WO2010113826A1 - 毛髪化粧料 - Google Patents
毛髪化粧料 Download PDFInfo
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- WO2010113826A1 WO2010113826A1 PCT/JP2010/055474 JP2010055474W WO2010113826A1 WO 2010113826 A1 WO2010113826 A1 WO 2010113826A1 JP 2010055474 W JP2010055474 W JP 2010055474W WO 2010113826 A1 WO2010113826 A1 WO 2010113826A1
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- Prior art keywords
- hair
- hair cosmetic
- group
- styling
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
- C08F220/286—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
Definitions
- the present invention relates to a hair cosmetic that has both fixing force and arranging power (including re-styling power). More specifically, the present invention relates to a hair cosmetic composition that can fix hair by fixing by incorporating a novel polymer and can be re-haired.
- Hair styling includes two functions: creating a hairstyle and holding the created hairstyle.
- the principle of exerting these two functions is said to be fixation and adhesion (Non-Patent Document 1).
- Hair styling by sticking is a method in which a film forming agent (polymer resin) called a set agent forms a solid film to fix the hair.
- a film forming agent polymer resin
- a set agent forms a solid film to fix the hair.
- conventional hair gels and hair sprays are mainly based on a hair styling mechanism using a set resin.
- Patent Document 1 describes a hair cosmetic using a film-forming polymer such as polyvinyl pyrrolidone, sodium polyacrylate, polyvinyl pyrrolidone-polyvinyl acetate copolymer as a set resin.
- Patent Document 2 discloses a hair cosmetic using a silylated urethane resin as a set resin, and forms a film having both softness and hardness, and is said to have a natural texture and a high keeping power.
- styling based on adhesion is a method in which hairs are adhered to each other by an oily component, and in recent years using a hair liquid mainly composed of an adhesive oily component such as polyalkylene glycol and the adhesiveness of a solid oil.
- hair waxes and the like that are preferred by young people are known.
- Patent Document 3 describes a cosmetic for hair that contains a wax and a water-soluble polymer having a stringiness and is excellent in re-styling.
- the subject in this invention is providing the hair cosmetics which can fix the hair (hairstyle) based on fixation, and are excellent also in the arrangement power (a re-hair-setting power is also included).
- the present inventors have formulated a new adhesive set resin having a moderate hardness and high adhesive force during film formation as a set resin, thereby fixing strength and arrangement.
- the present inventors have found that a hair cosmetic material having strength can be obtained and completed the present invention.
- n is an integer of 0 ⁇ 30 (CH 2)
- n comprises a branched chain
- R2 is H, OH, with OCH 3, OCH 2 CH 3 or phenyl At least one monomer (hereinafter referred to as “monomer A”);
- / or the following formula (B): (Wherein, R3 is H or CH 3, R4 and R5 may be the same or different, H, or (CH 2) l R 'a, l is an integer of 1 ⁇ 3, R' Is H, OH or —NR ′′ R ′ ′′, and R ′′ and R ′ ′′ may be the same or different and are H or a C1-C3 alkyl group).
- the hair cosmetic composition of the present invention can achieve both the fixing force and the arranging force, which were impossible with the conventional set resin, by blending the above-mentioned novel adhesive set resin. Furthermore, the adhesive function (arrangement force) can be further improved by combining the adhesive set resin with at least one selected from sugars, sugar alcohols and EO / PO derivatives.
- the hair cosmetic composition of the present invention contains an adhesive set resin obtained by polymerizing the monomer A and / or the monomer B, the monomer C and the monomer D as an essential component. That is, in the adhesive set resin of the present invention, it is essential to contain the monomer C and the monomer D, and the monomer A and the monomer B only need to contain one or both. With a resin (polymer) lacking the monomer C or the monomer D, good adhesive force and arrangement force (re-hair-setting ability) cannot be obtained.
- the adhesive set resin used in the present invention is particularly preferably one having a structure represented by the following formula (I).
- R1 to R9, n, m, p, and q have the same meaning as in the above formulas A to D
- a is 40 ⁇ a ⁇ 400
- b is 80 ⁇ b ⁇ 300
- c is 30.
- d is a number in the range of 0 ⁇ d ⁇ 10.
- the mass% of each monomer in the adhesive set resin (polymer of formula (I)) that satisfies the above conditions is approximately as follows. 7.5 ⁇ A ⁇ 62.5, 20 ⁇ B ⁇ 45, 7.5 ⁇ C ⁇ 60, 0 ⁇ D ⁇ 5.
- the adhesive set resin of the present invention is obtained by mixing the above monomers A and / or B and C and D in an appropriate ratio and subjecting them to a polymerization reaction using a standard method in an appropriate solvent as necessary.
- the blending amount of the adhesive set resin in the hair cosmetic composition of the present invention may vary depending on the product form, but is generally 0.1 to 30% by mass, preferably 1 to 20% by mass, more preferably 2 To 15% by mass. If it is less than 0.1% by mass, the arranging power may be insufficient, and if it exceeds 30% by mass, the hair may become stiff.
- the hair cosmetic composition of the present invention contains alcohol and water in addition to the above-mentioned adhesive set resin.
- the alcohol in the hair cosmetic composition of the present invention one or more selected from alcohols generally used in cosmetics such as ethanol can be appropriately selected and used.
- the compounding quantity of alcohol is not specifically limited, It can change with the aspect of hair cosmetics. Usually, it mix
- the water content in the cosmetic of the present invention is usually 5 to 80% by mass, preferably 10 to 70% by mass.
- the hair cosmetic composition of the present invention preferably contains at least one selected from sugars, sugar alcohols, and EO / PO derivatives. By blending these, the arranging power can be further improved.
- Saccharides used in the present invention include monosaccharides and oligosaccharides.
- monosaccharides include tricarbon sugars (eg, D-glyceryl aldehyde, dihydroxyacetone, etc.); tetracarbon sugars (eg, D-erythrose, D-erythrulose, D-threose, etc.); For example, L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc .; hexose (eg, D-glucose, D-talose, D-bucose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc.); heptacarbon (eg, aldheptose, heproose, etc.);
- oligosaccharides include sucrose, maltose, cellobiose, guntianose, umbelliferose, lactose, planteose, isolicnose, trehalose, raffinose, lycnose, umbilicin, and stachyose verbus course.
- derivatives thereof POE / POP addition, alkyl group addition, cationization, anionization, silylation
- sugar alcohol examples include mannitol, xylitol, erythritol, sorbitol, maltitol, inositol and the like. These derivatives (POE and / or POP adduct, alkyl group adduct, cationized product, anionized product, silylated product) and the like can also be used.
- the sugar and sugar alcohol used in the present invention are not limited. Among them, sugar alcohols, particularly maltitol and sorbitol are most suitable.
- the amount of sugar and / or sugar alcohol in the hair cosmetic composition of the present invention is generally 0.1 to 20% by mass, preferably 1 to 20% by mass, more preferably 3 to 10% by mass. If it is less than 0.1% by mass, the effect of improving the arranging power (re-hair-setting ability) may not be sufficient, and if it exceeds 30% by mass, stickiness may occur.
- the EO / PO derivatives used in the present invention are compounds including the following hair styling oil and polyalkylene glycols.
- the hair styling oil means an EO / PO adduct of monohydric to tetrahydric alcohol or monohydric to trivalent carboxylic acid.
- Commercially available products can be used, such as Unilube 50 MB 168, Unilube MB370, Berthamol P-700, Berthamol DG-25, Triol G-40, Sabondol SGP-7, Sabondol GP-9 (above Nissho Co., Ltd.) Este Mall 50 (Nisshin Oil Co., Ltd.).
- the polyalkylene glycol means a polyalkylene glycol, for example, an addition polymer of ethylene oxide (EO), propylene oxide (PO), butylene oxide (BO).
- EO addition polymer PEG200, PEG300, PEG400, PEG600, PEG1000, PEG1540, PEG2000, PEG4000, PEG6000, PEG11000, PEG20000 (Nissho Corporation or Toho Chemical Co.) with PO Polymers: UNIOR D-700, UNIOR D-1000, UNIOR D-1200, UNIOR D-2000 (above NOF Corporation) and the like.
- the polyalkylene glycols used in the present invention are not limited, but among them, polyethylene glycol is most suitable.
- the blending amount of the EO / PO derivative in the hair cosmetic composition of the present invention is generally 0.1 to 20% by mass, preferably 1 to 20% by mass, more preferably 3 to 10% by mass. If it is less than 0.1% by mass, the effect of improving the arranging power (re-hair-setting ability) may not be sufficient, and if it exceeds 30% by mass, stickiness may occur.
- the hair cosmetic composition of the present invention includes a novel adhesive set resin, and exhibits a fixing force and an arranging power by optionally including at least one selected from sugars, sugar alcohols, and EO / PO derivatives.
- the form can be provided in various forms such as hair liquid, hair foam, hair mousse, hair spray, hair mist, hair gel, hair wax and the like.
- the hair cosmetic of the present invention may be blended with other components conventionally used in hair cosmetics, for example, depending on the form thereof, as long as the effects of the present invention are not impaired.
- Samples were prepared using the resins of the above production examples and comparative production examples, and the fixing strength, adhesive strength, arranging power, hair styling power, and hair crispness when the samples were used were evaluated.
- the evaluation method and evaluation criteria for each characteristic are as follows.
- Adhesive strength After applying 0.5g of sample to a bundle of black virgin hair (length 20cm, mass 2g) and drying at room temperature, the adhesive strength on the hair is determined by 10 female panelists. Evaluation was made by a sensory test.
- Arranging power 10 gender panelists are able to arrange the hair bundle after applying 0.5g of sample to 1 bundle of black virgin hair (length 20cm, mass 2g) and drying at room temperature. Evaluation was made by a sensory test.
- Re-styling power A 0.5g sample is applied to a bundle of black virgin hair (length: 20cm, mass: 2g), and the hair bundle is dried at room temperature. The ease of hair styling (re-hair styling ability) was evaluated by a sensory test with 10 female panelists.
- Samples having the compositions listed in Table 2 below were prepared. The sample was prepared by adding each polymer to the mixture of (1) and (2) and stirring. The characteristics of each sample were then evaluated according to the above criteria. The results are also shown in Table 2.
- Examples 12 to 14 blended with an EO / PO derivative exhibited excellent characteristics, particularly in terms of adhesive strength, re-styling ability, and lack of roughness.
- Examples 16 to 18 in which a sugar alcohol was blended exhibited excellent characteristics, particularly in terms of adhesive strength, arranging power, and re-styling ability.
- Examples 20 to 22 in which EO / PO derivative was blended exhibited excellent characteristics particularly in terms of adhesive strength, arranging power, and re-styling ability.
- Example 23 Liquid styling agent (1) Residual ion exchange water (2) PEG-6 5 (3) PEG-8 5 (4) PEG-32 5 (5) Sorbitol 3 (6) Ethanol 35 (7) Perfume appropriate amount (8) Polymer 5 obtained in Production Example 3 (9) (alkyl alkylate / diacetone acrylamide) copolymer 2.5 (10) Citric acid appropriate amount
- ⁇ Production method> (1) Add water-soluble components (2) to (5) to water and dissolve with stirring to obtain water parts. Next, after (7) is added to (6) and stirred to solubilize, (8) and (9) are added and stirred to obtain alcohol parts. Water parts and alcohol parts were mixed and (10) was added to obtain a liquid styling agent.
- Example 25 Hair wax (1) Candelilla wax 2 (2) Microcrystalline wax 12 (3) Liquid paraffin 3.5 (4) Hydrogenated polyisobutene 3.5 (5) Pentaerythrityl tetraethylhexanoate 3 (6) PEG-60 glyceryl isostearate 1 (7) Glyceryl stearate 1 (8) Behenyl alcohol 3.3 (9) Stearyl alcohol 0.9 (10) Tocopherol 0.5 (11) Perfume appropriate amount (12) ion-exchanged water remaining (13) PG 8 (14) Sodium stearoylmethyl taurine 1.2 (15) Silicic anhydride 2.5 (16) TEA 0.4 (17) Polymer 3 obtained in Production Example 3 (18) Ethanol 5
- ⁇ Production method> (1) to (11) are dissolved by stirring at 80 to 90 ° C. to obtain an oil phase part. (12) to (14) are dissolved by stirring at 70 ° C. to 80 ° C., and this is used as the aqueous phase. (15) is added after adding an oil layer part to a water phase part and emulsifying with a homomixer. After neutralization by adding (16), (17) and (18) were added, deaerated and cooled to obtain a hair wax.
- Example 29 Hair Styling Gel (1) Carboxyvinyl Polymer 0.7 (2) Urethane resin aqueous dispersion of Production Example 2 (actual content: 40% by mass) 5.0 (3) Glycerin 2.5 (4) 1,3-butylene glycol 2.5 (5) Polyoxyethylene octyldodecyl ether (20EO) 0.5 (6) Polyether-modified dimethylpolysiloxane 1.0 (7) Sodium hydroxide (prepared to pH 7.5) Appropriate amount (8) Ethanol 20.0 (10) Fragrance 0.1 (11) Trisodium edetate 0.03 (12) Ion exchange water Residue (13) Polymer obtained in Production Example 3 5.0
- Example 30 Hair Styling Gel (1) (PEG-240 / decyltetradeceth-20 / HDI) Copolymer 2.0 (2) Polymer obtained in Production Example 3 1.0 (3) Diglycerin 2.5 (4) Polyethylene glycol 1000 2.5 (5) Polyoxyethylene hydrogenated castor oil (40EO) 0.5 (6) Both-terminal hydroxy-modified dimethylpolysiloxane (1,000,000 mPa ⁇ s) 1.0 (7) Sodium hydroxide (prepared to pH 7.5) Appropriate amount (8) Ethanol 20.0 (9) Polyoxyethylene octyldodecyl ether 0.1 (10) Fragrance 0.1 (11) Trisodium edetate 0.03 (12) Ion exchange water Residue (13) (alkyl alkyl alkyl / diacetone acrylamide) Copolymer 1.0
- Example 31 Styling mousse (1) Dimethylpolysiloxane (20 mPa ⁇ s) 5.0 (2) Isoparaffin 5.0 (3) High molecular weight polysiloxane 2.0 (4) Amino-modified high molecular weight silicone 0.5 (5) 1,3-butylene glycol 3.0 (6) Polyoxyethylene hydrogenated castor oil (40EO) 2.0 (7) Polymer obtained in Production Example 3 10.0 (8) Polyoxyethylene / polyoxypropylene decyl ether (12EO ⁇ 2PO) 1.0 (9) Behenyltrimethylammonium chloride 0.1 (10) Phenoxyethanol 0.1 (11) Ethanol 8.0 (12) Ion exchange water Residue (13) Fragrance Appropriate amount (14) (Octylacrylamide / hydroxypropyl acrylate / (Butylaminoethyl methacrylate) copolymer 1.0
- Example 32 Styling mousse (1) Dimethylpolysiloxane (6 mPa ⁇ s) 5.0 (2) Isoparaffin 5.0 (3) (PEG / amodimethicone) copolymer 1.0 (4) 1,3-butylene glycol 3.0 (5) Polyoxyethylene hydrogenated castor oil (40EO) 2.0 (6) Polymer obtained in Production Example 3 1.0 (7) Lauric acid diethanolamide 0.2 (8) Stearoxyhydroxypropylamine 0.1 (9) Phenoxyethanol 0.1 (10) Ethanol 8.0 (11) Ion exchange water Residue (12) Perfume appropriate amount (13) (octylacrylamide / hydroxypropyl acrylate / (Butylaminoethyl methacrylate) copolymer 0.5
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Abstract
Description
本発明者等は、前記の課題を解決すべく鋭意研究を重ねた結果、皮膜形成時に程よい固さと高い粘着力を有する新たな粘着性セット樹脂をセット樹脂として配合することにより、固定力とアレンジ力を兼ね備えた毛髪化粧料が得られることを見出し、本発明を完成するに至った。
下記式(A):
及び/又は
下記式(B):
及び
下記式(C):
及び
下記式D:
を重合させて得られる粘着性セット樹脂、アルコール、及び水を含有する毛髪化粧料を提供する。
本発明の毛髪化粧料は、前記粘着性セット樹脂に加えて、糖、糖アルコール及びEO/PO誘導体から選択される少なくとも1種を含有するが好ましい。
さらに、前記粘着性セット樹脂と、糖、糖アルコール及びEO/PO誘導体から選択される少なくとも1種とを組み合せることによって粘着機能(アレンジ力)を更に向上させることができる。
上記の条件を満たす粘着性セット樹脂(式(I)のポリマー)における各モノマーの質量%は、およそ次のようになる。7.5<A<62.5、20≦B<45、7.5<C<60、0<D<5。
本発明の毛髪化粧料におけるアルコールとしては、エタノール等の化粧品で一般に使用されているアルコール類から選択される1種又は2種以上を適宜選択して用いることができる。アルコールの配合量は、特に限定されるものではなく、毛髪化粧料の態様によって変化しうる。通常は、粘着性セット樹脂の溶媒として用いる下限量から80質量%まで配合される。また、使用性をコントロールする点で水の配合量に合わせて調整するのが好ましい場合もある。
本発明の化粧料における水の含有量は、通常は5~80質量%、好ましくは10~70質量%である。
本発明で用いられる糖及び糖アルコールは限定されないが、それらの中でも糖アルコール、特にマルチトール、ソルビトールが最適である。
整髪油分とは、一価~四価のアルコール、または一価~三価のカルボン酸のEO/PO付加体を意味する。市販のものを利用することができ、例えば、ユニルーブ50 MB 168、ユニルーブMB370、ベルタモール P-700、ベルタモールDG-25、トリオールG-40、サボンドールSGP-7、サボンドールGP-9(以上日油株式会社)エステモール50(日清製油株式会社)などを挙げることができる。
本発明で用いられるポリアルキレングリコール類は限定されないが、それらの中でもポリエチレングリコールが最適である。
下記表1に示したモノマー組成で重合を行い、本発明の粘着性セット樹脂(製造例1~6)及びモノマーCを含まない比較製造例1及びモノマーDを含まない比較製造例2を調製した。
具体的には、モノマー類100部を混合した混合物をあらかじめ用意し、この混合物の入った滴下漏斗、還流冷却気、温度計、窒素置換用管および、撹拌機が取り付けられた容量1Lの五つ口フラスコに、エタノール100部を仕込み、窒素気流下、昇温し、還流状態(約80℃)になったところで、このエタノール中に重合開始剤(2,2’-アゾビスイソブチロニトリル)1部を添加し、上記混合物を2時間連続して滴下する。その後、還流状態にて、8時間放置し重合反応を進行させた。次に五つ口フラスコ中の溶液から溶媒を留去および、エタノールを加えることでこの溶液の溶媒含有量を調整し、固形分濃度50%の毛髪化粧料基剤の溶液を得た。
上記製造例及び比較製造例の樹脂を用いて試料を調製し、当該試料を使用したときの固定力、粘着力、アレンジ力、再整髪力、及び髪のぱさつきについて評価した。
各特性の評価方法及び評価基準は以下の通りである。
黒色バージンヘア(長さ15cm,重さ1g)に、試料を0.4g塗布し、くしを使いなじませ、まっすぐになるよう形を整え、1試料あたり5本のストランドを作製した。これを50℃で1時間乾燥させた後目盛りの付いたボードに吊り下げ、温度30℃,湿度90%RHの恒温恒湿器にてストランドの撓んだ長さを(b)を測定した。試料未塗布時にあらかじめ測定しておいた、撓んだストランドの長さ(a)を用い、次式に従い固定力(キープ力)を求めた。数値が100%に近いほど固定力が高く、耐湿性に優れることを示している。
ヘアスタイルキープ力(%)={(a-b)/a}×100
◎:値が90%以上
○:値が70~90%未満
△:値が50~70%未満
×:値が50%未満
1束の黒色バージンヘア(長さ20cm,質量2g)に試料を0.5g塗布し、常温にて乾燥させた後の毛束について、毛髪上の粘着力を10名の女性専門パネラーによる官能試験にて評価した。
5点:かなり粘着を感じる
4点:やや粘着を感じる
3点:普通
2点:やや粘着を感じない
1点:粘着を感じない
<評価基準>
◎:合計点が40点以上
○:合計点が30点以上40点未満
△:合計点が20点以上30点未満
×:合計点が20点未満
1束の黒色バージンヘア(長さ20cm,質量2g)に試料を0.5g塗布し、常温にて乾燥させた後の毛束について、アレンジのしやすさを10名の女性専門パネラーによる官能試験にて評価した。
5点:かなりアレンジしやすい
4点:ややアレンジしやすい
3点:普通
2点:ややアレンジしにくい
1点:アレンジしにくい
<評価基準>
◎:合計点が40点以上
○:合計点が25点以上40点未満
△:合計点が20点以上25点未満
×:合計点が20点未満
1束の黒色バージンヘア(長さ20cm,質量2g)に試料を0.5g塗布し、常温にて乾燥させた後の毛束について、塗布直後に整髪を行い、その後1時間後に再度整髪した際のしやすさ(再整髪力)を10名の女性専門パネラーによる官能試験にて評価した。
5点:かなり再整髪力がある
4点:やや再整髪力がある
3点:普通
2点:やや再整髪力がない
1点:再整髪力がない
<評価基準>
◎:合計点が40点以上
○:合計点が25点以上40点未満
△:合計点が20点以上25点未満
×:合計点が20点未満
1束の黒色バージンヘア(長さ20cm,質量2g)に試料を0.5g塗布し、常温にて乾燥させた後の毛束について、整髪する際の毛髪のぱさつきのなさを10名の女性専門パネラーによる官能試験にて評価した。
5点:かなりぱさつかない
4点:ややぱさつかない
3点:普通
2点:ややぱさつく
1点:ぱさつく
<評価基準>
◎:合計点が40点以上
○:合計点が30点以上40点未満
△:合計点が20点以上30点未満
×:合計点が20点未満
(実施例23)
リキッド状スタイリング剤
(1)イオン交換水 残余
(2)PEG-6 5
(3)PEG-8 5
(4)PEG-32 5
(5)ソルビトール 3
(6)エタノール 35
(7)香料 適量
(8)製造例3で得られたポリマー 5
(9)(アルキル酸アルキル/ジアセトンアクリルアミド)コポリマー2.5
(10)クエン酸 適量
(1)水に(2)~(5)の水溶性成分を加え撹拌溶解し水パーツとする。次に、(6)に(7)を加え撹拌し可溶化させた後、(8)・(9)を加え撹拌しアルコールパーツとする。水パーツとアルコールパーツとを混ぜ、(10)を加えてリキッド状のスタイリング剤を得た。
ヘアリキッド
(1)エタノール 55
(2)プロピレングリコール 5
(3)ポリオキシエチレンポリオキシプロピレン
ペンタエリスリトールエーテル(5EO) 25
(4)パラメトキシケイ皮酸2-エチルヘキシル 0.5
(5)製造例3で得られたポリマー 5
(6)色素 適量
(7)イオン交換水 残余
(8)香料 適量
(1)に(2)~(5)を加えよく撹拌し溶解する。次に(8)を加え可溶化させアルコールパーツとする。一方(6)を(7)に撹拌溶解させたものを水パーツとして、それらをアルコールパーツと混合し、ヘアリキッドを得た。
ヘアワックス
(1)キャンデリラロウ 2
(2)マイクロクリスタリンワックス 12
(3)流動パラフィン 3.5
(4)水添ポリイソブテン 3.5
(5)テトラエチルヘキサン酸ペンタエリスリチル 3
(6)イソステアリン酸PEG‐60グリセリル 1
(7)ステアリン酸グリセリル 1
(8)ベヘニルアルコール 3.3
(9)ステアリルアルコール 0.9
(10)トコフェロール 0.5
(11)香料 適量
(12)イオン交換水 残余
(13)PG 8
(14)ステアロイルメチルタウリンナトリウム 1.2
(15)無水ケイ酸 2.5
(16)TEA 0.4
(17)製造例3で得られたポリマー 3
(18)エタノール 5
(1)~(11)を80~90℃で攪拌溶解させ、これを油相部とする。(12)~(14)を70℃~80℃で攪拌溶解させ、これを水相部とする。水相部に油層部を加えホモミキサーにて乳化させた後、(15)を加える。(16)を加えて中和した後、(17)(18)を加え、脱気、冷却し、ヘアワックスを得た。
ヘアワックス
(1)メチルポリシロキサン 2.0
(2)マイクロクリスタリンワックス 12.0
(3)流動パラフィン 3.5
(4)水添ポリイソブテン 3.5
(5)テトラ2-エチルヘキサン酸ペンタエリスリチル 3.0
(6)イソステアリン酸PEG-60グリセリル 1.0
(7)ステアリン酸グリセリル 1.0
(8)脱臭セタノール(植物油系) 3.3
(9)ステアリルアルコール 0.9
(10)トコフェロール 0.5
(11)香料 0.1
(12)イオン交換水 残余
(13)プロピレングリコール 8.0
(14)塩化ステアリルトリメチルアンモニウム 1.2
(15)カオリン 2.5
(16)トリエタノールアミン 0.4
(17)ポリビニルピロリドン-酢酸ビニル共重合体 1.8
(18)製造例3で得られたポリマー 2.0
(19)エタノール 5.0
(1)~(11)を85℃で撹拌溶解させた(油相部)。他方、(12)~(14)を75℃で撹拌溶解させた(水相部)。水相部に油相部を加え乳化させた後、(15)を加えた。次いで(16)を加えて中和させた後、(17)・(18)・(19)を加え、脱気、冷却した。
ヘアワックス
(1)カオリン 1.0
(2)揮発性イソパラフィン 5.0
(3)オクタン酸セチル 5.0
(4)フェニルメチルポリシロキサン 0.5
(5)キャンデリラロウ 3.0
(6)パラフィンワックス 8.0
(7)プロピレングリコール 5.0
(8)ステアリン酸グリセリル 1.0
(9)モノステアリン酸ポリオキシエチレングリセリン(5EO)1.0
(10)イソステアリン酸 1.0
(11)カルボキシビニルポリマー 0.4
(12)水酸化カリウム(pH7.5に調製) 適量
(13)イオン交換水 残余
(14)製造例3で得られたポリマー 5.0
(15)ソルビトール 3.0
(16)EDTA-2Na・2H2O 0.05
(17)フェノキシエタノール 0.5
(18)香料 適量
(19)高重合ポリエチレングリコール 0.1
(20)エタノール 5.0
(13)に(16)、(7)、(15)を加え溶解後、(11)を加え均一に攪拌分散させ、(1)を加えディスパーを用いて均一分散させ85℃に加温後、同様に85℃にて攪拌溶解させた(2)~(9)の混合物を加え、均一攪拌後(12)を加えホモミキサーにて乳化し、(14)、(15)、(17)~(20)を順次加え25℃に冷却しヘアワックスを得た。
ヘアワックス
(1)タルク 1.0
(2)流動パラフィン 5.0
(3)テトラエチルヘキサン酸ペンタエリスリチル 5.0
(4)ポリエーテル変性メチルポリシロキサン 0.5
(5)カルナバロウ 3.0
(6)ポリエチレンワックス 8.0
(7)ジプロピレングリコール 5.0
(8)ポリオキシエチレン硬化ヒマシ油(60EO) 2.0
(9)イソステアリン酸 1.0
(10)ステアリルアルコール 1.0
(11)(PEG-240/デシルテトラデセス-20/HDI)
コポリマー 2.0
(12)トリエタノールアミン(pH7.5に調製) 適量
(13)イオン交換水 残余
(14)製造例3で得られたポリマー 10.0
(15)(アルキル酸アルキル/ジアセトンアクリルアミド)
コポリマー 1.0
(16)2-アルキル-N-カルボキシメチル-N-
ヒドロキシエチルイミダゾリニウムベタイン 5.0
(17)フェノキシエタノール 0.5
(18)香料 適量
(19)高重合ポリアクリル酸ナトリウム 0.1
(20)エタノール 5.0
実施例26と同様にして得た。
ヘアスタイリングジェル
(1)カルボキシビニルポリマー 0.7
(2)製造例2のウレタン系樹脂水分散物(実分40質量%) 5.0
(3)グリセリン 2.5
(4)1,3-ブチレングリコール 2.5
(5)ポリオキシエチレンオクチルドデシルエーテル(20EO)0.5
(6)ポリエーテル変性ジメチルポリシロキサン 1.0
(7)水酸化ナトリウム(pH7.5に調製) 適量
(8)エタノール 20.0
(10)香料 0.1
(11)エデト酸三ナトリウム 0.03
(12)イオン交換水 残余
(13)製造例3で得られたポリマー 5.0
(3)、(4)、(5)、一部の(12)に(6)を添加し、ホモミキサーにより乳化する。次いで、一部の(12)を加えて乳化部とする。一方、残りの(12)に(1)、(2)、(7)、(8)、(9)、(10)、(11)(13)を均一溶解し、これに先の乳化部を添加し、乳化状ヘアスタイリングジェルを得た。
ヘアスタイリングジェル
(1)(PEG-240/デシルテトラデセス-20/HDI)
コポリマー 2.0
(2)製造例3で得られたポリマー 1.0
(3)ジグリセリン 2.5
(4)ポリエチレングリコール1000 2.5
(5)ポリオキシエチレン硬化ヒマシ油(40EO) 0.5
(6)両末端ヒドロキシ変性ジメチルポリシロキサン
(1,000,000mPa・s) 1.0
(7)水酸化ナトリウム(pH7.5に調製) 適量
(8)エタノール 20.0
(9)ポリオキシエチレンオクチルドデシルエーテル 0.1
(10)香料 0.1
(11)エデト酸三ナトリウム 0.03
(12)イオン交換水 残余
(13)(アルキル酸アルキル/ジアセトンアクリルアミド)
コポリマー 1.0
実施例29に準じて製造した。
スタイリングムース
(1)ジメチルポリシロキサン(20mPa・s) 5.0
(2)イソパラフィン 5.0
(3)高分子量ポリシロキサン 2.0
(4)アミノ変性高分子量シリコーン 0.5
(5)1,3-ブチレングリコール 3.0
(6)ポリオキシエチレン硬化ヒマシ油(40EO) 2.0
(7)製造例3で得られたポリマー 10.0
(8)ポリオキシエチレン・ポリオキシプロピレンデシルエーテル
(12EO・2PO) 1.0
(9)塩化ベヘニルトリメチルアンモニウム 0.1
(10)フェノキシエタノール 0.1
(11)エタノール 8.0
(12)イオン交換水 残余
(13)香料 適量
(14)(オクチルアクリルアミド/アクリル酸ヒドロキシプロピル/
メタクリル酸ブチルアミノエチル)コポリマー 1.0
(1)、(2)に(3)、(4)を撹拌溶解したものを(5)、(6)、一部の(12)に添加し、ホモミキサーにて乳化する(乳化パーツ)。一方、残部の(12)に(7)を添加しておく(水相パーツ)。(11)に(8)、(9)、(10)、(13)、(14)を添加し、撹拌溶解し、これを先の水相パーツに添加し、さらに、乳化パーツを添加し、均一に混合して、原液とする。この原液90部をエアゾール用の缶の詰め、弁をし、10部の液化石油ガス(LPG)を充填し、スタイリングムースを得た。
スタイリングムース
(1)ジメチルポリシロキサン(6mPa・s) 5.0
(2)イソパラフィン 5.0
(3)(PEG/アモジメチコン)コポリマー 1.0
(4)1,3-ブチレングリコール 3.0
(5)ポリオキシエチレン硬化ヒマシ油(40EO) 2.0
(6)製造例3で得られたポリマー 1.0
(7)ラウリン酸ジエタノールアミド 0.2
(8)ステアロキシヒドロキシプロピルアミン 0.1
(9)フェノキシエタノール 0.1
(10)エタノール 8.0
(11)イオン交換水 残余
(12)香料 適量
(13)(オクチルアクリルアミド/アクリル酸ヒドロキシプロピル/
メタクリル酸ブチルアミノエチル)コポリマー 0.5
実施例31に準じて製造した。
Claims (5)
- 下記式(A):
及び/又は
下記式(B):
及び
下記式(C):
及び
下記式D:
を重合させて得られる粘着性セット樹脂、アルコール、及び水を含有する毛髪化粧料。 - 糖、糖アルコール及びEO/PO誘導体から選択される少なくとも1種を更に含有することを特徴とする、請求項1又は2に記載の毛髪化粧料。
- 前記糖アルコールが、マルチトール及びソルビトールから選択されることを特徴とする、請求項3に記載の毛髪化粧料。
- 前記EO/PO誘導体が、ポリエチレングリコールであることを特徴とする、請求項3に記載の毛髪化粧料。
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BRPI1013183A BRPI1013183A2 (pt) | 2009-03-31 | 2010-03-28 | cosmético para o cabelo |
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WO2012057210A1 (ja) * | 2010-10-29 | 2012-05-03 | 三菱化学株式会社 | 共重合体および化粧料用組成物 |
JP2012097160A (ja) * | 2010-10-29 | 2012-05-24 | Mitsubishi Chemicals Corp | 共重合体および化粧料用組成物 |
JP2012107166A (ja) * | 2010-10-29 | 2012-06-07 | Mitsubishi Chemicals Corp | 共重合体および化粧料用組成物 |
WO2012077731A1 (ja) * | 2010-12-08 | 2012-06-14 | 株式会社資生堂 | ジェル状毛髪化粧料 |
CN103189404A (zh) * | 2010-10-29 | 2013-07-03 | 三菱化学株式会社 | 共聚物及化妆品用组合物 |
JP2017206478A (ja) * | 2016-05-20 | 2017-11-24 | 株式会社マンダム | 整髪剤組成物 |
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JP2011026304A (ja) * | 2009-06-24 | 2011-02-10 | Mitsubishi Chemicals Corp | 化粧料用共重合体、及びそれを含む化粧料用組成物 |
CN104379218B (zh) | 2012-05-15 | 2017-09-08 | 花王株式会社 | 毛发化妆品组合物 |
JP6505353B2 (ja) * | 2013-03-07 | 2019-04-24 | 株式会社ミルボン | クリーム状整髪剤 |
JP7114043B2 (ja) * | 2018-02-01 | 2022-08-08 | 株式会社アリミノ | 整髪料 |
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- 2010-03-28 BR BRPI1013183A patent/BRPI1013183A2/pt not_active IP Right Cessation
- 2010-03-29 TW TW099109414A patent/TW201034701A/zh unknown
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WO2012057210A1 (ja) * | 2010-10-29 | 2012-05-03 | 三菱化学株式会社 | 共重合体および化粧料用組成物 |
JP2012097160A (ja) * | 2010-10-29 | 2012-05-24 | Mitsubishi Chemicals Corp | 共重合体および化粧料用組成物 |
JP2012107166A (ja) * | 2010-10-29 | 2012-06-07 | Mitsubishi Chemicals Corp | 共重合体および化粧料用組成物 |
CN103189404A (zh) * | 2010-10-29 | 2013-07-03 | 三菱化学株式会社 | 共聚物及化妆品用组合物 |
WO2012077731A1 (ja) * | 2010-12-08 | 2012-06-14 | 株式会社資生堂 | ジェル状毛髪化粧料 |
JP2012136514A (ja) * | 2010-12-08 | 2012-07-19 | Shiseido Co Ltd | ジェル状毛髪化粧料 |
JP2017206478A (ja) * | 2016-05-20 | 2017-11-24 | 株式会社マンダム | 整髪剤組成物 |
Also Published As
Publication number | Publication date |
---|---|
BRPI1013183A2 (pt) | 2016-04-12 |
JP2010235499A (ja) | 2010-10-21 |
US20120045410A1 (en) | 2012-02-23 |
TW201034701A (en) | 2010-10-01 |
KR20120001752A (ko) | 2012-01-04 |
EP2415456A1 (en) | 2012-02-08 |
CN102448436A (zh) | 2012-05-09 |
JP5108817B2 (ja) | 2012-12-26 |
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