UA77953C2 - A method for preparing latex - Google Patents
A method for preparing latex Download PDFInfo
- Publication number
- UA77953C2 UA77953C2 UA2003076825A UA2003076825A UA77953C2 UA 77953 C2 UA77953 C2 UA 77953C2 UA 2003076825 A UA2003076825 A UA 2003076825A UA 2003076825 A UA2003076825 A UA 2003076825A UA 77953 C2 UA77953 C2 UA 77953C2
- Authority
- UA
- Ukraine
- Prior art keywords
- latexes
- monomers
- obtaining
- polymers
- seed
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 77
- 239000004816 latex Substances 0.000 title claims abstract description 71
- 229920000126 latex Polymers 0.000 title claims abstract description 71
- 239000000178 monomer Substances 0.000 claims abstract description 126
- 229920000642 polymer Polymers 0.000 claims abstract description 105
- 239000006185 dispersion Substances 0.000 claims abstract description 62
- 238000006116 polymerization reaction Methods 0.000 claims description 68
- 239000003999 initiator Substances 0.000 claims description 60
- 239000002245 particle Substances 0.000 claims description 42
- 238000009826 distribution Methods 0.000 claims description 28
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 27
- 239000011347 resin Substances 0.000 claims description 24
- 229920005989 resin Polymers 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 19
- 238000005345 coagulation Methods 0.000 claims description 13
- 230000015271 coagulation Effects 0.000 claims description 13
- 230000000737 periodic effect Effects 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 10
- 239000003381 stabilizer Substances 0.000 claims description 9
- 238000010526 radical polymerization reaction Methods 0.000 claims description 7
- 150000005690 diesters Chemical class 0.000 claims description 5
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 238000012876 topography Methods 0.000 claims 1
- 238000010899 nucleation Methods 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 description 61
- 239000002270 dispersing agent Substances 0.000 description 34
- 239000000243 solution Substances 0.000 description 26
- 239000007788 liquid Substances 0.000 description 23
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 21
- 125000004432 carbon atom Chemical group C* 0.000 description 18
- 239000003638 chemical reducing agent Substances 0.000 description 15
- 150000001451 organic peroxides Chemical class 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 150000008049 diazo compounds Chemical class 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- -1 peak quenchers Substances 0.000 description 8
- 239000003153 chemical reaction reagent Substances 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 238000007720 emulsion polymerization reaction Methods 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- MZQKADNPDLDGJD-UHFFFAOYSA-N 2,3,4,5-tetrapropylbenzenesulfonic acid Chemical compound CCCC1=CC(S(O)(=O)=O)=C(CCC)C(CCC)=C1CCC MZQKADNPDLDGJD-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 4
- 150000008052 alkyl sulfonates Chemical class 0.000 description 4
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 4
- 239000002952 polymeric resin Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 3
- 239000004970 Chain extender Substances 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 229920001944 Plastisol Polymers 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 3
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 3
- 150000008051 alkyl sulfates Chemical class 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000012933 diacyl peroxide Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 239000004999 plastisol Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004255 Butylated hydroxyanisole Substances 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 150000003926 acrylamides Chemical class 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 235000019282 butylated hydroxyanisole Nutrition 0.000 description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 2
- 229940043253 butylated hydroxyanisole Drugs 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- CWINGZLCRSDKCL-UHFFFAOYSA-N ethoxycarbonyloxy ethyl carbonate Chemical compound CCOC(=O)OOC(=O)OCC CWINGZLCRSDKCL-UHFFFAOYSA-N 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 150000002432 hydroperoxides Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 150000003385 sodium Chemical class 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- CSKKAINPUYTTRW-UHFFFAOYSA-N tetradecoxycarbonyloxy tetradecyl carbonate Chemical compound CCCCCCCCCCCCCCOC(=O)OOC(=O)OCCCCCCCCCCCCCC CSKKAINPUYTTRW-UHFFFAOYSA-N 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- ICAXUQIEOXHXKK-UHFFFAOYSA-N 1,4-dioxo-1,4-di(tridecoxy)butane-2-sulfonic acid Chemical compound CCCCCCCCCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCCCCCCCCC ICAXUQIEOXHXKK-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2,2'-azo-bis-isobutyronitrile Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 description 1
- XRUKRHLZDVJJSX-UHFFFAOYSA-N 4-cyanopentanoic acid Chemical compound N#CC(C)CCC(O)=O XRUKRHLZDVJJSX-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- JNCJGPIMMYWCBI-UHFFFAOYSA-N azane 1,2,3,4-tetrapropylbenzene Chemical compound N.CCCC1=CC=C(CCC)C(CCC)=C1CCC JNCJGPIMMYWCBI-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- PGOVCMQQKSNPOT-UHFFFAOYSA-N carboxyoxy cyclohexyl carbonate Chemical compound OC(=O)OOC(=O)OC1CCCCC1 PGOVCMQQKSNPOT-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
- YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 description 1
- XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- FRNAGPJXUXXMNR-UHFFFAOYSA-N diazanium;(2-nonylphenyl) phosphate Chemical class [NH4+].[NH4+].CCCCCCCCCC1=CC=CC=C1OP([O-])([O-])=O FRNAGPJXUXXMNR-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229940006487 lithium cation Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- GVRNEIKWGDQKPS-UHFFFAOYSA-N nonyl benzenesulfonate Chemical class CCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVRNEIKWGDQKPS-UHFFFAOYSA-N 0.000 description 1
- 150000002942 palmitic acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- HIDKSOTTZRMUML-UHFFFAOYSA-M potassium;dodecanoate Chemical class [K+].CCCCCCCCCCCC([O-])=O HIDKSOTTZRMUML-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical class [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- VLJNBZUVERYEMA-UHFFFAOYSA-M sodium;4-amino-4-oxo-2-sulfobutanoate Chemical class [Na+].NC(=O)CC(C([O-])=O)S(O)(=O)=O VLJNBZUVERYEMA-UHFFFAOYSA-M 0.000 description 1
- KQYLUTYUZIVHND-UHFFFAOYSA-N tert-butyl 2,2-dimethyloctaneperoxoate Chemical compound CCCCCCC(C)(C)C(=O)OOC(C)(C)C KQYLUTYUZIVHND-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0017073A FR2818649B1 (fr) | 2000-12-21 | 2000-12-21 | Procede de preparation de latex |
| PCT/EP2001/015381 WO2002050140A2 (fr) | 2000-12-21 | 2001-12-20 | Procede de preparation de latex |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA77953C2 true UA77953C2 (en) | 2007-02-15 |
Family
ID=8858238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA2003076825A UA77953C2 (en) | 2000-12-21 | 2001-12-20 | A method for preparing latex |
Country Status (30)
| Country | Link |
|---|---|
| US (1) | US7067578B2 (sl) |
| EP (1) | EP1358228B1 (sl) |
| JP (1) | JP4275411B2 (sl) |
| KR (1) | KR100854014B1 (sl) |
| CN (1) | CN100434446C (sl) |
| AT (1) | ATE376561T1 (sl) |
| AU (2) | AU2002229689B2 (sl) |
| BR (1) | BR0116386B1 (sl) |
| CA (1) | CA2432539C (sl) |
| CZ (1) | CZ20031714A3 (sl) |
| DE (1) | DE60131099T2 (sl) |
| DK (1) | DK1358228T3 (sl) |
| ES (1) | ES2295234T3 (sl) |
| FR (1) | FR2818649B1 (sl) |
| HU (1) | HUP0500959A3 (sl) |
| IL (1) | IL156481A0 (sl) |
| ME (1) | MEP41708A (sl) |
| MX (1) | MXPA03005652A (sl) |
| MY (1) | MY129839A (sl) |
| NO (1) | NO330325B1 (sl) |
| PL (1) | PL202977B1 (sl) |
| PT (1) | PT1358228E (sl) |
| RS (1) | RS50950B (sl) |
| RU (1) | RU2289594C2 (sl) |
| SI (1) | SI1358228T1 (sl) |
| SK (1) | SK287478B6 (sl) |
| TW (1) | TW583196B (sl) |
| UA (1) | UA77953C2 (sl) |
| WO (1) | WO2002050140A2 (sl) |
| ZA (1) | ZA200304763B (sl) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1379563A2 (fr) * | 2001-01-10 | 2004-01-14 | Solvay (Societe Anonyme) | Procede de preparation de polymeres halogenes en deux etapes et polymeres halogenes plurimodales |
| MX2017004771A (es) | 2014-10-13 | 2017-10-12 | Avery Dennison Corp | Emulsiones y productos de polímero de etilvinilacetato/acrílico y métodos relacionados con estos. |
| KR101898320B1 (ko) * | 2015-12-16 | 2018-10-04 | 주식회사 엘지화학 | 염화비닐계 중합체, 이의 제조방법 및 이를 포함하는 플라스티졸 |
| JP7105923B2 (ja) * | 2018-10-08 | 2022-07-25 | エルジー・ケム・リミテッド | 塩化ビニル系重合体重合用組成物及びこれを用いた塩化ビニル系重合体の製造方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE152347C (sl) * | ||||
| FR2044364A5 (sl) * | 1969-05-19 | 1971-02-19 | Pechiney Saint Gobain | |
| US3935151A (en) * | 1973-10-10 | 1976-01-27 | Borden, Inc. | Blended latex binder for exterior paints with wet primed adhesion |
| HU173513B (hu) * | 1975-04-30 | 1979-05-28 | Rhone Poulenc Ind | Sposob polimerizacii vinilkhlorida v sshitojj mikrosuspensii |
| US4327003A (en) * | 1975-08-30 | 1982-04-27 | Industrial Technology Research Institute | Polymerization process for the production of PVC latex and paste resin |
| US4168373A (en) * | 1975-11-24 | 1979-09-18 | Borden, Inc. | Removal of residual vinyl chloride monomer from polyvinyl chloride latex |
| SE430896B (sv) * | 1979-12-06 | 1983-12-19 | Kema Nord Ab | Forfarande for polymerisation av vinylklorid i nervaro av en stabiliserande polymerlatex |
| DE3132694C2 (de) * | 1981-08-19 | 1983-06-16 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von rieselfähigen, nicht klebenden Vinylchloridpfropfpolymeren |
| US4654392A (en) * | 1985-07-12 | 1987-03-31 | The Goodyear Tire & Rubber Company | BHA in vinyl chloride polymerization |
| KR100191378B1 (ko) * | 1989-09-18 | 1999-06-15 | 후루타 다케시 | 비닐 클로라이드 수지를 제조하기위한 미세현탁중합법 |
| BE1004570A3 (fr) * | 1990-09-17 | 1992-12-15 | Solvay | Procede pour la production de latex plurimodaux de polymeres du chlorure de vinyle. |
| DE4443752A1 (de) * | 1994-12-08 | 1996-06-13 | Vinnolit Kunststoff Gmbh | Verfahren zur radikalischen Polymerisation ethylenisch ungesättigter Monomere in wäßrigem Medium |
| CN1165150A (zh) * | 1995-11-22 | 1997-11-19 | 三菱化学株式会社 | 氯乙烯聚合物水分散体 |
| EP0810241A1 (fr) * | 1996-05-31 | 1997-12-03 | Elf Atochem S.A. | Latex bipopulé de copolymères du chlorure de vinyle, son procédé de fabrication et ses applications |
| JP3563234B2 (ja) * | 1997-05-16 | 2004-09-08 | 新第一塩ビ株式会社 | 塩化ビニル系重合体ラテックスの製造方法 |
| US6277954B2 (en) * | 1999-09-14 | 2001-08-21 | Kaneka Corporation | Method of stripping for latex of vinyl chloride paste resin, stripping apparatus, and vinyl chloride paste resin latex having low concentration of residual monomer |
-
2000
- 2000-12-21 FR FR0017073A patent/FR2818649B1/fr not_active Expired - Fee Related
-
2001
- 2001-12-20 WO PCT/EP2001/015381 patent/WO2002050140A2/fr active IP Right Grant
- 2001-12-20 RU RU2003122229/04A patent/RU2289594C2/ru not_active IP Right Cessation
- 2001-12-20 KR KR1020037008222A patent/KR100854014B1/ko not_active IP Right Cessation
- 2001-12-20 PT PT01990596T patent/PT1358228E/pt unknown
- 2001-12-20 EP EP01990596A patent/EP1358228B1/fr not_active Expired - Lifetime
- 2001-12-20 JP JP2002552030A patent/JP4275411B2/ja not_active Expired - Fee Related
- 2001-12-20 HU HU0500959A patent/HUP0500959A3/hu unknown
- 2001-12-20 BR BRPI0116386-8A patent/BR0116386B1/pt not_active IP Right Cessation
- 2001-12-20 CN CNB01822802XA patent/CN100434446C/zh not_active Expired - Fee Related
- 2001-12-20 DE DE60131099T patent/DE60131099T2/de not_active Expired - Lifetime
- 2001-12-20 AT AT01990596T patent/ATE376561T1/de active
- 2001-12-20 TW TW090131719A patent/TW583196B/zh not_active IP Right Cessation
- 2001-12-20 CZ CZ20031714A patent/CZ20031714A3/cs unknown
- 2001-12-20 ME MEP-417/08A patent/MEP41708A/xx unknown
- 2001-12-20 UA UA2003076825A patent/UA77953C2/uk unknown
- 2001-12-20 DK DK01990596T patent/DK1358228T3/da active
- 2001-12-20 US US10/450,533 patent/US7067578B2/en not_active Expired - Fee Related
- 2001-12-20 AU AU2002229689A patent/AU2002229689B2/en not_active Ceased
- 2001-12-20 ES ES01990596T patent/ES2295234T3/es not_active Expired - Lifetime
- 2001-12-20 AU AU2968902A patent/AU2968902A/xx active Pending
- 2001-12-20 MY MYPI20015791A patent/MY129839A/en unknown
- 2001-12-20 SK SK798-2003A patent/SK287478B6/sk not_active IP Right Cessation
- 2001-12-20 RS YUP-572/03A patent/RS50950B/sr unknown
- 2001-12-20 CA CA2432539A patent/CA2432539C/en not_active Expired - Fee Related
- 2001-12-20 SI SI200130799T patent/SI1358228T1/sl unknown
- 2001-12-20 MX MXPA03005652A patent/MXPA03005652A/es active IP Right Grant
- 2001-12-20 IL IL15648101A patent/IL156481A0/xx not_active IP Right Cessation
- 2001-12-20 PL PL362406A patent/PL202977B1/pl not_active IP Right Cessation
-
2003
- 2003-06-19 ZA ZA200304763A patent/ZA200304763B/en unknown
- 2003-06-20 NO NO20032843A patent/NO330325B1/no not_active IP Right Cessation
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2461083C2 (sl) | ||
| DE1570312A1 (de) | Verfahren zur Herstellung von Polymerisatdispersionen | |
| DE1595848C3 (de) | Verfahren zur Herstellung von Vinylchloridpolymerisaten | |
| DE2532021A1 (de) | Verfahren fuer die massenpolymerisation von vinylhalogenidpolymeren mit verminderter belagbildung im reaktor | |
| UA77953C2 (en) | A method for preparing latex | |
| EP0915106B1 (de) | Verfahren zur Herstellung von Homo- und Mischpolymerisaten des Vinylchlorids | |
| EP0016461B1 (de) | Verfahren zur Polymerisation von Vinylchlorid nach dem Mikrosuspensionsverfahren | |
| EP0072544B1 (de) | Kontinuierliches Verfahren zur Herstellung von Vinylchloridpolymerisaten in wässriger Suspension | |
| JPH1087707A (ja) | ２つの平均粒径を有する塩化ビニルをベースとするポリマーのラテックスと、その製造方法と、流動特性が改善されたプラスチゾルへのその応用 | |
| EP1395614B1 (de) | Verfahren zur herstellung einer wässrigen polymerdispersion durch radikalische wässrige emulsionspolymerisation mit einer kontinuierlich hergestellten wässrigen monomerenemulsion | |
| DE19928934A1 (de) | Verfahren zur Minderung der Geruchsemission wässriger Vinylaromat-1,3-Dien-Copolymerisatdispersionen | |
| JP4151419B2 (ja) | ペースト用塩化ビニル系重合体ラテックス、その製造方法及びそれよりなるペースト加工用塩化ビニル系樹脂の製造方法 | |
| KR102546715B1 (ko) | 염화비닐계 중합체 중합용 조성물 및 이를 이용한 염화비닐계 중합체의 제조방법 | |
| JP2018024739A (ja) | 塩化ビニル系樹脂シードの製造方法 | |
| JP2000219702A (ja) | 塩化ビニル重合体ラテックスの製造方法 | |
| DE1261673B (de) | Verfahren zur Herstellung von Pfropfcopolymerisaten | |
| DE4338878A1 (de) | Verfahren zur Herstellung von feinteiligem Polyacrylnitril | |
| JP4228203B2 (ja) | 共重合体ラテックスの製造方法 | |
| DE3132694A1 (de) | Verfahren zur herstellung von rieselfaehigen, nicht klebenden vinylchloridpfropfpolymeren | |
| DE2735022A1 (de) | Nach-massenpolymerisationsverfahren fuer polyvinylhalogenide und die dabei erhaltenen zusammensetzungen | |
| DE2163194A1 (de) | Gemische aus einem starren Polymeren von Vinylchlorid und Kautschuk enthaltenden Interpolymerteilchen | |
| DE3200203A1 (de) | Verfahren zur herstellung von pfropfpolymerisaten des vinylchlorids | |
| EP0057913A2 (de) | Verfahren zur Herstellung von Homo-, Co- oder Pfropfpolymerisaten des Vinylchlorids | |
| JPS62119210A (ja) | 塩化ビニル系樹脂製造方法 |