WO2008139602A1 - 繊維強化プラスチック成形材料及び繊維強化プラスチック成形品 - Google Patents

繊維強化プラスチック成形材料及び繊維強化プラスチック成形品 Download PDF

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Publication number
WO2008139602A1
WO2008139602A1 PCT/JP2007/059853 JP2007059853W WO2008139602A1 WO 2008139602 A1 WO2008139602 A1 WO 2008139602A1 JP 2007059853 W JP2007059853 W JP 2007059853W WO 2008139602 A1 WO2008139602 A1 WO 2008139602A1
Authority
WO
WIPO (PCT)
Prior art keywords
reinforced plastic
fiber reinforced
molding material
plastic molding
meth
Prior art date
Application number
PCT/JP2007/059853
Other languages
English (en)
French (fr)
Inventor
Kunihiro Kuroki
Naoki Ootsu
Original Assignee
Showa Highpolymer Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Highpolymer Co., Ltd. filed Critical Showa Highpolymer Co., Ltd.
Priority to US12/599,750 priority Critical patent/US8148469B2/en
Priority to PCT/JP2007/059853 priority patent/WO2008139602A1/ja
Priority to JP2009513936A priority patent/JPWO2008139602A1/ja
Priority to EP07743288A priority patent/EP2147950B1/en
Priority to AT07743288T priority patent/ATE557060T1/de
Priority to PT07743288T priority patent/PT2147950E/pt
Priority to KR1020097025879A priority patent/KR101457248B1/ko
Publication of WO2008139602A1 publication Critical patent/WO2008139602A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C08G59/1461—Unsaturated monoacids
    • C08G59/1466—Acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • C08J2363/10—Epoxy resins modified by unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C08J2375/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds

Abstract

　耐衝撃性、耐食性及び透明性の全てに優れた硬化物を与える繊維強化プラスチック成形材料を提供する。 　（Ａ）重量平均分子量が５００～６０００であるビニルエステル樹脂、（Ｂ）１分子中に少なくとも２つ以上のイソシアネート基を有するイソシアネート化合物と、１分子中に少なくとも１つ以上の水酸基を有する（メタ）アクリル化合物と、ポリエチレングリコールとを反応させて得られるウレタン（メタ）アクリル樹脂、（Ｃ）次の一般式（Ⅰ）：（式中、Ｒ１はヒドロキシアルキル基であり、Ｒ２はアルキル基又はヒドロキシアルキル基であり、Ｒ３はＨ又はＣＨ3である）で示される脂肪族アミン、（Ｄ）コバルト金属石鹸、及び（Ｅ）有機過酸化物を含むラジカル重合性樹脂組成物と、（Ｆ）ガラス繊維強化材とからなることを特徴とする繊維強化プラスチック成形材料とする。
PCT/JP2007/059853 2007-05-14 2007-05-14 繊維強化プラスチック成形材料及び繊維強化プラスチック成形品 WO2008139602A1 (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
US12/599,750 US8148469B2 (en) 2007-05-14 2007-05-14 Fiber reinforced plastic molding material and fiber reinforced plastic molded article
PCT/JP2007/059853 WO2008139602A1 (ja) 2007-05-14 2007-05-14 繊維強化プラスチック成形材料及び繊維強化プラスチック成形品
JP2009513936A JPWO2008139602A1 (ja) 2007-05-14 2007-05-14 繊維強化プラスチック成形材料及び繊維強化プラスチック成形品
EP07743288A EP2147950B1 (en) 2007-05-14 2007-05-14 Fiber reinforced plastic molding material and fiber reinforced plastic molded article
AT07743288T ATE557060T1 (de) 2007-05-14 2007-05-14 Formmasse aus faserverstärktem kunststoff und formkörper aus faserverstärktem kunststoff
PT07743288T PT2147950E (pt) 2007-05-14 2007-05-14 Material plástico reforçado com fibras para moldação e artigo moldado de plástico reforçado com fibras
KR1020097025879A KR101457248B1 (ko) 2007-05-14 2007-05-14 섬유 강화 플라스틱 성형 재료 및 섬유 강화 플라스틱 성형품

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2007/059853 WO2008139602A1 (ja) 2007-05-14 2007-05-14 繊維強化プラスチック成形材料及び繊維強化プラスチック成形品

Publications (1)

Publication Number Publication Date
WO2008139602A1 true WO2008139602A1 (ja) 2008-11-20

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Application Number Title Priority Date Filing Date
PCT/JP2007/059853 WO2008139602A1 (ja) 2007-05-14 2007-05-14 繊維強化プラスチック成形材料及び繊維強化プラスチック成形品

Country Status (7)

Country Link
US (1) US8148469B2 (ja)
EP (1) EP2147950B1 (ja)
JP (1) JPWO2008139602A1 (ja)
KR (1) KR101457248B1 (ja)
AT (1) ATE557060T1 (ja)
PT (1) PT2147950E (ja)
WO (1) WO2008139602A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130190453A1 (en) * 2010-02-11 2013-07-25 Arie Boer Den Two component resin system
KR20140085571A (ko) 2011-11-07 2014-07-07 쇼와 덴코 가부시키가이샤 압력 용기용 수지 조성물 및 압력 용기
WO2017086231A1 (ja) * 2015-11-16 2017-05-26 日本ユピカ株式会社 繊維強化プラスチック成形品、及びその製造方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115594819A (zh) * 2022-10-25 2023-01-13 广东粤港澳大湾区黄埔材料研究院（Cn） 一种乙烯基酯树脂增韧剂、乙烯基酯树脂及其制备方法

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Publication number Priority date Publication date Assignee Title
JPS62292839A (ja) * 1986-06-12 1987-12-19 Toa Nenryo Kogyo Kk 繊維強化複合材料
JPH02120312A (ja) * 1988-10-31 1990-05-08 Dainippon Ink & Chem Inc エポキシ樹脂組成物及びこれを用いたプリプレグと積層板の製法
JP2001500177A (ja) 1996-09-06 2001-01-09 ザ・ダウ・ケミカル・カンパニー エポキシビニルエステルとウレタンビニルエステル樹脂類との混合物を基にした熱硬化性樹脂類
JP2002138121A (ja) 2000-11-06 2002-05-14 Japan U-Pica Co Ltd 熱硬化性樹脂組成物及びそれを用いた人工大理石
JP2003128729A (ja) 2001-10-29 2003-05-08 Mitsui Chemicals Inc 高耐衝撃性メタクリル樹脂の製造法
JP2004263025A (ja) * 2003-02-28 2004-09-24 Dainippon Ink & Chem Inc プリプレグ及びそれを用いるｆｒｐ成形品
JP2006290640A (ja) * 2005-04-06 2006-10-26 Showa Highpolymer Co Ltd 湿潤体用樹脂組成物およびその構造体

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US4824919A (en) * 1983-06-09 1989-04-25 The Dow Chemical Company Toughening of cured vinyl ester resins by inclusion in the uncured resins of oligomeric vinyl-reactive urethanes which phase out upon curing
JPS60248771A (ja) * 1984-05-23 1985-12-09 Nippon Shokubai Kagaku Kogyo Co Ltd 透明性の高い難燃性繊維強化熱硬化性樹脂物品
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JPS62292839A (ja) * 1986-06-12 1987-12-19 Toa Nenryo Kogyo Kk 繊維強化複合材料
JPH02120312A (ja) * 1988-10-31 1990-05-08 Dainippon Ink & Chem Inc エポキシ樹脂組成物及びこれを用いたプリプレグと積層板の製法
JP2001500177A (ja) 1996-09-06 2001-01-09 ザ・ダウ・ケミカル・カンパニー エポキシビニルエステルとウレタンビニルエステル樹脂類との混合物を基にした熱硬化性樹脂類
JP2002138121A (ja) 2000-11-06 2002-05-14 Japan U-Pica Co Ltd 熱硬化性樹脂組成物及びそれを用いた人工大理石
JP2003128729A (ja) 2001-10-29 2003-05-08 Mitsui Chemicals Inc 高耐衝撃性メタクリル樹脂の製造法
JP2004263025A (ja) * 2003-02-28 2004-09-24 Dainippon Ink & Chem Inc プリプレグ及びそれを用いるｆｒｐ成形品
JP2006290640A (ja) * 2005-04-06 2006-10-26 Showa Highpolymer Co Ltd 湿潤体用樹脂組成物およびその構造体

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"Polyester resin handbook", 1988, NIKKAN KOGYO SHIMBUN, LTD.
SIKIZAI KYOKAI: "Toryo Yogo Jiten", 1993

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130190453A1 (en) * 2010-02-11 2013-07-25 Arie Boer Den Two component resin system
KR20140085571A (ko) 2011-11-07 2014-07-07 쇼와 덴코 가부시키가이샤 압력 용기용 수지 조성물 및 압력 용기
WO2017086231A1 (ja) * 2015-11-16 2017-05-26 日本ユピカ株式会社 繊維強化プラスチック成形品、及びその製造方法
JPWO2017086231A1 (ja) * 2015-11-16 2018-08-30 日本ユピカ株式会社 繊維強化プラスチック成形品、及びその製造方法

Also Published As

Publication number Publication date
KR20100017773A (ko) 2010-02-16
US8148469B2 (en) 2012-04-03
US20100311887A1 (en) 2010-12-09
KR101457248B1 (ko) 2014-10-31
ATE557060T1 (de) 2012-05-15
JPWO2008139602A1 (ja) 2010-07-29
EP2147950A4 (en) 2011-04-13
PT2147950E (pt) 2012-05-22
EP2147950B1 (en) 2012-05-09
EP2147950A1 (en) 2010-01-27

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