WO2008090906A1 - （メタ）アクリル系重合体粒子、その製造方法、（メタ）アクリル系重合体粒子を用いたプラスチゾル組成物及びこれを用いた物品 - Google Patents

（メタ）アクリル系重合体粒子、その製造方法、（メタ）アクリル系重合体粒子を用いたプラスチゾル組成物及びこれを用いた物品 Download PDF

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Publication number
WO2008090906A1
WO2008090906A1 PCT/JP2008/050853 JP2008050853W WO2008090906A1 WO 2008090906 A1 WO2008090906 A1 WO 2008090906A1 JP 2008050853 W JP2008050853 W JP 2008050853W WO 2008090906 A1 WO2008090906 A1 WO 2008090906A1
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particles
meth
compositions
production
acrylic polymer
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PCT/JP2008/050853
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English (en)
French (fr)
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Satoshi Mae
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Mitsubishi Rayon Co., Ltd.
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Priority to EP08703697A priority Critical patent/EP2116573B1/en
Priority to KR1020097017492A priority patent/KR101429790B1/ko
Priority to US12/524,255 priority patent/US8039541B2/en
Priority to JP2008507291A priority patent/JP5597923B2/ja
Priority to CN200880002865.4A priority patent/CN101589105B/zh
Publication of WO2008090906A1 publication Critical patent/WO2008090906A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
    • C09K2200/06—Macromolecular organic compounds, e.g. prepolymers
    • C09K2200/0615—Macromolecular organic compounds, e.g. prepolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09K2200/0625—Polyacrylic esters or derivatives thereof

Abstract

　貯蔵時においてゲル化を抑制しゾル状を維持することができる貯蔵安定性に優れ、特に４０°C以上の環境における貯蔵安定性に優れると共に、これを用いて得られる成形体において柔軟性を有し耐チッピング性に優れ、工業的に極めて有用なプラスチゾル用の（メタ）アクリル系重合体粒子や、その製造方法、これを用いたプラスチゾル組成物を提供することにある。 　単量体又は単量体混合物（Ａ）を重合して得られる重合体（ａ）の存在下、単量体又は単量体混合物（Ｂ）を重合して重合体（ｂ）を形成する（メタ）アクリル系重合体粒子の製造方法であって、重合体（ａ）のＦＯＸの式から求められるガラス転移温度（Ｔｇ）が９０°C以上であり、重合体（ａ）の溶解度パラメーターが１９．９０（Ｊ／ｃｍ３）１／２以下であり、重合体（ｂ）の溶解度パラメーターが２０．２２（Ｊ／ｃｍ３）１／２以上である。
PCT/JP2008/050853 2007-01-23 2008-01-23 （メタ）アクリル系重合体粒子、その製造方法、（メタ）アクリル系重合体粒子を用いたプラスチゾル組成物及びこれを用いた物品 WO2008090906A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP08703697A EP2116573B1 (en) 2007-01-23 2008-01-23 (meth)acrylic polymer particles, process for production thereof, plastisol compositions made by using the particles, and articles made by using the compositions
KR1020097017492A KR101429790B1 (ko) 2007-01-23 2008-01-23 (메트)아크릴계 중합체 입자, 그 제조 방법, (메트)아크릴계 중합체 입자를 이용한 플라스티졸 조성물 및 이것을 이용한 물품
US12/524,255 US8039541B2 (en) 2007-01-23 2008-01-23 (Meth)acrylic polymer particle, method for producing the same, plastisol composition made from the polymer particle, and article made from the plastisol composition
JP2008507291A JP5597923B2 (ja) 2007-01-23 2008-01-23 プラスチゾル組成物及びこれを用いた物品
CN200880002865.4A CN101589105B (zh) 2007-01-23 2008-01-23 (甲基)丙烯酸系聚合物粒子、其制造方法、使用(甲基)丙烯酸系聚合物粒子的增塑溶胶组合物以及使用其的物品

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007012646 2007-01-23
JP2007-012646 2007-01-23

Publications (1)

Publication Number Publication Date
WO2008090906A1 true WO2008090906A1 (ja) 2008-07-31

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PCT/JP2008/050853 WO2008090906A1 (ja) 2007-01-23 2008-01-23 （メタ）アクリル系重合体粒子、その製造方法、（メタ）アクリル系重合体粒子を用いたプラスチゾル組成物及びこれを用いた物品

Country Status (6)

Country Link
US (1) US8039541B2 (ja)
EP (1) EP2116573B1 (ja)
JP (2) JP5597923B2 (ja)
KR (1) KR101429790B1 (ja)
CN (1) CN101589105B (ja)
WO (1) WO2008090906A1 (ja)

Cited By (6)

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Publication number Priority date Publication date Assignee Title
JP2008285542A (ja) * 2007-05-16 2008-11-27 Mitsubishi Rayon Co Ltd ビニル系重合体及びその製造方法
JP2010065139A (ja) * 2008-09-10 2010-03-25 Mitsubishi Rayon Co Ltd ラテックスの製造方法、及びアクリルゾル組成物
WO2011155566A1 (ja) 2010-06-10 2011-12-15 三菱レイヨン株式会社 アクリル系重合体の製造方法、この製造方法により得られるアクリル系重合体及びこれを用いたプラスチゾル組成物
WO2013077293A1 (ja) 2011-11-22 2013-05-30 三菱レイヨン株式会社 アクリル系重合体の製造方法、アクリル系重合体、およびプラスチゾル組成物
JP2013147550A (ja) * 2012-01-18 2013-08-01 Mitsubishi Rayon Co Ltd アクリル系重合体の製造方法、アクリル系重合体及びプラスチゾル組成物
WO2015174372A1 (ja) * 2014-05-12 2015-11-19 三菱レイヨン株式会社 アクリル系重合体、その製造方法及びそのアクリル系重合体を含むプラスチゾル組成物

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US9914795B2 (en) * 2013-01-09 2018-03-13 Isp Investments Llc Polymers polymerized from at least four monomers, and compositions and uses thereof
US9976047B2 (en) 2013-06-25 2018-05-22 Polyone Corporation Acrylic-urethane IPN plastisol
US8877848B1 (en) * 2013-07-26 2014-11-04 Ppg Industries Ohio, Inc. Aqueous vibration damping compositions
WO2018009683A1 (en) 2016-07-06 2018-01-11 Eastman Chemical Company (meth)acrylic oligomers
KR102053052B1 (ko) 2018-05-31 2020-01-08 안성준 화장솜 제조장치

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008285542A (ja) * 2007-05-16 2008-11-27 Mitsubishi Rayon Co Ltd ビニル系重合体及びその製造方法
JP2010065139A (ja) * 2008-09-10 2010-03-25 Mitsubishi Rayon Co Ltd ラテックスの製造方法、及びアクリルゾル組成物
WO2011155566A1 (ja) 2010-06-10 2011-12-15 三菱レイヨン株式会社 アクリル系重合体の製造方法、この製造方法により得られるアクリル系重合体及びこれを用いたプラスチゾル組成物
WO2013077293A1 (ja) 2011-11-22 2013-05-30 三菱レイヨン株式会社 アクリル系重合体の製造方法、アクリル系重合体、およびプラスチゾル組成物
US9453096B2 (en) 2011-11-22 2016-09-27 Mitsubishi Rayon Co., Ltd. Method for producing acrylic polymer, acrylic polymer, and plastisol composition
US9738743B2 (en) 2011-11-22 2017-08-22 Mitsubishi Chemical Corporation Method for producing acrylic polymer, acrylic polymer, and plastisol composition
JP2013147550A (ja) * 2012-01-18 2013-08-01 Mitsubishi Rayon Co Ltd アクリル系重合体の製造方法、アクリル系重合体及びプラスチゾル組成物
WO2015174372A1 (ja) * 2014-05-12 2015-11-19 三菱レイヨン株式会社 アクリル系重合体、その製造方法及びそのアクリル系重合体を含むプラスチゾル組成物
JPWO2015174372A1 (ja) * 2014-05-12 2017-04-20 三菱レイヨン株式会社 アクリル系重合体、その製造方法及びそのアクリル系重合体を含むプラスチゾル組成物

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US8039541B2 (en) 2011-10-18
JP2014167131A (ja) 2014-09-11
CN101589105B (zh) 2014-08-27
JP5958499B2 (ja) 2016-08-02
JPWO2008090906A1 (ja) 2010-05-20
EP2116573A1 (en) 2009-11-11
KR101429790B1 (ko) 2014-08-18
JP5597923B2 (ja) 2014-10-01
CN101589105A (zh) 2009-11-25

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