WO2005085951A1 - マスク作製支援方法、マスクブランク提供方法、マスクブランク取引システム - Google Patents
マスク作製支援方法、マスクブランク提供方法、マスクブランク取引システム Download PDFInfo
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- WO2005085951A1 WO2005085951A1 PCT/JP2005/003901 JP2005003901W WO2005085951A1 WO 2005085951 A1 WO2005085951 A1 WO 2005085951A1 JP 2005003901 W JP2005003901 W JP 2005003901W WO 2005085951 A1 WO2005085951 A1 WO 2005085951A1
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- mask blank
- mask
- substrate
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/68—Preparation processes not covered by groups G03F1/20 - G03F1/50
- G03F1/72—Repair or correction of mask defects
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3607—Coatings of the type glass/inorganic compound/metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/3665—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties specially adapted for use as photomask
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/38—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal at least one coating being a coating of an organic material
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/68—Preparation processes not covered by groups G03F1/20 - G03F1/50
- G03F1/82—Auxiliary processes, e.g. cleaning or inspecting
- G03F1/84—Inspecting
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/355—Temporary coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31616—Next to polyester [e.g., alkyd]
Definitions
- Mask manufacturing support method mask blank providing method, mask blank trading system
- the present invention relates to a mask blank for manufacturing a semiconductor, and more particularly to the acquisition and management of quality information of a mask blank, and the manufacture of a mask blank and a mask.
- Japanese Patent Laid-Open Publication No. 2003-149793 is cited. According to the technique described in this publication, it is described that a blank maker classifies blanks according to defect ranks according to inspection results, and supplies blanks to a mask maker with defect information attached.
- Japanese Patent Application Laid-Open No. 2003-248299 discloses a technique for accurately grasping a defect position on a photomask substrate.
- the defect information provided together with the mask blank indicates the relative positional relationship between the defects existing on the mask blank surface, but the mask blank and the defect information are associated with each other. Because there was no standard, there was no way to know exactly where the defect was on the mask blank, even if there was defect information, and a pattern defect occurred during the drawing / developing process. Furthermore, a clear guarantee was made in matching the direction of the mask blank stored in the storage case with the direction of the defect information. As a result, the defect information force deviated from the actual mask blank by 90 degrees, 180 degrees, and 270 degrees, resulting in a pattern defect in the drawing / developing process.
- the substrate stored in a container such as a distribution case, a cassette, or a storage case is taken out, a predetermined process is performed on the substrate, and then the substrate is stored again in another container. It is also a force that does not provide a means to confirm that is the same in the first and second containers.
- pattern defects include, for example, defects called particles and pinholes.
- phase shift mask blanks As mask blanks corresponding to miniaturization of patterns.
- a halftone type phase shift mask blank which is a kind of a phase shift mask blank, a halftone film, a light shielding film, and in some cases, a resist film are further formed.
- the halftone film has a light blocking function and a phase shift function, and has a different role from the light blocking film.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2003-149793
- Patent Document 2 Japanese Patent Application Laid-Open No. 2003-248299
- a pattern defect is detected by using a focused ion beam (FIB), a laser, or the like. Forces corrected in the pattern correction process In some cases, corrections cannot be made due to the increasingly complex and miniaturized patterns. In these cases, the mask must be remanufactured.
- FIB focused ion beam
- the present invention has been made in view of such a situation, and an object of the present invention is to manufacture a mask capable of suppressing a pattern defect caused by a mask blank when manufacturing a mask blank force mask.
- Another object of the present invention is to provide a method of providing a mask blank to which film information is added so that a pattern defect caused by the mask blank can be suppressed when manufacturing a mask blank force mask, and a method of manufacturing the mask blank. is there.
- Another object of the present invention is to provide a transfer mask manufacturing method capable of improving the manufacturing yield and suppressing the manufacturing cost by checking the pattern to be formed using film information.
- the present invention provides the following technology.
- An object of the present invention is to provide a manufacturing support method, a mask blank providing method, a mask blank manufacturing method, and a method of manufacturing a transfer mask using the mask blank.
- a control number is assigned to the substrate, and film information of a plurality of films is collated based on the control number, or a plurality of films are formed at the same position in each film information.
- Another aspect of the present invention is as follows.
- the film information is surface information and surface morphology information of the film, for example, a convex shape, a concave shape, and the like of the film surface. It is a combination of these or film state information including optical property information and the like, and is information associated with film surface position information.
- the optical characteristics referred to here include transmittance, reflectance, absorbance, phase difference, and the like.
- the film information obtained for each of the plurality of films stacked on the substrate can be individually identified based on a management number or the like, and the information is collated.
- the relationship with the film information is guaranteed, the relationship between the plurality of film information can be guaranteed, and the position in the mask blank indicated by the position information included in the plurality of film information is guaranteed.
- board information regarding the board may be acquired.
- the substrate information is substrate state information including surface information and surface morphology information of the substrate, for example, convex and concave shapes of the substrate surface, a combination thereof, or optical characteristic information. Is the information associated with the position information of.
- the optical characteristics referred to here include transmittance, reflectance, light absorption, phase difference, and the like.
- the substrate information and the film information can be individually identified based on the management number and the like, and can be compared.
- the relationship between the mask blank individual and the acquired substrate information and film information can be guaranteed, and the relationship between the substrate information and the film information can be guaranteed, which is indicated by the position information included in the substrate information or the film information. The position in the mask blank is guaranteed.
- the mask blank is obtained by comparing a plurality of pieces of film information or the morphological information contained in the film information with the substrate information.
- the relationship between the individual and the acquired film information or substrate information can be guaranteed, the relationship between a plurality of film information or the relationship between the film information and the substrate information can be guaranteed, and the positional information included in the plurality of film information can be guaranteed.
- the position in the mask blank are guaranteed, and the relationship between the position information contained in the substrate information or film information and the position in the mask blank is guaranteed.
- the present invention for a mask blank composed of a substrate and a film formed on the substrate, substrate information and film information or mask blank information that also has a plurality of film information capabilities is provided. Have been obtained.
- the position information contained in the mask blank information is guaranteed to be in the mask blank. That is, the mask blank information in the present invention is three-dimensional information of the mask blank, and is characterized in that it is acquired so as to be recognizable as internal information of the mask blank, that is, information within the mask blank.
- the present invention includes a configuration in which the reference point of the position of the position information included in the mask blank information and the reference point of the position of the master blank are associated with each other to acquire information.
- a configuration is provided in which the reference point of the position of the position information included in the substrate information and the reference point of the position of the substrate are associated with each other to acquire information.
- a configuration is provided in which information is acquired by associating a reference point of the position of the position information included in the film information with a reference point of the position of the substrate or the film.
- the mask blank surface information including the surface morphology information and the position information is provided to the mask maker, and the surface information and the mask blank surface morphology are associated with each other by the provided reference points.
- a method for providing a mask blank, a method for providing a mask blank, a method for manufacturing a mask blank, and a method for manufacturing a transfer mask using the mask blank is.
- the film information is information obtained by inspecting each of the films immediately after being formed on the substrate.
- the film information includes surface morphology information indicating the location of the defect on the film and the 'size' type, etc., and the position, range, and state after the composition change of the film material in the film surface.
- the surface information including the surface morphology information of the uppermost film that becomes the surface after the mask blank is completed is stored in the mask blank table. This is called surface information.
- Another aspect of the present invention is as follows.
- the mask creator When providing the mask blank information to a mask maker, the mask creator provides a predetermined mask pattern to the mask blank by providing the mask blank information and a mask blank individual associated with this information in an associated manner.
- a mask manufacturing support method By providing a mask manufacturing support method, a mask blank information providing method, a mask blank providing method, a mask blank manufacturing method, and a method of manufacturing a transfer mask using the mask blank so that a region where a mask is to be formed can be selected. is there.
- the present invention includes a configuration in which the reference point of the position of the position information included in the mask blank information is associated with the reference point of the position of the master blank.
- the substrate or the mask blank when the substrate or the mask blank is stored in a storage device used in a mask blank manufacturing process and / or in providing a mask blank to a mask manufacturer, Alternatively, a configuration for managing the arrangement and directionality of the mask blanks is included. For example, it includes a mode in which a plurality of substrates or a plurality of mask blanks are housed in a predetermined direction. At this time, it may be stored with reference to a reference point provided on the substrate, film or mask blank.
- the storage device mentioned here includes, for example, a holder and a case described later.
- an identifiable mark can be used.
- the marks and reference marks used in the present invention include, for example, a mark provided on a substrate such as a notch mark described later, and a mark provided on a film called a film mark. Can be used.
- the mask blanks are stored and provided as described above, the mask blanks are provided in a predetermined arrangement and in a predetermined direction, so that the mask maker can identify the individual mask blanks, The reference point of the position of the mask blank can be grasped with or without reference to the reference point.
- the mask creator can use the provided mask blank information via the reference point of the position of the mask blank, and based on the provided mask blank information, the surface information of the mask blank for which the transfer mask is to be manufactured. And the internal information can be grasped, so that a region where a predetermined mask pattern is to be formed can be selected.
- the mask maker can grasp the presence of surface defects or internal defects that may cause pattern defects or hinder the desired function of the transfer mask before forming a predetermined mask pattern, so that the manufacturing yield can be reduced.
- the production of a transfer mask with high profitability or the production of an inexpensive transfer mask can be performed.
- the present invention is preferably used for a mask blank or a transfer mask on which a phase shift film, for example, a neutral tone film is formed.
- a phase shift film for example, a neutral tone film is formed.
- a halftone type phase shift mask which is a kind of a phase shift mask
- a halftone film and a light shielding film are formed on a light transmitting substrate.
- the halftone film has both a light blocking function of substantially blocking exposure light and a phase shift function of shifting the phase of exposure light.
- the halftone film controls transmittance and phase difference to form a pattern to be transferred to a transfer target. It has the function of emphasizing pattern edges.
- the halftone phase shift mask has a pattern of a halftone film formed on a light-transmitting substrate, and is a light that transmits light having an intensity substantially contributing to exposure without forming a pattern of the halftone film.
- the quality required of a mask blank on which a halftone film is formed is higher than that of a mask blank on which only a single light-shielding film is formed. In some cases, it is difficult to lower the defect rate It is.
- the present invention provides the following technology.
- a transfer mask When a transfer mask is manufactured by patterning the thin film from a mask blank having at least a plurality of films including a thin film to be a transfer pattern formed on a substrate, the pattern is formed in order to suppress pattern formation defects.
- a mask manufacturing support method for providing a mask maker with film information for specifying an area, wherein the film information is information obtained from a plurality of films constituting a mask blank. provide.
- the pattern may include a dense pattern forming region in which a relatively dense pattern is formed and a sparse pattern forming region in which a relatively sparse pattern is formed.
- the film information may include any of the type of the convex portion or the concave portion causing the pattern defect, the size of the convex portion or the concave portion, and the positional information of the convex portion or the concave portion! .
- the film may include a phase shift film having a phase shift function for exposure light!
- the present invention is a mask blank providing method for providing a mask maker together with the mask manufacturing support method described above, wherein the mask blank is stored in a storage case and the mask blank is held.
- the mask blank information is provided by being held by a holder provided with a holding slot formed so that the mask blank information is collated by mask blank specifying means indirectly provided to the mask blank.
- the mask blank information may be collated by the slot number given to the slot of the holder.
- the present invention also provides a step of preparing a mask blank substrate, a step of forming a thin film to be a transfer pattern on the substrate, and a thin film information obtaining step of obtaining thin film information.
- a film information collating step of collating information of collating information.
- a substrate information acquiring step of acquiring substrate information of the substrate may be included, and further, the substrate information acquired in the substrate information acquiring step may be used as information.
- a substrate information recording step of recording and storing the information on a storage medium may be included.
- a collation step for collating the substrate information with the film information may be provided.
- the method After preparing the mask blank substrate, the method includes a control number assigning step of assigning a control number to the mask blank substrate, and based on the assigned control number, the film information of the thin film and the film information of the resist film are compared. It is good also as collation. Further, the substrate information and the film information may be collated.
- the substrate information or the film information may include any of the type of the convex portion or the concave portion, the size of the convex portion or the concave portion, and the positional information of the convex portion or the concave portion.
- the position information may be created based on a notch mark formed on the substrate and Z or a film mark formed by a thin film formed on a peripheral portion on the main surface of the substrate.
- the substrate information, the film information of the thin film, and the film information of the resist film include a specific form formed at the same position included in the substrate information, the film information of the thin film, and the film information of the resist film, for example, a convex portion or a concave portion. You can also match by ⁇ ! / ,.
- the present invention uses a mask blank in which at least a film including a thin film to be a transfer pattern is formed on a substrate, and patterns the thin film in accordance with pattern data to be formed to form a transfer mask.
- a mask manufacturing method wherein mask blank information obtained by the above-described mask manufacturing support method is compared with the pattern data, and a pattern forming region in the mask blank is specified so as to suppress a pattern formation defect.
- a method for producing a transfer mask characterized by the above is provided.
- the pattern may include a dense pattern forming region where a relatively dense pattern is formed and a sparse pattern forming region where a relatively sparse pattern is formed.
- the present invention also includes the following inventions. That is, when a transfer mask is manufactured by patterning a thin film from a mask blank on which at least a film including a thin film serving as a transfer pattern is formed on a substrate, a region where a pattern is formed is specially suppressed to suppress pattern formation failure.
- the mask blank information includes the surface morphology information, and the reference of the position of the surface morphology in the mask blank provided to the mask maker The point and the reference point of the position information corresponding to the surface morphological information correspond, and the mask maker reflects the mask blank information on the mask blank via the reference point, grasps the state of the mask blank,
- a mask manufacturing support method characterized in that a region for pattern formation can be specified.
- a reference mark is provided on the substrate or on the substrate, and the reference point of the position information is created with a certain relationship with the reference mark, and corresponds to the reference point of the position of the surface morphology on the mask blank! Chiyo!
- a reference mark is provided on a substrate, a film, or a mask blank, and information is obtained such that a reference point of position information included in the information has a certain relationship with the reference mark when obtaining substrate information or film information.
- the reference point of the position of the mask blank information may correspond to the reference point of the position of the provided mask blank.
- the reference mark is provided so that the direction or direction of the substrate or the mask blank can be specified.
- the reference mark is provided on a portion adjacent to a corner of the substrate or the mask blank.
- the substrate or the mask blank may be provided. This is preferable because it is easy to specify the direction and direction of the object.
- the reference mark may have a shape that can specify the directionality of the substrate.
- the reference mark may be provided at a position which is not symmetrical with respect to a line parallel to the side of the substrate and passing through the center of the substrate.
- the reference mark is a notch mark formed on the substrate and a film mark formed by a thin film formed on Z or the main surface of the substrate.
- the substrate information and the film information may be information acquired in a specific direction based on the fiducial mark.
- the method includes a film forming step of forming a film including a thin film to be a transfer pattern on a substrate, and a surface information obtaining step of obtaining surface information of the film.
- the directionality of the substrate or the mask blank may be managed based on the reference mark.
- each step of manufacturing a mask blank when the substrate or the mask blank is stored in a case used for transporting the substrate or the mask blank to each step, the substrate or the mask blank is referred to based on the fiducial mark.
- the direction may be managed.
- the directionality of the substrate or the mask blank is managed in a predetermined manner, that is, a plurality of substrates or mask blanks are arranged so as to have a fixed orientation, and even when information is acquired.
- the information is obtained by aligning a plurality of substrates or mask blanks in a certain direction, which is particularly suitable for the present invention.
- the surface information may include at least one of substrate surface information and film surface information.
- the surface information of the film may include the surface information of the phase shift film!
- the surface morphology is such that when a transfer mask is manufactured by patterning a thin film with a mask blank force, the surface roughness or undulation, projections and Zs or depressions, foreign matter and dents, film detachment, and film loss that result in poor pattern formation. It may include particle-like defects and Z- or pinhole-like defects obtained by a defect inspection device!
- the surface information includes roughness, undulation height, wavelength and period, height and size of projections, depth and size of depressions, height and size of foreign matter, depth and size of dents, and height of particles.
- the size and size of the pinhole may include information on the depth and size of the pinhole.
- the pattern may include a dense pattern forming region in which a relatively dense pattern is formed and a sparse pattern forming region in which a relatively sparse pattern is formed.
- the sparse pattern formation region is a monitor chip type formed for testing electrical characteristics. Even if it is a realm.
- the transfer mask may be a transfer mask for manufacturing a system LSI.
- a plurality of mask blanks and mask blank information corresponding to each mask blank may be provided to a mask creator.
- the present invention is a mask blank transaction system for performing the above-described mask manufacturing support method, wherein each mask blank is specified directly or indirectly with respect to a plurality of mask blanks stored in a mask maker.
- a mask blank transaction system is provided in which the mask blank information is provided to a mask manufacturer together with the mask blank in association with the control number or the control symbol.
- the management number or the management symbol may be a holder having a slot formed to hold the mask blank and a slot number and a case number given to a storage case for storing the holder.
- the mask blank information may be provided to a mask manufacturer using a communication line.
- the mask blank information is stored in the information storage means (server) in association with the management number or the management symbol, and the mask maker accesses the information storage means (server) using a communication line to store the management number or the management code.
- the mask blank information may be obtained based on the control symbol.
- the present invention provides a step of preparing a mask blank substrate, a step of forming a film including a thin film to be a transfer pattern on a main surface of the substrate, and a step of patterning the thin film to form a transfer mask.
- a mask blank manufacturing method comprising the steps of: providing a reference mark on a substrate or a substrate, and acquiring surface information in a specific direction with reference to the reference mark. I will provide a.
- the fiducial mark may have a shape that can specify the directionality of the substrate.
- the reference mark is positioned asymmetrically with respect to a line parallel to the side of the substrate and passing through the center of the substrate. It may be provided in a location.
- the reference marks are notch marks formed on the substrate and Z or a film mark formed by a thin film formed on the main surface of the substrate.
- each step of manufacturing a mask blank when the substrate is stored in a case used for transporting the substrate to each step, the orientation of the substrate is controlled based on the fiducial mark. Small.
- the mask blank substrate After preparing the mask blank substrate, it has a control number assigning step of directly or indirectly assigning a management number specifying the substrate to the mask blank substrate, and is manufactured based on the assigned management number.
- the surface information of the mask blank may be collated.
- the method further includes a packing step of storing the mask blank in the storage case and packing the mask blank.
- the mask blank is provided by a holder having a slot formed to hold the mask blank stored in the storage case.
- the mask blank specifying means force for comparing the mask blank with the surface information may be directly or indirectly applied to and stored in the mask blank.
- the mask blank specifying means may be a slot number and a case number given to the holder and the storage case.
- the present invention also relates to a transfer mask for producing a transfer mask by patterning a thin film according to pattern data to be formed, using a mask blank having a film including at least a thin film to be a transfer pattern formed on a substrate.
- a manufacturing method the surface information of the mask blank, in which the position of the surface morphology of the mask blank obtained by the above-described mask manufacturing support method is associated, is compared with the pattern data, so that pattern formation defects are suppressed.
- a method for manufacturing a transfer mask characterized by specifying an area on a mask blank where a pattern is to be formed.
- the pattern data includes a dense pattern formation region in which a relatively dense pattern is formed and a sparse pattern formation region in which a relatively sparse pattern is formed. If a surface morphology that results in a defect is included, the surface information is compared with the pattern data, and the pattern data is arranged on the mask blank so that the surface morphology that results in the pattern defect is located outside the dense pattern formation area. You can also specify. [0093] Further, the present invention provides a transfer mask for producing a transfer mask by patterning a thin film according to pattern data to be formed, using a mask blank in which at least a film including a thin film to be a transfer pattern is formed on a substrate.
- the mask blank information on the mask blank obtained by the mask manufacturing support method according to the present invention is compared with the pattern data to form a pattern.
- the present invention provides a method for manufacturing a transfer mask, characterized by selecting a region in the mask blank where the pattern is to be formed so as to suppress the defect of the pattern and to prevent the function of the transfer mask or Z from being hindered.
- the pattern data includes a region having a relatively dense pattern and a region having a relatively sparse pattern, and the mask blank information causes a pattern defect.
- state information that causes the function of the transfer mask to be impaired that is, morphological information or optical characteristic information
- a position other than the position where the state exists is selected and relatively determined.
- a region for forming a dense pattern can be arranged.
- the present invention uses a mask blank in which a film including at least a thin film to be a transfer pattern is formed on a substrate, and performs patterning of the thin film according to pattern data to be formed to form a transfer mask.
- the present invention uses a mask blank in which a film including at least a thin film to be a transfer pattern is formed on a substrate, and performs patterning of the thin film according to pattern data to be formed to form a transfer mask.
- Transfer mask production support method for assisting the present invention uses a mask blank in which a film including at least a thin film to be a transfer pattern is formed on a substrate, and performs patterning of the thin film according to pattern data to be formed to form a transfer mask.
- the mask data and the pattern data of the mask blank obtained in advance according to the present invention are compared with each other to form a pattern.
- a transfer mask manufacturing support method for selecting a specific mask blank in order to suppress a defect and to prevent the function of the transfer mask or Z from being hindered.
- the sparse pattern formation region may be a monitor chip formation region formed for testing electrical characteristics.
- the transfer mask may be a transfer mask for manufacturing a system LSI.
- the present invention is a mask blank providing method for providing a mask maker together with the mask manufacturing supporting method described above to a mask maker, wherein the mask blank is stored in a storage case, and is stored in the storage case.
- the directionality of the mask blank and the directionality of the substrate in the surface information acquisition step of acquiring surface information may be associated with a reference mark.
- the mask blank information acquisition method of the present invention can also be described as follows.
- the mask blank information includes the substrate information and one or more pieces of film information, or
- the substrate information includes two or more pieces of film information, and the substrate information includes position information in a plane coordinate system (two-dimensional coordinate system) corresponding to the substrate surface, and state information indicating a state of the substrate associated with the position information.
- the film information includes position information in a plane coordinate system corresponding to one film and state information indicating the state of the film associated with the position information, and includes substrate information or film information included in the mask blank information.
- the present invention provides a method for acquiring mask blank information, wherein the plane coordinate system has a predetermined correspondence.
- a step of forming the first film on the substrate surface or another film formed on the substrate surface, and a first step related to a state of the formed first film Obtaining a film information; forming a second film on the first film; obtaining second film information relating to a state of the formed second film; And generating mask blank information including the first film information and the second film information.
- the step of preparing a substrate, the step of obtaining substrate information relating to the state of the prepared substrate, the step of forming a film on the surface of the substrate, and the state of the formed film The method may include a step of obtaining the film information and a step of generating mask blank information including the substrate information and the film information.
- the reference points of the plane coordinate system included in the substrate information and the film information may have a predetermined relationship with each other, or at least one of a mark formed on the substrate and a mark formed on the film. It may be determined based on one of them! / ,.
- the method may further include a step of comparing the substrate information and the Z or film information with each other.
- the state information may include at least one of information on surface morphology and information on optical characteristics.
- At least one of the films may be a phase shift film that shifts the phase of exposure light.
- Information generated by projecting film information of a plurality of films onto a plane may be included in the mask blank information.
- the method Prior to the acquisition of the film information, the method further comprises the step of providing a reference mark detectable as state information at a predetermined position on the substrate and at a predetermined position on the Z or the film, wherein the substrate is determined based on the reference mark.
- the reference mark may have a shape that can specify the direction.
- the contour of the substrate may have a shape having rotational symmetry, and the shape of the substrate including the provided reference mark may have rotational asymmetry.
- a typical outline of a substrate is a square including a square and a rectangle.
- the film A is formed on the substrate by the device A, and the film a is measured to obtain the film information a including the reference mark.
- the film information a including the reference mark.
- placing the substrate in a case in a predetermined direction with the fiducial mark as a reference transporting the case to the apparatus B, and pre-determining the substrate with the fiducial mark as a reference.
- the method may include a step of installing in the apparatus A and a step of forming the film a on the substrate by the apparatus A and measuring the film a to obtain the film information a including the reference mark.
- the individual of the mask blank may be identified by referring to the acquired mask blank information.
- the state information may include at least two types of measurement values.
- At least one of the substrate information and the film information may include at least one of the substrate information and the film information including position information in a three-dimensional coordinate system that further includes coordinates in the thickness direction of the substrate or the film.
- the present invention also relates to a method for providing mask blank information, which is information on a mask blank produced by stacking a plurality of films on a substrate, and obtaining the mask blank information described above.
- a method for providing mask blank information characterized in that the mask blank information obtained by the method is provided together with the mask blank.
- the present invention provides a method of providing mask blank information to a mask maker and supporting the production of a transfer mask, wherein the mask blank information providing method provides mask blank information to the mask maker.
- the mask blank information to be provided is used to identify the area where the mask pattern is to be formed on the mask blank prior to forming the mask pattern on the corresponding mask blank in order to prevent the production of a defective transfer mask.
- a method for supporting the production of a transfer mask is also used to identify the area where the mask pattern is to be formed on the mask blank prior to forming the mask pattern on the corresponding mask blank.
- the present invention provides a method of providing mask blank information to a mask maker and supporting the production of a transfer mask, wherein the step of providing mask blank information to the mask maker by the above-described mask blank information providing method is provided.
- This is a method for notifying the mask manufacturer of the reference point of the coordinate system in the mask blank information via a reference mark.
- the mask maker receiving the information acquires the correspondence between the planar coordinate systems via the reference mark, and determines a region in which a mask pattern is to be formed based on the acquired correspondence and the mask blank information.
- the mask pattern formed on the mask blank may include a block with a relatively dense pattern and a block with a relatively sparse pattern.
- the present invention provides a method of manufacturing a transfer mask by forming a mask pattern to be a transfer pattern on a mask blank, based on the mask blank information obtained by the above-described mask blank information obtaining method.
- the present invention provides a transfer mask manufacturing method characterized in that a region where a mask pattern is arranged on a mask blank is defined.
- the present invention also provides a method for manufacturing a mask blank, which includes the above-described method for obtaining mask blank information in a method for manufacturing a mask blank.
- the present invention relates to a system for acquiring mask blank information, which is information relating to a mask blank having a plurality of films stacked on a substrate surface, wherein the substrate information relating to the state of the substrate is provided.
- Acquiring means acquiring means for acquiring first film information relating to a state of a first film formed on the substrate surface or another film formed on the substrate surface, and forming a film on the substrate surface.
- the means for acquiring the second film information relating to the state of the second film which is a film other than the filmed first film
- at least two information acquiring means are provided.
- a mask blank information acquisition system comprising: means for generating mask blank information including information acquired by the above method.
- the substrate information includes position information in a plane coordinate system corresponding to the substrate surface and state information indicating the state of the substrate associated with the position information.
- the film information includes position information in the plane coordinate system corresponding to one film and state information indicating the state of the film associated with the position information, and the plane coordinates of the substrate information or the film information included in the mask blank information.
- the system may have a defined correspondence.
- the reference mark may be provided in a region that is polygonal and that is sandwiched between two sides adjacent to each other.
- an even number of reference marks may be provided at rotationally asymmetric positions with respect to each other.
- the mask blank information providing method described above provides mask blank information of a plurality of mask blanks to the mask maker.
- the mask blank information to be provided, including the steps, is referred to when selecting one of a plurality of mask blanks prior to forming a mask pattern.
- the invention provides.
- the method may further include, after the step of obtaining the film information b, setting the substrate in a predetermined direction with the fiducial mark as a reference and storing the substrate in a case. Good.
- the method may further include the step of storing the substrate in a case in a predetermined direction with the fiducial mark as a reference. Good.
- the direction of the substrate information and the film information can be matched with the actual direction of the substrate. Also, even if the substrate is handled in the wrong direction in the manufacturing process, an error in the direction can be detected by comparing the substrate information and the film information with each other.
- Individual mask blanks can be identified based on the obtained substrate information "film information. That is, the substrate information and the film information can be used as a kind of identifier.
- FIG. 1 is a flowchart for explaining a mask blank film information acquiring method of the present invention.
- FIG. 2B is a plan view for explaining a mask blank storage case 10.
- FIG. 3A is a view for explaining a tray mark 31 showing the front and back of a mask blank.
- FIG. 3B is a view for explaining a notch mark 1 showing the front and back of the mask blank.
- FIG. 5 is a block diagram for explaining a mask blank film information management system 50 of the present invention.
- FIG. 6 is a block diagram for describing a host computer 51.
- FIG. 7 is a block diagram for explaining a cassette number and slot number assigning device 52.
- FIG. 8 is a block diagram for explaining a primary film forming apparatus 53.
- FIG. 9 is a block diagram for explaining a primary film defect inspection device 54.
- FIG. 10 is a block diagram for explaining a resist film forming apparatus 57.
- FIG. 11 is a block diagram for explaining a mask production support system 110.
- FIG. 12 is a flowchart for explaining pattern drawing / developing processing in a mask manufacturing process in the client Z mask factory 12.
- FIG. 13A is a cross-sectional view of a mask blank before undergoing a drawing / developing process in a mask manufacturing process.
- FIG. 13B is a cross-sectional view of a transfer mask manufactured through a mask manufacturing process.
- FIG. 14 is a diagram for explaining the arrangement of a sparse pattern formation region and a dense pattern formation region performed based on blank film information and mask pattern data.
- FIG. 15 is a flowchart for explaining a mask blank manufacturing process and a method of acquiring and storing mask blank film information during the mask blank manufacturing process in the mask manufacturing support method of the present invention. It is.
- FIG. 16B is a view for explaining a film mark 31 of a mask blank.
- FIG. 17 is a graph for explaining an example of mask blank film information (surface information) obtained in the mask blank film information (surface information) obtaining step of the present invention.
- FIG. 18A is a cross-sectional view for explaining a storage case 10 that stores a mask blank.
- FIG. 18B is a plan view for explaining a storage case 10 for storing a mask blank.
- FIG. 19 is a block diagram for explaining a mask manufacturing support system 110.
- FIG. 20 is a flowchart for explaining a mask manufacturing process in which a mask factory 112 has a process of drawing and developing a resist film of a mask blank to form a pattern by using blank film information to form a pattern; It is.
- FIG. 21A is a cross-sectional view of a mask blank before performing a drawing / developing process in a mask manufacturing process.
- FIG. 21B is a cross-sectional view of a transfer mask manufactured through a mask manufacturing process.
- FIG. 22 is a diagram for explaining the arrangement of a sparse pattern formation region and a dense pattern formation region performed based on blank film information and mask pattern data.
- FIG. 23 is a view for explaining a mask blank film information management system 50 of the present invention.
- FIG. 25 is a block diagram for describing a host computer 51.
- FIG. 26 is a block diagram for explaining a primary film forming apparatus 53.
- FIG. 27 is a block diagram for explaining a primary film defect inspection device 54.
- FIG. 28 is a block diagram for explaining a resist film forming apparatus 57. Explanation of symbols
- Defect inspection condition control unit 546 Defect Inspection Equipment
- the film information includes the surface information as described above, and the film information can be read as the surface information as it is.
- a glass substrate on which the notch mark 1 is formed is prepared.
- the notch mark indicates the glass type of the substrate by its shape.
- the surface of the glass substrate is polished to obtain desired surface roughness and flatness.
- the glass substrate is stored in the distribution case 2 having an ID tag. In the distribution case 2, the glass substrate is aligned with the notch mark 1 as a reference and stored.
- the host computer uses a host computer that controls production, assign a control number to control each board to the ID tag attached to Distribution Case 2.
- the host computer collects, records and saves information on the order of the manufacturing process, setting of manufacturing conditions, and each manufacturing process.
- the glass substrate housed in the distribution case 2 is carried into the sputtering device, and the notch mark 1 is formed!
- a primary MoSiN halftone film is formed by reactive sputtering. I do.
- the film mark 3 is formed at a position where the MoSiN film is not formed by the substrate holder.
- the substrate with the MoSiN halftone film is stored in distribution case 4 different from distribution case 2.
- information on the completion of the primary film formation is stored in the host computer.
- the control number is transferred to the ID tag attached to distribution case 4.
- the substrates are aligned with the notch mark 1 (or the film mark 3) as a reference.
- the substrate with the halftone film accommodated in the distribution case 4 is carried into a defect inspection device for inspecting a defect of the primary film, and a defect inspection is performed to obtain film information.
- the obtained film information is referred to as primary film information.
- the board for which the defect inspection has been completed is stored in another distribution case 5.
- the management number is transferred to the ID tag of distribution case 5.
- the substrates are housed in the same direction based on the notch mark 1 (or the film mark 3).
- a Cr light-shielding film which is a secondary film, is formed on the primary film by reactive sputtering.
- a film mark 6 is formed at a position where the Cr film is not formed by the substrate holding portion.
- the substrate with the Cr light shielding film is housed in another distribution case 7.
- information on the completion of the secondary film formation is stored in the host computer.
- the control number is transferred to the ID tag attached to distribution case 7.
- the substrates are housed in the distribution case 7 with the orientation of the substrates aligned with the notch mark 1 (or the film marks 3 and 6) as a reference.
- the substrate with the Cr light-shielding film housed in the distribution case 7 is carried into a defect inspection device for inspecting a defect of the secondary film, and a defect inspection is performed to acquire film information (surface information of the film).
- the film information is stored in the host computer for each defect position information, defect size (size is displayed by rank), defect type (pinhole, particle, etc.) force control number.
- the obtained film information is called secondary film information.
- the board for which the defect inspection has been completed is stored in another distribution case 8. At the same time, the management number is transferred to the ID tag attached to distribution case 8.
- the substrates are accommodated in the flow case 8 with the directions aligned with the notch mark 1 (or the film marks 3 and 6).
- the substrate with the Cr light-shielding film housed in the distribution case 8 is carried into a spin coating device, and a resist film is coated on the secondary film by a spin coating method, and the resist film is formed through beta and cooling.
- the substrate with the resist film (mask blank) is stored in another distribution case 9.
- information on the completion of the formation of the resist film is stored in the host computer.
- the management number is transferred to the ID tag attached to distribution case 9.
- the mask blank is stored in the distribution case 9 with the direction of the mask blank aligned with the notch mark 1 (or the film marks 3 and 6) as a reference.
- the substrate with a resist film (mask blank) stored in the distribution case 9 is carried into a defect inspection device, and a defect inspection is performed to obtain film information.
- film information defect position information, defect size (size is displayed by rank), and defect type (pinhole, particle, etc.) are stored in the host computer for each control number.
- the obtained film information is referred to as resist film information.
- the substrate on which the defect inspection has been completed is stored in another distribution case 10. this At the same time, the management number is transferred to the ID tag attached to the distribution case 10.
- the mask blanks are aligned with the notch mark 1 (or the film marks 3 and 6) as a reference and stored.
- the defect information data of each film is collated based on the defect whose position does not change. This is based on the fact that if the primary film, which is the lowermost layer, has a defect, the secondary film and the resist film, which are layers above the primary film, also have defects. It is determined whether the direction of the other film information is correct based on the reference.
- a force that allows the directions between the membrane information to match each other For example, when a certain flow case force is transferred to a substrate in another flow case, the direction of the substrate may be incorrectly stored in the flow case. In such a case, even if the film information matches, the film information and the orientation of the substrate do not match.
- the worker when taking the substrate in and out of the distribution case or the storage case, the worker refers to the notch marks and the film marks 3 and 6 as a reference for the orientation of the substrate, and sets the orientation in a predetermined direction. The substrate is taken in and out along.
- the orientation of the substrate in the mask blank manufacturing process (1)-(9) is kept constant, the discrepancy between the orientation of the substrate and the orientation of the film information is avoided, and the orientation between the film information is reduced. Therefore, the direction of the substrate and the directions of all the film information can be matched. In addition, since the coincidence of the film information is confirmed, even if the substrate is placed in the distribution case or the storage case in a wrong direction in the manufacturing process, it can be detected.
- the mask blanks are stored in the storage case 20, packed and delivered to the mask manufacturer.
- the storage case 20 will be described with reference to FIGS. 2A and 2B.
- Each of the storage cases 20 is attached with a unique case number 21.
- the storage case 20 includes a lid 22 and an outer box 23.
- the outer box 23 further includes an inner box 24 and a slot 25.
- the inner box 24 is housed in the outer box 23 and functions as a substrate holder.
- the slot 25 is a partition between the boards, but for convenience of explanation, a portion for storing the board between two adjacent slots 25 is provided. Sometimes called a slot.
- Figure 2B has slots for storing five boards.
- Each slot is assigned a slot number, and is called slot No. 1, slot No. 2,... Slot No. 5.
- a front display 26 indicating the direction of the yarn inner case 20 is described.
- the mask blank stored in the storage case 20 is identified by combining the case number and the slot number.
- the mask blank In order to make the reference point of the position information of the film information in each mask blank correspond to the reference point of the above-mentioned position information stored in the storage case 20, the mask blank has a corresponding point.
- the mask blanks are stored with the orientation of the mask blanks aligned based on the notch marks 1 (or the film marks 3 and 6).
- the direction of the substrates is stored with the notch mark 1 (or film marks 3 and 6) as the reference, and the mask blank is stored in the storage case.
- the mask blank and the direction information of the defect information can be accurately matched by storing the mask blank in the same orientation based on the notch mark 1 (or film mark 3, 6). It is possible to prevent a pattern defect at the time of manufacturing a mask.
- the blank film information including the primary film information, the secondary film information, and the resist film information is transferred to the destination mask mask for each mask blank.
- the blank film information can be provided by (a) attaching a printed matter on which the blank film information is printed to the storage case 20; (b) storing a storage medium, such as a flexible disk or CD-ROM, on which the blank film information data is recorded. And (c) transmitting blank film information data to a computer or the like of a destination mask maker via a data communication line.
- the blank film information itself is attached to the storage case 20 along with the correspondence with the slot number.
- the mask manufacturer sends the case number and slot number, and receives the information by receiving the corresponding blank film information.
- the primary film formation step, the primary film inspection step, and the secondary film formation step A cleaning step may be provided between them.
- the front and back of the mask blank are distinguished by the film mark 31 and the notch mark 1 as shown in FIGS. 3 (A) and (B).
- a film mark 31 is marked on the surface.
- a notch mark 1 is written on the back surface.
- Each piece of film information includes an X coordinate and a Y coordinate of an XY coordinate system, a size of a defect, and a type of the defect, which are predetermined on the film based on a predetermined direction of the substrate.
- FIG. 4 is an example of blank film information. It can be seen that the defect occurred at the same position in both the secondary film and the resist film at the place where the defect was present at the stage of the primary film.
- a mask blank production control system 50 includes a host computer 51, a cassette number'slot number assigning device 52 (hereinafter, referred to as an assigning device 52), a primary film forming device 53, and a primary film defect inspecting device 54.
- the cassette has a plurality of slots for accommodating substrates, and also has an ID tag.
- the cassette number assigned to the cassette is recorded in the ID tag.
- the substrate in order to put a substrate into the production line, the substrate is placed in a cassette, and the cassette number, slot number, and process flow are input from the input unit 521 by the application device 52.
- the process flow is composed of the process order, the name of the device used in the process, and the recipe number used in each device, and is given in units of cassettes according to the mask to be produced.
- the substrate is specified by the position in the process, the cassette number, and the slot.
- the assigning device 52 writes the cassette number in the ID tag of the cassette, and transmits the cassette number, the slot number, and the process flow to the host computer 51 by the data transmitting / receiving unit 522.
- the host computer 51 stores the cassette number, slot number, and process flow in the process flow storage unit 512 in association with each other.
- cassette A When the cassette for which the cassette number has been input by the application device 52 (hereinafter, this cassette is referred to as cassette A) is set in the loader port 531 of the primary film forming device 53, the ID of the cassette A The tag number is also read from the cassette number and is notified to the host computer 51 by the data transmitting / receiving unit 532.
- host computer 51 transmits the cassette number of cassette A, the slot number, and the recipe number of sputter to primary film forming apparatus 53.
- the recipe number may be immediately before the start of the operation of the sputtering apparatus.
- the recipe number / sputter condition matching unit 533 checks the sputter condition corresponding to the recipe number, and accumulates the matched sputter condition in the sputter condition accumulation unit 534. I do.
- the sputtering condition control unit 535 controls the sputtering device 536 to perform a sputtering process.
- the sputtering apparatus 536 extracts the substrate from the cassette A and starts the sputtering process. In the process of sputter processing, the results of sputtering are collected and associated with the slot number.
- the substrate on which the sputtering process has been completed enters a slot of another cassette (hereinafter referred to as cassette B) prepared in advance at unloader port 538.
- cassette B a cassette
- the slot number, spatter record, and unloader slot number collection unit 537 collect the slot number in cassette A, the associated spatter record, and the slot number in cassette B.
- the data is transmitted to the host computer 51 using the data transmission / reception unit 532.
- the collection unit 537 notifies the host computer 51 of the fact together with the cassette number of the cassette B.
- the host computer 51 specifies the next step in the sequence of the cassette number B, the cassette number A, and the process flow, and instructs a cassette transport unit (not shown) of a transport destination.
- the host computer 51 transmits the cassette number of the cassette B and the sputter recipe number transmitted to the primary film forming apparatus 53 to the primary film defect inspection apparatus 54.
- primary film defect inspection apparatus 54 receives these at data transmission / reception section 541 and passes them to cassette number / recipe number verification section 542.
- the cassette number recipe number collating unit 542 collates the recipe number corresponding to the cassette number that has also read the ID tag strength of the cassette.
- the cassette number is that of the cassette B, the recipe number obtained when the substrate contained in the cassette B is subjected to the sputtering process is obtained.
- the defect inspection condition accumulation unit 544 stores in advance a correspondence relationship between a recipe number and an inspection condition to be performed on a film formed under the recipe condition indicated by the recipe number. When receiving the recipe number from the recipe number collating unit 542, it outputs the inspection conditions to be performed.
- the defect inspection condition control unit 545 controls the defect inspection device 546 to perform the inspection.
- the defect inspection device 546 outputs the inspection result as defect inspection information.
- the inspected substrate is stored in a slot of another cassette (hereinafter referred to as cassette C) set in the unloader port 547 in advance.
- the unloader cassette number and unloader slot number assigning section 548 assigns a force set number to the cassette C, as well as the cassette number of the cassette C, the slot number of the cassette C, and the defect of the substrate stored in the slot.
- the data is transmitted to the host computer 51 using the data transmitting / receiving unit 541 in association with the test information.
- the host computer 51 stores the transmitted information in the information storage unit 513 in association with the sputtering result obtained by the primary film forming apparatus 53 and the like.
- the secondary film deposition device 55 and the secondary film inspection device 56 are different from the primary film deposition device 53 and the primary film inspection device 54, respectively, due to the difference in the type of film to be deposited. Only the differences described above have no significant difference in the configuration elements and operations, and therefore description thereof is omitted. The same applies to the resist film forming apparatus 57 and the resist film defect inspection apparatus 58 shown in FIG.
- the defect information matching unit 514 generates the primary film information, the secondary film information, and the resist film information described in the first embodiment, These are collated with each other to generate blank film information as shown in FIG.
- a mask manufacturing support system 110 includes a mask blank factory 111 It comprises a mask factory 112 for manufacturing a mask based on a mask blank manufactured at a stap blank factory 111, and a data communication line 113 connecting the two factories.
- the mask blank field 111 includes the host computer 51 and the server 114.
- the mask blank manufactured at the mask blank factory 111 is stored in the storage case 10 described above and delivered to the mask factory 112.
- the host computer 51 is the host computer 51 of the mask blank production line control system 50 described above.
- the server 114 receives necessary information from the host computer 51 and provides the information to a computer at a remote location of the mask factory 112 via the Internet 113.
- the host computer 51 stores blank film information of a master blank manufactured in advance.
- the blank film information specifies the directionality based on the notch mark or film mark, and the reference point is guaranteed.
- the manufactured master blank is stored in the storage case 10 with the direction of the mask blank aligned based on the notch mark or the film mark, and delivered to the mask factory 112.
- a case number is attached to the storage case 10.
- the attachment of the case number is not limited to a visible state such as printing, but may be a machine code readable state such as a bar code, a magnetic recording medium, or an IC chip.
- the mask drawing / developing process in the mask factory 112 will be described.
- the worker at the mask factory 112 obtains the case number from the storage case 10 by visual or machine reading, and then uses a data communication device such as a computer to transmit the case number to the Internet or other data communication device.
- the data is transmitted to the server 114 via the line 113.
- the server 114 returns blank film information of the mask blank stored in each slot of the storage case of the case number (step S121).
- the mask factory 112 receiving the blank film information compares the blank film information with the mask pattern of the mask to be manufactured (step S122). As described above, at this time, the reference point of the position information in the mask blank corresponds to the reference point of the position information in the blank film information. Alternatively, at this time, the reference point of the position information in the mask blank corresponds to the reference point of the position information of the mask pattern data.
- the mask pattern has a dense pattern forming region 143 having a high density and a sparse pattern forming region 144 having a low density.
- these notch marks and film marks are used as a guide of the direction of the substrate so that they are always stored in the same direction when they are taken in and out of a container such as a distribution case, a cassette, or a storage case. From this, the directions of the primary film information, the secondary film information, and the resist film information all match the direction of the substrate.
- the number of films in the film information may be single!
- the present invention can be applied to defect information obtained by observing only the surface of a mask blank immediately before shipment from a mask blank factory, that is, only on the surface film, as in the prior art. Even in this case, there is an effect of ensuring that the direction of the defect information matches the direction of the substrate.
- a defect is a surface morphology that impairs the function of a transfer mask or causes a defective transfer mask. Or, it refers to optical characteristics. Specifically, a particle-like defect and a pinhole-like defect can be exemplified.
- the mask blank information is acquired by forming the primary film, the secondary film, and the resist film on a glass substrate and storing the mask blank in a case. This is performed using an inspection process performed in parallel.
- the substrate inspection is not shown in the example of FIG. 15, the substrate information can be obtained by preparing a glass substrate which has been subjected to a processing such as mirror polishing and performing the substrate inspection prior to the primary film formation.
- each time a thin film of the primary film, the secondary film, and the resist film is formed a defect inspection of the thin film is performed. Generates film information of the primary film, film information of the secondary film and film information of the resist film according to the inspection result, and records and saves this information in the host computer corresponding to each substrate (each mask blank). I do. Thereafter, the substrate information and film information recorded and stored in the host computer are collated, and mask blank information is generated collectively.
- the mask blank information is generated by integrating a plurality of pieces of surface information such as substrate information, primary film information, secondary film information, and resist film information.
- the surface information constituting the mask blank information is information on different sections of the same mask blank. For this reason, the mask blank information is information that three-dimensionally indicates the state inside the mask blank.
- the mask blank information is provided to the mask maker in association with each mask blank individual manufactured through the mask blank manufacturing process and stored in the storage case 20.
- the above information is provided from the mask blank maker to the mask maker using paper documents, electronic media, magnetic media, communication lines, and the like.
- FIG. 15 shows the structure of the film in the manufacturing process corresponding to each step and the form of the substrate with the film.
- the upper part of FIG. 15 shows the film information generated in the defect inspection process. In the following, the method of acquiring and storing film information will be described in detail along the flow of the manufacturing process of the lower master blank.
- a notch mark 1 is formed by obliquely cross-sectioning three surfaces of a main surface and two end surfaces forming the corner at a corner portion of a glass substrate. It has a surface shape formed by being cut into a shape. It should be noted that the type of glass (the type of glass) constituting the glass substrate can also be used for discrimination based on the number of notch marks formed and the formation position.
- notch mark 1 serves as a reference mark for specifying the directionality of the substrate and a role as a reference point in film information obtained in a defect inspection process described later. Having.
- the surface of the glass substrate is polished and polished to obtain desired surface roughness and flatness. Further, the glass substrate is washed to remove the abrasive used in the polishing process.
- the glass substrate is stored in the in-process distribution cassette 2 having the ID tag 2 '.
- this cassette is referred to as distribution cassette 2.
- the ID tag is an information management unit that can write or read information on the distribution cassette and the substrates or mask blanks stored in the distribution cassette.
- An ID tag is a medium that can record and hold information. For example, an IC tag can be used.
- a management number for managing each substrate or each mask blank stored in the distribution cassette for example, an identification number can be given to the ID tag and held.
- the direction of the cassette that is, front, rear, left, and right can be distinguished.
- a plurality of vertically extending grooves are formed at predetermined intervals on two opposing inner walls of the distribution cassette 2 so that a glass substrate or a mask blank can be stored in each groove.
- a single glass substrate or a mask blank is stored in each of the plurality of grooves in the same direction.
- the notch marks 1 formed on the glass substrate are stored in a predetermined relationship with respect to a predetermined position of the distribution cassette 2.
- a plurality of glass substrates or mask blanks in a cassette are arranged and stored in the same direction.
- the notch marks 1 of a plurality of glass substrates are stored in front of the distribution cassette 2 so as to be located at a specific position in front of the glass substrates.
- the substrate surface on which the notch mark 1 is formed is arranged toward the front surface of the cassette, and the plurality of stored glass substrates are viewed from the front surface of the cassette. Notch marks are stored in the same positional relationship.
- a control number for managing each board is assigned to the ID tag 2 'attached to the distribution cassette 2.
- the host computer associates the management number assigned to the ID tag with the order of the manufacturing process in which each substrate is to be processed and the manufacturing conditions used in each process.
- the host computer has a function of collecting information (for example, substrate information, film information, etc.) of each apparatus in the manufacturing process, and recording and storing the information for each management number.
- the host computer that performs production control assigns a management number for managing each of the distribution cassette or each of the stored substrates to each of the ID tags 2 'attached to each of the distribution cassettes. And record.
- the host computer associates the management number assigned to the ID tag 2 'with the order of a plurality of manufacturing processes and inspection processes for processing each substrate, the manufacturing conditions set in those processes, and the like.
- the host computer may store information (for example, substrate information, each thin film information) for each process acquired in the plurality of processes. It has a function to collect, record, and save film information generated in the film inspection process, manufacturing conditions and manufacturing recipes used in each thin film forming process for each substrate.
- the glass substrates stored in the distribution cassette 2 are taken out one by one, and the notch mark is formed so that the substrate surface on which the notch mark 1 is formed faces upward.
- the substrate is placed on the holder of the sputtering apparatus so as to face the S sputtering target.
- a halftone film as a phase shift film is formed on the glass substrate surface by a reactive sputtering method. I do.
- the film is formed on the main surface of the glass substrate facing (opposite to) the main surface on which the notch mark 1 is formed.
- a phase shift film which is a halftone film containing MoSiN, is formed on the glass substrate surface.
- the holder for the substrate is provided with shielding means so that the MoSiN halftone film is not formed in a predetermined region of the peripheral portion of the main surface of the substrate.
- the type of the thin film formed on the glass substrate can be determined from the difference in the shape of the film mark 3 and the position and arrangement of the film mark.
- a film mark used for a halftone film is used.
- the film mark 3 can be used as a reference mark for specifying the directionality of the substrate or a reference point in film information acquired in an inspection process described later, like the notch mark 1 described above.
- the film mark 31 As a specific example of the film mark 31, as shown in Fig. 16B, it can be provided at two corners on the main surface opposite to the side where the notch mark 1 is formed, as shown in the figure. .
- the substrate with the MoSiN halftone film in which the MoSiN film is formed on the glass substrate surface by the sputtering device is housed in the distribution cassette 4 different from the distribution cassette 2.
- the distribution cassette 4 has a plurality of substrates with halftone films based on the notch mark 1 or the film mark 3. Are stored in the same direction.
- the film marks 3 formed on the substrate are stored at a predetermined position of the distribution cassette 4 so as to be arranged in a predetermined relationship.
- the film marks 3 of the plurality of substrates with halftone films are stored so as to be at a specific position on the rear side of the flow force set 4 (below the flow cassette in FIG. 15). Have been.
- the film mark 3 is formed on the basis of the front surface provided to the distribution cassette 4, and the substrate surface on the medium side faces the cassette front surface, that is, the substrate on which the notch mark 1 is formed.
- the substrates are arranged so that the surface faces the front of the cassette, and the film marks 3 of the plurality of stored substrates are in the same positional relationship (downward with respect to the distribution cassette in FIG. 15), taking into account the force of the front of the cassette. It is stored in such a way.
- the information of the management number assigned to the ID tag 2 ' is transferred to the ID tag 4' attached to the distribution cassette 4.
- the management number transferred to the ID tag 4 ' may be the same as the management number assigned to the ID tag 2', or the host computer may assign a new management number. In the latter case, the management number assigned to the ID tag 2 'and the management number newly assigned to the ID tag 4' are stored in the host computer in association with each other.
- This step includes a step of acquiring the thin film information of the primary film, and a step of recording the acquired film information on the information storage medium and storing the information.
- the substrate with the halftone film stored in the distribution cassette 4 is taken out, and the substrate is placed on a defect inspection device for inspecting a defect of the primary film (MoSiN halftone film).
- the substrate is placed on the holder with the surface on which the notch mark 1 is formed facing downward and the surface on which the film mark 3 is formed facing upward.
- the surface of the film is scanned using a primary film defect inspection apparatus, and film information on the primary film is obtained.
- the film information is state information relating to the state of the film, and is surface information of the film obtained by scanning the surface of the film.
- the film information includes surface morphology information and optical property information.
- the acquired film information is configured to be projected on a plane and graspable as two-dimensional surface information.
- Defect inspection information for each defect includes position information (for example, X coordinate and Y coordinate in a plane coordinate system), a defect size, and a defect type that may cause a pattern defect in a mask manufacturing process.
- the result is stored in the host computer for each management number.
- the size of the defect may be stored as it is as a measurement value indicating the size of the defect such as a diameter, or a plurality of ranks for classifying the size of the defect may be determined in advance.
- the corresponding rank may be stored as the defect size.
- the types of the defects can be classified and stored as convex shapes, concave shapes, and other defects.
- Examples of the shape of the projection include a pinhole-shaped defect, and examples of the shape of the depression include a particle-shaped defect.
- the particle-like defect refers to a defect in which a foreign substance (eg, a granular substance) is attached on or in the film, and the pinhole-like defect is a substance in which the foreign substance attached to the film is dropped. This refers to defects in the state of traces and missing films.
- film loss There are two types of film loss: a state in which the state of the underlayer of the film can be completely confirmed, and a state in which the state of the underlayer of the film cannot be confirmed, and a locally thin film.
- the position information is obtained by calculating the center of the glass substrate main surface from the size of the glass substrate based on the notch mark 1 and setting this as a reference point (O), passing through the reference point and being parallel to each side of the glass substrate.
- the X- and Y-coordinates of each defect in the XY coordinate system with the virtual line as the virtual X and Y axes are stored.
- the above-described defect position information is obtained by calculating the center of the main surface of the glass substrate based on the size of the glass substrate, for example, the length of the side, based on the position of the notch mark 1. Is defined as a reference point (O), and then, using the reference point (O) as the origin, an orthogonal plane coordinate system (XY coordinate system) along the sides of the orthogonal glass substrate is defined. Finally, the two-dimensional XY In the coordinate system, the X coordinate position and Y coordinate position of each defect are calculated, and are stored as the X coordinate and Y coordinate values.
- the obtained thin film information is referred to as primary film information.
- the substrate with the neutral tone film on which the defect inspection has been completed is stored in a distribution cassette 5 different from the distribution cassette 4.
- the distribution cassette 5 has a plurality of sheets based on the notch mark 1 or the membrane mark 3.
- the substrate with the halftone film is stored in the same direction.
- the film marks 3 formed on the substrate are stored in a predetermined relationship in the distribution cassette 5 so as to be arranged in a predetermined relationship.
- the film cassette 3 of a plurality of substrates with a halftone film is accommodated in the distribution cassette 5 so as to be located at a specific position on the rear side (below the distribution cassette in FIG. 15). Has been delivered.
- the storage method is managed so that the storage directions of a plurality of substrates are aligned in a predetermined manner. Therefore, the directionality, coordinate system, and reference point of the surface information acquired in the inspection process are used for the inspection. The information is unified among the plurality of boards thus obtained.
- the storage method is controlled so that the storage directions of the plurality of substrates are aligned in a predetermined manner, so that the directionality (direction) of the substrate to be processed is maintained in the next step. .
- the information of the management number given to the ID tag 4 ' is transferred to the ID tag 5' of the distribution cassette 5.
- the management number transferred to the ID tag 5 ' may be the same as the management number assigned to the ID tag 4', or a new management number may be assigned.
- the substrate with the non-tone film stored in the distribution cassette 5 is placed on the holder of the in-line type sputtering apparatus. At this time, the substrate is placed on the holder with the surface of the substrate on which the notch mark 1 is formed facing upward and the surface of the substrate on which the film mark 3 is formed facing downward.
- a chromium (Cr) sputtering target argon gas or argon gas was used.
- a light-shielding film containing Cr as a secondary film (hereinafter referred to as a Cr light-shielding film) is formed on a MoSiN halftone film as a primary film by a reactive sputtering method. ) Is formed.
- a shielding means is provided on the substrate holder. For this reason, a predetermined region where the Cr light shielding film is not formed is formed on the MoSiN halftone film, and the film mark 6 is provided.
- the film type can be determined from the shape of the film mark 6. In the present embodiment, a film mark provided for a Cr light shielding film is used.
- the film mark 6 formed on the Cr light-shielding film is used for specifying the direction of the substrate, like the notch mark 1 formed on the glass substrate and the film mark 3 formed on the soft tone film. It can be used as a reference mark or a reference point in film information obtained in a defect inspection process described later.
- the MoSiN halftone film is covered by the Cr light shielding film. Therefore, it is difficult to see the film mark 3 from the surface of the substrate on which the film is formed. However, the film mark 3 provided on the halftone film can be confirmed through the glass substrate from the main surface on the opposite side of the substrate. When the direction of the substrate is to be specified by the film mark 3, it can be used from the side of the substrate where the film is not formed.
- the substrate with the Cr light-shielding film formed on the MoSiN halftone film by the in-line type sputtering device is housed in the distribution cassette 7 different from the distribution cassette 5.
- a plurality of base substrates with Cr light-shielding films are stored with the directions of the substrates aligned with reference to the film marks 6.
- the film marks 6 formed on the substrate are stored at a predetermined position of the distribution cassette 7 so as to be arranged in a predetermined relationship.
- the distribution cassette 7 is provided with film marks of a plurality of substrates with Cr light-shielding films.
- information on the completion of the secondary film formation is stored in the host computer for each management number.
- the information of the management number assigned to the ID tag 5 described above is transferred to the ID tag 7 attached to the distribution set 7.
- the management number transferred to the ID tag 7 ' may be the same as the management number assigned to the ID tag 5', or a new management number may be assigned.
- the substrate with a film in which the primary film and the secondary film are laminated on the substrate is housed in the cassette 7 and transported to the next step.
- This step is similar to the primary film inspection step.
- This step includes a step of acquiring thin film information of the secondary film, and a step of recording thin film information for recording and storing the acquired film information on the information storage medium.
- the substrate with the Cr light-shielding film housed in the distribution cassette 7 is set on a substrate mounting stage of an inspection device for detecting a defect of the secondary film (Cr light-shielding film).
- the surface on which the notch mark 1 is formed faces downward and the surface on which the film mark 6 is formed faces upward, and the notch mark 1 is moved to a predetermined position with respect to the mounting stage.
- the defect inspection of the secondary film is performed in the same manner as the defect inspection of the primary film described above, and the film information of the secondary film is obtained.
- the surface of the film is scanned using a secondary film defect inspection device, and film information on the secondary film is obtained.
- the film information is state information relating to the state of the film, and is surface information of the film obtained by scanning the surface of the film.
- the film information includes surface morphology information and optical property information.
- the acquired film information is configured to be projected on a plane and graspable as two-dimensional surface information.
- Defect detection equipment determines position information (for example, X coordinate and Y coordinate in a plane coordinate system) of a defect that may cause a pattern defect in a mask manufacturing process, a defect size, and a defect type. And the result is stored in the host computer for each management number [0271]
- the size of a defect can be stored separately for each defect size. For example, it may be displayed for each predetermined size rank.
- the types of defects can be classified and stored as a convex shape, a concave shape, and other defects.
- Examples of the shape of the projection include a pinhole-shaped defect, and examples of the shape of the depression include a particle-shaped defect.
- the particle-like defect refers to a defect in which a foreign substance (eg, a granular substance) is attached on or in the film, and the pinhole-like defect is a substance in which the foreign substance attached to the film is dropped. This refers to defects in the state of traces and missing films.
- film loss There are two types of film loss: a state in which the state of the underlayer of the film can be completely confirmed, and a state in which the state of the underlayer of the film cannot be confirmed, and a locally thin film.
- the position information is obtained by calculating the center of the main surface of the glass substrate from the size of the glass substrate based on the notch mark 1 and setting this as a reference point (O), passing through the reference point and parallel to each side of the glass substrate.
- the X- and Y-coordinates of each defect in the XY coordinate system with the virtual line as the virtual X and Y axes are stored.
- the position information of the above-described defect is first determined based on the size of the glass substrate, for example, the length of the side, based on the position of the notch mark 1, The center is calculated and defined as the reference point (O). Next, with this reference point (O) as the origin, a plane rectangular coordinate system (XY coordinate system) along the sides of the orthogonal glass substrate is defined. Then, in the two-dimensional XY coordinate system, the X coordinate position and the Y coordinate position of each defect are calculated, and are stored as the X coordinate and the Y coordinate values. The obtained film information is called secondary film information.
- the substrate with the Cr light-shielding film for which the defect inspection has been completed is housed in a distribution cassette 8 different from the distribution cassette 7.
- a plurality of substrates with a Cr light-shielding film are stored in a direction aligned with the film mark 6.
- the film marks 6 formed on the substrate are stored at a predetermined position of the distribution cassette 8 so as to be arranged in a predetermined relationship.
- the distribution cassette 8 has a film mark of a plurality of substrates with Cr light-shielding films.
- the surface on which the membrane mark 6 is formed faces the opposite side of the front surface of the cassette, that is, the surface on which the notch mark 1 is formed is the cassette. It is arranged toward the front. In view of the cassette front force, the film marks 6 on the plurality of stored substrates are aligned and stored so as to have the same positional relationship (upward with respect to the distribution cassette in FIG. 15).
- the storage method is controlled so that the storage directions of a plurality of substrates are aligned in a predetermined manner. Therefore, the directionality, coordinate system, and reference point of the surface information acquired in the inspection process are used for the inspection. The information is unified among the plurality of boards thus obtained.
- the storage method is managed so that the storage directions of the plurality of substrates are aligned in a predetermined manner, so that the directionality (direction) of the substrate to be processed is maintained in the next step. .
- Information on the management number given to the ID tag 7 ' is transferred to the ID tag 8' attached to the distribution cassette 8.
- the management number transferred to the ID tag 8 ' may be the same as the management number assigned to the ID tag 7', or a new management number may be assigned.
- the substrate with the Cr light-shielding film housed in the distribution cassette 8 is carried into a spin coating device, and a resist film is coated on the secondary film by a spin coating method, and the resist film is formed through beta and cooling.
- the produced mask blank is stored in a distribution cassette 9 different from the distribution cassette 8.
- a plurality of mask blanks are stored with the direction of the mask blanks aligned based on the film mark 6.
- the film marks 6 formed on the substrate are stored at a predetermined position of the distribution cassette 9 so as to be arranged in a predetermined relationship.
- a plurality of mask blank film marks 6 are stored in the distribution cassette 9 so as to be located at a specific position on the rear side (above the distribution cassette in FIG. 15).
- the surface on which the membrane mark 6 is formed faces the opposite side of the cassette front surface, that is, the surface on which the notch mark 1 is formed faces the cassette front surface.
- the film marks 6 of the plurality of stored substrates are stored in the same positional relationship (upward relative to the distribution cassette in FIG. 15) and stored as viewed from the front face of the cassette.
- the information of the management number assigned to the ID tag 8 ' is transferred to the ID tag 9' attached to the distribution case 9.
- the management number transferred to the ID tag 9 ' may be the same as the management number assigned to the ID tag 8', or a new management number may be assigned.
- This step is similar to the primary film inspection step and the secondary film inspection step.
- This step includes a step of acquiring thin film information of the resist film, and a step of recording the acquired film information on an information storage medium and storing the information.
- the substrate with a resist film (mask blank) stored in the distribution cassette 9 is set on a stage on which a substrate of a defect inspection device for inspecting a defect of the resist film is placed.
- the stage is placed on the stage with the notch mark 1 formed thereon facing downward and the film mark 6 formed surface facing upward. Also, set so that the notch mark 1 is located at a predetermined position with respect to the stage.
- a defect inspection of the resist film is performed to acquire film information of the resist film.
- the surface of the film is scanned using a resist film defect inspection apparatus, and film information on the resist film is obtained.
- the film information is state information relating to the state of the film, and is surface information of the film obtained by scanning the surface of the film.
- the film information includes surface morphology information and optical property information.
- the acquired film information is configured to be projected on a plane and graspable as two-dimensional surface information.
- the defect inspection apparatus determines position information (for example, X coordinate and Y coordinate in a plane coordinate system) of a defect that may cause a pattern defect in a mask manufacturing process, a defect size, and a defect type. And the result is stored in the host computer for each management number [0297]
- the position information is obtained by calculating the center of the main surface of the glass substrate from the size of the glass substrate based on the notch mark 1 and using this as a reference point (O), passing through the reference point and being parallel to each side of the glass substrate.
- the X- and Y-coordinates of each defect in the XY coordinate system with the virtual line as the virtual X and Y axes are stored.
- the position information of the above-described defect is first determined based on the position of the notch mark 1 and the size of the glass substrate (side length). ), The center of the main surface of the glass substrate is calculated and defined as a reference point (O). Then, using this reference point (o) as an origin, an orthogonal coordinate system ( XY coordinate system), and finally, in this XY coordinate system, the X coordinate position and Y coordinate position of each defect are calculated and stored with the X coordinate and Y coordinate values.
- the obtained film information is referred to as resist film film information.
- the mask blank on which the defect inspection has been completed is stored in a distribution cassette 10 different from the distribution cassette 9.
- a plurality of mask blanks are stored in the distribution cassette 10 with the mask blanks aligned in the direction based on the membrane mark 6.
- the film marks 6 formed on the substrate are housed at a predetermined position of the distribution cassette 10 so as to be arranged in a predetermined relationship.
- a plurality of mask blank film marks 6 are accommodated in the distribution cassette 10 so as to be located at a specific position on the rear side (above the distribution cassette in Fig. 15). That is, with the cassette front of the distribution cassette 10 as a reference, the surface on which the membrane mark 6 is formed is directed in the opposite direction to the front of the cassette, that is, the surface on which the notch mark 1 is formed is directed toward the front of the cassette.
- the mask blanks are arranged and, when viewed from the front of the cassette, stored and aligned so that the film marks 6 of the plurality of stored substrates have the same positional relationship (upward with respect to the distribution cassette in FIG. 15). I have.
- the storage method is controlled so that the storage directions of a plurality of mask blanks are aligned in a predetermined manner. Therefore, the directionality, coordinate system, and reference point of the surface information acquired in the inspection process are determined by the inspection. The information is unified among the plurality of provided mask blanks.
- the storing method is controlled so that the storing directions of a plurality of mask blanks are aligned in a predetermined manner. Therefore, the directionality (direction) of the mask blank is maintained in the next step.
- Information of the management number assigned to the ID tag 9 ' is transferred to the ID tag 10' attached to the distribution case 10. As described above, the management number transferred to the ID tag 10 'may be the same as the management number assigned to the ID tag 9', or a new management number may be assigned.
- the obtained film information is collated with each other.
- the substrate information can be collated with the film information.
- the film information relating to the mask blank to be collated can be specified by the management number.
- the film information is obtained as surface information.
- the reference point of the position in the surface information is obtained with a predetermined relationship with a notch mark or a film mark provided as a reference mark provided on the substrate or the mask blank. Also.
- the information is obtained by aligning all the substrates or mask blanks in the same direction.
- the position on the substrate does not change before and after the film forming process, that is, the film information of each film can be collated based on the shape at the same position.
- the directionality of other film information that is, whether the reference point in the position information and the XY coordinate system match each other can be checked and confirmed based on the primary film information.
- the primary film which is the lowermost film
- a defect also occurs in the secondary film, which is a film above the primary film, and the resist film. It is possible to determine whether the direction of the other film information is correct based on the reference.
- FIG. 17 shows an example in which primary film information, secondary film information, and resist film information are collated.
- the defects detected in common with the film information of the primary film, the film information of the secondary film, and the film information of the resist film are used as a reference.
- the position coordinates on the substrate do not change, This is an example in which the film information of the secondary film and the resist film is collated based on the location where the mouth, ⁇ , and X overlap).
- notch marks on a plurality of substrates and mask blanks are directed toward the front side of the distribution cassette.
- the substrates and mask blanks must be stored so that the notches are aligned at predetermined positions when viewed from the front of the cassette.
- the substrate and the mask blank are stored such that the membrane mark 3 is arranged at a lower position in the distribution cassette and the membrane mark 6 is arranged at an upper position in the distribution case.
- the notch mark or the film mark is placed on a stage so as to face a predetermined direction. Place the mark so that it is at the specified position and perform the specified inspection!
- the reference point and XY coordinate system of the mask blank are matched, and the reference point and XY coordinate of this mask blank are further matched.
- the system, the reference point of the film information of each film, and the XY coordinate system can be matched.
- the mask blank information is configured such that the plane coordinates of the position information included in the film information and the substrate information and the reference point of the position can be associated with each other. It can be recognized as internal three-dimensional information in the body.
- the mask blanks are stored in the storage case 20, packed and delivered to the mask manufacturer.
- the storage case 20 will be described with reference to Figs. 18A and 18B.
- Each of the storage cases 20 is attached with a unique case number 21.
- the storage case 20 works together with the lid 22 and the outer box 23, and the inner box 24 is further stored in the outer box 23.
- a plurality of partitions 25 are formed from above to below, and a plurality of grooves are formed at predetermined intervals between the slots 25 so that mask blanks can be stored in these grooves! /
- the slot 25 is a force acting as a partition between mask blanks.
- a groove portion for storing a substrate between two adjacent slots 25 may be referred to as a slot.
- FIG. 18B has five grooves, or five slots, for storing five substrates.
- a slot number is assigned to each groove, and these are called slot No. 1, slot No. 2, ... slot No. 5, respectively.
- the notch mark 1 formed on the mask blank is placed at a specific position on the front display 26 side in each groove (slot No. 1, slot No. 2, ... slot No. 5). Further, the film mark 3 is stored and packed so that the film mark 3 is disposed below the storage case and the film mark 6 is disposed above the storage case.
- the notch mark 1 formed on the mask blank in each groove is arranged at a specific position on the front display 26 side, and the film mark 3 is placed on the storage case.
- the film mark 6 by storing the film mark 6 so that the film mark 6 is arranged above the storage case, the reference point of each mask blank, the XY coordinate system, and the reference point of the film information or substrate information of each film The XY coordinate system can be matched.
- the mask blank individual and the mask blank information relating to the mask blank individual can be accurately associated with each other, and a pattern defect during mask production can be prevented.
- the mask blank individual information including the primary film information, the secondary film information, and the resist film information stored in the host computer for each management number is stored in the case.
- the mask blank is provided to the mask manufacturer together with the plurality of mask blanks stored in the storage case in association with the mask blank specified by the number and the slot number.
- the method of providing the mask blank information includes (a) attaching a printed matter on which information is printed to the storage case 20, and (b) storing a recording medium such as a flexible disk or a CD-ROM in which the information data is recorded. And (c) transmitting information data to a mask maker computer or the like via a data communication line.
- the information itself is attached to the storage case 20 together with the correspondence with the slot number.
- the mask maker also transmits the case number and the slot number, and receives the information by receiving the corresponding information.
- the information may be mapped in such a manner as to visually identify how each defect is arranged, or may be the type of each defect, the size of the defect, and the number of defects. It may be a data sheet of position information (X coordinate, Y coordinate). In general, information is provided to the mask manufacturer for each film information of each film.However, as shown in Fig. 17, the film information of each film may be provided to the mask manufacturer as one defect map! ,.
- the position information in the substrate information or the film information acquired as the surface information is obtained by calculating the center of the main surface of the substrate based on the notch mark 1 in this embodiment.
- This is defined as a reference point (O), which is represented by the X and Y coordinates of each defect in the XY coordinate system passing through the reference point.
- the notch mark 1 is also stored in the mask blank stored in the storage case. Since the reference point and the coordinate system in the mask blank stored in the storage case and the reference point and the coordinate system in the position information correspond to each other because they are aligned and stored at a specific position with respect to the case. It is provided to the mask manufacturer in an understandable or consistent manner.
- mask blank information corresponding to each individual mask blank is provided to the mask maker.
- the provided mask blank is provided to the mask maker in such a manner that the reference point or coordinate system of the position corresponds to the reference point or coordinate system of the position of the blank film information.
- the mask maker uses the means for identifying the mask blanks indirectly assigned to the mask blanks, such as the case number, slot number, control number, and control symbol, to individually provide the provided mask blank.
- the provided mask blank and the mask blank information can be identified, and the provided mask blank and the mask blank information can be collated via the reference point and the coordinate system having the predetermined relationship. Also, The state such as the surface morphology of each mask blank can be accurately grasped through a reference point and a coordinate system having a predetermined relationship.
- an area on a mask blank where a predetermined transfer pattern (mask pattern) is to be formed can be appropriately specified as desired. Therefore, it is possible to suppress the pattern formation failure of the pattern to be formed.
- a mask maker can specify a region where a mask pattern including a transfer pattern is to be formed on the provided mask blank, and perform pattern junging on the thin film formed on the mask blank to produce a transfer mask.
- the mask production support system 110 of the present invention will be described with reference to FIG. 19 as a specific example of the method for providing information via the data communication line described in (c) above.
- a mask manufacturing support system 110 connects a mask blank factory 111, a mask factory 112 that manufactures a mask based on a mask blank manufactured in the master blank factory 111, and the two factories.
- Data communication line 113 Further, the mask blank field 111 includes the host computer 51 and the server 114.
- the mask blank manufactured in the mask blank factory 111 is housed in the storage case 10 described above and delivered to the mask factory 112.
- the host computer 51 is the host computer 51 of the mask blank production line control system 50 described above.
- the server 114 receives necessary information (such as film information) from the host computer 51, and stores the case information specifying the mask blank delivered to the mask factory 112, the slot number, and the blank film information in association with each other. Then, predetermined information is provided to a computer at a remote location of the mask factory 112 via the Internet 113.
- necessary information such as film information
- the host computer 51 may store the mask blank information such as the case number specifying the mask blank delivered to the mask factory 112, the slot number, and the film information in association with each other.
- the case number After obtaining the case number from the storage case 10 by using the data communication device such as a computer, the case number is transmitted to the server 114 via the data communication line 113 such as the Internet.
- the server 114 replies the mask blank film information stored in each slot of the storage case with the case number in association with the case number and the slot number (step S121).
- a database indicating the correspondence between the case numbers and the information on the mask blanks stored in the grooves of the storage cases of the case numbers is installed on the server 114, and the case numbers input from the mask factory 112 side. It is also possible to return mask blank information such as film information according to the situation.
- the mask blank has a cross section as shown in Fig. 21A, and a plurality of layers of a primary film (halftone film), a secondary film (light shielding film), and a resist film are formed on a glass substrate. It is in a state of being laminated and formed into a film.
- the mask factory 112 that has received the film information collates the obtained film information with the mask pattern data of the mask to be manufactured (step S122).
- the reference point and XY coordinate system of the mask blank correspond to the reference point and XY coordinate system of the position information in the film information, and the film information is compared with the mask pattern data. By doing so, the arrangement of the mask pattern with respect to the mask blank can be determined.
- the mask factory 112 receives the mask blank information 141 from the mask blank factory 111 and intends to draw a mask pattern 142.
- the mask blank information 141 includes primary film information, secondary film information, and resist film information.
- Examples of the mask having the region 144 include a mask for manufacturing a system LSI.
- the mask fabrication support method of the present invention is particularly effective.
- the pattern drawing position is adjusted and determined (step S123).
- a pattern is drawn on the resist film according to the determined pattern drawing position, and the image is formed, thereby obtaining a mask having a mask pattern (transfer pattern) formed on a glass substrate (step S124).
- the mask manufactured through steps S121 to S124 as described above is arranged in a pinhole, a particle mask, or a sparse pattern formation region that may cause a pattern defect in the mask blank. Therefore, it is possible to suppress the formation failure of the mask pattern.
- the host computer 51 transmits information on each process from each device (for example, information such as substrate information and film information generated in each inspection process, manufacturing conditions, and recipes).
- information on each process from each device for example, information such as substrate information and film information generated in each inspection process, manufacturing conditions, and recipes.
- An example of the mask blank production line control system 50 that collects the data of (1) will be described in detail with reference to FIG.
- the mask blank production control system 50 includes a host computer 51, a cassette number'slot number assigning device 52 (hereinafter referred to as an assigning device 52), and a primary film deposition.
- An apparatus 53 a primary film defect inspection device 54, a secondary film deposition device 55, a secondary film defect inspection device 56, a resist film deposition device 57, and a resist film defect inspection device 58.
- the distribution cassette is provided with a plurality of grooves formed at predetermined intervals from top to bottom so that a plurality of substrates can be stored, and has an ID tag. Information for managing each board stored in the distribution cassette is added to the ID tag. Specifically, the cassette number of the distribution cassette is recorded.
- the substrate is placed in each groove of the distribution cassette, and the cassette number, slot number, and process flow are input from the input unit 521 to the ID tag by the assigning device 52. To enter.
- the process flow is made up of the process order, the name of the device used in the process, and the recipe number corresponding to the processing condition of the process performed in each device. Given. On the production line, the substrate can be specified by the position in the process, the cassette number, and the slot number.
- the assigning device 52 writes the cassette number in the ID tag of the distribution cassette, and transmits the cassette number, slot number, and process flow to the host computer 51 by the data transmission / reception unit 522.
- the host computer 51 stores the cassette number, the slot number, and the process flow in the process flow storage unit 512 in association with each other. .
- cassette A When the distribution cassette whose cassette number has been input by the application device 52 (hereinafter, this distribution cassette is referred to as cassette A) is set in the loader port 531 of the primary film forming apparatus 53, the force setting is performed.
- the ID tag power of A also reads the cassette number and notifies the host computer 51 by the data transmitting / receiving unit 532.
- the host computer 51 transmits the cassette number of the cassette A, the slot number, and the recipe number for sputter deposition to the primary film deposition apparatus 53.
- the recipe number may be immediately before the start of the sputtering film forming operation.
- the primary film forming apparatus 53 Upon receiving this, the primary film forming apparatus 53 checks the sputter condition corresponding to the recipe number in the recipe number-sputter condition matching unit 533, and stores the matched sputter condition in the sputter condition storage unit 534. I do. According to the sputter conditions, the sputter condition controller 535 The apparatus 536 is controlled to form a sputter film.
- the sputtering apparatus 536 removes the substrate from the cassette A and starts sputter deposition. In the process of sputter deposition, the actual sputtering results are collected and associated with the slot number.
- cassette B Another circulation cassette prepared in advance at unloader port 538.
- cassette B another circulation cassette
- unloader slot number collection unit 537 (Referred to hereafter as collecting section 53 7) unloader slot number collection unit 537, the slot number of the cassette A, the sputtering associated record, collect the slot number of the cassette B, using a data transceiver 532 To the host computer 51.
- the collection unit 537 notifies the host computer 51 of the fact together with the cassette number of the cassette B.
- the host computer 51 specifies the next step in the procedure of the cassette number B, the cassette number A, and the process flow, and instructs a cassette transport unit (not shown) of a transport destination.
- the host computer 51 transmits the cassette number of the cassette B and the sputter recipe number transmitted to the primary film forming apparatus 53 to the primary film defect inspection apparatus 54.
- primary film defect inspection apparatus 54 receives these at data transmitting / receiving section 541 and passes them to cassette number / recipe number comparing section 542.
- the cassette number recipe number collating unit 542 collates the recipe number corresponding to the cassette number read by the ID number of the distribution cassette.
- the cassette number is that of the cassette B, the recipe number at the time of sputtering film formation on the substrate contained in the cassette B is obtained.
- the defect inspection condition storage unit 544 stores in advance a correspondence relationship between a recipe number and an inspection condition to be performed on a film formed under the recipe condition indicated by the recipe number. When receiving the recipe number from the recipe number collating unit 542, it outputs the inspection conditions to be performed.
- the defect inspection condition control unit 545 controls the defect inspection device 546 to perform the inspection.
- the defect inspection device 546 outputs the inspection result as defect inspection information.
- the inspected board is placed in a slot of another distribution cassette (hereinafter referred to as force set C) set in the unloader port 547 in advance.
- force set C another distribution cassette
- the unloader cassette number and unloader slot number assigning section 548 assigns a force set number to the cassette C, as well as the cassette number of the cassette C, the slot number of the cassette C, and the defect of the substrate stored in the slot.
- the data is transmitted to the host computer 51 using the data transmitting / receiving unit 541 in association with the test information.
- the host computer 51 accumulates the transmitted information in the information accumulation unit 513 in association with the sputter results obtained by the primary film forming apparatus 53 and the like.
- the secondary film deposition device 55 and the secondary film inspection device 56 are different from the primary film deposition device 53 and the primary film inspection device 54, respectively, because of the difference in the type of film to be deposited. Only the differences described above have no significant difference in the configuration elements and operations, and therefore description thereof is omitted. The same applies to the resist film forming apparatus 57 and the resist film defect inspection apparatus 58 shown in FIG.
- the defect information matching unit 514 generates the primary film information, the secondary film information, and the resist film information described in the first embodiment, These are collated with each other to generate mask blank information as shown in FIG.
- a notch mark 1 when a substrate or mask blank is set on a distribution cassette, a storage case, a holder for a substrate of a sputtering apparatus, or a stage of a defect inspection apparatus, a notch mark 1, a film mark 3, 6
- the direction of the substrate can be specified only by the notch mark 1 in the entire mask blank manufacturing process, and the notch can be specified.
- the directionality of the substrate may be managed only by the mark 1.
- a reference mark provided to the substrate may be used.
- the reference mark can have a shape that can specify the directionality (direction) of the substrate.
- the reference mark on the substrate or on the mask blanks may be arranged at a rotationally asymmetric position with respect to the center of the substrate.
- the film information is the film information of a plurality of films formed on the substrate.
- the obtained film information may be a single film.
- the mask blank factory power can be applied even if the information is acquired when the mask blank is shipped. This place Even in this case, there is an effect of guaranteeing the coincidence between the reference point of the film information and the XY coordinate system, and the reference point of the mask blank and the ⁇ coordinate system.
- information on the substrate surface may be included in addition to the film information.
- the present invention is exemplified by a non-tone type phase shift mask blank in which a MoSiN halftone film, a Cr light shielding film, and a resist film are formed on a glass substrate as a mask blank.
- the method for supporting mask fabrication according to the present invention has been described.
- the present invention is not limited to this.
- a so-called photomask blank in which a Cr light-shielding film and a resist film are formed on a glass substrate, and a multilayer reflective film and an absorber film on a glass substrate.
- the present invention can be applied to a reflective mask blank on which a resist film is formed.
- the film material of the halftone film and the film material of the light-shielding film described in the embodiment are not limited to the film material but may be other film materials that can be generally applied to a mask blank. It doesn't matter.
- the ID tag is provided separately for each distribution case.
- the distribution case is separate, but the ID tag is used in place of the distribution case used in the next step. It does not matter.
- the film information in the above-described embodiment includes the X coordinate and the Y coordinate of the XY coordinate system predetermined on the film with reference to the predetermined direction of the substrate, the size of the defect, and the type of the defect.
- the type and number of measured values at each coordinate are not limited to these. It is conceivable that a value relating to a shape such as flatness, an electric characteristic value such as an electric resistance value, an optical characteristic value such as a refractive index, and the like are included as film information. All of these measured values may be included in the film information or a part of them.
- an orthogonal coordinate system was used as a coordinate system.
- the present invention is not limited to this, and other polar coordinate systems may be used.
- a dimensional coordinate system may be used.
- the XYZ coordinate system is used for the film information, if there is a hole at the position of depth Z at the point represented by X and Y on the film surface, it is possible to incorporate information that is more detailed, It is possible to obtain mask blank information.
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Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006519397A JP4503015B2 (ja) | 2004-03-09 | 2005-03-07 | マスクブランク情報習得方法及びシステム、マスクブランク情報提供方法、転写マスク作製支援及び製造方法並びにマスクブランク製造及び提供方法 |
DE112005000548.8T DE112005000548B4 (de) | 2004-03-09 | 2005-03-07 | Verfahren zur Unterstützung der Maskenherstellung, Verfahren zur Bereitstellung von Maskenrohlingen und Verfahren zur Handhabung von Maskenrohlingen |
KR1020107004958A KR101100003B1 (ko) | 2004-03-09 | 2005-03-07 | 마스크 블랭크 생산 시스템 |
CN2005800075702A CN1930520B (zh) | 2004-03-09 | 2005-03-07 | 掩模制作支援方法、掩模版提供方法、掩模版供取系统 |
US10/592,320 US7660456B2 (en) | 2004-03-09 | 2005-03-07 | Mask fabrication supporting method, mask blank providing method, and mask blank dealing system |
US12/685,218 US8196070B2 (en) | 2004-03-09 | 2010-01-11 | Mask fabrication supporting method, mask blank providing method, and mask blank dealing system |
US13/464,147 US8627239B2 (en) | 2004-03-09 | 2012-05-04 | Mask fabrication supporting method, mask blank providing method, and mask blank dealing system |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US55105704P | 2004-03-09 | 2004-03-09 | |
US60/551057 | 2004-03-09 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
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US10/592,320 A-371-Of-International US7660456B2 (en) | 2004-03-09 | 2005-03-07 | Mask fabrication supporting method, mask blank providing method, and mask blank dealing system |
US12/685,218 Division US8196070B2 (en) | 2004-03-09 | 2010-01-11 | Mask fabrication supporting method, mask blank providing method, and mask blank dealing system |
Publications (1)
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WO2005085951A1 true WO2005085951A1 (ja) | 2005-09-15 |
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PCT/JP2005/003901 WO2005085951A1 (ja) | 2004-03-09 | 2005-03-07 | マスク作製支援方法、マスクブランク提供方法、マスクブランク取引システム |
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US (3) | US7660456B2 (ja) |
JP (3) | JP4503015B2 (ja) |
KR (3) | KR100911595B1 (ja) |
CN (1) | CN1930520B (ja) |
DE (1) | DE112005000548B4 (ja) |
TW (2) | TWI281093B (ja) |
WO (1) | WO2005085951A1 (ja) |
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JP2006084786A (ja) * | 2004-09-16 | 2006-03-30 | Hoya Corp | マスクブランク提供システム、マスクブランク提供方法、マスクブランク用透明基板の製造方法、マスクブランクの製造方法及びマスクの製造方法 |
JP4520263B2 (ja) * | 2004-09-16 | 2010-08-04 | Hoya株式会社 | マスクブランク提供システム、マスクブランク提供方法、マスクブランク用透明基板の製造方法、マスクブランクの製造方法及びマスクの製造方法 |
JP2007298631A (ja) * | 2006-04-28 | 2007-11-15 | Shin Etsu Chem Co Ltd | フォトマスクブランクの製造方法およびフォトマスクブランク |
JP2007333783A (ja) * | 2006-06-12 | 2007-12-27 | Fujitsu Ltd | 露光用マスクの検査装置、検査方法、製造方法および露光用マスク |
JP2009134095A (ja) * | 2007-11-30 | 2009-06-18 | Toppan Printing Co Ltd | 不良解析システム及びそれを用いた不良解析方法 |
JP2010008738A (ja) * | 2008-06-27 | 2010-01-14 | Hoya Corp | フォトマスクの製造方法 |
JP4536804B2 (ja) * | 2008-06-27 | 2010-09-01 | Hoya株式会社 | フォトマスクの製造方法 |
CN102169286A (zh) * | 2010-01-29 | 2011-08-31 | Hoya株式会社 | 掩模板用基板、掩模板、转印用掩模的制造方法 |
JP2010122711A (ja) * | 2010-03-08 | 2010-06-03 | Hoya Corp | マスクブランクの製造方法及びマスクの製造方法 |
JP4520537B2 (ja) * | 2010-03-08 | 2010-08-04 | Hoya株式会社 | マスクブランクの製造方法及びマスクの製造方法 |
JP2013082612A (ja) * | 2011-09-28 | 2013-05-09 | Hoya Corp | マスクブランク用ガラス基板の製造方法、マスクブランクの製造方法及びマスクの製造方法、並びにインプリントモールドの製造方法 |
JP2018189997A (ja) * | 2018-09-11 | 2018-11-29 | Hoya株式会社 | フォトマスク基板、フォトマスクブランク、フォトマスク、フォトマスク基板の製造方法、表示装置の製造方法、フォトマスクのハンドリング方法、及びフォトマスク基板のハンドリング方法 |
Also Published As
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KR100911595B1 (ko) | 2009-08-07 |
TWI383247B (zh) | 2013-01-21 |
US20070178387A1 (en) | 2007-08-02 |
US20120260222A1 (en) | 2012-10-11 |
JP4503015B2 (ja) | 2010-07-14 |
KR20070011367A (ko) | 2007-01-24 |
US8627239B2 (en) | 2014-01-07 |
DE112005000548T5 (de) | 2007-02-01 |
DE112005000548B4 (de) | 2015-11-19 |
JP2010224581A (ja) | 2010-10-07 |
CN1930520A (zh) | 2007-03-14 |
US20100178597A1 (en) | 2010-07-15 |
KR20100038470A (ko) | 2010-04-14 |
US8196070B2 (en) | 2012-06-05 |
TW200538869A (en) | 2005-12-01 |
CN1930520B (zh) | 2010-12-29 |
KR20090060375A (ko) | 2009-06-11 |
KR101032526B1 (ko) | 2011-05-04 |
JP4750194B2 (ja) | 2011-08-17 |
US7660456B2 (en) | 2010-02-09 |
JP2009122708A (ja) | 2009-06-04 |
JPWO2005085951A1 (ja) | 2007-08-09 |
TWI281093B (en) | 2007-05-11 |
KR101100003B1 (ko) | 2011-12-28 |
JP4886061B2 (ja) | 2012-02-29 |
TW200712758A (en) | 2007-04-01 |
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