WO2008072672A1 - Modificateur de cheveux, produit d'entretien de chevelure et procédé de modification des cheveux - Google Patents

Modificateur de cheveux, produit d'entretien de chevelure et procédé de modification des cheveux Download PDF

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Publication number
WO2008072672A1
WO2008072672A1 PCT/JP2007/073969 JP2007073969W WO2008072672A1 WO 2008072672 A1 WO2008072672 A1 WO 2008072672A1 JP 2007073969 W JP2007073969 W JP 2007073969W WO 2008072672 A1 WO2008072672 A1 WO 2008072672A1
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WIPO (PCT)
Prior art keywords
hair
alcohol
acid
modifier
unsaturated
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PCT/JP2007/073969
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English (en)
Japanese (ja)
Inventor
Eiji Watanabe
Katsuhiko Matsuba
Takeshi Noguchi
Yoshimi Nakamura
Mitsuru Isobe
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Hoyu Co., Ltd.
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Application filed by Hoyu Co., Ltd. filed Critical Hoyu Co., Ltd.
Publication of WO2008072672A1 publication Critical patent/WO2008072672A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • the present invention relates to a hair modifying agent, a hair cosmetic, and a hair modifying method for reducing or repairing damage to the hair surface or protecting the hair surface.
  • the damaged and ionized hair surface is hydrophobized based on electrostatic interactions such as ion binding by STAC and physical phenomena such as adsorption.
  • electrostatic interactions such as ion binding by STAC and physical phenomena such as adsorption.
  • the frictional resistance of the hair surface is reduced compared to when it is damaged, and the hair surface is modified.
  • a hair modifier using a combination of gidarcosyl gallic acid (DGA) has been developed for the purpose of further strengthening the interaction between the hair surface and STAC (see Non-Patent Document 1).
  • the hair modifier using the electrostatic interaction due to the ionic bond, hydrogen bond or the like has a temporary effect, but the hair surface is covered by daily hair washing or the like.
  • Hair modifiers such as STAC and DGA are easily washed away.
  • the hydrophilic portion and the ionic portion of the hair surface are exposed again, and the hairiness, cohesiveness, and deterioration of finger touch are regenerated. Therefore, the use of the above-mentioned hair modifying agent is not a fundamental solution in the modification of the hair surface!
  • the sustainability of the hair modifying effect is low! / And! / It was.
  • hair cosmetics that allow protein hydrolyzate and amino acids to be applied to hair as a hair damage repair component can obtain hair effects, resilience and elasticity, but the sustainability of the effect is satisfactory! /, It was not a spider.
  • Patent Document 2 specifically discloses a method for treating keratin fibers in which a covalent bond is formed by an acylation reaction using an acid halide.
  • acid halides are easily used from the standpoints of stability in aqueous solutions used for normal hair, sensitization to the human body, and safety such as mutagenicity. I could't.
  • Non-Patent Document 1 Yuichi NISHIDA et al., "Repairing Effects of Diglucosyl Gallic Acid on Coloring-Damaged Hair", JOURNAL OF OLEO SCIENCE, Vol.53, No.6, 295—304 (2004)
  • Patent Document 1 Japanese Patent Laid-Open No. 11 139941
  • Patent Document 2 JP 2000-226763 Koyuki
  • the present invention provides a hair modifier that essentially modifies damaged hair, improves the cohesiveness, moisture retention, and elasticity of the hair, and has excellent durability.
  • a hair cosmetic containing a modifying agent and a method for modifying the hair using the hair cosmetic. Let's call it Mejiro.
  • the present inventors have found that the ester compound of an unsaturated dicarboxylic acid and a saturated or unsaturated alcohol having a linear or branched shape, and the deficiencies of conventional hair modifiers.
  • the present invention is completed by overcoming and finding that the hair modifying agent has convenience during treatment and safety to living body, and further has a remarkably excellent modifying effect on damaged hair. It came to.
  • a hair modifier containing an ester compound with a saturated or unsaturated alcohol having a branched shape is provided.
  • the ester compound is a diester compound, and at least one of the two carboxyl groups of the unsaturated dicarboxylic acid forms an ester bond with the saturated or unsaturated alcohol.
  • the two carboxyl groups of the unsaturated dicarboxylic acid form an ester bond with the saturated or unsaturated alcohol.
  • the unsaturated dicarboxylic acid is maleic acid.
  • the saturated alcohol having a saturated or unsaturated alcohol power of 18 to 22 carbon atoms and having a straight chain or branched chain is preferable.
  • the saturated or unsaturated alcohol is an unsaturated alcohol having 18 to 22 carbon atoms and linear or branched.
  • the unsaturated alcohol is oleyl alcohol.
  • the ester compound is dioleyl maleate.
  • a hair cosmetic containing the hair modifying agent there is provided a hair modification method comprising the step of applying the hair cosmetic composition to hair.
  • hair modifier means an agent that can improve hair cohesion, moisture retention, elasticity, etc. by reducing or repairing hair damage or protecting the hair surface.
  • hair cosmetics Means cosmetics that come into contact with or are configured to come into contact with keratinous substances present in the human body, including hair, body hair, and the like. Examples of such hair cosmetics include hair care agents and styling agents. Examples of hair care agents include shampoos, rinses, and treatments. Examples of styling agents include jewels, emulsions, mousses, and waxes.
  • hair cosmetics in addition to the above hair care agents and styling agents, it is added as an additive component to hair dyes such as hair dyes, hair manicures, permanent agents, hair straighteners, etc. And a topical cosmetic composition.
  • the hair modifier according to the present embodiment includes an unsaturated dicarboxylic acid having 4 to 6 carbon atoms and a saturated or unsaturated structure having 12 to 24 carbon atoms and linear or branched. Contains ester compounds with alcohol. In this ester compound, at least one of the two carboxyl groups of the unsaturated dicarboxylic acid forms an ester bond with the saturated or unsaturated alcohol.
  • the hair cosmetic composition according to this embodiment contains the hair modifier, that is, the ester compound.
  • Examples of the ester compound include a diester compound in which two carboxyl groups of the unsaturated dicarboxylic acid form an ester bond with the saturated or unsaturated alcohol.
  • a diester compound which forms an ester bond with an alcohol other than the saturated or unsaturated alcohol.
  • the ester compound only one of the two carboxyl groups of the unsaturated dicarboxylic acid forms an ester bond with the saturated or unsaturated alcohol, and the other.
  • These carboxyl groups form an ester bond! /, NA! /, Monoester compounds.
  • each of the diester compounds is preferred.
  • ester compounds in the hair modifier and hair cosmetic according to the present embodiment are not particularly limited, and are produced from an unsaturated dicarboxylic acid corresponding to the ester compound and a saturated or unsaturated alcohol. Ester compound having ester bond If it is.
  • the diester compound in which the two carboxyl groups of the unsaturated dicarboxylic acid form an ester bond with the saturated or unsaturated alcohol can be obtained, for example, by the following method. That is, this diester compound is obtained by dehydrating an unsaturated dicarboxylic acid or unsaturated dicarboxylic acid anhydride and a long-chain alcohol compound in an azeotropic dewaterable solvent to which a catalyst is added, and then removing the solvent. Can be obtained. In the production of this diester compound, for example, toluene may be mentioned as the azeotropic dehydrating solvent.
  • a diester compound forming an ester bond with alcohol can be obtained, for example, by the following method. That is, the diester compound is obtained by subjecting an unsaturated dicarboxylic acid or unsaturated dicarboxylic acid anhydride and two or more alcohol compounds to dehydration esterification in a solvent capable of azeotropic dehydration to which a catalyst has been added, followed by distillation or It can be obtained by separation and purification with a silica gel column using an appropriate developing solvent. In the production of this diester compound, for example, toluene is mentioned as the azeotropic dehydrating solvent.
  • Examples of the unsaturated dicarboxylic acid include fumaric acid, maleic acid, acetylenedicarboxylic acid, itaconic acid, citraconic acid, trans-monoglutaconic acid, trans-trans-mumuconic acid, and cis-cis-muconic acid. It is done. Of these, maleic acid is preferred.
  • saturated or unsaturated alcohol for example, lauryl alcohol, 1 tridecano monore, myristino rare renore, 1-penda de cannole, cetino derenore, 1-heptadecanol, stearyl alcohol, 1 nonade Forced alcohol, arakin alcohol, 1-to-1 nicosanol, 1-to-co-co-anol, 1-tricosanol, 1-tetracosanol, 2--dodecanol, 4-methyl 1-dodecanol, 2-tridecanol, 4-methylenole 1-tridecanol, 2-tetra Decanol, 4-Methyl-1-tetradecanol, 2 Pentadecanol, 2 Hexadecanol, 7 Methyl-1 Monohexadenol, 4 Heptadecanol, Isostearyl alcohol, 2 Octadecanol, 2 Nonadecanol, 9 -Mech
  • saturated or unsaturated alcohols having a carbon number of 18 to 22 and having a linear or branched shape are preferred.
  • Unsaturated having a linear or branched shape having a carbon number of 18 to 22 Alcohol is particularly preferred. These alcohols may be used alone or in combination of two or more.
  • alcohols other than the saturated or unsaturated alcohols include alcohols having 1 to 11 carbon atoms. As such alcohols, alcohols having carbon numbers of 8 to 8 are preferred. Specifically, methyl alcohol, ethyl alcohol, isopropyl alcohol and octyl alcohol are preferred! /.
  • the diester compound in which two carboxyl groups of the unsaturated dicarboxylic acid form an ester bond with the saturated or unsaturated alcohol is exemplified as a specific example of the unsaturated dicarboxylic acid.
  • Examples thereof include diester compounds of the compound and the compounds mentioned as specific examples of the saturated or unsaturated alcohol.
  • the diester compound examples include dilauryl maleate, dimyristyl maleate, dicetyl maleate, distearyl maleate, dibehenyl maleate, dioleyl maleate, dilinoleyl maleate, dilinolenyl maleate, Di (11 icosenyl) maleate, diisostearyl maleate, di (3, 7, 11, 15 tetramethyl-2-hexadecenyl), cetyloleyl maleate, oleylstearyl maleate, linoleinoleinorelate maleate, Icosenolinoleinore maleate, linolenoleolein maleate, linoleyl maleol maleate, linoleyl maleate maleate, dilauryl fumarate, dimyristyl fumarate, dicetyl fumarate, distearyl fumarate, To Give Fumarate Ninore , Diisostearyl
  • ester compounds of the unsaturated dicarboxylic acid and the saturated alcohol and the ester compounds of the unsaturated dicarboxylic acid and the unsaturated alcohol the touch of hair, specifically the feeling of unity and moistness of the hair.
  • an ester compound of an unsaturated dicarboxylic acid and an unsaturated alcohol is preferred because of its excellent softness.
  • the diester compound formed include ethylolyl maleate, ethyl stearyl maleate, ethylisostearyl maleate, ethyl cetinole maleate, and maleate.
  • examples include cutylolyl, octylstearyl maleate, and octylisostearyl maleate.
  • ester compounds may be contained alone in the hair modifier or hair cosmetic, or may be contained in combination of two or more. Since the content of the ester compound in the hair modifying agent or the hair cosmetic composition can effectively improve the moisture feeling and fingering property of the hair, and can give the hair a favorable feel. Preferably, it is 0.0;! To 20% by mass, more preferably 0.05 to 10% by mass, and particularly preferably 0.;! To 5% by mass.
  • the hair modifying agent and the hair cosmetic may contain at least one component selected from an oily component, a surfactant, and a polymer compound as a component other than the ester compound.
  • a polymer compound include a cationic polymer, an anionic polymer, an amphoteric polymer, and a nonionic polymer.
  • the oily component imparts moisture to the hair and improves the finger penetration of the hair.
  • the oil component include fats and oils, waxes, higher alcohols, higher fatty acids, alkyl glycerinol ethers, esters, hydrocarbons, and silicones.
  • oils and fats include olive oil, camellia oil, shea fat, almond oil, tea seed oil, sasanqua oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, beef fat, cocoa butter, corn oil, Peanut oil, Rapeseed oil, Rice bran oil, Rice germ oil, Wheat germ oil, Roh, Barley oil, Grape seed oil, avocado oil, Power lot oil, Magadamia nut oil, Castor oil, Amani oil, Palm oil, Mink Oil, and egg yolk oil.
  • waxes include beeswax, candelilla wax, carnauba wax, jojoba oil, and lanolin.
  • Examples of the higher alcohol include lauryl alcohol, myristino-leanolone, ceteno-leno-no-conole (setano-monore), stearino-leano-leconole, ceto-stearino-leno-no-conole, araquinano-reconole, behenino-leano.
  • Reconole 2-hexinoredecanol, isostearinoreanolol, 2-otatildodecanol, decyltetradecanol, oleyl alcohol, linoleyl alcohol, linolenyl alcohol, and lanolin alcohol .
  • Examples of the higher fatty acid include lauric acid, myristic acid, normitic acid, stearic acid, behenic acid, isostearic acid, hydroxystearic acid, oleic acid, undecylenic acid, and linoleic acid.
  • Examples include oxalic acid, ricinoleic acid, and lanolin fatty acid.
  • alkyl glyceryl ether examples include batyl alcohol (monostearyl glyceryl ether), chyminole alcohol (monocetyl dariserinoreether), and seraquinolea.
  • esters examples include diisopropyl adipate, diisobutyl adipate, dioctyl adipate, 2-hexyldecyl adipate, diisostearyl adipate, isopropyl myristate, cetyl octanoate, cetyl isooctanoate, isononanoic acid isonoel, isononane Isodecyl acid, isotridecyl isononanoate, diisopropyl sebacate pill, octyldodecyl myristate, isopropyl palmitate, stearyl stearate, stearyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate , Triisodecyl myristate,
  • hydrocarbon examples include ⁇ -olefin oligomer, light isoparaffin, light liquid isoparaffin, liquid isoparaffin, liquid paraffin, squalane, polybutene, paraffin, polyethylene, microcrystalline wax, and petrolatum.
  • silicone examples include dimethyl silicone, methyl phenyl silicone, cyclic dimethyl silicone, cyclic silicone, methyl hydrogen silicone, amino-modified silicone, ammonium-modified silicone, and dimethylpolysiloxane having a terminal modified with a hydroxyl group.
  • Alcohol-modified silicone aliphatic alcohol-modified silicone, alkyl-modified silicone, polyether-modified silicone, epoxy-modified silicone, and fluorine-modified silicone.
  • silicone examples include, for example, otamethylcyclo Tetrasiloxane, Otamethinotritrisiloxane, Methylenopolysiloxane (Dimethicone), Dimethylsiloxane.Methyl stearoxysiloxane copolymer, Dimethylsiloxane 'methinorecetyloxysiloxane copolymer, Stear oxymethyltrimethylsilane, Stearoxymethyl Polysiloxane, Decamethylcyclopentasiloxane, Decamethyltetrasiloxane, Tetradecamethylcycloheptasiloxane, Tetradecamethylhexasiloxane, Tetrahydrotetramethinorecyclotetrasiloxane, Dodecamethinorecyclohexasiloxane, Tris (Tributoxysiloxy ) Methylsilane, trimethylsiloxyketic acid, bisphenyls
  • silicone at least one selected from the ability to improve the finger penetration of hair, dimethyl silicone, polyether-modified silicone, and amino-modified silicone is also preferred.
  • oil components may be contained alone or in combination of two or more in the hair modifier or hair cosmetic. Since the content of the oil component in the hair modifier or hair cosmetic can effectively improve the moisture feeling of the hair and the fingering ability, and can prevent stickiness of the hair. Preferably, it is 0.0;! To 30% by mass, more preferably 0.05 to 20% by mass, and particularly preferably 0.;! To 10% by mass.
  • the surfactant stabilizes the hair modifying agent and the hair cosmetic, and improves the feel of the hair.
  • stabilization of hair modifiers and hair cosmetics include solubilization of solvents and improvement of dispersibility of ingredients.
  • non-ionic field Surface active agents non-ionic field Surface active agents, cationic surfactants, cation surfactants, and amphoteric surfactants.
  • polyoxyethylene is referred to as POE and polyoxypropylene is referred to as POP.
  • nonionic surfactant examples include POE alkyl ethers, POE alkynol phenyl ethers, ⁇ POP alkyl ethers, POE sorbitan fatty acid esters, POE propylene glycol fatty acid esters, and aliphatic alkyls.
  • Examples include strong noramides.
  • Examples of the cationic surfactant include lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, alkyltrimethylammonium chloride, distearyldimethylammonium chloride, Cetyltrimethylammonium bromide, stearyltrimethylammonium bromide, lanolin fatty acid ethyl sulfate, aminopropylethyldimethylammonium, stearyltrimethylammonium saccharine, cetyltrimethylammonium saccharin, and behenyltrimethyl methylsulfate Ammoyuum.
  • anionic surfactant examples include alkyl sulfate, POE alkyl sulfate, alkyl sulfate ester salt, sodium stearoylmethyl taurate, dodecylbenzene triethanolamine sulfonate, sodium tetradecenesulfonate, POE lauryl ether phosphate. And its salts, N-lauroyl glutamates, N-lauroylmethyl.
  • alkyl sulfate examples include sodium lauryl sulfate.
  • POE alkyl sulfate examples include sodium POE lauryl ether sulfate.
  • alkyl sulfate ester salt examples include lauryl sulfate triethanolamine.
  • amphoteric surfactant examples include 2-undecyl-N-carboxymethyl-N-hydroxyethylimidazoline sodium betaine, cocoamidopropyl betaine, and lauryldimethylaminoacetic acid betaine.
  • the cationic polymer, the anionic polymer, the amphoteric polymer, and the nonionic polymer are generally known as polymer compounds.
  • the cationic polymer is a water-soluble polymer containing an amino group or an ammonium group bonded to a polymer chain, or at least Is also a water-soluble polymer containing dimethyl diallyl ammonium halide as a structural unit.
  • Cationic polymers include, for example, cationized cellulose derivatives, cationic starch, cationized guar gum derivatives, diallyl quaternary ammonium salt polymers, diallyl quaternary ammonium salts, acrylamide copolymers, and quaternized polybutylpyrrolidone derivatives. I can get lost.
  • cationized cellulose derivatives include, for example, “Leoguard G” and “Leoguard GP” trade names of Lion Corporation, polymers “JR-125”, “JR 400”, “JR—” of Union Carbide Corporation. 30M “,” LR-400 ", and” LR-30M ".
  • cationized cellulose derivatives other than thiolated cellulose derivatives include hydroxyethyl cellulose dimethyl diallyl ammonium chloride.
  • examples of commercially available products of hydroxyethyl cellulose dimethyl diallyl ammonium chloride include trade names “Cellcoat H-100” and “L-200” of National Starch and Chemical Co., Ltd.
  • Examples of the cationized guar gum derivatives include RHONE—POULENC ⁇ trade names “Jaguar C—13S”, “Jaguar C—14S”, “Jaguar C—17”, “Jaguar C—2 10”, “Jaguar C—162”. And “HI-CARE1000”.
  • An example of a commercially available product of the diallyl quaternary ammonium salt polymer is “Marcote 100”, a trade name of Ondeo Narco.
  • Commercially available products of the above-mentioned dialyl quaternary ammonium salt / acrylamide copolymer include, for example, trade names “MARCOAT 2200” and “MARCOAT 550” available from ONDEALNALCO.
  • the molecular weight of the quaternized polybylpyrrolidone derivative is preferably 10,000 to 200,000.
  • Commercially available quaternized polybylpyrrolidone derivatives include, for example, trade names “Guff Coat 734”, “ And “Guff Coat 755” and “Guff Coat 7 55N”.
  • Examples of useful cationic polymers other than the above specific examples of the cationic polymer include chloromethacrylic acid ester polymers. Specifically, for example, 2-methacryloyl roxychetyl phosphorylcholine polymer, 2- Methacryloyloxychetyl phosphorylcholine / butyl methacrylate copolymer, 2-Methacryloyloxychetyl phosphorylcholine '2-hydroxy-3-methacryloyloxypropyltrimethylammonium chloride copolymer, and choline chloride A polymer is mentioned.
  • Chloromethacrylic acid ester polymers Examples of commercially available products containing “Salcare SC95” and “Salcare SC96” manufactured by Ciba “Specialty” Chemicals, “Revisior HM”, “Revisitor PM B”, and “Revisitor C” manufactured by Nippon Oil & Fats Co., Ltd. Can be mentioned. These cationic polymers may be contained alone! /, Or two or more may be contained in combination! /.
  • anionic polymer examples include acrylic acid / acrylic acid amide 'acrylic acid ethyl copolymer, acrylic acid / acrylic acid amide' ethyl acrylate copolymer potassium salt solution, acrylic acid alkyl ester 'and methacrylic acid.
  • Alkyl ester * Diacetone acrylamide methacrylic acid copolymer solution, acrylic acid 'alkyl methacrylate copolymer, acrylic resin anolecanamine solution, carboxybule polymer, hydroxypropyl acrylate, butylaminoethyl methacrylate, octylamide acrylate Copolymers of butyl acetate / crotonic acid, butyl acetate / crotonic acid / neodecanoyl butyl copolymer, butyl acetate / crotonic acid, propionate butyl copolymer, and methyl butyl ether / mono maleate Butyl ester copolymer Is mentioned.
  • amphoteric polymer for example, N-methacryloylethyl N, N-dimethylammonium ⁇ — ⁇ -methylcarboxybetaine ′ butyl methacrylate copolymer, hydroxypropyl acrylate. Butylaminoethyl methacrylate.
  • Acrylic Octylamide copolymer, dimethyldiallyl ammonium chloride ⁇ acrylic acid copolymer, dimethyldiallylmonium chloride ⁇ acrylamide ⁇ terpolymer of acrylic acid, and acrylic acid ⁇ methyl acrylate • methacrylamidopropyltrimethyl chloride Ammonium copolymer may be mentioned.
  • ⁇ -Methacryloylethyl ⁇ , ⁇ -dimethylammonium ⁇ - ⁇ -methylcarboxybetaine Commercially available butyl methacrylate copolymer, for example, “Yukafomer AM-75” strength S manufactured by Mitsubishi Chemical Corporation It is done. Examples of commercially available products of hydroxypropyl acrylate / butylaminomethacrylate / octylamide acrylate copolymer include “Amphomer 28-4910” manufactured by National Starch. Examples of commercial products of dimethyl diallyl ammonium chloride / acrylic acid copolymer include “MARCOT 280” and “MARCOAT 295” manufactured by Ondeal Nalco.
  • Examples of commercially available terpolymers of dimethyldiallyl ammonium chloride 'acrylamide' acrylic acid include “MARCOAT PLUS 3330” and “MARCOAT PLUS 3331” manufactured by Ondeo Narco.
  • Acrylic acid As a commercial product of a methyl crylate / methacrylamidopropyltrimethylammonium chloride copolymer, for example, “Marcote 2001” manufactured by Ondeal Co., Ltd. can be cited.
  • the type of the nonionic polymer is not limited, and specific examples include natural nonionic polymers, semi-synthetic nonionic polymers, and synthetic nonionic polymers.
  • Examples of the natural nonionic polymer include cellulose, guar gum, agar, starch, hydrolyzed starch, and dextrin.
  • Examples of the semi-synthetic nonionic polymer include methyl cellulose, ethyl cellulose, and hydroxyethyl cetate.
  • polyethyl ethyl acrylate for example, polyethyl ethyl acrylate, polyacrylamide resin, polyethylene glycol, polypropylene glycol, POE'POP copolymer, POP butyl ether, POE'POP to xylene glycol ether, POP butyl ether, Polybulpyrrolidone, POE monostearate, and POE distearate.
  • the synthetic nonionic polymer for example, polyethyl ethyl acrylate, polyacrylamide resin, polyethylene glycol, polypropylene glycol, POE'POP copolymer, POP butyl ether, POE'POP to xylene glycol ether, POP butyl ether, Polybulpyrrolidone, POE monostearate, and POE distearate.
  • the hair modifier and hair cosmetic according to the present embodiment may appropriately contain, in addition to the above-described components, components used in normal hair cosmetics depending on the purpose.
  • components include, for example, solvents, anti-dandruff agents, vitamins, antiseptics, anti-inflammatory agents, chelating agents, dyes, pigments and other colorants, carboxybule polymers, xanthan gum, clay minerals, etc.
  • Agents citrate, 2-amino-2-methyl-1-propanol, pH adjusters such as sodium hydroxide, hydrolysis PPTs and amino acids and their derivatives, reducing agents, oxidizing agents, extracts extracted from plants, animals or microorganisms , Pearlizing agents, fragrances, pigments, ultraviolet absorbers, antioxidants, and propellants.
  • These ingredients include, for example, cosmetic raw material standards, cosmetic ingredient-specific formulation standards, legal dye handbooks, Japan Cosmetic Industry Federation component table unnamed list, IN I tongue rf ie International osmetic Ingredient Dictionary and Handbook), Pharmaceutical Department Ingredient raw material standards, Quasi-drug raw material standards 2006, Japanese Pharmacopoeia, Pharmaceutical Additive Standards, and ingredients listed in the Food Additives Standard are listed.
  • the pH of the hair modifying agent and the hair cosmetic is preferably from pH 3 to 10 by a single pH adjusting agent or a pH buffering agent containing a buffering organic acid or inorganic acid and a salt thereof. More preferably between pH 4.5 and 8.5, particularly preferably at pH 6. Adjusted between 0 and 8 ⁇ 0.
  • the organic acid contained in the ⁇ buffer include citrate, glycolic acid, succinic acid, tartaric acid, lactic acid, fumaric acid, malic acid, and levulinic acid.
  • the inorganic acid contained in the ⁇ buffer include phosphoric acid, sulfuric acid, and nitric acid.
  • these acid salts include alkali metal salts and alkanolamine salts.
  • the alkali metal salt include sodium salt and potassium salt.
  • alkanolamine salts include ammonium salts and triethanolamine salts.
  • Examples of dosage forms for hair modifying agents and hair cosmetics include liquids, water-in-oil emulsions, oil-in-water emulsions, composite emulsions, microemulsions, sprays, gels, foams, granules, lotions, and creams. Shape.
  • the hair modifying agent and the hair cosmetic may be used directly on the hair as a hair care agent such as shampoo, rinse, treatment, or as a styling agent such as jewel, emulsion, mousse, wax.
  • Hair modifiers and hair cosmetics are intended for hair dyes, hair nail polish and other hair dyeing agents, perm and hair straightening agents such as wave / straightening agents, and hair growth. May be included as an additional component to the drug!
  • the hair modifying agent and the hair cosmetic may be washed away with water or warm water after being applied to the hair, or may not be washed away while attached to the hair.
  • the hair modifier or hair cosmetic according to the present embodiment is applied to the hair and heated, thereby allowing the hair modifier or hair cosmetic to react with the hair surface and penetrate into the hair.
  • Power S to promote S The heating may be heating and leaving using a heating device. Examples of the heating device include a dryer, a warmer, a steamer, a high-temperature hairstyling iron, a heating lot, and a self-heating device. Appropriate standing time for heating is about! ⁇ 30 minutes. When a hot hairstyling iron is used for heating, the contact time between the hair and the hot hairstyling iron per site is appropriately 2 seconds to 1 minute.
  • the hair modifier and hair cosmetic according to the present embodiment are hair dyeing agents such as oxidative hair dyes and acid hair dyes, or hair treatment agents such as bleaching agents, permanent wave agents, and hair straighteners.
  • hair treatment agents such as bleaching agents, permanent wave agents, and hair straighteners.
  • the effect can be exerted even when applied to hair damaged by factors other than the hair treatment agent such as ultraviolet rays. That is, book
  • the hair modifying agent and hair cosmetic according to the embodiment modifies damaged hair by reducing or repairing damage to the hair surface or protecting the hair surface, and the cohesiveness of the hair. In addition, it can effectively improve moisture retention and elasticity, and exhibits excellent long-term sustainability and a feeling of touch after finishing.
  • the unsaturated bond adjacent to the ester site has a high reaction activity, so that the ester compound is easily and firmly covalently bonded to the hair surface. It is presumed that the ability of the ester compound to adsorb to the hair surface is increased.
  • each hair treatment having the composition shown in Table 1 was prepared by the following method.
  • the content of the ester compound per 100 g of hair treatment was set to 3 mol of 3 ⁇ 1 CT.
  • Reference Example 1 does not contain an ester compound.
  • the unit of numerical values in the column corresponding to each component is mass%.
  • the “smoothness” of the hair surface, the “elasticity”, “coherence”, “feel (smoothness, moistness, softness, oiliness)” of the hair and its “sustainability” ”And“ damage reduction effect ”of hair Table 3 shows the results of these tests.
  • a hair bundle of 15 cm in length and 2. Og in weight was created. Next, this hair bundle was subjected to bleaching treatment using Promaster LT manufactured by Hoyu Co., Ltd. twice, and a hair bundle for evaluation was produced.
  • the evaluation hair bundle was shampooed using Hoyu's Promaster Color Care Shampoo, and then the evaluation hair bundle was wiped with a towel.
  • 0.2 g of hair treatment of each example, comparative example, or reference example was uniformly applied to the evaluation hair bundle, and the evaluation hair bundle was allowed to stand for 10 minutes at a constant temperature bath of 50 ° C. Thereafter, the hair treatment was washed with strength, washed with water, and the evaluation hair bundle was dried using a dryer.
  • the hair bundles treated with the hair treatments of the examples and comparative examples are very good compared to the reference example 1 with the hair bundle treated with the hair treatment men of the reference example 1 as a control ( ⁇ ), good compared to Reference Example 1 ( ⁇ ), equivalent to Reference Example 1 ( ⁇ ), slightly poorer than Reference Example 1 (X), and compared to Reference Example 1 It was evaluated in 5 grades (XX).
  • a hair bundle of 25 cm in length and 10 g in weight was created.
  • this hair bundle was subjected to a bleaching process twice using Hoyuyu Promaster LT, and Hoyu Perm treatment was performed using Fit Me Wave 45 made by the manufacturer, and a hair bundle for evaluation was prepared.
  • the evaluation hair bundle was shampooed using Hoyu's Promaster Color Care Shampoo, and then the evaluation hair bundle was wiped with a towel.
  • a shampoo using Promaster Color Care Shabubu made by Hoyu Co., Ltd. and drying with a dryer were repeated 20 times on the evaluation hair bundles subjected to the sensory evaluation.
  • the treated hair bundles after the treatment were again subjected to sensory evaluation according to the criteria shown in Table 2 by the five expert panelists to evaluate the sustainability of the effect.
  • the hair bundles treated with each hair treatment in the examples and comparative examples are very good compared to Reference Example 1 with the hair bundle treated with the hair treatment men of Reference Example 1 as a control ( ⁇ ), good compared to Reference Example 1 ( ⁇ ), equivalent to Reference Example 1 ( ⁇ ), slightly poorer than Reference Example 1 (X), and compared to Reference Example 1
  • the evaluation was based on five grades of (XX) being defective.
  • the evaluation hair bundle was shampooed using Hoyu's Promaster Color Care Shampoo, and then the evaluation hair bundle was wiped with a towel.
  • 0.2 g of hair treatment of each example, comparative example, or reference example was uniformly applied to the entire evaluation hair bundle, and the evaluation hair bundle was allowed to stand for 10 minutes in a thermostatic bath at 50 ° C. Thereafter, the hair treatment was washed, washed with water, and the evaluation hair bundle was dried using a dryer.
  • the moisture content which a fixed amount of hair absorbs was measured.
  • the degree of damage was compared by taking advantage of the fact that the moisture absorption rate of hair increases in proportion to the increase in hair damage. If the moisture absorption rate of the hair was low, it was judged that there was an effect of reducing hair damage.
  • the hair modifier and hair cosmetic according to the present invention are By essentially reducing damaged hair and protecting the hair surface, the damaged hair is essentially modified to improve hair cohesion, moisture retention and elasticity, and to achieve long-lasting effects and finishes. I was able to confirm that it was very good!
  • a shampoo prepared by mixing the components shown in Table 4 by a conventional method was excellent in smoothness during rinsing, cohesiveness after drying, and moisture retention.
  • Treatments that are prepared by mixing the ingredients shown in Table 5 in a conventional manner and that do not wash away have a force S that has an appropriate oily feeling when the finishing force S is reduced, and the stickiness is suppressed. Hair mass It was excellent in property and moisture retention.
  • a styling agent prepared by mixing the components shown in Table 6 by a conventional method had an appropriate setting force when finished, and was excellent in hair cohesiveness and elasticity.

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Abstract

La présente invention concerne un modificateur de cheveux qui modifie essentiellement les cheveux abîmés, améliore la maniabilité, l'hydratation et l'élasticité de la chevelure et fait preuve d'un excellent effet de durabilité, un produit d'entretien de chevelure contenant le modificateur de cheveux et un procédé de modification de cheveux utilisant le produit d'entretien de la chevelure. Le modificateur de cheveux contient un composé ester d'un acide dicarboxylique insaturé ayant 4 à 6 atomes de carbone et un alcool linéaire ou ramifié, saturé ou insaturé ayant 12 à 24 atomes de carbone. Le produit d'entretien de la chevelure contient le modificateur de cheveux. Le procédé de modification des cheveux comprend une étape d'application du produit d'entretien de la chevelure sur les cheveux.
PCT/JP2007/073969 2006-12-15 2007-12-12 Modificateur de cheveux, produit d'entretien de chevelure et procédé de modification des cheveux WO2008072672A1 (fr)

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JP2006-338712 2006-12-15
JP2006338712A JP2008150308A (ja) 2006-12-15 2006-12-15 毛髪改質剤、毛髪改質剤成分を含有する毛髪化粧料、及び毛髪の改質方法

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CN102716046A (zh) * 2012-07-04 2012-10-10 广东雅威生物科技有限公司 一种含有天然橄榄油及其衍生物的洗发水及其制备方法
US10639505B2 (en) 2013-08-01 2020-05-05 Olaplex, Inc. Methods for fixing hair and skin
US10792233B2 (en) 2016-07-12 2020-10-06 Olaplex, Inc. Methods and formulations for curling hair
US11191707B2 (en) 2015-04-24 2021-12-07 Olaplex, Inc. Methods for treating relaxed hair

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JP5579396B2 (ja) * 2009-02-13 2014-08-27 株式会社ミルボン 毛髪化粧料
JP2013514263A (ja) * 2009-12-18 2013-04-25 ロレアル ケラチン繊維を処理する方法
DK3142637T3 (da) * 2014-05-16 2020-08-24 Olaplex Inc Keratin treatment formulations and methods
JP6821916B2 (ja) * 2015-02-26 2021-01-27 大正製薬株式会社 外用組成物
JP7466350B2 (ja) 2019-03-28 2024-04-12 株式会社コーセー 毛髪化粧料
BR102021006988A2 (pt) * 2021-04-12 2022-10-25 Chemyunion Ltda Composições capilares, seus processos de produção, usos e métodos de tratamento capilar

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CN102716046A (zh) * 2012-07-04 2012-10-10 广东雅威生物科技有限公司 一种含有天然橄榄油及其衍生物的洗发水及其制备方法
US10639505B2 (en) 2013-08-01 2020-05-05 Olaplex, Inc. Methods for fixing hair and skin
US11446525B2 (en) 2013-08-01 2022-09-20 Olaplex, Inc. Methods for fixing hair and skin
US11191707B2 (en) 2015-04-24 2021-12-07 Olaplex, Inc. Methods for treating relaxed hair
US10792233B2 (en) 2016-07-12 2020-10-06 Olaplex, Inc. Methods and formulations for curling hair

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