  • a 10% ethanol solution of the scent suppressing fragrance (fragrance) in Table 27 was prepared, and 1% ethanol solution (fecal odor solution) of the same stool odor model as in Example 1 was mixed in each solution in various proportions. Then, the solution was put in an atomizer and sprayed twice on a commercial kitchen paper cut into 6 cm square. And 9 subjects sniff the scent remaining on the sprayed paper at the time when the ethanol odor disappeared, and sensory evaluation judgment was performed on the presence or absence of masking effect on fecal odor and the presence or absence of modulation effect Performed as in Example 1. The results are shown in Table 28.
  • the fragrance of Example 11 has an excellent masking effect when the concentration of the fecal odor solution is in the range of 1% to 20%. It can also be seen that although the concentration of the fecal odor solution is in a narrow range around 5%, a relatively good modulation effect is observed.
  • Comparative Example 1 The fragrance (fragrance) of Comparative Example 1 was prepared according to the formulation shown in Table 29.
  • Comparative Example 2 The fragrance (fragrance) of Comparative Example 2 was prepared according to the formulation shown in Table 31.
  • Example 13 About 0.5 g of the polymer absorbent material is put in a cap cap made of plastic having an inner diameter of about 4.5 cm, and 3.0 g of the same fecal odor model (10% dipropylene glycol solution) as in Example 1 is absorbed therein. It was. The cap top surface was covered with gauze and fixed with tape. The cap was placed in a glass petri dish having an inner diameter of about 8 cm, capped with a glass petri dish having an inner diameter of about 9 cm, and allowed to stand at room temperature for about 1 hour. Next, the fragrance undiluted solution used in Examples 1 to 6 was evenly dropped onto a commercial kitchen paper cut into 5 cm squares, and a 5 cm square kitchen paper was put on top of it and placed in a petri dish.
  • the fragrances of Examples 1 to 6 according to the present invention are included in the kitchen paper, and the absorbent that holds the stool odor is covered, thereby masking the stool odor that leaks through the kitchen paper. It can be seen that the modulation effect is sufficiently exhibited. In particular, the fragrance of Example 2 showed a strong effect in a small amount.
  • Example 14 About 1.5 g of the polymer absorbent material was put on the outside of a glass petri dish having an inner diameter of about 8 cm, and the fragrance stock solution used in Examples 1 and 2 was dropped evenly. Next, the lid was capped with a petri dish made of glass having an inner diameter of about 9 cm and allowed to stand at room temperature for about 15 minutes. Next, 0.2 g of the polymer absorbent material was pushed into a cap lid made of plastic with an inner diameter of about 2 cm, and 2.5 g of the same fecal odor model (10% dipropylene glycol solution) as in Example 1 was absorbed. The cap lid was placed in the center of the petri dish, and the petri dish was capped again.
  • the lid of the petri dish was opened at any time, and evaluation was performed by sniffing from about 10 cm above the center of the petri dish. In this procedure, the operation of smelling was repeated 10 times or more per day. The amount of the two types of fragrances used, the time until the fecal odor was undetected, and the number of days in which the scent was not detected were evaluated. The results are shown in Table 34.

Abstract

La présente invention concerne une fragrance destinée à supprimer les odeurs fécales qui permet, lorsqu'on sent des odeurs fécales, de les incorporer sous la forme d'un composant de la fragrance et de les convertir en une meilleure senteur, qui ne peut pas être obtenue avec des agents aromatiques conventionnels ou équivalents. De plus, la composition de la formulation de la fragrance est simple. La fragrance est préparée en suivant une formulation différentielle dans laquelle seul le composant de parfum mis en évidence est éliminé d'une formulation cible pour la fragrance principale à base de plantes comprenant : un composant de parfum dominant ayant une senteur florale ; un composant de parfum de modulation comprenant un parfum d'animal ayant une odeur d'animal ou une senteur à base de gras et modulant la senteur florale basée sur le composant de parfum dominant de sorte à la mélanger à la senteur de la peau humaine, formant une senteur modulée à base de plantes ; et le composant de parfum mis en évidence précité comprenant un parfum d'animal ayant une odeur fécale et soulignant et renforçant la forte odeur dégagée par la senteur modulée à base de plantes. Bien que l'odeur de la senteur modulée à base de plantes seule soit plus faible que la fragrance principale à base de plantes selon la formulation cible, lorsqu'une odeur fécale est cachée par une senteur modulée à base de plantes, l'odeur fécale est incorporée sous la forme d'un composant de substitution pour le composant de parfum mis en évidence, et l'odeur de la senteur modulée à base de plantes ressort.
PCT/JP2012/069489 2011-08-01 2012-07-31 Fragrance destinée à supprimer les odeurs fécales, fragrance encapsulée dans des microcapsules utilisant celle-ci, textile pouvant supprimer les odeurs fécales, pastilles destinées à supprimer les odeurs fécales, pulvérisation d'une fragrance encapsulée dans des microcapsules, et dispositif de pulvérisation d'un parfum destiné à supprimer les odeurs fécales WO2013018805A1 (fr)

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JP2018108192A (ja) * 2016-12-28 2018-07-12 小林製薬株式会社 芳香剤組成物
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JP2019162346A (ja) * 2018-03-20 2019-09-26 日油株式会社 アスファルト用消臭剤
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