WO2006134015A1 - Neuartige arbeitsmedien für kälteprozesse - Google Patents
Neuartige arbeitsmedien für kälteprozesse Download PDFInfo
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- WO2006134015A1 WO2006134015A1 PCT/EP2006/062567 EP2006062567W WO2006134015A1 WO 2006134015 A1 WO2006134015 A1 WO 2006134015A1 EP 2006062567 W EP2006062567 W EP 2006062567W WO 2006134015 A1 WO2006134015 A1 WO 2006134015A1
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- methylimidazolium
- ethyl
- working medium
- refrigerant
- methyl
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/047—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for absorption-type refrigeration systems
Definitions
- the invention relates to novel working media for refrigeration processes and in particular describes the use of ideally under normal conditions or at temperatures ⁇ 60 0 C liquid organic salts as an additive or sorbent for refrigeration processes.
- the use of the substances used or co-used according to the invention as an additive or sorbent leads to improvements in the properties of the working medium.
- the invention includes novel process variants for refrigeration processes with advantages over the prior art.
- a chiller or heat pump based on the circulation of a working medium (also referred to as refrigerant), wherein at different pressure levels heat is added or removed.
- refrigerant working medium
- the basic principle is described by a so-called reverse Clausius-Rankine process and thus represents a direct reversal of a heat engine.
- at the refrigerant passes through the steps of (a) compression, (b) condensation, (c) relaxation and (d) evaporation.
- Heat is raised from a low to a higher temperature level.
- the aim here is to lift a large amount of heat to a higher temperature level and dissipate there with a given amount of mechanical, electrical or thermal energy. In this case, it is possible to realize the change of the temperature or the pressure level by one or more stages.
- chillers The difference between chillers and heat pumps results from the temperature level used.
- heat pumps the heat (usually on the condenser) at a high temperature level, e.g. used for heating purposes, while in a chiller (usually on the evaporator) to be supplied heat is used for cooling purposes.
- Heat pumps can also be designed in the form of high-temperature condensing technology, wherein the heat of condensation of the water vapor contained in flue gases is used above the Rauchgastauwels.
- part of the water vapor in the exhaust gas is absorbed in an absorber by a hygroscopic washing solution (eg LiBr solution) and then expelled again in a desorber at a higher temperature.
- a hygroscopic washing solution eg LiBr solution
- Both from cooling and condensation of the expelled water vapor, as well as from the cooling of the wash solution before returning to the absorber heat can now be used at a high temperature level.
- Compression steam refrigerators or compression refrigerators typically perform the above-described cycle using mechanical compressors. These compress the refrigerant, which is at least partially vaporous or supercritical.
- Steam blast chillers have steam jet compressors instead of mechanical compressors and use water as a refrigerant. They evaporate a part of the water at low working pressure and extract the heat of vaporization from the residual water, which can be used as a refrigerant. Steam jet refrigeration systems can also be designed as open processes.
- absorption chillers characteristically, in the above-described cycle, at least one stage of mechanical compression of the vaporous refrigerant is replaced by a so-called thermal compression (alternative compression). This consists of the absorption of the vaporous refrigerant in an absorbent, the compression of the resulting liquid mixture and a subsequent supply of heat to expel the refrigerant at a high pressure level.
- the sorbent must be liquid in continuous sorption refrigerators, the concentration of refrigerant in the sorbent being dependent on absorbance, pressure and temperature. Within the pressure and temperature range that the refrigerant and sorbent in sorption chillers undergo, both substances must be miscible, and they must not form an azeotrope.
- the working medium may also be mixed with one or more additives with the aim of improving the absorption capacity, the heat capacity or the heat transfer and to reduce the solidification temperature of the working medium and decomposition phenomena.
- an advantageous working medium should be chemically and thermally stable, non-toxic, non-flammable, non-environmentally hazardous, and non-corrosive.
- Nezu Working Group [Nezu, Y .; Hisada, N .; Ishiyama, T .; Watanabe, K. Thermodynamic properties of working-fluid pairs with R-134a for absorption refrigeration system. Natural Working Fluids 2002, HR Gustav Lorentzen Conference, 5th, Guangzhou, China, Sept. 17-20, 2002 (2002), 446-453. CODEN: 69EZUG CAN 140: 113462 AN 2004: 79935 CAPLUS] has for the use of (e) halogenated hydrocarbons, such as Rl34a (CF 3 -CH 2 -F) as refrigerant N, N-dimethylformamide or N, N-dimethylacetamide Sorption agent proposed.
- Rl34a CF 3 -CH 2 -F
- the working medium is understood in the context of this invention, occurring at least at one point of the refrigeration process maximum number of system components.
- the working medium is thus a mixture consisting of sorbent and refrigerant and, if appropriate, additives.
- the working medium that mixture which is compressed in the compressor.
- additives may be added as described in Kim, J. -S. et al., Applied Thermal Engineering 19 (1999) 217-225 or Glebov, D. and Setterwall, F., International Journal of Refrigeration 25 (2002) 538-545 or Ziegler, F. and Grossman, G., International Journal of Refrigeration 19 (1996) 301-309 described by way of example.
- the known working media show a limited absorption behavior or contain substances that have too high a crystallization temperature, a high risk (due to toxicity or flammability), polluting properties (for example by damage to the ozone layer, or by a large greenhouse potential), are corrosive or have a very high vapor pressure.
- the working media in absorption chillers can only be incompletely separated into the refrigerant and sorbent after compression because conventional high-melting sorbents (such as lithium bromide) crystallize out in a concentrated state.
- Low-melting sorbents such as N, N-dimethylformamide
- Low-melting sorbents usually have a significant volatility, which at high concentration of the sorbent leads to contamination of the refrigerant, thereby necessitating the installation of further separation equipment behind the expeller.
- the return of insufficiently concentrated sorption of the expeller back to the absorber is disadvantageous, since the sorbents there accordingly can absorb only correspondingly small amounts of refrigerant and thus undesirable large and energetically adverse recirculation flows.
- the object of the present invention was to find a working medium which is suitable for use in refrigeration processes and / or refrigerating machines, in particular in absorption heat pumps, absorption refrigerating machines, steam jet refrigerating machines,
- Compression refrigeration and / or heat transformers is suitable and does not have at least one of the disadvantages mentioned, preferably as many of the disadvantages mentioned.
- a working medium for refrigeration processes and / or refrigeration machines in particular absorption heat pumps, absorption chillers, steam jet refrigeration machines, compression refrigeration, heat pumps and / or heat transformers at least one refrigerant and at least one sorbent, wherein the sorbent at least one non-volatile under normal conditions liquid organic salt or a mixture organic nic salts, with the proviso that it is liquid under normal conditions, and wherein the salt or mixture has a greater thermal stability has 15O 0 C, it is not possible to readily foreseeable way,
- Steam jet chillers, compression chillers and / or heat transformers comprises:> providing a non-toxic, non-explosive working medium, to make available a working medium with a comparatively high chemical resistance,
- the partial pressure of refrigerants, in particular of water can be significantly reduced, wherein the use of diethyl-polypropoxy-methylammonium chloride, bis (2-hydroxyethyl) dimethylammonium methylsulfonate and / or l-ethyl-3 Methylimidazoliummethansulfonat has proven particularly useful because it allows a reduction by a factor of ⁇ 4.7.
- the working medium according to the invention contains at least one refrigerant.
- refrigerants for the purposes of the present invention are those which absorb heat in a refrigeration system by low temperature, low pressure evaporation and release heat by liquefaction at higher temperature and pressure. They are specified in greater detail in DIN 8962 of August 1968 ("Refrigerants").
- the refrigerant desirably has an enthalpy of vaporization ⁇ 300 kJ / kg, more preferably ⁇ 350 kJ / kg.
- the refrigerants can each be used individually or else as a mixture of two or more of the abovementioned components.
- the working medium according to the invention also contains at least one sorbent.
- Sorption substances are those which are described in more detail below, preferably under normal conditions, liquid organic salts or salt mixtures.
- liquid organic salts is understood as meaning salts, preferably organic salts having a melting point of less than 100 ° C., more preferably organic salts which are already in use, preferably under normal conditions (20 ° C., 1013 mbar), in the liquid state
- the definition is also intended to include mixtures of solid salts and liquid organic salts which are liquid under conditions of use, preferably under normal conditions.
- liquid organic salts are characterized by favorable properties, in particular with regard to their potential use as solvents, and are regarded as a new class of solvents and selective auxiliaries. Liquid organic salts have a very low content under moderate conditions
- Vapor pressure at the same time relatively low solution viscosities, so they at
- liquid organic salts represent by their combinatorial diversity, which is due to the variation of the Anions and cations results in a particularly flexible sorbent concept, which can be adapted exactly to the technical tasks to be solved by selecting suitable combinations and concentrations.
- liquid organic salts consist in most cases of anions such as, for example, hydroxide, halides, carboxylates, phosphates, thiocyanate, isothiocyanate, dicyanamide, sulfate, alkyl sulfates, sulfonates, alkyl sulfonates, tetrafluoroborate, hexafluorophosphate or else bis (trifluoromethylsulfonyl) imide with, for example, substituted ammonium, phosphonium, pyridinium or imidazolium cations, the abovementioned anions and cations representing a small selection from the large number of possible anions and cations and thus not claiming to be exhaustive or even restrictive.
- anions such as, for example, hydroxide, halides, carboxylates, phosphates, thiocyanate, isothiocyanate, dicyanamide, sulfate, alkyl sulfates, s
- organic salts preferably used as sorbent which are ideally liquid under normal conditions, consist of at least one cation of the general formulas:
- R 1 , R 2 , R 3 , R 4 are identical or different and hydrogen, a linear or branched optionally double bonds containing aliphatic hydrocarbon radical having 1 to 30 carbon atoms, an optionally double bonds containing cycloaliphatic hydrocarbon radical having 5 to 40 carbon atoms, an aromatic hydrocarbon radical having 6 to 40 carbon atoms, an alkylaryl group having 7 to 40 carbon atoms, one by one or more heteroatoms
- Double bonds containing Ci- to C 3 o-alkyl radical in particular
- Hydrocarbon radical having 2 to 30 carbon atoms, one by one or more functionalities selected from the
- R 5 is a linear or branched hydrocarbon radical containing 2 to 4 carbon atoms, n is 1 to 100, preferably 2 to 60, and R 6 is hydrogen, a linear or branched, optionally double bond-containing aliphatic hydrocarbon radical
- Hydrocarbon radical having 1 to 30 carbon atoms, an optionally double bonds containing cycloaliphatic hydrocarbon radical having 5 to 40 carbon atoms, an aromatic hydrocarbon radical having 6 to 40 carbon atoms, an alkyl aryl radical having 7 to 40 carbon atoms or a radical -C (O) -R 7 with R 7 is a linear or branched optionally double bond-containing aliphatic hydrocarbon radical having 1 to 30 carbon atoms, an optionally double bonds containing cycloaliphatic hydrocarbon radical having 5 to 40 carbon atoms, an aromatic hydrocarbon radical having 6 to 40 carbon atoms, an alkylaryl radical having 7 to 40 carbon atoms.
- ions which are derived from saturated or unsaturated cyclic compounds and from aromatic compounds each having at least one trivalent nitrogen atom in a 4- to 10-, preferably 5- to 6-membered heterocyclic ring which may optionally be substituted .
- Such cations can be simplified (i.e., without specifying exact location and number of double bonds in the molecule) by the general formulas (5), (6) and (7) below, wherein the heterocyclic rings may optionally also contain a plurality of heteroatoms.
- R 1 and R 2 have the abovementioned meaning
- R is a hydrogen, a linear or branched optionally double bonds containing aliphatic hydrocarbon radical having 1 to 30 carbon atoms, a cycloaliphatic optionally double bonds included a hydrocarbon radical having 5 to 40 carbon atoms, an aromatic hydrocarbon radical having 6 to 40 carbon atoms or an alkylaryl radical having 7 to 40 carbon atoms and
- cyclic nitrogen compounds of the abovementioned type are pyrrolidine, dihydropyrrole, pyrrole, imidazoline, oxazalonine, oxazole, thiazoline, thiazole, isoxazole, isothiazole, indole, carbazole, piperidine, pyridine, the isomeric picolines and lutidines, quinoline and isobutylene. quinoline.
- Examples of such compounds are pyrazole, 3, 5-dimethylpyrazole, imidazole, benzimidazole, N-methylimidazole, dihydropyrazole, pyrazolidine, pyridazine, pyrimidine, pyrazine, pyridazine, 2,3-, 2,5- and 2,6 Dimethylpyrazine, cinnoline, phthalazine, quinazoline, phenazine and piperazine.
- imidazole and its alkyl and phenyl derivatives are leaded cations of the general formula (8) have proven to be part of ionic liquid.
- ions which contain two nitrogen atoms are represented by the general formula (8)
- R 8 , R 9 , R 10 , R 11 , R 12 are identical or different and hydrogen, a linear or branched optionally double bonds containing aliphatic hydrocarbon radical having 1 to 30 carbon atoms, a cycloaliphatic optionally double bonds containing hydrocarbon radical having 5 to 40 carbon atoms, an aro- matic hydrocarbon radical having 6 to 40 carbon atoms, an alkylaryl radical having 7 to 40 carbon atoms, is interrupted by one or more heteroatoms (oxygen, NH, NR ⁇ R ⁇ equal to one, where appropriate, containing double bonds, Ci to C 3 o-alkyl) interrupted linear or branched optionally double bonds containing aliphatic hydrocarbon radical having 1 to 30 carbon atoms, one by one or more functionalities selected from the group -0-C (O) -, - (O) CO-, -NH -C (O) -, - (O) C-NH, - (CH 3 ) NC (O) -,
- R 6 is hydrogen, a linear or branched, optionally double bond-containing aliphatic hydrocarbon radical having 1 to 30 carbon atoms, a cycloaliphatic optionally double bond-containing hydrocarbon radical having 5 to 40 carbon atoms, an aromatic hydrocarbon radical having 6 to 40 carbon atoms, an alkylaryl radical having 7 to 40 carbon atoms or a radical -C (O) -R 7 with
- R 7 is a linear or branched optionally double bonds containing aliphatic hydrocarbon radical having 1 to 30 carbon atoms, an optionally
- liquid organic salts preferably used according to the invention consist of at least one of the abovementioned cations combined with at least one of the following anions.
- Preferred anions are selected from the group of hydroxyl ions or a hydroxide anion, halides, bis (perfluoroalkylsulfonyl) amides, alkyl and aryl tosylates, fluoroalkyl tosylates, haloantimonate, nitrates, sulfates, hydrogensulfates, alkyl and aryl sulfates, polyether sulfates and sulfonates , Fluoroalkyl sulfates, sulfonates, alkyl and aryl sulfonates, fluorinated alkyl and aryl sulfonates, alkyl and aryl carboxylates, fluoroalkyl carboxylates, chlorates, borates, cyanates, chloroaluminates, halocuprates, halogen zincates, halo aluminates, saccharinates, anion of dicyanamide, preferably An
- the organic salts used as sorbent preferably has a viscosity according to DIN 53 019 at 20 0 C in a range of 1 to 15,000 mPa.s, preferably from 2 to 10,000 mPa.s, more preferably in a range of 5 to 5,000 mPa.s and more preferably in a range of 10 to 3,000 mPa.s.
- the organic salts are liquid at a temperature of 50 0 C and a viscosity of less than 3,000 mPa.s, more preferably of less than 2000 mPa.s and more preferably less than 1,000 mPa.s exhibit.
- liquid organic salts described above may be used alone or as a mixture of at least two different organic salts. Further inventively preferred liquid organic salts and processes for their preparation are described in Angewandte Chemie, 2000, 112, pp 3926-3945. The disclosure of this article is hereby incorporated by reference and is considered part of the disclosure of the present invention.
- Particularly preferred sorbents for the purposes of the present invention include: distearyl dimethyl ammonium chloride,
- the Z. B. is available under the name Tego® IL M90 from Degussa AG, l-ethyl-3-methylimidazolium-ethyl sulfate,
- m and n each represent numbers in the range of 1 to 300, preferably in the range of 1 to 200, particularly preferably in the range of 1 to 100.
- Name ECOENG1111P can be obtained from Solvent Innovation GmbH, 1-ethyl-3-methylimidazolium ethylsulfate (CAS #: 342573-75-5), 1-ethyl-3-methylimidazolium methylsulfonate (CAS #: 342789-815), l -Ethyl-3-methylimidazolium hydroxide, whose synthesis is based on the in P. Wasserscheid, T. Welton Ionic Liquids in
- sorbents include: 1-butyl-3-methylimidazolium methanesulfonate (CAS #: 342789-81-5), which is e.g. B. under the name Basionic ST 78 can be obtained from BASF AG, methyl tri-n-butylammonium methyl sulfate (CAS #: 13106-24-6), the z. B. under the name Basionic ST 62 can be obtained from BASF AG,
- Basionic ST 33 1, 2, 4-Trimethylpyrazoliummethylsulfat, the z. B. under the name Basionic ST 33 can be obtained from BASF AG, 1-ethyl-2,3-dimethylimidazolium ethylsulfate (CAS #: 516474-08-01), which is e.g. B. under the name Basionic ® ST 67 can be obtained from BASF AG,
- 1,2,3-trimethyl-imidazoliuramethylsulfate (CAS #: 65086-12-6), e.g. B. under the name Basionic ® ST 99 can be obtained from BASF AG,
- Methylimidazolium chloride (CAS #: 35487-17-3), the z. B. under the name Basionic ® AC 75 can be obtained from BASF AG, Methylimidazoliumhydrogensulfat (CAS #: 681281-87-8), the z. B. under the name Basionic ® AC 39 can be obtained from BASF AG, l-ethyl-3-methylimidazoliumhydrogensulfat (CAS #: 412009-61-1), the z. B. under the name Basionic AC 25 can be obtained from BASF AG, l-butyl-3-methylimidazolium hydrogen sulfate (CAS #: 80432-05-9), the z. B.
- Basionic AC 28 can be obtained from BASF AG, l-butyl-3-methylimidazolium acetate (CAS #: 284049-75-8), the z. B. under the name Basionic ® BC 02 can be obtained from BASF AG, l-butyl-3-methylimidazolium methylsulfate (CAS #: 401788-98-5), the z. B. under the name Basionic LQ 02 can be obtained from BASF AG, l-ethyl-3-methylimidazolium thiocyanate (CAS #: 331717-63-6), the z. B.
- Basionic ® ST VS 01 can be obtained from BASF AG, l-butyl-3-methylimidazolium thiocyanate (CAS #: 344790-87-0), the z. B. under the name Basionic ® ST VS 02 can be obtained from BASF AG, Choline acetate (CAS #: 14586-35-7), e.g. B. under the
- Designation Basionic ® FS 85 can be obtained from BASF AG,
- Choline salicylate (CAS #: 2016-36-6), e.g. B. under the name Basionic ® FS 65 can be obtained from BASF AG,
- BASF AG can be obtained.
- Sorbents particularly favorable: 1-ethyl-3-methylimidazolium dicyanamide,
- Still another group of preferred ionic liquids comprises: 1-ethyl-3-methyl-imidazolium nitrate, 1-ethyl-3-methyl-imidazolium tosylate, 1-ethyl-3-methyl-imidazolium bromide, 1-allyl-3-methylimidazolium chloride, 1-methyl 3-propyl-imidazolium iodide, 1-butyl-1-methylpyrrolidinium dicyanamide and
- Tributylmethylphosphoniuramethylsulfat (CYPHOSO), the z. B. from the company Ionic Liquids Technologies are available.
- the inventively used ionic liquid or mixture of ionic liquids is characterized by a thermal stability greater than 15O 0 C out.
- the determination of the thermal stability can be carried out in a manner known per se. However, has proven particularly the
- thermostable ionic liquids preferably show a weight reduction of less than 50%, particularly preferably less than 30%, advantageously less than 20%, even more preferably less than 10% and in particular less than 5%, in each case based on the initial weight.
- the working medium according to the invention has a comparatively high storage stability. After storage at 7O 0 C for 8000 h, the degradation of the working medium is preferably at most 5%, preferably at most 4%, more preferably at most 3%, each based on the starting composition, ie preferably at least 95%, preferably at least 96%, particularly preferred at least 97% of the constituents are chemically identical.
- the chemical identity test can be carried out using standard procedures. Infrared spectroscopy, NMR and mass spectroscopy studies have proven particularly useful in this context.
- the storage of the working medium is preferably carried out under conditions customary for the application, particularly preferably under air and moisture-free conditions.
- the working medium according to the invention is relatively harmless from a health point of view. It preferably has an LD 50 value greater than 1000 mg / kg, more preferably greater than 1500 mg / kg, in particular greater than 2000 mg / kg, and / or an EC 50 value greater than 50 mg / 1, particularly preferably greater than 75 mg / 1 , in particular greater than 100 mg / 1. Conveniently, both criteria are met simultaneously.
- the working medium according to the invention is significantly less corrosive than the working media previously known from the prior art. It is expediently characterized in that it is in the glassware corrosion test according to ASTM D1384 shows a maximum removal of 5 g / m 2 , preferably of not more than 3 g / m 2 , particularly preferably of not more than 2 g / m 2 .
- metal-tipped plates preferably copper, soft solder, brass, steel, gray cast iron or cast aluminum
- Copper, soft solder and brass are each conductively connected by brass spacers, steel, gray cast iron and cast aluminum by means of steel spacers, but the resulting "packages" are isolated from one another
- the test specimen is placed in the medium and the approach to increase the corrosion rate 14 After being heated for days at 88 ° C., the coupons are cleaned, weighed again and the removal determined.
- the removal measurement is carried out using soft solder platelets.
- the removal measurement is carried out using cast aluminum platelets.
- the working medium according to the invention also has a significantly improved absorption capacity.
- 3O 0 C for a composition consisting of 90% by mass of organic salt or mixture of salts and 10% by mass of refrigerant to the vapor pressure of the refrigerant at 3O 0 C, preferably at least a factor 1.5, advantageously at least the Factor 3, preferably at least the factor 4, particularly preferably at least the factor 5, even more preferably at least the factor 6 and in particular at least the factor 7.
- the preparation of the working medium according to the invention can be carried out in a conventional manner by mixing the components.
- Particularly suitable application areas include ventilation or air conditioning technology, such as building technology, vehicle technology, ship technology, aerospace and container technology, cold stores or refrigerated trucks, such as reefers or refrigerated trucks, for the transport of food, gases, chemicals and / or animals and the process technology for air drying, preferably according to the condensation principle, for the absorption of gases, central or mobile systems for heat recovery, such as thermal power plants or solar-powered systems, refrigerators, freezers and air conditioners.
- ventilation or air conditioning technology such as building technology, vehicle technology, ship technology, aerospace and container technology, cold stores or refrigerated trucks, such as reefers or refrigerated trucks, for the transport of food, gases, chemicals and / or animals and the process technology for air drying, preferably according to the condensation principle, for the absorption of gases, central or mobile systems for heat recovery, such as thermal power plants or solar-powered systems, refrigerators, freezers and air conditioners.
- At least one component of the working medium passes through a cyclic process with the supply or removal of heat or mechanical energy.
- the ionic liquid conveniently acts as a sorbent for the absorption of at least one vapor or gaseous refrigerant.
- the separation of the refrigerant and the sorbent is preferably carried out in an expeller and subsequent condensation of the refrigerant in a cooler with return.
- the expeller and return cooler of an absorption refrigeration system can be replaced by at least one apparatus in which a liquid-liquid phase separation takes place and the two liquid phases are withdrawn separately.
- an absorbent-containing liquid phase having an absorbent concentration of at least 20% by weight and a refrigerant-containing liquid phase having a refrigerant concentration of at least 20% by weight are favorably formed (see Fig. 1).
- the present invention furthermore relates to refrigerating machines, in particular absorption heat pumps, absorption refrigerating machines, steam jet refrigerating machines, heat pumps, heat transformers or compression refrigerating machines which contain a condenser, an expansion element, a heat exchanger and / or an absorber and the working medium according to the invention.
- the chillers in particular absorption heat pumps, absorption chillers, steam jet chillers or compression chillers preferably comprise a mixer-settler for liquid-liquid separation of the working medium.
- Absorption isotherms result from the amount of a volatile component (here the refrigerant), which at a given temperature and at pressures which are generally smaller than the pure vapor pressure of the refrigerant, in a very high-boiling or non-volatile liquid (here Sorbent) in an equilibrium state.
- a volatile component here the refrigerant
- a very high-boiling or non-volatile liquid here Sorbent
- a sorbent should absorb the refrigerant after its expansion and evaporation at a low pressure.
- An advantageous sorption material absorbs as much refrigerant as possible at a given pressure, whereupon the volume and the masses of the circulation streams minimize (or lower pressure with the same composition). As a result, the system achieves greater efficiency and can be more advantageous in terms of its dimensions and the amount of absorber used.
- Sorbent 2 results from the slope of the fugacity for a near zero mole fraction of Component 1, i. simplified at the saturation vapor pressure of the sorbent 2
- Example System I 2,2,2-trifluoroethanol as a refrigerant
- liquid organic salts l-butyl-3-methyl-imidazolium tetrafluoroborate and l-butyl-3-methyl-imidazolium bromide are suitable as sorbents for 2, 2, 2-trifluoroethanol.
- Kim, K.S. et al. in "Ionic Liquids as New Working Fluids for Use in Absorption Heat Pumps or Chillers" (Fifteenth Symposium on Thermophysical Properties, Boulder, CO., USA, June 22-27, 2003) which is superior to the 1-butyl-3- Methyl imidazolium tetrafluoroborate superior absorbency of the l-butyl-3-methyl-imidazolium bromide set forth.
- Table I below shows the partial pressure of the refrigerant trifluoroethanol at the respective mass fraction of the ionic liquid. The measurements were carried out at 7O 0 C.
- the tested organic salts (s. Table I) that, compared to the prior art by the use of l-ethyl-3-methylimidazolium hydroxide, 1-ethyl-3-methylimidazolium methylsulfonate (EMIM Mesos) ⁇ bis (2- hydroxy-ethyl) -dimethylammonium chloride, 4-methyl-N-butylpyridinium chloride (MBP Cl), 1-ethyl-3-methylimidazolium acetate (EMIM OAc) and 1-ethyl-3-methylimidazolium chloride (EMIM Cl) have demonstrated significantly improved absorbency has been.
- EMIM Mesos 1-ethyl-3-methylimidazolium methylsulfonate
- MBP Cl 4-methyl-N-butylpyridinium chloride
- EMIM OAc 1-ethyl-3-methylimidazolium acetate
- EMIM Cl 1-ethyl-3-methylimidazol
- l-butyl-3-methyl-imidazolium bromide has a melting point of 82 0 C.
- the of Absorbency superior liquid organic salts such as l-ethyl-3-methylimidazolium methylsulfonat and l-ethyl-3-methylimidazolium acetate can also be the pure substance melting point of the sorbent by an amount of 47 K to over 100 K lowered.
- the sorption in the expeller can now be more concentrated without a crystallization of the sorbent must be feared. Residues of refrigerant to prevent crystallization are - depending on the temperature in the sorbent - not necessary or can be much lower than in the prior art. This minimizes useless cycle flows and increases efficiency.
- Table II below shows the partial pressure of the refrigerant Rl34a at the respective mass fraction of the sorbent. The measurements were carried out at 2O 0 C.
- the refrigerant Rl34a the N, N-dimethylformamide as a very beneficial sorbent.
- the selected organic salts l-ethyl-2,3-dimethylimidazolium acetate (EMMIM OAc) and l-ethyl-2,3-dimethylimidazolium chloride (EMMIM Cl) become considerably larger Absorptive capacity realized.
- the advantageous conventional sorbent N, N-dimethylformamide has a measurable volatility which may require the installation of additional separation equipment downstream of the expeller to separate sorbent residue from the refrigerant.
- a further advantage of the liquid organic salts according to the invention is that, when used as a sorbent, no such internals are required because of their immeasurably low volatility.
- Example system IV water as refrigerant
- the lithium bromide is the most advantageous sorbent.
- Lithium bromide has a pure substance melting point of 550 0 C, whereupon in the expeller, a concentration of this
- Mass percent residual water content can be made. Below this limit, the lithium bromide crystallizes at least partially and the continuous process comes to a standstill.
- sorption substances according to the invention such as, for example, 1-ethyl-3-methylimidazolium methylsulfonate or 1-ethyl-3-methylimidazolium acetate and 1-ethyl-3-methylimidazolium hydroxide, results in the already mentioned advantages of a considerably higher concentration of Sorption agent in the expeller.
- the ionic liquid bis (2-hydroxyethyl) dimethylammonium methylsulfonate (C7H 19 NO 5 S) is manufactured by several companies. Hints on the synthesis can be found in the publication P. Wasserscheid, T. Welton Ionic Liquids in Synthesis Wiley-VCH, ISBN 3-527-30515-7.
- the use of LiBr as an absorbent and water as a refrigerant is very widespread. Disadvantages of the prior art are - the crystallization of LiBr in water at LiBr-
- the ionic liquid bis (2-hydroxyethyl) dimethylammonium methyl sulfonate according to the invention eliminates these disadvantages of the prior art. In addition to its very good water absorption capacity, this ionic liquid does not crystallize at T ⁇ 20 0 C, even at concentrations greater than 65% by mass of ionic liquid in water.
- the working range of refrigeration processes such as absorption chillers is thus when using this significantly larger ionic liquid, which allows more efficient absorption chillers (same size) or smaller absorption chillers (same power) can be built.
- this ionic liquid according to the invention exhibits a significantly lower corrosivity than LiBr and thus also allows the use of cheaper materials in cooling processes such as absorption chillers. Negative environmental influences of the LiBr are also significantly reduced by this ionic liquid according to the invention.
- the ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate (CsHi 6 N 2 CUS, also called EMIM ES) can be obtained from Degussa AG under the name TEGO IL IM ES (LD 50 > 2000 mg / kg, EC 50 > 100 mg / dm 3 ).
- TEGO IL IM ES LD 50 > 2000 mg / kg, EC 50 > 100 mg / dm 3 .
- the vapor pressure of pure water at 2O 0 C is 23.37 mbar and was thus lowered by the factor 1.56 by the presence of TEGO IL IM ES.
- the use of LiBr as an absorbent and water as a refrigerant is very widespread. Disadvantages of the prior art are - the crystallization of LiBr in water at LiBr-
- the ionic liquid TEGO IL IM ES according to the invention eliminates these disadvantages of the prior art. In addition to its very good water absorption capacity, this ionic liquid does not crystallize at T ⁇ 20 0 C, even at concentrations greater than 65% by mass of ionic liquid in water. The working range of refrigeration processes such as absorption chillers is thus significantly greater when using this ionic liquid, which allows more efficient absorption chillers (same size) or smaller absorption chillers (same power) can be built. In addition, this ionic liquid according to the invention exhibits a significantly lower corrosivity than LiBr and thus also allows the use of cheaper materials in cooling processes such as absorption chillers. Negative environmental influences of the LiBr are also significantly reduced by this ionic liquid according to the invention.
- Example X Example X:
- the ethoxylated Cocosdiethanolamoniumchlorid is an ionic liquid, which can be obtained from Degussa AG under the name TEGO IL K5.
- the ionic liquid TEGO IL K5 according to the invention eliminates these disadvantages of the prior art. In addition to its very good water absorption capacity, this ionic liquid does not crystallize at T ⁇ 20 0 C, even at concentrations greater than 65% by mass of ionic liquid in water.
- the working range of refrigeration processes such as absorption chillers is thus significantly greater when using this ionic liquid, which allows more efficient absorption chillers (same size) or smaller absorption chillers (same power) can be built.
- this ionic liquid according to the invention exhibits a significantly lower corrosivity than LiBr and thus also allows the use of cheaper materials in cooling processes such as absorption chillers. Negative environmental influences of the LiBr are also significantly reduced by this ionic liquid according to the invention.
- the ionic liquid diethyl-polypropoxy-methylammonium chloride can be obtained from Degussa AG under the name TEGO IL P9.
- the ionic liquid TEGO IL P9 according to the invention eliminates these disadvantages of the prior art. In addition to its very good water absorption capacity, this ionic liquid does not crystallize at T ⁇ 20 0 C, even at concentrations greater than 65% by mass of ionic liquid in water.
- the working range of refrigeration processes such as absorption chillers is thus when using this significantly larger ionic liquid, which allows more efficient absorption chillers (same size) or smaller absorption chillers (same power) can be built.
- this ionic liquid according to the invention exhibits a significantly lower corrosivity than LiBr and thus also allows the use of cheaper materials in cooling processes such as absorption chillers. Negative environmental influences of the LiBr are also significantly reduced by this ionic liquid according to the invention.
- EMIM MeSO3 The ionic liquid l-ethyl-3-methylimidazolium methanesulfonate (CAS No.: 145022-45-3, hereinafter referred to as EMIM MeSO3) can be obtained from the German company Solvent Innovation GmbH.
- EMIM MeSO3 ionic liquid l-ethyl-3-methylimidazolium methanesulfonate
- the ionic liquid EMIM MeSO3 according to the invention eliminates these disadvantages of the prior art. In addition to its very good water absorption capacity, this ionic liquid does not crystallize at T ⁇ 20 0 C, even at concentrations greater than 65% by mass of ionic liquid in water.
- the working range of refrigeration processes such as absorption chillers is thus significantly greater when using this ionic liquid, which allows more efficient absorption chillers (same size) or smaller absorption chillers (same performance) can be built.
- this ionic liquid according to the invention exhibits a significantly lower corrosivity than LiBr and thus also allows the use of cheaper materials in cooling processes such as absorption refrigerating machines. Negative environmental influences of the LiBr are also significantly reduced by this ionic liquid according to the invention.
- Example XIII Example XIII:
- the process according to the invention in Figure 1 can also not with LiBr, but, with suitable ionic liquids, a liquid-liquid miscibility gap forming at 0 0 C ⁇ T ⁇ 150 0 C and 1% by mass ⁇ w ⁇ L ⁇ 99 mass% with water operate.
- suitable ionic liquids are the abovementioned compounds, in particular: a) 1-methyl-3-octylimidazolium tetrafluoroborate (CAS: 244193-52-0) b) butylmethylpyrrolidinium bis (trifluoromethylsulfonyl) imide
- the ionic liquids of the invention for use as a sorbent in a working medium for a conventional absorption chill or absorption heat pumping process have lower viscosity or density, greater heat capacity, lower volatility, lower biotoxicity, greater chemical or thermal stability over the prior art , a lower price, a greater absorption capacity for the working fluid water and / or a lower solidification temperature.
- An example of an ionic liquid that can not be used for the purposes of the present invention is 2-hydroxyethylartimium formate. This substance has a number of disadvantages that can be at least partially avoided by using the inventive selection of ionic liquids:
- 2-Hydroxyethylammonium formate is thermally stable only to 15O 0 C [as described by N.Bicak in: Journal of Molecular Liquids 116 (2005) 15-18].
- ⁇ 2-hydroxyethylammonium at 25 0 C has a vapor pressure of 2.2 x 10 -2 Torr [as of N.Bicak in: described Journal of Molecular Liquids 116 (2005) 15-18].
- the vapor pressure of the ionic liquids according to the invention is preferably less than that of 2-hydroxyethylammonium formate, which leads to advantages in absorption refrigeration machines in the separation of refrigerant and absorbent, but also in the operating and investment costs.
- a higher vapor pressure also means a higher risk potential.
- the synthesis of 2-hydroxyethylammonium formate is highly exothermic and, in contrast to the synthesis of the ionic liquids according to the invention, requires efficient cooling in order to control the hazard potentials.
- the viscosity behavior of the ionic liquid 2-hydroxyethylammonium formate is more temperature-dependent than the viscosity behavior of ionic liquids, which are used with particular preference for the purposes of the present invention.
- 2-Hydroxyethylammonium formate is more toxic than the ionic liquids which are preferably used for the purposes of the present invention, such as e.g. B. 1-ethyl-3-methylimidazolium ethylsulfate (TEGO IL IMES). ⁇ 2-Hydroxyethylartimoniumformiat is relatively expensive.
- the working fluid is performed after the absorber 1 by means of a pump 2 into at least one heat exchanger 3a, in which it absorbs heat Q or write. Due to the heat absorption or heat dissipation, the working solution which is still homogeneously liquid at point 1 and which can contain additives in addition to the sorption substance and the refrigerant is in a liquid-liquid mixture gap which is characterized by an upper or lower critical solution temperature.
- the Settier closes. 4 in which the working solution segregates into two liquid phases, a sorption-rich and a cold-rich-rich phase.
- the settler may contain coalescence and sediment promoting internals.
- the refrigerant-rich phase is then passed through at least one heat exchanger 3b and a throttle 5a.
- the largely liquid refrigerant absorbs heat Q to and is thereby converted at least partially in the vaporous gatMap aggregates.
- a new heat transfer in a heat exchanger takes place before the refrigerant-rich phase introduced into the absorber, absorbed by a sorbent and thereby the heat of absorption Q ab is discharged.
- the high-sorbent phase can again be conveyed through a heat exchanger (for example 3a) before it is then expanded to absorber pressure in a throttle 5b and fed to the absorber 1.
- a heat exchanger for example 3a
- a temperature of -50 0 C ⁇ T ⁇ 250 0 C preferably from -20 0 C ⁇ T ⁇ 200 0 C and particularly preferably from -10 0 C ⁇ T ⁇ 180 0 C at a settler settler system pressure between 0.01 bar ⁇ P ⁇ 200 to choose bar
- a temperature of -50 0 C ⁇ T ⁇ 200 0 C preferably from -30 0 C ⁇ T ⁇ 150 0 C and particularly preferably from -20 0 C ⁇ T ⁇ 100 0 C at an absorber system pressure between 0.01 bar ⁇ P ⁇ 60 to choose bar
- the heat exchangers 3a and 3b each have a heat transfer area of 0.1 m 2 ⁇ A ⁇ 300 m 2 , preferably from 0.2 m 2 ⁇ A ⁇ 200 m 2 and more preferably from 0.3 m 2 ⁇ A ⁇ 150 m 2 to provide.
- the sorption substances or additives according to the invention can also be used in at least one stage of a single-stage or multi-stage absorption refrigeration system with at least one heated expeller and subsequent refrigerant condenser - as exemplified in Vauck, WRA and Müller, HA, Basic Operations of Chemical Process Engineering, 10th edition, page 527, für 1994, ISBN 3-342-00629-3 described - are used.
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- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Gas Separation By Absorption (AREA)
- Sorption Type Refrigeration Machines (AREA)
Abstract
Description
Claims
Priority Applications (4)
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ES06763258.8T ES2596853T3 (es) | 2005-06-17 | 2006-05-24 | Medios de trabajo novedosos para procesos de refrigeración |
US11/922,241 US8069687B2 (en) | 2005-06-17 | 2006-05-24 | Working media for refrigeration processes |
EP06763258.8A EP1893716B1 (de) | 2005-06-17 | 2006-05-24 | Neuartige arbeitsmedien für kälteprozesse |
IL187928A IL187928A (en) | 2005-06-17 | 2007-12-06 | Working media for refrigeration processes |
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DE102005028451.5 | 2005-06-17 | ||
DE102005028451.5A DE102005028451B4 (de) | 2005-06-17 | 2005-06-17 | Verfahren zum Transport von Wärme |
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WO2006134015A1 true WO2006134015A1 (de) | 2006-12-21 |
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PCT/EP2006/062567 WO2006134015A1 (de) | 2005-06-17 | 2006-05-24 | Neuartige arbeitsmedien für kälteprozesse |
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US (1) | US8069687B2 (de) |
EP (1) | EP1893716B1 (de) |
DE (1) | DE102005028451B4 (de) |
ES (1) | ES2596853T3 (de) |
IL (1) | IL187928A (de) |
WO (1) | WO2006134015A1 (de) |
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Also Published As
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DE102005028451A1 (de) | 2007-01-04 |
US8069687B2 (en) | 2011-12-06 |
IL187928A (en) | 2013-03-24 |
ES2596853T3 (es) | 2017-01-12 |
EP1893716B1 (de) | 2016-07-13 |
EP1893716A1 (de) | 2008-03-05 |
DE102005028451B4 (de) | 2017-02-16 |
US20100095703A1 (en) | 2010-04-22 |
IL187928A0 (en) | 2008-03-20 |
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