US20050205883A1 - Photonic crystal light emitting device - Google Patents
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- US20050205883A1 US20050205883A1 US10/804,810 US80481004A US2005205883A1 US 20050205883 A1 US20050205883 A1 US 20050205883A1 US 80481004 A US80481004 A US 80481004A US 2005205883 A1 US2005205883 A1 US 2005205883A1
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
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- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/10—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a light reflecting structure, e.g. semiconductor Bragg reflector
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- H—ELECTRICITY
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- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/20—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/36—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
- H01L33/38—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape
- H01L33/382—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape the electrode extending partially in or entirely through the semiconductor body
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Definitions
- the present invention relates to semiconductor light emitting devices including photonic crystal structures.
- LEDs Light emitting diodes
- An LED includes a forward biased p-n junction. When driven by a current, electrons and holes are injected into the junction region, where they recombine and release their energy by emitting photons.
- the quality of an LED can be characterized, for example, by its extraction efficiency, which measures the intensity of the emitted light for a given number of photons generated within the LED chip.
- the extraction efficiency is limited, for example, by the emitted photons suffering multiple total internal reflections at the walls of the high refractive index semiconductor medium. As a result, the emitted photons do not escape into free space, leading to poor extraction efficiencies, typically less than 30%.
- the extraction efficiency can be increased, for example, by enlarging the spatial angle in which the emitted photons can escape by developing suitable geometries, including cubic, cylindrical, pyramidal, and dome like shapes.
- suitable geometries including cubic, cylindrical, pyramidal, and dome like shapes.
- none of these geometries can entirely eliminate losses from total internal reflection.
- a further source of loss is the reflection caused by the refractive index mismatch between the LED and the surrounding media. While such losses could be reduced with an anti-reflection coating, complete cancellation of reflection can be achieved only at a specific photon energy and one angle of incidence.
- U.S. Pat. No. 5,955,749 entitled “Light Emitting Device Utilizing a Periodic Dielectric Structure,” granted to J. Joannopoulos et al., describes an approach to the problem of enhancing the extraction efficiency.
- a photonic crystal is created by forming a lattice of holes completely through the semiconductor layers of the light emitting diode.
- the lattice of holes creates a medium with a periodically modulated dielectric constant, affecting the way light propagates through the medium.
- the photons of the light emitting diode can be characterized by their spectrum or dispersion relation, describing the relation between the energy and the wavelength of the photons.
- the relationship may be plotted, yielding a photonic band diagram consisting of energy bands, or photonic bands, separated by band gaps.
- the photonic band diagram is analogous to the spectrum of electrons in crystalline lattices as expressed in an electronic band diagram, the photonic band diagram is unrelated to the electronic band diagram.
- U.S. Pat. No. 5,955,749 describes an n-doped layer, an active layer, a p-doped layer, and a lattice of holes formed in these layers.
- the device of U.S. Pat. No. 5,955,749 is not operational and therefore is not a LED.
- electrodes are not described, even though electrodes are needed for the successful operation of a photonic crystal LED (“PXLED”).
- PXLED photonic crystal LED
- the fabrication of electrodes in regular LEDs is known in the art, for PXLEDs neither the fabrication of electrodes, nor their influence on the operation of the PXLED is obvious.
- suitably aligning the mask of the electrode layer with the lattice of holes may require new fabrication techniques.
- electrodes are typically thought to reduce the extraction efficiency as they reflect a portion of the emitted photons back into the LED, and absorb another portion of the emitted light.
- U.S. Pat. No. 5,955,749 proposes fabricating photonic crystal light emitting devices from GaAs.
- GaAs is indeed a convenient and hence popular material for fabricating regular LEDs.
- the surface recombination velocity expresses the rate of the recombination of electrons and holes on the surface of the diode. Electrons and holes are present in the junction region of the LED, originating from the n-doped layer and the p-doped layer, respectively.
- a photonic crystal LED can be formed from Lee et al.'s light emitting design by including electrodes. The addition of the electrodes, however, will substantially affect the extraction and the spontaneous emission of the LED. Since this effect is unknown, it cannot be disregarded in the design of a LED. Since the Lee et al. design does not include such electrodes, the overall characteristics of an LED formed from that design are unclear. This questions the usefulness of the design of Lee et al.
- a photonic crystal structure is formed in an n-type region of a III-nitride semiconductor structure including an active region sandwiched between an n-type region and a p-type region.
- a reflector is formed on a surface of the p-type region opposite the active region.
- the growth substrate on which the n-type region, active region, and p-type region are grown is removed, in order to facilitate forming the photonic crystal in an n-type region of the device, and to facilitate forming the reflector on a surface of the p-type region underlying the photonic crystal.
- the photonic crystal and reflector form a resonant cavity, which may allow control of light emitted by the active region.
- FIG. 1 is a cross sectional view of a photonic crystal light emitting diode.
- FIG. 2 is a cross sectional view of an embodiment of a photonic crystal light emitting device lacking a growth substrate.
- FIG. 3 is a plan view of the device of FIG. 2 .
- FIG. 4 illustrates a method of fabricating the device of FIG. 2 .
- FIG. 5 illustrates an epitaxial structure prior to bonding to a host substrate.
- FIG. 6 illustrates a method of bonding an epitaxial structure to a host substrate.
- FIG. 7 illustrates a method of removing a sapphire substrate from a III-nitride epitaxial structure.
- FIG. 8 illustrates photoelectrochemical etching to thin the epitaxial layers after growth substrate removal.
- FIGS. 9-12 illustrate a method of forming a photonic crystal structure.
- FIG. 13 illustrates an alternative embodiment of the present invention.
- FIGS. 14A-14D are cut away plan views of the device of FIG. 13 .
- FIG. 15 is a plan view of a photonic crystal structure comprising a planar lattice of holes.
- FIGS. 16A and 16B illustrate a method of forming a photonic crystal structure.
- FIG. 1 illustrates a III-nitride photonic crystal LED (PXLED) 100 , described in more detail in application Ser. No. 10/059,588, “LED Efficiency Using Photonic Crystal Structure,” filed Jan. 28, 2002 and incorporated herein by reference.
- PXLED III-nitride photonic crystal LED
- an n-type region 108 is formed over host substrate 102 which may be, for example, sapphire, SiC, or GaN; an active region 112 is formed over n-type region 108 ; and a p-type region 116 is formed over active region 112 .
- host substrate 102 which may be, for example, sapphire, SiC, or GaN
- an active region 112 is formed over n-type region 108
- a p-type region 116 is formed over active region 112 .
- regions 108 , 112 , and 116 may be a single layer or multiple layers of the same or different composition, thickness, or dopant concentration.
- a portion of p-type region 116 and active region 112 are etched away to expose a portion of n-type region 108 , then a p-contact 120 is formed on p-type region 116 and an n-contact 104 is formed on the exposed portion of n-type region 108 .
- Active region 112 includes a junction region where electrons from n-type region 108 combine with holes of p-type region 116 and ideally emit energy in the form of photons.
- Active layer 112 may include a quantum well structure to optimize the generation of photons. Many different quantum well structures have been described, for example, by G. B. Stringfellow and M. George Craford in “High Brightness Light Emitting Diodes,” published by the Associated Press in 1997.
- the photonic crystal of PXLED 100 of FIG. 1 is created by forming a periodic structure of holes 122 - i in the LED.
- the photonic crystal structure in the device of FIG. 1 may be formed by, for example, dry etching into the p-type region to form a periodic structure. Dry etching could be reactive ion, inductively coupled plasma, focused ion beam, sputter etching, electron cyclotron resonance, or chemically assisted ion beam etching.
- Dry etching of p-type material is problematic because etching can damage the crystal, causing vacancies which create n-type donors.
- p-type region 116 the presence of n-type donors lowers the concentration of holes and, in cases of severe damage to the crystal, can change the conductivity type of region 116 to n-type.
- the inventors have discovered that the damage caused by dry etching is not limited to a localized area around the etched region, and may propagate vertically and laterally through the non-etched areas of the crystal, possibly eliminating the p-n junction and rendering the device electrically non-operational.
- 5,955,749 also etch through p-type material, and therefore may suffer from the same widespread damage observed by the inventors.
- portions of the active region are removed to form the photonic crystal structure, reducing the amount of active region material and potentially reducing the amount of light generated in the device.
- etching through the quantum wells creates surface recombination, potentially lowering the efficiency of the device.
- a photonic crystal is formed in an n-type layer of a III-nitride device attached to a host substrate and from which the growth substrate has been removed.
- Such devices may emit light between about 280 and about 650 nm and usually emit light between about 420 and about 550 nm.
- FIG. 2 is a cross sectional view of an embodiment of the invention.
- FIG. 3 is a plan view of the device of FIG. 2 .
- the photonic crystal 122 is formed in n-type region 108 , rather than p-type region 116 .
- N-contact 10 is formed on a region of n-type region 108 that is not textured with the photonic crystal, though in other embodiments n-contact 10 may be formed on the photonic crystal area of n-type region 108 . Since the photonic crystal is formed in an n-type region, the n-type material is able to laterally inject current from contact 10 to photonic crystal 122 . Light is extracted from the device through photonic crystal 122 , thus the arrangement of n-contact 10 is selected to maximize the area of the photonic crystal. For example, as illustrated in FIG. 3 , n-contact 10 may surround photonic crystal region 122 - i .
- N-contact 10 is not limited to a ring contact but could also be a grid or other structure that facilitates proper current spreading. To avoid light being absorbed by the n-contact 10 , implantation or a dielectric can be used on the epitaxial material under n-contact 10 , preventing current flow and light generation in that area.
- a reflective p-contact 12 is formed on p-type region 116 . In contrast to the device illustrated in FIG. 1 , the device of FIG. 2 has the p- and n-contacts formed on opposite sides of the device.
- P-contact 12 connects the epitaxial layers 20 to a host substrate 16 either directly or via optional bonding layers 14 .
- An optional contact 18 may be formed on the surface of host substrate 16 opposite the device layers 20 .
- FIGS. 13 and 14 A- 14 D illustrate an alternative embodiment of the present invention.
- FIGS. 14A, 14B , 14 C, and 14 D are cut away plan views along axes 90 , 91 , 92 , and 93 , respectively, illustrated in the cross sectional view of FIG. 13 .
- both p and n-contacts 12 and 10 are on the host substrate side of the device, eliminating absorption of light by a top side n-contact, as in the device of FIGS. 2 and 3 .
- One or more vias are etched down to n-type region 108 through p-type region 116 and active region 112 to make n-contact 10 .
- Host substrate structure 49 is fabricated in a layered structure to electrically isolate the p- and n-contacts.
- An example of the layer structure is illustrated by FIGS. 14A-14D , which show plan view slices of the host substrate along axes 90 , 91 , 92 , and 93 of FIG. 13 .
- N-metal 301 and p-metal 303 are routed such that at the bottom of the host substrate the positive and negative contacts are separate and can be easily soldered to another structure.
- N-metal 301 and p-metal 303 may be electrically isolated by dielectric 305 .
- the photonic crystal structure of the device to be formed in an n-type region.
- Etching the photonic crystal structure in an n-type region rather than a p-type region avoids the type-conversion problem associated with p-type III-nitrides, described above. Also, vacancies introduced in the n-type region from etching do not affect the conductivity of the material.
- the photonic structure in n-type region 108 is separated from p-type region 116 and active region 112 , damage to these regions caused by etching the photonic structure is avoided.
- the exposed top n-type layer allows for formation of the photonic crystal proximal to the active region. In alternative embodiments where surface recombination is low the photonic crystal may penetrate the active region and p-type region.
- a device with an exposed top n-type region may be formed by growing the p-type region first on a growth substrate, followed by an active region and n-type region. Ignoring the growth difficulties, this would present n-type layer on the surface just as in FIG. 2 , such that etching damage is not a concern.
- Contacts to the p-GaN layers would have to be formed on the surface by first exposing the p-type layers by etching a mesa. Therefore current would have to spread laterally along resistive p-type layers, creating a device with high operating voltage, a result that is undesirable in many applications.
- the substrate could be removed from this structure so that the operating voltage is not high. This is done by first bonding a host to the top n-type layers and then removing the growth substrate. Next etching is performed to remove the initial growth layers and expose the p-type region. Then a second bonding step with a second host is performed on the now-exposed p-type layers. The first host is removed re-exposing the n-type region for photonic crystal formation. The resulting structure is the same as FIG. 2 .
- the photonic crystal structure can include a periodic variation of the thickness of n-type region 108 , with alternating maxima and minima.
- An example is a grating (one-dimensional lattice) or planar lattice of holes 122 (two-dimensional lattice).
- the lattice is characterized by the diameter of the holes, d, the lattice constant a, which measures the distance between the centers of nearest neighbor holes, the depth of the holes w, and the dielectric constant of the dielectric, disposed in the holes, ⁇ h .
- Parameters a, d, w, and ⁇ h influence the density of states of the bands, and in particular, the density of states at the band edges of the photonic crystal's spectrum.
- Parameters a, d, w, and ⁇ h thus influence the radiation pattern emitted by the device, and can be selected to enhance the extraction efficiency from the device.
- the radiation pattern of the emitted light can be narrowed, increasing the radiance of the LED. This is useful in applications where light at only specific angles is useful.
- the photonic crystal parameters are chosen such that greater than 50% of radiation exiting the device is emitted in an exit cone defined by an angle of 45 degrees to an axis normal to a surface of the device.
- Holes 122 - i can be arranged to form triangular, square, hexagonal, honeycomb, or other well-known two-dimensional lattice types. In some embodiments, different lattice types are formed in different regions of the device. Holes 122 - i can have circular, square, hexagonal, or other cross sections. In some embodiments, the lattice spacing a is between about 0.1 ⁇ and about 10 ⁇ , preferably between about 0.1 ⁇ and about 4 ⁇ , where ⁇ is the wavelength in the device of light emitted by the active region. In some embodiments, holes 122 may have a diameter d between about 0.1 a and about 0.5 a, where a is the lattice constant. Holes 122 - i can be filled with air or with an optional dielectric 11 ( FIG. 2 ) of dielectric constant ⁇ h , often between about 1 and about 16. Possible dielectrics include silicon oxides.
- Photonic crystal 122 and the reflection of the photonic crystal from reflective p-contact 12 form a GaN resonant cavity.
- the resonant cavity offers superior control of the light.
- the GaN cavity is thinned the optical mode volume is reduced. Fewer waveguided modes can be trapped in the cavity increasing the chances for the light to exit the device. This can be explained in the following discussion.
- the photonic crystal can affect the waveguided modes by scattering them out of the crystal. As the number of waveguided modes is reduced the more efficient the light extraction of the LED. For example if the epitaxial layers are thin enough to support only one waveguided mode (m), then initially 50% of the light would exit the GaN (L out ) and 50% would be waveguided in the epitaxial layers (L in ).
- the thickness of the cavity i.e. the thickness of epitaxial layers 20
- the thickness of epitaxial layers 20 is selected such that the epitaxial layers are as thin as possible to reduce the number of waveguided modes, but thick enough to efficiently spread current.
- the thickness of epitaxial layers 20 is less than about 1 ⁇ m, and preferably less than about 0.5 ⁇ m.
- the thickness of epitaxial layers 20 is between about ⁇ and about 5 ⁇ , between about 0.18 ⁇ m and about 0.94 ⁇ m for a device that emits 450 nm light.
- Holes 122 have a depth between about 0.05 ⁇ and the entire thickness of n-type region 108 . Generally, holes 122 are formed entirely within n-type region 08 and do not penetrate into the active region. N-type region 108 usually has a thickness of about 0.1 microns or more. The depth of holes 122 is selected to place the bottoms of holes 122 as close to the active region as possible without penetrating the active region. In alternative embodiments the photonic crystal penetrates the active layers and p-type layers.
- the radiation pattern emitted from the device can be tuned by changing the lattice type, distance between the active region and the photonic crystal, lattice parameter a, diameter d, depth w, and epitaxial thickness ( 20 ).
- the lattice parameter a and diameter d are illustrated in FIG. 15 .
- the radiation pattern may be adjusted to emit light preferentially in a chosen direction.
- the periodic structure is a variation of the thickness of one or more selected semiconductor layers.
- the periodic structure can include variations of the thickness along one direction within the plane of the semiconductor layers, but extending along a second direction without variation, in essence forming a set of parallel grooves.
- Two-dimensional periodic variations of the thickness include various lattices of indentations.
- the device illustrated in FIGS. 2 and 3 may be fabricated by the method illustrated in FIG. 4 .
- stage 31 epitaxial layers 20 of FIG. 2 are grown on a conventional growth substrate.
- the epitaxial layers are then attached to a host substrate in stage 33 , such that the growth substrate can be removed in stage 35 .
- the epitaxial layers may be thinned in optional stage 37 , then a photonic crystal structure is formed on the exposed surface of the epitaxial layers in stage 39 .
- FIG. 5 illustrates stage 31 of FIG. 4 in more detail.
- Epitaxial layers 20 of the device of FIG. 2 are grown on a substrate 40 such as sapphire, SiC, or GaN.
- Optional preparation layers 41 which may include, for example, buffer layers or nucleation layers, may be grown first on substrate 40 to provide a suitable growth substrate.
- One or more optional etch stop layers 42 may then be grown. Etch stop layers 42 may facilitate release of the growth substrate or facilitate thinning of the epitaxial layers, as described below.
- the epitaxial layers 20 are grown over etch stop layers 42 and include n-type region 108 , active region 112 , and p-type region 116 .
- the n-type region is grown first, followed by the active region and the p-type region.
- a p-contact 12 is formed on the surface of p-type region 116 .
- P-contact 12 may be a single layer or may include multiple layers such as an ohmic contact layer, a reflective layer, and a guard metal layer.
- the reflective layer is usually silver or aluminum.
- the guard metal may include, for example, nickel, titanium, or tungsten. The guard metal may be chosen to prevent the reflective metal layer from migrating, particularly in the case of a silver reflective layer, and to provide an adhesion layer for a bonding layer 14 A, used to bond the epitaxial structure to a host substrate.
- FIG. 6 illustrates stage 33 of FIG. 4 , attaching the epitaxial layers to a host substrate, in more detail.
- Bonding layers 14 A and 14 B typically metal, serve as compliant materials for thermo-compression or eutectic bonding between the epitaxial structure and the host substrate. Examples of suitable bonding layer metals include gold and silver.
- Host substrate 16 provides mechanical support to the epitaxial layers after the growth substrate is removed, and provides electrical contact to p-contact 12 .
- Host substrate 16 is selected to be electrically conductive (i.e. less than about 0.1 ⁇ cm), to be thermally conductive, to have a coefficient of thermal expansion (CTE) matched to that of the epitaxial layers, and to be flat (i.e.
- CTE coefficient of thermal expansion
- Suitable materials include, for example, metals such as Cu, Mo, Cu/Mo, and Cu/W; semiconductors with metal contacts (layers 46 and 18 of FIG. 6 ), such as Si with ohmic contacts and GaAs with ohmic contacts including, for example, one or more of Pd, Ge, Ti, Au, Ni, Ag; and ceramics such as compressed diamond.
- CTE Thermal conductivity Material (10 ⁇ 6 /K) (W/m ⁇ K) Electrical resistance ( ⁇ cm) GaN 2.4 130 0.01 Al 2 O 3 6.8 40 Very high Si 2.7 150 0.01 plus contact resistance GaAs 6.0 59 0.01 plus contact resistance Mo 4.8 140 5 ⁇ 10 ⁇ 6
- Host substrate structure 49 and epitaxial structure 48 are pressed together at elevated temperature and pressure to form a durable metal bond between bonding layers 14 A and 14 B.
- bonding is done on a wafer scale, before a wafer with an epitaxial structure is diced into individual devices.
- the temperature and pressure ranges for bonding are limited on the lower end by the strength of the resulting bond, and on the higher end by the stability of the host substrate structure and the epitaxial structure.
- high temperatures and/or high pressures can cause decomposition of the epitaxial layers in structure 48 , delamination of p-contact 12 , failure of diffusion barriers, for example in p-contact 12 , or outgassing of the component materials in the epitaxial layers.
- a suitable temperature range is, for example, about 200° C. to about 500° C.
- a suitable pressure range is, for example, about 100 psi to about 300 psi.
- FIG. 7 illustrates a method of removing a sapphire growth substrate, stage 35 in FIG. 4 .
- Portions of the interface between sapphire substrate 40 and the III-nitride layers 45 are exposed, through the sapphire substrate, to a high fluence pulsed ultraviolet laser 70 in a step and repeat pattern.
- the photon energy of the laser is above the band gap of the III-nitride layer adjacent to the sapphire (GaN in some embodiments), thus the pulse energy is effectively converted to thermal energy within the first 100 nm of epitaxial material adjacent to the sapphire.
- sufficiently high fluence i.e. greater than about 1.5 J/cm 2
- a photon energy above the band gap of GaN and below the absorption edge of sapphire i.e.
- the resulting structure includes epitaxial layers 45 bonded to host substrate structure 49 .
- Exposure to the laser pulse results in large temperature gradients and mechanical shock waves traveling outward from the exposed region, resulting in thermal and mechanical stress within the epitaxial material sufficient to cause cracking of the epitaxial material and failure of wafer bond 14 , which limits the yield of the substrate removal process.
- the damage caused by thermal and mechanical stresses may be reduced by patterning the epitaxial structure down to the sapphire substrate or down to a suitable depth of the epitaxial structure, to form trenches between individual devices on the wafer.
- the trenches are formed by conventional masking and dry etching techniques, before the wafer is bonded to the host substrate structure.
- the laser exposure region is then matched to the pattern of trenches on the wafer.
- the trench isolates the impact of the laser pulse to the semiconductor region being exposed.
- a suitable growth substrate may include a thin layer of SiC grown or processed on to a thick layer of Si or SiO x .
- the Si base layer and/or oxide layer may be easily removed by conventional silicon processing techniques.
- the remaining SiC layer may be thin enough to be removed entirely by known etching techniques.
- N-contact 10 may then be formed on the exposed surface of the epitaxial layers. Alternatively, N-contact 10 may be formed in the holes in the SiC layer.
- the remaining epitaxial layers may optionally be thinned to form a cavity between the photonic crystal and p-contact 12 of optimal depth and of uniform thickness, usually with thickness variations less than about 20 nm.
- the epitaxial layers may be thinned by, for example, chemical mechanical polishing, conventional dry etching, or photoelectrochemical etching (PEC). PEC is illustrated in FIG. 8 .
- the host substrate and epitaxial layers (structure 53 ) are immersed in a basic solution 50 .
- a suitable basic solution is 0.1 M KOH, though many other suitable basic solutions may be used and typically depend on the composition of the material to be etched.
- the epitaxial surface of structure 53 often an n-type GaN layer, is exposed to light with energy greater than the band gap of the surface layer.
- ultraviolet light with a wavelength of about 365 nm and an intensity between about 10 and about 100 mW/cm 2 is used. Exposure to the light generates electron-hole pairs in the surface semiconductor layer. The holes migrate to the surface of the epitaxial layers under the influence of the electric field in the n-type semiconductor.
- An external electric potential may be applied across electrodes 51 and 52 to accelerate and control the etching process.
- an etch stop layer is incorporated into the epitaxial layers, as described above in FIG. 4 .
- the etch stop layer may have a band gap greater than the layer to be etched.
- the etched layer may be GaN
- the etch stop layer may be AlGaN.
- the light sources used to expose structure 53 is selected to have an energy greater than the band gap of the layer to be etched, but less than the band gap of the etch stop layer. Accordingly, exposure to the light does not generate electron-hole pairs in the etch stop layer, effectively halting the etch once the etch stop layer is reached.
- InGaN may be used as the etch stop layer.
- Indium oxide, formed as the InGaN decomposes, is insoluble in the etchant solution and coats the surface of the etched layer, terminating the etch.
- n-type region 108 may be patterned such that the portion under contact 10 is thicker than the portion forming the photonic crystal, in order to minimize the thickness of the cavity, while providing enough n-type material under contact 10 for adequate current spreading, optimal contact resistance, and mechanical strength.
- FIGS. 9-12 illustrate a method of fabricating the photonic crystal structure of the device of FIG. 2 .
- One or more resist, metal, or dielectric layers 202 are formed over the top surface of the epitaxial layers, as illustrated in FIG. 9 .
- Resist layers 202 are patterned to form a lattice of openings in FIG. 10 , using a high resolution lithography technique such as electron beam lithography, nano-imprint lithography, deep X-ray lithography, interferometric lithography, hot embossing, or microcontact printing.
- a high resolution lithography technique such as electron beam lithography, nano-imprint lithography, deep X-ray lithography, interferometric lithography, hot embossing, or microcontact printing.
- epitaxial layers 200 are etched using known etching techniques.
- Damage caused by dry etching can be mitigated by a subsequent short wet chemical etch, anneal, a combination thereof, or other surface passivation techniques.
- the remaining resist layer 202 is then removed in FIG. 12 .
- Other techniques for forming a photonic crystal such as epitaxial lateral overgrowth, are described in more detail in application Ser. No. 10/059,588, “LED Efficiency Using Photonic Crystal Structure.” As illustrated in FIG. 2 , a portion of the surface of the exposed n-type layer may not be textured with a photonic crystal, such that n-contact 10 may be formed on a planar layer. After the photonic crystal is formed, n-contact 10 is deposited by conventional techniques.
- FIGS. 16A and 16B illustrate an alternative method for forming the photonic crystal. Rather than etching the photonic crystal after removing the growth substrate, a buried photonic crystal is formed during epitaxial growth.
- epitaxial growth is stopped before the active layers are grown.
- a photonic crystal is then formed in n-type region 108 , for example, by etching as illustrated above in FIGS. 9-12 .
- the material is then placed back into the growth reactor and first a smoothing n-type layer 310 , often GaN, is grown.
- the depth of the photonic crystal holes is greater than the diameter of the holes.
- the growth parameters of smoothing layer 310 are chosen so lateral growth is faster than vertical growth, ensuring that the photonic crystal holes are not filled.
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US10/804,810 US20050205883A1 (en) | 2004-03-19 | 2004-03-19 | Photonic crystal light emitting device |
EP05101807.5A EP1577958B1 (de) | 2004-03-19 | 2005-03-09 | Licht emittierendes Bauelement mit photonischem Kristall |
TW094107956A TWI366281B (en) | 2004-03-19 | 2005-03-16 | Light emitting device and method of forming a semiconductor light emitting device |
JP2005118867A JP2005317959A (ja) | 2004-03-19 | 2005-03-18 | 光結晶発光装置 |
US11/373,636 US7442965B2 (en) | 2004-03-19 | 2006-03-09 | Photonic crystal light emitting device |
US12/259,120 US7675084B2 (en) | 2004-03-19 | 2008-10-27 | Photonic crystal light emitting device |
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TW200603436A (en) | 2006-01-16 |
US7675084B2 (en) | 2010-03-09 |
EP1577958B1 (de) | 2019-12-11 |
EP1577958A1 (de) | 2005-09-21 |
US20060163606A1 (en) | 2006-07-27 |
JP2005317959A (ja) | 2005-11-10 |
US7442965B2 (en) | 2008-10-28 |
TWI366281B (en) | 2012-06-11 |
US20090045427A1 (en) | 2009-02-19 |
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