WO1995014748A1 - Wässriges antislipmittel - Google Patents
Wässriges antislipmittel Download PDFInfo
- Publication number
- WO1995014748A1 WO1995014748A1 PCT/EP1994/003744 EP9403744W WO9514748A1 WO 1995014748 A1 WO1995014748 A1 WO 1995014748A1 EP 9403744 W EP9403744 W EP 9403744W WO 9514748 A1 WO9514748 A1 WO 9514748A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- slip agent
- agent according
- slip
- weight
- Prior art date
Links
- 239000012748 slip agent Substances 0.000 title claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 11
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 10
- 229920003023 plastic Polymers 0.000 claims abstract description 10
- 239000004033 plastic Substances 0.000 claims abstract description 10
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004375 Dextrin Substances 0.000 claims abstract description 8
- 229920001353 Dextrin Polymers 0.000 claims abstract description 8
- 235000019425 dextrin Nutrition 0.000 claims abstract description 8
- 229920003086 cellulose ether Polymers 0.000 claims abstract description 6
- 239000004814 polyurethane Substances 0.000 claims abstract description 5
- 229920002635 polyurethane Polymers 0.000 claims abstract description 5
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 5
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 5
- 229920000084 Gum arabic Polymers 0.000 claims abstract description 4
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 4
- 239000000205 acacia gum Substances 0.000 claims abstract description 4
- 235000010443 alginic acid Nutrition 0.000 claims abstract description 4
- 229920000615 alginic acid Polymers 0.000 claims abstract description 4
- 239000005018 casein Substances 0.000 claims abstract description 4
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000021240 caseins Nutrition 0.000 claims abstract description 4
- 229920000159 gelatin Polymers 0.000 claims abstract description 4
- 235000019322 gelatine Nutrition 0.000 claims abstract description 4
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 claims abstract description 4
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 4
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 3
- 239000004584 polyacrylic acid Substances 0.000 claims abstract description 3
- 241000978776 Senegalia senegal Species 0.000 claims abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- -1 polyethylene Polymers 0.000 claims description 13
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 10
- 229920000881 Modified starch Polymers 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 7
- 235000019426 modified starch Nutrition 0.000 claims description 7
- 239000008107 starch Substances 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003380 propellant Substances 0.000 claims description 6
- 150000005846 sugar alcohols Polymers 0.000 claims description 6
- 239000004604 Blowing Agent Substances 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 235000010493 xanthan gum Nutrition 0.000 claims description 4
- 239000000230 xanthan gum Substances 0.000 claims description 4
- 229920001285 xanthan gum Polymers 0.000 claims description 4
- 229940082509 xanthan gum Drugs 0.000 claims description 4
- 108010010803 Gelatin Proteins 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000001294 propane Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 150000000180 1,2-diols Chemical class 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 10
- 239000000443 aerosol Substances 0.000 abstract description 10
- 239000002250 absorbent Substances 0.000 abstract description 8
- 230000002745 absorbent Effects 0.000 abstract description 3
- 239000004088 foaming agent Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000011111 cardboard Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 229960005150 glycerol Drugs 0.000 description 3
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 2
- 235000007173 Abies balsamea Nutrition 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004857 Balsam Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 244000018716 Impatiens biflora Species 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 229940071118 cumenesulfonate Drugs 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
- 241001264730 Callistemon salignus Species 0.000 description 1
- 241000218631 Coniferophyta Species 0.000 description 1
- 101100480530 Danio rerio tal1 gene Proteins 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 101100480538 Mus musculus Tal1 gene Proteins 0.000 description 1
- 101100312945 Pasteurella multocida (strain Pm70) talA gene Proteins 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000004146 Propane-1,2-diol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000001212 derivatisation Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001033 ether group Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- SYUXAJSOZXEFPP-UHFFFAOYSA-N glutin Natural products COc1c(O)cc2OC(=CC(=O)c2c1O)c3ccccc3OC4OC(CO)C(O)C(O)C4O SYUXAJSOZXEFPP-UHFFFAOYSA-N 0.000 description 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- OCNPXKLQSGAGKT-UHFFFAOYSA-N propyl benzenesulfonate Chemical compound CCCOS(=O)(=O)C1=CC=CC=C1 OCNPXKLQSGAGKT-UHFFFAOYSA-N 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/149—Antislip compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
- C09D193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
Definitions
- the present invention relates to an aqueous anti-slip agent and its use for non-absorbent articles.
- Antislip agents are intended to prevent slipping, ie to prevent an unintentional sliding movement of two objects relative to one another, but to enable their separation from one another without further ado. This is generally achieved in that the anti-slip agent opposes large resistance to movements in the sliding direction, movements perpendicular to it, but no or so little resistance that the surfaces of the separated objects are not damaged.
- the raw material basis for these anti-slip agents are usually natural or synthetic macromolecular substances, as are also used for adhesives. Similar to the adhesives, the anti-slip agents can also be applied to an object to be secured free of evaporating solvents or dispersing agents (see, for example, DE-A-19 17 566). This process requires special devices for melting and applying the anti-slip agent.
- the macromolecular substances in the form of a solution in organic solvents or in the form of an aqueous dispersion.
- the anti-slip agents are generally based on aqueous solutions or dispersions today.
- DE-C-1943731 describes the use of aqueous solutions of the colloid xanthan gum as an adhesive for packaging materials.
- DE-C-1262897 proposes the use of aqueous dispersions of polymers of olefinically unsaturated compounds, in particular polyvinyl acetates and their copolymers.
- aqueous dispersions of paraffins and / or polyalkylenes can also be used.
- DD 156612 describes a method for backing carpeting material which gives the carpeting a firm, transparent, non-stick and non-slip finish.
- a low-viscosity mixture of a copolymer latex of butadiene with styrene and / or acrylonitrile with powdery polyvinyl chloride with a mixture solids content of 40 to 55% is produced, applied to the back of the carpet and then dried.
- the addition of the polyvinyl chloride to the butadiene copolymer reduces its otherwise troublesome tack, without interfering with the good non-slip behavior on different types of flooring, such as wood, stone wood and plastic.
- the coating mixture shows very good adhesion properties to natural as well as synthetic fibers.
- Antislip agents based on an organic solution of polymers or resins are generally used for non-water-absorbent articles.
- JP-A-59172569 proposes solutions of ethylene-vinyl acetate copolymers and a hydrogenated glycidyl ester of rosin (ester gum H) in toluene for use in aerosol cans.
- Other conventional anti-slip agents use chlorinated hydrocarbons such as methylene chloride as a solvent for rosin or synthetic polymers such as polybutadiene.
- German patent application P 4230472.5 from September 14, 1992 describes an anti-slip agent for objects that do not absorb water. It contains a) a polymer, in particular a polymer of olefinically unsaturated compounds, b) an alcohol, in particular a monohydric alcohol having 1 to 4 carbon atoms, c) a blowing agent, in particular a mixture of propane and butane and / or dimethyl ether and d) water-soluble or water-dispersible additives, in particular a protective colloid, a defoamer and / or a re-emulsifier.
- a polymer in particular a polymer of olefinically unsaturated compounds
- an alcohol in particular a monohydric alcohol having 1 to 4 carbon atoms
- a blowing agent in particular a mixture of propane and butane and / or dimethyl ether
- water-soluble or water-dispersible additives in particular a protective colloid, a defoamer and / or a
- the object of the invention is to provide antislip agents which do not have these disadvantages, that is to say allow unproblematic processing even on non-water-absorbent objects with plastic surfaces, and lead to a high temperature and water-soluble antislip agent, which contain water or aqueous solutions of hygienically and / or ecologically harmless organic solvents as solvents and / or dispersants without deteriorating handling or usage properties and which can be applied from aerosol cans if necessary.
- the aqueous anti-slip agent according to the invention for objects with plastic surfaces thus contains
- the rosin is a glassy amorphous mass with average molecular weights below 2,000 g / mol. They are obtained from the raw resin of conifers. They mainly consist of unsaturated carboxylic acids with the gross formula C20H30O2 such as abietic acid and its isomers. In addition, however it also contains more or less neutral substances such as fatty acid esters, terpene alcohols and hydrocarbons.
- a derivatized colophonic resin is preferably used, for example a hydrogenated or disproportionated colophonic resin, the derivatization serving above all to increase water solubility, for example saponification or addition of maleic acid.
- Usable rosins and its derivatives are balsam, Tal1 and root resin. Water-soluble balsam resin derivatives with a solubility of at least 3 g in 100 g of water at 25 ° C. are particularly suitable. Water-soluble rosin derivatives are preferably used, in particular saponified derivatives.
- the monohydric or polyhydric alcohols not only serve as solubilizers, they are also essential for the adhesion of the anti-slip agent to the plastic surface. They are therefore preferably liquid and evaporate from the adhesive system at 25 ° C. in accordance with practical requirements. Alcohols with a solubility of more than 3 g in 100 g of water at 25 ° C. are preferably used.
- the alcohols can be aliphatic or cycloaliphatic, saturated or unsaturated hydrocarbons with a straight or branched chain. They can also contain further heteroatoms, e.g. 0 in the form of an ether group.
- dihydric and polyhydric alcohols in particular ethane-1,2-diol, propane-1,2-diol and / or propane-1,2,3-triol.
- Suitable liquefying agents are alkali or alkaline earth metal alkylbenzenesulfonates with up to 18, in particular with 1 to 4, carbon atoms in the alkyl radical, in particular the sodium salt of propylbenzenesulfonate.
- halogenated hydrocarbons are no longer used as propellants for aerosol packaging.
- propane, butane or mixtures thereof, optionally with ethanol, in particular dimethyl ether, are used. But CO2 is also possible.
- the water-soluble polymers are at least one of the following natural or synthetic polymers: gelatin, alginates, glutin, xanthan gum, gum arabic, starch, starch derivatives, dextrin, cellulose ether, casein, polyvinyl pyrrolidone, polyvinyl acrylic acid, polyvinyl methyl ether, polyvinyl acetate , Polyurethane and polyvinyl alcohol.
- Starch derivatives are those which can be obtained by converting native or degraded, for example oxidatively degraded, starch. These starch derivatives are generally reaction products with, for example, ethylene oxide, propylene oxide, acrylonitrile, chloroacetic acid or also epoxypropanesulfonic acid.
- the degree of substitution should be relatively low, approximately between 0.02 and 0.1 DS.
- the commercially available thin, medium or thick-boiling dextrin can be used as the dextrin, which can be obtained in a known manner by breaking down starch.
- Starch, starch derivatives, dextrin and cellulose ether are preferably used.
- antislip agents In order to favorably influence certain processing properties of the antislip agents, other additives such as commercially available defoamers, anti-aging agents and / or agents to facilitate the re-emulsifiability of the dried film can be added.
- additives such as commercially available defoamers, anti-aging agents and / or agents to facilitate the re-emulsifiability of the dried film
- examples of the latter are urea, organic amines such as, for example, triethanola in and / or similar compounds.
- concentration of the individual components in the anti-slip agent is generally
- the viscosity without propellant should be 100 to 3,000, in particular 500 to 1,000, mPa-s (Brookfield, 23 ° C, spindle 3, 20 rev / minute).
- the pH of the anti-slip agent is adjusted to a value between 7 and 10, preferably 8.5 and 9.5, with alkali or ammonia.
- the anti-slip agent preferably does not contain any halogenated organic solvents.
- the solids content of the anti-slip agent is generally 40 to 60% by weight, in particular 50 to 55% by weight. However, it can also lie outside this range if, for example, with lower values a longer evaporation time is accepted or with higher values the evaporation time is reduced.
- the preparation of the anti-slip agent from the individual components is simple and does not pose any difficulties for the person skilled in the art, since it is carried out in the usual way with the usual means.
- the anti-slip agent is also applied to the objects in a known manner, for example by means of rollers, nozzles or brushes, but preferably " sprayed " with a propellant from an aerosol can. It is important that the surfaces are dry before the objects touch one another be stacked.
- the anti-slip agents according to the invention are suitable both for the equipment of water-absorbent objects, and also for the anti-slip equipment of non-water-absorbent objects made of metals or plastics.
- the plastics are e.g. around polystyrene, polycarbonate, polyvinyl chloride and polyethylene terephthalate. But polyethylene and polypropylene can also be effectively equipped with a non-slip finish.
- the anti-slip agents according to the invention have a number of favorable processing properties:
- the adhesive is transparent and does not leave any brittle, crumbling residues when it dries
- agents according to the invention are preferably used as anti-slip agents, this application form is only as one Considering an application example, other applications in which "metered adhesive force is also important" also belong to the scope of the invention, for example the use when winding a web onto a sleeve, the web or the sleeve being made of plastic or paper or cardboard .
- Resitherm CA-HE is a rosin with an acid number of approx. 160 and a saponification number of approx. 170.
- components 1, 2 and 3 were introduced and heated to about 85 ° C. After cooling to 40 to 80 ° C, components 4 and 5 were then added. The viscosity was adjusted to the desired value with water. Finally, component 6 was bleached. The viscosity was 1,800 mPas at 25 ° C, the pH 8.5. The solids content was 65%.
- the active ingredient (75 parts by weight) was filled together with the propellant dimethyl ether (25 parts by weight) into aerosol cans in the usual way.
- an antislip agent for aerosol cans was produced from the following components:
- the viscosity was 800 mPas at 25 ° C, the pH 9 and the solids content 67%. 75 parts by weight of this mixture were filled with aerosol cans in the usual way using 25 parts by weight of dimethyl ether.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
- Laminated Bodies (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK95900715T DK0729496T3 (da) | 1993-11-20 | 1994-11-11 | Vandigt antislipmiddel |
US08/648,099 US5672199A (en) | 1993-11-20 | 1994-11-11 | Water-containing antislip composition |
CA002177030A CA2177030A1 (en) | 1993-11-20 | 1994-11-11 | Aqueous anti-slip agent |
DE59407104T DE59407104D1 (de) | 1993-11-20 | 1994-11-11 | Wässriges antislipmittel |
EP95900715A EP0729496B1 (de) | 1993-11-20 | 1994-11-11 | Wässriges antislipmittel |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4339642A DE4339642A1 (de) | 1993-11-20 | 1993-11-20 | Wäßriges Antislipmittel |
DEP4339642.9 | 1993-11-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995014748A1 true WO1995014748A1 (de) | 1995-06-01 |
Family
ID=6503065
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1994/003744 WO1995014748A1 (de) | 1993-11-20 | 1994-11-11 | Wässriges antislipmittel |
Country Status (8)
Country | Link |
---|---|
US (1) | US5672199A (de) |
EP (1) | EP0729496B1 (de) |
AT (1) | ATE172230T1 (de) |
CA (1) | CA2177030A1 (de) |
DE (2) | DE4339642A1 (de) |
DK (1) | DK0729496T3 (de) |
ES (1) | ES2122508T3 (de) |
WO (1) | WO1995014748A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110894407A (zh) * | 2019-11-26 | 2020-03-20 | 山东柯帷博伟耐火材料有限公司 | 一种无甲醛粘结剂及其应用 |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19529965A1 (de) | 1995-08-14 | 1997-02-20 | Henkel Kgaa | Polyacrylamidhaltige Klebstoffzusammensetzung, ihre Herstellung und Verwendung |
GB2357292A (en) * | 1999-12-17 | 2001-06-20 | Reginald Paul Mitchell | Anti-creep for rugs, mats and door mats |
CN1100840C (zh) * | 1999-12-24 | 2003-02-05 | 中国科学院感光化学研究所 | 喷雾防滑剂及其制备方法 |
GB2364637A (en) * | 2000-07-01 | 2002-02-06 | Reginald Paul Mitchell | Polymer anti-creep for rugs and mats |
DE10060474A1 (de) * | 2000-12-06 | 2002-06-13 | Bayer Ag | Verfahren zur Herstellung von Mischungen aus Polyvinylchlorid und Polymerisaten auf Basis von konjugierten Dienen und Acrylnitril |
US6767586B1 (en) | 2001-10-16 | 2004-07-27 | Steven R. Coven | Method of application of anti-slip material for surfaces |
WO2003041993A1 (en) * | 2001-11-12 | 2003-05-22 | Anna Capozzi | Rug, mat & car mat anti-creep |
GB2406097A (en) * | 2003-09-18 | 2005-03-23 | Natural Building Technologies | A water-based polymer coating composition |
KR100519411B1 (ko) * | 2005-06-28 | 2005-10-06 | 주식회사 케이엠지 | 미끄럼방지제 |
US20090142282A1 (en) * | 2007-12-04 | 2009-06-04 | Jonathan Lee Kendall | High-solids alcoholic solutions of rosin esters for varnish applications |
CZ20199U1 (cs) * | 2009-04-03 | 2009-11-09 | Zemanová@Zdenka | Prípravek pro zabránení smyku mezi dvema povrchy, nádoba pro nanášení tohoto prípravku a obuv s touto nádobou s tímto prípravkem |
CZ305513B6 (cs) * | 2009-04-14 | 2015-11-11 | Genzerová Ludmila | Podrážka obuvi, zejména sportovní, zabraňující smyku po povrchu |
KR101254137B1 (ko) * | 2010-06-04 | 2013-04-15 | 진재호 | 미끄럼 방지 및 화장품 원료용 유성 및 수성 송진액체 제조방법 |
AT511047B1 (de) * | 2011-01-19 | 2014-08-15 | Austria Wirtschaftsservice Gmbh | Zusammensetzungen zur herstellung rutschhemmender oberflächen |
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DE1943732A1 (de) * | 1969-08-28 | 1971-03-11 | Henkel & Cie Gmbh | Haftmittel |
DE2240608A1 (de) * | 1972-08-18 | 1974-02-28 | Kurt Dr Polzhofer | Verfahren zum rutschfestmachen von gegenstaenden |
DD200089A1 (de) * | 1981-07-30 | 1983-03-16 | Wolfgang Nette | Thermoplastisches antislipmittel |
DE3335522A1 (de) * | 1983-09-30 | 1985-04-11 | Jakob 7900 Ulm Schuler | Anti-rutsch-mittel |
DE4230472A1 (de) * | 1992-09-14 | 1994-03-17 | Henkel Kgaa | Antislipmittel |
JPH06136304A (ja) * | 1992-10-29 | 1994-05-17 | Koyo Kagaku Kk | 水系塗料用スリップ剤及びその製造方法 |
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DE200089C (de) * | ||||
DE156612C (de) * | ||||
US2698250A (en) * | 1951-02-28 | 1954-12-28 | William G Leichner | Resinous compositions |
US2921918A (en) * | 1954-06-29 | 1960-01-19 | Us Rubber Co | Method of providing pneumatic tires with an anti-skid coating |
DE1262897B (de) * | 1965-12-24 | 1968-03-07 | Wacker Chemie Gmbh | Haftmittel |
DE1917566A1 (de) * | 1969-04-05 | 1970-12-10 | Hoechst Ag | Verfahren zur Rutschfestausruestung von Verpackungsmaterialien |
BE755201A (fr) * | 1969-08-28 | 1971-02-24 | Henkel & Cie Gmbh | Adhesif pour empecher le glissement ou le deplacement d'elements empaquetes dans des emballages |
DE2031881C3 (de) * | 1970-06-27 | 1981-12-10 | Henkel KGaA, 4000 Düsseldorf | Haftmittel |
US3734801A (en) * | 1970-08-25 | 1973-05-22 | Henkel & Cie Gmbh | Method for preventing the sliding or riding up of packaged articles by coating with adhesive compositions |
JPS59172569A (ja) * | 1983-03-22 | 1984-09-29 | Konishi Kk | エアゾル型スプレ−接着剤 |
US5453219A (en) * | 1990-06-04 | 1995-09-26 | Fox Valley Systems, Inc. | Aerosol-based compositions useful for the production of an abrasive surface and a method for the production thereof |
-
1993
- 1993-11-20 DE DE4339642A patent/DE4339642A1/de not_active Withdrawn
-
1994
- 1994-11-11 DK DK95900715T patent/DK0729496T3/da active
- 1994-11-11 WO PCT/EP1994/003744 patent/WO1995014748A1/de active IP Right Grant
- 1994-11-11 AT AT95900715T patent/ATE172230T1/de not_active IP Right Cessation
- 1994-11-11 ES ES95900715T patent/ES2122508T3/es not_active Expired - Lifetime
- 1994-11-11 CA CA002177030A patent/CA2177030A1/en not_active Abandoned
- 1994-11-11 EP EP95900715A patent/EP0729496B1/de not_active Expired - Lifetime
- 1994-11-11 DE DE59407104T patent/DE59407104D1/de not_active Expired - Fee Related
- 1994-11-11 US US08/648,099 patent/US5672199A/en not_active Expired - Fee Related
Patent Citations (6)
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DE1943732A1 (de) * | 1969-08-28 | 1971-03-11 | Henkel & Cie Gmbh | Haftmittel |
DE2240608A1 (de) * | 1972-08-18 | 1974-02-28 | Kurt Dr Polzhofer | Verfahren zum rutschfestmachen von gegenstaenden |
DD200089A1 (de) * | 1981-07-30 | 1983-03-16 | Wolfgang Nette | Thermoplastisches antislipmittel |
DE3335522A1 (de) * | 1983-09-30 | 1985-04-11 | Jakob 7900 Ulm Schuler | Anti-rutsch-mittel |
DE4230472A1 (de) * | 1992-09-14 | 1994-03-17 | Henkel Kgaa | Antislipmittel |
JPH06136304A (ja) * | 1992-10-29 | 1994-05-17 | Koyo Kagaku Kk | 水系塗料用スリップ剤及びその製造方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110894407A (zh) * | 2019-11-26 | 2020-03-20 | 山东柯帷博伟耐火材料有限公司 | 一种无甲醛粘结剂及其应用 |
Also Published As
Publication number | Publication date |
---|---|
DE4339642A1 (de) | 1995-05-24 |
EP0729496B1 (de) | 1998-10-14 |
ATE172230T1 (de) | 1998-10-15 |
DK0729496T3 (da) | 1999-06-23 |
ES2122508T3 (es) | 1998-12-16 |
EP0729496A1 (de) | 1996-09-04 |
US5672199A (en) | 1997-09-30 |
CA2177030A1 (en) | 1995-06-01 |
DE59407104D1 (de) | 1998-11-19 |
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