WO2008136262A1 - (メタ)アクリレート化合物、それを含有する樹脂組成物及びその硬化物並びに光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物 - Google Patents

(メタ)アクリレート化合物、それを含有する樹脂組成物及びその硬化物並びに光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物 Download PDF

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Publication number
WO2008136262A1
WO2008136262A1 PCT/JP2008/057407 JP2008057407W WO2008136262A1 WO 2008136262 A1 WO2008136262 A1 WO 2008136262A1 JP 2008057407 W JP2008057407 W JP 2008057407W WO 2008136262 A1 WO2008136262 A1 WO 2008136262A1
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WIPO (PCT)
Prior art keywords
resin composition
cured product
optical lens
lens sheet
energy ray
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PCT/JP2008/057407
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English (en)
French (fr)
Inventor
Hideaki Kametani
Satoshi Ogi
Kikuo Imazumi
Noriko Kiyoyanagi
Junko Ichikawa
Takafumi Mizuguchi
Ritsuko Shitara
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Nippon Kayaku Kabushiki Kaisha
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Priority to KR1020157000682A priority Critical patent/KR101573754B1/ko
Priority to JP2009512915A priority patent/JPWO2008136262A1/ja
Priority to CN200880013424.4A priority patent/CN101675089B/zh
Publication of WO2008136262A1 publication Critical patent/WO2008136262A1/ja

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67Unsaturated compounds having active hydrogen
    • C08G18/68Unsaturated polyesters
    • C08G18/683Unsaturated polyesters containing cyclic groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/58Epoxy resins
    • C08G18/581Reaction products of epoxy resins with less than equivalent amounts of compounds containing active hydrogen added before or during the reaction with the isocyanate component
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67Unsaturated compounds having active hydrogen
    • C08G18/671Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C08G18/6725Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen containing ester groups other than acrylate or alkylacrylate ester groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7678Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing condensed aromatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14Polycondensates modified by chemical after-treatment
    • C08G59/1433Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1477Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

【課題】  透明性に優れ、樹脂単独で高い屈折率と高い密着性を有し、かつ十分な硬度を有する硬化物を与える感光性樹脂、及び離型性、型再現性、基材への密着性に優れ、高屈折率でガラス転移点が高く、耐光性の良い光学レンズシート用樹脂組成物を提供する。 【解決手段】 下記一般式(1) で表される化合物をエピハロヒドリンと反応させて得られるエポキシ樹脂(a)と分子中にエチレン性不飽和基を有するモノカルボン酸化合物(b)と芳香族系ポリイソシアネート化合物(c)を反応させて得られることを特徴とするウレタン化合物(A)、並びにこのウレタン化合物(A)及び光重合開始剤(B)を含むことを特徴とする光学レンズシート用エネルギー線硬化型樹脂組成物。
PCT/JP2008/057407 2007-04-27 2008-04-16 (メタ)アクリレート化合物、それを含有する樹脂組成物及びその硬化物並びに光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物 WO2008136262A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR1020157000682A KR101573754B1 (ko) 2007-04-27 2008-04-16 (메타)아크릴레이트 화합물, 이를 함유하는 수지 조성물, 그 경화물 및 광학 렌즈 시트용 에너지선 경화형 수지 조성물 및 그 경화물
JP2009512915A JPWO2008136262A1 (ja) 2007-04-27 2008-04-16 (メタ)アクリレート化合物、それを含有する樹脂組成物及びその硬化物並びに光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物
CN200880013424.4A CN101675089B (zh) 2007-04-27 2008-04-16 (甲基)丙烯酸酯化合物、含有该化合物的树脂组合物及其固化物以及光学透镜片用能量射线固化型树脂组合物及其固化物

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007-118233 2007-04-27
JP2007118233 2007-04-27
JP2007186585 2007-07-18
JP2007-186585 2007-07-18

Publications (1)

Publication Number Publication Date
WO2008136262A1 true WO2008136262A1 (ja) 2008-11-13

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JP (1) JPWO2008136262A1 (ja)
KR (2) KR101573754B1 (ja)
CN (1) CN101675089B (ja)
TW (1) TW200911862A (ja)
WO (1) WO2008136262A1 (ja)

Cited By (9)

* Cited by examiner, † Cited by third party
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JP2010191427A (ja) * 2009-02-17 2010-09-02 Bayer Materialscience Ag 新規なホログラフィック媒体およびフォトポリマー
CN101885809A (zh) * 2009-05-13 2010-11-17 日本化药株式会社 能量射线固化型树脂组合物及其固化物和光学透镜片
WO2011126066A1 (ja) * 2010-04-09 2011-10-13 日本化薬株式会社 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物
JP2012226040A (ja) * 2011-04-18 2012-11-15 Nippon Kayaku Co Ltd 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物
JP2013028662A (ja) * 2011-07-27 2013-02-07 Nippon Kayaku Co Ltd 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物
CN103183809A (zh) * 2011-12-27 2013-07-03 日本化药株式会社 透明电路基板用环氧树脂组合物及层叠玻璃片
KR101558338B1 (ko) 2009-02-18 2015-10-07 닛뽄 가야쿠 가부시키가이샤 에너지선 경화형 수지 조성물 및, 그의 경화물 및 광학 렌즈 시트
KR20150131994A (ko) 2014-05-16 2015-11-25 닛뽄 가야쿠 가부시키가이샤 (메타)아크릴레이트 화합물 및 그것을 함유하는 활성 에너지선 경화형 수지 조성물 그리고 그의 경화물
KR20160023555A (ko) 2014-08-22 2016-03-03 닛뽄 가야쿠 가부시키가이샤 에폭시(메타)아크릴레이트 화합물 및 그것을 함유하는 수지 조성물 그리고 그의 경화물, 컬러 필터 및 표시 소자

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JP5696858B2 (ja) * 2010-11-30 2015-04-08 日産化学工業株式会社 マイクロレンズ用感光性樹脂組成物
JP5099280B1 (ja) * 2011-05-18 2012-12-19 Dic株式会社 ラジカル重合性組成物、硬化物及びプラスチックレンズ
JP5897915B2 (ja) * 2012-01-27 2016-04-06 株式会社タムラ製作所 紫外線硬化性透明樹脂組成物
JP2013168395A (ja) * 2012-02-14 2013-08-29 Taiyo Holdings Co Ltd めっきレジスト用樹脂組成物、多層プリント配線板及び多層プリント配線板の製造方法
KR101749504B1 (ko) * 2012-03-12 2017-06-21 디아이씨 가부시끼가이샤 라디칼 중합성 조성물, 그 경화물 및 플라스틱 렌즈
JP6049055B2 (ja) * 2012-08-08 2016-12-21 日本化薬株式会社 紫外線硬化型樹脂組成物、硬化物及び物品
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JP6128604B2 (ja) * 2013-12-05 2017-05-17 日本化薬株式会社 樹脂組成物
JP6172753B2 (ja) * 2014-03-03 2017-08-02 日本化薬株式会社 ポリウレタン化合物及びそれを含有する樹脂組成物
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JP2019077605A (ja) * 2017-10-26 2019-05-23 住友電気工業株式会社 紫外線硬化型樹脂組成物及び光ファイバ
CN109810668A (zh) * 2019-01-29 2019-05-28 宁波路宝科技实业集团有限公司 一种聚氨酯粘结剂及其制备方法
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010191427A (ja) * 2009-02-17 2010-09-02 Bayer Materialscience Ag 新規なホログラフィック媒体およびフォトポリマー
KR101558338B1 (ko) 2009-02-18 2015-10-07 닛뽄 가야쿠 가부시키가이샤 에너지선 경화형 수지 조성물 및, 그의 경화물 및 광학 렌즈 시트
CN101885809A (zh) * 2009-05-13 2010-11-17 日本化药株式会社 能量射线固化型树脂组合物及其固化物和光学透镜片
JP2010265346A (ja) * 2009-05-13 2010-11-25 Nippon Kayaku Co Ltd 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物
WO2011126066A1 (ja) * 2010-04-09 2011-10-13 日本化薬株式会社 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物
JP5744847B2 (ja) * 2010-04-09 2015-07-08 日本化薬株式会社 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物
JP2012226040A (ja) * 2011-04-18 2012-11-15 Nippon Kayaku Co Ltd 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物
JP2013028662A (ja) * 2011-07-27 2013-02-07 Nippon Kayaku Co Ltd 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物
CN103183809A (zh) * 2011-12-27 2013-07-03 日本化药株式会社 透明电路基板用环氧树脂组合物及层叠玻璃片
KR20150131994A (ko) 2014-05-16 2015-11-25 닛뽄 가야쿠 가부시키가이샤 (메타)아크릴레이트 화합물 및 그것을 함유하는 활성 에너지선 경화형 수지 조성물 그리고 그의 경화물
JP2015232126A (ja) * 2014-05-16 2015-12-24 日本化薬株式会社 (メタ)アクリレート化合物及びそれを含有する活性エネルギー線硬化型樹脂組成物並びにその硬化物
KR102245467B1 (ko) 2014-05-16 2021-04-27 닛뽄 가야쿠 가부시키가이샤 (메타)아크릴레이트 화합물 및 그것을 함유하는 활성 에너지선 경화형 수지 조성물 그리고 그의 경화물
KR20160023555A (ko) 2014-08-22 2016-03-03 닛뽄 가야쿠 가부시키가이샤 에폭시(메타)아크릴레이트 화합물 및 그것을 함유하는 수지 조성물 그리고 그의 경화물, 컬러 필터 및 표시 소자

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KR101573754B1 (ko) 2015-12-04
CN101675089A (zh) 2010-03-17
KR101635801B1 (ko) 2016-07-04
TW200911862A (en) 2009-03-16
JPWO2008136262A1 (ja) 2010-07-29
KR20100014469A (ko) 2010-02-10
CN101675089B (zh) 2015-06-17
KR20150013355A (ko) 2015-02-04

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