WO1998010439A1 - Materiau magnetique composite, procede de fabrication et materiau permettant de supprimer les interferences electromagnetiques - Google Patents
Materiau magnetique composite, procede de fabrication et materiau permettant de supprimer les interferences electromagnetiques Download PDFInfo
- Publication number
- WO1998010439A1 WO1998010439A1 PCT/JP1997/003067 JP9703067W WO9810439A1 WO 1998010439 A1 WO1998010439 A1 WO 1998010439A1 JP 9703067 W JP9703067 W JP 9703067W WO 9810439 A1 WO9810439 A1 WO 9810439A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- magnetic
- electromagnetic interference
- composite magnetic
- composite
- magnetic material
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/20—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder
- H01F1/22—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
- H01F1/24—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0073—Shielding materials
- H05K9/0081—Electromagnetic shielding materials, e.g. EMI, RFI shielding
- H05K9/0083—Electromagnetic shielding materials, e.g. EMI, RFI shielding comprising electro-conductive non-fibrous particles embedded in an electrically insulating supporting structure, e.g. powder, flakes, whiskers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/20—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder
- H01F1/22—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
- H01F1/24—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated
- H01F1/26—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated by macromolecular organic substances
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/34—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials non-metallic substances, e.g. ferrites
- H01F1/36—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials non-metallic substances, e.g. ferrites in the form of particles
- H01F1/37—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials non-metallic substances, e.g. ferrites in the form of particles in a bonding agent
Definitions
- the present invention relates to a composite magnetic material in which a magnetic powder is dispersed in an organic binder, and more particularly, to a complex magnetic permeability characteristic effective for suppressing electromagnetic interference which is a problem in a high-frequency electronic circuit Z device.
- the present invention relates to an excellent composite magnetic body, a method for producing the same, and an electromagnetic interference suppressor made of the composite magnetic body.
- the present invention relates to a composite magnetic material that is rich in flexibility, for example, FPC (Flexible Printed Circuit).
- FFC Flexible Flat Cable
- the present invention relates to a method of manufacturing the same, and an electromagnetic interference suppressor made of the composite magnetic body.
- RAM random access memory
- ROM read-only memory
- MPU microprocessor
- CPU central processing unit
- IPALU image processor arithmetic and logic unit
- logic circuits and logic elements are composed of LSI and IC composed of a large number of semiconductor elements as active elements, and are mounted on a printed wiring board. In these logic circuits and logic elements, the operation speed is increased and the signal processing speed is increased. In such logic circuits and the like, signals that change at high speed involve abrupt changes in voltage and current, so that the positive IKl element generates inductive noise and also causes high-frequency noise.
- This high-frequency noise acts synergistically with crosstalk noise and noise due to impedance mismatch.
- high frequency noise is often due to inductive noise generated by active elements. Due to this inductive noise, a high-frequency magnetic field is induced on the same surface as the device mounting surface of the wiring board and on the opposite surface.
- connection of a filter to a circuit that generates inductive noise in an electronic device or the problematic circuit is affected by radiated electromagnetic interference. Measures such as keeping away from the receiving circuit, shielding, and grounding are generally used.
- a printed wiring board used in an electronic device has a relatively small electromagnetic coupling between signal lines such as electromagnetic induction generated from the inside of the board at a low frequency. As the frequency becomes higher, the electromagnetic coupling between signal lines becomes denser. As a result, the above-described problem occurs.
- the conductor shield is a measure against electromagnetic interference that utilizes the reflection of electromagnetic waves due to impedance mismatch with the space, so even if a shielding effect is obtained, electromagnetic shielding due to reflection from unnecessary radiation sources is possible. Coupling is promoted, and in many cases secondary electromagnetic interference is caused as a result.
- An object of the present invention is to provide a composite magnetic material for use in a high-frequency electronic device, particularly an electromagnetic interference suppressor that is effective in suppressing electromagnetic interference inside a mobile communication device, and a method of manufacturing the same.
- an object of the present invention is to provide a composite magnetic material having excellent flexibility and flame retardancy and a method for producing the same.
- Another object of the present invention is to provide an electromagnetic interference suppressor made of the composite magnetic material.
- an object of the present invention is to provide an electromagnetic interference suppressor which is rich in flexibility and can be attached to, for example, a curved surface of a housing of an FPC, FFC, or electronic device and has excellent flame retardancy.
- an electrically non-conductive magnetic material substantially composed of a magnetic powder and an organic binder, wherein the magnetic materials appear in different frequency ranges from each other.
- the composite magnetic material has a plurality of magnetic resonances, and the organic binder is chlorinated polyethylene.
- the plurality of magnetic resonances appearing in the mutually different frequency regions are a plurality of anisotropic magnetic fields having mutually different magnitudes.
- (H k) is a composite magnetic material.
- an electromagnetic interference suppressor substantially composed of a composite magnetic material, wherein the composite magnetic material has electrical non-conductivity, and comprises a magnetic powder and an organic binder.
- the electromagnetic interference suppressor further comprises at least two magnetic resonances among a plurality of magnetic resonances appearing in a microphone mouth wave frequency region generated by at least two anisotropic magnetic fields (H k).
- the electromagnetic interference suppressor is characterized in that the anisotropic magnetic fields have different magnitudes from each other, and chlorinated polyethylene is used as the organic binder.
- the composite magnetic body includes a plurality of magnetic resonances, and each of the plurality of magnetic resonances corresponds to an anisotropic magnetic field having a different size. Appearing in different frequency regions from each other, and the lowest one of the plurality of magnetic resonances is in a frequency region lower than the lower limit of the electromagnetic interference suppression frequency band caused by the composite magnetic layer. An electromagnetic interference suppressor is obtained.
- the diamagnetic powder is a mixture of at least two types of diamagnetic powder having different sizes of magnetic anisotropy. An electromagnetic interference suppressor is obtained.
- the diamagnetic powder has an oxide layer on a surface.
- At least two kinds of ⁇ magnetic powder having magnetic anisotropy of different sizes from each other and chlorinated polyethylene used as an organic binder are mixed and molded to be electrically non-conductive.
- a method for producing a composite magnetic body having good conductivity and having at least two magnetic resonances caused by anisotropic magnetic fields (H k) having different magnitudes from each other is obtained.
- the diamagnetic powder in the method for producing a composite magnetic body, includes an oxide layer on a surface thereof. Is obtained.
- a gas phase gradual acid method or a liquid phase gradual acid method may be used before or during the mixing of the ferromagnetic powder with the organic binder.
- a method for producing a composite magnetic material characterized in that the surface is oxidized by an oxygen-containing mixed gas, is obtained.
- the effective anisotropic magnetic field is an algebraic sum of the demagnetizing field depending on the shape of the sample.
- Means for obtaining a plurality of anisotropic magnetic fields used in the present invention include: These methods may be used. It is important to provide a plurality of anisotropic magnetic fields so as to obtain a desired magnetic loss band. In particular, for the anisotropic magnetic field that gives the magnetic resonance appearing at the lowest frequency side, the dispersion of the imaginary part magnetic permeability (magnetic loss) occurs with the decrease of the real part magnetic permeability. It is necessary to set a value that gives magnetic resonance to a frequency range lower than the lower limit of the electromagnetic interference suppression frequency band.
- a metal ferromagnetic material such as an iron aluminum silicon alloy (Sendust), an iron nickel alloy (Permalloy), or an amorphous alloy having a high high-frequency magnetic permeability is used.
- ⁇ magnetic powder of the present invention powder of an oxide ⁇ magnetic material such as spinel type ferrite or planar type ferrite can be used, and mixed use with the metal soft magnetic powder is also possible.
- chlorinated polyethylene is used to obtain the intended effect of the present invention, that is, to obtain excellent flexibility and flame retardancy. I have.
- Means for obtaining the composite magnetic material by dispersing the constituent elements of the present invention described above is not particularly limited, and a preferred method may be selected based on the properties of the binder used and the ease of the process.
- the composite magnetic body and the electromagnetic interference suppressor of the present invention have a plurality of anisotropic magnetic fields (Hk) having different magnitudes from each other, and accordingly, a plurality of magnetic resonances appear in different frequency regions. Therefore, the imaginary part magnetic permeability /// appearing in different frequency regions due to the plurality of magnetic resonances is superimposed, and as a result, //// dispersion characteristics in a wide band can be obtained.
- the imaginary part permeability ⁇ ⁇ is a magnetic loss term necessary for absorbing electromagnetic waves, and an excellent electromagnetic interference suppression effect appears when the value of is large and over a wide band.
- the magnetic powder used in the present invention has at least its surface oxidized.
- a magnetic powder Fe-At Si alloy, average particle size is 35 ⁇ m, aspect ratio is 5 or more
- titanate coupling 0.8 parts by weight of the treating agent is stirred with a mixer, and the magnetic powder is subjected to a coupling treatment in advance.
- 80 parts by weight of the magnetic powder subjected to the coupling treatment and 20 parts by weight of an organic binder (chlorinated polyethylene) were igiged with a kneader to obtain a mixture.
- a composite magnetic material is obtained.
- the obtained composite magnetic material is rolled by passing it between rolls arranged in parallel to form a sheet. Thereby, an electromagnetic interference suppressor having excellent flexibility and flame retardancy can be obtained.
- the composite magnetic body of the present invention and the electromagnetic interference suppressor using the same have a plurality of anisotropic magnetic fields (Hk) having different magnitudes from each other, and accordingly have a different frequency range. Since multiple magnetic resonances appear, broadband ⁇ ⁇ dispersion characteristics can be obtained.
- the composite magnetic material of the present invention has excellent flexibility and flame retardancy.
- FPCs and FFCs For example, it has become possible to attach it to the housing of electronic devices with complicated shapes, and also to meet severe fire resistance requirements. .
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Electromagnetism (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Soft Magnetic Materials (AREA)
- Hard Magnetic Materials (AREA)
- Coils Or Transformers For Communication (AREA)
- Aerials With Secondary Devices (AREA)
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE69730310T DE69730310T2 (de) | 1996-09-02 | 1997-09-02 | Magnetische kompositfolie, herstellungsverfahren und material zur unterdruckung von elektromagnetischen interferenzen |
EP97937876A EP0871183B1 (en) | 1996-09-02 | 1997-09-02 | Composite magnetic sheet, method for manufacturing the same, and electromagnetic interference suppressing material |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8/231957 | 1996-09-02 | ||
JP23195796A JP3404618B2 (ja) | 1996-09-02 | 1996-09-02 | 電磁干渉抑制体 |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08809220 Continuation | 1996-07-22 | ||
PCT/JP1996/002040 Continuation WO1997004469A1 (fr) | 1995-07-20 | 1996-07-22 | Materiau magnetique composite et produit pour eliminer les interferences electromagnetiques |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09066382 A-371-Of-International | 1997-09-02 | ||
US09374860 Continuation | 1999-08-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998010439A1 true WO1998010439A1 (fr) | 1998-03-12 |
Family
ID=16931716
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1997/003067 WO1998010439A1 (fr) | 1996-09-02 | 1997-09-02 | Materiau magnetique composite, procede de fabrication et materiau permettant de supprimer les interferences electromagnetiques |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0871183B1 (ja) |
JP (1) | JP3404618B2 (ja) |
KR (1) | KR100396257B1 (ja) |
CN (1) | CN1143325C (ja) |
DE (1) | DE69730310T2 (ja) |
TW (1) | TW399350B (ja) |
WO (1) | WO1998010439A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11587705B2 (en) | 2017-09-29 | 2023-02-21 | Maxell, Ltd. | Electromagnetic wave absorbing composition and electromagnetic wave absorbing body |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6432159B1 (en) * | 1999-10-04 | 2002-08-13 | Daido Tokushuko Kabushiki Kaisha | Magnetic mixture |
JP3641797B2 (ja) | 1999-10-18 | 2005-04-27 | Necトーキン株式会社 | 電磁干渉抑制体 |
JP2001210510A (ja) * | 2000-01-28 | 2001-08-03 | Tokin Corp | 軟磁性粉末及びそれを用いた複合磁性体 |
DE10155898A1 (de) * | 2001-11-14 | 2003-05-28 | Vacuumschmelze Gmbh & Co Kg | Induktives Bauelement und Verfahren zu seiner Herstellung |
US20040041121A1 (en) * | 2002-08-30 | 2004-03-04 | Shigeyoshi Yoshida | Magnetic loss material and method of producing the same |
DE60218905T2 (de) * | 2002-11-11 | 2007-07-12 | Nec Tokin Corp., Sendai | Gegen-emi-komponente und gegen-emi-verfahren |
JP4249227B2 (ja) * | 2004-12-03 | 2009-04-02 | ニッタ株式会社 | 電磁干渉抑制体、アンテナ装置、及び電子情報伝達装置 |
JP2014192327A (ja) * | 2013-03-27 | 2014-10-06 | Riken Corp | 近傍界用電波吸収シートおよびその製造方法 |
CN104004307B (zh) * | 2014-04-25 | 2016-08-03 | 电子科技大学 | 一致取向的片状FeSiAl粉体颗粒复合材料制备方法 |
WO2018016522A1 (ja) * | 2016-07-22 | 2018-01-25 | マクセルホールディングス株式会社 | 電磁波吸収体 |
JP6934660B2 (ja) * | 2017-07-31 | 2021-09-15 | 北川工業株式会社 | 電磁波抑制シート |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04328805A (ja) * | 1991-04-30 | 1992-11-17 | Tokin Corp | 形状異方性軟磁性合金粉末及びその製造方法 |
JPH04343207A (ja) * | 1991-05-20 | 1992-11-30 | Kenichi Arai | 磁性材料および誘導電磁器の製造方法 |
JPH05145271A (ja) * | 1991-11-25 | 1993-06-11 | Bando Chem Ind Ltd | 筒状電磁波遮蔽装置 |
JPH06204021A (ja) * | 1993-01-06 | 1994-07-22 | Kawasaki Steel Corp | 複合磁性材料およびその製造方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0935927A (ja) * | 1995-07-20 | 1997-02-07 | Tokin Corp | 複合磁性体及びそれを用いた電磁干渉抑制体 |
JPH0993034A (ja) * | 1995-09-22 | 1997-04-04 | Tokin Corp | 複合磁性体及びその製造方法ならびに電磁干渉抑制体 |
-
1996
- 1996-09-02 JP JP23195796A patent/JP3404618B2/ja not_active Expired - Lifetime
-
1997
- 1997-09-02 DE DE69730310T patent/DE69730310T2/de not_active Expired - Lifetime
- 1997-09-02 EP EP97937876A patent/EP0871183B1/en not_active Expired - Lifetime
- 1997-09-02 WO PCT/JP1997/003067 patent/WO1998010439A1/ja active IP Right Grant
- 1997-09-02 KR KR10-1998-0703163A patent/KR100396257B1/ko not_active IP Right Cessation
- 1997-09-02 TW TW086112620A patent/TW399350B/zh not_active IP Right Cessation
- 1997-09-02 CN CNB971911223A patent/CN1143325C/zh not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04328805A (ja) * | 1991-04-30 | 1992-11-17 | Tokin Corp | 形状異方性軟磁性合金粉末及びその製造方法 |
JPH04343207A (ja) * | 1991-05-20 | 1992-11-30 | Kenichi Arai | 磁性材料および誘導電磁器の製造方法 |
JPH05145271A (ja) * | 1991-11-25 | 1993-06-11 | Bando Chem Ind Ltd | 筒状電磁波遮蔽装置 |
JPH06204021A (ja) * | 1993-01-06 | 1994-07-22 | Kawasaki Steel Corp | 複合磁性材料およびその製造方法 |
Non-Patent Citations (1)
Title |
---|
See also references of EP0871183A4 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11587705B2 (en) | 2017-09-29 | 2023-02-21 | Maxell, Ltd. | Electromagnetic wave absorbing composition and electromagnetic wave absorbing body |
Also Published As
Publication number | Publication date |
---|---|
DE69730310D1 (de) | 2004-09-23 |
DE69730310T2 (de) | 2005-09-01 |
KR100396257B1 (ko) | 2003-10-17 |
JP3404618B2 (ja) | 2003-05-12 |
EP0871183A4 (en) | 2000-04-12 |
EP0871183B1 (en) | 2004-08-18 |
KR20000064303A (ko) | 2000-11-06 |
TW399350B (en) | 2000-07-21 |
JPH1074611A (ja) | 1998-03-17 |
CN1143325C (zh) | 2004-03-24 |
CN1199495A (zh) | 1998-11-18 |
EP0871183A1 (en) | 1998-10-14 |
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