US20070087944A1 - Lubricant compositions - Google Patents
Lubricant compositions Download PDFInfo
- Publication number
- US20070087944A1 US20070087944A1 US10/554,653 US55465304A US2007087944A1 US 20070087944 A1 US20070087944 A1 US 20070087944A1 US 55465304 A US55465304 A US 55465304A US 2007087944 A1 US2007087944 A1 US 2007087944A1
- Authority
- US
- United States
- Prior art keywords
- phosphate
- lubricant composition
- neutral
- sulphur
- mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 0 *P(C)(C)=O Chemical compound *P(C)(C)=O 0.000 description 10
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
- C10M2203/1065—Naphthenic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2221/041—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving sulfurisation of macromolecular compounds, e.g. polyolefins
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
Definitions
- This invention relates to novel lubricant compositions that are useful as lubricants in high load carrying oils, e.g. metal working fluids, gear oils, extreme pressure turbine oils and hydraulic oils.
- the lubricant compositions of the invention are especially useful in metal working fluids.
- the cutting of metal involves the expenditure of significant amounts of energy and the development of high temperatures as the cutting tool removes metal from the workpiece.
- the lubricant used is able to operate efficiently under the conditions of operation. This means essentially that it is capable of working at very high loads and quickly removing the heat generated by the cutting process.
- Mineral oil alone does not have sufficient lubricity to perform this function and it is necessary to incorporate additives to enhance this aspect of the oil's performance.
- the most common extreme pressure additives have been those containing chlorine (for example C14-17 chlorinated paraffins), phosphorus containing additives in the form of neutral triaryl phosphates, alkyl or alkylaryl acid phosphates and alkylpolyalkoxy or alkylarylpolyalkoxy acid phosphates and sulphur carriers (for example sulphurised olefins, sulphurised esters, and sulphurised fats).
- sulphur carriers for example sulphurised olefins, sulphurised esters, and sulphurised fats.
- the level of performance offered by the different additives varies depending on the temperatures at which the active species are released to form a salt layer at the metal surface. This in turn depends on the speed and feed rate of the cutting tool, the type and hardness of the alloy being machined and the specific machining operation.
- oil in water emulsions and water based solutions are also commonly used in applications which require less lubricity.
- additives are required to improve the lubrication performance of the fluid.
- the type of phosphorus-containing additives which are found in metal working fluids are typically alkyl or alkylaryl acid phosphates and alkylpolyalkoxy or alkylarylpolyalkoxy acid phosphates used either as the free acid or neutralised with basic materials such as alkanolamines and caustic soda e.g. products sold under the trade marks of Lubrhophos and Rhodafac; neutral triaryl phosphates e.g. synthetic isopropylated phenyl phosphates such as are available commercially under the Durad trde mark.
- One objective of the present invention is to provide a novel lubricant composition which improves the cutting performance of both neat oil and water based cutting fluids.
- Another objective of the present invention is to replace acid phosphates as extreme pressure/anti wear additives in metal working applications. This objective has been achieved by the combination of certain neutral alkyl phosphorus compounds with certain sulphur carriers.
- a lubricant composition for a high load carrying oil comprising:
- the lubricant composition of the invention can comprise one or more of the compounds of general formulae I to XIII.
- the neutral alkyl phosphorus compound and the sulphur carrier are utilised in a weight ratio of P to S content from 1:50 to 1:1, preferably a weight ratio of 1:1 to 1:30.
- Preferred sulphur carriers are selected from at least one of sulphurised synthetic esters, sulphurised hydrocarbons (e.g. sulphurised olefins), sulphurised vegetable oils and fats, metal sulphonates, metal dialkyldithiophosphates and triaryl phosphorothionates.
- sulphurised synthetic esters e.g. sulphurised hydrocarbons (e.g. sulphurised olefins), sulphurised vegetable oils and fats, metal sulphonates, metal dialkyldithiophosphates and triaryl phosphorothionates.
- the sulphur carriers serve to release sulphur at the cutting face of the workpiece where it reacts to form a lubricating film at relatively high temperatures.
- the present invention is also a high load carrying oil which contains a lubricant composition as described above.
- the high load carrying oil may be a metal working fluid, a gear oil, an extreme pressure turbine oil or a hydraulic oil.
- the present invention is also a method for working metal comprising (a) contacting a metal workpiece with a lubricant composition as described above and (b) working the metal workpiece.
- the lubricant composition of the invention can include other components conventional in the art, e.g. surfactants, non-ionic alcohols.
- Durad is a registered trade mark of Great Lakes Chemical Corporation.
- an automatic drilling machine is used to drill holes in metal discs 40 mm thick.
- the holes are 18 mm deep while, for oil-based cutting fluids, the drill feeds and speeds were 0.13 mm/rev (or 156 mm/min) and 1200 rpm respectively. Tests were carried out until the drill failed either due to breakage or to excessive wear. The average of at least duplicate test results are quoted.
- the metal used was EN24T carbon steel; the drill feeds and speeds were as indicated below and the base stock was an ISO VG 22 paraffinic oil. In this case the S/P ratio was 13:1.
- the formulation containing Durad TiBP is seen to be significantly more active than the chlorparaffin.
- Formulation (w/w) 1 2 3 TiBP 0.6 — Sulphur carrier (36.7% sulphur - all active) 2.5 — 4.3 Chlorparaffin (40% chlorine) — 8.0 — ISO VG 22 paraffinic oil 96.9 92.0 95.7 Holes drilled to failure 280 140 100
- B Drill Life Tests on Stainless Steel Using Neat Oil: A Comparison with Acid Phosphates
- Stainless steel type 304 was used for this study.
- the sulphur carriers used were a 4:1 mix of a sulphurised fatty acid ester (26% total sulphur of which 15% is active) and a dialkyl polysulphide (40% total sulphur of which 36% is active).
- the levels of sulphur and phosphorus used were 1.5% and 0.5% respectively giving an S/P ratio of 3:1.
- the oil used was an ISO VG 22 Group 1 base.
- Durad TiBP is seen to be a most effective additive which in combination with the sulphur carriers shows a significant improvement over the sulphur carriers alone.
- the sulphur carriers used RC2526 and RC2540 were the same as used in the previous Examples.
- the drill feed rate was 150 mm/min and the speed was 1500 rpm. The depth of hole was 18 mm.
- Formulation (w/w) Holes drilled to failure Sulphur carriers alone 56 Sulphur carriers plus Dioctyl octyl phosphonate 336 Sulphur carriers plus TBEP 500+
- lubricity additives such as fatty oils and long chain esters can be used in cutting fluids, these were not included in the formulations shown above.
- a major benefit of the present invention is that neutral alkyl phosphorus compounds provide a synergistic performance with sulphur carriers in both neat oil and aqueous cutting fluids on both mild steel and stainless steel. Such a synergistic combination enables the formulation of cutting fluids with the following properties:
- neutral alkyl phosphorus compounds also allows higher levels of phosphorus to be used when necessary. Where acid phosphates are used, the acidity effectively limits the level of phosphorus that can be used because the acid can become corrosive at high levels. This allows for more flexibility in formulating mixtures of P/S and higher levels where necessary depending on the severity of the worling process.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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GB0309571 | 2003-04-28 | ||
GB0309571.8 | 2003-04-28 | ||
PCT/GB2004/001750 WO2004096959A1 (en) | 2003-04-28 | 2004-04-23 | Lubricant compositions |
Publications (1)
Publication Number | Publication Date |
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US20070087944A1 true US20070087944A1 (en) | 2007-04-19 |
Family
ID=33397008
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/554,653 Abandoned US20070087944A1 (en) | 2003-04-28 | 2004-04-23 | Lubricant compositions |
Country Status (5)
Country | Link |
---|---|
US (1) | US20070087944A1 (ko) |
EP (1) | EP1618173A1 (ko) |
JP (1) | JP2006524734A (ko) |
KR (1) | KR20060015536A (ko) |
WO (1) | WO2004096959A1 (ko) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090036333A1 (en) * | 2007-07-31 | 2009-02-05 | Chevron U.S.A. Inc. | Metalworking Fluid Compositions and Preparation Thereof |
US20090036338A1 (en) * | 2007-07-31 | 2009-02-05 | Chevron U.S.A. Inc. | Metalworking Fluid Compositions and Preparation Thereof |
WO2010119417A1 (en) * | 2009-04-15 | 2010-10-21 | Dorf Ketal Chemicals (I) Pvt. Ltd. | An effective novel non - polymeric and non - fouling additive for inhibiting high - temperature naphthenic acid corrosion and method of using the same |
US10414964B2 (en) | 2015-06-30 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Lubricant compositions containing phosphates and/or phosphites and methods of making and using same |
CN111662773A (zh) * | 2019-03-07 | 2020-09-15 | 东莞市鹏润压铸材料科技有限公司 | 一种长效全合成镁合金切削液及加工方法 |
US10844264B2 (en) | 2015-06-30 | 2020-11-24 | Exxonmobil Chemical Patents Inc. | Lubricant compositions comprising diol functional groups and methods of making and using same |
US11274261B2 (en) * | 2018-11-19 | 2022-03-15 | Lamberti Spa | Lubricant additives for metal working |
US20240076571A1 (en) * | 2020-12-15 | 2024-03-07 | Totalenergies Onetech | Lubricating composition to prevent corrosion and/or tribocorrosion of metallic parts in an engine |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0420256D0 (en) | 2004-09-13 | 2004-10-13 | Cassells John M | Method and apparatus for sampling and analysis of fluids |
EP1690920A1 (en) * | 2005-02-11 | 2006-08-16 | JohnsonDiversey, Inc. | Lubricant concentrate containing a phosphate triester |
JP4979244B2 (ja) * | 2006-02-28 | 2012-07-18 | Jx日鉱日石エネルギー株式会社 | 金属加工油組成物 |
JP5232372B2 (ja) * | 2006-09-26 | 2013-07-10 | 株式会社ネオス | 水溶性金属加工油剤組成物 |
EP2147968A1 (en) | 2008-06-05 | 2010-01-27 | Castrol Limited | Compositions and methods |
US9771540B2 (en) | 2009-01-20 | 2017-09-26 | Exxonmobil Research And Engineering Company | Hydraulic oil compositions with improved hydraulic motor efficiency |
JP2017132875A (ja) | 2016-01-27 | 2017-08-03 | 東燃ゼネラル石油株式会社 | 潤滑油組成物 |
JP6730122B2 (ja) * | 2016-07-28 | 2020-07-29 | Emgルブリカンツ合同会社 | 潤滑油組成物 |
JP7099876B2 (ja) * | 2018-05-30 | 2022-07-12 | 出光興産株式会社 | 潤滑油組成物及びその製造方法、駆動系機器の潤滑方法並びに駆動系機器 |
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- 2004-04-23 KR KR1020057020339A patent/KR20060015536A/ko not_active Application Discontinuation
- 2004-04-23 EP EP04729132A patent/EP1618173A1/en not_active Withdrawn
- 2004-04-23 JP JP2006506173A patent/JP2006524734A/ja active Pending
- 2004-04-23 WO PCT/GB2004/001750 patent/WO2004096959A1/en active Application Filing
- 2004-04-23 US US10/554,653 patent/US20070087944A1/en not_active Abandoned
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
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US20090036333A1 (en) * | 2007-07-31 | 2009-02-05 | Chevron U.S.A. Inc. | Metalworking Fluid Compositions and Preparation Thereof |
US20090036338A1 (en) * | 2007-07-31 | 2009-02-05 | Chevron U.S.A. Inc. | Metalworking Fluid Compositions and Preparation Thereof |
KR101644592B1 (ko) | 2009-04-15 | 2016-08-01 | 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 | 고온 나프텐산 부식 억제에 효과적인 신규 비중합 및 논-파울링 첨가제, 및 이를 이용한 고온 나프텐산 부식 억제 방법 |
KR20120013380A (ko) * | 2009-04-15 | 2012-02-14 | 도르프 케탈 케미칼즈 (아이) 피브이티 리미티드 | 고온 나프텐산 부식 억제에 효과적인 신규 비중합 및 논-파울링 첨가제, 및 이를 이용한 고온 나프텐산 부식 억제 방법 |
CN102459521A (zh) * | 2009-04-15 | 2012-05-16 | 多尔夫凯塔尔化学制品(I)私人有限公司 | 用于抑制高温环烷酸腐蚀的有效的新型非聚合物且不污性添加剂及其使用方法 |
AU2010238162B2 (en) * | 2009-04-15 | 2014-05-15 | Dorf Ketal Chemicals (I) Pvt. Ltd. | An effective novel non - polymeric and non - fouling additive for inhibiting high - temperature naphthenic acid corrosion and method of using the same |
WO2010119417A1 (en) * | 2009-04-15 | 2010-10-21 | Dorf Ketal Chemicals (I) Pvt. Ltd. | An effective novel non - polymeric and non - fouling additive for inhibiting high - temperature naphthenic acid corrosion and method of using the same |
US9777230B2 (en) | 2009-04-15 | 2017-10-03 | Dorf Ketal Chemicals (India) Private Limited | Effective novel non-polymeric and non-fouling additive for inhibiting high-temperature naphthenic acid corrosion and method of using the same |
US10414964B2 (en) | 2015-06-30 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Lubricant compositions containing phosphates and/or phosphites and methods of making and using same |
US10844264B2 (en) | 2015-06-30 | 2020-11-24 | Exxonmobil Chemical Patents Inc. | Lubricant compositions comprising diol functional groups and methods of making and using same |
US11274261B2 (en) * | 2018-11-19 | 2022-03-15 | Lamberti Spa | Lubricant additives for metal working |
CN111662773A (zh) * | 2019-03-07 | 2020-09-15 | 东莞市鹏润压铸材料科技有限公司 | 一种长效全合成镁合金切削液及加工方法 |
US20240076571A1 (en) * | 2020-12-15 | 2024-03-07 | Totalenergies Onetech | Lubricating composition to prevent corrosion and/or tribocorrosion of metallic parts in an engine |
Also Published As
Publication number | Publication date |
---|---|
EP1618173A1 (en) | 2006-01-25 |
WO2004096959A1 (en) | 2004-11-11 |
KR20060015536A (ko) | 2006-02-17 |
JP2006524734A (ja) | 2006-11-02 |
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