WO1998027831A2 - Verfahren zur verstärkung der süsskraft und zur geschmacksverbesserung einer mischung hochintensiver süssstoffe - Google Patents

Verfahren zur verstärkung der süsskraft und zur geschmacksverbesserung einer mischung hochintensiver süssstoffe Download PDF

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Publication number
WO1998027831A2
WO1998027831A2 PCT/EP1997/006756 EP9706756W WO9827831A2 WO 1998027831 A2 WO1998027831 A2 WO 1998027831A2 EP 9706756 W EP9706756 W EP 9706756W WO 9827831 A2 WO9827831 A2 WO 9827831A2
Authority
WO
WIPO (PCT)
Prior art keywords
sweetness
weight
mixture
sucrose
acesulfame
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1997/006756
Other languages
German (de)
English (en)
French (fr)
Other versions
WO1998027831A3 (de
Inventor
Martin Jager
Margit DÖRR
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Sales Germany GmbH
Original Assignee
Nutrinova Nutrition Specialties and Food Ingredients GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19653344A external-priority patent/DE19653344C1/de
Priority claimed from DE19732351A external-priority patent/DE19732351A1/de
Priority to BR9714426-6A priority Critical patent/BR9714426A/pt
Priority to CA002273241A priority patent/CA2273241A1/en
Priority to DE59711346T priority patent/DE59711346D1/de
Priority to DK97952865T priority patent/DK0946111T3/da
Priority to HU0000393A priority patent/HUP0000393A3/hu
Priority to AT97952865T priority patent/ATE260048T1/de
Application filed by Nutrinova Nutrition Specialties and Food Ingredients GmbH filed Critical Nutrinova Nutrition Specialties and Food Ingredients GmbH
Priority to JP52829298A priority patent/JP2001507222A/ja
Priority to NZ336326A priority patent/NZ336326A/en
Priority to AU56590/98A priority patent/AU724947B2/en
Priority to EP97952865A priority patent/EP0946111B1/de
Publication of WO1998027831A2 publication Critical patent/WO1998027831A2/de
Publication of WO1998027831A3 publication Critical patent/WO1998027831A3/de
Priority to NO992782A priority patent/NO992782D0/no
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30Artificial sweetening agents
    • A23L27/33Artificial sweetening agents containing sugars or derivatives

Definitions

  • the present invention relates to a method for increasing the sweetness and improving the taste of a mixture of high-intensity sweeteners by adding an oligosaccharide.
  • EP-A 646 326 describes a sweetener combination which contains an oligosaccharide in solid or powdered form which is coated with a sweetener.
  • the object of this invention is to provide a solid sweetener mixture with oligosaccharides, in which there is no sticking or clumping of the oligosaccharide particles.
  • Another object mentioned is to provide a sweetener mixture with improved flow behavior and sweetening power.
  • the synergism that can be derived from the examples and tables is only slight.
  • Example 2 of this document relates to an effervescent tablet which contains, in addition to inulin, inter alia also acesulfame and aspartame and which, when dissolved in water, gives a soft drink. Information about the sweetness of Mixtures of sweeteners and inulin cannot be found in the document.
  • sweetener mixtures which have a taste and mouthfeel as similar as possible to a sucrose solution and which achieve this effect with the lowest possible concentrations of sweetener.
  • mixtures of at least two high-intensity sweeteners and an oligosaccharide have a sweetness enhancement which far exceeds the expectations of a person skilled in the art and comes very close to the taste and mouthfeel of sucrose.
  • the present invention thus relates to a process for increasing the sweetness and for improving the taste of a mixture of high-intensity sweeteners, characterized in that an oligosaccharide is added to the mixture.
  • Oligosaccharides in the sense of the present invention are in particular water-soluble, generally, but not necessarily, non-digestible oligosaccharides, which consist of at least two monosaccharide building blocks. Upwards, the number of monosaccharide building blocks from which a sophisticated oligosaccharide can consist is largely open and is determined in particular by the water solubility normally required. As a rule, oligosaccharides have 2 to 60 monosaccharide building blocks.
  • Monosaccharides from which the claimed oligosaccharides can consist are generally hexoses, which can be present as furanosides or pyranosides.
  • Examples of monosaccharides are glucose, galactose and fructose.
  • Preferred oligosaccharides are, in particular, inulins, oligofructoses, galactooligosaccharides, isomaltooligosaccharides, lactosucrose, maltose, glycosyl sucrose, maltotetraose and trehalose.
  • Inulin acts as an energy reserve in numerous fruits and plants. Inulin is manufactured industrially from chicory in Europe. The naturally occurring inulin molecules are extracted from the root of the chicory, cleaned and dried. Inulin contains oligofructose, which is to a certain extent a fraction of the inulin with a low degree of polymerization (approximately from 2 to 9). It is obtained from inulin by hydrolysis. Inulin and oligofructose are recognized in Europe as food ingredients.
  • Galactooligosaccharides are also carbohydrates, chemically considered a mixture of poly and oligosaccharides. The degree of polymerization is between 1 and 7 molecules. Galactooligosaccharides are manufactured industrially from lactose by enzymatic hydrolysis.
  • Isomaltooligosaccharides are produced by enzymatic hydrolysis from high-strength starch hydrolyzates.
  • Lactosucrose is produced with the help of the enzyme fructofuranosydase from lactose, which is contained in milk, and sucrose from cane sugar.
  • Maltose and trehalose are both disaccharides that consist of two molecules of glucose, but differ in the way the two glucose components are linked. Maltose is similar to sucrose in terms of digestibility, calorific value and cariogenicity.
  • Glycosyl sucrose is made from a mixture of sucrose and starch hydrolyzates by the enzyme transferase. It has the same sweetness profile and calorific calorific value as sucrose, but is significantly less sweet.
  • Maltotetraose is a tetrasaccharide made up of four molecules of glucose.
  • the oligosaccharides can be used alone or in mixtures with one another by the process according to the invention.
  • Mixtures of these high-intensity sweeteners can consist of two or more individual components, the respective mixing ratios being in principle not critical.
  • suitable mixing ratios are, for example, between 95: 5 and 5:95, in particular between 70:30 and 30:70, in the case of an acesulfame-K aspartame mixture, preferably 50:50.
  • the best sweetening enhancement is usually achieved in combination with oligosaccharides if each sweetener in the sweetener mixture contributes approximately the same sweetness intensity to the sweetener mixture.
  • Suitable mixtures of two are, for example, acesulfame-K / cyclamate, acesulfame-K / saccharin, aspartame / cyclamate, aspartame / saccharin, cyclamate / saccharin, acesulfame-K / alitame, aspartame / alitame, aspartame / sucralose, cyclamate / sucralose, cyclamate / alcamate
  • saccharin / sucralose saccharin / alitam, alitam / sucralose and acesulfame-K / sucralose.
  • a mixture of acesulfame-K and aspartame is preferred.
  • the oligosaccharides can be added to the sweetener mixture in different concentrations, which primarily depend on the particular application.
  • the mixtures of high-intensity sweeteners can also contain flavor-modifying substances such as Neohesperidin DC (NHDC), thaumatin or rhamnose can be added.
  • NHDC Neohesperidin DC
  • thaumatin thaumatin
  • rhamnose can be added.
  • the additional quantity can fluctuate within wide limits and depends primarily on the intended use.
  • the oligosaccharides are admixed to the high-intensity sweeteners by methods known per se, for example by mixing the components in suitable mixers or granulators or in Fluid bed apparatus. Dissolving in water together is also possible.
  • the sweetness gain which is created by such a combination with ASK and APM in equal parts, is thus 40%.
  • this already known sweetness enhancement was taken into account by including it in the tests: Because, as stated above, it is known that 90 mg / kg ASK and 90 mg / kg APM have the same sweetness as a 4.9% sucrose solution, the determined sweetness of the respective oligosaccharide was simply added mathematically. The result of this calculation is the theoretical sweetening power that the respective acesulfame-K / aspartame / oligosaccharide mixture should have.
  • sucrose a 10% aqueous solution of inulin is 0.1 times as sweet as sucrose.
  • the mixture of 90 mg / kg acesulfame-K and 90 mg / kg aspartame is as sweet as a 4.9% sucrose solution or the acesulfame-K / aspartame mixture is 0.49 times as sweet as sucrose. If you add both sweeteners, i.e. 0.37 of lactosucrose + 0.49 of acesulfame-K / aspartame, you get a theoretical sweetness of 0.86 of the sweetness of sucrose or a sweetness that corresponds to an 8.6% sucrose Solution corresponds.
  • the method according to the invention for enhancing the sweetness and for improving the taste can thus be used in the production of a wide variety of foods.
  • baked goods such as sponge cakes, sweets, such as gummy bears, Hard caramels and chocolate, but in particular also beverages, such as lemonades, fruit juice drinks, showers and fruit juices, and liquid and semi-liquid milk products, such as yoghurt, drinking yoghurt, sour or buttermilk, as well as spreads and all types of ice cream.
  • the method according to the invention can also be used in the production of pet and farm animal feed and medicament formulations.
  • Example 1 A repetition of Example 1 with further oligosaccharides, but also with acesulfame-K and aspartame and in the same weight ratios gave the following results:
  • sucrose ad 100% by weight made up with water.
  • a drinking yogurt was as follows
  • a drinking yogurt was as follows
  • a drinking yoghurt of the following composition was used as a comparative example (standard): 30% whey by weight
  • sucrose ad 100% by weight filled with natural yoghurt (fat content: 1.5%).
  • an orange juice drink was as follows
  • sucrose ad 100% by weight made up with water.
  • An orange fruit juice drink of the following composition was produced: 10% by weight of orange juice concentrate, 4.5% by weight of maltose 0.0050% by weight acesulfame-K
  • an orange juice drink was as follows
  • sucrose ad 100% by weight made up with water.
  • an orange juice drink was as follows
  • sucrose ad 100 wt .-% made up with water 6.5 wt .-% sucrose ad 100 wt .-% made up with water.

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  • Life Sciences & Earth Sciences (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Seasonings (AREA)
  • Confectionery (AREA)
  • Jellies, Jams, And Syrups (AREA)
PCT/EP1997/006756 1996-12-20 1997-12-03 Verfahren zur verstärkung der süsskraft und zur geschmacksverbesserung einer mischung hochintensiver süssstoffe Ceased WO1998027831A2 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
AU56590/98A AU724947B2 (en) 1996-12-20 1997-12-03 Method of increasing the sweetening power and enhancing the taste of a mixture of high-intensity sweeteners
EP97952865A EP0946111B1 (de) 1996-12-20 1997-12-03 Verfahren zur verstärkung der süsskraft und zur geschmacksverbesserung einer mischung hochintensiver süssstoffe
JP52829298A JP2001507222A (ja) 1996-12-20 1997-12-03 極めて強力な甘味料の混合物の甘味力を向上させそして味を向上させる方法
DE59711346T DE59711346D1 (de) 1996-12-20 1997-12-03 Verfahren zur verstärkung der süsskraft und zur geschmacksverbesserung einer mischung hochintensiver süssstoffe
DK97952865T DK0946111T3 (da) 1996-12-20 1997-12-03 Fremgangsmåde til forstærkning af sødekraften og til smagsforbedring af en blanding af højintensive sødestoffer
HU0000393A HUP0000393A3 (en) 1996-12-20 1997-12-03 Method for increasing the sweetening power and enhancing the taste of a mixture of extremely powerful sweetening agents
AT97952865T ATE260048T1 (de) 1996-12-20 1997-12-03 Verfahren zur verstärkung der süsskraft und zur geschmacksverbesserung einer mischung hochintensiver süssstoffe
BR9714426-6A BR9714426A (pt) 1996-12-20 1997-12-03 Processo para reforçar a intensidade adoçante e para aperfeiçoar o sabor de uma mistura de adoçantes altamente intensos
CA002273241A CA2273241A1 (en) 1996-12-20 1997-12-03 Method for increasing the sweetening power and enhancing the taste of a mixture of extremely powerful sweetening agents
NZ336326A NZ336326A (en) 1996-12-20 1997-12-03 Method for increasing the sweetening power and enhancing the taste of a mixture of extremely powerful sweetening agents
NO992782A NO992782D0 (no) 1996-12-20 1999-06-08 FremgangsmÕte for Õ forsterke s°tningskraften og forbedre smaken av s°tningsmidler med h°y intensitet

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19653344A DE19653344C1 (de) 1996-12-20 1996-12-20 Verfahren zur Verstärkung der Süßkraft und zur Geschmacksverbesserung einer wäßrigen Lösung einer Mischung hochintensiver Süßstoffe
DE19653344.9 1996-12-20
DE19732351A DE19732351A1 (de) 1997-07-28 1997-07-28 Verfahren zur Herstellung der Süßkraft und zur Geschmacksverbesserung einer Mischung hochintensiver Süßstoffe
DE19732351.0 1997-07-28

Publications (2)

Publication Number Publication Date
WO1998027831A2 true WO1998027831A2 (de) 1998-07-02
WO1998027831A3 WO1998027831A3 (de) 1998-08-27

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PCT/EP1997/006756 Ceased WO1998027831A2 (de) 1996-12-20 1997-12-03 Verfahren zur verstärkung der süsskraft und zur geschmacksverbesserung einer mischung hochintensiver süssstoffe

Country Status (19)

Country Link
US (2) US20020025366A1 (enExample)
EP (1) EP0946111B1 (enExample)
JP (1) JP2001507222A (enExample)
CN (1) CN1099250C (enExample)
AR (1) AR010367A1 (enExample)
AT (1) ATE260048T1 (enExample)
AU (1) AU724947B2 (enExample)
BR (1) BR9714426A (enExample)
CA (1) CA2273241A1 (enExample)
DE (1) DE59711346D1 (enExample)
DK (1) DK0946111T3 (enExample)
ES (1) ES2212816T3 (enExample)
HU (1) HUP0000393A3 (enExample)
NO (1) NO992782D0 (enExample)
NZ (1) NZ336326A (enExample)
PL (1) PL334015A1 (enExample)
RU (1) RU2216209C2 (enExample)
TR (1) TR199901368T2 (enExample)
WO (1) WO1998027831A2 (enExample)

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WO2006074881A1 (en) * 2005-01-14 2006-07-20 Nutrinova Nutrition Specialties & Food Ingredients Gmbh Mixture of high fructose corn syrup (hfcs 42 or hfcs 55) and high-intensity sweeteners with a taste profile of pure sucrose
JP2015154781A (ja) * 1998-10-28 2015-08-27 三栄源エフ・エフ・アイ株式会社 スクラロースを含有する組成物及びその応用
EP2047254B1 (en) * 2006-04-20 2015-10-28 Givaudan SA Method relating to sweetness enhancement

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JP2015154781A (ja) * 1998-10-28 2015-08-27 三栄源エフ・エフ・アイ株式会社 スクラロースを含有する組成物及びその応用
JP2018121638A (ja) * 1998-10-28 2018-08-09 三栄源エフ・エフ・アイ株式会社 スクラロースを含有する組成物及びその応用
WO2005013728A1 (en) * 2003-08-11 2005-02-17 Nutrinova Nutrition Specialties & Food Ingredients Gmbh Mixtures of high fructose corn syrup (hfcs 42 or hfcs 55) and high-intesity sweeteners with a taste profile of pure sucrose
WO2006074881A1 (en) * 2005-01-14 2006-07-20 Nutrinova Nutrition Specialties & Food Ingredients Gmbh Mixture of high fructose corn syrup (hfcs 42 or hfcs 55) and high-intensity sweeteners with a taste profile of pure sucrose
EP2047254B1 (en) * 2006-04-20 2015-10-28 Givaudan SA Method relating to sweetness enhancement
EP2995950A1 (en) * 2006-04-20 2016-03-16 Givaudan SA Method relating to sweetness enhancement

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US20020025366A1 (en) 2002-02-28
DE59711346D1 (de) 2004-04-01
JP2001507222A (ja) 2001-06-05
AU724947B2 (en) 2000-10-05
RU2216209C2 (ru) 2003-11-20
EP0946111B1 (de) 2004-02-25
HUP0000393A3 (en) 2000-12-28
ES2212816T3 (es) 2004-08-01
BR9714426A (pt) 2000-04-25
PL334015A1 (en) 2000-01-31
HUP0000393A2 (hu) 2000-06-28
ATE260048T1 (de) 2004-03-15
CA2273241A1 (en) 1998-07-02
CN1099250C (zh) 2003-01-22
US20030077369A1 (en) 2003-04-24
NO992782L (no) 1999-06-08
NO992782D0 (no) 1999-06-08
NZ336326A (en) 2001-02-23
AU5659098A (en) 1998-07-17
AR010367A1 (es) 2000-06-07
CN1241118A (zh) 2000-01-12
TR199901368T2 (xx) 1999-08-23
DK0946111T3 (da) 2004-06-21
EP0946111A2 (de) 1999-10-06
WO1998027831A3 (de) 1998-08-27

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