WO2006132048A1 - 光拡散板とその製造方法 - Google Patents
光拡散板とその製造方法 Download PDFInfo
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- WO2006132048A1 WO2006132048A1 PCT/JP2006/309425 JP2006309425W WO2006132048A1 WO 2006132048 A1 WO2006132048 A1 WO 2006132048A1 JP 2006309425 W JP2006309425 W JP 2006309425W WO 2006132048 A1 WO2006132048 A1 WO 2006132048A1
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- Prior art keywords
- light diffusing
- light
- layer
- matrix
- light diffusion
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Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B21/00—Projectors or projection-type viewers; Accessories therefor
- G03B21/54—Accessories
- G03B21/56—Projection screens
- G03B21/60—Projection screens characterised by the nature of the surface
- G03B21/62—Translucent screens
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3405—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
- G02B5/0205—Diffusing elements; Afocal elements characterised by the diffusing properties
- G02B5/0236—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element
- G02B5/0242—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element by means of dispersed particles
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
- G02B5/0268—Diffusing elements; Afocal elements characterized by the fabrication or manufacturing method
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
- G02B5/0273—Diffusing elements; Afocal elements characterized by the use
- G02B5/0278—Diffusing elements; Afocal elements characterized by the use used in transmission
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
Definitions
- the present invention relates to a transmission screen used for projection televisions, microfilm readers, and the like, mainly a light diffusing plate used therefor, and a method for manufacturing the same.
- Projection television in particular, projection light from an optical engine (projector) 11 is projected onto the back side of the screen 13 through the front mirror 12 and the rear projection type (rear) Type) PTV10 (see Fig. 4) is attracting attention as being able to realize large screens such as home theaters at low cost.
- the screen (transmission type) 13 emits the diffused light from the surface mirror as substantially parallel light and the substantially parallel light from the Fresnel sheet 2 in a horizontal direction and emits it. It consists of at least two lens sheets of lenticular sheet 3. Further, a configuration in which a protector 4 having functions such as lens protection, low reflection anti-damper, and fingerprint removal is arranged on the exit side of the lenticular sheet 3 is also common. 31 is a light shielding layer.
- the horizontal viewing angle is expanded by the lens action of the lenticular sheet 3, whereas the vertical viewing angle is increased by a light diffusion agent.
- Light diffiision property is used.
- the light diffusing material a material containing fine particles having a particle diameter of about 1 to 30 m is used. Examples of such a material containing fine particles include an embodiment in which fine particles are kneaded into the protector 4 and an embodiment in which a diffusion film containing fine particles is laminated on the protector 4.
- a hard coat layer (layer thickness: 20 ⁇ m) is coated and formed on one side of a transparent resin substrate with an ultraviolet curable acrylic resin in which silica is dispersed at a concentration of 30%.
- the organic layer (layer thickness 20 ⁇ m) is coated and formed with acrylic resin in which MS (acrylic-styrene copolymer) cross-linked beads are dispersed at a concentration of 10%, and the organic layer is laminated on the lenticular sheet as an adhesive layer. It is shown.
- Patent Document 2 As another example of combining an inorganic material and an organic material, there has been proposed a mode in which the material is arranged opposite to the above in the light transmission direction (see Patent Document 2).
- the projection pupil diameter of a projection lens is smaller in a PTV using a high-definition liquid crystal panel than in a CRT type PTV. It describes the problem of preventing the occurrence of hot spot phenomenon and scintillation phenomenon (unnecessary flicker visible on the projected image plane).
- a first light diffusion sheet having a thickness of 500 to 1000 / zm containing 5 to 20 wt% of organic fine particles having an average of 5 to 15 ⁇ m in the substrate, and an average particle diameter of 2 to A transmission type screen comprising: a second light diffusion sheet having a thickness of 50 to 500 (or 5000) ⁇ m, which contains 1 to L0 wt% of L0 m inorganic fine particles in a substrate.
- a first light diffusion sheet is arranged on the viewer side and the second light diffusion sheet is arranged on the projector side is shown (see FIG. 2B of Patent Document 2).
- Patent Document 2 the problems of the hot spot phenomenon and the scintillation phenomenon are solved.
- Fresnel sheet and A transmissive screen has been proposed in which at least one of the lenticular sheets has a structure of two or more layers in which the dispersion concentration of the light diffusing material is different in the thickness direction of the sheet substrate (see Patent Document 3).
- Patent Document 3 describes that since the light diffusion layer has a multilayer structure, it is suitable for controlling the light diffusion characteristics according to the lens characteristics of the entire light diffusion substrate or the lens sheet.
- a structure in which two light diffusing layers having a layer thickness of 20 ⁇ are laminated on a transparent substrate and a material of the diffusing material are disclosed as organic materials or a combination of inorganic materials and organic materials.
- concentration distribution is the combination of a layer containing 30% diffusing material and a layer containing 15%.
- Another example of the transmission type screen having the same purpose as described above, including a multilayer light diffusion layer having a different concentration distribution of the light diffusion material, is a first light diffusion layer containing 20 to 50% by weight of a light diffusion material (the thickness 50 ⁇ 200 ⁇ m), 0. 1 ⁇ :. L0 0 wt 0/0 transmission screen comprising two layers of the second light diffusion layer containing (thickness 500 to 5000 mu m) is disclosed (See Patent Document 4).
- the light diffusing material described in Patent Document 4 is a light-transmitting fine particle having a weight average particle diameter of 1 to 12 m in any layer, and the light-transmitting fine particle contained in the first light diffusing layer is a substrate (
- the refractive index difference ⁇ with respect to the light-transmitting plastic) is limited to 0.007-0.17, and the second light diffusion layer is defined by the haze value of 50 to 85% of the entire layer.
- ⁇ of the translucent fine particles contained in the second light diffusion layer a value of 0.01-0.1 smaller than that of the first light diffusion layer is exemplified.
- the specific layer structure disclosed here is a light diffusion having a large ⁇ on a thick substrate (second light diffusion layer) containing a small amount (0.1 to 10% by weight) of a light diffusion material having a small ⁇ .
- a light diffusion film (first light diffusion layer) containing a large amount (20 to 50% by weight) of the material is laminated.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2003-131325
- Patent Document 2 Japanese Patent Laid-Open No. 2003-131326
- Patent Document 3 Japanese Patent Laid-Open No. 2002-236319
- Patent Document 4 Japanese Unexamined Patent Publication No. 2000-180973
- Patent Document 5 Japanese Patent Laid-Open No. 2002-357868
- the thickness of the layer (film or substrate) containing the light diffusing material as described above and the amount of the light diffusing material are highly related to the screen characteristics. That is, if the light diffusing layer is made thick and multiple light diffusing materials are present in the light transmission direction, the effect of widening the viewing angle can be sufficiently obtained. In addition, since the light diffusion layer has a certain thickness, the rigidity of the layer can be secured. On the other hand, if the light diffusing layer is thick, the imaging surface becomes thick (the number of imaging in the thickness direction is large), so the resolution is essentially reduced and the amount of light diffusing material in the light transmission direction is reduced. The higher the value, the lower the peak gain (screen brightness).
- the present invention provides a transmissive screen used in a PTV, particularly a transmissive screen suitable for use in a high-definition PTV equipped with an optical engine such as an MD, and a light diffusing plate used therefor. It is aimed.
- an object of the present invention is to provide a high-rigidity transmission screen that can cope with an increase in size when a glass plate is used as a substrate, and a light diffusion plate used therefor. More specifically, even if it is used for high-definition PTV, it not only satisfies both the viewing angle expansion and peak gain due to the light diffusion layer, but also ensures high resolution and high contrast, and also provides scintillation.
- a light diffusing plate that can be reduced and has excellent durability such as scratch resistance and weather resistance, a method for producing the same, and the expansion It is an object of the present invention to provide a transmissive screen including a scattering plate and a rear projection type projection television using the transmissive screen.
- the light diffusion layer is laminated on the transparent substrate, a highly rigid light diffusion plate can be easily obtained.
- the present inventor has studied such a diffusion plate so as to have a diffusivity that satisfies the screen characteristics required for PTV, particularly suitable for high-definition PTV.
- scintillation is suppressed by adding a large amount of light diffusing material or thickening the light diffusing layer to increase the diffusibility. This is a problem that the peak power gain, resolution, and contrast decrease. is there. For this reason, it is necessary to balance these characteristics with diffusivity (viewing angle expansion).
- the light diffusion layer is a combination of a layer containing a large ⁇ and a light diffusing material at a low density (low volume ratio) and a layer containing a light diffusing material at a low ⁇ at a high density (high volume ratio).
- the first light diffusing layer containing a light diffusing material satisfying 0.0 04 ⁇ ⁇ ⁇ ⁇ 0.2 at a low density of less than 40% for the above ⁇ ⁇ .
- a light diffusion material satisfying 0.005 ⁇ ⁇ ⁇ 0.04 with a high density of 40% or more.
- the two-layer structure with the second light diffusing layer included in (1) makes it possible to reduce the overall thickness of the light diffusing layer, to ensure peak gain and resolution, and to combine all of the specific layers, It was found that the diffusibility of the body can be made uniform, thereby reducing scintillation.
- a CCD camera-type luminance meter can be used to capture the entire screen and evaluate the variation in luminance.
- the refractive index difference ( ⁇ ) between the matrix and the light diffusing material is the absolute value of the difference in refractive index between the matrix and the light diffusing material.
- the second light diffusion layer is filled with a light diffusion material having a small ⁇ , that is, a small diffusion capability, which causes a powerful refraction regardless of the transmitted light.
- a light diffusion material having a small ⁇ that is, a small diffusion capability, which causes a powerful refraction regardless of the transmitted light.
- the number of minute diffusions can be increased to make the diffusion uniform.
- the first light diffusion layer containing a light diffusion material with a large ⁇ , that is, a high diffusion capacity allows different diffusion due to the difference in ⁇ from the second light diffusion layer, making the diffusion uniform, Scintillation can be reduced.
- the second light diffusion layer since the light diffusing material has a high density, the number of diffusions can be ensured even if the layer thickness is small.
- the first light diffusion layer if the light diffusion material has a large ⁇ , the viewing angle can be expanded even with a thin film containing a small amount of this, so that the thickness of the light diffusion layer as a whole can be reduced, Scintillation reduction can be achieved without loss of peak gain, resolution and contrast.
- the second light diffusion layer is disposed on the incident side of the transmitted light. It is particularly preferable.
- the scintillation can be further prevented by including a plurality of kinds of light diffusing materials in the second light diffusion layer. It was confirmed that the diffusion plate having such a structure satisfies the above characteristics, and the present invention as described below has been completed.
- the light diffusing plate according to the present invention is a light diffusing plate including a substrate and a light diffusing layer formed on the substrate, and the light diffusing layer has a refractive index of the first matrix and the first matrix.
- the difference in refractive index between the first light diffusion layer including the first light diffusing material having the difference ⁇ of 0.04 ⁇ 0.2, and the second and second matrices, ⁇ is 0.005 ⁇ ⁇ 0. 04 containing the second light diffusing material
- the volume ratio of the first light diffusing material in the first light diffusing layer is less than 40%, and the volume of the second light diffusing material in the second light diffusing layer. 40% rate
- the light diffusing plate has a total layer thickness of 5 to 200 / zm after curing.
- the light diffusing plate according to the present invention is a light diffusing plate including a substrate and a light diffusing layer formed on the substrate, and the light diffusing layer is refracted by the first matrix and the first matrix.
- the first light diffusion layer in the first light diffusion layer is composed of at least two layers including a second light diffusion layer including a scattering material, and the first light diffusion material and the ridge or the second light diffusion material include a plurality of types of light diffusion materials.
- the volume fraction of the material is less than 35%, the volume ratio of the second light diffusing material in the second light diffusing layer is 35% or more, and the total thickness of the light diffusing layers is 5 in the layer thickness after curing. It is a light diffusing plate of ⁇ 200 / zm.
- Patent Document 1 discloses a hard coat layer 30 (20 m) having a silica concentration of 30% and MS crosslinked beads. A structure in which organic layer B (20 m) with a concentration of 10% is separately laminated on both sides of a transparent resin substrate is shown.
- Patent Document 1 does not disclose ⁇ and volume ratio at all for each layer.
- Patent Document 1 is characterized by the use of the shape of fine particles, and also has a description that the concentration of the light diffusing material cannot be increased because the front brightness is lowered, and the present invention is described. Is fundamentally different.
- Patent Document 2 a two-layer structure disclosed in Patent Document 2 consisting of a first light diffusion sheet containing 5 to 20 wt% of organic fine particles and a second light diffusion sheet containing 1 to 10 wt% of inorganic fine particles is shown. Even the thickness of one light diffusion sheet is as thick as 500-1000 m.
- Patent Document 3 which shows a structure in which two light diffusing layers (20 ⁇ m each) containing a light diffusing material are laminated on one side of a transparent substrate, has a specific ⁇ n and volume ratio for each layer. Is not disclosed. Even if the ⁇ in each layer may be different due to the use of a light diffusing material combining inorganic and organic materials, the light diffusing material is contained in a high density with a volume ratio of more than 40%. The embodiment and the necessity thereof are not shown.
- Patent Document 3 shows one of transparent resin substrates that do not contain a light diffusing material. Two or more resin layers (light diffusion layers) containing a light diffusing material are laminated on the surface, and the other surface of the transparent resin substrate is laminated with an adhesive layer so that it faces the lenticular lens. It is. In this configuration, since the distance between the lenticular lens and the diffusion layer is long, there is a problem that the resolution of the image is lowered.
- a diffusion material having a large ⁇ is formed on a substrate containing a light diffusion material having a small ⁇ at a low concentration (0.1 to 10% by weight).
- the relationship between the magnitude of ⁇ and the level of concentration in each layer is as follows: a layer containing a light diffuser with a large ⁇ at a low density (low volume ratio) and a light diffuser with a small ⁇ at a high density (high volume ratio). It is the reverse combination of the present invention by the combination with the layer.
- the volume ratio of the first light diffusion material in the first light diffusion layer is 10% or more and less than 40%, and the volume ratio of the second light diffusion material in the second light diffusion layer is 40. % To 60%.
- the substrate is preferably a glass plate.
- the second light diffusion layer is preferably formed on the substrate through the first light diffusion layer in contact with the first light diffusion layer.
- the second light diffusion layer is preferably disposed on the incident side of the transmitted light.
- the first light diffusion layer and the second light diffusion layer as described above can be formed as a coating film.
- the light diffusion includes a substrate and a light diffusion layer formed on the substrate.
- a method of manufacturing a plate comprising: a first light diffusing material having a refractive index difference ⁇ of 0.04 ⁇ 0.2 between the first matrix forming component and the first matrix forming component;
- the first light diffusion layer forming coating solution having a volume ratio in the liquid of the light diffusing material of less than 40% is applied onto the substrate, and the refractive index difference ⁇ between the second matrix forming component and the second matrix forming component is 0. 005 ⁇ ⁇ 0. 0
- the second light diffusing material is 4 and the volume ratio of the second light diffusing material in the liquid is 40% or more.
- the second light diffusing layer forming coating solution is applied onto the substrate to form the light diffusing layer. This is a method of manufacturing a light diffusion plate to be formed.
- the present invention includes the above-described light diffusion plate together with a Fresnel sheet and a lenticular sheet, and in the order of the Fresnel sheet, the lenticular sheet, and the light diffusion plate, A transmissive screen is provided in which a light diffusing layer side of a light diffusing plate is disposed on the lenticular sheet side.
- the transmission screen according to the present invention is suitable as a screen for rear projection type projection television.
- the light diffusing plate according to the present invention can provide a good viewing angle (diffusibility) without lowering the peak gain, and can reduce scintillation. Therefore, it is possible to ensure the high resolution and high contrast of the projection light particularly having optical engine power.
- the light diffusing plate having a glass plate as a substrate is excellent in durability such as scratch resistance and weather resistance. In addition, it is highly versatile because it is not easily affected by changes in the design of the lens sheet.
- the transmission screen of the present invention including such a diffusion plate is suitable as a rear projection type PTV screen, particularly as a high definition MD type PTV screen.
- FIG. 1 is a side sectional view showing a diffusion plate of the present invention.
- FIG. 2 is a perspective view schematically showing an embodiment of a transmission screen according to the present invention.
- FIG. 3 is a perspective view schematically showing another embodiment of the transmission screen of the present invention.
- FIG. 4 is an explanatory diagram of a rear projection type projection television.
- FIG. 5 is a perspective view schematically showing a conventional transmission screen.
- Second light diffusion layer (light diffusion layer)
- FIG. 1 is a side sectional view schematically showing a light diffusing plate according to the present invention.
- the light diffusing plate 1 has a substrate 100 and a light diffusing layer 110 formed on the surface 1 OOa of which a light diffusing material is dispersed in a matrix.
- the diffusion layer 110 may be formed on one side of the substrate 100 or on both sides.
- the light diffusing layer 110 is composed of at least two layers including light diffusing materials having different refractive index differences ⁇ from the matrix.
- the first light diffusion layer 101 including the first light diffusing material in which ⁇ as ⁇ is 0.04 ⁇ ⁇ 0.2, and ⁇ force ⁇
- a light diffusion comprising a second light diffusion layer 102 including a second light diffusion material, where 005 ⁇ ⁇ ⁇ 0.04
- FIG. 1 shows a preferred embodiment in which the light diffusion layer 110 is laminated on the substrate 100 in the order of the first light diffusion layer 101 and the second light diffusion layer 102.
- a mode in which the order of the layer 102 and the first light diffusion layer 101 is reversed, that is, the first light diffusion layer 101 may be laminated via the second light diffusion layer 102.
- the matrix refers to a material that forms the light diffusion layer itself, specifically, a matrix-forming component described later, and, in some cases, curing necessary for curing the matrix-forming component. It means a layer component formed from an agent.
- the refractive index of the matrix means the refractive index of the layer (cured product) formed from the matrix-forming component, which is almost the same as the refractive index of the matrix-forming component contained in the light diffusion layer forming coating liquid described later. It is the same.
- the substrate is preferably a transparent substrate in order to exhibit its function as a diffusion plate.
- the visible light transmittance (JIS K7361-1 (1997)) power is 3 ⁇ 45% or more.
- substrates made of transparent resin materials such as acrylic resin, polycarbonate resin, acrylic styrene copolymer resin, polyester resin, polyethylene resin such as polyethylene resin, or glass plates are used. can do.
- the glass plate is preferable because it has high rigidity in addition to high transparency and surface flatness.
- tempered glass is more preferable because it has high resistance to impact and is not easily damaged. If the glass plate has high rigidity, the size of the PTV screen will increase.
- Inch (1016mm or more) can be easily handled.
- the glass plate has excellent durability such as scratch resistance and weather resistance, and is less likely to be warped due to changes in atmospheric pressure or external impacts. Therefore, it is possible to avoid the influence caused by the warp on the lens sheet combined with the diffusion plate, for example, the defect that the lenticular sheet and the Fresnel sheet are rubbed and scraped off.
- the surface 100b of the substrate 100 (the surface on which the light diffusion layer 110 is not formed) serves as an observation surface in the diffusion plate 1, so that the substrate 100 has a high flatness. If so, it is possible to realize a high-quality screen that hardly deteriorates the image quality of the display image due to the undulation of the surface 100b of the substrate 100.
- the light diffusion layer 110 can be formed by application of a coating liquid for forming a light diffusion layer (for example, paint or ink) in which a matrix forming component and a light diffusion material are dispersed.
- the flatness of the surface 100a (the surface on which the light diffusion layer 110 is formed) of the substrate 100 is high, and uniform application of the paint becomes easy, and the light diffusion layer 110 can be obtained with a uniform thickness. As a result, scintillation due to non-uniform layer thickness (film unevenness) can be suppressed.
- the thickness of the substrate varies depending on the material and the size of the screen. In the case of a glass plate, the thickness is preferably 1.5 to 4.5 mm.
- the substrate may be colored in order to improve the contrast of the display image. This colorant is preferably a dye or a pigment when the substrate is made of a transparent resin material.
- the matrix-forming component constituting the matrix of the light diffusing layer 110 functions as a binder for the light diffusing material after the layer is formed. Further, the matrix-forming component is a material having adhesiveness with the substrate after forming the layer, and is preferably transparent.
- the matrix forming component is preferably a material that enables formation of a layer by coating. Particularly, a crosslinked coating material that is cured by heat, ultraviolet rays, or the like is preferable.
- matrix-forming components include urethane-based resins, acrylic-based resins, styrene-based resins, polycarbonate-based resins, polymethylpentene-based resins, acrylic-styrene copolymerized resins, and epoxy-based resins.
- the refractive index of the matrix-forming component is preferably 1.42 to L 59 for organic materials and 1.45 to 2.7 for inorganic materials. Note that the refractive index of the matrix forming component is almost the same as the refractive index of the matrix in which the matrix forming component force is also formed.
- the material of the first matrix forming component constituting the first matrix in the first light diffusing layer 101 and the material of the second matrix forming component forming the second matrix in the second light diffusing layer 102 May be the same or different from each other.
- the materials of the two matrix forming components are preferably the same from the viewpoint of production efficiency.
- the light diffusing material contained in the light diffusing layer 110 is a fine particle that is transparent, that is, a fine particle having almost no absorption in the visible light region and a fine particle diameter of about several microns.
- the light diffusing material include transparent inorganic oxide fine particles such as silica and alumina, inorganic fine particles such as glass beads, organic fine particles such as transparent polymer beads, or a mixture thereof.
- the organic fine particles include polymer beads.
- polymer beads include those made of acrylic, styrene, or silicone-based resin.
- cross-linked resins such as acrylic (PMMA) resin fine particles and MS (acrylic-styrene copolymer) resin fine particles are chemically resistant. This is preferable.
- the shape of the polymer beads is a spherical shape because it can be uniformly dispersed in the coating film.
- the average particle diameter of the light diffusing material is preferably 1 to 20 ⁇ m, particularly preferably 5 to 10 ⁇ m. If it is less than 1 ⁇ m, wavelength dispersion occurs in the refractive index of light, and if it exceeds 20 m immediately, the in-plane luminance distribution tends to be a rough film, which is not preferable.
- the refractive index of the light diffusing material varies depending on the material, but is not particularly limited as long as it satisfies the refractive index difference in the present invention. Specifically, the refractive index of the light diffusing material is preferably 1.42 to L59.
- the materials of the first light diffusing material and the second light diffusing material contained in each of the first light diffusing layer 101 and the second light diffusing layer 102 satisfy ⁇ and the volume ratio in the layer described later, They may be the same or different.
- at least the light diffusing material of the second light diffusion layer is preferably a spherical polymer bead that enables high-density filling.
- both the first light diffusing material and the second light diffusing material are spherical polymer beads. It is preferable.
- the first light diffusing material included in the first light diffusing layer has a refractive index difference ⁇ ⁇ with the first matrix of 0.0 4 ⁇ ⁇ ⁇ 0.2, preferably 0.05 ⁇ ⁇ ⁇ 0.1. The one is selected.
- the second light diffusing material contained in the second light diffusing layer has a refractive index difference ⁇ from the second matrix.
- the refractive index of the matrix may be lower or higher than the refractive index of the light diffusing agent, and is not particularly limited.
- the difference in refractive index means the absolute value of the difference between the two types of refractive indexes.
- Both the first light diffusing material and the ridge or the second light diffusing material may be not only one type but also a plurality of types. When there are multiple types, ⁇ and ⁇ are the types of light diffusing material.
- a + B + A in [Equation 1] means (mass content of light diffusing material a in layer Z specific gravity of light diffusing material a), and B in [Equation 1] is ( The mass content of the light diffusing material b in the layer means the specific gravity of the Z light diffusing material b).
- the difference in refractive index between the light diffusing material and the matrix contained in multiple types is 0.01 ⁇ ⁇ ⁇ 0.2 for the first diffusion layer and 0 for the second diffusion layer for all the light diffusing materials included. 005 ⁇ 0. 08
- the degree of diffusion locally changes, which may cause non-uniform diffusion, which is not preferable.
- the difference in refractive index between the light diffusing materials is 0.01 to 0.3 for the first diffusion layer and 0 for the second diffusion layer. 005-0. 1 is preferred in terms of non-uniform diffusion.
- the use of multiple types of light diffusing materials for the second light diffusing layer is preferable in that the uniformity of diffusion is further improved.
- the volume fraction of the first light diffusing material in the first light diffusing layer (hereinafter sometimes abbreviated as the volume fraction in the layer (first)) is less than 40%, preferably 10% or more and less than 40%. is there.
- the volume fraction of the second light diffusing material in the second light diffusion layer (hereinafter sometimes abbreviated as the volume fraction in the layer (second)) is 40% or more, preferably 40% or more and 60% or less. .
- the volume ratio of the light diffusing material in each layer (hereinafter sometimes abbreviated as the volume ratio in the layer) is the volume percentage of the light diffusing material in the layer, the volume percentage of the light diffusing material in the layer, and the matrix. It is the value divided by the total volume percentage.
- the volume ratio in the layer can be obtained by observing the cross section of the light diffusion layer with SEM or the like, and is almost the same as the volume ratio (volume ratio in liquid) of the light diffusing material in the coating liquid described later. It is.
- the volume fraction in the layer is calculated as the sum of the volume fractions in the layers of the respective light diffusing materials.
- the volume ratio (first) in the layer is less than 35%, preferably 10% or more and less than 35%.
- the volume fraction in the layer (second) is 35% or more, preferably 35% or more and 60%.
- the second light diffusing material uses a plurality of types of light diffusing materials, and the first light diffusing material uses one type of light diffusing material.
- the second light diffusing material uses multiple types of the second light diffusing material, the effect of increasing the uniformity of diffusion can be obtained by combining multiple types of diffusion.
- the volume ratio of the scattering material in the layer) ⁇ (the volume ratio of the light diffusing material having a low refractive index) to increase the filling rate of the diffusion material and maintain the diffusion uniformity.
- the refractive index is high, the volume ratio of the light diffusing material in the layer is 1 to 40%, the refractive index is low !, and the volume ratio of the light diffusing material in the layer is 60 to 99%! /.
- the total thickness of the light diffusing layers composed of at least two layers of the first light diffusing layer and the second light diffusing layer is 5 to 200 m in thickness after curing. And preferably 10 to: LOO / zm.
- the second light diffusion layer thickness after curing is preferably 1 to: LOO / zm, especially 2 to 50 ⁇ m, more preferably 20 to 30 ⁇ m.
- the layer thickness is preferably 1 to: LOO / zm, particularly 2 to 50 111, more preferably 20 to 30 / zm.
- the visible light transmittance of the light diffusing plate is preferably (JIS K7361-1 (1997)) of 85% or more from the viewpoint of using light of light source power without loss.
- the light diffusion material is uniformly dispersed in the matrix!
- the light diffusion layer in the present invention comprises at least two layers of the first light diffusion layer and the second light diffusion layer, and the second light diffusion layer is formed on the substrate via the first light diffusion layer.
- the first light diffusion layer may be formed via the second light diffusion layer.
- a layer other than the first light diffusion layer and the second light diffusion layer may be provided.
- a layer such as an antistatic layer for preventing dust adsorption.
- the light diffusing plate having the above-described layer structure is formed by applying a coating liquid for forming a light diffusing layer (hereinafter sometimes abbreviated as a coating liquid) in which a matrix forming component or a light diffusing material is dispersed onto a substrate. By doing so, it can be formed.
- the coating is preferably performed separately for each coating solution.
- the coating liquid is usually a composition in which a matrix-forming component and a light diffusing material are dispersed in the liquid, and it is preferable that the coating liquid be uniformly dispersed.
- the coating solution further contains a curing agent for curing the matrix-forming component, if necessary.
- the content of the curing agent in the coating solution is preferably 20% by mass or less, and preferably 10% by mass, from the viewpoint of not impairing the properties as the diffusion plate.
- the coating solution may contain other components as long as the object of the present invention is not impaired. Examples of other components include reinforcing agents, dispersants, surfactants that improve wettability to substrates, antifoaming agents, leveling agents, and the like, which are components for improving adhesion to the substrate.
- the other components are preferably 10% by mass or less in the coating solution from the viewpoint of not impairing the properties as a diffusion plate.
- a general-purpose solvent suitable for coating can be appropriately selected depending on the material.
- volume ratio of the light diffusing material in the coating liquid (hereinafter sometimes abbreviated as “volume ratio in liquid”) can be expressed by the volume ratio as shown below in consideration of the characteristics of the light diffusion layer. preferable.
- “mass content of light diffusing material in coating solution” means the total of matrix forming components, curing agent and light diffusing material in coating solution. This means the mass content of the light diffusing material with respect to the mass, and the “mass content of the matrix in the coating solution” means the matrix forming component and the matrix forming component in the coating solution, the curing agent and the light diffusing material in total. It means the total mass content of the curing agent.
- the “specific gravity of the light diffusing material” means the specific gravity of the light diffusing material itself, and the “specific gravity of the matrix” means a mass weighted average of the specific gravity of the matrix-forming component and the specific gravity of the hardener.
- the specific gravity of the light diffusing material is preferably 1.1 to 1.3 for an organic material and 1.9 to 5.5 for an inorganic material.
- the specific gravity is 1.2.
- the specific gravity of the structural unit PMMA (1.2) and the specific gravity of PS (1.06) and the copolymerization specific power of each unit can also be calculated.
- the specific gravity of the matrix-forming component is preferably 1.1 to 1.3 for organic materials and 1.9 to 5.5 for inorganic materials.
- the specific gravity of the curing agent is preferably 1.1 to 1.2.
- the specific gravity of the glass adhesive reinforcing agent is preferably 0.9 to 1.0.
- the mass content is calculated as the sum of the mass content of each light diffusing material.
- the specific gravity of the light diffusing material is calculated by the following equation, where the type of light diffusing material is light diffusing material & and light diffusing material b ". [Equation 3] Mass content of light diffusing material a in coating solution + mass content of light diffusion Wb in coating solution 10 ... Average specific gravity
- volume ratio of the light diffusing material in the second light diffusion layer forming coating liquid for forming the second light diffusion layer (hereinafter sometimes abbreviated as second coating liquid) (2) may be abbreviated to 40% or more and 60% or less.
- the matrix-forming component itself is liquid, it can be used as it is as a coating solution without using a solvent. Further, in order to obtain a sufficient layer thickness capable of exhibiting a substantial effect, the total solid concentration in the coating solution is preferably set to 10% by mass or more.
- the volume fraction in liquid is calculated as the sum of the mass contents of each light diffusing material.
- the volume ratio in liquid (first) is less than 35%, preferably 10% or more and less than 35%.
- the volume fraction in liquid (second) is 35% or more, preferably 35% or more and 60% or less.
- the types of light diffusing materials are the light diffusing material a and the light diffusing material b ", the following equation is calculated.
- Equation 4 Volume in liquid [ A X B
- a in Equation 4 means (mass content of light diffusing material a in coating solution Z specific gravity of light diffusing material a)
- B in Equation 4 is (light diffusion in coating solution). Mass content of material b Z specific gravity of light diffusing material b).
- volume ratio of light diffusing material in liquid with high refractive index ⁇ (volume ratio in liquid of light diffusing material with low refractive index)
- the volume ratio of the light diffusing material having a high refractive index is preferably 140%
- the volume ratio of the light diffusing material having a low refractive index is preferably 60 99%.
- the first light diffusing material contained in the first coating solution has a refractive index difference ⁇ of 0.04 ⁇ ⁇ 0.2, preferably 0.05 ⁇ 0.1, with respect to the first matrix forming component. Is selected. Further, the second light diffusing material contained in the second coating liquid has a refractive index difference ⁇ with respect to the second matrix forming component.
- the refractive index of the matrix forming component may be lower or higher than the refractive index of the light diffusing agent, and is not particularly limited.
- the two light diffusing materials may be not only one type but also a plurality of types. In the case of a plurality of types, ⁇ 1 and ⁇ 2 are calculated as shown in the following equation, where the type of light diffusing material is light diffusing material a and light diffusing material b ′ ′.
- a in Equation 5 means (mass content of light diffusing material a in coating solution Z specific gravity of light diffusing material a), and B in several 5 km means (light diffusion in coating solution). Mass content of material b Z specific gravity of light diffusing material b).
- the difference in refractive index between the light diffusing material and the matrix contained in multiple types is 0.01 ⁇ ⁇ ⁇ 0.3 for the first diffusion layer and 0.005 ⁇ ⁇ 0.08 for the second diffusion layer. Is preferred. Above range la lb
- the degree of diffusion changes locally, which may cause non-uniformity in diffusion, which is not preferable.
- the difference in refractive index between the light diffusing materials is 0.01 to 0.3 in the first diffusion layer and in the second diffusion layer.
- a value of 0.005 to 0.1 is preferable in terms of non-uniformity in diffusion.
- the substrate is a glass plate because the coating solution can be applied uniformly when compared with a resin plate.
- a method for applying the coating solution known methods such as bar coating, spin coating, dip coating, screen printing, and die coating used for coating film formation can be applied without any particular limitation.
- a bar coat is particularly preferable.
- Curing of the coating film can be applied by appropriately selecting heating or ultraviolet irradiation according to the matrix material as necessary. Heating is preferably performed at a low temperature of 80 to 150 ° C. for 5 to 60 minutes in the atmosphere, which is preferably performed at a temperature that is not so high. It is preferable to apply the second (first) coating solution after the first (second) coating solution is applied and after heating under the above heating conditions.
- the light diffusing plate according to the present invention may be configured to include other films and substrates in addition to the substrate and the light diffusing layer as long as the object of the present invention is not impaired!
- a low-reflective layer or anti-glare film (both not shown) for preventing the reflection of external light is laminated on the substrate observation surface, or anti-dirter treatment is applied to the substrate observation surface. You may give it.
- Materials or materials for imparting the above low reflectivity and anti-glare properties As the method, a known technique can be appropriately applied.
- the transmission screen according to the present invention includes the light diffusion plate as described above, and is not particularly limited except that the light diffusion layer of the light diffusion plate is disposed on the light emission side of the lens sheet.
- FIG. 2 is a perspective view schematically showing the configuration of an aspect of the transmission screen of the present invention.
- FIG. 3 is a perspective view schematically showing a configuration of a transmission screen including another embodiment lenticular sheet 3.
- the transmissive screen 10 is arranged in the order of the Fresnel sheet 2, the lenticular sheet 3, and the diffusion plate 1.
- the light diffusion layer 110 side is arranged on the lenticular sheet 3 side.
- the same reference numerals indicate the same or corresponding members, and redundant description thereof is omitted.
- an arrow indicates a traveling direction of projection light from an optical engine (not shown).
- the Fresnel sheet 2 is a lens sheet that emits image light from the optical engine as substantially parallel light (toward the viewer) and uniformly brightens the entire screen.
- the lenticular sheet 3 is a lens sheet in which convex cylindrical lens groups that refract the substantially parallel light from the Fresnel sheet 2 in the horizontal direction are arranged in parallel in the horizontal direction, and the image light is refracted and diffused in the horizontal direction of the observer. And expand the horizontal viewing angle (observation area).
- the shape of these lenses varies depending on the optical engine.
- a lenticular sheet 3 having lenses formed on both sides as shown in Fig. 2 is often used.
- a transmissive screen used in a high-definition MD type PTV such as a liquid crystal with a small projection pupil diameter of the projection lens
- a lenticular sheet 3 having a lens formed on only one side as shown in FIG. 3 is used. There are many cases.
- a stripe-shaped light shielding layer 31 that absorbs external light is formed in the non-condensing portion region without passing image light to improve contrast! This is preferred.
- the lens sheet can be combined with the diffusion plate 1 by selecting an appropriate one from widely known ones according to the type of the optical engine.
- the transmission screen as described above is suitable as a rear projection type PTV, particularly as a transmission screen for high-definition PTV such as MD having high directivity of projection light.
- the light diffusing plate of the present invention has the second difference in the refractive index ⁇ of the second light diffusing layer.
- the concentration of fine particles in the light diffusion layer It is possible to increase the concentration of fine particles in the light diffusion layer and to make light diffusion uniform. Furthermore, by setting the refractive index difference ⁇ of the first light diffusion layer to a large value, it is possible to maintain both the brightness and the viewing angle. Also, by making the diffusion different from that of the second light diffusion layer, the diffusion can be made uniform, and scintillation can be prevented. Further, by setting the volume ratio in the layer within a preferable range, minute diffusion can be increased, and as a result, the diffusion can be made uniform.
- urethane resin solution two-component curable screen ink MABOO 0, solid content 45% by weight, specific gravity of resin 1.2, refractive index 1.55
- curing agent for urethane resin 210 hardener, specific gravity 1.1
- glass adhesive reinforcement made by Teikoku Mfg. Co., Ltd.
- acrylic resin fine particles Sekisui Plastics Co., Ltd.: MBX — Coating liquid A was obtained by mixing and stirring 17.5 g of 8 (true spherical fine particles of crosslinked PMMA), specific gravity 1.2, average particle diameter 8 m, refractive index 1.49).
- the volume ratio of coating solution A in the solution was 26%, and the solid content concentration was 14% by mass.
- Coating solution B was obtained in the same manner as above except that 41 g of 56) was used. The volume ratio of coating solution B in the solution was 47%, and the solid content concentration was 28% by mass.
- the volume fraction in liquid was calculated using [Equation 2].
- the specific gravity of the matrix used in [Equation 2] was calculated by mass-weighted average from the specific gravity and content of the urethane resin and the curing agent as matrix forming components.
- the specific gravity of the matrix in Example 1 thus determined was 1.19.
- the specific gravity of the matrix determined by the above calculation is Used for calculation of medium volume fraction.
- the coating liquid A was applied with a bar coater (No. 22) to the surface of a 30cm square glass plate (non-tempered glass, thickness 3mm, visible light transmittance (JIS K7361-1 (1997)) 91%)
- the first light diffusion layer was formed by drying in the air for 30 minutes with a dryer at 150 ° C.
- coating solution B was applied with a bar coater (No. 22), dried in the air for 30 minutes with a dryer at 150 ° C, and the second light diffusion layer was laminated, and the light diffusion layer was laminated on one side of the glass plate.
- Table 1 shows the layer structure and evaluation results
- Table 2 shows the composition of the coating solution. In addition, the contrast of the obtained light diffusing plate is favorable.
- the volume fraction in the layer is obtained by observing the cross section of each layer with SEM photographs.
- the layer thickness was determined with a micrometer.
- Front luminance (peak gain) The surface on which the light diffusing layer was formed was turned to the light source side, and the light diffusing plate was illuminated with a certain illuminance by a projector (manufactured by Hitachi, Ltd .: PJ-TX10-J). The luminance on the surface opposite to the light source was measured by a spectral luminance meter (C-Force Minolta Holdings, Inc .: C S -1000A). It is practically preferable to be 1100 or more.
- Diffusivity (viewing angle): Under the measurement conditions for the front luminance, the luminance was measured while shifting the angle with respect to the light diffusion plate of the spectroluminometer, and the angle (OC) that was half the front luminance was measured. .
- the evaluation criteria are as follows. It is practically preferable that it is ⁇ .
- Example 1 except that the coating order of coating solutions A and B was reversed, a light diffusion layer was formed on one side of the glass plate in the same manner as in Example 1 to obtain a light diffusion plate.
- the light diffusing plate was evaluated in the same manner as in Example 1. Table 1 shows the layer structure and evaluation results, and Table 2 shows the composition of the coating solution. In addition, the contrast of the obtained light diffusing plate is favorable.
- a coating solution C was prepared in the same manner as the coating solution A except that the amount of the light diffusing material in the coating solution A was changed to the amount shown in Table 2.
- the volume fraction in the coating liquid C was 44%, and the solid content concentration was 27% by mass.
- a coating solution D was prepared in the same manner as the coating solution B except that the amount of the light diffusing material in the coating solution B was changed to the amount shown in Table 2.
- the volume ratio of the coating liquid D in the liquid was 27%, and the solid content concentration was 14% by mass.
- a light diffusion layer was formed in the same manner as in Example 1 except that the coating liquid C was used instead of the coating liquid A of Example 1, and the coating liquid D was used instead of the coating liquid B. .
- the light diffusion plate was evaluated in the same manner as in Example 1. Table 1 shows the layer structure and evaluation results, and Table 2 shows the composition of the coating solution.
- a light diffusion layer was obtained in the same manner as in Example 2 except that the coating liquid D was used instead of the coating liquid A of Example 1 and the coating liquid C was used instead of the coating liquid B. .
- the light diffusion plate was evaluated in the same manner as in Example 1. Table 1 shows the layer structure and evaluation results, and Table 2 shows the composition of the coating solution.
- a coating solution E was prepared in the same manner as the coating solution A except that the amount of the light diffusing material in the coating solution A was changed to the amount shown in Table 2.
- the volume ratio of the coating liquid E in the liquid was 33%, and the solid content concentration was 19% by mass.
- the light diffusion plate was evaluated in the same manner as in Example 1.
- Table 1 shows the layer structure and evaluation results, and Table 2 shows the composition of the coating solution.
- Comparative Example 3 a light diffusing plate was obtained in the same manner as Comparative Example 3 except that the coating liquid B was used instead of the coating liquid E.
- the light diffusion plate was evaluated in the same manner as in Example 1.
- Table 1 shows the layer structure and evaluation results, and Table 2 shows the composition of the coating solution.
- a coating solution F was obtained in the same manner as the coating solution B except that the amount of the light diffusing material used in the coating solution B was 80 g.
- the volume ratio of the coating liquid F in the liquid was 63%.
- Comparative Example 3 a light diffusing plate was obtained in the same manner as in Comparative Example 3 except that the coating liquid F was used instead of the coating liquid E.
- the light diffusion plate was evaluated in the same manner as in Example 1.
- Table 1 shows the layer structure and evaluation results, and Table 2 shows the composition of the coating solution.
- Example 1 A commercially available light diffusing material kneaded plate was evaluated in the same manner as in Example 1.
- Table 1 shows the layer structure and evaluation results, and
- Table 2 shows the composition of the coating solution.
- the formed light diffusion plate has a visible light transmittance of 90% or more in any example.
- Example 2 Example 3 and Comparative Examples 1 to 5, which will be described later, were evaluated for variation with a CCD-type luminance meter, and the diffusion was uniform in these examples. Further, the formed light diffusing plate is excellent in durability such as scratch resistance and weather resistance in any example.
- Wood 1 Refractive index difference between matrix and fine particles (absolute value) * 2) Volume ratio of light diffusing material to matrix in layer * 3) Light diffusing material fine particle kneading type diffusion plate (commercial product, thickness 2m) m ⁇ Thu 4) Membrane spots are so severe that all items cannot be evaluated 2] Table 2
- Example 1 In place of 17.5 g of acrylic resin fine particles 17.5 g which is the light diffusing material of coating solution A in Example 1, Styrene resin fine particles (manufactured by Sekisui Plastics Co., Ltd .: SBX-4 (spherical fine particles of crosslinked polystyrene), Specific gravity 1.06, average particle diameter 4 / ⁇ ⁇ , refractive index 1.59) 14.
- a coating solution A2 was prepared in the same manner as in Example 1 except that 2 g was used. The volume ratio of the coating liquid A2 in the liquid was 24%, and the solid content concentration was 12% by mass. At this time, the refractive index difference ⁇ between the matrix and the light diffusing material was 0.04.
- MS resin fine particles which is a light diffusing material for coating solution in Example 1
- acrylic resin fine particles manufactured by Sekisui Plastics Co., Ltd .: MBX-8 (spherical fine particles of crosslinked PMMA)) , Specific gravity 1.2, average particle size 8; ⁇ ⁇ , refractive index 1.49) 14g and MS slag fine particles (manufactured by Sekisui Plastics Co., Ltd .: SMX-8M (PMMAZPS spherical particles), specific gravity 1 1.
- a coating solution B2 was prepared in the same manner as in Example 1 except that 20 g of two types of fine particles were used.
- the refractive index difference ⁇ between the matrix and the light diffusing material at this time n was 0.03 when calculated using [Equation 5].
- a light diffusion layer was obtained in the same manner as in Example 1 except that the coating liquid A2 was used instead of the coating liquid A in Example 1 and the coating liquid B2 was used instead of the coating liquid B.
- the refractive index difference ⁇ between the first light diffusing material and the first matrix in the first light diffusing layer is 0.04, and the refractive index difference between the second light diffusing material and the second matrix in the second light diffusing layer. ⁇ was 0.03 when calculated using [Equation 1].
- the volume fraction in the layer was determined by observing the cross section of each layer with SEM photographs.
- the first light diffusion layer was 24% and the second light diffusion layer was 41%.
- the layer thickness was 25 ⁇ m for both layers as measured by a micrometer.
- This light diffusion plate was evaluated in the same manner as in Example 1. As a result, the front luminance was 1400, the viewing angle and the resolution were ⁇ , and the scintillation was ⁇ . The contrast of the obtained light diffusing plate is good.
- the refractive index difference and the volume ratio are within the scope of the present invention, and the diffusibility, scintillation and resolution are good.
- the luminance is at the same level as the kneaded plate and is good.
- Example 3 uses a plurality of light diffusing materials in the second light diffusing layer, and as a result, the uniformity of diffusion is further improved, so that diffusibility, scintillation and resolution are improved.
- Comparative Examples 1 and 2 cannot increase the minute diffusion that the refractive index difference and the volume ratio of the second diffusion layer are within the range of the present invention, which is not preferable because of poor scintillation. Further, it is not preferable because the luminance is low because many fine particles having a large refractive index difference from the matrix are contained.
- Comparative Examples 3 to 5 are not preferable because the characteristics of force scintillation, which is a layer in which only one diffusion layer is provided, cannot be satisfied. Also, the kneading plate of Comparative Example 6 is not preferable because the light diffusion layer is too thick at 2 mm and the resolution is poor.
- the light diffusing plate according to the present invention is useful as a light diffusing plate for a transmissive screen for PTV, a light diffusing plate for a knock light of a liquid crystal display panel, and the like.
- the entire contents of the specification, patent claims, drawings, and abstract of Japanese Patent Application 2005-165908, filed on June 6, 2005, are incorporated herein by reference. And that is what we take in.
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Abstract
Description
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Priority Applications (2)
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JP2007520044A JP4826582B2 (ja) | 2005-06-06 | 2006-05-10 | 光拡散板とその製造方法 |
US11/949,801 US7727626B2 (en) | 2005-06-06 | 2007-12-04 | Light diffusion plate and its production process |
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JP2005-165908 | 2005-06-06 | ||
JP2005165908 | 2005-06-06 |
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US11/949,801 Continuation US7727626B2 (en) | 2005-06-06 | 2007-12-04 | Light diffusion plate and its production process |
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WO2006132048A1 true WO2006132048A1 (ja) | 2006-12-14 |
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PCT/JP2006/309425 WO2006132048A1 (ja) | 2005-06-06 | 2006-05-10 | 光拡散板とその製造方法 |
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US (1) | US7727626B2 (ja) |
JP (1) | JP4826582B2 (ja) |
KR (1) | KR20080012340A (ja) |
CN (1) | CN100555005C (ja) |
WO (1) | WO2006132048A1 (ja) |
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GB2436498A (en) * | 2005-07-09 | 2007-09-26 | Ncast Ltd | Rear projection screen |
WO2008090929A1 (ja) * | 2007-01-23 | 2008-07-31 | Asahi Glass Company, Limited | 光拡散板、光拡散層形成用組成液および光拡散板の製造方法 |
US20080241508A1 (en) * | 2007-03-31 | 2008-10-02 | Tomoegawa Co., Ltd. | Optical layered product |
JP2008292987A (ja) * | 2007-04-24 | 2008-12-04 | Tomoegawa Paper Co Ltd | 光学積層体 |
CN101802654B (zh) * | 2007-09-07 | 2012-05-30 | 可隆工业株式会社 | 多功能光学膜 |
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JP2014142368A (ja) * | 2011-05-13 | 2014-08-07 | Sharp Corp | 光拡散部材およびその製造方法、表示装置 |
JP5324728B1 (ja) | 2012-01-19 | 2013-10-23 | リンテック株式会社 | 光拡散フィルムの製造方法および光拡散フィルム |
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US20220415221A1 (en) * | 2021-06-29 | 2022-12-29 | Christin Paige MINNOTTE | Light sensitive display system |
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JP2000180973A (ja) * | 1998-12-18 | 2000-06-30 | Mitsubishi Rayon Co Ltd | 透過型スクリーン |
JP2002236319A (ja) * | 2001-02-09 | 2002-08-23 | Toppan Printing Co Ltd | 透過型スクリーン |
JP2003131326A (ja) * | 2001-10-30 | 2003-05-09 | Toppan Printing Co Ltd | 透過型スクリーン |
JP2004271923A (ja) * | 2003-03-10 | 2004-09-30 | Hitachi Ltd | 背面投写型スクリーン及びそれを用いた画像表示装置 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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GB2436498A (en) * | 2005-07-09 | 2007-09-26 | Ncast Ltd | Rear projection screen |
GB2436498B (en) * | 2005-07-09 | 2009-01-07 | Ncast Ltd | Rear projection screen |
WO2008090929A1 (ja) * | 2007-01-23 | 2008-07-31 | Asahi Glass Company, Limited | 光拡散板、光拡散層形成用組成液および光拡散板の製造方法 |
US20080241508A1 (en) * | 2007-03-31 | 2008-10-02 | Tomoegawa Co., Ltd. | Optical layered product |
US8778489B2 (en) * | 2007-03-31 | 2014-07-15 | Tomoegawa Co., Ltd. | Optical layered product |
JP2008292987A (ja) * | 2007-04-24 | 2008-12-04 | Tomoegawa Paper Co Ltd | 光学積層体 |
CN101802654B (zh) * | 2007-09-07 | 2012-05-30 | 可隆工业株式会社 | 多功能光学膜 |
Also Published As
Publication number | Publication date |
---|---|
US7727626B2 (en) | 2010-06-01 |
CN100555005C (zh) | 2009-10-28 |
JPWO2006132048A1 (ja) | 2009-01-08 |
US20080090063A1 (en) | 2008-04-17 |
JP4826582B2 (ja) | 2011-11-30 |
KR20080012340A (ko) | 2008-02-11 |
CN101189538A (zh) | 2008-05-28 |
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