EP1584324B1 - Composition de soin capillaire comprenant un acide dicarboxylique et de l'acide édétique - Google Patents

Composition de soin capillaire comprenant un acide dicarboxylique et de l'acide édétique Download PDF

Info

Publication number
EP1584324B1
EP1584324B1 EP05004106A EP05004106A EP1584324B1 EP 1584324 B1 EP1584324 B1 EP 1584324B1 EP 05004106 A EP05004106 A EP 05004106A EP 05004106 A EP05004106 A EP 05004106A EP 1584324 B1 EP1584324 B1 EP 1584324B1
Authority
EP
European Patent Office
Prior art keywords
hair
acid
cosmetic composition
hair cosmetic
feel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP05004106A
Other languages
German (de)
English (en)
Other versions
EP1584324A1 (fr
Inventor
Kenichi c/o Kao Corporation Research Lab. Ueyama
Nozomi c/o Kao Corpor. Research Lab. Nagashima
Kazuhisa c/o Kao Corpor. Research Lab. Fukuhara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Publication of EP1584324A1 publication Critical patent/EP1584324A1/fr
Application granted granted Critical
Publication of EP1584324B1 publication Critical patent/EP1584324B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/362—Polycarboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01K—ANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K61/00—Culture of aquatic animals
    • A01K61/70—Artificial fishing banks or reefs
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • E—FIXED CONSTRUCTIONS
    • E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02B—HYDRAULIC ENGINEERING
    • E02B3/00—Engineering works in connection with control or use of streams, rivers, coasts, or other marine sites; Sealings or joints for engineering works in general
    • E02B3/04—Structures or apparatus for, or methods of, protecting banks, coasts, or harbours
    • E02B3/043—Artificial seaweed
    • E—FIXED CONSTRUCTIONS
    • E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02B—HYDRAULIC ENGINEERING
    • E02B3/00—Engineering works in connection with control or use of streams, rivers, coasts, or other marine sites; Sealings or joints for engineering works in general
    • E02B3/04—Structures or apparatus for, or methods of, protecting banks, coasts, or harbours
    • E02B3/046—Artificial reefs

Definitions

  • the present invention relates to a leave-on hair cosmetic composition containing an organic dicarboxylic acid or salt thereof.
  • Examples of commercially available leave-on hair cosmetic compositions mainly used now include emulsion type products such as hair cream having wax, higher alcohol and surfactant to provide the hair with manageability and protect the hair from excessive drying; and gel products having a film forming polymer (set polymer) incorporated therein.
  • emulsion type products such as hair cream having wax, higher alcohol and surfactant to provide the hair with manageability and protect the hair from excessive drying
  • gel products having a film forming polymer (set polymer) incorporated therein Such hair cosmetic compositions can temporarily overcome the problems such as poor manageability and excessive dryness by causing an oil or fat or a polymer to adhere to the hair surface, thereby forming a film structure, but cannot fundamentally improve the hair luster or manageability.
  • compositions using a specific organic acid and organic solvent are known as those using a technology intended to improve hair quality by acting on the inside of the hair (refer to, for example, JP-A-1995-112921 , JP-A-1994-172131 , JP-A-1997-301831 and JP-A-1994-298625 ). These compositions promote manageability of the hair by softening the hair which is stiff and therefore, hard to handle.
  • a leave-on hair cosmetic composition which contains the following components (A), (B) and (C):
  • a hair quality improving method which includes treating the hair with the above-described composition.
  • the present invention relates to a leave-on hair cosmetic composition capable of providing benefits such as essentially improving the hair quality, improving luster and manageability of the hair, and providing excellent feel of the hair.
  • the present inventors have completed the present invention upon finding that the improvement in feel of the hair upon shampooing, alleviation of unfavorable feel of the hair such as stiffness of the hair after permanent waving or frictional feel upon shampooing, and improvement in strength/body and luster can be achieved when an edetic acid or a salt thereof is added to a hair cosmetic composition containing an organic dicarboxylic acid and a penetration-accelerating organic solvent, since by doing so not only is its salt-resistant performance improved but also edetic acid is adsorbed to the hair in advance which suppresses the formation of scum.
  • the term "hair quality improving" means resolving unfavorable feel of the hair and improving strength/body and luster of the hair.
  • the organic dicarboxylic acid to be used as Component (A) of the invention has from 2 to 8 carbon atoms and examples include malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid and tartaric acid. Of these, those having at least 3 carbon atoms are preferred, with hydroxydicarboxylic acids such as malic acid and tartaric acid, and malonic acid and succinic acid being preferred. Among them, malic acid is preferred.
  • the salts of these organic dicarboxylic acids include salts with an alkali metal, alkaline earth metal, ammonia and organic amine compound.
  • Component (A) may be used in combination of two or more.
  • the content of Component (A) in the hair cosmetic composition of the invention is preferably from 0.01 to 30 wt.%, more preferably from 0.1 to 20 wt.%, even more preferably from 0.5 to 10 wt.% in consideration of internal hair-quality improving effects (pore repairing effects and the like), set retention improving effects and manageability improving effects.
  • the organic solvent to be used as Component (B) of the invention is at least one or more selected from the group consisting of benzyl alcohol and benzyloxyethanol.
  • Component (B) to be used in the invention is a liquid at 25°C and has a ClogP of from -2 to 3, in particular from -1 to 2 in view of penetration promotion.
  • ClogP as used herein means a measure indicating the distribution of a substance between an octanol phase and an aqueous phase. It is a calculated value of an octanol-water distribution coefficient (logP) as defined by the below-described equation and its example is described in Chemical Reviews, 71(6), 1971 .
  • ClogP of the compounds usable as Component (B) benzyl alcohol (1.1), 2-benzyloxyethanol (1.2).
  • the two compounds may be used in combination.
  • Its content in the hair cosmetic composition of the invention is preferably from 0.1 to 40 wt.%, more preferably from 0.5 to 10 wt.%, even more preferably from 1 to 5 wt.% in view of its feeling upon use, hair luster and hair quality improving effects (improvement of elasticity, improvement of moisture resistance, and the like).
  • alkali metal salts such as sodium salts and potassium salts can be used. Specific examples include disodium edetate, trisodium edetate and tetrasodium edetate.
  • edetic acid or a salt thereof is added to the hair cosmetic composition, not only is its salt-resistant performance improved but also edetic acid is adsorbed to the hair in advance which suppresses the formation of scum, resulting in the improvement in hair feel upon shampooing, alleviation of stiffness of the hair after permanent waving or unfavorable feel of the hair upon shampooing, and improvement in strength/body and luster.
  • Component (C) two or more compounds may be used in combination. Its content in the hair cosmetic composition of the invention is preferably from 0.01 to 10 wt.%, more preferably from 0.05 to 5 wt.%, even more preferably from 0.1 to 2 wt.%.
  • a weight ratio (A):(B) of the organic dicarboxylic acid or salt thereof as Component (A) to the organic solvent as Component (B) preferably ranges from 10:1 to 1:7, more preferably from 4:1 to 1:3 in order to effectively produce internal hair-quality improving (pore repairing) effects, set retention improving effects and manageability improving effects.
  • the organic solvent as Component (B) and edetic acid or salt thereof as Component (C) are preferably added at a weight ratio ranging from 2000:1 to 2:1, more preferably within a range of from 500:1 to 5:1 in order to promote the penetration of Component (C) in the hair and effectively produce the improving effect of strength/body of the hair and set retention.
  • the hair cosmetic composition of the invention may further contain ethanol.
  • Ethanol contributes to the solubilization or stable dispersion of Component (B). It also contributes to the solubilization of Components (A) and (C), whereby the penetration into the hair is promoted.
  • the content of ethanol in the hair cosmetic composition of the invention is preferably from 0.01 to 50 wt.%, more preferably from 1 to 20 wt.%.
  • a weight ratio of ethanol to Component (B) preferably ranges from 40:1 to 2:1, more preferably from 20:1 to 3:1 from the viewpoint of penetration promotion of Components (A) through (C) into the hair.
  • the hair cosmetic composition of the invention may further contain a set polymer in view of improvement of hair styling, regulation of viscosity, stability, improvement of adhesion upon application to the hair, improvement of feel of the hair and early expression of hair quality improving effects.
  • a polymer include polyvinylpyrrolidone polymer compounds such as polyvinylpyrrolidone, vinylpyrrolidone/vinyl acetate copolymer, vinylpyrrolidone/vinyl acetate/vinyl propionate tertiary copolymer, vinylpyrrolidone/alkylaminoacrylate (quaternized chloride) copolymer, vinylpyrrolidone/acrylate/(meth)acrylic acid copolymer, and vinylpyrrolidone/alkylaminoacrylate/vinylcaprolactam copolymer; acidic vinyl ether polymer compounds such as methyl vinyl ether/maleic anhydride alkyl half ester copolymer; acidic polyvinyl acetate
  • These set polymers may be used either singly or in combination of two or more.
  • Their content in the hair cosmetic composition of the invention is preferably from 0.1 to 10 wt.%, more preferably from 0.5 to 5 wt.%.
  • At least one or more conditioning components selected from the group consiting of silicones and oily substances can be incorporated in order to improve conditioning effects further.
  • the silicones include dimethylpolysiloxanes, polyether-modified silicones, amino-modified silicones, carboxy-modified silicones, methylphenylpolysiloxanes, fatty acid-modified silicones, alcohol-modified silicones, aliphatic alcohol-modified silicones, epoxy-modified silicones, fluorine-modified silicones, cyclic silicones, and alkyl-modified silicones.
  • dimethylpolysiloxanes, polyether-modified silicones and amino-modified silicones are preferred.
  • Dimethylpolysiloxanes, polyether-modified silicones and amino-modified silicones can impart the hair with good lubricity, smoothness and moist feeling, respectively.
  • various silicones can be used either singly or in combination of two or more, depending on the desired performance.
  • those having a viscosity of from 5 mm 2 /s to 10 million mm 2 /s can be used depending on the desired feel of the hair, wherein those having a viscosity of 10 million mm 2 /s are often supplied in the form of an emulsion.
  • those having a viscosity falling within a range of from 5000 mm 2 /s to 10 million mm 2 /s are preferred, with those having a viscosity of from 50000 mm 2 /s to 10 million mm 2 /s being more preferred.
  • polyether-modified silicones is a generic name of polyoxyethylene/methylpolysiloxane copolymers and poly(oxyethylene ⁇ oxypropylene)methylpolysiloxane copolymers and those having various HLBs are known.
  • Examples of the commercially available products thereof include “Silicone KF351A”, “Silicone KF353A”, “Silicone KF6008”, “Silicone KF6016", “Silicone KF6011”, and “Silicone KF6012” (each, trade name; product of Shin-etsu Chemical), and "SH3771C”, “SH3773C”, and “SH3775C” (each, trade name; product of Dow Corning Toray Silicone).
  • As the amino-modified silicones amodimethicone oil or an emulsion thereof is preferred.
  • the content of the silicones in the hair cosmetic composition of the invention is preferably from 0.05 to 20 wt.%, more preferably from 0.1 to 10 wt.%, even more preferably from 0.5 to 5 wt.% in consideration of smooth finger combing and stickiness-free feel.
  • the oily substance is added to improve the hair manageability after drying.
  • hydrocarbons such as squalene, squalane, liquid isoparaffin, light liquid paraffin, heavy liquid isoparaffin, ⁇ -olefin oligomer, liquid paraffin and cycloparaffin
  • glycerides such as castor oil, cacao oil, mink oil, avocado oil and olive oil
  • waxes such as bees wax, spermaceti, lanolin, microcrystalline wax, ceresin wax and carnauba wax
  • higher alcohols such as cetyl alcohol, oleyl alcohol, stearyl alcohol, isostearyl alcohol and 2-octyldodecanol
  • esters such as octyldodecyl myristate, hexyl laurate, cetyl lactate, propylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, is
  • the content of the oily substance in the hair cosmetic composition of the invention is preferably from 0.05 to 20 wt.%, more preferably from 0.1 to 10 wt.%, even more preferably from 0.5 to 5 wt.% in view of good manageability and stickiness-free feel.
  • a surfactant may be incorporated from the viewpoints of the stabilization of the system including the solubilization and dispersion of the solvent and improvement in the feel of the hair.
  • the surfactant any one of cationic surfactant, nonionic surfactant, amphoteric surfactant and anionic surfactant can be used.
  • cationic surfactant examples include quaternary ammonium salts represented by the following formula (6): wherein R 6 and R 7 each independently represents a hydrogen atom, a C 1-28 alkyl group or a benzyl group, with the proviso that they do not simultaneously represent a hydrogen atom, a benzyl group or a C 1-3 lower alkyl group, and Z - represents an anion.
  • Either one of R 6 and R 7 preferably represents an alkyl group having from 16 to 24 carbon atoms, more preferably 22 carbon atoms, even more preferably a linear alkyl group, while the other one represents a lower C 1-3 alkyl group, preferably a methyl group.
  • the anion Z - include halide ions such as chloride ions and bromide ions, and organic anions such as ethyl sulfate ions and methyl carbonate ions. Of these, halide ions are preferred, among which chloride ions are preferred.
  • mono(long chain alkyl) quaternary ammonium salts are preferred. Specific examples include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, arachyltrimethylammonium chloride and behenyltrimethylammonium chloride. Of these, stearyltrimethylammonium chloride and behenyltrimethylammonium chloride are preferred.
  • nonionic surfactant examples include polyoxyalkylene alkyl ethers, polyoxyalkylene alkenyl ethers, higher fatty acid sucrose esters, polyglycerin fatty acid esters, higher fatty acid mono- or diethanolamides, polyoxyethylene hydrogenated castor oils, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene sorbitol fatty acid esters, alkyl saccharide surfactants, alkylamine oxides, and alkylamide amine oxides.
  • polyoxyalkylene alkyl ethers, polyoxyethylene hydrogenated castor oil are preferred, with polyoxyethylene alkyl ethers being more preferred.
  • amphoteric surfactant imidazoline, carbobetaine, amidobetaine, sulfobetaine, hydroxysulfobetaine, and amidosulfobetaine can be used.
  • anionic surfactant examples include alkylbenzene sulfonates, alkyl or alkenyl ether sulfates, alkyl or alkenyl sulfates, olefin sulfonates, alkane sulfonates, saturated or unsaturated fatty acid salts, alkyl or alkenyl ether carboxylates, ⁇ -sulfone fatty acid salts, N-acylamino acid surfactants, mono- or di-phosphate surfactants and sulfosuccinates.
  • Examples of the counterion as the anionic residue of the above-described surfactants include alkali metal ions such as sodium ion and potassium ion; alkaline earth metal ions such as calcium ion and magnesium ion, ammonium ions, alkanolamines having 1 to 3 alkanol groups with 2 or 3 carbon atoms (such as monoethanolamine, diethanolamine, triethanolamine and triisopropanolamine).
  • alkali metal ions such as sodium ion and potassium ion
  • alkaline earth metal ions such as calcium ion and magnesium ion, ammonium ions
  • alkanolamines having 1 to 3 alkanol groups with 2 or 3 carbon atoms such as monoethanolamine, diethanolamine, triethanolamine and triisopropanolamine.
  • Examples of the counterion as the cationic residue include halide ions such as chloride ions, bromide ions and iodide ions, methosulfate ions and
  • cationic surfactants are preferred in view of feel of the hair. These surfactants may be used either singly or in combination of two or more.
  • the content of the surfactant(s) in the hair cosmetic composition of the invention is preferably from 0.01 to 10 wt.%, more preferably from 0.05 to 3 wt.% in view of stabilization of the system including solubilization of the solvent and emulsification of the oily substance.
  • the hair cosmetic composition of the invention may further contain a polyhydric alcohol.
  • the polyhydric alcohol contributes to solubilization and stable dispersion of Component (B).
  • the enhancement of the hair luster and the hair quality improving effect is accelerated by the synergistic action between the polyhydric alcohol and Component (B).
  • the polyhydric alcohol include ethylene glycol, glycerin, sorbitol, propylene glycol, 1,3-butyleneglycol and dipropylene glycol. Of these, glycerin is preferred.
  • These polyhydric alcohols may be used either singly or in combination of two or more. Its content in the hair cosmetic composition of the invention is preferably from 0.1 to 10 wt.%, more preferably from 0.5 to 5 wt.%.
  • the hair cosmetic composition of the invention may further contain, as needed, components employed for ordinary hair cosmetic compositions depending on their purpose of use.
  • components include antidandruffs, vitamin preparations, bactericides, antiinflammatories, chelating agents other than Component (C), humectants such as sorbitol and panthenol, coloring agents such as dyes and pigments, viscosity regulators such as hydroxyethyl cellulose, methyl cellulose, polyethylene glycol and clay mineral, pH regulators such as organic acids other than Component (A), sodium hydroxide and potassium hydroxide, plant extracts, pearling agents, perfumes, colorants, ultraviolet absorbers, antioxidants, and the other components as described in ENCYCLOPEDIA OF SHAMPOO INGREDIENTS (MICELLE PRESS ).
  • the hair cosmetic composition of the invention is adjusted to have a pH of from 2 to 5 (at 25°C when diluted to 20 times the weight with water), preferably from 2.5 to 4, more preferably from 3 to 4 upon application to the hair from the standpoints of promoting penetration and adsorption of Components (A) and (B) to the hair and at the same time, giving luster, flexibility, manageability and pliability to the hair.
  • the form of the hair cosmetic composition of the invention can be selected from liquid, gel, paste, cream and wax as needed, but that in the form of a solution using, as a solvent, water is preferred:
  • the hair cosmetic composition of the invention is preferably used as a hair styling agent or hair conditioning agent. It can be provided, for example, as a pump spray, aerosol spray, pump foam, aerosol foam, gel or lotion.
  • the heating temperature is preferably 60°C or greater, especially preferably 70°C or greater.
  • the pH in the below-described example and comparative compositions is a value at 25°C when diluted to 20 times the weight with water.
  • a hair bundle of 10 cm in length, 1.5 cm in width and 1 g in weight was made using the hair of a Japanese female who's hair was had not been subjected to chemical treatment such as permanent waving and hair coloring.
  • the hair bundle was bleached (by "Ravenus Color Appeal Inazuma Bleach”; product of Kao) twice and the resulting hair bundle was provided for the evaluation of setting property.
  • the hair bundle to be evaluated was subjected to shampooing (with "Ravenus Designing Shampoo", product of Kao), towel drying, uniform application of 0.1 g of the invention or comparative compositions (which will hereinafter be called “treatment agent”), and drying for 10 minutes with hot air of 70°C. This treatment was repeated six times in total. After shampooing, towel drying and application of the treatment agent similarly, the hair bundle was wound around a rod having a diameter of 4 cm and dried for 10 minutes with hot air of 70°C.
  • the internal hair-quality improving effect was studied by evaluating the set retention after the treatment agent on the hair surface was washed away. After completion of the pre-shampoo evaluation, each hair bundle was shampooed and towel dried. Without application of the treatment agent to the hair, the hair bundle was wound around a rod having a diameter of 4 cm and dried for 10 minutes with hot air of 70°C.
  • the curled bundle was removed from the rod and a comb (ring comb) was caused to run through the bundle 20 times to disentangle it. It was suspended in a thermo-hydrostatic box (25°C and 98%RH) to determine the set retention power. Described specifically, the length of the hair bundle thus suspended (distance from the bundled position to the end of the hair) was measured. The length of the hair bundle right after suspension was set as the set-retention percentage of 100% and the initial length of the hair bundle (10 cm) before curling was set as the set-retention percentage of 0%. A relative value (%) of the length of the hair bundle after 30 minutes, that is, a set-retention percentage after 30 minutes was determined in accordance with the following equation:
  • Set retention % ( initial length of the hair bundle ) - length of the hair bundle after 30 minutes / ( initial length of the hair bundle ) - length of the hair bundle right after curling ⁇ 100
  • a hair bundle of 25 cm in length and 6 g in weight was made using the hair of a Japanese female not subjected to chemical treatment such as permanent waving and hair coloring.
  • the hair bundle was bleached (by "Ravenus Color Appeal Inazuma Bleach”; product of Kao) twice and the resulting hair bundle was provided for the evaluation.
  • the hair bundle to be evaluated was subjected to shampooing (with "Ravenus Designing Shampoo", product of Kao), towel drying, uniform application of 0.6 g of the treatment agent, and drying for 10 minutes with hot air of 70°C while running a ring comb through the hair bundle. This treatment was repeated seven times in total.
  • the hair bundle after completion of the pre-shampoo evaluation was shampooed and towel-dried, and then dried for 10 minutes with hot air of 70°C while running a ring comb through the hair bundle.
  • Organoleptic evaluation by a panel of 5 experts was performed in accordance with the criteria shown in Table 1 and an average of the scores is shown in Table 2.
  • the above-described results have revealed that unlike hair cosmetic compositions obtainable by the conventional technology that has not overcome the problems such as stiffness and stickiness, the composition according to the examples achieved providing a good set retention, strength/body improving effects, manageability and improved feel of the hair. Even after the removal of the components attached to the surface of the hair by shampooing, the above-described effects last. In addition, the hair quality improving effects such as elimination of pores inside of the hair were confirmed.
  • Example 2 (Pump spray) (wt.%) Malic acid 4.0 Stearyltrimethylammonium chloride 0.25 Glycerin 1.0 2-Benzyloxyethanol 2.5 Propylene glycol (Mw400) 1.0 Ethanol 4.5 Disodium edetate 0.3 Perfume 0.02 Water Balance Sodium hydroxide (pH regulator) Amount to adjust pH to 3.7
  • Example 3 (Pump mist) (wt.%) Malic acid 3.5 Malonic acid 1.0 2-Benzyloxyethanol 2.5 N-methylpyrrolidone 0.5 Polyvinylpyrrolidone 3.0 Ethanol 8.0 Trisodium edetate 0.5 Perfume 0.05 Water Balance Sodium hydroxide (pH regulator) Amount to adjust pH to 3.7
  • Example 4 (Hair gel) (wt. %) Malic acid 2.5 Succinic acid 1.5 Glycerin 2.0 2-Benzyloxyethanol 2.5 ⁇ -lactone 0.5 Hydroxyethyl cellulose 2.0 - Ethanol 8.0 Disodium edetate 0.1 Trisodium edetate 0.05 Perfume 0.05 Water Balance Potassium hydroxide (pH regulator) Amount to adjust pH to 3.7
  • Example 5 (Hair lotion) (wt. %) Malic acid 4.0 Lactic acid 1.0 Glycerin 1.0 2-Benzyloxyethanol 2.5 Ethanol 7.0 Tetrasodium edetate 0.2 Perfume 0.02 Water Balance Sodium hydroxide (pH regulator) Amount to adjust pH to 3.7
  • Example 6 (Hair lotion) (wt.%) Malic acid 2.5 Lactic acid 2.5 2-Benzyloxyethanol 2.5 Propylene carbonate 0.5 Stearyltrimethylammonium chloride 0.1 Polyethylene glycol 400 0.45 Ethanol 4.5 Disodium edetate 0.2 Trisodium edetate 0.05 Tetrasodium edetate 0.05 Perfume 0.02 Water Balance Sodium hydroxide (pH regulator) Amount to adjust pH to 3.7
  • Example 7 (Pump foam) (wt.%) Malic acid 2.5 Lactic acid 2.5 Polyoxyethylene lauryl ether (16E.O.) 1.0 Stearyltrimethylammonium chloride 0.1 Glycerin 1.0 2-Benzyloxyethanol 2.5 Ethanol 5.5 Disodium edetate 0.08 Perfume 0.02 Water Balance Sodium hydroxide (pH regulator) Amount to adjust pH to 3.7

Claims (5)

  1. Composition cosmétique capillaire non rinçable comprenant les composants suivants (A), (B) et (C) :
    (A) un acide organique dicarboxylique en C2-θ ou son sel,
    (B) un ou plusieurs solvant(s) organique(s) choisi (s) dans le groupe formé par l'alcool benzylique et le 2-benzyloxyéthanol, dans lequel le solvant organique présente un ClogP de -2 à 3, et
    (C) un acide édétique ou son sel ;
    dans lequel la composition cosmétique a un pH de 2 à 5 à 25°C lorsqu'elle est diluée jusqu'à 20 fois son poids avec de l'eau.
  2. Composition cosmétique capillaire selon la revendication 1, comprenant de plus un polymère fixant.
  3. Composition cosmétique capillaire selon la revendication 1 ou 2, comprenant de plus un ou plusieurs composant(s) de conditionnement choisi(s) dans le groupe formé par les silicones et les substances huileuses.
  4. Composition cosmétique capillaire selon l'une quelconque des revendications 1 à 3, comprenant de plus un agent tensioactif cationique.
  5. Procédé pour l'amélioration de la qualité capillaire, comprenant le traitement des cheveux avec une composition cosmétique capillaire telle que définie dans l'une quelconque des revendications 1 à 4.
EP05004106A 2004-02-27 2005-02-25 Composition de soin capillaire comprenant un acide dicarboxylique et de l'acide édétique Active EP1584324B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2004053710 2004-02-27
JP2004053710A JP4381169B2 (ja) 2004-02-27 2004-02-27 毛髪化粧料

Publications (2)

Publication Number Publication Date
EP1584324A1 EP1584324A1 (fr) 2005-10-12
EP1584324B1 true EP1584324B1 (fr) 2007-11-21

Family

ID=34908756

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05004106A Active EP1584324B1 (fr) 2004-02-27 2005-02-25 Composition de soin capillaire comprenant un acide dicarboxylique et de l'acide édétique

Country Status (7)

Country Link
US (1) US7981407B2 (fr)
EP (1) EP1584324B1 (fr)
JP (1) JP4381169B2 (fr)
KR (1) KR101196280B1 (fr)
CN (1) CN1679474B (fr)
DE (1) DE602005003389T2 (fr)
TW (1) TWI343822B (fr)

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7700076B2 (en) 2002-10-25 2010-04-20 Foamix, Ltd. Penetrating pharmaceutical foam
US7704518B2 (en) 2003-08-04 2010-04-27 Foamix, Ltd. Foamable vehicle and pharmaceutical compositions thereof
US8114385B2 (en) 2003-08-04 2012-02-14 Foamix Ltd. Oleaginous pharmaceutical and cosmetic foam
US8119109B2 (en) 2002-10-25 2012-02-21 Foamix Ltd. Foamable compositions, kits and methods for hyperhidrosis
US8119150B2 (en) 2002-10-25 2012-02-21 Foamix Ltd. Non-flammable insecticide composition and uses thereof
US8119106B2 (en) 2003-04-28 2012-02-21 Foamix Ltd Foamable iodine compositions
US8343945B2 (en) 2007-12-07 2013-01-01 Foamix Ltd. Carriers, formulations, methods for formulating unstable active agents for external application and uses thereof
US8486376B2 (en) 2002-10-25 2013-07-16 Foamix Ltd. Moisturizing foam containing lanolin
US8486374B2 (en) 2003-08-04 2013-07-16 Foamix Ltd. Hydrophilic, non-aqueous pharmaceutical carriers and compositions and uses
US8512718B2 (en) 2000-07-03 2013-08-20 Foamix Ltd. Pharmaceutical composition for topical application
US8518376B2 (en) 2007-12-07 2013-08-27 Foamix Ltd. Oil-based foamable carriers and formulations
US8618081B2 (en) 2009-10-02 2013-12-31 Foamix Ltd. Compositions, gels and foams with rheology modulators and uses thereof
US8636982B2 (en) 2007-08-07 2014-01-28 Foamix Ltd. Wax foamable vehicle and pharmaceutical compositions thereof
US8709385B2 (en) 2008-01-14 2014-04-29 Foamix Ltd. Poloxamer foamable pharmaceutical compositions with active agents and/or therapeutic cells and uses
US8722021B2 (en) 2002-10-25 2014-05-13 Foamix Ltd. Foamable carriers
US8795693B2 (en) 2003-08-04 2014-08-05 Foamix Ltd. Compositions with modulating agents
US8795635B2 (en) 2006-11-14 2014-08-05 Foamix Ltd. Substantially non-aqueous foamable petrolatum based pharmaceutical and cosmetic compositions and their uses
US8900554B2 (en) 2002-10-25 2014-12-02 Foamix Pharmaceuticals Ltd. Foamable composition and uses thereof
US9072667B2 (en) 2009-07-29 2015-07-07 Foamix Pharmaceuticals Ltd. Non surface active agent non polymeric agent hydro-alcoholic foamable compositions, breakable foams and their uses
US9167813B2 (en) 2009-07-29 2015-10-27 Foamix Pharmaceuticals Ltd. Non surfactant hydro-alcoholic foamable compositions, breakable foams and their uses
US9211259B2 (en) 2002-11-29 2015-12-15 Foamix Pharmaceuticals Ltd. Antibiotic kit and composition and uses thereof
US9265725B2 (en) 2002-10-25 2016-02-23 Foamix Pharmaceuticals Ltd. Dicarboxylic acid foamable vehicle and pharmaceutical compositions thereof
US9320705B2 (en) 2002-10-25 2016-04-26 Foamix Pharmaceuticals Ltd. Sensation modifying topical composition foam
US9439857B2 (en) 2007-11-30 2016-09-13 Foamix Pharmaceuticals Ltd. Foam containing benzoyl peroxide
US9539208B2 (en) 2002-10-25 2017-01-10 Foamix Pharmaceuticals Ltd. Foam prepared from nanoemulsions and uses
US9884017B2 (en) 2009-04-28 2018-02-06 Foamix Pharmaceuticals Ltd. Foamable vehicles and pharmaceutical compositions comprising aprotic polar solvents and uses thereof
US10117812B2 (en) 2002-10-25 2018-11-06 Foamix Pharmaceuticals Ltd. Foamable composition combining a polar solvent and a hydrophobic carrier
US10517882B2 (en) 2009-10-02 2019-12-31 Foamix Pharmaceuticals Ltd. Method for healing of an infected acne lesion without scarring
US10849847B2 (en) 2016-09-08 2020-12-01 Foamix Pharamaceuticals Ltd. Compositions and methods for treating rosacea and acne

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9668972B2 (en) 2002-10-25 2017-06-06 Foamix Pharmaceuticals Ltd. Nonsteroidal immunomodulating kit and composition and uses thereof
JP4866173B2 (ja) * 2006-01-25 2012-02-01 大日精化工業株式会社 ヒドロキシアルキル化キトサン溶液
TWI474836B (zh) * 2007-04-17 2015-03-01 Kao Corp 毛髮化妝料
JP5379970B2 (ja) * 2007-12-06 2013-12-25 花王株式会社 毛髪形状制御剤第１剤
JP5112836B2 (ja) * 2007-12-06 2013-01-09 花王株式会社 毛髪形状制御剤第１剤
WO2016179017A1 (fr) 2015-05-01 2016-11-10 L'oreal Utilisation d'agents actifs pendant des traitements chimiques
KR20210084681A (ko) 2015-11-24 2021-07-07 로레알 모발 처리를 위한 조성물
US10441518B2 (en) 2015-11-24 2019-10-15 L'oreal Compositions for treating the hair
JP6930994B2 (ja) 2015-11-24 2021-09-01 ロレアル 毛髪をトリートメントするための組成物
US11135150B2 (en) 2016-11-21 2021-10-05 L'oreal Compositions and methods for improving the quality of chemically treated hair
US11433011B2 (en) 2017-05-24 2022-09-06 L'oreal Methods for treating chemically relaxed hair
WO2019133785A1 (fr) 2017-12-29 2019-07-04 L'oreal Compositions modifiant la couleur des cheveux
US11090249B2 (en) 2018-10-31 2021-08-17 L'oreal Hair treatment compositions, methods, and kits for treating hair
US11419809B2 (en) 2019-06-27 2022-08-23 L'oreal Hair treatment compositions and methods for treating hair

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0621052B2 (ja) 1986-12-16 1994-03-23 花王株式会社 パ−マネントウエ−ブ用液
JPH05178726A (ja) 1991-12-27 1993-07-20 Kao Corp 整髪剤組成物
JP3148365B2 (ja) 1992-06-29 2001-03-19 花王株式会社 ケラチン質繊維改質剤キット
JP2906201B2 (ja) * 1992-12-09 1999-06-14 花王株式会社 毛髪化粧料
JP3522786B2 (ja) 1993-04-20 2004-04-26 花王株式会社 毛髪処理剤組成物
JP3492738B2 (ja) 1993-10-13 2004-02-03 サンスター株式会社 毛髪化粧料
EP0770705A1 (fr) 1995-04-10 1997-05-02 Kao Corporation Procede de metallisation au bain chaud, et procede et equipement de production de matrices
JPH09301831A (ja) * 1996-05-08 1997-11-25 Hoyu Co Ltd 毛髪化粧料および毛髪処理方法
JP3276871B2 (ja) 1997-02-12 2002-04-22 花王株式会社 ヘアーコンディショニング剤組成物
JPH1160447A (ja) 1997-08-11 1999-03-02 Kao Corp 毛髪化粧料
JP2000109411A (ja) 1998-08-07 2000-04-18 Kao Corp 毛髪化粧料
EP0978272A1 (fr) 1998-08-07 2000-02-09 Kao Corporation Préparation pour les soins de la medulla
JP3638490B2 (ja) 2000-01-07 2005-04-13 花王株式会社 染色毛髪用処理組成物
TWI278328B (en) 2000-07-21 2007-04-11 Kao Corp Hair cosmetic composition
US6878368B2 (en) * 2001-03-29 2005-04-12 San-Ei Kagaku Co., Ltd. Composition for blending to hair treating agents and a hair treating agent
JP4619581B2 (ja) 2001-08-10 2011-01-26 花王株式会社 毛髪化粧料
DE60332386D1 (de) * 2002-11-26 2010-06-10 Kao Corp Kosmetisches haarpräparat

Cited By (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8512718B2 (en) 2000-07-03 2013-08-20 Foamix Ltd. Pharmaceutical composition for topical application
US10117812B2 (en) 2002-10-25 2018-11-06 Foamix Pharmaceuticals Ltd. Foamable composition combining a polar solvent and a hydrophobic carrier
US9492412B2 (en) 2002-10-25 2016-11-15 Foamix Pharmaceuticals Ltd. Penetrating pharmaceutical foam
US8119109B2 (en) 2002-10-25 2012-02-21 Foamix Ltd. Foamable compositions, kits and methods for hyperhidrosis
US7700076B2 (en) 2002-10-25 2010-04-20 Foamix, Ltd. Penetrating pharmaceutical foam
US9265725B2 (en) 2002-10-25 2016-02-23 Foamix Pharmaceuticals Ltd. Dicarboxylic acid foamable vehicle and pharmaceutical compositions thereof
US9320705B2 (en) 2002-10-25 2016-04-26 Foamix Pharmaceuticals Ltd. Sensation modifying topical composition foam
US8900554B2 (en) 2002-10-25 2014-12-02 Foamix Pharmaceuticals Ltd. Foamable composition and uses thereof
US10322085B2 (en) 2002-10-25 2019-06-18 Foamix Pharmaceuticals Ltd. Dicarboxylic acid foamable vehicle and pharmaceutical compositions thereof
US8486376B2 (en) 2002-10-25 2013-07-16 Foamix Ltd. Moisturizing foam containing lanolin
US9539208B2 (en) 2002-10-25 2017-01-10 Foamix Pharmaceuticals Ltd. Foam prepared from nanoemulsions and uses
US8840869B2 (en) 2002-10-25 2014-09-23 Foamix Ltd. Body cavity foams
US8741265B2 (en) 2002-10-25 2014-06-03 Foamix Ltd. Penetrating pharmaceutical foam
US11033491B2 (en) 2002-10-25 2021-06-15 Vyne Therapeutics Inc. Dicarboxylic acid foamable vehicle and pharmaceutical compositions thereof
US8722021B2 (en) 2002-10-25 2014-05-13 Foamix Ltd. Foamable carriers
US10821077B2 (en) 2002-10-25 2020-11-03 Foamix Pharmaceuticals Ltd. Dicarboxylic acid foamable vehicle and pharmaceutical compositions thereof
US8435498B2 (en) 2002-10-25 2013-05-07 Foamix Ltd. Penetrating pharmaceutical foam
US8119150B2 (en) 2002-10-25 2012-02-21 Foamix Ltd. Non-flammable insecticide composition and uses thereof
US9211259B2 (en) 2002-11-29 2015-12-15 Foamix Pharmaceuticals Ltd. Antibiotic kit and composition and uses thereof
US8486375B2 (en) 2003-04-28 2013-07-16 Foamix Ltd. Foamable compositions
US8119106B2 (en) 2003-04-28 2012-02-21 Foamix Ltd Foamable iodine compositions
US9050253B2 (en) 2003-08-04 2015-06-09 Foamix Pharmaceuticals Ltd. Oleaginous pharmaceutical and cosmetic foam
US8486374B2 (en) 2003-08-04 2013-07-16 Foamix Ltd. Hydrophilic, non-aqueous pharmaceutical carriers and compositions and uses
US8362091B2 (en) 2003-08-04 2013-01-29 Foamix Ltd. Foamable vehicle and pharmaceutical compositions thereof
US8518378B2 (en) 2003-08-04 2013-08-27 Foamix Ltd. Oleaginous pharmaceutical and cosmetic foam
US8795693B2 (en) 2003-08-04 2014-08-05 Foamix Ltd. Compositions with modulating agents
US8114385B2 (en) 2003-08-04 2012-02-14 Foamix Ltd. Oleaginous pharmaceutical and cosmetic foam
US7704518B2 (en) 2003-08-04 2010-04-27 Foamix, Ltd. Foamable vehicle and pharmaceutical compositions thereof
US9101662B2 (en) 2003-08-04 2015-08-11 Foamix Pharmaceuticals Ltd. Compositions with modulating agents
US8703105B2 (en) 2003-08-04 2014-04-22 Foamix Ltd. Oleaginous pharmaceutical and cosmetic foam
US8795635B2 (en) 2006-11-14 2014-08-05 Foamix Ltd. Substantially non-aqueous foamable petrolatum based pharmaceutical and cosmetic compositions and their uses
US11103454B2 (en) 2007-08-07 2021-08-31 Vyne Therapeutics Inc. Wax foamable vehicle and pharmaceutical compositions thereof
US8636982B2 (en) 2007-08-07 2014-01-28 Foamix Ltd. Wax foamable vehicle and pharmaceutical compositions thereof
US9439857B2 (en) 2007-11-30 2016-09-13 Foamix Pharmaceuticals Ltd. Foam containing benzoyl peroxide
US9161916B2 (en) 2007-12-07 2015-10-20 Foamix Pharmaceuticals Ltd. Carriers, formulations, methods for formulating unstable active agents for external application and uses thereof
US8518376B2 (en) 2007-12-07 2013-08-27 Foamix Ltd. Oil-based foamable carriers and formulations
US9549898B2 (en) 2007-12-07 2017-01-24 Foamix Pharmaceuticals Ltd. Oil and liquid silicone foamable carriers and formulations
US11433025B2 (en) 2007-12-07 2022-09-06 Vyne Therapeutics Inc. Oil foamable carriers and formulations
US8343945B2 (en) 2007-12-07 2013-01-01 Foamix Ltd. Carriers, formulations, methods for formulating unstable active agents for external application and uses thereof
US8900553B2 (en) 2007-12-07 2014-12-02 Foamix Pharmaceuticals Ltd. Oil and liquid silicone foamable carriers and formulations
US8709385B2 (en) 2008-01-14 2014-04-29 Foamix Ltd. Poloxamer foamable pharmaceutical compositions with active agents and/or therapeutic cells and uses
US9884017B2 (en) 2009-04-28 2018-02-06 Foamix Pharmaceuticals Ltd. Foamable vehicles and pharmaceutical compositions comprising aprotic polar solvents and uses thereof
US10213384B2 (en) 2009-04-28 2019-02-26 Foamix Pharmaceuticals Ltd. Foamable vehicles and pharmaceutical compositions comprising aprotic polar solvents and uses thereof
US10588858B2 (en) 2009-04-28 2020-03-17 Foamix Pharmaceuticals Ltd. Foamable vehicles and pharmaceutical compositions comprising aprotic polar solvents and uses thereof
US11219631B2 (en) 2009-07-29 2022-01-11 Vyne Pharmaceuticals Inc. Foamable compositions, breakable foams and their uses
US9072667B2 (en) 2009-07-29 2015-07-07 Foamix Pharmaceuticals Ltd. Non surface active agent non polymeric agent hydro-alcoholic foamable compositions, breakable foams and their uses
US9572775B2 (en) 2009-07-29 2017-02-21 Foamix Pharmaceuticals Ltd. Non surfactant hydro-alcoholic foamable compositions, breakable foams and their uses
US10092588B2 (en) 2009-07-29 2018-10-09 Foamix Pharmaceuticals Ltd. Foamable compositions, breakable foams and their uses
US9167813B2 (en) 2009-07-29 2015-10-27 Foamix Pharmaceuticals Ltd. Non surfactant hydro-alcoholic foamable compositions, breakable foams and their uses
US10238746B2 (en) 2009-10-02 2019-03-26 Foamix Pharmaceuticals Ltd Surfactant-free water-free foamable compositions, breakable foams and gels and their uses
US10821187B2 (en) 2009-10-02 2020-11-03 Foamix Pharmaceuticals Ltd. Compositions, gels and foams with rheology modulators and uses thereof
US10137200B2 (en) 2009-10-02 2018-11-27 Foamix Pharmaceuticals Ltd. Surfactant-free water-free foamable compositions, breakable foams and gels and their uses
US10265404B2 (en) 2009-10-02 2019-04-23 Foamix Pharmaceuticals Ltd. Compositions, gels and foams with rheology modulators and uses thereof
US8865139B1 (en) 2009-10-02 2014-10-21 Foamix Pharmaceuticals Ltd. Topical tetracycline compositions
US10322186B2 (en) 2009-10-02 2019-06-18 Foamix Pharmaceuticals Ltd. Topical tetracycline compositions
US10517882B2 (en) 2009-10-02 2019-12-31 Foamix Pharmaceuticals Ltd. Method for healing of an infected acne lesion without scarring
US10086080B2 (en) 2009-10-02 2018-10-02 Foamix Pharmaceuticals Ltd. Topical tetracycline compositions
US10610599B2 (en) 2009-10-02 2020-04-07 Foamix Pharmaceuticals Ltd. Topical tetracycline compositions
US10213512B2 (en) 2009-10-02 2019-02-26 Foamix Pharmaceuticals Ltd. Topical tetracycline compositions
US8618081B2 (en) 2009-10-02 2013-12-31 Foamix Ltd. Compositions, gels and foams with rheology modulators and uses thereof
US10835613B2 (en) 2009-10-02 2020-11-17 Foamix Pharmaceuticals Ltd. Compositions, gels and foams with rheology modulators and uses thereof
US8992896B2 (en) 2009-10-02 2015-03-31 Foamix Pharmaceuticals Ltd. Topical tetracycline compositions
US10946101B2 (en) 2009-10-02 2021-03-16 Vyne Therapeutics Inc. Surfactant-free water-free foamable compositions, breakable foams and gels and their uses
US10967063B2 (en) 2009-10-02 2021-04-06 Vyne Therapeutics Inc. Surfactant-free, water-free formable composition and breakable foams and their uses
US10029013B2 (en) 2009-10-02 2018-07-24 Foamix Pharmaceuticals Ltd. Surfactant-free, water-free formable composition and breakable foams and their uses
US8871184B2 (en) 2009-10-02 2014-10-28 Foamix Ltd. Topical tetracycline compositions
US8945516B2 (en) 2009-10-02 2015-02-03 Foamix Pharmaceuticals Ltd. Surfactant-free water-free foamable compositions, breakable foams and gels and their uses
US11324691B2 (en) 2016-09-08 2022-05-10 Journey Medical Corporation Compositions and methods for treating rosacea and acne
US10849847B2 (en) 2016-09-08 2020-12-01 Foamix Pharamaceuticals Ltd. Compositions and methods for treating rosacea and acne

Also Published As

Publication number Publication date
JP2005239665A (ja) 2005-09-08
KR20060042221A (ko) 2006-05-12
CN1679474A (zh) 2005-10-12
EP1584324A1 (fr) 2005-10-12
DE602005003389T2 (de) 2008-10-02
TWI343822B (en) 2011-06-21
DE602005003389D1 (de) 2008-01-03
TW200531704A (en) 2005-10-01
JP4381169B2 (ja) 2009-12-09
CN1679474B (zh) 2012-02-01
US7981407B2 (en) 2011-07-19
KR101196280B1 (ko) 2012-11-06
US20050201966A1 (en) 2005-09-15

Similar Documents

Publication Publication Date Title
EP1584324B1 (fr) Composition de soin capillaire comprenant un acide dicarboxylique et de l'acide édétique
EP1568350B1 (fr) Composition capillaire
EP1579844B1 (fr) Composition cosmetique pour les cheveux
EP1579842B1 (fr) Composition cosmétique capillaire
US8007773B2 (en) Hair cosmetic composition
JP4926371B2 (ja) 毛髪化粧料
JP4452523B2 (ja) 毛髪化粧料
US20050214238A1 (en) Hair cosmetic composition
JP5026802B2 (ja) 毛髪化粧料
JP2005239568A (ja) 毛髪化粧料
JP2005272399A (ja) 毛髪化粧料
JP4381164B2 (ja) 毛髪化粧料
JP4381165B2 (ja) 毛髪化粧料
JP4164466B2 (ja) 毛髪化粧料
JP2005272394A (ja) 毛髪化粧料
JP2005272393A (ja) 毛髪化粧料
JP2005272379A (ja) 毛髪化粧料
JP4284219B2 (ja) 毛髪化粧料
JP2007055918A (ja) 毛髪化粧料
JP2005272391A (ja) 毛髪化粧料
JP2005272395A (ja) 毛髪化粧料

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR LV MK YU

17P Request for examination filed

Effective date: 20060315

RIC1 Information provided on ipc code assigned before grant

Ipc: A61Q 5/06 20060101ALI20060503BHEP

Ipc: A61K 8/44 20060101ALI20060503BHEP

Ipc: A61K 8/362 20060101AFI20060503BHEP

Ipc: A61Q 5/12 20060101ALI20060503BHEP

Ipc: A61K 8/365 20060101ALI20060503BHEP

AKX Designation fees paid

Designated state(s): DE FR GB

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE FR GB

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 602005003389

Country of ref document: DE

Date of ref document: 20080103

Kind code of ref document: P

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20080822

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 13

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20230110

Year of fee payment: 19

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20230105

Year of fee payment: 19

Ref country code: DE

Payment date: 20221230

Year of fee payment: 19

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230522