US20130045387A1 - Articles, Coating Compositions, and Methods - Google Patents
Articles, Coating Compositions, and Methods Download PDFInfo
- Publication number
- US20130045387A1 US20130045387A1 US13/695,674 US201113695674A US2013045387A1 US 20130045387 A1 US20130045387 A1 US 20130045387A1 US 201113695674 A US201113695674 A US 201113695674A US 2013045387 A1 US2013045387 A1 US 2013045387A1
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- US
- United States
- Prior art keywords
- nanoparticles
- nonspherical
- coating composition
- spherical
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
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- 238000000034 method Methods 0.000 title claims abstract description 64
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- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- AFUGHDIJIUNVTK-UHFFFAOYSA-F O=C(CCO[SiH2]OO[Na])O[Na].O=P(O)(CCO[SiH2]OO[Na])O[Na].O=S(=O)(CC(O)COCCCO[SiH2]OO[Na])O[Na].O=S(=O)(CCCO[SiH2]OO[Na])O[Na].O=S(=O)(O)CC(O)COCCCO[SiH](O)O.O=S(=O)(O)CCCO[SiH](O)O Chemical compound O=C(CCO[SiH2]OO[Na])O[Na].O=P(O)(CCO[SiH2]OO[Na])O[Na].O=S(=O)(CC(O)COCCCO[SiH2]OO[Na])O[Na].O=S(=O)(CCCO[SiH2]OO[Na])O[Na].O=S(=O)(O)CC(O)COCCCO[SiH](O)O.O=S(=O)(O)CCCO[SiH](O)O AFUGHDIJIUNVTK-UHFFFAOYSA-F 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- WPMWEFXCIYCJSA-UHFFFAOYSA-N Tetraethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCO WPMWEFXCIYCJSA-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 102100023185 Transcriptional repressor scratch 1 Human genes 0.000 description 1
- 101710171414 Transcriptional repressor scratch 1 Proteins 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- BKUYVGOACRJHQO-UHFFFAOYSA-N benzenesulfonic acid;sulfuric acid Chemical class OS(O)(=O)=O.OS(=O)(=O)C1=CC=CC=C1 BKUYVGOACRJHQO-UHFFFAOYSA-N 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000003922 charged colloid Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000010415 colloidal nanoparticle Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010511 deprotection reaction Methods 0.000 description 1
- RIYMMMMNTRGESK-UHFFFAOYSA-M dimagnesium;chloride;nitrate Chemical compound [Mg+2].[Mg+2].[Cl-].[O-][N+]([O-])=O RIYMMMMNTRGESK-UHFFFAOYSA-M 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 125000005496 phosphonium group Chemical group 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- FVEFRICMTUKAML-UHFFFAOYSA-M sodium tetradecyl sulfate Chemical class [Na+].CCCCC(CC)CCC(CC(C)C)OS([O-])(=O)=O FVEFRICMTUKAML-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000005341 toughened glass Substances 0.000 description 1
- 238000000411 transmission spectrum Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
- H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02167—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
- H01L31/02168—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells the coatings being antireflective or having enhancing optical properties for the solar cells
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/425—Coatings comprising at least one inhomogeneous layer consisting of a porous layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/465—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific shape
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
- C03C2217/478—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31—Surface property or characteristic of web, sheet or block
- Y10T428/315—Surface modified glass [e.g., tempered, strengthened, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31525—Next to glass or quartz
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31645—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31667—Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
Definitions
- 6,838,178 disclosed a color neutral absorbing film that is applied as a coating on a glass substrate, to which a conductive coating is first applied. An additional metal oxide layer is deposited on the absorbing film.
- the coating is suitable for use in anti-reflective coatings containing other metal oxides to achieve a coated glass article having a visible light transmittance of 30% or greater and a reflectance of less than 5%.
- the coated glass article is absorbing, anti-reflective and conducting.
- U.S. Pat. No. 6,858,306 disclosed a coated article including a glass substrate, a coating of antimony doped tin oxide deposited on and adhering to the glass substrate and a coating of fluorine doped tin oxide.
- the low emittance of the coated glass article when combined with the surprisingly selective solar absorption of the multilayer stack provides improved heat rejection in summer and heat retention in winter, while permitting the transmittance of a relatively high degree of visible light.
- only spherical nanoparticles are functionalized. It should be understood that, in these embodiments, although a certain portion of the population of shperical nanoparticles can be bare particles upon applying the coating composition to a substrate, a large portion, and preferably a majority, of the shperical nanoparticles have functionalities (e.g., epoxy group, amine group, hydroxyl, olefin, alkyne, (meth) acrylato, mercapto, or combinations thereof) covalently bonded thereto.
- functionalities e.g., epoxy group, amine group, hydroxyl, olefin, alkyne, (meth) acrylato, mercapto, or combinations thereof
- the colloidal silica particles obtained by this method are elongate-shaped silica particles that have elongations of a uniform thickness within the range of 5 to 40 nm extending in only one plane.
- the nonspherical silica sol may also be prepared as described by Watanabe et al. in U.S. Pat. No. 5,597,512.
- the functional groups include various chemical groups that allow for binding to the nanoparticles. Such groups are typically provided by functional compound represented by the formula A-L-F2.
- the functional group F1 includes the amine groups.
- the group A is the nanoparticle surface-bonding group
- L can be a bond or any of a variety of organic linkers.
- Organic linkers L can be linear or branched alkylene, arylene, or a combination of alkylene and arylene groups, optionally including heteroatoms.
- the silanol groups on the surfaces of the silica nanoparticles are reacted with at least one silanol, alkoxysilane, or chlorosilane group of a functional compound to form a functionalized nanoparticle.
- exemplary conditions for reacting functional compounds with silica nanoparticles are described in the Examples Section.
- the surface-bonding groups in the described in invention may not be limited to silanols or alkoxy silanes. Ionic bonds or hydrogen bonds and other types of covalent bonds to nanoparticle surfaces may also be included.
- the coating composition includes more than 100 mole-% olefin, alkyne, (meth) acrylato, mercapto groups, more than a monolayer of the olefin, alkyne, (meth) acrylato, mercapto siloxane is created on the particle surface.
- An excess of hydrolyzed olefin, alkyne, (meth) acrylato, mercapto alkoxysilane, when present, can also function as a primer on the surface of the substrate.
- hydrophilic groups can be provided using hydrophilic compounds of the formula A-L-WD.
- Suitable surface-bonding groups A of the hydrophilic compounds are described herein for the epoxy functional compounds, for example. Examples include silanols, alkoxysilanes, or chlorosilanes.
- the surfactant concentration in coating compositions of the present invention is preferably at least 0.01 percent by weight of the coating composition, more preferably at least 0.04 wt %, and even more preferably at least 0.1 wt %. If used, the surfactant concentration is preferably no greater than 10 wt % of the coating composition, more preferably no greater than 5 wt % of the coating composition.
- composition of claim 18 wherein the nonspherical nanoparticles have an average particle size between 1 and 200 nm and an aspect ratio between 2 and 100.
- Nonspherical silica nanoparticles dispersions IPA-ST-UP, ST-OUP, ST-UP and ST-PS-S were obtained from Nissan Chemical Industries, LTD.
- Coating solutions (3 wt %) were prepared by mixing appropriate amounts of SMN and BN solutions with water and surfactants to improve wetting as indicated in Table 1.
- Example 23 was prepared by gradually adding 15.0 g BN5 to 21.0 g SMN5. Then 14.0 g deionized water was added to dilute the solution by the addition of 0.75 g of a 10% solution of TRITON BG10.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2801185A (en) * | 1952-05-16 | 1957-07-30 | Du Pont | Silica hydrosol powder |
| WO2009085680A1 (en) * | 2007-12-26 | 2009-07-09 | 3M Innovative Properties Company | Removable antifogging coatings, articles, coating compositions, and methods |
| US20100035039A1 (en) * | 2008-08-07 | 2010-02-11 | 3M Innovative Properties Company | Acicular silica coating for enhanced hydrophilicity/transmittivity |
Family Cites Families (130)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH219890A (de) | 1939-05-27 | 1942-03-15 | Jenaer Glaswerk Schott & Gen | Verfahren zur Herstellung einer oder mehrerer übereinanderliegender, dünner, widerstandsfähiger Schichten auf festen Gegenständen. |
| US2432484A (en) | 1943-03-12 | 1947-12-09 | American Optical Corp | Reflection reducing coating having a gradually increasing index of refraction |
| US2536764A (en) | 1947-04-05 | 1951-01-02 | American Optical Corp | Method of forming a reflection reducing coating |
| US2601123A (en) | 1947-04-05 | 1952-06-17 | American Optical Corp | Composition for reducing the reflection of light |
| US2803552A (en) | 1953-06-23 | 1957-08-20 | Ca Nat Research Council | Antifog materials and method of producing the same |
| US3075228A (en) | 1958-02-24 | 1963-01-29 | Nathaniel M Elias | Anti-fogging article |
| US3337351A (en) | 1962-01-24 | 1967-08-22 | Union Carbide Corp | Organosilicon anti-fogging agents |
| US3507897A (en) | 1966-07-18 | 1970-04-21 | Union Carbide Corp | Novel silicon sulfonate compositions and novel processes for making same |
| US3819522A (en) | 1972-09-25 | 1974-06-25 | Colgate Palmolive Co | Anti-fogging window cleaner surfactant mixture |
| US3976497A (en) | 1974-06-25 | 1976-08-24 | Dow Corning Corporation | Paint compositions |
| US3986997A (en) | 1974-06-25 | 1976-10-19 | Dow Corning Corporation | Pigment-free coating compositions |
| US4152165A (en) | 1978-04-11 | 1979-05-01 | Minnesota Mining And Manufacturing Company | One-part hydrophilic treatment compositions |
| US4275118A (en) | 1979-01-15 | 1981-06-23 | Dow Corning Corporation | Pigment-free coatings with improved resistance to weathering |
| US4338377A (en) | 1979-10-10 | 1982-07-06 | Minnesota Mining And Manufacturing Company | Sulfonato-organosilanol compounds and aqueous solutions thereof |
| JPS5699263A (en) | 1980-01-10 | 1981-08-10 | Nippon Sheet Glass Co Ltd | Coating composition |
| US4478909A (en) | 1980-10-24 | 1984-10-23 | Toray Industries, Inc. | Anti-fogging coating film |
| JPS5890604A (ja) | 1981-11-25 | 1983-05-30 | Toyota Central Res & Dev Lab Inc | 赤外線遮蔽積層体 |
| JPS58209549A (ja) | 1982-06-01 | 1983-12-06 | 株式会社豊田中央研究所 | 熱線しゃへい積層体 |
| JPS5915473A (ja) | 1982-07-19 | 1984-01-26 | Mitsubishi Petrochem Co Ltd | 防曇剤組成物 |
| US4467073A (en) | 1982-10-20 | 1984-08-21 | Hydromer, Inc. | Transparent anti-fog coating compositions |
| JPS6044147A (ja) | 1983-08-19 | 1985-03-09 | Daicel Chem Ind Ltd | 鋳物砂の製造方法 |
| JPS6044149A (ja) | 1983-08-23 | 1985-03-09 | Toshiba Corp | 真空吸引ガラス鋳型 |
| JPS6044148U (ja) | 1983-08-29 | 1985-03-28 | 日産自動車株式会社 | バ−コ−ド表示装置 |
| US4522958A (en) | 1983-09-06 | 1985-06-11 | Ppg Industries, Inc. | High-solids coating composition for improved rheology control containing chemically modified inorganic microparticles |
| EP0145308A3 (en) | 1983-11-21 | 1986-03-19 | Dow Corning Corporation | Phenolic resin-containing aqueous compositions |
| CA1275208C (en) | 1985-01-25 | 1990-10-16 | Roger W. Lange | Silica coating |
| IL84025A0 (en) | 1986-10-03 | 1988-02-29 | Ppg Industries Inc | Organosiloxane/metal oxide coating compositions and their production |
| US4876039A (en) | 1986-11-04 | 1989-10-24 | Dow Corning Corporation | Process for preparing silicone microparticles cured by a Michael addition reaction |
| US5204219A (en) | 1987-07-30 | 1993-04-20 | Minnesota Mining And Manufacturing Company | Photographic element with novel subbing layer |
| US5221497A (en) | 1988-03-16 | 1993-06-22 | Nissan Chemical Industries, Ltd. | Elongated-shaped silica sol and method for preparing the same |
| US4944294A (en) | 1988-04-20 | 1990-07-31 | Borek Jr Theodore S | Face mask with integral anti-glare, anti-fog eye shield |
| CA2002449C (en) | 1988-12-05 | 2001-05-08 | Mark A. Strobel | Pressure-sensitive article with priming layer |
| US5126394A (en) | 1989-10-18 | 1992-06-30 | Dow Corning Corporation | Radiation curable abrasion resistant coatings from colloidal silica and acrylate monomer |
| US5639546A (en) | 1991-09-03 | 1997-06-17 | Minnesota Mining And Manufacturing Company | Coated article having improved adhesion to organic coatings |
| JPH05163463A (ja) | 1991-12-12 | 1993-06-29 | Japan Synthetic Rubber Co Ltd | コーティング用組成物の製造方法 |
| CA2093686A1 (en) | 1992-05-11 | 1993-11-12 | Gautam A. Patel | Heat curable primerless silicone hardcoat compositions, and thermoplastic composites |
| US5637368A (en) | 1992-06-04 | 1997-06-10 | Minnesota Mining And Manufacturing Company | Adhesive tape having antistatic properties |
| US5286782A (en) | 1992-08-31 | 1994-02-15 | E. I. Du Pont De Nemours And Company | Coating composition of an acrylic polymer, polyol and polyisocyanate crosslinking agent |
| US5354797A (en) | 1992-08-31 | 1994-10-11 | E. I. Du Pont De Nemours And Company | Coating composition of hydroxy functional acrylic polymer, polyol and polyisocyanate crosslinking agent |
| US5873931A (en) | 1992-10-06 | 1999-02-23 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective and anti-fogging properties |
| US5427847A (en) | 1993-05-20 | 1995-06-27 | Rexham Graphics Inc. | Receptor sheet using low glass transition coating |
| JP3517913B2 (ja) | 1993-10-15 | 2004-04-12 | 日産化学工業株式会社 | 細長い形状のシリカゾルの製造法 |
| US5464900A (en) | 1993-10-19 | 1995-11-07 | Minnesota Mining And Manufacturing Company | Water soluble organosiloxane compounds |
| GB9417112D0 (en) | 1994-08-24 | 1994-10-12 | Glaverbel | Coated substrate and process for its formation |
| WO1996018691A2 (en) | 1994-12-12 | 1996-06-20 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective and anti-fogging properties |
| US5585186A (en) | 1994-12-12 | 1996-12-17 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective, and anti-fogging properties |
| DE69634528T2 (de) | 1995-10-06 | 2006-03-23 | Mitsubishi Chemical Corp. | Polyalkoxysiloxane und Verfahren zu deren Herstellung |
| US5820978A (en) | 1995-11-09 | 1998-10-13 | Minnesota Mining And Manufacturing Company | Durability improved colloidal silica coating |
| US5753373A (en) | 1995-12-21 | 1998-05-19 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective and anti-fogging properties |
| US6040053A (en) | 1996-07-19 | 2000-03-21 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective and anti-fogging properties |
| US6165256A (en) | 1996-07-19 | 2000-12-26 | Toto Ltd. | Photocatalytically hydrophilifiable coating composition |
| US5989515A (en) | 1996-07-24 | 1999-11-23 | Nissan Chemical Industries, Ltd. | Process for producing an acidic aqueous alumina sol |
| US5756226A (en) | 1996-09-05 | 1998-05-26 | Sterling Diagnostic Imaging, Inc. | Transparent media for phase change ink printing |
| US5922299A (en) | 1996-11-26 | 1999-07-13 | Battelle Memorial Institute | Mesoporous-silica films, fibers, and powders by evaporation |
| KR19980079940A (ko) | 1997-03-05 | 1998-11-25 | 후지이 히로시 | 빗물오염방지성 도막, 도료 조성물, 도막 형성방법 및 도장물 |
| EP0897898B1 (de) | 1997-08-16 | 2004-04-28 | MERCK PATENT GmbH | Verfahren zur Abscheidung optischer Schichten |
| EP0974560B2 (en) | 1997-12-09 | 2015-12-30 | Nippon Sheet Glass Co., Ltd. | Antireflection glass plate, process for producing the same, and antireflection coating composition |
| ES2255244T3 (es) | 1998-02-06 | 2006-06-16 | E.I. Du Pont De Nemours And Company | Oligomeros reactivos de silicio y composiciones de recubrimeinto obtrenidas a partir de los mismos. |
| US6040378A (en) | 1998-05-15 | 2000-03-21 | Afg Industries, Inc. | Coating for glass substrate for anti-reflective properties with abrasion, chemical and UV resistance |
| WO2000000855A1 (en) | 1998-06-30 | 2000-01-06 | Kimberly-Clark Worldwide, Inc. | Coating composition for reducing reflection and fogging |
| US6395149B1 (en) | 1998-06-30 | 2002-05-28 | 3M Innovative Properties Company | Method of making light colored, electrically conductive coated particles |
| JP4126788B2 (ja) | 1998-12-09 | 2008-07-30 | 日産化学工業株式会社 | シリカ−フッ化マグネシウム水和物複合ゾル及びその製造法 |
| CN1344301A (zh) | 1999-03-17 | 2002-04-10 | 纳幕尔杜邦公司 | 高固含量透明涂料组合物 |
| US6096469A (en) | 1999-05-18 | 2000-08-01 | 3M Innovative Properties Company | Ink receptor media suitable for inkjet printing |
| JP3459408B2 (ja) | 1999-06-18 | 2003-10-20 | 日本山村硝子株式会社 | シリコーンオリゴマー溶液の製造方法及び該溶液から形成されたオルガノポリシロキサン膜 |
| US6858306B1 (en) | 1999-08-10 | 2005-02-22 | Pilkington North America Inc. | Glass article having a solar control coating |
| EP1167313B1 (en) | 1999-12-13 | 2015-09-23 | Nippon Sheet Glass Co., Ltd. | Low-reflection glass article |
| JP2001254072A (ja) | 2000-03-09 | 2001-09-18 | Central Glass Co Ltd | 防曇性組成物、防曇性コーティング剤および防曇性被膜形成基材の製造方法 |
| JP2001316630A (ja) | 2000-05-09 | 2001-11-16 | Nippon Paint Co Ltd | 上塗り用塗料組成物 |
| US7066998B2 (en) | 2000-06-14 | 2006-06-27 | The Procter & Gamble Company | Coatings for modifying hard surfaces and processes for applying the same |
| US6838178B1 (en) | 2000-07-26 | 2005-01-04 | Libbey-Owens-Ford Co. | Glass article with anti-reflective coating |
| US6797391B2 (en) | 2000-08-24 | 2004-09-28 | Basf Nof Coatings Co., Ltd. | Stain resistant coating compositions, methods of coating and coated articles |
| DE10051725A1 (de) | 2000-10-18 | 2002-05-02 | Merck Patent Gmbh | Wäßrige Beschichtungslösung für abriebfeste SiO2-Antireflexschichten |
| US6467897B1 (en) | 2001-01-08 | 2002-10-22 | 3M Innovative Properties Company | Energy curable inks and other compositions incorporating surface modified, nanometer-sized particles |
| FR2827854B1 (fr) | 2001-07-25 | 2003-09-19 | Saint Gobain Rech | Substrat revetu d'un film composite, procede de fabrication et applications |
| CN1538909A (zh) | 2001-11-08 | 2004-10-20 | 日本板硝子株式会社 | 皮膜覆盖物品、以及使用它的功能性皮膜覆盖物品 |
| US6599976B2 (en) | 2001-11-26 | 2003-07-29 | Mitsubishi Chemical Corporation | Coating process and silicon-containing liquid composition |
| DE10158437A1 (de) | 2001-11-29 | 2003-06-12 | Nano X Gmbh | Beschichtung zur dauerhaften Hydrophilierung von Oberflächen und deren Verwendung |
| US7369122B2 (en) | 2001-12-14 | 2008-05-06 | 3M Innovative Properties Company | Touch panel spacer dots and methods of making |
| US20050095420A1 (en) | 2002-03-22 | 2005-05-05 | Institut Fur Neue Materialien Gem. Gmbh | Plastic film with a multilayered interference coating |
| JP4419422B2 (ja) | 2002-06-24 | 2010-02-24 | 三菱化学株式会社 | 活性エネルギー線硬化性有機無機ハイブリッド樹脂組成物 |
| DE10239762A1 (de) | 2002-08-26 | 2004-03-11 | Syntec Gesellschaft Für Chemie Und Technologie Der Informationsaufzeichnung Mbh | Hydrophile Schutzschicht |
| US6727309B1 (en) | 2002-10-08 | 2004-04-27 | 3M Innovative Properties Company | Floor finish composition |
| CN100337914C (zh) | 2002-10-14 | 2007-09-19 | 阿克佐诺贝尔公司 | 含水二氧化硅分散液 |
| CN1754108A (zh) | 2003-02-06 | 2006-03-29 | Sdc技术－亚洲株式会社 | 制造已经受低反射处理的制品的方法,形成低反射层的溶液和经受低反射处理的制品 |
| TWI238894B (en) | 2003-02-21 | 2005-09-01 | Asahi Kasei Corp | Laminate containing silica and application composition for forming porous silica layer |
| JP4370111B2 (ja) | 2003-03-06 | 2009-11-25 | 日華化学株式会社 | 親水化処理剤組成物及び親水性保護膜形成方法 |
| WO2004113966A1 (ja) | 2003-06-18 | 2004-12-29 | Asahi Kasei Kabushiki Kaisha | 反射防止膜 |
| JP2005010470A (ja) * | 2003-06-19 | 2005-01-13 | Asahi Kasei Corp | 反射防止膜用塗布組成物および反射防止膜 |
| US7074463B2 (en) | 2003-09-12 | 2006-07-11 | 3M Innovative Properties Company | Durable optical element |
| US7282272B2 (en) | 2003-09-12 | 2007-10-16 | 3M Innovative Properties Company | Polymerizable compositions comprising nanoparticles |
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-
2010
- 2010-05-11 CN CN201010170156.6A patent/CN102241899B/zh not_active Expired - Fee Related
-
2011
- 2011-04-25 US US13/695,674 patent/US20130045387A1/en not_active Abandoned
- 2011-04-25 PL PL11781000T patent/PL2569260T3/pl unknown
- 2011-04-25 EP EP11781000.2A patent/EP2569260B1/en not_active Revoked
- 2011-04-25 WO PCT/US2011/033723 patent/WO2011142956A2/en active Application Filing
- 2011-04-25 JP JP2013510117A patent/JP5882989B2/ja not_active Expired - Fee Related
-
2015
- 2015-10-23 JP JP2015208700A patent/JP6181729B2/ja not_active Expired - Fee Related
-
2018
- 2018-03-23 US US15/933,412 patent/US10297698B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2801185A (en) * | 1952-05-16 | 1957-07-30 | Du Pont | Silica hydrosol powder |
| WO2009085680A1 (en) * | 2007-12-26 | 2009-07-09 | 3M Innovative Properties Company | Removable antifogging coatings, articles, coating compositions, and methods |
| US20100035039A1 (en) * | 2008-08-07 | 2010-02-11 | 3M Innovative Properties Company | Acicular silica coating for enhanced hydrophilicity/transmittivity |
Non-Patent Citations (2)
| Title |
|---|
| Brinker ("Hydrolysis and Condensation of Silicates: Effects on Structure," Journal of Non-Crystalline Solids 100(1-3), pp. 31-50, March 1988) * |
| Laane et al. ("Photosensitized electron transfer processes in SiO2 colloids and sodium lauryl sulfate micellar systems: Correlation of quantum yields with interfacial surface potentials," Proceedings of the National Academy of Science 78(10), pp. 5928-5932, October 1981) * |
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| CN114042614A (zh) * | 2021-12-09 | 2022-02-15 | 大连理工大学 | 一种大面积制备超亲水薄膜的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011142956A3 (en) | 2012-03-01 |
| US10297698B2 (en) | 2019-05-21 |
| JP2016029181A (ja) | 2016-03-03 |
| CN102241899B (zh) | 2014-05-14 |
| US20180212076A1 (en) | 2018-07-26 |
| PL2569260T3 (pl) | 2017-11-30 |
| JP6181729B2 (ja) | 2017-08-16 |
| WO2011142956A2 (en) | 2011-11-17 |
| JP2013527879A (ja) | 2013-07-04 |
| EP2569260B1 (en) | 2017-06-21 |
| CN102241899A (zh) | 2011-11-16 |
| JP5882989B2 (ja) | 2016-03-09 |
| EP2569260A2 (en) | 2013-03-20 |
| EP2569260A4 (en) | 2014-07-16 |
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