WO2010091538A1 - 环保型瓷塑复合材料及其制备方法 - Google Patents
环保型瓷塑复合材料及其制备方法 Download PDFInfo
- Publication number
- WO2010091538A1 WO2010091538A1 PCT/CN2009/000724 CN2009000724W WO2010091538A1 WO 2010091538 A1 WO2010091538 A1 WO 2010091538A1 CN 2009000724 W CN2009000724 W CN 2009000724W WO 2010091538 A1 WO2010091538 A1 WO 2010091538A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ash
- polymer composite
- parts
- plastic polymer
- friendly
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
- C04B18/08—Flue dust, i.e. fly ash
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Definitions
- the invention belongs to the field of building materials, and particularly relates to an environment-friendly porcelain plastic polymer composite material formula and a preparation method thereof.
- the invention provides a novel environmental protection high according to the mechanism that the thermoplastic polymer PE, PP and PVC have good fluidity and cohesive property at the melting temperature and can be copolymerized with other modified powdery or granular materials.
- Molecular composite material formulation and preparation method thereof and are made into profiles with stable physical and chemical properties, non-toxic, tasteless, acid-resistant, alkali-resistant, high-low temperature resistant.
- the technical scheme of the invention is: an environment-friendly porcelain plastic polymer composite material, comprising a thermoplastic, a bamboo powder, a plasticizer, an internal and external lubricant, a crosslinking modifier, a filler, a flame retardant, a pigment, Also included is the ash.
- the ash material includes one or more of sludge ash, fly ash, (waste) brick ash, ceramic ash, and broken calcium.
- the formulation of an environmentally friendly porcelain plastic polymer composite material consists of the following components by weight: 10 to 70 parts of thermoplastic, 10 to 90 parts of ash, 0 to 40 parts of bamboo powder, and plasticizer 0 5 ⁇ 2 parts, internal and external lubricants 0. 3 ⁇ 5 parts, cross-linking modifier 0. 5 ⁇ 5 parts, filler 0. 1 ⁇ 2, flame retardant 0 ⁇ i5 parts, the amount of pigment.
- thermoplastic is either "PVC” or “Phase” or a mixture of two.
- the plasticizer includes one or more of atactic polypropylene or a transparent styrene-butadiene copolymer or a thermoplastic rubber. Plasticizers can be used as optional materials in special high-end materials.
- the internal and external lubricants include zinc polystearate or calcium stearate or paraffin wax or vinyl wax, wherein zinc polystearate and calcium stearate are internal lubricants, and paraffin wax and bake wax are external lubricants.
- the crosslinking modifier includes an aluminate coupling agent or a Y-aminopropyltrisoxysilane coupling agent.
- Filling agents include: antioxidant 168 or antioxidant 1010, UV-resistant agent UV-531, stabilizer.
- the stabilizer is an ACR processing aid.
- the flame retardant is decabromohexane and lanthanum trioxide, and the weight fraction thereof is 0 to 10 parts of decabromo alkoxide and 0 to 5 parts by weight of silicon dioxide. Flame retardants can be used as optional materials in special high-end materials.
- the cross-linking modifier, external lubricant and plasticizer are placed in a high-mixer and ash, bamboo wood powder for thorough mixing, and the cross-linking modifier is used to coat the ash and bamboo powder. Sex, mixing time at 120 ° C for 3 - 5 minutes;
- thermoplastic, antioxidant 168 or antioxidant 1010, UV-resistant UV-53K stabilizer are simultaneously mixed in a high-mixer, mixed at 120 ° C - 130 ° C for 5 minutes;
- step (5) Finally put the internal lubricant, all materials are fully mixed at 120 °C for 1 ⁇ 5 minutes, the material is discharged and sent to the granulation equipment for granulation, into the polymer composite material, packaged into the warehouse.
- a flame retardant or a pigment as an optional material is added according to the product requirements.
- bamboo wood powder may be used, or bamboo wood powder may be selected.
- the extraction program provided by the invention saves energy and reduces emissions; the material is resistant to acid and alkali; the temperature sensitivity is low, and the physical and chemical properties are superior. All kinds of materials manufactured by using the material of the invention have stable physical and chemical properties, high strength, no toxicity, no odor, acid and alkali resistance, high and low resistance, and after surface treatment, woody feeling can be produced, and the simulation degree is quite high, completely or partially replaced. Some wood-plastic profiles and logs have secondary processing properties that can be sawed, nailed, cut or screwed. For example: It is made into indoor and outdoor paving, floor, door and window frames, industrial pallets of various specifications, warehouse mats, various types of packaging boxes, etc.
- the flow rate ratio of the material in the device is stable, and the temperature is easily controlled and adjusted; the material does not cause carbonization, and the production cost is saved.
- This material and having a remodeling properties, scrap or waste products can be recycled by a re-extrusion ,, after crushing +, styling products manufactured profiles.
- the environmentally friendly porcelain-plastic polymer composite material has high economic added value after being manufactured into various profiles, and can be widely used in municipal, garden construction, building materials, home, environmental decoration and related industries.
- the social and environmental protection significance of the invention is very obvious, in line with the national "resource-saving, environment-friendly" development ideas, for the country “energy-saving emission reduction", "development of circular economy” Have a positive contribution.
- Example 1 The technical solutions of the present invention are further illustrated by the following examples, but are not limited to the embodiments.
- Example 1
- An environmentally friendly porcelain plastic polymer composite consists of the following components by weight: Thermoplastic PE 60
- a suitable method for preparing an environmentally-friendly porcelain-plastic sorghum composite material the steps of which are:
- thermoplastic the antioxidant 168 or the antioxidant 1010.
- UV-resistant agent UV-531 the decabromo alkane
- silicon arsenide ACR processing aid the pigment
- a preparation method of environmentally friendly porcelain plastic polymer composite material the specific steps are as follows:
- thermoplastic, antioxidant 168 or antioxidant 1010, UV-resistant agent UV-531, decabromo alkane, silicon oxychloride, ACR processing aid, pigment and high-mixer at 120° C-13 (TC mixed for 5 minutes;
- Antioxidant 1010 0.06
- Anti-UV agent UV-531 0. 12 decabromo alkane 1. 6 SiO 2 ⁇ 0. 7
- ACR processing aid 0. 5 pigment Appropriate amount An environmentally friendly porcelain plastic polymer composite material is prepared in the same manner as in Example 2.
- ACR processing aid 0. 4 pigment Appropriate amount An environmentally friendly porcelain plastic polymer composite material preparation method is the same as in the second embodiment.
- ACR processing aid 0. 3 pigment Appropriate amount An environmentally friendly porcelain plastic polymer composite material preparation method is the same as in the second embodiment.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Civil Engineering (AREA)
- Combustion & Propulsion (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2752416A CA2752416C (en) | 2009-02-13 | 2009-06-29 | Environmentally-friendly ceramic-plastic composite and the preparation method thereof |
JP2011549414A JP2012517510A (ja) | 2009-02-13 | 2009-06-29 | 環境保護型セラミックス・プラスチック複合材料処方及びその製造方法 |
EP09839861A EP2397516A4 (en) | 2009-02-13 | 2009-06-29 | ENVIRONMENTALLY FRIENDLY CERAMIC PLASTIC COMPOSITE MATERIAL AND METHOD OF MANUFACTURING THEREOF |
US13/201,222 US20120245255A1 (en) | 2009-02-13 | 2009-06-29 | Environmentally-friendly ceramic-plastic composite and the preparation method thereof |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200910014308.0 | 2009-02-13 | ||
CN2009100143080A CN101580615B (zh) | 2009-02-13 | 2009-02-13 | 一种环保型瓷塑高分子复合材料配方及其制备方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010091538A1 true WO2010091538A1 (zh) | 2010-08-19 |
Family
ID=41362940
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2009/000724 WO2010091538A1 (zh) | 2009-02-13 | 2009-06-29 | 环保型瓷塑复合材料及其制备方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20120245255A1 (zh) |
EP (1) | EP2397516A4 (zh) |
JP (1) | JP2012517510A (zh) |
KR (1) | KR20120027108A (zh) |
CN (1) | CN101580615B (zh) |
CA (1) | CA2752416C (zh) |
WO (1) | WO2010091538A1 (zh) |
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CN111995827A (zh) * | 2020-08-14 | 2020-11-27 | 福建悦科拓瓷塑科技有限公司 | 一种长寿命可再生环保瓷塑材料及其制备方法 |
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- 2009-02-13 CN CN2009100143080A patent/CN101580615B/zh active Active
- 2009-06-29 CA CA2752416A patent/CA2752416C/en not_active Expired - Fee Related
- 2009-06-29 US US13/201,222 patent/US20120245255A1/en not_active Abandoned
- 2009-06-29 EP EP09839861A patent/EP2397516A4/en not_active Withdrawn
- 2009-06-29 JP JP2011549414A patent/JP2012517510A/ja active Pending
- 2009-06-29 WO PCT/CN2009/000724 patent/WO2010091538A1/zh active Application Filing
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CN1363624A (zh) * | 2001-12-29 | 2002-08-14 | 中国科学院长春应用化学研究所 | 粉煤灰和废旧塑料复合制枕木的生产方法 |
CN1385465A (zh) * | 2002-05-16 | 2002-12-18 | 上海交通大学 | 脱墨污泥粉填充改性热塑性聚合物复合材料及制造方法 |
CN1500832A (zh) * | 2002-11-18 | 2004-06-02 | 华昌工贸有限公司 | 聚氯乙烯(pvc)塑木板材 |
CN1621637A (zh) * | 2004-12-17 | 2005-06-01 | 中国科学院长春应用化学研究所 | 固体废弃物模压复合法制备新型建筑板材 |
CN101224966A (zh) * | 2007-12-27 | 2008-07-23 | 中国科学院长春应用化学研究所 | 木硅塑网络地板及其制备方法 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012149180A (ja) * | 2011-01-19 | 2012-08-09 | Wpc Corporation Kk | 難燃性合成木材用の成形材料及び難燃性合成木材 |
CN111995827A (zh) * | 2020-08-14 | 2020-11-27 | 福建悦科拓瓷塑科技有限公司 | 一种长寿命可再生环保瓷塑材料及其制备方法 |
Also Published As
Publication number | Publication date |
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KR20120027108A (ko) | 2012-03-21 |
CN101580615A (zh) | 2009-11-18 |
EP2397516A1 (en) | 2011-12-21 |
JP2012517510A (ja) | 2012-08-02 |
CA2752416A1 (en) | 2010-08-19 |
EP2397516A4 (en) | 2012-11-21 |
CA2752416C (en) | 2013-12-10 |
US20120245255A1 (en) | 2012-09-27 |
CN101580615B (zh) | 2010-12-08 |
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