EP3229911A2 - Produit de soin et de coiffage combiné à effet chauffant - Google Patents

Produit de soin et de coiffage combiné à effet chauffant

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Publication number
EP3229911A2
EP3229911A2 EP15785144.5A EP15785144A EP3229911A2 EP 3229911 A2 EP3229911 A2 EP 3229911A2 EP 15785144 A EP15785144 A EP 15785144A EP 3229911 A2 EP3229911 A2 EP 3229911A2
Authority
EP
European Patent Office
Prior art keywords
cosmetic composition
copolymer
composition according
polyquaternium
hair
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15785144.5A
Other languages
German (de)
English (en)
Inventor
Maria Catalina Bermudez Agudelo
Anna PULS
Julia Bibiane Lange
Cyrielle Martinez
Bernd Richters
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3229911A2 publication Critical patent/EP3229911A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/24—Thermal properties
    • A61K2800/242—Exothermic; Self-heating; Heating sensation
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/31—Anhydrous
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • the present invention relates to a cosmetic composition for hair setting or for the temporary shaping and care of keratinic fibers, in particular human hair, with a warming effect.
  • the cosmetic composition according to the invention comprises at least one polyethylene glycol having 4 to 20 oxyethylene units, a copolymer of hydrogenated castor oil and an n-alkyldicarboxylic acid having 4 to 10 carbon atoms and (c) at least one film former.
  • hair treatment agents which serve a temporary shaping of the hair, play an important role.
  • Corresponding temporary deformation agents usually contain synthetic polymers and / or waxes as the setting agent.
  • Means for supporting the temporary shaping of hair can be formulated, for example, as hair spray, hair wax, hair gel, hair foam.
  • a hair temporary deformation agent hereafter called a styling agent
  • a styling agent The most important property of a hair temporary deformation agent, hereafter called a styling agent, is to treat the treated fibers in the newly modeled form - i. a form imprinted on the hair - to give as strong a hold as possible.
  • the hairstyle hold is essentially determined by the type and amount of setting agents used, but also an influence of the other ingredients of the styling agent may be given.
  • styling agents In addition to a high degree of hold, styling agents must meet a whole range of other requirements. These may be broad in properties on the hair, properties of the particular formulation, e.g. Properties of the foam, the gel or the sprayed aerosol, and properties that affect the handling of the styling agent, are subdivided, with the properties of the hair is of particular importance. Particularly noteworthy are moisture resistance, low tack and a balanced conditioning effect. Furthermore, a styling agent should be universally applicable for all hair types and mild to hair and skin.
  • the polymers can be subdivided into cationic, anionic, nonionic and amphoteric setting polymers.
  • waxes are used as strengthening active ingredients.
  • the polymers and / or waxes when applied to hair, provide a polymer film which, on the one hand, gives the hairstyle a strong hold but, on the other hand, is sufficiently flexible not to break under stress. If the (polymer) film is too brittle, it results in the formation of so-called Filmpiaken, that is residues that detach during the movement of the hair and give the impression that the user of the corresponding styling agent would dandruff.
  • Hair care products are usually hair conditioners and hair conditioners or shampoos with care effect. These contain as a nourishing agent a lipophilic base, such as oils, fats and waxes.
  • the aim of hair care products is to restore the cuticle of the hair (cuticle), which may be damaged due to external influences.
  • a known ingredient of hair care products such as shampoos and rinses capable of repairing the cuticle layer is commercially available under the name Crodabond® CSA (Croda Company). It is a copolymer of hydrogenated castor oil and sebacic acid. The use of this copolymer in mascaras is described in WO 2012/012084 A2.
  • the feeling of a nourishing effect can be enhanced for the user if the cosmetic composition develops heat when applied to the hair, or a warming effect is simply perceived as pleasant.
  • Substances that are used in cosmetics and can develop a warming effect are, for. B. polyethylene glycols. These are hygroscopic to a certain extent and develop heat on contact with water or moisture.
  • Heat-developing compositions containing polyethylene blends are commercially available under the designation XO Therm® (Chemsil Silicones Inc.). These are mixtures of PEG-4, PEG-8 and PVP and possibly also continue to polypropylene glycol. The manufacturer of the suitability for skin care, body care and intimate care is specified.
  • properties required for styling agents such as good film-forming and / or setting properties, a high degree of retention, flexibility, if possible no visible residues, easy applicability to the hair and dispersibility in the hair should also be achieved or maintained.
  • the present invention provides:
  • a cosmetic composition having a warming effect for the care and temporary transformation of keratinic fibers which contains:
  • composition according to item 1 wherein as component (a) two or more polyethylene glycols are included.
  • composition according to item 1 or 2 wherein as component (a) one or more polyethylene glycols containing 4 to 10 oxyethylene units is / are.
  • component (b) is an oligoester of hydrogenated castor oil and sebacic acid.
  • composition according to item 6 wherein as film former (c) is a polyvinylpyrrolidone or a combination of a polyvinylpyrrolidone and Polyquaternium-46 (INCI).
  • film former (c) is a polyvinylpyrrolidone or a combination of a polyvinylpyrrolidone and Polyquaternium-46 (INCI).
  • composition according to one of the preceding points, wherein the composition further contains a hydrophobicized metal oxide powder, in particular hydrophobicized silica.
  • composition according to any one of the preceding claims, wherein the composition contains 20% or more by weight of glycerin, based on the total weight of the cosmetic composition.
  • composition according to any one of the preceding claims, wherein the composition contains from 0.1 to 2.0% by weight of copolymer (b) of hydrogenated castor oil and of N-alkyldicarboxylic acid of from 4 to 10 carbon atoms, relative to the total weight of the cosmetic Composition.
  • composition according to one of the preceding points, wherein the composition contains 20 to 80 wt .-%, preferably 50 to 70 wt .-%, of a mixture of PEG-4, PEG-8 and polyvinylpyrrolidone, based on the total weight of the cosmetic Composition.
  • composition according to one of the preceding points, wherein the composition contains 0.1 to 2.0 wt .-% Polyquaternium-46 (INCI), based on the total weight of the cosmetic composition.
  • ICI Polyquaternium-46
  • styling agents can be provided which also act as a hair care product and unfold a warming effect when applied.
  • the care effect, the effect as a styling agent and the warming effect can be strengthened and / or changed.
  • keratinic fibers according to the invention comprises furs, wool and feathers, but in particular human hair.
  • the composition according to the invention necessarily contains, as component (a), at least one polyethylene glycol having 4 to 20 oxyethylene units.
  • polyethylene glycols are hygroscopic up to a certain chain length, wherein the hygroscopic behavior decreases with increasing chain length, and develop heat on contact with water or moisture.
  • the polyethylene glycol preferably contains 4 to 10 oxyethylene units, more preferably 4 to 8 oxyethylene units.
  • the polyethylene glycol (a) may preferably be a mixture of two or more polyethylene glycols. Particularly preferred according to the invention is a mixture of PEG-4 and PEG-8.
  • PEG-4 and PEG-8-containing mixtures according to the invention are commercially available under the name XO-Therm® (Chemsil Silicones Inc.).
  • Preferred examples are XO-Therm® SP (INCI: PEG-4 (and) PEG-8 (and) PVP, viscosity RVT # 2 @ 20 rpm: 1900 cS), XO-Therm® CG (INCI: PEG-4 (cf.
  • component (a) is preferably contained in total in an amount of about 15 to 75% by weight, based on the total weight of the cosmetic composition, more preferably about 20 to 70% by weight, more preferably about 45 to 65% by weight. %.
  • the weight ratio of the two PEGs is preferably 90/10 to 10/90, more preferably 70/30 to 30/70 , more preferably 60/40 to 40/60 or about 50/50.
  • the cosmetic composition of the present invention is disclosed in U.S.P.
  • anhydrous thus contains essentially no free water, preferably less than 1, 0 wt .-% free water, more preferably less than 0.5 wt .-% free water, based on the total weight of the cosmetic composition.
  • the cosmetic composition according to the invention contains as care component (b) a copolymer of hydrogenated castor oil and an n-alkyldicarboxylic acid having 4 to 10 C atoms, preferably an oligoester of hydrogenated castor oil and sebacic acid.
  • care component (b) a copolymer of hydrogenated castor oil and an n-alkyldicarboxylic acid having 4 to 10 C atoms, preferably an oligoester of hydrogenated castor oil and sebacic acid.
  • an oligoester of hydrogenated castor oil and sebacic acid (C10) is preferred.
  • Hydrogenated castor oil contains as its main constituent hydrogenated triricinolein (triglyceride of hydrogenated ricinoleic acid).
  • the OH groups at position 12 of two of the hydrogenated ricinoleic acid residues of triricinolein are esterified with a carboxyl group of the dicarboxylic acid.
  • the invention is an oligomer having 3 to 12, more preferably 4 to 10 repeating units.
  • the commercially available Crodabond® CSA with the INCI name Hydrogenated Castor Oil / Sebacic Acid Copolymer (Croda) is used as component (b), which is a pale yellow viscous liquid at ambient temperature.
  • the copolymer (b) of hydrogenated castor oil and an n-alkyldicarboxylic acid having 4 to 10 carbon atoms is preferably contained in the cosmetic composition of the present invention in an amount of 0.1 to 2% by weight, more preferably 0.5 to 1.5% by weight .-%, based on the total weight of the cosmetic composition.
  • the cosmetic composition of the present invention contains as another caring ingredient glycerol, preferably at a purity of 99.0% by weight or higher, more preferably 99.5% by weight or higher.
  • the glycerol also serves as a cosmetically acceptable carrier.
  • Other cosmetically acceptable carriers such as ethylene glycol, 1,2-propanediol or lower alcohols of 1 to 4 carbon atoms, e.g. Isopropanol may also be included.
  • the glycerin is preferably present in the cosmetic composition according to the invention in a proportion of 10% by weight or more, preferably 20% by weight to 80% by weight, more preferably 20 to 40% by weight, most preferably about 25 to 35 Wt .-%, contained.
  • the cosmetic composition of the invention further contains at least one film former (c) to fulfill the function as a styling agent.
  • the film former is at least polyvinylpyrrolidone.
  • a film former a cationic and / or amphiphilic polymer, in particular a quaternary ammonium compound.
  • PVP polyvinylpyrrolidone
  • a combination of polyvinylpyrrolidone with a quaternary ammonium compound is contained, in particular polyquaternium-46.
  • the polyvinylpyrrolidone is a vinylpyrrolidone homopolymer. It is preferred according to the invention to select the vinylpyrrolidone homopolymers from vinylpyrrolidone homopolymers having a K value (1% strength by weight solution of PVP, Brookfield at 23 ° C.) in water of 20 to 100. More preferred is a K. Value of 80 to 100, more preferably about 90.
  • the K value which is also referred to as intrinsic viscosity, is a parameter which can be easily determined from the relative viscosity by means of viscosity measurements of polymer solutions for the characterization of polymers.
  • Luviskol® K 30 Preferred vinylpyrrolidone homopolymers are available under the trade name Luviskol® K 30, Luviskol® K 80, Luviskol® K 85, Luviskol® K 90, in each case from BASF SE.
  • Luviskol® K 90 is most preferred according to the invention.
  • Luviskol® K90 is a 20% aqueous, colorless to slightly yellowish solution of polyvinylpyrrolidone. The product has a K value of 90.0 to 98.0 (1% (mV) in water), a solids content of 19.0 to 21.0% by weight and a pH of 7.0 to 9.0 ( 10% by weight solids content in water).
  • Combinations of at least one polyethylene glycol as component (a) and polyvinyl pyrrolidone as film former (c) are commercially available, which are the above-mentioned mixtures called XO-Therm® (Chemsil Silicones Inc.).
  • Preferred examples are XO-Therm® SP (INCI: PEG-4 (and) PEG-8 (and) PVP, viscosity RVT # 2 @ 20 rpm: 1900 cS), XO-Therm® CG (INCI: PEG-4 (cf.
  • the cosmetic composition preferably contains the mixture in an amount of 20 to 80% by weight, preferably 50 to 75% by weight or 60 to 70 wt .-%, based on the total weight of the cosmetic composition.
  • a mixture of PEG-4 and PEG-8 is particularly preferably used as the polyethylene glycol.
  • the vinylpyrrolidone homopolymer is present, for example, in a total amount of from 1.0 to 12.0% by weight, preferably from 2.0% by weight to 10.0% by weight, more preferably from 3 , 0 to 8.0 wt .-%, contained in the composition according to the invention, each stated as the solids content of active substance in the cosmetic composition.
  • Quaternary ammonium compounds are known as constituents of styling agents, and may be exemplified by polyquaternium compounds such as Polyquaternium-1, Polyquaternium-2, Polyquaternium-4, Polyquaternium-5, Polyquaternium-6, Polyquaternium-7, Polyquaternium-8, Polyquaternium-9, Polyquaternium -10, Polyquaternium-1 1, Polyquaternium-12, Polyquaternium-13, Polyquaternium-14, Polyquaternium-15, Polyquaternium-16, Polyquaternium-17, Polyquaternium-18, Polyquaternium-19, Polyquaternium-20, Polyquaternium-22, Polyquaternium- 24, Polyquaternium-27, Polyquaternium-28, Polyquaternium-29, Polyquaternium-30, Polyquaternium-31, Polyquaternium-32, Polyquaternium-33, Polyquaternium-34, Polyquaternium-35, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-45, Polyquaternium
  • Polyquaternium-46 is particularly preferred according to the invention.
  • Polyquaternium-46 is commercially available, for example, under the name Luviquat® Hold AT2 as a 20% by weight aqueous solution.
  • Luviquat® Hold AT2 is preferred according to the invention.
  • quaternary ammonium compound When a quaternary ammonium compound is contained in the cosmetic composition of the present invention, it is preferably contained in an amount of 0.1 to 2.0% by weight, more preferably 0.5 to 1.5% by weight, based on the total weight the cosmetic composition, wherein the quaternary ammonium compound is preferably Polyquaternium-46 (INCI).
  • composition according to the invention additionally comprises at least one hydrophobic or hydrophobized metal oxide powder, preferably a hydrophobicized silica, more preferably hydrophobicized fumed silica.
  • the hydrophobization of the metal oxide can preferably be carried out with hexamethyldisilazane.
  • a preferable example is a hydrophobized fumed silica obtained by treating hydrophilic silica with hexamethyldisilazane, especially hydrophilic fumed silica having a BET specific surface area of about 200 to 400 m 2 / g, more preferably about 300 m 2 / g.
  • hydrophobic metal oxide powder in particular of hydrophobicized silica, which can be used according to the invention is an increase in hair volume, so that the styling agent properties can be regulated by incorporating a hydrophobicized metal oxide powder with respect to the volume of the hair.
  • the hydrophobicized metal oxide powder in particular hydrophobicized silica, is preferably present in an amount of from 0.1 to 2.0% by weight, more preferably from 0.5 to 1.5% by weight, based on the total weight of the cosmetic composition.
  • the nourishing effect of the compositions according to the invention can be enhanced or changed by including further lipophilic, nourishing active ingredients.
  • oil bodies are particularly suitable.
  • the natural and synthetic cosmetic oil bodies include, for example, vegetable oils, liquid paraffin oils, isoparaffin oils and synthetic hydrocarbons and di-n-alkyl ethers having a total of between 12 and 36 carbon atoms, in particular 12 to 24 carbon atoms. Vegetable oil bodies are preferred.
  • Particularly suitable care substances are dicarboxylic acid esters, symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, triflic acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol or fatty acid partial glycerides, which are understood to mean monoglycerides, diglycerides and technical mixtures thereof.
  • a preferred oil body according to the invention is, for example, sweet almond oil.
  • Cosmetic compositions according to the invention may also contain at least one oil body from the group of silicone oils.
  • the group of silicone oils includes in particular the dimethicones, to which the cyclomethicones are also to be expected, the amino-functional silicones and the dimethiconols.
  • the dimethicones may be both linear and branched as well as cyclic or cyclic and branched.
  • Suitable silicone oils or silicone gums are, in particular, dialkyl and alkylaryl siloxanes, for example dimethylpolysiloxane and methylphenylpolysiloxane, and also their alkoxylated, quaternized or else anionic derivatives. Preference is given to cyclic and linear polydialkylsiloxanes, their alkoxylated and / or aminated derivatives, dihydroxypolydimethylsiloxanes and polyphenylalkylsiloxanes.
  • the agent may for example also contain at least one protein hydrolyzate and / or one of its derivatives.
  • Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins).
  • the term protein hydrolyzates also means total hydrolyzates as well as individual amino acids and their derivatives as well as mixtures of different amino acids.
  • the molecular weight of the protein hydrolysates which can be used according to the invention is between 75, the molecular weight for glycine, and 200,000, preferably the molecular weight is 75 to 50,000 and very particularly preferably 75 to 20,000 daltons.
  • composition of the invention may contain other conventional ingredients of styling agents.
  • the cosmetic composition of the present invention further contains one or more other component (s) acting as thickeners or gelling agents, which are different from the above-described film formers (c) and which promote film formation.
  • other component (s) acting as thickeners or gelling agents which are different from the above-described film formers (c) and which promote film formation.
  • examples are cationic, anionic, nonionic or amphoteric polymers.
  • the proportion by weight of this further component in the total weight of the cosmetic composition is for example 0.02 to 20 wt .-%, preferably 0.1 to 10.0 wt .-%, more preferably 1, 0 to 5.0 wt .-%.
  • Examples are homopolyacrylic acid (INCI: Carbomer), which is commercially available under the name Carbopol® in various designs, Acrylamide / Ammonium Acrylate Copolymer, Acrylamide / DMAPA Acrylate / Methoxy PEG Methacrylate Copolymer, Acrylamidopropyltrimonium Chloride / Acrylamide Copolymer, Acrylamidopropyltrimonium Chloride / Acrylate Copolymer , Acrylates / Acetoacetoxyethyl Methacrylate Copolymer, Acrylates / Acrylamide Copolymer, Acrylates / Ammonium Methacrylate Copolymer, Acrylates / t-Butylacrylamide Copolymer, Acrylates Copolymer, Acrylates / C1-2 Succinates / Hydroxy Acrylates Copolymer, Acrylates / Lauryl Acrylates / Stearyl Acrylates / Ethylamine Ox
  • nonionic polymers examples are:
  • Luviskol Vinylpyrrolidone vinyl ester copolymers, such as those sold under the trademark Luviskol (BASF). Luviskol VA 64 and Luviskol VA 73, in each case vinylpyrrolidone vinyl acetate copolymers, are preferred nonionic polymers.
  • Cellulose ethers such as hydroxypropylcellulose, hydroxyethylcellulose and methylhydroxypropylcellulose, as marketed, for example, under the trademarks Culminal and Benecel (AQUALON).
  • siloxanes can be both water-soluble and water-insoluble. Both volatile and nonvolatile siloxanes are suitable, nonvolatile siloxanes being understood as meaning those compounds whose boiling point is above 200 ° C. under normal pressure.
  • Preferred siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, such as, for example, polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups.
  • compositions of the invention may further contain cosmetically acceptable preservatives.
  • An example of a preferred preservative is 2-phenoxyethanol.
  • compositions according to the invention may furthermore contain cosmetically acceptable perfumes or perfumes.
  • the cosmetic composition may be formulated in the forms customary for the temporary shaping of hair, for example as a styling cream or styling paste, hair gel, wax, cream, paste, foam or lotion.
  • the cosmetic composition according to the invention is preferably viscous-liquid, and this preparation can also be referred to as singling serum.
  • the present invention also relates to the use of cosmetic compositions according to the invention for the temporary reshaping of keratinic fibers, in particular of human hair, and to a method for the temporary deformation of keratinic fibers, in particular human hair, in which the cosmetic composition according to the invention is applied to keratinic fibers.
  • composition of some preferred cosmetic agents can be found in the following tables (data as solids content and in% by weight relative to the total weight of the cosmetic composition, unless stated otherwise).
  • Glycerol purity> 99.5% 10 to 80 20 to 60 20 to 40 25 to 35
  • Glycerol purity> 99.5% 10 to 80 20 to 60 20 to 40 25 to 35
  • Glycerol purity> 99.5% 10 to 80 20 to 60 20 to 40 25 to 35
  • Polyquaternium-46 0.01 to 0.5 0.02 to 0.4 0.05 to 0.35 0.1 to 0.3
  • Glycerol purity> 99.5% 10 to 80 20 to 60 20 to 40 25 to 35
  • Glycerol purity> 99.5% 10 to 80 20 to 60 20 to 40 25 to 35
  • Glycerol purity> 99.5% 10 to 80 20 to 60 20 to 40 25 to 35
  • Glycerol purity> 99.5% 10 to 80 20 to 60 20 to 40 25 to 35
  • the quantities in the table are given in wt .-% of the respective raw material, based on the total composition.
  • Styling agent 1 Warming, nourishing styling agent
  • Damaged hair was treated with Styling Agent 1 by carefully spreading a predetermined amount in the hair into towel-dry, yet damp hair. Before treatment with the styling agent 1, the hair had microscopically visible split ends and damage to the cuticle. After treatment, a microscopic observation showed that split ends and cuticle damage were significantly reduced.
  • Styling agent 2 More warming, nourishing styling agent with volume effect Similar results were observed for styling agent 1 with respect to repair of damaged hair.
  • Styling Agent 3 More warming, nourishing styling agent with volume effect and stronger hold Similar results were observed for styling agent 2 with respect to repair of damaged hair and heat development.
  • the hairstyle was stronger than styling 1 and 2.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
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Abstract

La présente invention concerne une composition cosmétique pour la fixation ou la mise en forme temporaire et pour le soin de fibres kératiniques, notamment de cheveux humains, à effet chauffant. La composition cosmétique selon l'invention contient au moins un polyéthylène glycol comportant 4 à 20 unités oxyéthylène, un copolymère constitué d'huile de ricin hydrogénée et d'un acide n-alkyldicarboxylique comportant 4 à 10 atomes de carbone et (c) au moins un agent filmogène.
EP15785144.5A 2014-12-11 2015-10-28 Produit de soin et de coiffage combiné à effet chauffant Withdrawn EP3229911A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014225546.5A DE102014225546A1 (de) 2014-12-11 2014-12-11 Kombiniertes Pflege- und Stylingmittel mit wärmender Wirkung
PCT/EP2015/074945 WO2016091449A2 (fr) 2014-12-11 2015-10-28 Produit de soin et de coiffage combiné à effet chauffant

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EP3229911A2 true EP3229911A2 (fr) 2017-10-18

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US (1) US10251829B2 (fr)
EP (1) EP3229911A2 (fr)
DE (1) DE102014225546A1 (fr)
WO (1) WO2016091449A2 (fr)

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DE102020123258A1 (de) 2020-09-07 2022-03-10 Henkel Ag & Co. Kgaa Klare flüssige haarmaske mit transformierender erscheinung für nicht-beschwerende pflege

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AU6346880A (en) * 1979-10-17 1981-07-02 Johnson Co. Ltd. Self heating cosmetic composition
DE3725080A1 (de) 1987-07-29 1989-02-09 Wella Ag Haarwachs
DE4227203C2 (de) * 1992-08-17 1994-03-24 Kao Corp Gmbh Mittel und Verfahren zur Haarbehandlung
WO2001072262A2 (fr) * 2000-03-27 2001-10-04 Schott Glas Nouvelles compositions de produits cosmetiques, d'hygiene personnelle, d'agents de nettoyage et de supplements nutritionnels contenant du verre bioactif, et procedes de fabrication et d'utilisation de ces dernieres
DE10103093A1 (de) * 2001-01-24 2002-07-25 Beiersdorf Ag Bei Kontakt mit Feuchtigkeit Wärme erzeugende Haarkur
US7255869B2 (en) * 2001-10-30 2007-08-14 The Procter & Gamble Company Anhydrous cosmetic compositions containing polyols
JP2006124352A (ja) 2004-11-01 2006-05-18 Croda Japan Kk 毛髪化粧料
JP4754326B2 (ja) * 2005-11-01 2011-08-24 株式会社アリミノ 毛髪化粧料
WO2009015108A1 (fr) * 2007-07-20 2009-01-29 Borish Edward T Esters ayant des propriétés de chauffage
WO2012012084A2 (fr) 2010-06-30 2012-01-26 Aveda Corporation Système fixateur pour poils polymère dérivé d'un produit naturel avec du pullulane, et compositions de mascara le comprenant

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WO2016091449A2 (fr) 2016-06-16
DE102014225546A1 (de) 2016-06-16
WO2016091449A3 (fr) 2016-08-04
US10251829B2 (en) 2019-04-09
US20170273891A1 (en) 2017-09-28

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