US9254398B2 - Self-dispersible coated metal oxide powder, and process for production and use - Google Patents
Self-dispersible coated metal oxide powder, and process for production and use Download PDFInfo
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- US9254398B2 US9254398B2 US13/202,092 US201013202092A US9254398B2 US 9254398 B2 US9254398 B2 US 9254398B2 US 201013202092 A US201013202092 A US 201013202092A US 9254398 B2 US9254398 B2 US 9254398B2
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/85—Polyesters
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/893—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A61Q19/00—Preparations for care of the skin
- A61Q19/04—Preparations for care of the skin for chemically tanning the skin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/22—Compounds of iron
- C09C1/24—Oxides of iron
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/34—Compounds of chromium
- C09C1/346—Chromium oxides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3653—Treatment with inorganic compounds
- C09C1/3661—Coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3669—Treatment with low-molecular organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3684—Treatment with organo-silicon compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
- C09C1/407—Aluminium oxides or hydroxides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
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- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
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Definitions
- the present application relates generally to a self-dispersible particle or powder, compositions containing the self-dispersible particle or powders, and methods for forming such particles or powders and compositions containing the particles or powders.
- Particularly useful compositions that may contain the self-dispersible particles or powders are cosmetic compositions.
- Metal oxides such as titanium dioxide, zinc oxide, and iron oxides have been employed as attenuators of ultraviolet light in applications such as sunscreens, paints, coatings, and plastic films and resins.
- the metal oxide is often present in the end-product as dispersed particles, so better dispersion mechanisms are always needed.
- Metal oxides of large or small particle size, even when coated like methicone and silane, are known to have poor dispersibility in esters, vegetable oil, mineral oil and hydrocarbons. Poor dispersibility can adversely affect UV attenuation and transparency in sunscreens and color strength in pigments, as well as skin feel and formulation stability.
- Dispersion of micro metal oxides have been disclosed in literature.
- the process disclosed in the literature requires milling the metal oxides, and the milling process involves equipment that is not often available to many formulators.
- only mechanical mixers or homogenizers are available to the formulator of the end-product to disperse particulates. Even when a milling process is available, the variation of formulation and complexity of ingredient will make the formulation of a proper dispersion difficult.
- cosmetic formulators are often not familiar with dispersion technology, and do not have time to find out the best dispersion and best use level for their system.
- a self-dispersible metal oxide has a dispersing agent coated on the metal oxide that removes the need to separately add a dispersing agent and improves the dispersibility of the pigment.
- a particulate metal oxide having a coating that includes a polyhydroxy stearic acid in an amount that makes the particulate metal oxide self-dispersible.
- the particulate metal oxide may be titanium dioxide, zinc oxide, aluminum oxide, or an iron oxide.
- a composition that incorporates the self-dispersible particulate metal oxide into a dispersing medium to form a dispersion.
- the coated particulate metal oxide includes a particulate metal oxide substrate having a coating that includes a polyhydroxy stearic acid to modify the surface of the particulate metal oxide.
- the modified surface containing the polyhydroxy stearic acid provides the metal oxide with self-dispersing properties.
- the coated particulate metal oxide is incorporated into a composition such as a cosmetic composition.
- the cosmetic composition may be liquid or dry make-up such as a sunscreen, foundation or pressed powder, lipstick, blush, eye-shadow, or mascara. Additionally, the cosmetic composition may be anhydrous or an emulsion.
- Also disclosed herein is a process for rendering the particulate metal oxide self-dispersible.
- the process includes providing a particulate metal oxide substrate and coating the powder with a composition containing a polyhydroxy stearic acid.
- the self-dispersible powder disclosed herein relates to a particulate metal oxide substrate coated an organic dispersant, a method for producing such coated metal oxides, and cosmetic formulations including the same.
- the self-dispersible property of the coated metal oxide powder makes the powder especially attractive to formulators in the cosmetics industry enabling the novel coated powder to be specified for a wide range of applications without undue concern as to what dispersing agent and/or how much dispersing agent to use.
- the coated powder disclosed herein is suitable for a wide range of cosmetic compositions used in everyday cosmetic products. Unlimited examples include liquid or powder makeup, lipstick, nail enamel, eye shadow, and mascara
- Suitable metal oxides may include, without limitation, titanium dioxide, zinc oxide, iron oxide, alumina oxide, chromium oxide, composites of metal oxides or of a metal oxide and an inorganic salt, and combinations of these metal oxides.
- the metal oxides may have any desired regular or irregular shape including spherical or ball like particles (with regular or irregular porous surfaces), needles, rods, flakes, rhomboids, nodular, acicular, granular, ellipsoidal, hexagonal, prismatic, star-like, Y-shaped, and the like.
- the metal oxide may include micronized particles (i.e., nanoparticles) or pigmentary grade particles. It may be beneficial to use metal oxides that are free of oversize particles that may impart grittiness and are also free of overly fine particles whose presence may be undesirable in the processes of the invention described herein.
- nanoparticles and “micronized particles” are interchangeable and include a material having 5% or more of the nanoparticles, in which the nanoparticles have a size less than about 100 nm.
- pigmentary grade particles are particles having a size greater than 100 nm.
- the micronized metal oxide may have a primary particle size of about 5 nm to about 150 nm if the particles are spherical or granular. If the particles are acicular the primary particle size may be about 5 nm to about 50 nm by about 50 nm to 150 nm. Primary particle size may be analyzed using TEM.
- Suitable organic dispersants may include, without limitation, substituted carboxylic acids, soap bases and polyhydroxy acids.
- typical dispersing agents are those based on ricinoleic acid, hydroxy stearic acid, hydrogenated castor oil fatty acid which contains in addition to 12-hydroxystearic acid small amounts of stearic acid and palmitic acid as taught in the '753 patent and U.S. Pat. No. 7,220,305.
- the organic dispersant is polyhydroxy stearic acid.
- Polyhydroxy stearic acid is a polyester which is obtainable for example by heating hydroxy stearic acid, e.g. commercial 12-hydroxystearic acid, 9- or 10-hydroxystearic acid, at 160° C. to 200° C. in the presence of an inert organic diluent, such as toluene or xylene, and removing from the reaction mixture the water formed in the course of esterification.
- the organic dispersant such as a polyhydroxy stearic acid
- the coating may be a solution that contains the organic dispersant in one or more suitable solvents, i.e., those capable of dissolving the organic dispersant, applied to the metal oxide particles that is allowed to dry.
- suitable solvents i.e., those capable of dissolving the organic dispersant, applied to the metal oxide particles that is allowed to dry.
- the organic dispersant is polyhydroxy stearic acid
- unlimited representative examples of the solvent may be isopropyl alcohol, hexane, heptane, isoheptane, isooctane, and isononane.
- the solvent may alternately be any solvent that dissolves the organic dispersant, promotes even distribution of the polyhydroxy stearic acid over the surface of the substrate powders, and may readily evaporate, optionally upon heating, to facilitate drying.
- the organic dispersant is present on the metal oxide particles in an amount that renders the metal oxide self-dispersible in an organic medium.
- the organic dispersant is PHSA and is present on a metal oxide to provide improved adhesion characteristics, which makes the pigments easier to wet and any agglomerates formed are easier to break in powder or in liquid. Agglomerates are undesirable in cosmetics because it is believed that they create cavities that can entrap excessive oil.
- the PHSA may be applied as a 1% PHSA composition.
- Suitable organic liquid medium for dispersing the self-dispersible metal oxide powder may include, without limitation, esters, oils, hydrocarbons, alkyl modified silicon fluid.
- esters include diisopropyl adipate, isopropyl myristate, and butyl stearate
- oils include vegetable oil and mineral oil
- hydrocarbons include isododecane
- alkyl modified silicon fluid include caprylyl methicone, such as Silsoft 034.
- the particulate metal oxide may comprise substantially pure metal oxide, but in one embodiment the metal oxide particles may include an inorganic coating in addition to the coating containing the organic dispersant.
- the metal oxide particles may be coated with oxides of other elements such as oxides of aluminium, zirconium or silicon, or mixtures thereof such as alumina and silica as disclosed in GB-2205088-A, the teaching of which is incorporated herein by reference.
- the preferred amount of inorganic coating is in the range from 2% to 25%, more preferably 4% to 20%, particularly 6% to 15%, and especially 8% to 12% by weight, calculated with respect to the weight of particulate metal oxide.
- the inorganic coating may be applied using techniques known in the art.
- a typical process comprises forming an aqueous dispersion of metal oxide particles in the presence of a soluble salt of the inorganic element whose oxide will form the coating.
- This dispersion is usually acidic or basic, depending upon the nature of the salt chosen, and precipitation of the inorganic oxide is achieved by adjusting the pH of the dispersion by the addition of acid or alkali, as appropriate.
- the inorganic coating if present, is preferably applied as a first layer to the surface of the metal oxide.
- the particulate metal oxide may include a hydrophobic coating applied to the inorganic coating.
- the hydrophobic coating agent may be, for example, a silicone, a silane, a metal soap, a titanate, an organic wax, and mixtures thereof.
- the hydrophobic coating may alternatively include a fatty acid, for example, a fatty acid containing 10 to 20 carbon atoms, such as lauric acid, stearic acid, isostearic acid, and salts of these fatty acids.
- the fatty acid may be isopropyl titanium trisostearate.
- the hydrophobic coating may be a methicone, a dimethicone, their copolymers or mixtures thereof.
- the silicone may also be an organosilicon compound, for example dimethylpolysiloxanes having a backbone of repeating -Me2SiO— units (“Me” is methyl, CH 3 ), methyl hydrogen polysiloxanes having a backbone of repeating -MeHSiO— units and alkoxysilanes of formula R n OSiH( 4-n ) where “R” is alkyl and “n” is the integer 1, 2 or 3.
- the hydrophobic coating agent may be an alkoxysilanes, for example, an alkyltriethoxy or an alkyltrimethoxy silanes available from OSI Specialities or PCR.
- the alkoxysilane may be a triethoxycaprylylsilane or a perfluoroalkylethyl triethoxysilane having a C3 to C12 alkyl group that is straight or branched.
- One such alkoxysilane is Dynasylan® OCTEO available from Degussa AG.
- the hydrophobic coating agent may be a metal myristate, metal stearate, a metal palmitate, a metal laurate or other fatty acid derivatives known to one of skill in the art.
- the metal for example, may be magnesium or aluminum.
- the hydrophobic coating agent may be an organotitanate as taught in U.S. Pat. No. 4,877,604 to Mitchell Schlossman (“Schlossman '604” hereinafter), the disclosure of which is herein incorporated by reference thereto.
- Schlossman '604 discloses isopropyl titanium triisostearate as one preferred coating agent.
- the hydrophobic coating agent may be a synthetic wax like polyethylene or a natural wax like carnauba wax.
- a suitable solvent is needed.
- a suitable aprotic solvent can be employed for the functionalized silane or other silicon compound.
- the silane can be solubilized in a volatile organic solvent such as isopropyl alcohol, heptane, isoheptane, isooctane, isononane and petroleum distillates such as those available from Phillips Chemical under the trade names or trademarks Soltrol 130, Soltrol 150 and Soltrol 170.
- Another useful solvent for functionalized silicon compounds is an isopar solvent.
- Isopar solvents are a range of solvents each comprising a high-purity, fractionated partially neutralized mixture of isoparaffinic acids which are available in different grades such as isopar C, which comprises C7-C8 solvents, isopar E or isopar G. Water or other suitable solvent may be employed for the organotitanate as described in Schlossman '604.
- the hydrophobic coatings may be applied using any conventional process.
- metal oxide particles are dispersed in water and heated to a temperature in the range of about 50° C. to about 80° C.
- a fatty acid for example, is then deposited on the metal oxide particles by adding a salt of the fatty acid (e.g. sodium stearate) to the dispersion, followed by an acid.
- the metal oxide core particles can be mixed with a solution of the water-repellent material in an organic solvent, followed by evaporation of the solvent.
- the particles are treated with up to 25%, more preferably in the range from 3% to 20%, particularly 6% to 17%, and especially 10% to 15% by weight of organic material calculated with respect to the metal oxide core particles.
- the hydrophobic coating is preferably applied to the particulate metal oxide as a first layer.
- the inorganic and organic coatings may be present in various amounts as taught in U.S. Pat. No. 7,220,305, which is incorporated herein by reference in its entirety.
- the organic dispersant coating may be applied to the metal oxide particulate or powder using a variety of techniques, including those known to a person of ordinary skill in the art.
- the metal oxide can be treated with a suitable coating agent in a liquid medium, for example by mixing or spraying the coating agent with or on the powder.
- Another method may involve making a slurry of the metal oxide and the organic dispersant.
- the coated powder may be dried by heating to remove the solvents, optionally under vacuum if the solvents are volatile solvents.
- the mixture may be heated at a temperature of about 30° C. to about 150° C. to remove the solvent and dry the powder. Other suitable times and temperatures will be known to those of skill in the art, having regard to the materials employed, or can be determined without undue experimentation.
- the powder may be milled or pulverized using, for example, a jet mill, hammer mill, or other suitable mill to a desired size.
- the treated powder may then be dried by heating to remove the solvent and further heated for about 1 to about 10 hours at a temperature of about 30° C. to about 150° C.
- the process may also include milling the treated powder to remove any agglomerates or overly sized coated powders.
- the reactants and reaction conditions employed in treating the metal oxide with the organic dispersant are selected to provide covalent bonding to metal oxide, hydroxide, carbonate, silicate or other reactive moieties on the surfaces of the particulate.
- ionic, hydrogen or van der Waals bonding in addition to, or in the alternative, may also provide satisfactory bonding between the coating and the substrate powder particle.
- the coating agent may react, for example, with hydroxyl groups, oxide ions, available oxygen atoms or other suitable reactive groups normally present on the surface of the cosmetic powder being coated.
- the self-dispersible metal oxide powder having the organic dispersant coating thereon may be added to a dispersing medium to form a slurry, or preferably a liquid dispersion, of the metal oxides.
- the dispersing medium may be any suitable aqueous or organic liquid medium, such as those discussed above.
- liquid dispersion is meant a true dispersion, i.e., where the solid particles are stable to aggregation.
- the particles in the dispersion are relatively uniformly dispersed and resistant to settling out on standing, but if some settling out does occur, the particles can be easily redispersed by simple agitation.
- a C12-C15 alcohol benzoate is mixed in a laboratory mixer, for example, a Hockeyer Lab mixer, at about 800-1000 rpm and treated micro TiO 2 was added slowly with mixing. When all the TiO 2 powder is added, the mixing speed may be increased, for example, to 1500 rpm. A dispersion of TiO 2 in the C12-C15 alcohol benzoate is obtained. In one embodiment, 0.5 kg of the treated micro TiO 2 with a primary size of about 15 ⁇ 80 nm was dispersed in 1 kg of Finsolv TN, a C12-C15 alcohol benzoate, available from Finetex, Inc. with the laboratory mixer according to this procedure to obtain a 40% dispersion of micro TiO 2 . This method is one example of a suitable way to make a metal oxide dispersion and is not meant to be limiting.
- any of the coated powders and/or a dispersion of the coated powders described herein may be incorporated into a cosmetic composition.
- the cosmetic compositions may be anhydrous or an emulsion.
- Some examples of cosmetic compositions in which the powders may be employed include liquid or dry make-ups such as foundation or pressed powder, lipsticks, blushes, eye-shadow, and mascara.
- the coated metal oxides are beneficial in cosmetic compositions in that the powders are self-dispersible, with enhanced dispersibility in organic liquid media, such as esters, oils, and hydrocarbons, and alkyl modified silicone fluids while still allowing the beneficial properties of the metal oxides to be used in the compositions, such as attenuating UV light while being transparent to visible light and reduced skin whitening.
- the particulate metal oxide may be incorporated in the form of a lotion or cream of a solid and/or semi-solid dispersion.
- Suitable solid or semi-solid dispersions may contain, for example, in the range from 50% to 90%, preferably 60% to 85% by weight of particulate metal oxide according to the present invention, together with any one or more of the organic liquid media disclosed herein.
- the particulate metal oxide and dispersions of the present invention are useful as ingredients for preparing sunscreen compositions, especially in the form of emulsions.
- the emulsion may be an oil-in-water, water-in-oil, or a water-in-silicon emulsion.
- the dispersion may further contain conventional additives suitable for use in the intended application, such as conventional cosmetic ingredients used in sunscreens. Because the metal oxides attenuate ultraviolet light, a sunscreen composition may include other sunscreen agents, such as organic materials.
- Suitable organic sunscreens include, without limitation, p-methoxy cinnamic acid esters, salicylic acid esters, p-amino benzoic acid esters, non-sulphonated benzophenone derivatives, derivatives of dibenzoyl methane and esters of 2-cyanoacrylic acid.
- useful organic sunscreens include benzophenone-1, benzophenone-2, benzophenone-3, benzophenone-6, benzophenone-8, benzophenone-12, isopropyl dibenzoyl methane, butyl methoxy dibenzoyl methane, ethyl dihydroxypropyl PABA, glyceryl PABA, octyl dimethyl PABA, octyl methoxycinnamate, homosalate, octyl salicylate, octyl triazone, octocrylene, etocrylene, menthyl anthranilate, and 4-methylbenzylidene camphor.
- coated powders may be incorporated into other industrial products where the particle material is customarily used and where hydrophobic and lipophobic properties are beneficial, for example, in paints, coatings, and plastics.
- a self-dispersible particulate metal oxide powder was prepared with the following coatings applied there to in the order listed in Table 1.
- the coated metal oxide disclosed in Table 1 may be prepared as follows:
- coated metal oxide disclosed in Table 1 may be prepared as follows:
- a dispersion was made using the coated metal oxide powder of Example 1.
- composition including a dispersion, that includes the self-dispersible coated substrate of metal oxides disclosed herein may include at least one biocompatible excipient, such as, without limitation a buffer (neutralizer or pH adjusters), emulsifier, surfactant, diluent, adjuvant, preservative, and/or electrolyte.
- a buffer neutralizer or pH adjusters
- emulsifier emulsifier
- surfactant e.g., surfactant, diluent, adjuvant, preservative, and/or electrolyte.
- metal oxides coated in accordance with the invention are useful in the manufacture of compact powders.
- a compact powder was prepared using the Formula A ingredients of Table 2.
- Part 1 The ingredients of Part 1 were blended using a pulverizer until the color was fully developed.
- the mineral oil of Part 2 was then added with blending using the pulverizer until the resulting mixture was well blended.
- the mixture was then pressed with a conventional compact powder fabricating device at 250 psi.
- the metal oxide in Formula A has only a hydrophobic coating.
- a second compact powder using the Formula B ingredients was made in accordance with the formulation in shown in Table 3.
- Part 1 The ingredients of Part 1 were blended using a pulverizer until the color was fully developed.
- the mineral oil of Part 2 was then added with blending using the pulverizer until the resulting mixture was well blended.
- the mixture was then pressed with a conventional compact powder fabricating device at 250 psi.
- the metal oxide in Formula A has only a hydrophobic coating.
- the metal oxide pigments in the compact of Formula B have a polyhydroxy stearic acid (PHSA) deposit over the hydrophobic treatment.
- PHSA polyhydroxy stearic acid
- the drop test results also indicate that the PHSA coating surprisingly improves the pressability of the power. This means that less liquid binder needs to be used and the spreading of the powder on skin feel is smoother and less greasy.
- Part 1 The ingredients of Part 1 were blended using a pulverizer until the color was fully developed.
- the dimethicone of Part 2 was then added with blending using the pulverizer until the resulting mixture was well blended.
- the mixture was then pressed with a conventional compact powder fabricating device at 250 psi.
- the “treatment” of the sericite with treatment, the Talc N with treatment, and the TiO 2 with treatment of Table 5 includes:
- Treatment A Isopropyl Titanium Triisostearate treatment
- Treatment B Triethoxycaprylylsilane treatment
- Treatment C Polyhydroxy stearic acid and triethoxycaprylylsilane treatment.
- Example 5 Three different compact powders were formed using the procedure of Example 5 where the first compact powder included Treatment A, the second compact powder included Treatment B, and the third compact powder included Treatment C on sericite, Talc N, and TiO 2 . Drop tests were performed on the three powders. The results of the tests are noted in Table 6:
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EP (1) | EP2411162B1 (ko) |
JP (1) | JP6184099B2 (ko) |
KR (1) | KR101770835B1 (ko) |
CN (1) | CN102361702B (ko) |
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US11679068B2 (en) | 2017-09-05 | 2023-06-20 | Vizor, Llc | Hydroxy cinnamate and silanol adduct coated inorganic sunscreen agents |
US11707422B2 (en) | 2017-09-05 | 2023-07-25 | Vizor, Llc | Inorganic sunscreen agents with higher UV radiation protection |
WO2021173367A1 (en) | 2020-02-28 | 2021-09-02 | L'oreal | Powder compositions having reduced fragility |
US11642287B2 (en) | 2020-02-28 | 2023-05-09 | L'oreal | Powder compositions having reduced fragility |
FR3109088A1 (fr) | 2020-04-09 | 2021-10-15 | L'oreal | Compositions de poudre ayant une fragilite reduite |
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KR20110133490A (ko) | 2011-12-12 |
CN102361702A (zh) | 2012-02-22 |
EP2411162A4 (en) | 2012-09-12 |
EP2411162B1 (en) | 2020-04-01 |
JP2012521442A (ja) | 2012-09-13 |
CN102361702B (zh) | 2016-02-03 |
US20160213578A1 (en) | 2016-07-28 |
PL2411162T3 (pl) | 2020-11-02 |
EP2411162A1 (en) | 2012-02-01 |
US20120003287A1 (en) | 2012-01-05 |
KR101770835B1 (ko) | 2017-08-23 |
WO2010111279A1 (en) | 2010-09-30 |
ES2802461T3 (es) | 2021-01-19 |
JP6184099B2 (ja) | 2017-08-23 |
PT2411162T (pt) | 2020-07-03 |
US9662280B2 (en) | 2017-05-30 |
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