US20020091220A1 - Room temperature curable organopolysiloxane compositions - Google Patents
Room temperature curable organopolysiloxane compositions Download PDFInfo
- Publication number
- US20020091220A1 US20020091220A1 US09/974,843 US97484301A US2002091220A1 US 20020091220 A1 US20020091220 A1 US 20020091220A1 US 97484301 A US97484301 A US 97484301A US 2002091220 A1 US2002091220 A1 US 2002091220A1
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- US
- United States
- Prior art keywords
- parts
- composition
- radicals
- hydrocarbon radical
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 0 *C* Chemical compound *C* 0.000 description 3
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/045—Polysiloxanes containing less than 25 silicon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S528/901—Room temperature curable silicon-containing polymer
Definitions
- This invention relates to room temperature curable organopolysiloxane compositions capable of maintaining improved adhesion upon exposure to hot steam and useful in bonding and securing of architectural parts and electrical and electronic parts.
- RTV silicone rubber compositions which crosslink with moisture are used in a wide variety of applications including building sealants and adhesives for electrical and electronic parts.
- silicone rubber which crosslinks with moisture is often employed due to heat resistance and adherence.
- the silicone rubber as cured is required to have initial adherence and heat resistant adherence to the adherends, glass and coated steel plate and to maintain adherence even upon exposure to hot steam.
- silane coupling agents in the form of silicon compounds is effective.
- RTV silicone rubber compositions containing various conventional silane coupling agents such as aminopropyltriethoxysilane are good in initial adherence and heat resistant adherence, but fail to improve adherence upon exposure to hot steam.
- U.S. Pat. No. 4,629,775 and JP-A 61-64753 disclose RTV silicone rubber compositions comprising as adhesive aids the reaction product of a mercaptosilane with an isocyanate or polyisocyanate compound. They are good in initial adherence, but insufficient in adherence upon exposure to hot steam.
- An object of the invention is to provide a room temperature curable organopolysiloxane composition which can maintain adherence to glass even upon exposure to hot steam.
- the present invention provides a room temperature curable organopolysiloxane composition
- a room temperature curable organopolysiloxane composition comprising
- R 1 is a substituted or unsubstituted monovalent hydrocarbon radical of 1 to 10 carbon atoms, and n is an integer of at least 10, and/or an organopolysiloxane of the following general formula (2):
- R 1 and n are as defined above, R 2 is a substituted or unsubstituted monovalent hydrocarbon radical of 1 to 6 carbon atoms, and m is independently an integer of 0 or 1,
- R 1 and R 2 are as defined above, R 3 is a divalent hydrocarbon radical of 1 to 10 carbon atoms, R 4 is a divalent aromatic ring-bearing hydrocarbon radical of 7 to 10 carbon atoms, and p is an integer of 1 to 3, at least one of the NH and NH 2 radicals being not directly attached to the aromatic ring in R 4 .
- component (A) is an organopolysiloxane of the general formula (1) and/or (2).
- R 1 stands for a substituted or unsubstituted monovalent hydrocarbon radical of 1 to 10 carbon atoms, for example, alkyl radicals such as methyl, ethyl and propyl, cycloalkyl radicals such as cyclohexyl, alkenyl radicals such as vinyl and allyl, aryl radicals such as phenyl and tolyl, and substituted ones of the foregoing radicals in which some of the hydrogen atoms attached to carbon atoms are replaced by halogen atoms or the like, such as 3,3,3-trifluoropropyl. Of these, methyl is preferred.
- the plural R 1 radicals in formulae (1) and (2) may be the same or different.
- n is an integer of at least 10, preferably such an integer that the diorganopolysiloxane may have a viscosity of about 25 to 500,000 centistokes at 25° C., especially about 500 to 100,000 centistokes at 25° C.
- R 2 stands for a substituted or unsubstituted monovalent hydrocarbon radical of 1 to 6 carbon atoms, for example, alkyl radicals such as methyl, ethyl and propyl, cycloalkyl radicals such as cyclohexyl, alkenyl radicals such as vinyl, allyl and propenyl, and phenyl. Of these, methyl is preferred.
- the letter m is 0 or 1 independently on the right or left side.
- Component (B) is a silane compound having on the average at least two hydrolyzable radicals each attached to a silicon atom in a molecule, the remaining radicals attached to silicon atoms being selected from among methyl, ethyl, propyl, vinyl and phenyl, and/or a partial hydrolyzate thereof.
- the silane compound generally has the formula:
- R 5 is a radical selected from among methyl, ethyl, propyl, vinyl and phenyl
- X is a hydrolyzable radical
- a is 2 or 3.
- the silane compound may be used alone or in admixture of two or more.
- hydrolyzable radicals in the silane compound or partial hydrolyzates thereof include ketoxime, alkoxy, acetoxy and isopropenoxy radicals, with the ketoxime, alkoxy and isopropenoxy radicals being especially preferred.
- Illustrative examples of the silane compound (B) include ketoximesilanes such as methyltris(dimethyl ketoxime)silane, methyltris(methyl ethyl ketoxime)silane, ethyltris(methyl ethyl ketoxime)silane, methyltris(methyl isobutyl ketoxime)silane, vinyltris(methyl ethyl ketoxime)silane, and phenyltris(methyl ethyl ketoxime)silane; as well as alkoxysilanes such as methyltrimethoxysilane, dimethyldimethoxysilane, vinyltrimethoxysilane, phenyltrimethoxysilane and methyltriethoxysilane; isopropenoxy radical-containing silanes such as methyltriisopropenoxysilane, ethyltriisopropenoxysilane and vinyltriisopropenoxysi
- An appropriate amount of the silane compound or partial hydrolyzate thereof (B) used is 0.1 to 30 parts by weight, preferably 0.5 to 20 parts by weight, and more preferably 1 to 15 parts by weight per 100 parts by weight of the organopolysiloxane (A). Less than 0.1 part of component (B) induces insufficient crosslinking, failing to give a cured rubber having desired elasticity. More than 30 parts of component (B) tends to adversely affect mechanical properties of cured compositions.
- the organosilicon compound (C) has a critical function of enhancing the adherence of the composition upon exposure to steam.
- the organosilicon compound (C) should have an imino (NH) radical and an amino (NH 2 ) radical, and an aromatic ring between the NH and NH 2 radicals, such that at least one of the NH and NH 2 radicals is not directly attached to the aromatic ring.
- This compound is described in detail in U.S. Pat. No. 5,231,207.
- the organosilicon compound has the following general formula (3).
- R 1 and R 2 are as defined above, R 3 is a divalent hydrocarbon radical of 1 to 10 carbon atoms, R 4 is a divalent aromatic ring-bearing hydrocarbon radical of 7 to 10 carbon atoms, and p is an integer of 1 to 3, at least one of the NH and NH 2 radicals being not directly attached to the aromatic ring in R 4 .
- R 2 is preferably methyl or ethyl.
- divalent hydrocarbon radical represented by R 3 include alkylene radicals such as methylene, ethylene, propylene, tetramethylene, hexamethylene, octamethylene, decamethylene, and 2-methylpropylene, arylene radicals such as phenylene, and combinations of alkylene and arylene radicals.
- R 3 is methylene, ethylene or propylene, with the propylene being most preferred.
- R 4 is preferably a combination of phenylene with alkylene. Preferred combinations for R 4 include the following structures (4) to (12).
- the alkylene portion attached to the right side (NH 2 side in formula (3)) of the phenylene radical may be at the ortho, meta- or para-position of phenylene.
- organosilicon compound of formula (3) is given below by formulae (13) through (123).
- An appropriate amount of the organosilicon compound (C) used is 0.1 to 10 parts, and preferably 1 to 5 parts by weight per 100 parts by weight of the organopolysiloxane (A).
- Exemplary fillers are silica including ground silica, fumed silica and wet silica, carbonaceous powders such as carbon black including acetylene black, calcium carbonate, zinc carbonate, basic zinc carbonate, zinc oxide and magnesium oxide. Among them, silica and carbon black are preferred. The silica is preferably surface treated.
- the fillers are blended in amounts of 0 to about 500 parts, preferably about 2 to 200 parts, and more preferably about 3 to 100 parts by weight per 100 parts by weight of the organopolysiloxane (A).
- Useful catalysts include well-known condensation reaction catalysts such as organic tin ester compounds, organic tin chelate compounds, alkoxytitanium compounds, titanium chelate compounds, and guanidyl radical-bearing silicon compounds.
- the catalysts are used in catalytic amounts, usually up to about 10 parts, preferably 0.001 to 10 parts, and more preferably 0.01 to 5 parts by weight per 100 parts by weight of the organopolysiloxane (A).
- additives for example, polyethers for improving thixotropy, pigments, anti-mildew agents, and anti-fungus agents.
- composition of the invention may be prepared by mixing components (A) to (C) in a commonly used mixer such as a Shinagawa mixer, planetary mixer or flow jet mixer, preferably under anhydrous conditions.
- a commonly used mixer such as a Shinagawa mixer, planetary mixer or flow jet mixer, preferably under anhydrous conditions.
- Composition 1 was prepared by mixing 90 parts of a trimethoxysilyl end-blocked polydimethylsiloxane having a viscosity of 900 centistokes at 25° C. with 10 parts of fumed silica surface treated with dimethyldichlorosilane in a mixer. Then 2 parts of vinyltrimethoxysilane and 0.1 part of dioctyltin dilaurate were added to the mixture, which was thoroughly mixed under vacuum. Further, 2.0 parts of a silane compound of the formula:
- Composition 2 was prepared by mixing 90 parts of a silanol end-blocked polydimethylsiloxane having a viscosity of 700 centistokes at 25° C. with 10 parts of acetylene black in a mixer. Then 6 parts of methyltributanoximesilane and 0.1 part of dibutyltin dioctate were added to the mixture, which was thoroughly mixed under vacuum. Further, 2.0 parts of a silane compound of the formula:
- Composition 3 was prepared by mixing 90 parts of a silanol end-blocked polydimethylsiloxane having a viscosity of 700 centistokes at 25° C. with 10 parts of acetylene black in a mixer. Then 6 parts of vinyltriisopropenoxysilane and 0.5 part of tetramethylguanidylpropyltrimethoxysilane were added to the mixture, which was thoroughly mixed under vacuum. Further, 2.0 parts of a silane compound of the formula:
- Composition 4 was prepared by mixing 90 parts of a silanol end-blocked polydimethylsiloxane having a viscosity of 700 centistokes at 25° C. with 10 parts of acetylene black in a mixer. Then 6 parts of vinyltriisopropenoxysilane and 0.5 part of tetramethylguanidylpropyltrimethoxysilane were added to the mixture, which was thoroughly mixed under vacuum. Further, 2.0 parts of a silane compound of the formula:
- Composition 5 was prepared by mixing 90 parts of a silanol end-blocked polydimethylsiloxane having a viscosity of 700 centistokes at 25° C. with 10 parts of acetylene black in a mixer. Then 6 parts of vinyltriisopropenoxysilane and 0.5 part of tetramethylguanidylpropyltrimethoxysilane were added to the mixture, which was thoroughly mixed under vacuum. Further, 2.0 parts of a silane compound of the formula:
- Composition 6 was prepared by mixing 90 parts of a silanol end-blocked polydimethylsiloxane having a viscosity of 700 centistokes at 25° C. with 10 parts of acetylene black in a mixer. Then 6 parts of vinyltriisopropenoxysilane and 0.5 part of tetramethylguanidylpropyltrimethoxysilane were added to the mixture, which was thoroughly mixed under vacuum. Further, 2.0 parts of a silane compound of the formula:
- the room temperature curable organopolysiloxane composition of the invention cures into silicone rubber which can maintain adherence even upon exposure to hot steam.
- the silicone rubber finds use as sealants used in wet areas and in the bonding and securing of electrical and electronic parts which are to be exposed to water vapor.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/694,186 US7026426B2 (en) | 2000-10-12 | 2003-10-28 | Room temperature curable organopolysiloxane compositions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000312022A JP3714402B2 (ja) | 2000-10-12 | 2000-10-12 | 室温硬化性オルガノポリシロキサン組成物 |
JP2000-312022 | 2000-10-12 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/694,186 Division US7026426B2 (en) | 2000-10-12 | 2003-10-28 | Room temperature curable organopolysiloxane compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
US20020091220A1 true US20020091220A1 (en) | 2002-07-11 |
Family
ID=18791689
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/974,843 Abandoned US20020091220A1 (en) | 2000-10-12 | 2001-10-12 | Room temperature curable organopolysiloxane compositions |
US10/694,186 Expired - Lifetime US7026426B2 (en) | 2000-10-12 | 2003-10-28 | Room temperature curable organopolysiloxane compositions |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/694,186 Expired - Lifetime US7026426B2 (en) | 2000-10-12 | 2003-10-28 | Room temperature curable organopolysiloxane compositions |
Country Status (4)
Country | Link |
---|---|
US (2) | US20020091220A1 (de) |
EP (1) | EP1197525B1 (de) |
JP (1) | JP3714402B2 (de) |
DE (1) | DE60119468T2 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030162928A1 (en) * | 2002-02-05 | 2003-08-28 | Three Bond Co., Ltd. | One-pack room temperature-curable sealant composition for automobile |
US20060217498A1 (en) * | 2005-03-25 | 2006-09-28 | Shin-Etsu Chemical Co., Ltd. | Room temperature curable organopolysiloxane composition |
CN105348534A (zh) * | 2015-11-30 | 2016-02-24 | 苏州太湖电工新材料股份有限公司 | 一种纳米二氧化硅杂化乙烯基苯基硅中物、其制备方法及应用 |
CN109642079A (zh) * | 2016-08-26 | 2019-04-16 | 信越化学工业株式会社 | 脱醇型室温固化性有机聚硅氧烷组合物和用该组合物的固化物密封的物品 |
Families Citing this family (11)
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DE102004014216A1 (de) * | 2004-03-23 | 2005-10-13 | Wacker-Chemie Gmbh | Vernetzbare Massen auf der Basis von Organosiliciumverbindungen |
EP1879505B1 (de) * | 2005-04-29 | 2012-10-24 | Vivasure Medical Limited | Medizinische Interventionalverschlussvorrichtung |
JP4569765B2 (ja) * | 2005-05-13 | 2010-10-27 | 信越化学工業株式会社 | 電気・電子部品保護用室温硬化型シリコーンゴム組成物、並びに実装回路板、銀電極及び銀チップ抵抗器 |
JP4743511B2 (ja) * | 2005-12-27 | 2011-08-10 | 信越化学工業株式会社 | 熱硬化性オルガノポリシロキサン組成物の硬化方法 |
JP2007321122A (ja) * | 2006-06-05 | 2007-12-13 | Shin Etsu Chem Co Ltd | 室温硬化性オルガノポリシロキサン組成物 |
EP2166953B8 (de) * | 2007-06-15 | 2018-11-07 | Vivasure Medical Limited | Verschlussvorrichtung |
JP4984086B2 (ja) * | 2008-05-14 | 2012-07-25 | 信越化学工業株式会社 | 室温硬化性オルガノポリシロキサン組成物 |
DE102010042712A1 (de) * | 2010-10-20 | 2012-04-26 | Wacker Chemie Ag | Selbsthaftende Härterzusammensetzung |
JP6039894B2 (ja) | 2011-10-20 | 2016-12-07 | 東レ・ダウコーニング株式会社 | 多成分型室温硬化性シリコーンエラストマー組成物 |
KR20170106404A (ko) * | 2015-01-21 | 2017-09-20 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 실온 경화성 오르가노폴리실록산 조성물 |
CN105349034B (zh) * | 2015-11-30 | 2017-06-20 | 苏州太湖电工新材料股份有限公司 | 一种低粘度耐高温耐电晕环保绝缘漆及其制备方法 |
Family Cites Families (12)
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GB1238093A (de) * | 1969-04-11 | 1971-07-07 | ||
JPS6131461A (ja) * | 1984-07-24 | 1986-02-13 | Shin Etsu Chem Co Ltd | 室温硬化性オルガノシロキサン組成物 |
JPS6165891A (ja) | 1984-09-06 | 1986-04-04 | Asahi Shiyueebell Kk | 新規なシラン化合物およびその製造法 |
JPS6164753A (ja) | 1984-09-06 | 1986-04-03 | Shin Etsu Chem Co Ltd | 室温硬化性オルガノシロキサン組成物 |
JPS62232459A (ja) * | 1986-04-02 | 1987-10-12 | Shin Etsu Chem Co Ltd | 室温硬化性オルガノポリシロキサン組成物 |
JPH04359058A (ja) * | 1991-06-03 | 1992-12-11 | Shin Etsu Chem Co Ltd | 室温硬化性オルガノポリシロキサン組成物の製造方法 |
JP2538152B2 (ja) * | 1991-10-15 | 1996-09-25 | 信越化学工業株式会社 | 有機けい素化合物 |
US5300611A (en) * | 1991-10-21 | 1994-04-05 | Shin-Etsu Chemical Co., Ltd. | Room temperature curable organopolysiloxane compositions |
KR100323071B1 (ko) * | 1994-01-21 | 2002-07-08 | 와따루 이찌세 | 접착성조성물과그의경화방법 |
JP3295287B2 (ja) * | 1995-10-26 | 2002-06-24 | 信越化学工業株式会社 | オートマチックトランスミッションオイルシール用オルガノポリシロキサン組成物 |
JP3714861B2 (ja) * | 2000-09-20 | 2005-11-09 | 信越化学工業株式会社 | 室温硬化性オルガノポリシロキサン組成物 |
US6833407B1 (en) * | 2003-10-16 | 2004-12-21 | Csl Silicones Inc. | Solvent free silicone coating composition |
-
2000
- 2000-10-12 JP JP2000312022A patent/JP3714402B2/ja not_active Expired - Fee Related
-
2001
- 2001-10-10 DE DE60119468T patent/DE60119468T2/de not_active Expired - Lifetime
- 2001-10-10 EP EP01308654A patent/EP1197525B1/de not_active Expired - Lifetime
- 2001-10-12 US US09/974,843 patent/US20020091220A1/en not_active Abandoned
-
2003
- 2003-10-28 US US10/694,186 patent/US7026426B2/en not_active Expired - Lifetime
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030162928A1 (en) * | 2002-02-05 | 2003-08-28 | Three Bond Co., Ltd. | One-pack room temperature-curable sealant composition for automobile |
US6713546B2 (en) * | 2002-02-05 | 2004-03-30 | Three Bond Co., Ltd. | One-pack room temperature-curable sealant composition for automobile |
US20060217498A1 (en) * | 2005-03-25 | 2006-09-28 | Shin-Etsu Chemical Co., Ltd. | Room temperature curable organopolysiloxane composition |
US20090159203A1 (en) * | 2005-03-25 | 2009-06-25 | Shin-Etsu Chemical Co., Ltd. | Room temperature curable organopolysiloxane composition |
US7723442B2 (en) | 2005-03-25 | 2010-05-25 | Shin-Etsu Chemical Co., Ltd. | Room temperature curable organopolysiloxane composition |
CN105348534A (zh) * | 2015-11-30 | 2016-02-24 | 苏州太湖电工新材料股份有限公司 | 一种纳米二氧化硅杂化乙烯基苯基硅中物、其制备方法及应用 |
CN109642079A (zh) * | 2016-08-26 | 2019-04-16 | 信越化学工业株式会社 | 脱醇型室温固化性有机聚硅氧烷组合物和用该组合物的固化物密封的物品 |
US11401419B2 (en) * | 2016-08-26 | 2022-08-02 | Shin-Etsu Chemical Co., Ltd. | Dealcoholization room-temperature curable organopolysiloxane composition, and article sealed by cured product of same |
Also Published As
Publication number | Publication date |
---|---|
EP1197525A2 (de) | 2002-04-17 |
EP1197525A3 (de) | 2003-03-12 |
DE60119468T2 (de) | 2007-05-03 |
JP2002121385A (ja) | 2002-04-23 |
US7026426B2 (en) | 2006-04-11 |
EP1197525B1 (de) | 2006-05-10 |
JP3714402B2 (ja) | 2005-11-09 |
US20040092694A1 (en) | 2004-05-13 |
DE60119468D1 (de) | 2006-06-14 |
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