WO2016030186A1 - Utilisation d'une association d'un copolymère de polyuréthane-polyéther et d'un homopolymère ou copolymère de vinylpyrrolidone - Google Patents

Utilisation d'une association d'un copolymère de polyuréthane-polyéther et d'un homopolymère ou copolymère de vinylpyrrolidone Download PDF

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Publication number
WO2016030186A1
WO2016030186A1 PCT/EP2015/068557 EP2015068557W WO2016030186A1 WO 2016030186 A1 WO2016030186 A1 WO 2016030186A1 EP 2015068557 W EP2015068557 W EP 2015068557W WO 2016030186 A1 WO2016030186 A1 WO 2016030186A1
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WIPO (PCT)
Prior art keywords
copolymer
cosmetic composition
vinylpyrrolidone
composition according
polyurethane
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PCT/EP2015/068557
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German (de)
English (en)
Inventor
Julia Bibiane Lange
Bernd Richters
Cyrielle Martinez
Maria Catalina Bermudez Agudelo
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Henkel Ag & Co. Kgaa
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Priority claimed from DE102014217201.2A external-priority patent/DE102014217201A1/de
Priority claimed from DE102014217205.5A external-priority patent/DE102014217205A1/de
Application filed by Henkel Ag & Co. Kgaa filed Critical Henkel Ag & Co. Kgaa
Publication of WO2016030186A1 publication Critical patent/WO2016030186A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48—Thickener, Thickening system
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • the present invention relates to a cosmetic composition for the hair setting or for the temporary reshaping of keratinic fibers, in particular human hair, wherein the composition contains a combination of two nonionic polymers.
  • hair treatment agents which serve a temporary shaping of the hair, play an important role.
  • Corresponding temporary deformation agents usually contain synthetic polymers and / or waxes as the setting agent.
  • Means for supporting the temporary shaping of hair can be formulated, for example, as hair spray, hair wax, hair gel, hair foam.
  • a hair temporary deformation agent hereafter called a styling agent
  • a styling agent The most important property of a hair temporary deformation agent, hereafter called a styling agent, is to treat the treated fibers in the newly modeled form - i. a form imprinted on the hair - to give as strong a hold as possible.
  • the hairstyle stop is in
  • styling agents In addition to a high degree of hold, styling agents must meet a whole range of other requirements. These may be broad in properties on the hair, properties of the particular formulation, e.g. Properties of the foam, the gel or the sprayed aerosol, and properties that affect the handling of the styling agent, are subdivided, with the properties of the hair is of particular importance. Particularly noteworthy are moisture resistance, low tack and a balanced conditioning effect. Furthermore, a styling agent should be universally applicable for all hair types and mild to hair and skin.
  • the polymers can be solidified in cationic, anionic, nonionic and amphoteric Divide polymers.
  • the polymers when applied to hair, the polymers give a polymer film which, on the one hand, gives the hairstyle strong hold but, on the other hand, is sufficiently flexible not to break under stress. If the polymer film is too brittle, it results in the formation of so-called Filmpiaken, that is residues that detach during the movement of the hair and give the impression that the user of the corresponding styling agent would dandruff. Similar problems arise when waxes find use as a firming agent in the styling agent. If the styling agent is a gel or a paste, the polymers should also have thickening properties.
  • Polyvinylpyrrolidone (PVP). These are homopolymers of vinylpyrrolidone.
  • Vinylpyrrolidone homopolymers are sold, for example, under the name Luviskol® (BASF) and are usually used as film formers and / or thickeners.
  • the product series Luviskol® K (BASF) is available in the market.
  • Vinylpyrrolidone homopolymers in various molecular weights are offered.
  • VP / VA vinylpyrrolidone / vinyl acetate copolymers
  • BASF Luviskol® VA
  • polyether polyurethanes which are offered in a variety of forms.
  • a specific polyether polyurethane is z. In FR 2975900 A1,
  • FR 2984235 B1, FR 2996760, US 2010029705 A1 and WO 2010/133658 A2 as a constituent of styling agents. It is a terpolymer of polyether, polyurethane and a polyalkylene glycol alkyl ether having the INCI name Steareth-100 / PEG-136 / HDI copolymer, commercially available under the name Rheolate® FX 1 100 (Elementis Specialties, Inc.) and may have a function as a thickener or viscosity regulator.
  • the present invention provides:
  • a cosmetic composition for the temporary transformation of keratinous fibers which contains:
  • a polyurethane-polyether copolymer composed of the following units: a diisocyanate (b1), a polyalkylene glycol (b2) and a polyalkylene glycol alkyl ether (b3).
  • composition according to item 1 wherein the vinylpyrrolidone homo- or copolymer (a) is selected from the group of vinylpyrrolidone homopolymers and preferably a K value (1 wt .-% solution of PVP, Brookfield at 23 ° .] C) in water from 20 to 100 has.
  • composition according to item 1 wherein the vinylpyrrolidone homo- or copolymer (a) is selected from the group of vinylpyrrolidone-vinyl acetate copolymers and preferably a ratio of vinylpyrrolidone (VP) to vinyl acetate (VA) of 30:70 to 70 : 30, preferably 50:70 to 30:50.
  • VP vinylpyrrolidone
  • VA vinyl acetate
  • composition according to item 1 wherein the vinylpyrrolidone homo- or copolymer (a) is selected from the group of vinylpyrrolidone-vinyl acetate copolymers and preferably has a ratio of vinylpyrrolidone (VP) to vinyl acetate (VA) of about 60:40 ,
  • diisocyanate (b1) is an alkylene diisocyanate.
  • Polyalkylene glycol (b2) is a polyethylene glycol having 100 to 150 ethylene glycol units.
  • Polyalkylenglykolalkylether (b3) 80 to 120 alkylene oxide units.
  • Polyalkylenglykolalkylether (b3) is a Polyethylenglycolalkylether.
  • Polyalkylene glycol alkyl ether (b3) is a polyalkylene glycol stearyl ether, in particular
  • composition according to one of the preceding points, wherein the polyurethane-polyether copolymer (b) has the INCI name steareth-100 / PEG-136 / HDI copolymer and the vinylpyrrolidone homo- or copolymer (a) is a vinylpyrrolidone Homopolymer having a K value of 80 to 100, especially about 90, has.
  • composition according to one of the preceding points, wherein the polyurethane-polyether copolymer (b) has the INCI name Steareth-100 / PEG-136 / HDI copolymer and the vinylpyrrolidone homo- or copolymer (a) is a vinylpyrrolidone-vinyl acetate copolymer having a ratio of vinylpyrrolidone (VP) to vinyl acetate (VA) of about 60:40.
  • Composition further contains at least one thickener, in particular a carbomer.
  • Cosmetic composition according to one of the preceding points which, based on the total weight of the cosmetic composition, contains:
  • Cosmetic composition according to one of the preceding points which, based on the total weight of the cosmetic composition, contains:
  • Cosmetic composition according to one of the preceding points containing, based on the total weight of the cosmetic composition:
  • Cosmetic composition according to one of the preceding points containing, based on the total weight of the cosmetic composition:
  • composition as a hair gel, hair spray, hair foam or hair wax, in particular as a hair gel, is present.
  • keratinic fibers according to the invention comprises furs, wool and feathers, but in particular human hair.
  • the essential constituents of the cosmetic composition according to the invention are the vinylpyrrolidone homo- or copolymer (a) and the polyurethane-polyether copolymer (b).
  • the agent according to the invention necessarily contains, as component (a), a vinylpyrrolidone homo- or copolymer.
  • Vinylpyrrolidone homopolymers having a K value (1 wt.% Solution of PVP, Brookfield at 23 ° C) in water of 20 to 100. More preferred is a K value of 80 to 100, more preferably about 90.
  • the K value which is also referred to as inherent viscosity, is one of the relative viscosity by means of
  • Luviskol® K 30 Preferred vinylpyrrolidone homopolymers are available under the trade name Luviskol® K 30, Luviskol® K 80, Luviskol® K 85, Luviskol® K 90, in each case from BASF SE.
  • Luviskol® K 90 is most preferred according to the invention.
  • Luviskol® K90 is a 20% aqueous, colorless to slightly yellowish solution of polyvinylpyrrolidone.
  • the product has a K value of 90.0 to 98.0 (1% (w / v) in water), a solids content of 19.0 to 21 .0 wt.% And a pH of 7.0 to 9 , 0 (10% by weight solids content in water).
  • vinylpyrrolidone copolymers are vinylpyrrolidone-vinyl acetate copolymers.
  • Vinylpyrrolidone-vinyl acetate copolymers are copolymers of vinylpyrrolidone and vinyl acetate, which with
  • VP / VA copolymers with a higher vinylpyrrolidone content are water-soluble, for example from a VP content of 60%.
  • VP / VA copolymers with lower VP content can be dissolved in ethanol.
  • the vinylpyrrolidone-vinyl acetate copolymer (a) has a weight ratio of vinylpyrrolidone (VP) to vinyl acetate (VA) of 30:70 to 70:30, preferably 50:70 to 30:50, more preferably about 60:40.
  • Preferred vinylpyrrolidone-vinyl acetate copolymers are available under the trade name
  • Luviskol® VA 64 P (pulverulent, solids content at least 95% by weight, K value 26-34) or Luviskol® VA 64 W (about 50% strength by weight aqueous solution, K value 26-34) is most preferred according to the invention ).
  • the K value which is also referred to as intrinsic viscosity, is a parameter which can be easily determined from the relative viscosity by means of viscosity measurements of polymer solutions for the characterization of polymers.
  • VA / VP copolymers preferred according to the invention have a K value (1% by weight in ethanol) of about 20 to 40, preferably about 25 to 35.
  • the vinylpyrrolidone-vinyl acetate copolymer (a) usually contains no further in the present invention comonomers. The presence of further comonomers is erfindunsclean but not excluded in certain embodiments.
  • the polyurethane-polyether copolymer (b) contains as constituents the diisocyanate (b1),
  • Polyalkylene glycol (b2) and the polyalkylene glycol alkyl ether (b3) The polyether-polyurethane copolymer according to the invention usually has hydrophilic regions due to the polyalkylene glycol units and hydrophobic Breiche due to the diisocyanate units.
  • the polyurethane-polyether copolymer (b) can be constructed according to the invention from further monomer units. This is preferred
  • Polyurethane-polyether copolymer (b) but composed only of the units (b1), (b2) and (b3), d. H. it consists of units derived from these monomer units.
  • the diisocyanate (b1) is an alkylene diisocyanate having a linear alkylene chain of 2 to 10 carbon atoms.
  • the diisocyanate is hexamethylene diisocyanate (HDI).
  • diisocyanates are, for. Example, toluene-2-4-diisocyanate (2,4-TDI), toluene-2-6-diisocyanate (2,6-TDI) or methylene diisocyanates such as diphenylmethane-2,2'-diisocyanate (2,2'-MDI) , Diphenylmethane-2,4'-diisocyanate (2,4'-MDI) and diphenylmethane-4,4'-diisocyanate (4,4'-MDI).
  • toluene-2-4-diisocyanate (2,4-TDI
  • toluene-2-6-diisocyanate 2,6-TDI
  • methylene diisocyanates such as diphenylmethane-2,2'-diisocyanate (2,2'-MDI) , Diphenylmethane-2,4'-diisocyanate (2,4'-MDI)
  • the polyalkylene glycol (b2) according to the invention is usually a polyethylene glycol (PEG).
  • Polypropylene glycols should also be included according to the invention. This is preferred
  • Polyethylene glycol in the present invention a polyethylene glycol, which is more preferably about 100 to 150 ethylene glycol units, more preferably about 130 to 140
  • Ethylene glycol units Particularly preferred is the use of PEG 136.
  • the polyalkylene glycol alkyl ether (b3) according to the invention is preferably a polyethylene glycol ether.
  • polypropylene glycol ethers are also included as examples.
  • Polyalkylene glycol alkyl ethers (b3) in particular the polyethylene glycol ethers, 80 to 120
  • Alkylene oxide units which are ethylene oxide units in the case of the polyethylene glycol ether.
  • the polyalkylene glycol alkyl ether (b3) is preferably a polyalkylene glycol C10-C20 alkyl ether, especially polyethylene glycol stearyl ether.
  • Further suitable polyalkylene glycol alkyl ethers are, for example, polyethylene glycol lauryl ether, polyethylene glycol cetyl ether or
  • Particularly preferred according to the invention is the use of a polyurethane-polyether copolymer (b) having the INCI name steareth-100 / PEG-136 / HDI copolymer.
  • a polyurethane-polyether copolymer is described in FR 2975900 as an alpha-omega-stearyl-polyoxyethylene-terminated polyether-polyurethane and is commercially available as RHEOLATE® FX 1 100 (Elementis).
  • the cosmetic composition of the present invention contains the vinylpyrrolidone homo- or copolymer (a) and the polyurethane-polyether copolymer (b) in suitable and suitable amounts for styling agents, which can be adapted for the specific application and packaging.
  • the vinylpyrrolidone homopolymer (a) is e.g. in a total amount of from 0.01 to 5% by weight, preferably from 0.01% to 3.0% by weight, more preferably from 0.1 to 2.0% by weight, most preferably from 0 , 3 wt .-% to 1, 5 wt .-%, most preferably from 0.6 wt .-% to 1, 4 wt .-%, and particularly preferably from 0.8 to 1, 2 wt .-% contained in the composition according to the invention, in each case indicated as the solids content of active substance in the cosmetic composition.
  • the cosmetic composition of the invention contains the polyurethane-polyether copolymer (b), based on the total weight of the cosmetic composition, for. In an amount of 0.05 to 5.0 wt .-%, preferably 0.1 to 4.0 wt .-%, more preferably 0.5 to 3.0 wt .-%, also preferably from 0, 5 to 1, 5 wt .-%, and particularly preferably from 0.8 to 1, 2 wt .-%, each expressed as the solids content of active substance in the cosmetic composition.
  • a polyurethane-polyether copolymer (b) having the INCI name steareth-100 / PEG-136 / HDI copolymer used was a particularly good
  • a combination of a vinylpyrrolidone / vinyl acetate copolymer (a) with a ratio of vinylpyrrolidone (VP) to
  • a polyurethane-polyether copolymer (b) having the INCI name Steareth-100 / PEG-136 / HDI copolymer was a particularly good
  • the cosmetic composition of the present invention contains one or more other component (s) acting as a thickener or gelling agent, which are / are different from components (a) and (b) and also aid in film formation.
  • component (s) acting as a thickener or gelling agent examples are cationic, anionic, nonionic or amphoteric polymers.
  • the proportion by weight of this further component in the total weight of the cosmetic composition can be reduced due to the presence of the Components (a) and (b) may be comparatively low and is, for example, 0.02 to 3% by weight, preferably 0.05 to 1.5% by weight and more preferably 0.2 to 0.8% by weight.
  • Examples are Acrylamide / Ammonium Acrylate Copolymer, Acrylamide / DMAPA Acrylate / Methoxy PEG Methacrylate Copolymer, Acrylamidopropyltrimonium Chloride / Acrylamide Copolymer,
  • Diethylenetriamine Copolymer Adipic Acid / Isophthalic Acid / Neopentyl Glycol / Trimethylolpropane Copolymer, Allyl Stearate / VA Copolymer, Aminoethyl Acrylates Phosphate / Acrylates Copolymer, Aminoethylpropanediol Acrylates / Acrylamide Copolymer, Aminoethylpropanediol AMPD Acrylates / Diacetone Acrylamide Copolymer, Ammonium VA / Acrylates Copolymer, AMPD Acrylates / diacetone acrylamide copolymer, AMP acrylates / allyl methacrylate copolymer, AMP acrylates / C1 -18 alkyl acrylates / C1 -8 alkyl acrylamide copolymer, AMP acrylates / diacetone acrylamide copolymer, AMP acrylates / dimethyl
  • Butyloxyamodimethicone / PEG-60 Copolymer Butyl Acrylate / Ethylhexyl Methacrylate Copolymer, Butyl Acrylate / Hydroxypropyl Dimethicone Acrylate Copolymer, Butylated PVP, Butyl Ester of Ethylene / MA Copolymer, Butyl Ester of PVM / MA Copolymer, Calcium / Sodium PVM / MA Copolymer, Com
  • nonionic polymers examples are:
  • Cellulose ethers such as hydroxypropylcellulose, hydroxyethylcellulose and methylhydroxypropylcellulose, as marketed, for example, under the trademarks Culminal and Benecel (AQUALON).
  • siloxanes can be both water-soluble and water-insoluble. Suitable are both volatile and non-volatile siloxanes, such as non-volatile siloxanes
  • siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, such as, for example, polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups.
  • the further component acting as gelling agent is preferably a homopolyacrylic acid (INCI:
  • Carbomer which is commercially available under the name Carbopol® in different designs.
  • the carbomer is preferably in a proportion of 0.02 to 3.0% by weight, preferably 0.05 to 1.5% by weight, and more preferably 0.2 to 0.8% by weight, in terms of the total weight of the cosmetic composition.
  • the cosmetic composition according to the invention may contain other conventional substances
  • Styling products included.
  • Other suitable auxiliaries and additives are in particular additional care substances.
  • the agent may contain, for example, at least one protein hydrolyzate and / or one of its derivatives.
  • Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins).
  • the term protein hydrolyzates also means total hydrolysates as well as individual amino acids and their derivatives as well as mixtures of different amino acids.
  • the molecular weight of the protein hydrolysates which can be used according to the invention is between 75, the molecular weight for glycine, and 200,000, preferably the molecular weight is 75 to 50,000 and very particularly preferably 75 to 20,000 daltons.
  • the agent according to the invention may further comprise at least one vitamin, a provitamin, a vitamin precursor and / or one of their derivatives.
  • vitamins, provitamins and vitamin precursors are preferred, which are usually assigned to groups A, B, C, E, F and H.
  • panthenol increases the flexibility of the polymer film formed using the composition of the present invention.
  • the compositions according to the invention may further contain at least one plant extract, but also mono- or oligosaccharides and / or lipids.
  • oil bodies are suitable as a care substance.
  • the natural and synthetic cosmetic oil bodies include, for example, vegetable oils, liquid paraffin oils, isoparaffin oils and synthetic hydrocarbons and di-n-alkyl ethers having a total of between 12 and 36 carbon atoms, in particular 12 to 24 carbon atoms.
  • Preferred cosmetic agents according to the invention contain at least one oil body, preferably at least one oil body from the group of silicone oils.
  • the group of silicone oils includes in particular the dimethicones, to which the cyclomethicones are also to be expected, the amino-functional silicones and the dimethiconols.
  • the dimethicones may be both linear and branched as well as cyclic or cyclic and branched.
  • Suitable silicone oils or silicone gums are, in particular, dialkyl and alkylaryl siloxanes, for example dimethylpolysiloxane and methylphenylpolysiloxane, and also their alkoxylated, quaternized or else anionic derivatives. Preference is given to cyclic and linear polydialkylsiloxanes, their alkoxylated and / or aminated derivatives, dihydroxypolydimethylsiloxanes and polyphenylalkylsiloxanes.
  • Ester oils ie esters of C6-C30 fatty acids with C2-C30 fatty alcohols, preferably monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms such as isopropyl myristate (Rilanil® IPM), lsononanklare-C16-18-alkyl ester (Cetiol® SN), 2-ethylhexyl palmitate (Cegesoft® 24),
  • Stearic acid 2-ethylhexyl ester (Cetiol® 868), cetyl oleate, glycerol tricaprylate, coconut fatty alcohol caprinate / caprylate (Cetiol® LC), n-butyl stearate, oleyl erucate (Cetiol® J 600), isopropyl palmitate (Rilanil® IPP), oleyl oleate (Cetiol ®), lauric acid hexyl ester (Cetiol® A), di-n-butyladipate (Cetiol® B), myristyl myristate (Cetiol® MM), cetearyl isononanoate (Cetiol® SN), oleic acid decyl ester (Cetiol® V) are further preferred caring oil bodies.
  • dicarboxylic acid esters symmetrical, unsymmetrical or cyclic esters of carbonic acid with fatty alcohols
  • triflic acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol or fatty acid partial glycerides which are understood to mean monoglycerides, diglycerides and technical mixtures thereof.
  • composition according to the invention emulsifiers or
  • PEG derivatives of hydrogenated castor oil the z. Sold under the name PEG Hydrogenated Castor Oil, e.g. PEG-30 Hydrogenated Castor Oil, PEG-33 Hydrogenated Castor Oil, PEG-35 Hydrogenated Castor Oil, PEG-36
  • Hydrogenated Castor Oil or PEG-40 Hydrogenated Castor Oil is the use of PEG-40 hydrogenated castor oil. These are preferably contained in an amount of 0.05 to 1.5% by weight, more preferably 0.1 to 1.0% by weight, and also preferably 0.2 to 0.8% by weight or 0.3 to 0.6% by weight.
  • the cosmetic composition of the present invention may further contain neutralizers or pH adjusters. Examples of neutralizers used in styling products are primary amino alcohols. An example of such a neutralizer which can preferably be used according to the invention is aminomethyl propanol (INCI), which is commercially available, for example, under the name AMP-ULTRA® PC. AMP-ULTRA® PC 2000 is preferred according to the invention and contains 5% water.
  • the agents according to the invention contain the ingredients or active ingredients in a cosmetically acceptable carrier.
  • Preferred cosmetically acceptable carriers are aqueous, alcoholic or aqueous-alcoholic media with preferably at least 10% by weight of water, calculated on the total weight of the agent.
  • the cosmetic carrier according to the invention particularly preferably comprises water, in particular in the amount, that the cosmetic agent, calculated on the total weight of the composition, is at least 10% by weight, in particular at least 20.0% by weight, most preferably at least 40% by weight. Contains% water. Very particularly preferred cosmetic agents are characterized in that, based on their total weight, they contain 50 to 98% by weight, preferably 70 to 98% by weight and in particular 80 to 98% by weight of water.
  • alcohols it is possible in particular to include the lower alcohols having 1 to 4 carbon atoms usually used for cosmetic purposes, such as, for example, ethanol and isopropanol.
  • water-soluble solvents as cosolvent are glycerol and / or ethylene glycol and / or 1, 2-propylene glycol in an amount of 0 to 30 wt .-% based on the total agent.
  • the cosmetic composition of the present invention may be formulated in the forms customary for the temporary shaping of hair, e.g. B. as a hair gel, hair spray
  • Hair foam or hair wax Preference is given to the preparation as a hair gel.
  • the present invention also relates to the use of cosmetic compositions according to the invention for the temporary reshaping of keratinic fibers, in particular of human hair, as well as a method for the temporary deformation of keratinic fibers, in particular human hair, in which the cosmetic composition according to the invention is applied to keratinic fibers.
  • composition of some preferred cosmetic agents can be found in the following tables (data in% by weight based on the total weight of the cosmetic agent, unless stated otherwise).
  • Carbomer 0.02 to 3.0 0.05 to 2.0 0.1 to 1.5, 0.2 to 1.0, 0.4 to 0.8
  • Carbomer 0.02 to 3.0 0.05 to 2.0 0.1 to 1.5, 0.2 to 1.0, 0.4 to 0.8
  • Carbomer 0.02 to 3.0 0.05 to 2.0 0.1 to 1.5 0.2 to 1.0 0.4 to 0.8
  • Carbomer 0.02 to 3.0 0.05 to 2.0 0.1 to 1.5 0.2 to 1.0 0.4 to 0.8
  • Carbomer 0.02 to 3.0 0.05 to 2.0 0.1 to 1.5 0.2 to 1.0 0.4 to 0.8
  • Carbomer 0.02 to 3.0 0.05 to 2.0 0.1 to 1.5 0.2 to 1.0 0.4 to 0.8
  • Carbomer 0.02 to 3.0 0.05 to 2.0 0.1 to 1.5 0.2 to 1.0 0.4 to 0.8
  • Carbomer 0.02 to 3.0 0.05 to 2.0 0.1 to 1.5 0.2 to 1.0 0.4 to 0.8
  • Aminomethyl Propanol 0.01 to 2.0 0.05 to 1.5, 0.1 to 0.1, 0.1 to 0J 0.2 to 0.5
  • “Mise” is to be understood as meaning a cosmetic carrier, in particular water and optionally further customary constituents of styling products.

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Abstract

La présente invention concerne une composition cosmétique pour la mise en forme temporaire de cheveux, cette composition contenant une association de deux (co)polymères non ioniques. Cette composition cosmétique possède, outre les propriétés requises de rigidité et de tenue longue durée, une très haute résistance à l'humidité.
PCT/EP2015/068557 2014-08-28 2015-08-12 Utilisation d'une association d'un copolymère de polyuréthane-polyéther et d'un homopolymère ou copolymère de vinylpyrrolidone WO2016030186A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE102014217201.2A DE102014217201A1 (de) 2014-08-28 2014-08-28 Verwendung einer Kombination von Rheolate FX 1100 und Luviskol K90
DE102014217201.2 2014-08-28
DE102014217205.5A DE102014217205A1 (de) 2014-08-28 2014-08-28 Verwendung einer Kombination von Rheolate FX 1100 und Luviskol VA 64 W
DE102014217205.5 2014-08-28

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WO2016030186A1 true WO2016030186A1 (fr) 2016-03-03

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2894817A1 (fr) * 2005-12-20 2007-06-22 Oreal Procede de maquillage ou de soin des matieres keratiniques comprenant l'application de composes a et b dont l'un au moins est silicone
FR2917974A1 (fr) * 2007-06-29 2009-01-02 Oreal Composition anhydre comprenant au moins un colorant direct, au moins un complexe peroxyde d'hydrogene et d'un polymere particulier et procede de coloration la mettant en oeuvre
DE102011081608A1 (de) * 2011-08-26 2013-02-28 Henkel Ag & Co. Kgaa Wasserstoffperoxid-haltige Mittel mit verbesserter Viskositätseinstellung

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2894817A1 (fr) * 2005-12-20 2007-06-22 Oreal Procede de maquillage ou de soin des matieres keratiniques comprenant l'application de composes a et b dont l'un au moins est silicone
FR2917974A1 (fr) * 2007-06-29 2009-01-02 Oreal Composition anhydre comprenant au moins un colorant direct, au moins un complexe peroxyde d'hydrogene et d'un polymere particulier et procede de coloration la mettant en oeuvre
DE102011081608A1 (de) * 2011-08-26 2013-02-28 Henkel Ag & Co. Kgaa Wasserstoffperoxid-haltige Mittel mit verbesserter Viskositätseinstellung

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