WO2010125847A1 - 液晶パネルの製造方法、液晶パネル用ガラス基板およびこれを備えた液晶パネル - Google Patents
液晶パネルの製造方法、液晶パネル用ガラス基板およびこれを備えた液晶パネル Download PDFInfo
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- WO2010125847A1 WO2010125847A1 PCT/JP2010/052849 JP2010052849W WO2010125847A1 WO 2010125847 A1 WO2010125847 A1 WO 2010125847A1 JP 2010052849 W JP2010052849 W JP 2010052849W WO 2010125847 A1 WO2010125847 A1 WO 2010125847A1
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- liquid crystal
- crystal panel
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- film
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/136—Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
- G02F1/1362—Active matrix addressed cells
- G02F1/1368—Active matrix addressed cells in which the switching element is a three-electrode device
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/133374—Constructional arrangements; Manufacturing methods for displaying permanent signs or marks
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/133388—Constructional arrangements; Manufacturing methods with constructional differences between the display region and the peripheral region
Definitions
- the present invention relates to a manufacturing method of a liquid crystal panel including a step of marking various information on a marking pad provided on a glass substrate for a liquid crystal panel by laser marking, and a liquid crystal provided with a marking pad including a marking region suitable for laser marking.
- the present invention relates to a glass substrate for a panel and a liquid crystal panel provided with the same.
- a liquid crystal panel is suitably used for a liquid crystal television as a display device, a display of a personal computer, and the like, and in recent years, there has been a remarkable spread.
- Various information such as serial information and application information is marked on the liquid crystal panel because of the necessity for management during production and the necessity for maintenance after shipment.
- laser marking is preferably used for this marking, and the above-mentioned various information is marked by irradiating a glass substrate for a liquid crystal panel, which is a component part of the liquid crystal panel, in the production process.
- a method of marking various kinds of information on a glass substrate for a liquid crystal panel using laser marking for example, a method of marking by irradiating a laser beam onto an ITO (Indium Thin Oxide) film formed on the surface of a glass substrate (special Refer to Kaihei 6-51328 (Patent Document 1) and a method of marking an alignment film formed on the surface of a glass substrate by irradiating a laser beam (Japanese Patent Laid-Open No. 10-278422 (Patent Document 2)).
- a method of marking by irradiating a metal film formed on the surface of a glass substrate with laser light is known.
- the metal film is formed on the peripheral portion of the glass substrate that does not become the liquid crystal display portion.
- a marking pad is provided, and a laser beam is irradiated on the marking pad to form a through hole in the marking pad, whereby the glass substrate is marked.
- the various information marked in this way is marked on the glass substrate as a two-dimensional data code obtained by converting the information into a data matrix, and the information is read out using either a reflection type or transmission type camera. It is.
- JP-A-6-51328 Japanese Patent Laid-Open No. 10-278422
- the following two types of process flows are envisaged when marking a metal film formed on a glass substrate for a liquid crystal panel by irradiating a laser beam.
- the first process flow is called single plate processing, where a TFT (Thin Film Transistor) substrate, which is a glass substrate on which marking is performed, and a CF (Color Filter) substrate, to which a color filter is attached, are bonded together.
- TFT Thin Film Transistor
- CF Color Filter
- the marking pad is directly irradiated with laser light, so that it passes through the quality of the marking to be formed (that is, the shape and size of the through hole, the darkness of the periphery of the through hole, etc.). It can be suitable for readout using a type or reflection type camera.
- the laser marking process is performed after the TFT substrate and the CF substrate are bonded together, so that the number of TFT substrates and CF substrates manufactured in parallel can be managed in a balanced manner. This makes it possible to obtain an effect that enables efficient production of a liquid crystal panel.
- the marking pad when the marking pad is formed of a metal film, various processes such as a film forming process for forming a TFT and an etching process may be performed after the metal film is formed. .
- the metal film constituting the marking pad may be corroded and deteriorated during the film forming process or the etching process.
- the quality of the marking to be formed becomes low quality with the deterioration of the marking pad, and reading using the above-described transmission type or reflection type camera occurs. Result in a recognition error.
- an object of the present invention is to provide a method for manufacturing a liquid crystal panel that can effectively prevent a marking pad including a metal film provided on a glass substrate for a liquid crystal panel from corroding during the production process of the liquid crystal panel. .
- Another object of the present invention is to provide a glass substrate for a liquid crystal panel and a liquid crystal panel provided with a marking pad suitable for laser marking processing.
- the method for manufacturing a liquid crystal panel according to the present invention includes the following steps (A) to (G).
- An insulating film is formed on the main surface of the glass substrate for a liquid crystal panel and patterned to form a TFT gate insulating film in the portion that becomes the liquid crystal display portion, and the marking in the peripheral portion.
- a protective insulating film in contact with the lower layer so as to cover the lower layer of the pad;
- D A step of performing various film forming processes and patterning processes in the portion that becomes the liquid crystal display portion and the peripheral portion while maintaining the state in which the lower layer of the marking pad is covered with the protective insulating film.
- E A step of exposing a main surface excluding a peripheral edge of the lower layer of the marking pad by removing a part of the protective insulating film and at least a part of various films formed thereon.
- F By forming an ITO film on the main surface of the glass substrate for a liquid crystal panel and patterning it, a pixel electrode is formed in the portion that becomes the liquid crystal display portion, and the protective insulating film is formed in the peripheral portion.
- the step (B) of forming the lower layer of the gate electrode and the marking pad described above includes the step of sequentially laminating a plurality of metal films of different materials. May be.
- the liquid crystal panel manufacturing method according to the present invention may further include the following step (H). (H) Anodizing the main surfaces of the lower layer of the gate electrode and the marking pad.
- the glass substrate for a liquid crystal panel according to the present invention includes a portion that becomes a liquid crystal display portion and a peripheral portion that does not become a liquid crystal display portion.
- a TFT is provided on the main surface of the portion that becomes the liquid crystal display portion.
- the TFT includes a metal film as a gate electrode, an insulating film as a gate insulating film, and an ITO film as a pixel electrode. Contains.
- a marking pad for marking by irradiating laser light is provided, and the marking pad is composed only of a metal film as a lower layer and an ITO film as an upper layer.
- It has a marking region made of a laminated body constituted and a peripheral region including an insulating film covering the periphery of the metal film as the lower layer.
- the metal film as the gate electrode and the metal film as the lower layer are formed at the same time in one step, and the insulating film as the gate insulating film and the insulating film constituting the surrounding region are:
- the ITO film as the pixel electrode and the ITO film as the upper layer are formed at the same time in one process.
- the lower layer of the gate electrode and the marking pad may be composed of a laminated film of a plurality of metal films made of different materials.
- the main surface of the lower layer of the gate electrode and the marking pad may be anodized.
- the liquid crystal panel according to the present invention includes any one of the glass substrates for liquid crystal panels described above.
- a marking pad including a metal film provided on a glass substrate for a liquid crystal panel is effectively prevented from corroding during the production process of the liquid crystal panel.
- a glass substrate for liquid crystal panel and a liquid crystal panel provided with a marking pad suitable for laser marking processing can be obtained.
- FIG. 1 is a schematic plan view of a liquid crystal panel according to an embodiment of the present invention
- FIG. 2 is a schematic enlarged view of an information recording unit of the liquid crystal panel shown in FIG.
- FIG. 3 is a schematic cross-sectional view of the liquid crystal panel shown in FIG.
- the liquid crystal panel 1 in the present embodiment mainly includes a TFT substrate 10, a CF substrate 20, a seal member 30, and a liquid crystal 32.
- the liquid crystal panel 1 in the present embodiment is a so-called active matrix type liquid crystal panel in which a plurality of display pixels arranged in a matrix are individually controlled by TFTs provided in the display pixels.
- the TFT substrate 10 is also called an active matrix substrate, and includes a glass substrate 11 as a base material, a plurality of TFTs 40 formed on the main surface 11a, and a plurality of pixel electrodes 46 electrically connected to the TFTs 40.
- the TFT substrate 10 includes a portion A that becomes a liquid crystal display portion for displaying an image and a peripheral portion B that does not become the liquid crystal display portion.
- the plurality of TFTs 40 and the pixel electrodes 46 described above are liquid crystal displays. Arranged in a matrix in the portion A to be the display section.
- the TFT substrate 10 (in some cases, the glass substrate 11 as a base material of the TFT substrate 10) corresponds to the glass substrate for the first liquid crystal panel.
- the CF substrate 20 is also called a counter substrate, and includes a glass substrate 21 as a base material, a color filter (not shown) attached on the main surface thereof, and a counter electrode (not shown) formed on the color filter. ).
- the CF substrate 20 has only a portion that becomes a liquid crystal display portion.
- the color filter is affixed to the portion of the glass substrate 21 that becomes the liquid crystal display portion, and the plurality of counter electrodes described above are arranged in a matrix on the main surface of the color filter.
- the CF substrate 20 (in some cases, the glass substrate 21 as a base material of the CF substrate 20) corresponds to the second liquid crystal panel glass substrate.
- the TFT substrate 10 and the CF substrate 20 are bonded to each other with a predetermined distance (for example, about 5 ⁇ m) by the seal member 30.
- the seal member 30 is provided so as to surround the liquid crystal display portion, and the liquid crystal 32 is sealed in a space surrounded by the seal member 30 and sandwiched between the TFT substrate 10 and the CF substrate 20.
- the liquid crystal 32 has a property of changing the light transmittance according to the applied voltage.
- the liquid crystal 32 includes a pixel electrode 46 provided on the TFT substrate 10 described above and a counter electrode provided on the CF substrate 20 described above. Located between. Note that an alignment film (not shown) is provided on the portion of the TFT substrate 10 and the CF substrate 20 facing the liquid crystal 32.
- An information recording unit 2 in which various kinds of information are recorded is provided at a predetermined position of the peripheral portion B that does not become a liquid crystal display unit of the TFT substrate 10.
- the information recording unit 2 includes a marking pad 50 on which various types of information are recorded in a two-dimensional data code, and a character data unit 60 on which various types of information are recorded as character data.
- the marking pad 50 in which various types of information are recorded in a two-dimensional data code is recorded by providing a through hole 58 in the marking pad 50 by performing laser marking processing described later. .
- the TFT 40 is provided on the main surface 11 a of the glass substrate 11 in the portion A that becomes the liquid crystal display portion of the TFT substrate 10.
- the TFT 40 includes a gate electrode 41 electrically connected to the gate wiring, a gate insulating film 42 formed so as to cover the gate electrode 41, and a first electrode formed above the gate electrode 41 with the gate insulating film 42 interposed therebetween.
- the gate electrode 41 is composed of a single layer metal film such as aluminum (Al), copper (Cu), tantalum (Ta), titanium (Ti) or the like.
- the gate insulating film 42 is formed of a single-layer or multi-layer insulating film such as silicon nitride (SiNx) or silicon oxide (SiOx).
- the first semiconductor layer 43 is formed of an intrinsic semiconductor film such as amorphous silicon.
- the second semiconductor layer 44 is composed of an impurity-added semiconductor film such as n + type amorphous silicon.
- the second semiconductor layer 44 functions as a contact layer between the first semiconductor layer 43 and the source electrode 45a and between the first semiconductor layer 43 and the drain electrode 45b.
- the source electrode 45a and the drain electrode 45b are composed of a single-layer or multi-layer metal film such as aluminum, copper, tantalum, or titanium.
- the pixel electrode 46 is made of, for example, an ITO film (that is, a mixed film of indium oxide (In 2 O 3 ) and tin oxide (SnO 2 )).
- a marking pad 50 is provided on the main surface 11 a of the glass substrate 11 in the peripheral portion B that does not become the liquid crystal display portion of the TFT substrate 10.
- the marking pad 50 has a marking area C where marking is performed and a surrounding area D surrounding the marking area C.
- the marking area C includes a metal film as the lower layer 51 and an ITO film as the upper layer 56.
- the periphery of the metal film as the lower layer 51 is covered with the protective insulating film 52 in the surrounding region D, and the first semiconductor is further formed on the protective insulating film 52.
- a first coating film 53 made of a layer, a second coating film 54 made of a second semiconductor layer, and a third coating film 55 made of a metal film are located.
- the metal film as the lower layer 51 is composed of a single-layer metal film such as aluminum, copper, tantalum, or titanium.
- the main surface of the metal film as the lower layer 51 (that is, the surface in contact with the upper layer 56) may be anodized.
- the lower layer 51 in the marking region C of the marking pad 50 is formed at the same time as the gate electrode 41 of the TFT 40 described above, and the material and film thickness thereof are the same as the metal film constituting the gate electrode 41 of the TFT 40. It is.
- the upper layer 56 in the marking region C of the marking pad 50 is formed at the same time as the pixel electrode connected to the TFT 40 described above, and the material and film thickness thereof are ITO constituting the pixel electrode 46 connected to the TFT 40. Identical to the membrane.
- the protective insulating film 52 located in the peripheral region D of the marking pad 50 is formed at the same time as the gate insulating film 42 of the TFT 40 described above, and the material and film thickness thereof are the same as the gate insulating film 42 of the TFT 40. .
- the first coating film 53 and the second coating film 54 located in the peripheral region D of the marking pad 50 are formed simultaneously with the first semiconductor layer 43 and the second semiconductor layer 44 of the TFT 40 described above, respectively.
- the material and film thickness are the same as those of the first semiconductor layer 43 and the second semiconductor layer 44 of the TFT 40, respectively.
- the third coating film 55 located in the peripheral region D of the marking pad 50 is formed at the same time as the source electrode 45a and the drain electrode 45b of the TFT 40 described above, and the material and film thickness thereof are the source electrode 45a of the TFT 40. And the drain electrode 45b.
- a plurality of through holes 58 penetrating the ITO film as the upper layer 56 and the metal film as the lower layer 51 are provided.
- This through hole 58 is obtained by converting various information such as serial information and application information into a two-dimensional data code, and the information is read out using a transmission type or reflection type camera.
- FIG. 4 is a flowchart for explaining a method for manufacturing a liquid crystal panel according to the present embodiment.
- FIGS. 5A to 8 show production when a liquid crystal panel is manufactured according to the method for manufacturing a liquid crystal panel according to the present embodiment. It is a schematic cross section in the process. Next, with reference to FIGS. 4 to 8, a method for manufacturing the liquid crystal panel in the present embodiment will be described.
- the TFT substrate 10 is manufactured (step S101), and the CF substrate 20 paired with the TFT substrate 10 is manufactured (step S102). ) Are performed concurrently.
- the CF substrate 20 is manufactured, a glass substrate 21 is prepared, a color film is attached thereto, a counter electrode is formed, and an alignment film is further formed, whereby the CF substrate 20 is manufactured.
- the following processing is specifically performed.
- a glass substrate 11 including a portion A that becomes a liquid crystal display portion and a peripheral portion B that does not become a liquid crystal display portion is prepared.
- the gate electrode 41 of the TFT 40 is formed in the portion A that becomes the display portion, and the lower layer 51 of the marking pad 50 is formed in the peripheral portion B.
- an aluminum film is formed on the main surface 11a of the glass substrate 11 by using, for example, a sputtering method, and this is patterned by using a photolithography method to form the gate electrode 41 and the lower layer 51.
- the etching process in the photolithography method for example, dry etching using BCl 3 + Cl 2 , CF 4 (+ O 2 ), or the like can be used.
- the main surface of the formed aluminum film may be anodized as necessary.
- an insulating film is formed on the main surface 11a of the glass substrate 11 and patterned to form a gate insulating film 42 of the TFT 40 in the portion A that becomes the liquid crystal display portion.
- a protective insulating film 52 of the marking pad 50 is formed in the peripheral portion B. More specifically, for example, a silicon nitride film is formed on the main surface 11a of the glass substrate 11 using a PECVD (Plasma Enhanced Chemical Vapor Deposition) method, which is patterned using a photolithography method to form the gate insulating film 42 and A protective insulating film 52 is formed.
- PECVD Pullasma Enhanced Chemical Vapor Deposition
- an amorphous silicon layer is formed on the main surface 11a of the glass substrate 11 and patterned, so that the first semiconductor layer 43 and the second semiconductor are formed in the portion A that becomes the liquid crystal display portion.
- the layer 44 is formed, and the first semiconductor layer as the first coating film 53 and the second semiconductor layer as the second coating film 54 are formed in the peripheral portion B.
- the second semiconductor layer 44 and the second coating film 54 are shaped to cover the entire main surface of the first semiconductor layer 43 and the entire main surface of the first coating film 53, respectively. It is formed by ion implantation using an ion implantation method as appropriate in the upper layer portion of the layer.
- the etching process at the time of patterning for example, dry etching using CF 4 + O 2 , CCl 4 + O 2 , SF 6 or the like can be used.
- a metal film is formed on the main surface 11a of the glass substrate 11 and patterned, so that the source electrode 45a and the drain electrode 45b of the TFT 40 are formed in the portion A that becomes the liquid crystal display portion.
- the third coating film 55 is formed in the peripheral portion B. More specifically, for example, an aluminum film is formed on the main surface 11a of the glass substrate 11 using a sputtering method, which is patterned using a photolithography method to form a source electrode 45a, a drain electrode 45b, and a third coating film. 55 is formed.
- etching process in the photolithography method for example, dry etching using BCl 3 + Cl 2 , CF 4 (+ O 2 ), or the like can be used.
- the channel portion is formed in the first semiconductor layer 43 by etching and patterning the second semiconductor layer 44 using the source electrode 45a and the drain electrode 45b as a mask.
- the etching process at the time of patterning for example, dry etching using CF 4 + O 2 , CCl 4 + O 2 , SF 6 or the like can be used.
- portions of the protective insulating film 52 and the first to third coating films 53 to 55 formed in the peripheral portion B are etched and removed.
- a recess 57 having the bottom surface of the main surface of the metal film as the lower layer 51 is formed.
- the main surface of the lower layer 51 corresponding to the marking region C is exposed.
- an ITO film is formed on the main surface 11a of the glass substrate 11 and patterned, whereby the pixel electrode 46 that is electrically connected to the TFT 40 in the portion A that becomes the liquid crystal display portion. And the upper layer 56 of the marking pad 50 is formed in the peripheral portion B. More specifically, an ITO film is formed on the glass substrate 11 by using, for example, a sputtering method, and is patterned by using a photolithography method to form the pixel electrode 46 and the upper layer 56. As an etching process in the photolithography method, for example, wet etching using HCl + HNO 3 or the like can be used.
- the TFT substrate 10 manufactured in step S101 and the CF substrate 20 manufactured in step S102 are bonded together (step S103).
- a seal member 30 is disposed so as to surround a portion A that becomes a liquid crystal display portion of the TFT substrate 10, and the CF substrate 20 is positioned so as to be in contact with the seal member 30.
- the TFT substrate 10 and the CF substrate 20 are bonded together by being disposed so as to face the TFT substrate 10 and the seal member 30 being cured.
- the sealing member 30 to be used a thermosetting sealing material, a photo-curing sealing material, a combination thereof, or the like can be used.
- the glass substrate 11 that is the base material of the TFT substrate 10 and the glass substrate 21 that is the base material of the CF substrate 20 are both made of a mother glass substrate. Therefore, after the CF substrate 20 is bonded to the TFT substrate 10, the portion that does not become the liquid crystal display portion of the CF substrate 20 is located opposite to the peripheral portion B that does not become the liquid crystal display portion of the TFT substrate 10. That is, the CF substrate 20 is disposed so as to face the main surface of the marking region C of the marking pad 50 formed in the peripheral portion B that does not become the liquid crystal display portion of the TFT substrate 10 with a distance.
- the laser marking process is performed by irradiating the laser beam (step S104).
- the laser beam 100 is irradiated from the CF substrate 20 side to the marking region C of the marking pad 50 through the CF substrate 20.
- a fundamental wave (wavelength 1064 nm) of a YVO 4 laser which is a general YAG (yttrium, aluminum, garnet) laser beam or a neodymium-added YAG laser beam is preferably used.
- the upper layer 56 and the lower layer 51 constituting the marking region C of the marking pad 50 in the portion irradiated with the laser beam 100 are locally heated and sublimated, and a through-hole penetrating the upper layer 56 and the lower layer 51. 58 is formed.
- step S105 various processes such as a process of enclosing the liquid crystal 32 are performed.
- step S106 the TFT substrate 10 and the CF substrate 20 are divided along the dividing line E1 shown in FIG. 8
- step S107 the manufacture of the liquid crystal panel 1 shown in FIGS. 1 and 3 is completed.
- the film is already formed during the etching process or the film forming process performed on the TFT substrate 10 to manufacture the TFT 40.
- the metal film as the lower layer 51 of the marking pad 50 thus made can be always protected by the protective insulating film 52. Therefore, it is possible to reliably prevent the lower layer 51 of the marking pad 50 from being corroded and deteriorated by the etching gas or the etching solution during the etching process or the film forming process.
- the marking pad 50 provided on the TFT substrate 10 is irradiated with the laser light 100 through the CF substrate 20 (that is, the double plate processing). Even when the operation is performed), it is possible to perform high-quality marking.
- the high quality means a quality suitable for reading out information using a reflection type or transmission type camera.
- the quality of the through hole 58 formed by the irradiation of the laser beam 100 is defined. This means that the shape and size, the darkness of the periphery of the through hole 58, etc. are suitable for detection.
- the marking to be formed is low quality, when reading information using a reflective or transmissive camera, a two-dimensional data code read error occurs and the information differs from the original information.
- the formed marking is of high quality as in the present embodiment, information is read correctly without causing a read error.
- the liquid crystal panel 1 by manufacturing the liquid crystal panel 1 according to the method for manufacturing a liquid crystal panel in the present embodiment, the above-described double plate processing can be performed. Therefore, efficient production of a liquid crystal panel obtained by using the double plate processing is possible. And two effects of cost reduction can be obtained.
- the liquid crystal panel 1 by manufacturing the liquid crystal panel 1 according to the manufacturing method of the liquid crystal panel in the present embodiment, it becomes possible to adopt a double plate process while realizing high-quality marking, so the liquid crystal 32 is used during the laser marking process. Is already in a state of being isolated from the outside including the peripheral portion B by the seal member 30, and various types constituting the marking region C of the marking pad 50 that is sublimated with the laser marking process. The film can be prevented from entering the space as a foreign substance, and the yield can be improved.
- a glass substrate for a liquid crystal panel including a marking pad 50 suitable for laser marking and a liquid crystal panel including the glass substrate are provided. be able to. Therefore, by manufacturing the liquid crystal panel 1 using the TFT substrate 10, it is possible to obtain a liquid crystal panel from which various information such as serial information and application information can be accurately read.
- the mechanism by which high-quality marking can be performed by following the method for manufacturing a liquid crystal panel in the present embodiment is not clear, but one reason may be as follows. That is, when performing the double plate processing according to the conventional method, since the TFT substrate and the CF substrate are arranged close to each other with a minute gap of about 5 ⁇ m, the periphery of the marking pad is a substantially sealed space. As a result, the film that makes up the marking pad becomes difficult to sublimate, and the heat generated by the irradiation of the laser beam is trapped in the space, causing discoloration around the through-holes, which results in high-quality marking. It is thought that it is difficult to perform.
- the marking pad is constituted by a laminated body made only of the metal film and the ITO film, so that the heat applied to the vicinity of the marking pad And the sublimation of the metal film and ITO film constituting the marking pad is promoted by optimizing the influence of the environment, and heat is also prevented from being trapped in the sealed space, resulting in high-quality marking. Conceivable.
- FIG. 9A is an enlarged photograph showing an example of a marking pad to which the present invention is applied and laser marking processing is performed by double plate processing.
- FIG. 9B is a laser marking processing by double plate processing without applying the present invention. It is an enlarged photograph which shows an example of the marking pad in which No. was performed. With reference to these enlarged photographs, even when the double plate processing is adopted, the marking quality such as the size and shape of the through hole and the darkness around the through hole can be kept high by applying the present invention. On the other hand, if the present invention is not applied, it is understood that the marking quality becomes low.
- the present inventors verified the change in marking quality when various changes were made to the marking pad film configuration after adopting the double plate process, and thereby the film configuration of the present invention. It was found that (that is, a two-layer structure of metal film / ITO film) is optimal. Prototype other film configurations (for example, metal film / insulating film two-layer film structure, metal film / insulating film / metal film three-layer film structure, metal film / insulating film / ITO film three-layer film structure, etc.) In the case of verification, good results were not obtained in either case.
- FIG. 10 is a flowchart for explaining another example of the manufacturing method of the liquid crystal panel in the present embodiment
- FIG. 11 shows the liquid crystal panel according to another example of the manufacturing method of the liquid crystal panel in the present embodiment. It is a schematic cross section in the production process at the time of manufacturing.
- the TFT substrate 10 is manufactured (step S201), and the CF substrate 20 paired with the TFT substrate 10 is formed.
- Production (step S202) is performed in parallel.
- the specific process related to the manufacture of the TFT substrate 10 and the specific process related to the manufacture of the CF substrate 20 are both the same as those in the method of manufacturing the liquid crystal panel in the present embodiment described above.
- laser marking is performed by irradiating the TFT substrate 10 that has been manufactured with laser light (step S203).
- the laser beam 100 is irradiated from the main surface side of the TFT substrate 10 on which the marking pad 50 is formed in the marking region C of the marking pad 50.
- a fundamental wave (wavelength 1064 nm) of a YVO 4 laser which is a general YAG laser beam or a neodymium-added YAG laser beam is preferably used.
- the upper layer 56 and the lower layer 51 constituting the marking region C of the marking pad 50 in the portion irradiated with the laser beam 100 are locally heated and sublimated, and a through-hole penetrating the upper layer 56 and the lower layer 51. 58 is formed.
- step S204 the TFT substrate 10 subjected to the laser marking process in step S203 and the CF substrate 20 manufactured in step S202 are bonded together.
- the details are the same as those in the present embodiment described above.
- step S205 various processes such as a process of encapsulating the liquid crystal 32 are performed.
- step S206 the TFT substrate 10 and the CF substrate 20 are divided (step S206), and the CF substrate 20 is further divided to remove unnecessary portions (step S207).
- step S207 the manufacture of the liquid crystal panel 1 shown in FIGS. 1 and 3 is completed.
- the liquid crystal panel 1 is manufactured according to another example of the liquid crystal panel manufacturing method according to the present embodiment described above, the liquid crystal panel 1 is manufactured according to the liquid crystal panel manufacturing method according to the above-described embodiment. It is possible to obtain substantially the same effect as the case. That is, it is possible to reliably prevent the lower layer 51 of the marking pad 50 from being corroded and deteriorated during the etching process or the film forming process for manufacturing the TFT 40, and to mark the marking pad 50 with high quality. it can.
- FIGS. 12 and 13 are schematic cross-sectional views of the marking pads according to the first and second modified examples.
- Each of the marking pads 50A and 50B according to the first and second modified examples is formed by laminating a metal film constituting the lower layer 51 of the marking region C of the marking pad 50 of the present embodiment described above. It is.
- the lower layer 51 of the marking region C of the marking pad 50A is formed so as to cover, for example, the first metal film 51a and the main surface of the first metal film 51a. Further, it is composed of a two-layer laminated film with the second metal film 51b.
- the first metal film 51a and the second metal film 51b are formed by sequentially forming metal films of different materials using a sputtering method or the like when the lower layer 51 of the marking pad 50A is formed. In this case, the main surface of the second metal film 51b may be anodized.
- a tantalum film is preferably used as the first metal film 51a, and an aluminum film or a copper film is preferably used as the second metal film 51b.
- the lower layer 51 of the marking region C of the marking pad 50A made of a two-layer laminated film is formed simultaneously with the gate electrode 41 of the TFT 40 described above.
- the metal film to be configured is also formed as a two-layer laminated film having the above-described configuration.
- the lower layer 51 of the marking region C of the marking pad 50B is formed so as to cover, for example, the first metal film 51a and the main surface of the first metal film 51a.
- the third metal film 51b and a third metal film 51c formed so as to cover the main surface of the second metal film 51b.
- the first metal film 51a, the second metal film 51b, and the third metal film 51c are formed by sequentially forming metal films of different materials using a sputtering method or the like when the lower layer 51 of the marking pad 50B is formed. Formed with. In this case, the main surface of the third metal film 51c may be anodized.
- a tantalum film is preferably used as the first metal film 51a
- an aluminum film or a copper film is preferably used as the second metal film 51b
- a tantalum film is preferably used as the third metal film 51c.
- the lower layer 51 in the marking region C of the marking pad 50B made of the three-layer laminated film is formed at the same time as the gate electrode 41 of the TFT 40 described above.
- the metal film to be configured is also formed as a three-layer laminated film having the above-described configuration.
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Abstract
Description
(A)液晶表示部になる部分および液晶表示部にならない周辺部分を含む液晶パネル用ガラス基板を準備する工程。
(B)上記液晶パネル用ガラス基板の主表面上に金属膜を成膜してパターニングすることにより、上記液晶表示部になる部分においてTFTのゲート電極を形成するとともに、上記周辺部分においてマーキングパッドの下部層を形成する工程。
(C)上記液晶パネル用ガラス基板の主表面上に絶縁膜を成膜してパターニングすることにより、上記液晶表示部になる部分においてTFTのゲート絶縁膜を形成するとともに、上記周辺部分において上記マーキングパッドの上記下部層を覆うように上記下部層に接触して保護絶縁膜を形成する工程。
(D)上記マーキングパッドの上記下部層を上記保護絶縁膜によって覆った状態を維持しつつ、上記液晶表示部になる部分および上記周辺部分において各種の成膜処理およびパターニング処理を行なう工程。
(E)上記保護絶縁膜の一部およびその上方に成膜された各種の膜の少なくとも一部を除去することにより、上記マーキングパッドの上記下部層の周縁を除く主表面を露出させる工程。
(F)上記液晶パネル用ガラス基板の主表面上にITO膜を成膜してパターニングすることにより、上記液晶表示部になる部分において画素電極を形成するとともに、上記周辺部分において上記保護絶縁膜によって覆われていない部分の上記マーキングパッドの上記下部層の主表面を覆うように上記下部層に接触して上記マーキングパッドの上部層を形成する工程。
(G)上記マーキングパッドにレーザ光を照射することにより、上記マーキングパッドの上記上部層および上記下部層を貫通する貫通孔を設けてマーキングを行なう工程。
(H)上記ゲート電極および上記マーキングパッドの上記下部層の主表面を陽極酸化処理する工程。
Claims (7)
- 液晶表示部になる部分(A)および液晶表示部にならない周辺部分(B)を含む液晶パネル用ガラス基板(11)を準備する工程と、
前記液晶パネル用ガラス基板(11)の主表面上に金属膜を成膜してパターニングすることにより、前記液晶表示部になる部分(A)においてTFT(40)のゲート電極(41)を形成するとともに、前記周辺部分(B)においてマーキングパッド(50)の下部層(51)を形成する工程と、
前記液晶パネル用ガラス基板(11)の主表面上に絶縁膜を成膜してパターニングすることにより、前記液晶表示部になる部分(A)においてTFT(40)のゲート絶縁膜(42)を形成するとともに、前記周辺部分(B)において前記マーキングパッド(50)の前記下部層(51)を覆うように前記下部層(51)に接触して保護絶縁膜(52)を形成する工程と、
前記マーキングパッド(50)の前記下部層(51)を前記保護絶縁膜(52)によって覆った状態を維持しつつ、前記液晶表示部になる部分(A)および前記周辺部分(B)において各種の成膜処理およびパターニング処理を行なう工程と、
前記保護絶縁膜(52)の一部およびその上方に成膜された各種の膜の少なくとも一部を除去することにより、前記マーキングパッド(50)の前記下部層(51)の周縁を除く主表面を露出させる工程と、
前記液晶パネル用ガラス基板(11)の主表面上にITO膜を成膜してパターニングすることにより、前記液晶表示部になる部分(A)において画素電極(46)を形成するとともに、前記周辺部分(B)において前記保護絶縁膜(52)によって覆われていない部分の前記マーキングパッド(50)の前記下部層(51)の主表面を覆うように前記下部層(51)に接触して前記マーキングパッド(50)の上部層(56)を形成する工程と、
前記マーキングパッド(50)にレーザ光(100)を照射することにより、前記マーキングパッド(50)の前記上部層(56)および前記下部層(51)を貫通する貫通孔(58)を設けてマーキングを行なう工程とを備えた、液晶パネルの製造方法。 - 前記ゲート電極(41)および前記マーキングパッド(50)の前記下部層(51)を形成する工程は、複数の異なる材質の金属膜を順次積層形成する工程を含む、請求の範囲第1項に記載の液晶パネルの製造方法。
- 前記ゲート電極(41)および前記マーキングパッド(50)の前記下部層(51)の主表面を陽極酸化処理する工程をさらに備えた、請求の範囲第1項に記載の液晶パネルの製造方法。
- 液晶表示部になる部分(A)と液晶表示部にならない周辺部分(B)とを含む液晶パネル用ガラス基板であって、
前記液晶表示部になる部分(A)の主表面上には、TFT(40)が設けられ、
前記TFT(40)は、ゲート電極(41)としての金属膜と、ゲート絶縁膜(42)としての絶縁膜と、画素電極(46)としてのITO膜とを含み、
前記周辺部分(B)の主表面上には、レーザ光を照射することでマーキングを施すためのマーキングパッド(50)が設けられ、
前記マーキングパッド(50)は、下部層(51)としての金属膜および上部層(56)としてのITO膜のみから構成された積層体からなるマーキング領域(C)と、前記下部層(51)としての金属膜の周縁を覆う絶縁膜(52)を含む周囲領域(D)とを有し、
前記ゲート電極(41)としての金属膜と、前記下部層(51)としての金属膜とが、一の工程で同時に形成されたものであり、
前記ゲート絶縁膜(42)としての絶縁膜と、前記周囲領域(D)を構成する絶縁膜(52)とが、一の工程で同時に形成されたものであり、
前記画素電極(46)としてのITO膜と、前記上部層(56)としてのITO膜とが、一の工程で同時に形成されたものである、液晶パネル用ガラス基板。 - 前記ゲート電極(41)および前記マーキングパッド(50)の前記下部層(51)が、複数の異なる材質の金属膜の積層膜からなる、請求の範囲第4項に記載の液晶パネル用ガラス基板。
- 前記ゲート電極(41)および前記マーキングパッド(50)の前記下部層(51)の主表面が、陽極酸化処理されている、請求の範囲第4項に記載の液晶パネル用ガラス基板。
- 請求の範囲第4項に記載の液晶パネル用ガラス基板を備えた、液晶パネル。
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EP10769547A EP2426551A4 (en) | 2009-04-30 | 2010-02-24 | METHOD FOR PRODUCING A LIQUID CRYSTAL DISPLAY PANEL, GLASS SUBSTRATE FOR A LIQUID CRYSTAL DISPLAY PANEL AND LIQUID CRYSTAL DISPLAY PANEL THEREWITH |
BRPI1015380A BRPI1015380A2 (pt) | 2009-04-30 | 2010-02-24 | método de fabricação de painel de cristal líquido, substrato de vidro para painel de cristal líquido e painel de cristal líquido que inclui o mesmo |
CN201080019088.1A CN102422212B (zh) | 2009-04-30 | 2010-02-24 | 液晶面板的制造方法、液晶面板用玻璃基板和具备该液晶面板用玻璃基板的液晶面板 |
JP2011511339A JP5242777B2 (ja) | 2009-04-30 | 2010-02-24 | 液晶パネルの製造方法、液晶パネル用ガラス基板およびこれを備えた液晶パネル |
RU2011148603/28A RU2481608C1 (ru) | 2009-04-30 | 2010-02-24 | Способ изготовления жидкокристаллической панели, стеклянная подложка для жидкокристаллической панели и жидкокристаллическая панель, включающая в себя стеклянную подложку |
US13/258,540 US8582073B2 (en) | 2009-04-30 | 2010-02-24 | Method of manufacturing liquid crystal panel, glass substrate for liquid crystal panel, and liquid crystal panel including the same |
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US8901715B1 (en) * | 2013-07-05 | 2014-12-02 | Infineon Technologies Ag | Method for manufacturing a marked single-crystalline substrate and semiconductor device with marking |
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KR101881256B1 (ko) | 2017-05-31 | 2018-08-24 | 주식회사 맥사이언스 | Oled 조명 패널을 이용한 조명기구 제조 장치 및 이를 이용한 조명기구 제조 방법 |
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CN102422212A (zh) | 2012-04-18 |
JP5242777B2 (ja) | 2013-07-24 |
US20120019764A1 (en) | 2012-01-26 |
RU2481608C1 (ru) | 2013-05-10 |
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