WO2000053649A1 - Copolymere greffe styrene et son procede de preparation - Google Patents

Copolymere greffe styrene et son procede de preparation Download PDF

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Publication number
WO2000053649A1
WO2000053649A1 PCT/KR2000/000181 KR0000181W WO0053649A1 WO 2000053649 A1 WO2000053649 A1 WO 2000053649A1 KR 0000181 W KR0000181 W KR 0000181W WO 0053649 A1 WO0053649 A1 WO 0053649A1
Authority
WO
WIPO (PCT)
Prior art keywords
styrenic
styrene
carbon
group
syndiotactic
Prior art date
Application number
PCT/KR2000/000181
Other languages
English (en)
Inventor
Sung Kyung Jung
Xue Quan Zhang
Original Assignee
Samsung Electronics Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samsung Electronics Co., Ltd. filed Critical Samsung Electronics Co., Ltd.
Publication of WO2000053649A1 publication Critical patent/WO2000053649A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors

Definitions

  • R 10 is an alkyl of C ⁇ . 8
  • j is an integer from 2 to 50.
  • the acrylonitrile derivative includes: vinylidene cyanate, alpha-methoxy acrylonitrile, alpha-phenyl acrylonitrile, and alpha-acetoxy acrylonitrile.
  • the thermoplastic resin which can be used in the resin compositions includes all kinds of resins which are obtained through an add reaction or a condensation reaction.
  • the preferable examples include: polyolefin, ethylenevinyl copolymer, amorphous polystyrene, polyester, polyacetal, polycarbonate, polyacrylate, polyamide, polyether, polyphenylene oxide, polyphenylene sulfide, polyoxy methylene, polyimide, polysulfone, polyether sulfone, polyurethane, acrylate resin, and halogenated resin.
  • These compounds can be denatured or grafted by the styrenic monomers so as to increase the compatibility with the syndiotactic styrenic polymers. Or they are transformed so as to have a reactive functional group or they originally have it, thereby improving the blending efficiency.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

L'invention porte sur un copolymère greffé styrène dans lequel un ou plusieurs monomères aux liaisons éthyléniquement insaturées sont greffés sur un polystyrène syndiotactique. Le copolymère greffé styrène est obtenu de la manière suivante: (1) on prépare un polymère styrène stéréorégulier syndiotactique possédant des motifs de répétition (A) en polymérisant des monomères aromatiques vinyliques sous système catalyseur, ce système catalyseur comprenant des composés de métaux de transition (I) comme composants principaux et des composés d'aluminium organique ou aluminoxanes (II) comme composants cocatalyseurs; et (2) on effectue une polymérisation avec greffage des monomères de la formule (B) aux liaisons éthyléniquement insaturées avec le polymère styrène stéréorégulier syndiotactique. Dans la formule (A) R1 représente un hydrogène, un halogène ou un substituant ne contenant pas de liaisons doubles carbone-carbone, mais un ou plusieurs composants sélectionnés dans le groupe comprenant: carbone, oxygène, soufre, phosphore, sélénium, silicium et étain; et m est un nombre entier compris entre 1 et 3 (si m vaut 2 ou 3, R1 est identique ou inférieur). Dans la formule (B), chacun des R2 à R5 représente un hydrogène, un halogène ou un substituant contenant un ou plusieurs composants sélectionnés dans le groupe comprenant carbone, oxygène, azote, soufre, phosphore, sélénium, silicium et étain.
PCT/KR2000/000181 1999-03-08 2000-03-07 Copolymere greffe styrene et son procede de preparation WO2000053649A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-1999-0007544A KR100369625B1 (ko) 1999-03-08 1999-03-08 스티렌계 그라프트 공중합체 및 그 제조방법
KR1999/7544 1999-03-08

Publications (1)

Publication Number Publication Date
WO2000053649A1 true WO2000053649A1 (fr) 2000-09-14

Family

ID=19575824

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2000/000181 WO2000053649A1 (fr) 1999-03-08 2000-03-07 Copolymere greffe styrene et son procede de preparation

Country Status (2)

Country Link
KR (1) KR100369625B1 (fr)
WO (1) WO2000053649A1 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002048222A1 (fr) * 2000-12-12 2002-06-20 Idemitsu Petrochemical Co., Ltd. Procede de production d'une composition polymere
EP1290046A1 (fr) * 2000-06-02 2003-03-12 Samsung General Chemicals Co., Ltd. Procede de preparation d'un polystyrene syndiotactique a monomere greffe a polarite
WO2003082941A1 (fr) * 2002-03-28 2003-10-09 Kometra Kunststoff-Modifikatoren Und -Additiv Ag Procede de production de polystyrenes syndiotactiques fonctionnalises
WO2008074744A1 (fr) * 2006-12-18 2008-06-26 Akzo Nobel N.V. Procédé de préparation d'un article en caoutchouc réticulé
CN101573402B (zh) * 2006-12-18 2012-03-21 阿克佐诺贝尔股份有限公司 制备交联橡胶制品的方法
US8277664B2 (en) 2008-10-03 2012-10-02 California Institute Of Technology Extraction of anions from solutions and mixtures using hyperbranched macromolecules
US8658702B2 (en) 2009-12-17 2014-02-25 Mamadou Diallo Soluble anion exchangers from hyperbranched macromolecules
US9815712B2 (en) 2008-10-03 2017-11-14 California Institute Of Technology High capacity perchlorate-selective resins from hyperbranched macromolecules
CN109627665A (zh) * 2018-12-20 2019-04-16 广州辰东新材料有限公司 一种用于激光直接成型的热塑性树脂组合物及其制备方法
CN114456321A (zh) * 2020-10-21 2022-05-10 中国石油化工股份有限公司 一种核壳结构的聚合物微球及其制备方法和应用

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100340276B1 (ko) * 2000-04-06 2002-06-12 박호군 관능기를 갖는 마크로모노머와 이를 이용한 결정성-무정형그래프트 공중합체의 제조 방법
KR100714658B1 (ko) * 2001-04-16 2007-05-07 삼성토탈 주식회사 신디오탁틱 폴리스티렌 반응기 공중합체
CN116425919B (zh) * 2023-03-06 2024-01-12 湖南工业大学 聚（甲基）丙烯酰亚胺泡沫材料及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02219843A (ja) * 1989-02-21 1990-09-03 Idemitsu Kosan Co Ltd スチレン系樹脂組成物
JPH0517533A (ja) * 1990-12-10 1993-01-26 Idemitsu Kosan Co Ltd グラフト共重合体及びその製造方法
JPH05247147A (ja) * 1992-03-03 1993-09-24 Idemitsu Kosan Co Ltd グラフト共重合体及びその製造方法
EP0733675A1 (fr) * 1994-10-05 1996-09-25 Idemitsu Kosan Company Limited Composition de resine de polystyrene extremement resistante aux chocs
JPH1025382A (ja) * 1997-04-07 1998-01-27 Asahi Chem Ind Co Ltd 耐熱性樹脂組成物

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02219843A (ja) * 1989-02-21 1990-09-03 Idemitsu Kosan Co Ltd スチレン系樹脂組成物
JPH0517533A (ja) * 1990-12-10 1993-01-26 Idemitsu Kosan Co Ltd グラフト共重合体及びその製造方法
JPH05247147A (ja) * 1992-03-03 1993-09-24 Idemitsu Kosan Co Ltd グラフト共重合体及びその製造方法
EP0733675A1 (fr) * 1994-10-05 1996-09-25 Idemitsu Kosan Company Limited Composition de resine de polystyrene extremement resistante aux chocs
JPH1025382A (ja) * 1997-04-07 1998-01-27 Asahi Chem Ind Co Ltd 耐熱性樹脂組成物

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1290046A1 (fr) * 2000-06-02 2003-03-12 Samsung General Chemicals Co., Ltd. Procede de preparation d'un polystyrene syndiotactique a monomere greffe a polarite
EP1290046A4 (fr) * 2000-06-02 2006-09-13 Samsung Atofina Co Ltd Procede de preparation d'un polystyrene syndiotactique a monomere greffe a polarite
WO2002048222A1 (fr) * 2000-12-12 2002-06-20 Idemitsu Petrochemical Co., Ltd. Procede de production d'une composition polymere
US6696525B2 (en) 2000-12-12 2004-02-24 Idemitsu Petrochemical Co., Ltd. Process for producing polymer composition
WO2003082941A1 (fr) * 2002-03-28 2003-10-09 Kometra Kunststoff-Modifikatoren Und -Additiv Ag Procede de production de polystyrenes syndiotactiques fonctionnalises
CN101573402B (zh) * 2006-12-18 2012-03-21 阿克佐诺贝尔股份有限公司 制备交联橡胶制品的方法
WO2008074744A1 (fr) * 2006-12-18 2008-06-26 Akzo Nobel N.V. Procédé de préparation d'un article en caoutchouc réticulé
US8298617B2 (en) 2006-12-18 2012-10-30 Akzo Nobel N.V. Process for the preparation of a cross-linked rubber article
US8277664B2 (en) 2008-10-03 2012-10-02 California Institute Of Technology Extraction of anions from solutions and mixtures using hyperbranched macromolecules
US9815712B2 (en) 2008-10-03 2017-11-14 California Institute Of Technology High capacity perchlorate-selective resins from hyperbranched macromolecules
US8658702B2 (en) 2009-12-17 2014-02-25 Mamadou Diallo Soluble anion exchangers from hyperbranched macromolecules
CN109627665A (zh) * 2018-12-20 2019-04-16 广州辰东新材料有限公司 一种用于激光直接成型的热塑性树脂组合物及其制备方法
CN109627665B (zh) * 2018-12-20 2021-05-28 广州辰东新材料有限公司 一种用于激光直接成型的热塑性树脂组合物及其制备方法
CN114456321A (zh) * 2020-10-21 2022-05-10 中国石油化工股份有限公司 一种核壳结构的聚合物微球及其制备方法和应用

Also Published As

Publication number Publication date
KR20000059728A (ko) 2000-10-05
KR100369625B1 (ko) 2003-01-30

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